Magnetic susceptibility
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In electromagnetism, the magnetic susceptibility (Latin: susceptibilis, "receptive"; denoted χ) is one measure of the magnetic properties of a material. The susceptibility indicates whether a material is attracted into or repelled out of a magnetic field, which in turn has implications for practical applications. Quantitative measures of the magnetic susceptibility also provide insights into the structure of materials, providing insight into bonding and energy levels.
If the magnetic susceptibility is greater than zero, the substance is said to be "paramagnetic"; the magnetization of the substance is higher than that of empty space. If the magnetic susceptibility is less than zero, the substance is "diamagnetic"; it tends to exclude a magnetic field from its interior.^{[1]}
Mathematically it is the ratio of magnetization M (magnetic moment per unit volume) to the applied magnetizing field intensity H.
Contents
Definition[edit]
Volume susceptibility[edit]
Magnetic susceptibility is a dimensionless proportionality constant that indicates the degree of magnetization of a material in response to an applied magnetic field. A related term is magnetizability, the proportion between magnetic moment and magnetic flux density.^{[2]} A closely related parameter is the permeability, which expresses the total magnetization of material and volume.
The volume magnetic susceptibility, represented by the symbol χ_{v} (often simply χ, sometimes χ_{m} – magnetic, to distinguish from the electric susceptibility), is defined in the International System of Units — in other systems there may be additional constants — by the following relationship:^{[3]}
Here
- M is the magnetization of the material (the magnetic dipole moment per unit volume), measured in amperes per meter, and
- H is the magnetic field strength, also measured in amperes per meter.
χ_{v} is therefore a dimensionless quantity.
Using SI units, the magnetic induction B is related to H by the relationship
where μ_{0} is the vacuum permeability (see table of physical constants), and (1 + χ_{v}) is the relative permeability of the material. Thus the volume magnetic susceptibility χ_{v} and the magnetic permeability μ are related by the following formula:
Sometimes^{[4]} an auxiliary quantity called intensity of magnetization I (also referred to as magnetic polarisation J) and measured in teslas, is defined as
This allows an alternative description of all magnetization phenomena in terms of the quantities I and B, as opposed to the commonly used M and H.
Mass susceptibility and molar susceptibility[edit]
There are two other measures of susceptibility, the mass magnetic susceptibility (χ_{mass} or χ_{g}, sometimes χ_{m}), measured in m^{3}/kg (SI) and the molar magnetic susceptibility (χ_{mol}) measured in m^{3}/mol that are defined below, where ρ is the density in kg/m^{3} and M is molar mass in kg/mol:
- ;
- .
In CGS units[edit]
Note that the definitions above are according to SI conventions. However, many tables of magnetic susceptibility give cgs values (more specifically emu-cgs, short for electromagnetic units, or Gaussian-cgs; both are the same in this context). These units rely on a different definition of the permeability of free space:^{[5]}
The dimensionless cgs value of volume susceptibility is multiplied by 4π to give the dimensionless SI volume susceptibility value:^{[5]}
For example, the cgs volume magnetic susceptibility of water at 20 °C is ×10^{−7}, which is −7.19×10^{−6} using the −9.04SI convention.
In physics it is common to see cgs mass susceptibility given in cm^{3}/g or emu/g·Oe^{−1}, so to convert to SI volume susceptibility we use the conversion ^{[6]}
where ρ^{cgs} is the density given in g/cm^{3}, or
- .
The molar susceptibility is measured cm^{3}/mol or emu/mol·Oe^{−1} in cgs and is calculated using the molar mass in g/mol.
Paramagnetism and diamagnetism[edit]
If χ is positive, a material can be paramagnetic. In this case, the magnetic field in the material is strengthened by the induced magnetization. Alternatively, if χ is negative, the material is diamagnetic. In this case, the magnetic field in the material is weakened by the induced magnetization. Generally, nonmagnetic materials are said to be para- or diamagnetic because they do not possess permanent magnetization without external magnetic field. Ferromagnetic, ferrimagnetic, or antiferromagnetic materials possess permanent magnetization even without external magnetic field and do not have a well defined zero-field susceptibility.
Experimental measurement[edit]
Volume magnetic susceptibility is measured by the force change felt upon a substance when a magnetic field gradient is applied.^{[7]} Early measurements are made using the Gouy balance where a sample is hung between the poles of an electromagnet. The change in weight when the electromagnet is turned on is proportional to the susceptibility. Today, high-end measurement systems use a superconductive magnet. An alternative is to measure the force change on a strong compact magnet upon insertion of the sample. This system, widely used today, is called the Evans balance.^{[8]} For liquid samples, the susceptibility can be measured from the dependence of the NMR frequency of the sample on its shape or orientation.^{[9]}^{[10]}^{[11]}^{[12]}^{[13]} Another method using NMR techniques measures the magnetic field distortion around a sample immersed in water inside an MR scanner. This method is highly accurate for diamagnetic materials with susceptibilities similar to water.^{[14]}
Tensor susceptibility[edit]
The magnetic susceptibility of most crystals is not a scalar quantity. Magnetic response M is dependent upon the orientation of the sample and can occur in directions other than that of the applied field H. In these cases, volume susceptibility is defined as a tensor
where i and j refer to the directions (e.g., x and y in Cartesian coordinates) of the applied field and magnetization, respectively. The tensor is thus rank 2 (second order), dimension (3,3) describing the component of magnetization in the ith direction from the external field applied in the jth direction.
Differential susceptibility[edit]
In ferromagnetic crystals, the relationship between M and H is not linear. To accommodate this, a more general definition of differential susceptibility is used
where χ^{d}
_{ij} is a tensor derived from partial derivatives of components of M with respect to components of H. When the coercivity of the material parallel to an applied field is the smaller of the two, the differential susceptibility is a function of the applied field and self interactions, such as the magnetic anisotropy. When the material is not saturated, the effect will be nonlinear and dependent upon the domain wall configuration of the material.
In the frequency domain[edit]
When the magnetic susceptibility is measured in response to an AC magnetic field (i.e. a magnetic field that varies sinusoidally), this is called AC susceptibility. AC susceptibility (and the closely related "AC permeability") are complex number quantities, and various phenomena, such as resonance, can be seen in AC susceptibility that cannot in constant-field (DC) susceptibility. In particular, when an AC field is applied perpendicular to the detection direction (called the "transverse susceptibility" regardless of the frequency), the effect has a peak at the ferromagnetic resonance frequency of the material with a given static applied field. Currently, this effect is called the microwave permeability or network ferromagnetic resonance in the literature. These results are sensitive to the domain wall configuration of the material and eddy currents.
In terms of ferromagnetic resonance, the effect of an AC-field applied along the direction of the magnetization is called parallel pumping.
Examples[edit]
Material | Temp. | Pressure | Molar susc., χ_{mol} | Mass susc., χ_{mass} | Volume susc., χ_{v} | Molar mass, M | Density, | |||
---|---|---|---|---|---|---|---|---|---|---|
(°C) | (atm) | SI (m^{3}/mol) |
CGS (cm^{3}/mol) |
SI (m^{3}/kg) |
CGS (cm^{3}/g) |
SI |
CGS (emu) |
(10^{−3} kg/mol = g/mol) |
(10^{3} kg/m^{3} = g/cm^{3}) | |
Helium^{[15]} | 20 | 1 | ×10^{−11} −2.38 | ×10^{−6} −1.89 | ×10^{−9} −5.93 | ×10^{−7} −4.72 | ×10^{−10} −9.85 | ×10^{−11} −7.84 | 4.0026 | ×10^{−4} 1.66 |
Xenon^{[15]} | 20 | 1 | ×10^{−10} −5.71 | ×10^{−5} −4.54 | ×10^{−9} −4.35 | ×10^{−7} −3.46 | ×10^{−8} −2.37 | ×10^{−9} −1.89 | 131.29 | ×10^{−3} 5.46 |
Oxygen^{[15]} | 20 | 0.209 | ×10^{−8} +4.3 | ×10^{−3} +3.42 | ×10^{−6} +1.34 | ×10^{−4} +1.07 | ×10^{−7} +3.73 | ×10^{−8} +2.97 | 31.99 | ×10^{−4} 2.78 |
Nitrogen^{[15]} | 20 | 0.781 | ×10^{−10} −1.56 | ×10^{−5} −1.24 | ×10^{−9} −5.56 | ×10^{−7} −4.43 | ×10^{−9} −5.06 | ×10^{−10} −4.03 | 28.01 | ×10^{−4} 9.10 |
Air (NTP)^{[16]} | 20 | 1 | ×10^{−7} +3.6 | ×10^{−8} +2.9 | 28.97 | ×10^{−3} 1.29 | ||||
Water^{[17]} | 20 | 1 | ×10^{−10} −1.631 | ×10^{−5} −1.298 | ×10^{−9} −9.051 | ×10^{−7} −7.203 | ×10^{−6} −9.035 | ×10^{−7} −7.190 | 18.015 | 0.9982 |
Paraffin oil, 220–260 cSt^{[14]} | 22 | 1 | ×10^{−8} −1.01 | ×10^{−7} −8.0 | ×10^{−6} −8.8 | ×10^{−7} −7.0 | 0.878 | |||
PMMA^{[14]} | 22 | 1 | ×10^{−9} −7.61 | ×10^{−7} −6.06 | ×10^{−6} −9.06 | ×10^{−7} −7.21 | 1.190 | |||
PVC^{[14]} | 22 | 1 | ×10^{−9} −7.80 | ×10^{−7} −6.21 | ×10^{−5} −1.071 | ×10^{−7} −8.52 | 1.372 | |||
Fused silica glass^{[14]} | 22 | 1 | ×10^{−9} −5.12 | ×10^{−7} −4.07 | ×10^{−5} −1.128 | ×10^{−7} −8.98 | 2.20 | |||
Diamond^{[18]} | r.t. | 1 | ×10^{−11} −7.4 | ×10^{−6} −5.9 | ×10^{−9} −6.2 | ×10^{−7} −4.9 | ×10^{−5} −2.2 | ×10^{−6} −1.7 | 12.01 | 3.513 |
Graphite^{[19]} χ_{∥} (to c-axis) | r.t. | 1 | ×10^{−11} −7.5 | ×10^{−6} −6.0 | ×10^{−9} −6.3 | ×10^{−7} −5.0 | ×10^{−5} −1.4 | ×10^{−6} −1.1 | 12.01 | 2.267 |
Graphite^{[19]} χ_{∥} | r.t. | 1 | ×10^{−9} −3.2 | ×10^{−4} −2.6 | ×10^{−7} −2.7 | ×10^{−5} −2.2 | ×10^{−4} −6.1 | ×10^{−5} −4.9 | 12.01 | 2.267 |
Graphite^{[19]} χ_{∥} | −173 | 1 | ×10^{−9} −4.4 | ×10^{−4} −3.5 | ×10^{−7} −3.6 | ×10^{−5} −2.9 | ×10^{−4} −8.3 | ×10^{−5} −6.6 | 12.01 | 2.267 |
Aluminium^{[20]} | 1 | ×10^{−10} +2.2 | ×10^{−5} +1.7 | ×10^{−9} +7.9 | ×10^{−7} +6.3 | ×10^{−5} +2.2 | ×10^{−6} +1.75 | 26.98 | 2.70 | |
Silver^{[21]} | 961 | 1 | ×10^{−5} −2.31 | ×10^{−6} −1.84 | 107.87 | |||||
Bismuth^{[22]} | 20 | 1 | ×10^{−9} −3.55 | ×10^{−4} −2.82 | ×10^{−8} −1.70 | ×10^{−6} −1.35 | ×10^{−4} −1.66 | ×10^{−5} −1.32 | 208.98 | 9.78 |
Copper^{[16]} | 20 | 1 | ×10^{−9} −1.0785 | ×10^{−6} −9.63 | ×10^{−7} −7.66 | 63.546 | 8.92 | |||
Nickel^{[16]} | 20 | 1 | 600 | 48 | 58.69 | 8.9 | ||||
Iron^{[16]} | 20 | 1 | 000 200 | 900 15 | 55.847 | 7.874 |
Sources of confusion in published data[edit]
The CRC Handbook of Chemistry and Physics has one of the only published magnetic susceptibility tables. Some of the data (e.g., for aluminium, bismuth, and diamond) is listed as cgs, which has caused confusion to some readers. "cgs" is an abbreviation of centimeters–grams–seconds; it represents the form of the units, but cgs does not specify units. Correct units of magnetic susceptibility in cgs is cm^{3}/mol or cm^{3}/g. Molar susceptibility and mass susceptibility are both listed in the CRC. Some table have listed magnetic susceptibility of diamagnets as positives. It is important to check the header of the table for the correct units and sign of magnetic susceptibility readings.
See also[edit]
References and notes[edit]
- ^ Roger Grinter, The Quantum in Chemistry: An Experimentalist's View, John Wiley & Sons, 2005, ISBN 0470017627 page 364
- ^ "magnetizability, ξ". IUPAC Compendium of Chemical Terminology—The Gold Book (2nd ed.). International Union of Pure and Applied Chemistry. 1997.
- ^ O'Handley, Robert C. (2000). Modern Magnetic Materials. Hoboken, NJ: Wiley. ISBN 9780471155669.
- ^ Richard A. Clarke. "Magnetic properties of materials". Info.ee.surrey.ac.uk. Retrieved 2011-11-08.
- ^ ^{a} ^{b} Bennett, L. H.; Page, C. H. & Swartzendruber, L. J. (1978). "Comments on units in magnetism". Journal of Research of the National Bureau of Standards. NIST, USA. 83 (1): 9–12.
- ^ "IEEE Magnetic unit conversions".
- ^ L. N. Mulay (1972). A. Weissberger; B. W. Rossiter, eds. Techniques of Chemistry. 4. Wiley-Interscience: New York. p. 431.
- ^ "Magnetic Susceptibility Balances". Sherwood-scientific.com. Retrieved 2011-11-08.
- ^ J. R. Zimmerman, and M. R. Foster (1957). "Standardization of NMR high resolution spectra". J. Phys. Chem. 61 (3): 282–289. doi:10.1021/j150549a006.
- ^ Robert Engel; Donald Halpern & Susan Bienenfeld (1973). "Determination of magnetic moments in solution by nuclear magnetic resonance spectrometry". Anal. Chem. 45 (2): 367–369. doi:10.1021/ac60324a054.
- ^ P. W. Kuchel; B. E. Chapman; W. A. Bubb; P. E. Hansen; C. J. Durrant & M. P. Hertzberg (2003). "Magnetic susceptibility: solutions, emulsions, and cells". Concepts Magn. Reson. A 18: 56–71. arXiv:q-bio/0601030 . doi:10.1002/cmr.a.10066.
- ^ K. Frei & H. J. Bernstein (1962). "Method for determining magnetic susceptibilities by NMR". J. Chem. Phys. 37 (8): 1891–1892. Bibcode:1962JChPh..37.1891F. doi:10.1063/1.1733393.
- ^ R. E. Hoffman (2003). "Variations on the chemical shift of TMS". J. Magn. Reson. 163 (2): 325–331. Bibcode:2003JMagR.163..325H. doi:10.1016/S1090-7807(03)00142-3. PMID 12914848.
- ^ ^{a} ^{b} ^{c} ^{d} ^{e} Wapler, M. C.; Leupold, J.; Dragonu, I.; von Elverfeldt, D.; Zaitsev, M.; Wallrabe, U. (2014). "Magnetic properties of materials for MR engineering, micro-MR and beyond". JMR. 242: 233–242. arXiv:1403.4760 . Bibcode:2014JMagR.242..233W. doi:10.1016/j.jmr.2014.02.005.
- ^ ^{a} ^{b} ^{c} ^{d} R. E. Glick (1961). "On the Diamagnetic Susceptibility of Gases". J. Phys. Chem. 65 (9): 1552–1555. doi:10.1021/j100905a020.
- ^ ^{a} ^{b} ^{c} ^{d} John F. Schenck (1993). "The role of magnetic susceptibility in magnetic resonance imaging: MRI magnetic compatibility of the first and second kinds". Medical Physics. 23: 815–850. Bibcode:1996MedPh..23..815S. doi:10.1118/1.597854. PMID 8798169.
- ^ G. P. Arrighini; M. Maestro & R. Moccia (1968). "Magnetic Properties of Polyatomic Molecules: Magnetic Susceptibility of H_{2}O, NH_{3}, CH_{4}, H_{2}O_{2}". J. Chem. Phys. 49 (2): 882–889. Bibcode:1968JChPh..49..882A. doi:10.1063/1.1670155.
- ^ J. Heremans, C. H. Olk and D. T. Morelli (1994). "Magnetic Susceptibility of Carbon Structures". Phys. Rev. B. 49 (21): 15122–15125. Bibcode:1994PhRvB..4915122H. doi:10.1103/PhysRevB.49.15122.
- ^ ^{a} ^{b} ^{c} N. Ganguli & K.S. Krishnan (1941). "The Magnetic and Other Properties of the Free Electrons in Graphite" (PDF). Proceedings of the Royal Society. 177 (969): 168–182. Bibcode:1941RSPSA.177..168G. doi:10.1098/rspa.1941.0002.
- ^ Nave, Carl L. "Magnetic Properties of Solids". HyperPhysics. Retrieved 2008-11-09.
- ^ R. Dupree & C. J. Ford (1973). "Magnetic susceptibility of the noble metals around their melting points". Phys. Rev. B. 8 (4): 1780–1782. Bibcode:1973PhRvB...8.1780D. doi:10.1103/PhysRevB.8.1780.
- ^ S. Otake, M. Momiuchi & N. Matsuno (1980). "Temperature Dependence of the Magnetic Susceptibility of Bismuth". J. Phys. Soc. Jpn. 49 (5): 1824–1828. Bibcode:1980JPSJ...49.1824O. doi:10.1143/JPSJ.49.1824. The tensor needs to be averaged over all orientations: χ = 1/3χ_{∥} + 2/3χ_{⊥}.
External links[edit]
- Linear Response Functions in Eva Pavarini, Erik Koch, Dieter Vollhardt, and Alexander Lichtenstein (eds.): DMFT at 25: Infinite Dimensions, Verlag des Forschungszentrum Jülich, 2014 ISBN 978-3-89336-953-9