1.
Petrology
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Petrology is the branch of geology that studies the origin, composition, distribution and structure of rocks. In the petroleum industry, lithology, or more specifically mud logging, is the representation of geological formations being drilled through. As the cuttings are circulated out of the borehole they are sampled, examined and tested chemically when needed, Petrology utilizes the fields of mineralogy, petrography, optical mineralogy, and chemical analysis to describe the composition and texture of rocks. Igneous rocks include volcanic and plutonic rocks, sedimentary petrology focuses on the composition and texture of sedimentary rocks. Experiments are particularly useful for investigating rocks of the lower crust and they are also one of the prime sources of information about completely inaccessible rocks such as those in the Earths lower mantle and in the mantles of the other terrestrial planets and the Moon. The work of experimental petrologists has laid a foundation on which modern understanding of igneous, important publications in petrology Ore Soil Best, Myron G. Igneous and Metamorphic Petrology. ISBN 1-4051-0588-7 Blatt, Harvey, Tracy, Robert J. Owens, Brent, Petrology, igneous, sedimentary, ISBN 978-0-7167-3743-8 Dietrich, Richard Vincent, Skinner, Brian J. Gems, Granites, and Gravels, knowing and using rocks and minerals. ISBN 978-0-521-10722-8 Fei, Yingwei, Bertka, Constance M. Mysen, mantle Petrology, field observations and high-pressure experimentation. ISBN 0-941809-05-6 Philpotts, Anthony, Ague, Jay, Principles of Igneous and Metamorphic Petrology
2.
Chemical element
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A chemical element or element is a species of atoms having the same number of protons in their atomic nuclei. There are 118 elements that have identified, of which the first 94 occur naturally on Earth with the remaining 24 being synthetic elements. There are 80 elements that have at least one stable isotope and 38 that have exclusively radioactive isotopes, iron is the most abundant element making up Earth, while oxygen is the most common element in the Earths crust. Chemical elements constitute all of the matter of the universe. The two lightest elements, hydrogen and helium, were formed in the Big Bang and are the most common elements in the universe. The next three elements were formed mostly by cosmic ray spallation, and are rarer than those that follow. Formation of elements with from 6 to 26 protons occurred and continues to occur in main sequence stars via stellar nucleosynthesis, the high abundance of oxygen, silicon, and iron on Earth reflects their common production in such stars. The term element is used for atoms with a number of protons as well as for a pure chemical substance consisting of a single element. A single element can form multiple substances differing in their structure, when different elements are chemically combined, with the atoms held together by chemical bonds, they form chemical compounds. Only a minority of elements are found uncombined as relatively pure minerals, among the more common of such native elements are copper, silver, gold, carbon, and sulfur. All but a few of the most inert elements, such as gases and noble metals, are usually found on Earth in chemically combined form. While about 32 of the elements occur on Earth in native uncombined forms. For example, atmospheric air is primarily a mixture of nitrogen, oxygen, and argon, the history of the discovery and use of the elements began with primitive human societies that found native elements like carbon, sulfur, copper and gold. Later civilizations extracted elemental copper, tin, lead and iron from their ores by smelting, using charcoal, alchemists and chemists subsequently identified many more, almost all of the naturally occurring elements were known by 1900. Save for unstable radioactive elements with short half-lives, all of the elements are available industrially, almost all other elements found in nature were made by various natural methods of nucleosynthesis. On Earth, small amounts of new atoms are produced in nucleogenic reactions, or in cosmogenic processes. Of the 94 naturally occurring elements, those with atomic numbers 1 through 82 each have at least one stable isotope, Isotopes considered stable are those for which no radioactive decay has yet been observed. Elements with atomic numbers 83 through 94 are unstable to the point that radioactive decay of all isotopes can be detected, the very heaviest elements undergo radioactive decay with half-lives so short that they are not found in nature and must be synthesized
3.
Ion
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An ion is an atom or a molecule in which the total number of electrons is not equal to the total number of protons, giving the atom or molecule a net positive or negative electrical charge. Ions can be created, by chemical or physical means. In chemical terms, if an atom loses one or more electrons. If an atom gains electrons, it has a net charge and is known as an anion. Ions consisting of only a single atom are atomic or monatomic ions, because of their electric charges, cations and anions attract each other and readily form ionic compounds, such as salts. In the case of ionization of a medium, such as a gas, which are known as ion pairs are created by ion impact, and each pair consists of a free electron. The word ion comes from the Greek word ἰόν, ion, going and this term was introduced by English physicist and chemist Michael Faraday in 1834 for the then-unknown species that goes from one electrode to the other through an aqueous medium. Faraday also introduced the words anion for a charged ion. In Faradays nomenclature, cations were named because they were attracted to the cathode in a galvanic device, arrhenius explanation was that in forming a solution, the salt dissociates into Faradays ions. Arrhenius proposed that ions formed even in the absence of an electric current, ions in their gas-like state are highly reactive, and do not occur in large amounts on Earth, except in flames, lightning, electrical sparks, and other plasmas. These gas-like ions rapidly interact with ions of charge to give neutral molecules or ionic salts. These stabilized species are commonly found in the environment at low temperatures. A common example is the present in seawater, which are derived from the dissolved salts. Electrons, due to their mass and thus larger space-filling properties as matter waves, determine the size of atoms. Thus, anions are larger than the parent molecule or atom, as the excess electron repel each other, as such, in general, cations are smaller than the corresponding parent atom or molecule due to the smaller size of its electron cloud. One particular cation contains no electrons, and thus consists of a single proton - very much smaller than the parent hydrogen atom. Since the electric charge on a proton is equal in magnitude to the charge on an electron, an anion, from the Greek word ἄνω, meaning up, is an ion with more electrons than protons, giving it a net negative charge. A cation, from the Greek word κατά, meaning down, is an ion with fewer electrons than protons, there are additional names used for ions with multiple charges
4.
Mineral
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A mineral is a naturally occurring chemical compound, usually of crystalline form and abiogenic in origin. A mineral has one specific chemical composition, whereas a rock can be an aggregate of different minerals or mineraloids, the study of minerals is called mineralogy. There are over 5,300 known mineral species, over 5,070 of these have been approved by the International Mineralogical Association, the silicate minerals compose over 90% of the Earths crust. The diversity and abundance of species is controlled by the Earths chemistry. Silicon and oxygen constitute approximately 75% of the Earths crust, which translates directly into the predominance of silicate minerals, minerals are distinguished by various chemical and physical properties. Differences in chemical composition and crystal structure distinguish the various species, changes in the temperature, pressure, or bulk composition of a rock mass cause changes in its minerals. Minerals can be described by their various properties, which are related to their chemical structure. Common distinguishing characteristics include crystal structure and habit, hardness, lustre, diaphaneity, colour, streak, tenacity, cleavage, fracture, parting, more specific tests for describing minerals include magnetism, taste or smell, radioactivity and reaction to acid. Minerals are classified by key chemical constituents, the two dominant systems are the Dana classification and the Strunz classification, the silicate class of minerals is subdivided into six subclasses by the degree of polymerization in the chemical structure. All silicate minerals have a unit of a 4− silica tetrahedron—that is, a silicon cation coordinated by four oxygen anions. These tetrahedra can be polymerized to give the subclasses, orthosilicates, disilicates, cyclosilicates, inosilicates, phyllosilicates, other important mineral groups include the native elements, sulfides, oxides, halides, carbonates, sulfates, and phosphates. The first criterion means that a mineral has to form by a natural process, stability at room temperature, in the simplest sense, is synonymous to the mineral being solid. More specifically, a compound has to be stable or metastable at 25 °C, modern advances have included extensive study of liquid crystals, which also extensively involve mineralogy. Minerals are chemical compounds, and as such they can be described by fixed or a variable formula, many mineral groups and species are composed of a solid solution, pure substances are not usually found because of contamination or chemical substitution. Finally, the requirement of an ordered atomic arrangement is usually synonymous with crystallinity, however, crystals are also periodic, an ordered atomic arrangement gives rise to a variety of macroscopic physical properties, such as crystal form, hardness, and cleavage. There have been recent proposals to amend the definition to consider biogenic or amorphous substances as minerals. The formal definition of an approved by the IMA in 1995, A mineral is an element or chemical compound that is normally crystalline. However, if geological processes were involved in the genesis of the compound, Mineral classification schemes and their definitions are evolving to match recent advances in mineral science
5.
Partition coefficient
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In the physical sciences, a partition-coefficient or distribution-coefficient is the ratio of concentrations of a compound in a mixture of two immiscible phases at equilibrium. This ratio is therefore a measure of the difference in solubility of the compound in two phases. In the chemical and pharmaceutical sciences, both phases usually are solvents, most commonly, one of the solvents is water while the second is hydrophobic such as 1-octanol. Hence the partition coefficient measures how hydrophilic or hydrophobic a chemical substance is, partition coefficients are useful in estimating the distribution of drugs within the body. Hydrophobic drugs with high octanol/water partition coefficients are distributed to hydrophobic areas such as lipid bilayers of cells. Conversely hydrophilic drugs are primarily in aqueous regions such as blood serum. If one of the solvents is a gas and the other a liquid, for example, the blood/gas partition coefficient of a general anesthetic measures how easily the anesthetic passes from gas to blood. Partition coefficients can also be defined one of the phases is solid, for instance, when one phase is a molten metal. The partitioning of a substance into a solid results in a solid solution, partition coefficients can be measured experimentally in various ways or estimated via calculation based on a variety of methods. Despite formal recommendation to the contrary, the partition coefficient remains the predominantly used term in the scientific literature. In contrast, the IUPAC recommends that the term no longer be used, rather. When one of the solvents is water and the other is a non-polar solvent, for measurements of distribution coefficients, the pH of the aqueous phase is buffered to a specific value such that the pH is not significantly perturbed by the introduction of the compound. In addition, since log D is pH-dependent, the pH at which the log D was measured must be specified. In areas such as drug discovery—areas involving partition phenomena in systems such as the human body—the log D at the physiologic pH,7.4, is of particular interest. It is often convenient to express the log D in terms of P I, defined above, the values in the following table are from the Dortmund Data Bank. They are sorted by the coefficient, smallest to largest. Values for other compounds may be found in a variety of available reviews, critical discussions of the challenges of measurement of log P, and related computation of its estimated values, appear in several reviews. Hence, the log P of a molecule is one used in decision-making by medicinal chemists in pre-clinical drug discovery, for example
6.
Magma
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Besides molten rock, magma may also contain suspended crystals, dissolved gas and sometimes gas bubbles. Magma often collects in magma chambers that may feed a volcano or solidify underground to form an intrusion, magma is capable of intruding into adjacent rocks, extrusion onto the surface as lava, and explosive ejection as tephra to form pyroclastic rock. Magma is a complex high-temperature fluid substance, temperatures of most magmas are in the range 700 °C to 1300 °C, but very rare carbonatite magmas may be as cool as 600 °C, and komatiite magmas may have been as hot as 1600 °C. Environments of magma formation and compositions are commonly correlated, environments include subduction zones, continental rift zones, mid-ocean ridges and hotspots. Despite being found in such locales, the bulk of the Earths crust. Except for the outer core, most of the Earth takes the form of a rheid. Magma, as liquid, preferentially forms in high temperature, low pressure environments within several kilometers of the Earths surface, magma compositions may evolve after formation by fractional crystallization, contamination, and magma mixing. By definition rock formed of solidified magma is called igneous rock, melting of solid rocks to form magma is controlled by three physical parameters, temperature, pressure, and composition. Mechanisms are discussed in the entry for igneous rock, as a rock melts, its volume changes. When enough rock is melted, the small globules of melt link up, under pressure within the earth, as little as a fraction of a percent partial melting may be sufficient to cause melt to be squeezed from its source. The degree of melting is critical for determining what type of magma is produced. The degree of partial melting required to form a melt can be estimated by considering the relative enrichment of incompatible elements versus compatible elements, incompatible elements commonly include potassium, barium, cesium, and rubidium. Rock types produced by small degrees of melting in the Earths mantle are typically alkaline. Typically, primitive melts of this composition form lamprophyre, lamproite, kimberlite and sometimes nepheline-bearing mafic rocks such as alkali basalts, pegmatite may be produced by low degrees of partial melting of the crust. Some granite-composition magmas are eutectic melts, and they may be produced by low to high degrees of melting of the crust. At high degrees of melting of the crust, granitoids such as tonalite, granodiorite and monzonite can be produced. Being only the time in recorded history that magma had been reached, IDDP decided to invest in the hole. A cemented steel case was constructed in the hole with a perforation at the close to the magma
7.
Fractional crystallization (geology)
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Fractional crystallization, or crystal fractionation, is one of the most important geochemical and physical processes operating within the Earths crust and mantle. It is one of the processes of magmatic differentiation. Fractional crystallization is the removal and segregation from a melt of mineral precipitates, except in special cases, in essence, fractional crystallization is the removal of early formed crystals from an originally homogeneous magma so that these crystals are prevented from further reaction with the residual melt. The composition of the melt becomes relatively depleted in some components and enriched in others. Addition and loss of water, carbon dioxide, hydrogen, for example, the partial pressure of water in silicate melts can be of prime importance, as in near-solidus crystallization of magmas of granite composition. Experiments have provided examples of the complexities that control which mineral is crystallized first as the melt cools down past the liquidus. One example concerns crystallization of melts that form mafic and ultramafic rocks, mgO and SiO2 concentrations in melts are among the variables that determine whether forsterite olivine or enstatite pyroxene is precipitated, but the water content and pressure are also important. In some compositions, at high pressures without water crystallization of enstatite is favored, granitic magmas provide additional examples of how melts of generally similar composition and temperature, but at different pressure, may crystallize different minerals. Pressure determines the water content of a magma of granite composition. During the process of crystallization, melts become enriched in incompatible elements. Hence, knowledge of the sequence is critical in understanding how melt compositions evolve. Textures of rocks provide insights, as documented in the early 1900s by Bowens reaction series, a variety of Cr, Fe, and Ti oxides show such textures, like intergranular chromite in a siliceous matrix. Experimentally-determined phase diagrams for simple mixtures provide insights into general principles, numerical calculations with special software have become increasingly able to simulate natural processes accurately. Cumulate rock Flow banding Fractional crystallization Igneous differentiation Layered intrusion
8.
Mantle (geology)
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The mantle is a layer inside a terrestrial planet and some other rocky planetary bodies. For a mantle to form, the body must be large enough to have undergone the process of planetary differentiation by density. The mantle surrounds the planetary core, the mantle is surrounded by the crust. The terrestrial planets, the Moon, two of Jupiters moons and the asteroid Vesta each have a made of silicate rock. Interpretation of spacecraft data suggests that at least two moons of Jupiter, as well as Titan and Triton each have a mantle made of ice or other solid volatile substances. The interior of Earth, similar to the terrestrial planets, is divided into layers of different composition. The mantle is a layer between the crust and the outer core, Earths mantle is a silicate rocky shell with an average thickness of 2,886 kilometres. The mantle makes up about 84% of Earths volume and it is predominantly solid but in geological time it behaves as a very viscous fluid. The mantle encloses the hot core rich in iron and nickel, past episodes of melting and volcanism at the shallower levels of the mantle have produced a thin crust of crystallized melt products near the surface. A thin crust, the part of the lithosphere, surrounds the mantle and is about 5 to 75 km thick. In some places under the ocean the mantle is exposed on the surface of Earth. The mantle is divided into sections which are based upon results from seismology and these layers are the following, the upper mantle, the transition zone, the lower mantle, and anomalous core–mantle boundary with a variable thickness. The uppermost mantle plus overlying crust are relatively rigid and form the lithosphere, below the lithosphere the upper mantle becomes notably more plastic. In some regions below the lithosphere, the shear velocity is reduced. Inge Lehmann discovered a seismic discontinuity at about 220 km depth, although this discontinuity has been found in other studies, the transition zone is an area of great complexity, it physically separates the upper and lower mantle. Very little is known about the lower mantle apart from that it appears to be relatively seismically homogeneous, the D layer at the core–mantle boundary separates the mantle from the core. A principal source of the heat that drives plate tectonics is the decay of uranium, thorium. The mantle differs substantially from the crust in its properties as the direct consequence of the difference in composition
9.
Crust (geology)
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In geology, the crust is the outermost solid shell of a rocky planet or natural satellite, which is chemically distinct from the underlying mantle. The crust of the Earth is composed of a variety of igneous, metamorphic. The crust is underlain by the mantle, the upper part of the mantle is composed mostly of peridotite, a rock denser than rocks common in the overlying crust. The boundary between the crust and mantle is conventionally placed at the Mohorovičić discontinuity, a boundary defined by a contrast in seismic velocity, the crust occupies less than 1% of Earths volume. The crust of the Earth is of two types, oceanic and continental. The oceanic crust is 5 km to 10 km thick and is composed primarily of basalt, diabase, the continental crust is typically from 30 km to 50 km thick and is mostly composed of slightly less dense rocks than those of the oceanic crust. Some of these less dense rocks, such as granite, are common in the continental crust, both the continental and oceanic crust float on the mantle. Because the continental crust is thicker, it both to greater elevations and greater depth than the oceanic crust. The slightly lower density of continental rock compared to basaltic oceanic rock contributes to the higher relative elevation of the top of the continental crust. As the top of the continental crust reaches elevations higher than that of the oceanic, the temperature of the crust increases with depth, reaching values typically in the range from about 200 °C to 400 °C at the boundary with the underlying mantle. The crust and underlying relatively rigid uppermost mantle make up the lithosphere, because of convection in the underlying plastic upper mantle and asthenosphere, the lithosphere is broken into tectonic plates that move. The temperature increases by as much as 30 °C for every kilometer locally in the part of the crust. Earth has probably always had some form of basaltic crust, in contrast, the bulk of the continental crust is much older. The oldest continental crustal rocks on Earth have ages in the range from about 3.7 to 4, some zircon with age as great as 4.3 billion years has been found in the Narryer Gneiss Terrane. The average age of the current Earths continental crust has been estimated to be about 2.0 billion years, most crustal rocks formed before 2.5 billion years ago are located in cratons. Such old continental crust and the underlying mantle asthenosphere are less dense than elsewhere in Earth, formation of new continental crust is linked to periods of intense orogeny, these periods coincide with the formation of the supercontinents such as Rodinia, Pangaea and Gondwana. The continental crust has a composition similar to that of andesite. The most abundant minerals in Earths continental crust are feldspars, which make up about 41% of the crust by weight, followed by quartz at 12%, Continental crust is enriched in incompatible elements compared to the basaltic ocean crust and much enriched compared to the underlying mantle
