1.
System of measurement
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A system of measurement is a collection of units of measurement and rules relating them to each other. Systems of measurement have historically been important, regulated and defined for the purposes of science and commerce, systems of measurement in modern use include the metric system, the imperial system, and United States customary units. The French Revolution gave rise to the system, and this has spread around the world. In most systems, length, mass, and time are base quantities, later science developments showed that either electric charge or electric current could be added to extend the set of base quantities by which many other metrological units could be easily defined. Other quantities, such as power and speed, are derived from the set, for example. Such arrangements were satisfactory in their own contexts, the preference for a more universal and consistent system only gradually spread with the growth of science. Changing a measurement system has substantial financial and cultural costs which must be offset against the advantages to be obtained using a more rational system. However pressure built up, including scientists and engineers for conversion to a more rational. The unifying characteristic is that there was some definition based on some standard, eventually cubits and strides gave way to customary units to met the needs of merchants and scientists. In the metric system and other recent systems, a basic unit is used for each base quantity. Often secondary units are derived from the units by multiplying by powers of ten. Thus the basic unit of length is the metre, a distance of 1.234 m is 1,234 millimetres. Metrication is complete or nearly complete in almost all countries, US customary units are heavily used in the United States and to some degree in Liberia. Traditional Burmese units of measurement are used in Burma, U. S. units are used in limited contexts in Canada due to the large volume of trade, there is also considerable use of Imperial weights and measures, despite de jure Canadian conversion to metric. In the United States, metric units are used almost universally in science, widely in the military, and partially in industry, but customary units predominate in household use. At retail stores, the liter is a used unit for volume, especially on bottles of beverages. Some other standard non-SI units are still in use, such as nautical miles and knots in aviation. Metric systems of units have evolved since the adoption of the first well-defined system in France in 1795, during this evolution the use of these systems has spread throughout the world, first to non-English-speaking countries, and then to English speaking countries
2.
SI derived unit
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The International System of Units specifies a set of seven base units from which all other SI units of measurement are derived. Each of these units is either dimensionless or can be expressed as a product of powers of one or more of the base units. For example, the SI derived unit of area is the metre. The degree Celsius has an unclear status, and is arguably an exception to this rule. The names of SI units are written in lowercase, the symbols for units named after persons, however, are always written with an uppercase initial letter. In addition to the two dimensionless derived units radian and steradian,20 other derived units have special names, some other units such as the hour, litre, tonne, bar and electronvolt are not SI units, but are widely used in conjunction with SI units. Until 1995, the SI classified the radian and the steradian as supplementary units, but this designation was abandoned, International System of Quantities International System of Units International Vocabulary of Metrology Metric prefix Metric system Non-SI units mentioned in the SI Planck units SI base unit I. Mills, Tomislav Cvitas, Klaus Homann, Nikola Kallay, IUPAC, Quantities, Units and Symbols in Physical Chemistry. CS1 maint, Multiple names, authors list
3.
Catalysis
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Catalysis is the increase in the rate of a chemical reaction due to the participation of an additional substance called a catalyst. In most cases, reactions occur faster with a catalyst because they require less activation energy, furthermore, since they are not consumed in the catalyzed reaction, catalysts can continue to act repeatedly. Often only tiny amounts are required in principle, in the presence of a catalyst, less free energy is required to reach the transition state, but the total free energy from reactants to products does not change. A catalyst may participate in multiple chemical transformations, the effect of a catalyst may vary due to the presence of other substances known as inhibitors or poisons or promoters. Catalyzed reactions have an activation energy than the corresponding uncatalyzed reaction, resulting in a higher reaction rate at the same temperature. However, the mechanics of catalysis is complex. Usually, the catalyst participates in this slowest step, and rates are limited by amount of catalyst, in heterogeneous catalysis, the diffusion of reagents to the surface and diffusion of products from the surface can be rate determining. A nanomaterial-based catalyst is an example of a heterogeneous catalyst, analogous events associated with substrate binding and product dissociation apply to homogeneous catalysts. Although catalysts are not consumed by the reaction itself, they may be inhibited, deactivated, in heterogeneous catalysis, typical secondary processes include coking where the catalyst becomes covered by polymeric side products. Additionally, heterogeneous catalysts can dissolve into the solution in a system or sublimate in a solid–gas system. The production of most industrially important chemicals involves catalysis, similarly, most biochemically significant processes are catalysed. Research into catalysis is a field in applied science and involves many areas of chemistry, notably organometallic chemistry. Catalysis is relevant to aspects of environmental science, e. g. the catalytic converter in automobiles. Many transition metals and transition metal complexes are used in catalysis as well, Catalysts called enzymes are important in biology. A catalyst works by providing a reaction pathway to the reaction product. The rate of the reaction is increased as this route has a lower activation energy than the reaction route not mediated by the catalyst. The disproportionation of hydrogen peroxide creates water and oxygen, as shown below,2 H2O2 →2 H2O + O2 This reaction is preferable in the sense that the reaction products are more stable than the starting material, though the uncatalysed reaction is slow. In fact, the decomposition of hydrogen peroxide is so slow that hydrogen peroxide solutions are commercially available and this reaction is strongly affected by catalysts such as manganese dioxide, or the enzyme peroxidase in organisms
4.
SI base unit
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The International System of Units defines seven units of measure as a basic set from which all other SI units can be derived. The SI base units form a set of mutually independent dimensions as required by dimensional analysis commonly employed in science, thus, the kelvin, named after Lord Kelvin, has the symbol K and the ampere, named after André-Marie Ampère, has the symbol A. Many other units, such as the litre, are not part of the SI. The definitions of the units have been modified several times since the Metre Convention in 1875. Since the redefinition of the metre in 1960, the kilogram is the unit that is directly defined in terms of a physical artifact. However, the mole, the ampere, and the candela are linked through their definitions to the mass of the platinum–iridium cylinder stored in a vault near Paris. It has long been an objective in metrology to define the kilogram in terms of a fundamental constant, two possibilities have attracted particular attention, the Planck constant and the Avogadro constant. The 23rd CGPM decided to postpone any formal change until the next General Conference in 2011
5.
Mole (unit)
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The mole is the unit of measurement in the International System of Units for amount of substance. This number is expressed by the Avogadro constant, which has a value of 6. 022140857×1023 mol−1, the mole is one of the base units of the SI, and has the unit symbol mol. The mole is used in chemistry as a convenient way to express amounts of reactants and products of chemical reactions. For example, the chemical equation 2 H2 + O2 →2 H2O implies that 2 moles of dihydrogen and 1 mole of dioxygen react to form 2 moles of water. The mole may also be used to express the number of atoms, ions, the concentration of a solution is commonly expressed by its molarity, defined as the number of moles of the dissolved substance per litre of solution. For example, the relative molecular mass of natural water is about 18.015, therefore. The term gram-molecule was formerly used for essentially the same concept, the term gram-atom has been used for a related but distinct concept, namely a quantity of a substance that contains Avogadros number of atoms, whether isolated or combined in molecules. Thus, for example,1 mole of MgBr2 is 1 gram-molecule of MgBr2 but 3 gram-atoms of MgBr2, in honor of the unit, some chemists celebrate October 23, which is a reference to the 1023 scale of the Avogadro constant, as Mole Day. Some also do the same for February 6 and June 2, thus, by definition, one mole of pure 12C has a mass of exactly 12 g. It also follows from the definition that X moles of any substance will contain the number of molecules as X moles of any other substance. The mass per mole of a substance is called its molar mass, the number of elementary entities in a sample of a substance is technically called its amount. Therefore, the mole is a convenient unit for that physical quantity, one can determine the chemical amount of a known substance, in moles, by dividing the samples mass by the substances molar mass. Other methods include the use of the volume or the measurement of electric charge. The mass of one mole of a substance depends not only on its molecular formula, since the definition of the gram is not mathematically tied to that of the atomic mass unit, the number NA of molecules in a mole must be determined experimentally. The value adopted by CODATA in 2010 is NA =6. 02214129×1023 ±0. 00000027×1023, in 2011 the measurement was refined to 6. 02214078×1023 ±0. 00000018×1023. The number of moles of a sample is the sample mass divided by the mass of the material. The history of the mole is intertwined with that of mass, atomic mass unit, Avogadros number. The first table of atomic mass was published by John Dalton in 1805
6.
Second
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The second is the base unit of time in the International System of Units. It is qualitatively defined as the division of the hour by sixty. SI definition of second is the duration of 9192631770 periods of the corresponding to the transition between the two hyperfine levels of the ground state of the caesium 133 atom. Seconds may be measured using a mechanical, electrical or an atomic clock, SI prefixes are combined with the word second to denote subdivisions of the second, e. g. the millisecond, the microsecond, and the nanosecond. Though SI prefixes may also be used to form multiples of the such as kilosecond. The second is also the unit of time in other systems of measurement, the centimetre–gram–second, metre–kilogram–second, metre–tonne–second. Absolute zero implies no movement, and therefore zero external radiation effects, the second thus defined is consistent with the ephemeris second, which was based on astronomical measurements. The realization of the second is described briefly in a special publication from the National Institute of Standards and Technology. 1 international second is equal to, 1⁄60 minute 1⁄3,600 hour 1⁄86,400 day 1⁄31,557,600 Julian year 1⁄, more generally, = 1⁄, the Hellenistic astronomers Hipparchus and Ptolemy subdivided the day into sixty parts. They also used an hour, simple fractions of an hour. No sexagesimal unit of the day was used as an independent unit of time. The modern second is subdivided using decimals - although the third remains in some languages. The earliest clocks to display seconds appeared during the last half of the 16th century, the second became accurately measurable with the development of mechanical clocks keeping mean time, as opposed to the apparent time displayed by sundials. The earliest spring-driven timepiece with a hand which marked seconds is an unsigned clock depicting Orpheus in the Fremersdorf collection. During the 3rd quarter of the 16th century, Taqi al-Din built a clock with marks every 1/5 minute, in 1579, Jost Bürgi built a clock for William of Hesse that marked seconds. In 1581, Tycho Brahe redesigned clocks that displayed minutes at his observatory so they also displayed seconds, however, they were not yet accurate enough for seconds. In 1587, Tycho complained that his four clocks disagreed by plus or minus four seconds, in 1670, London clockmaker William Clement added this seconds pendulum to the original pendulum clock of Christiaan Huygens. From 1670 to 1680, Clement made many improvements to his clock and this clock used an anchor escapement mechanism with a seconds pendulum to display seconds in a small subdial
7.
International System of Units
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The International System of Units is the modern form of the metric system, and is the most widely used system of measurement. It comprises a coherent system of units of measurement built on seven base units, the system also establishes a set of twenty prefixes to the unit names and unit symbols that may be used when specifying multiples and fractions of the units. The system was published in 1960 as the result of an initiative began in 1948. It is based on the system of units rather than any variant of the centimetre-gram-second system. The motivation for the development of the SI was the diversity of units that had sprung up within the CGS systems, the International System of Units has been adopted by most developed countries, however, the adoption has not been universal in all English-speaking countries. The metric system was first implemented during the French Revolution with just the metre and kilogram as standards of length, in the 1830s Carl Friedrich Gauss laid the foundations for a coherent system based on length, mass, and time. In the 1860s a group working under the auspices of the British Association for the Advancement of Science formulated the requirement for a coherent system of units with base units and derived units. Meanwhile, in 1875, the Treaty of the Metre passed responsibility for verification of the kilogram, in 1921, the Treaty was extended to include all physical quantities including electrical units originally defined in 1893. The units associated with these quantities were the metre, kilogram, second, ampere, kelvin, in 1971, a seventh base quantity, amount of substance represented by the mole, was added to the definition of SI. On 11 July 1792, the proposed the names metre, are, litre and grave for the units of length, area, capacity. The committee also proposed that multiples and submultiples of these units were to be denoted by decimal-based prefixes such as centi for a hundredth, on 10 December 1799, the law by which the metric system was to be definitively adopted in France was passed. Prior to this, the strength of the magnetic field had only been described in relative terms. The technique used by Gauss was to equate the torque induced on a magnet of known mass by the earth’s magnetic field with the torque induced on an equivalent system under gravity. The resultant calculations enabled him to assign dimensions based on mass, length, a French-inspired initiative for international cooperation in metrology led to the signing in 1875 of the Metre Convention. Initially the convention only covered standards for the metre and the kilogram, one of each was selected at random to become the International prototype metre and International prototype kilogram that replaced the mètre des Archives and kilogramme des Archives respectively. Each member state was entitled to one of each of the prototypes to serve as the national prototype for that country. Initially its prime purpose was a periodic recalibration of national prototype metres. The official language of the Metre Convention is French and the version of all official documents published by or on behalf of the CGPM is the French-language version
8.
Enzyme
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Enzymes /ˈɛnzaɪmz/ are macromolecular biological catalysts. Enzymes accelerate, or catalyze, chemical reactions, the molecules at the beginning of the process upon which enzymes may act are called substrates and the enzyme converts these into different molecules, called products. Almost all metabolic processes in the cell need enzymes in order to occur at rates fast enough to sustain life, the set of enzymes made in a cell determines which metabolic pathways occur in that cell. The study of enzymes is called enzymology, enzymes are known to catalyze more than 5,000 biochemical reaction types. Most enzymes are proteins, although a few are catalytic RNA molecules, enzymes specificity comes from their unique three-dimensional structures. Like all catalysts, enzymes increase the rate of a reaction by lowering its activation energy, some enzymes can make their conversion of substrate to product occur many millions of times faster. An extreme example is orotidine 5-phosphate decarboxylase, which allows a reaction that would take millions of years to occur in milliseconds. Chemically, enzymes are like any catalyst and are not consumed in chemical reactions, enzymes differ from most other catalysts by being much more specific. Enzyme activity can be affected by other molecules, inhibitors are molecules that decrease enzyme activity, many drugs and poisons are enzyme inhibitors. An enzymes activity decreases markedly outside its optimal temperature and pH, some enzymes are used commercially, for example, in the synthesis of antibiotics. French chemist Anselme Payen was the first to discover an enzyme, diastase and he wrote that alcoholic fermentation is an act correlated with the life and organization of the yeast cells, not with the death or putrefaction of the cells. In 1877, German physiologist Wilhelm Kühne first used the term enzyme, the word enzyme was used later to refer to nonliving substances such as pepsin, and the word ferment was used to refer to chemical activity produced by living organisms. Eduard Buchner submitted his first paper on the study of yeast extracts in 1897, in a series of experiments at the University of Berlin, he found that sugar was fermented by yeast extracts even when there were no living yeast cells in the mixture. He named the enzyme that brought about the fermentation of sucrose zymase, in 1907, he received the Nobel Prize in Chemistry for his discovery of cell-free fermentation. Following Buchners example, enzymes are usually named according to the reaction they carry out, the biochemical identity of enzymes was still unknown in the early 1900s. Sumner showed that the enzyme urease was a protein and crystallized it. These three scientists were awarded the 1946 Nobel Prize in Chemistry, the discovery that enzymes could be crystallized eventually allowed their structures to be solved by x-ray crystallography. This high-resolution structure of lysozyme marked the beginning of the field of structural biology, an enzymes name is often derived from its substrate or the chemical reaction it catalyzes, with the word ending in -ase
