1.
Polytetrafluoroethylene
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Polytetrafluoroethylene is a synthetic fluoropolymer of tetrafluoroethylene that has numerous applications. The best known name of PTFE-based formulas is Teflon by Chemours. Chemours is a spin-off of DuPont Co. which discovered the compound in 1938, PTFE is a fluorocarbon solid, as it is a high-molecular-weight compound consisting wholly of carbon and fluorine. PTFE is hydrophobic, neither water nor water-containing substances wet PTFE, PTFE has one of the lowest coefficients of friction of any solid. PTFE is used as a coating for pans and other cookware. It is very non-reactive, partly because of the strength of carbon–fluorine bonds, where used as a lubricant, PTFE reduces friction, wear and energy consumption of machinery. It is commonly used as a material in surgical interventions. Also, it is employed as coating on catheters, this interferes with the ability of bacteria and other infectious agents to adhere to catheters. PTFE was accidentally discovered in 1938 by Roy Plunkett while he was working in New Jersey for DuPont. Since Plunkett was measuring the amount of gas used by weighing the bottle, he became curious as to the source of the weight and he found the bottles interior coated with a waxy white material that was oddly slippery. Analysis showed that it was polymerized perfluoroethylene, with the iron from the inside of the container having acted as a catalyst at high pressure, Kinetic Chemicals patented the new fluorinated plastic in 1941, and registered the Teflon trademark in 1945. By 1948, DuPont, which founded Kinetic Chemicals in partnership with General Motors, was producing two million pounds of Teflon brand PTFE per year in Parkersburg, West Virginia. In 1954, the wife of French engineer Marc Grégoire urged him to try the material he had been using on fishing tackle on her cooking pans and he subsequently created the first Teflon-coated, non-stick pans under the brandname Tefal. In the United States, Marion A. Trozzolo, who had been using the substance on scientific utensils, marketed the first US-made Teflon-coated pan, The Happy Pan, however, Tefal was not the only company to utilize PTFE in nonstick cookware coatings. Other cookware companies, such as Meyer Corporations Anolon, use Teflon nonstick coatings purchased from DuPont, in the 1990s, it was found that PTFE could be radiation cross-linked above its melting point in an oxygen-free environment. Electron beam processing is one example of radiation processing, cross-linked PTFE has improved high-temperature mechanical properties and radiation stability. This was significant because, for years, irradiation at ambient conditions has been used to break down PTFE for recycling. This radiation-induced chain scission allows it to be more easily reground, PTFE is produced by free-radical polymerization of tetrafluoroethylene
2.
Polystyrene
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Polystyrene /ˌpɒliˈstaɪriːn/ is a synthetic aromatic polymer made from the monomer styrene. Polystyrene can be solid or foamed, general-purpose polystyrene is clear, hard, and rather brittle. It is an inexpensive resin per unit weight and it is a rather poor barrier to oxygen and water vapor and has a relatively low melting point. Polystyrene is one of the most widely used plastics, the scale of its production being several million tonnes per year, Polystyrene can be naturally transparent, but can be colored with colorants. Uses include protective packaging, containers, lids, bottles, trays, tumblers, as a thermoplastic polymer, polystyrene is in a solid state at room temperature but flows if heated above about 100 °C, its glass transition temperature. It becomes rigid again when cooled and this temperature behavior is exploited for extrusion and also for molding and vacuum forming, since it can be cast into molds with fine detail. Polystyrene is very slow to biodegrade and is therefore a focus of controversy among environmentalists, Polystyrene was discovered in 1839 by Eduard Simon, an apothecary from Berlin. From storax, the resin of the American sweetgum tree Liquidambar styraciflua, he distilled an oily substance, several days later, Simon found that the styrol had thickened into a jelly he dubbed styrol oxide because he presumed an oxidation. By 1845 Jamaican-born chemist John Buddle Blyth and German chemist August Wilhelm von Hofmann showed that the transformation of styrol took place in the absence of oxygen. They called the product metastyrol, analysis showed that it was identical to Simons Styroloxyd. In 1866 Marcelin Berthelot correctly identified the formation of metastyrol/Styroloxyd from styrol as a polymerization process, about 80 years later it was realized that heating of styrol starts a chain reaction that produces macromolecules, following the thesis of German organic chemist Hermann Staudinger. This eventually led to the substance receiving its present name, polystyrene, the company I. G. Farben began manufacturing polystyrene in Ludwigshafen, about 1931, hoping it would be a suitable replacement for die-cast zinc in many applications. Success was achieved when they developed a reactor vessel that extruded polystyrene through a tube and cutter. In 1941, Dow Chemical invented a Styrofoam process, before 1949, the chemical engineer Fritz Stastny developed pre-expanded PS beads by incorporating aliphatic hydrocarbons, such as pentane. These beads are the raw material for moulding parts or extruding sheets, BASF and Stastny applied for a patent that was issued in 1949. The moulding process was demonstrated at the Kunststoff Messe 1952 in Düsseldorf, the crystal structure of isotactic polystyrene was reported by Giulio Natta. In 1954, the Koppers Company in Pittsburgh, Pennsylvania, developed expanded polystyrene foam under the trade name Dylite, in 1960, Dart Container, the largest manufacturer of foam cups, shipped their first order. In 1988, the first U. S. ban of general polystyrene foam was enacted in Berkeley, in chemical terms, polystyrene is a long chain hydrocarbon wherein alternating carbon centers are attached to phenyl groups
3.
Epoxy
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Epoxy is either any of the basic components or the cured end products of epoxy resins, as well as a colloquial name for the epoxide functional group. Epoxy resins, also known as polyepoxides, are a class of reactive prepolymers and polymers which contain epoxide groups, Epoxy resins may be reacted either with themselves through catalytic homopolymerisation, or with a wide range of co-reactants including polyfunctional amines, acids, phenols, alcohols and thiols. These co-reactants are often referred to as hardeners or curatives, reaction of polyepoxides with themselves or with polyfunctional hardeners forms a thermosetting polymer, often with high mechanical properties, temperature and chemical resistance. Epoxy resins are low molecular weight pre-polymers or higher molecular weight polymers which contain at least two epoxide groups. The epoxide group is sometimes referred to as a glycidyl or oxirane group. A wide range of epoxy resins are produced industrially, the raw materials for epoxy resin production are today largely petroleum derived, although some plant derived sources are now becoming commercially available. Epoxy resins are polymeric or semi-polymeric materials, and as such rarely exist as pure substances, high purity grades can be produced for certain applications, e. g. using a distillation purification process. One downside of high purity liquid grades is their tendency to form crystalline solids due to their highly regular structure, an important criterion for epoxy resins is the epoxide content. Epoxies are typically cured with stoichiometric or near-stoichiometric quantities of curative to achieve maximum physical properties, use of blending, additives and fillers is often referred to as formulating. Important epoxy resins are produced from combining epichlorohydrin and bisphenol A to give bisphenol A diglycidyl ethers, as the molecular weight of the resin increases, the epoxide content reduces and the material behaves more and more like a thermoplastic. Very high molecular weight polycondensates form a class known as phenoxy resins and these resins do however contain hydroxyl groups throughout the backbone, which may also undergo other cross-linking reactions, e. g. with aminoplasts, phenoplasts and isocyanates. Bisphenol F may also undergo epoxidation in a fashion to bisphenol A. Compared to DGEBA, bisphenol F epoxy resins have lower viscosity and a higher mean epoxy content per gramme, reaction of phenols with formaldehyde and subsequent glycidylation with epichlorohydrin produces epoxidised novolacs, such as epoxy phenol novolacs and epoxy cresol novolacs. These are highly viscous to solid resins with typical mean epoxide functionality of around 2 to 6, the high epoxide functionality of these resins forms a highly crosslinked polymer network displaying high temperature and chemical resistance, but low flexibility. Aliphatic epoxy resins are typically formed by glycidylation of aliphatic alcohols or polyols, the resulting resins may be monofunctional, difunctional, or higher functionality. These resins typically display low viscosity at room temperature and are referred to as reactive diluents. They are rarely used alone, but are employed to modify the viscosity of other epoxy resins. This has led to the term ‘modified epoxy resin’ to denote those containing viscosity-lowering reactive diluents, a related class is cycloaliphatic epoxy resin, which contains one or more cycloaliphatic rings in the molecule
4.
Bisphenol A
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Bisphenol A is an organic synthetic compound with the chemical formula 2C2 belonging to the group of diphenylmethane derivatives and bisphenols, with two hydroxyphenyl groups. It is a solid that is soluble in organic solvents. It has been in use since 1957. BPA is employed to make certain plastics and epoxy resins, bPA-based plastic is clear and tough, and is made into a variety of common consumer goods, such as water bottles, sports equipment, CDs, and DVDs. Epoxy resins containing BPA are used to water pipes, as coatings on the inside of many food and beverage cans. In 2015, an estimated 4 million tonnes of BPA chemical were produced for manufacturing polycarbonate plastic, BPA exhibits estrogen mimicking, hormone-like properties that raise concern about its suitability in some consumer products and food containers. Since 2008, several governments have investigated its safety, which prompted some retailers to withdraw polycarbonate products. The U. S. Food and Drug Administration has ended its authorization of the use of BPA in baby bottles and infant formula packaging, based on market abandonment, the European Union and Canada have banned BPA use in baby bottles. The FDA states BPA is safe at the current levels occurring in foods based on extensive research, in February 2016, France announced that it intends to propose BPA as a REACH Regulation candidate substance of very high concern. World production capacity of Bisphenol A was 1 million tons in the 1980s and it is a high production volume chemical. In 2003, U. S. consumption was 856,000 tons, 72% of which used to make polycarbonate plastic and 21% going into epoxy resins. In the U. S. less than 5% of the BPA produced is used in food contact applications, Bisphenol A was first synthesized by the Russian chemist Alexander Dianin in 1891. This compound is synthesized by the condensation of acetone with two equivalents of phenol, the reaction is catalyzed by a strong acid, such as hydrochloric acid or a sulfonated polystyrene resin. Bisphenol A is used primarily to make plastics, and products using bisphenol A-based plastics have been in use since 1957. At least 3.6 million tonnes of BPA are used by manufacturers yearly and it is a key monomer in production of epoxy resins and in the most common form of polycarbonate plastic. Bisphenol A and phosgene react to give polycarbonate under biphasic conditions, phenol is eliminated instead of hydrochloric acid. This transesterification process avoids the toxicity and handling of phosgene, BPA is also used in the synthesis of polysulfones and polyether ketones, as an antioxidant in some plasticizers, and as a polymerization inhibitor in PVC. Bisphenol A is also a precursor to the flame retardant tetrabromobisphenol A, Bisphenol A is a preferred color developer in carbonless copy paper and thermal point of sale receipt paper
5.
Polyethylene terephthalate
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It may also be referred to by the brand name Dacron, in Britain, Terylene, or, in Russia and the former Soviet Union, Lavsan. The majority of the worlds PET production is for synthetic fibers, in the context of textile applications, PET is referred to by its common name, polyester, whereas the acronym PET is generally used in relation to packaging. Polyester makes up about 18% of world production and is the fourth-most-produced polymer, polyethylene, polypropylene and polyvinyl chloride are first, second and third. PET consists of polymerized units of the monomer ethylene terephthalate, with repeating units, PET is commonly recycled, and has the number 1 as its recycling symbol. Depending on its processing and thermal history, polyethylene terephthalate may exist both as an amorphous and as a semi-crystalline polymer, the semicrystalline material might appear transparent or opaque and white depending on its crystal structure and particle size. Polymerization is through a reaction of the monomers with water as the byproduct. Because PET is an excellent water and moisture barrier material, plastic bottles made from PET are widely used for soft drinks, for certain specialty bottles, such as those designated for beer containment, PET sandwiches an additional polyvinyl alcohol layer to further reduce its oxygen permeability. Biaxially oriented PET film can be aluminized by evaporating a thin film of metal onto it to reduce its permeability and these properties are useful in many applications, including flexible food packaging and thermal insulation. Because of its mechanical strength, PET film is often used in tape applications. Non-oriented PET sheet can be thermoformed to make packaging trays and blister packs, if crystallizable PET is used, the trays can be used for frozen dinners, since they withstand both freezing and oven baking temperatures. As opposed to amorphous PET, which is transparent, crystallizable PET or CPET tends to be black in colour, when filled with glass particles or fibres, it becomes significantly stiffer and more durable. PET is also used as a substrate in thin film solar cells, Terylene is also spliced into bell rope tops to help prevent wear on the ropes as they pass through the ceiling. PET was patented in 1941 by John Rex Whinfield, James Tennant Dickson and their employer the Calico Printers Association of Manchester, DuPont de Nemours in Delaware, USA, first used the trademark Mylar in June 1951 and received registration of it in 1952. It is still the name used for polyester film. The current owner of the trademark is DuPont Teijin Films US, in the Soviet Union, PET was first manufactured in the laboratories of the Institute of High-Molecular Compounds of the USSR Academy of Sciences in 1949, and its name Lavsan is an acronym thereof. The PET bottle was patented in 1973 by Nathaniel Wyeth, PET in its natural state is a colorless, semi-crystalline resin. Based on how it is processed, PET can be semi-rigid to rigid and it makes a good gas and fair moisture barrier, as well as a good barrier to alcohol and solvents. PET becomes white when exposed to chloroform and also certain other chemicals such as toluene, about 60% crystallization is the upper limit for commercial products, with the exception of polyester fibers
6.
Starch
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Starch or amylum is a polymeric carbohydrate consisting of a large number of glucose units joined by glycosidic bonds. This polysaccharide is produced by most green plants as an energy store and it is the most common carbohydrate in human diets and is contained in large amounts in staple foods such as potatoes, wheat, maize, rice, and cassava. Pure starch is a white, tasteless and odorless powder that is insoluble in water or alcohol. It consists of two types of molecules, the linear and helical amylose and the branched amylopectin, depending on the plant, starch generally contains 20 to 25% amylose and 75 to 80% amylopectin by weight. Glycogen, the store of animals, is a more branched version of amylopectin. In industry, starch is converted into sugars, for example by malting and it is processed to produce many of the sugars used in processed foods. Dissolving starch in water gives wheatpaste, which can be used as a thickening, stiffening or gluing agent. The biggest industrial non-food use of starch is as an adhesive in the papermaking process, starch can be applied to parts of some garments before ironing, to stiffen them. The word starch is from a Germanic root with the strong, stiff. Amylum for starch is from the Greek αμυλον, amylon which means not ground at a mill, the root amyl is used in biochemistry for several compounds related to starch. Starch grains from the rhizomes of Typha as flour have been identified from grinding stones in Europe dating back to 30,000 years ago, starch grains from sorghum were found on grind stones in caves in Ngalue, Mozambique dating up to 100,000 years ago. Pure extracted wheat starch paste was used in Ancient Egypt possibly to glue papyrus, the extraction of starch is first described in the Natural History of Pliny the Elder around AD 77–79. Romans used it also in cosmetic creams, to powder the hair, persians and Indians used it to make dishes similar to gothumai wheat halva. Rice starch as surface treatment of paper has been used in production in China. In addition to starchy plants consumed directly,66 million tonnes of starch were being produced per year world-wide by 2008. In the EU this was around 8.5 million tonnes, with around 40% being used for applications and 60% for food uses. Most green plants use starch as their energy store, an exception is the family Asteraceae, where starch is replaced by the fructan inulin. In photosynthesis, plants use light energy to produce glucose from carbon dioxide, the glucose is used to make cellulose fibers, the structural component of the plant, or is stored in the form of starch granules, in amyloplasts
7.
Natural rubber
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Natural rubber, also called India rubber or caoutchouc, as initially produced, consists of polymers of the organic compound isoprene, with minor impurities of other organic compounds, plus water. Malaysia and Indonesia are two of the leading rubber producers, forms of polyisoprene that are used as natural rubbers are classified as elastomers. Currently, rubber is harvested mainly in the form of the latex from the tree or others. The latex is a sticky, milky colloid drawn off by making incisions in the bark, the latex then is refined into rubber ready for commercial processing. In major areas, latex is allowed to coagulate in the collection cup, the coagulated lumps are collected and processed into dry forms for marketing. Natural rubber is used extensively in many applications and products, either alone or in combination with other materials, in most of its useful forms, it has a large stretch ratio and high resilience, and is extremely waterproof. The major commercial source of rubber latex is the Pará rubber tree. This species is preferred because it grows well under cultivation, a properly managed tree responds to wounding by producing more latex for several years. Congo rubber, formerly a source of rubber, came from vines in the genus Landolphia. These cannot be cultivated, and the drive to collect latex from wild plants was responsible for many of the atrocities committed under the Congo Free State. The latex exhibits the quality as the natural rubber from rubber trees. In the wild types of dandelion, latex content is low, in Nazi Germany, research projects tried to use dandelions as a base for rubber production, but failed. In collaboration with Continental Tires, IME began a pilot facility, many other plants produce forms of latex rich in isoprene polymers, though not all produce usable forms of polymer as easily as the Pará. Some of them require more processing to produce anything like usable rubber. Some produce other desirable materials, for example gutta-percha and chicle from Manilkara species, the term gum rubber is sometimes applied to the tree-obtained version of natural rubber in order to distinguish it from the synthetic version. The first use of rubber was by the cultures of Mesoamerica. The earliest archeological evidence of the use of latex from the Hevea tree comes the Olmec culture. The Pará rubber tree is indigenous to South America, charles Marie de La Condamine is credited with introducing samples of rubber to the Académie Royale des Sciences of France in 1736
8.
Molecule
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A molecule is an electrically neutral group of two or more atoms held together by chemical bonds. Molecules are distinguished from ions by their lack of electrical charge, however, in quantum physics, organic chemistry, and biochemistry, the term molecule is often used less strictly, also being applied to polyatomic ions. In the kinetic theory of gases, the molecule is often used for any gaseous particle regardless of its composition. According to this definition, noble gas atoms are considered molecules as they are in fact monoatomic molecules. A molecule may be homonuclear, that is, it consists of atoms of one element, as with oxygen, or it may be heteronuclear. Atoms and complexes connected by non-covalent interactions, such as hydrogen bonds or ionic bonds, are not considered single molecules. Molecules as components of matter are common in organic substances and they also make up most of the oceans and atmosphere. Also, no typical molecule can be defined for ionic crystals and covalent crystals, the theme of repeated unit-cellular-structure also holds for most condensed phases with metallic bonding, which means that solid metals are also not made of molecules. In glasses, atoms may also be together by chemical bonds with no presence of any definable molecule. The science of molecules is called molecular chemistry or molecular physics, in practice, however, this distinction is vague. In molecular sciences, a molecule consists of a system composed of two or more atoms. Polyatomic ions may sometimes be thought of as electrically charged molecules. The term unstable molecule is used for very reactive species, i. e, according to Merriam-Webster and the Online Etymology Dictionary, the word molecule derives from the Latin moles or small unit of mass. Molecule – extremely minute particle, from French molécule, from New Latin molecula, diminutive of Latin moles mass, a vague meaning at first, the vogue for the word can be traced to the philosophy of Descartes. The definition of the molecule has evolved as knowledge of the structure of molecules has increased, earlier definitions were less precise, defining molecules as the smallest particles of pure chemical substances that still retain their composition and chemical properties. Molecules are held together by covalent bonding or ionic bonding. Several types of non-metal elements exist only as molecules in the environment, for example, hydrogen only exists as hydrogen molecule. A molecule of a compound is made out of two or more elements, a covalent bond is a chemical bond that involves the sharing of electron pairs between atoms
9.
Protein
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Proteins are large biomolecules, or macromolecules, consisting of one or more long chains of amino acid residues. Proteins perform a vast array of functions within organisms, including catalysing metabolic reactions, DNA replication, responding to stimuli, a linear chain of amino acid residues is called a polypeptide. A protein contains at least one long polypeptide, short polypeptides, containing less than 20–30 residues, are rarely considered to be proteins and are commonly called peptides, or sometimes oligopeptides. The individual amino acid residues are bonded together by peptide bonds, the sequence of amino acid residues in a protein is defined by the sequence of a gene, which is encoded in the genetic code. In general, the code specifies 20 standard amino acids, however. Sometimes proteins have non-peptide groups attached, which can be called prosthetic groups or cofactors, proteins can also work together to achieve a particular function, and they often associate to form stable protein complexes. Once formed, proteins only exist for a period of time and are then degraded and recycled by the cells machinery through the process of protein turnover. A proteins lifespan is measured in terms of its half-life and covers a wide range and they can exist for minutes or years with an average lifespan of 1–2 days in mammalian cells. Abnormal and or misfolded proteins are degraded more rapidly due to being targeted for destruction or due to being unstable. Like other biological macromolecules such as polysaccharides and nucleic acids, proteins are essential parts of organisms, many proteins are enzymes that catalyse biochemical reactions and are vital to metabolism. Proteins also have structural or mechanical functions, such as actin and myosin in muscle and the proteins in the cytoskeleton, other proteins are important in cell signaling, immune responses, cell adhesion, and the cell cycle. In animals, proteins are needed in the diet to provide the essential amino acids that cannot be synthesized, digestion breaks the proteins down for use in the metabolism. Methods commonly used to study structure and function include immunohistochemistry, site-directed mutagenesis, X-ray crystallography, nuclear magnetic resonance. Most proteins consist of linear polymers built from series of up to 20 different L-α-amino acids, all proteinogenic amino acids possess common structural features, including an α-carbon to which an amino group, a carboxyl group, and a variable side chain are bonded. Only proline differs from this structure as it contains an unusual ring to the N-end amine group. The amino acids in a chain are linked by peptide bonds. Once linked in the chain, an individual amino acid is called a residue, and the linked series of carbon, nitrogen. The peptide bond has two forms that contribute some double-bond character and inhibit rotation around its axis, so that the alpha carbons are roughly coplanar
10.
Polycarbonate
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Polycarbonates are a group of thermoplastic polymers containing carbonate groups in their chemical structures. Polycarbonates used in engineering are strong, tough materials, and some grades are optically transparent and they are easily worked, molded, and thermoformed. Because of these properties, polycarbonates find many applications, Polycarbonates do not have a unique resin identification code and are identified as Other,7 on the RIC list. Products made from polycarbonate can contain the precursor monomer bisphenol A. Polycarbonates received their name because they are polymers containing carbonate groups, a balance of useful features, including temperature resistance, impact resistance and optical properties, positions polycarbonates between commodity plastics and engineering plastics. The main polycarbonate material is produced by the reaction of bisphenol A, the net reaction from the diphenoxide is, Na22CMe2 + COCl2 → 1/n n +2 NaCl In this way, approximately one billion kilograms of polycarbonate is produced annually. Many other diols have been tested in place of bisphenol A, e. g.1, the cyclohexane is used as a comonomer to suppress crystallisation tendency of the BPA-derived product. Tetrabromobisphenol A is used to enhance fire resistance, tetramethylcyclobutanediol has been developed as a replacement for BPA. Although it has high impact-resistance, it has low scratch-resistance, therefore, a hard coating is applied to polycarbonate eyewear lenses and polycarbonate exterior automotive components. The characteristics of polycarbonate compare to those of polymethyl methacrylate, but polycarbonate is stronger, Polycarbonate is highly transparent to visible light, with better light transmission than many kinds of glass. Polycarbonate has a transition temperature of about 147 °C, so it softens gradually above this point. Tools must be held at high temperatures, generally above 80 °C to make strain-free and stress-free products, low molecular mass grades are easier to mold than higher grades, but their strength is lower as a result. The toughest grades have the highest molecular mass, but are more difficult to process. Unlike most thermoplastics, polycarbonate can undergo plastic deformations without cracking or breaking. As a result, it can be processed and formed at room temperature using sheet metal techniques, even for sharp angle bends with a tight radius, heating may not be necessary. This makes it valuable in prototyping applications where transparent or electrically non-conductive parts are needed, pMMA/Acrylic, which is similar in appearance to polycarbonate, is brittle and cannot be bent at room temperature. Due to its chemical properties it is not conducive to laser-cutting, Injection molding into ready articles Polycarbonate may become brittle when exposed to ionizing radiation above 25 kGy. Polycarbonate is mainly used for applications that capitalize on its collective safety features. Being a good insulator and having heat-resistant and flame-retardant properties, it is used in various products associated with electrical
