A conjugate acid, within the Brønsted–Lowry acid–base theory, is a chemical compound formed by the reception of a proton by a base—in other words, it is a base with a hydrogen ion added to it. On the other hand, a conjugate base is what is left over after an acid has donated a proton during a chemical reaction. Hence, a conjugate base is a species formed by the removal of a proton from an acid; because some acids are capable of releasing multiple protons, the conjugate base of an acid may itself be acidic. In summary, this can be represented as the following chemical reaction: Acid + Base ⇌ Conjugate Base + Conjugate Acid Johannes Nicolaus Brønsted and Martin Lowry introduced the Brønsted–Lowry theory, which proposed that any compound that can transfer a proton to any other compound is an acid, the compound that accepts the proton is a base. A proton is a nuclear particle with a unit positive electrical charge. A cation can be a conjugate acid, an anion can be a conjugate base, depending on which substance is involved and which acid–base theory is the viewpoint.
The simplest anion which can be a conjugate base is the solvated electron whose conjugate acid is the atomic hydrogen. In an acid-base reaction, an acid plus a base reacts to form a conjugate base plus a conjugate acid: Conjugates are formed when an acid loses a hydrogen proton or a base gains a hydrogen proton. Refer to the following figure: We say that the water molecule is the conjugate acid of the hydroxide ion after the latter received the hydrogen proton donated by ammonium. On the other hand, ammonia is the conjugate base for the acid ammonium after ammonium has donated a hydrogen ion towards the production of the water molecule. We can refer to OH- as a conjugate base of H2O, since the water molecule donates a proton towards the production of NH+4 in the reverse reaction, the predominating process in nature due to the strength of the base NH3 over the hydroxide ion. Based on this information, it is clear that the terms "Acid", "Base", "conjugate acid", "conjugate base" are not fixed for a certain chemical species.
The strength of a conjugate acid is directly proportional to its dissociation constant. If a conjugate acid is strong, its dissociation will have a higher equilibrium constant and the products of the reaction will be favored; the strength of a conjugate base can be seen as the tendency of the species to "pull" hydrogen protons towards itself. If a conjugate base is classified as strong, it will "hold on" to the hydrogen proton when in solution and its acid will not dissociate. On the other hand, if a species is classified as a strong acid, its conjugate base will be weak in nature. An example of this case would be the dissociation of Hydrochloric acid HCl in water. Since HCl is a strong acid, its conjugate base will be a weak conjugate base. Therefore, in this system, most H+ will be in the form of a Hydronium ion H3O+ instead of attached to a Cl anion and the conjugate base will be weaker than a water molecule. If an acid is weak, its conjugate base will be strong; when considering the fact that the Kw is equal to the product of the concentrations of H+ and OH.
A weak acid will have a low concentration of H+. The Kw divided by a low H+ concentration will result in a low OH- concentration as well. Therefore, weak acids will have weak conjugate bases, unlike the misconception that they have strong conjugate bases; the acid and conjugate base as well as the base and conjugate acid are known as conjugate pairs. When finding a conjugate acid or base, it is important to look at the reactants of the chemical equation. In this case, the reactants are the acids and bases, the acid corresponds to the conjugate base on the product side of the chemical equation. To identify the conjugate acid, look for the pair of compounds that are related; the acid–base reaction can be viewed in a before and after sense. The before is the reactant side of the after is the product side of the equation; the conjugate acid in the after side of an equation gains a hydrogen ion, so in the before side of the equation the compound that has one less hydrogen ion of the conjugate acid is the base.
The conjugate base in the after side of the equation lost a hydrogen ion, so in the before side of the equation, the compound that has one more hydrogen ion of the conjugate base is the acid. Consider the following acid–base reaction: HNO3 + H2O → H3O+ + NO−3Nitric acid is an acid because it donates a proton to the water molecule and its conjugate base is nitrate; the water molecule acts as a base because it receives the Hydrogen Proton and its conjugate acid is the hydronium ion. One use of conjugate acids and bases lies in buffering systems. In a buffer, a weak acid and its conjugate base, or a weak base and its conjugate acid, are used in order to limit the pH change during a titration process. Buffers have both non-organic chemical applications. For example, besides buffers being used in lab processes, our blood acts as a buffer to maintain pH; the most important buffer in our bloodstream is the carbonic acid-bicarbonate buffer, which prevents drastic pH changes when CO2 is introduced. This functions as such: CO 2 + H 2 O ↽ − − ⇀ H 2 CO 3 ↽
Solid is one of the four fundamental states of matter. In solids particles are packed, it is characterized by structural resistance to changes of shape or volume. Unlike liquid, a solid object does not flow to take on the shape of its container, nor does it expand to fill the entire volume available to it like a gas does; the atoms in a solid are bound to each other, either in a regular geometric lattice or irregularly. Solids cannot be compressed with little pressure whereas gases can be compressed with little pressure because in gases molecules are loosely packed; the branch of physics that deals with solids is called solid-state physics, is the main branch of condensed matter physics. Materials science is concerned with the physical and chemical properties of solids. Solid-state chemistry is concerned with the synthesis of novel materials, as well as the science of identification and chemical composition; the atoms, molecules or ions that make up solids may be arranged in an orderly repeating pattern, or irregularly.
Materials whose constituents are arranged in a regular pattern are known as crystals. In some cases, the regular ordering can continue unbroken over a large scale, for example diamonds, where each diamond is a single crystal. Solid objects that are large enough to see and handle are composed of a single crystal, but instead are made of a large number of single crystals, known as crystallites, whose size can vary from a few nanometers to several meters; such materials are called polycrystalline. All common metals, many ceramics, are polycrystalline. In other materials, there is no long-range order in the position of the atoms; these solids are known as amorphous solids. Whether a solid is crystalline or amorphous depends on the material involved, the conditions in which it was formed. Solids that are formed by slow cooling will tend to be crystalline, while solids that are frozen are more to be amorphous; the specific crystal structure adopted by a crystalline solid depends on the material involved and on how it was formed.
While many common objects, such as an ice cube or a coin, are chemically identical throughout, many other common materials comprise a number of different substances packed together. For example, a typical rock is an aggregate of several different minerals and mineraloids, with no specific chemical composition. Wood is a natural organic material consisting of cellulose fibers embedded in a matrix of organic lignin. In materials science, composites of more than one constituent material can be designed to have desired properties; the forces between the atoms in a solid can take a variety of forms. For example, a crystal of sodium chloride is made up of ionic sodium and chlorine, which are held together by ionic bonds. In diamond or silicon, the atoms share form covalent bonds. In metals, electrons are shared in metallic bonding; some solids most organic compounds, are held together with van der Waals forces resulting from the polarization of the electronic charge cloud on each molecule. The dissimilarities between the types of solid result from the differences between their bonding.
Metals are strong and good conductors of both electricity and heat. The bulk of the elements in the periodic table, those to the left of a diagonal line drawn from boron to polonium, are metals. Mixtures of two or more elements in which the major component is a metal are known as alloys. People have been using metals for a variety of purposes since prehistoric times; the strength and reliability of metals has led to their widespread use in construction of buildings and other structures, as well as in most vehicles, many appliances and tools, road signs and railroad tracks. Iron and aluminium are the two most used structural metals, they are the most abundant metals in the Earth's crust. Iron is most used in the form of an alloy, which contains up to 2.1% carbon, making it much harder than pure iron. Because metals are good conductors of electricity, they are valuable in electrical appliances and for carrying an electric current over long distances with little energy loss or dissipation. Thus, electrical power grids rely on metal cables to distribute electricity.
Home electrical systems, for example, are wired with copper for its good conducting properties and easy machinability. The high thermal conductivity of most metals makes them useful for stovetop cooking utensils; the study of metallic elements and their alloys makes up a significant portion of the fields of solid-state chemistry, materials science and engineering. Metallic solids are held together by a high density of shared, delocalized electrons, known as "metallic bonding". In a metal, atoms lose their outermost electrons, forming positive ions; the free electrons are spread over the entire solid, held together by electrostatic interactions between the ions and the electron cloud. The large number of free electrons gives metals their high values of electrical and thermal conductivity; the free electrons prevent transmission of visible light, making metals opaque and lustrous. More advanced models of metal properties consider the effect of the positive ions cores on the delocalised electrons.
As most metals have crystalline structure, those ions are arranged into a periodic lattice. Mathematically, the potential of the ion cores can be treated by various models, the simplest being the nearly free electron model. Minerals are
Stoichiometry is the calculation of reactants and products in chemical reactions. Stoichiometry is founded on the law of conservation of mass where the total mass of the reactants equals the total mass of the products, leading to the insight that the relations among quantities of reactants and products form a ratio of positive integers; this means that if the amounts of the separate reactants are known the amount of the product can be calculated. Conversely, if one reactant has a known quantity and the quantity of the products can be empirically determined the amount of the other reactants can be calculated; this is illustrated in the image here, where the balanced equation is: CH4 + 2 O2 → CO2 + 2 H2O. Here, one molecule of methane reacts with two molecules of oxygen gas to yield one molecule of carbon dioxide and two molecules of water; this particular chemical equation is an example of complete combustion. Stoichiometry measures these quantitative relationships, is used to determine the amount of products and reactants that are produced or needed in a given reaction.
Describing the quantitative relationships among substances as they participate in chemical reactions is known as reaction stoichiometry. In the example above, reaction stoichiometry measures the relationship between the methane and oxygen as they react to form carbon dioxide and water; because of the well known relationship of moles to atomic weights, the ratios that are arrived at by stoichiometry can be used to determine quantities by weight in a reaction described by a balanced equation. This is called composition stoichiometry. Gas stoichiometry deals with reactions involving gases, where the gases are at a known temperature and volume and can be assumed to be ideal gases. For gases, the volume ratio is ideally the same by the ideal gas law, but the mass ratio of a single reaction has to be calculated from the molecular masses of the reactants and products. In practice, due to the existence of isotopes, molar masses are used instead when calculating the mass ratio; the term stoichiometry was first used by Jeremias Benjamin Richter in 1792 when the first volume of Richter's Stoichiometry or the Art of Measuring the Chemical Elements was published.
The term is derived from the Ancient Greek words στοιχεῖον stoicheion "element" and μέτρον metron "measure". In patristic Greek, the word Stoichiometria was used by Nicephorus to refer to the number of line counts of the canonical New Testament and some of the Apocrypha. A stoichiometric amount or stoichiometric ratio of a reagent is the optimum amount or ratio where, assuming that the reaction proceeds to completion: All of the reagent is consumed There is no deficiency of the reagent There is no excess of the reagent. Stoichiometry rests upon the basic laws that help to understand it better, i.e. law of conservation of mass, the law of definite proportions, the law of multiple proportions and the law of reciprocal proportions. In general, chemical reactions combine in definite ratios of chemicals. Since chemical reactions can neither create nor destroy matter, nor transmute one element into another, the amount of each element must be the same throughout the overall reaction. For example, the number of atoms of a given element X on the reactant side must equal the number of atoms of that element on the product side, whether or not all of those atoms are involved in a reaction.
Chemical reactions, as macroscopic unit operations, consist of a large number of elementary reactions, where a single molecule reacts with another molecule. As the reacting molecules consist of a definite set of atoms in an integer ratio, the ratio between reactants in a complete reaction is in integer ratio. A reaction may consume more than one molecule, the stoichiometric number counts this number, defined as positive for products and negative for reactants. Different elements have a different atomic mass, as collections of single atoms, molecules have a definite molar mass, measured with the unit mole. By definition, carbon-12 has a molar mass of 12 g/mol. Thus, to calculate the stoichiometry by mass, the number of molecules required for each reactant is expressed in moles and multiplied by the molar mass of each to give the mass of each reactant per mole of reaction; the mass ratios can be calculated by dividing each by the total in the whole reaction. Elements in their natural state are mixtures of isotopes of differing mass, thus atomic masses and thus molar masses are not integers.
For instance, instead of an exact 14:3 proportion, 17.04 kg of ammonia consists of 14.01 kg of nitrogen and 3 × 1.01 kg of hydrogen, because natural nitrogen includes a small amount of nitrogen-15, natural hydrogen includes hydrogen-2. A stoichiometric reactant is a reactant, consumed in a reaction, as opposed to a catalytic reactant, not consumed in the overall reaction because it reacts in one step and is regenerated in another step. Stoichiometry is not only used to balance chemical equations but used in conversions, i.e. converting from grams to moles using molar mass as the conversion factor, or from grams to milliliters using density. For example, to find the amount of NaCl in 2.00 g, one would do the following: 2.00 g NaCl 58.44 g NaCl mol − 1 = 0.034 mol In the above example, when written out in fraction form, the units of grams form a multiplicative identity, equivalent to one, wit
A carbocation is an ion with a positively charged carbon atom. Among the simplest examples are the methenium CH+3, methanium CH+5 and vinyl C2H+3 cations. Carbocations that bear more than one positively charged carbon atom are encountered; until the early 1970s, all carbocations were called carbonium ions. In present-day chemistry, a carbocation is any ion with a positively charged carbon atom, classified in two main categories according to the coordination number of the charged carbon: three in the carbenium ions and five in the carbonium ions; this nomenclature was proposed by G. A. Olah. Carbonium ions, as defined by Olah, are characterized by a three-center two-electron delocalized bonding scheme and are synonymous with so-called'nonclassical carbocations', which are carbocations that contain bridging C–C or C–H σ-bonds. However, others have more narrowly defined the term'carbonium ion' as formally protonated or alkylated alkanes, to the exclusion of nonclassical carbocations like the 2-norbornyl cation.
According to the IUPAC, a carbocation is any cation containing an number of electrons in which a significant portion of the positive charge resides on a carbon atom. Prior to the observation of five-coordinate carbocations by Olah and coworkers and carbonium ion were used interchangeably. Olah proposed a redefinition of carbonium ion as a carbocation featuring any type of three-center two-electron bonding, while a carbenium ion was newly coined to refer to a carbocation containing only two-center two-electron bonds with a three-coordinate positive carbon. Subsequently, others have used the term carbonium ion more narrowly to refer to species that are derived from electrophilic attack of H+ or R+ on an alkane, in analogy to other main group onium species, while a carbocation that contains any type of three-centered bonding is referred to as a nonclassical carbocation. In this usage, 2-norbornyl cation is not a carbonium ion, because it is formally derived from protonation of an alkene rather than an alkane, although it is a nonclassical carbocation due to its bridged structure.
The IUPAC acknowledges the three divergent definitions of carbonium ion and urges care in the usage of this term. For the remainder of this article, the term carbonium ion will be used in this latter restricted sense, while nonclassical carbocation will be used to refer to any carbocation with C–C and/or C–H σ-bonds delocalized by bridging. Since the late 1990s, most textbooks have stopped using the term carbonium ion for the classical three-coordinate carbocation. However, some university-level textbooks continue to use the term carbocation as if it were synonymous with carbenium ion, or discuss carbocations with only a fleeting reference to the older terminology of carbonium ions or carbenium and carbonium ions. One textbook retains the older name of carbonium ion for carbenium ion to this day, uses the phrase hypervalent carbonium ion for CH+5. A carbocation with an two-coordinate sp-hybridized positive carbon is known as a vinyl cation, while a two-coordinate sp2-hybridized cation resulting from the formal removal of a hydride ion from an arene is termed an aryl cation.
These carbocations are unstable and are infrequently encountered. Hence, they are omitted from introductory and intermediate level textbooks; the IUPAC definition stipulates. The history of carbocations dates back to 1891 when G. Merling reported that he added bromine to tropylidene and heated the product to obtain a crystalline, water-soluble material, C7H7Br, he did not suggest a structure for it. This ion is predicted to be aromatic by Hückel's rule. In 1902, Norris and Kehrman independently discovered that colorless triphenylmethanol gives deep-yellow solutions in concentrated sulfuric acid. Triphenylmethyl chloride formed orange complexes with aluminium and tin chlorides. In 1902, Adolf von Baeyer recognized the salt-like character of the compounds formed, he dubbed the relationship between color and salt formation halochromy, of which malachite green is a prime example. Carbocations are reactive intermediates in many organic reactions; this idea, first proposed by Julius Stieglitz in 1899, was further developed by Hans Meerwein in his 1922 study of the Wagner–Meerwein rearrangement.
Carbocations were found to be involved in the SN1 reaction, the E1 reaction, in rearrangement reactions such as the Whitmore 1,2 shift. The chemical establishment was reluctant to accept the notion of a carbocation and for a long time the Journal of the American Chemical Society refused articles that mentioned them; the first NMR spectrum of a stable carbocation in solution was published by Doering et al. in 1958. It was the heptamethylbenzenium ion, made by treating hexamethylbenzene with methyl chloride and aluminium chloride; the stable 7-norbornadienyl cation was prepared by Story et al. in 1960 by reacting norbornadienyl chloride with silver tetrafluoroborate in sulfur dioxide at −80 °C. The NMR spectrum established. In 1962, Olah directly observed the tert-butyl carbocation by nuclear magnetic resonance as a stable species on dissolving tert-butyl fluoride in magic acid; the NMR of the norbornyl cation was first reported by Schleyer et al. and it was shown to undergo proton-scrambling over a barrier by Saunders et al.
Catalysis is the process of increasing the rate of a chemical reaction by adding a substance known as a catalyst, not consumed in the catalyzed reaction and can continue to act repeatedly. Because of this, only small amounts of catalyst are required to alter the reaction rate in principle. In general, chemical reactions occur faster in the presence of a catalyst because the catalyst provides an alternative reaction pathway with a lower activation energy than the non-catalyzed mechanism. In catalyzed mechanisms, the catalyst reacts to form a temporary intermediate, which regenerates the original catalyst in a cyclic process. A substance which provides a mechanism with a higher activation energy does not decrease the rate because the reaction can still occur by the non-catalyzed route. An added substance which does reduce the reaction rate is not considered a catalyst but a reaction inhibitor. Catalysts may be classified as either heterogeneous. A homogeneous catalyst is one whose molecules are dispersed in the same phase as the reactant's molecules.
A heterogeneous catalyst is one whose molecules are not in the same phase as the reactant's, which are gases or liquids that are adsorbed onto the surface of the solid catalyst. Enzymes and other biocatalysts are considered as a third category. In the presence of a catalyst, less free energy is required to reach the transition state, but the total free energy from reactants to products does not change. A catalyst may participate in multiple chemical transformations; the effect of a catalyst may vary due to the presence of other substances known as inhibitors or poisons or promoters. Catalyzed reactions have a lower activation energy than the corresponding uncatalyzed reaction, resulting in a higher reaction rate at the same temperature and for the same reactant concentrations. However, the detailed mechanics of catalysis is complex. Catalysts may bind to the reagents to polarize bonds, e.g. acid catalysts for reactions of carbonyl compounds, or form specific intermediates that are not produced such as osmate esters in osmium tetroxide-catalyzed dihydroxylation of alkenes, or cause dissociation of reagents to reactive forms, such as chemisorbed hydrogen in catalytic hydrogenation.
Kinetically, catalytic reactions are typical chemical reactions. The catalyst participates in this slowest step, rates are limited by amount of catalyst and its "activity". In heterogeneous catalysis, the diffusion of reagents to the surface and diffusion of products from the surface can be rate determining. A nanomaterial-based catalyst is an example of a heterogeneous catalyst. Analogous events associated with substrate binding and product dissociation apply to homogeneous catalysts. Although catalysts are not consumed by the reaction itself, they may be inhibited, deactivated, or destroyed by secondary processes. In heterogeneous catalysis, typical secondary processes include coking where the catalyst becomes covered by polymeric side products. Additionally, heterogeneous catalysts can dissolve into the solution in a solid–liquid system or sublimate in a solid–gas system; the production of most industrially important chemicals involves catalysis. Most biochemically significant processes are catalysed.
Research into catalysis is a major field in applied science and involves many areas of chemistry, notably organometallic chemistry and materials science. Catalysis is relevant to many aspects of environmental science, e.g. the catalytic converter in automobiles and the dynamics of the ozone hole. Catalytic reactions are preferred in environmentally friendly green chemistry due to the reduced amount of waste generated, as opposed to stoichiometric reactions in which all reactants are consumed and more side products are formed. Many transition metals and transition metal complexes are used in catalysis as well. Catalysts called. A catalyst works by providing an alternative reaction pathway to the reaction product; the rate of the reaction is increased as this alternative route has a lower activation energy than the reaction route not mediated by the catalyst. The disproportionation of hydrogen peroxide creates oxygen, as shown below. 2 H2O2 → 2 H2O + O2This reaction is preferable in the sense that the reaction products are more stable than the starting material, though the uncatalysed reaction is slow.
In fact, the decomposition of hydrogen peroxide is so slow that hydrogen peroxide solutions are commercially available. This reaction is affected by catalysts such as manganese dioxide, or the enzyme peroxidase in organisms. Upon the addition of a small amount of manganese dioxide, the hydrogen peroxide reacts rapidly; this effect is seen by the effervescence of oxygen. The manganese dioxide is not consumed in the reaction, thus may be recovered unchanged, re-used indefinitely. Accordingly, manganese dioxide catalyses this reaction. Catalytic activity is denoted by the symbol z and measured in mol/s, a unit, called katal and defined the SI unit for catalytic activity since 1999. Catalytic activity is not a kind of reaction rate, but a property of the catalyst under certain conditions, in relation to a specific chemical reaction. Catalytic activity of one katal of a catalyst means one mole of that catalyst will catalyse 1 mole of the reactant to product in one second. A catalyst may and will have different catalytic activity for di
Mass spectrometry is an analytical technique that ionizes chemical species and sorts the ions based on their mass-to-charge ratio. In simpler terms, a mass spectrum measures the masses within a sample. Mass spectrometry is used in many different fields and is applied to pure samples as well as complex mixtures. A mass spectrum is a plot of the ion signal as a function of the mass-to-charge ratio; these spectra are used to determine the elemental or isotopic signature of a sample, the masses of particles and of molecules, to elucidate the chemical structures of molecules and other chemical compounds. In a typical MS procedure, a sample, which may be solid, liquid, or gas, is ionized, for example by bombarding it with electrons; this may cause some of the sample's molecules to break into charged fragments. These ions are separated according to their mass-to-charge ratio by accelerating them and subjecting them to an electric or magnetic field: ions of the same mass-to-charge ratio will undergo the same amount of deflection.
The ions are detected by a mechanism capable of detecting charged particles, such as an electron multiplier. Results are displayed as spectra of the relative abundance of detected ions as a function of the mass-to-charge ratio; the atoms or molecules in the sample can be identified by correlating known masses to the identified masses or through a characteristic fragmentation pattern. In 1886, Eugen Goldstein observed rays in gas discharges under low pressure that traveled away from the anode and through channels in a perforated cathode, opposite to the direction of negatively charged cathode rays. Goldstein called these positively charged anode rays "Kanalstrahlen". Wilhelm Wien found that strong electric or magnetic fields deflected the canal rays and, in 1899, constructed a device with perpendicular electric and magnetic fields that separated the positive rays according to their charge-to-mass ratio. Wien found. English scientist J. J. Thomson improved on the work of Wien by reducing the pressure to create the mass spectrograph.
The word spectrograph had become part of the international scientific vocabulary by 1884. Early spectrometry devices that measured the mass-to-charge ratio of ions were called mass spectrographs which consisted of instruments that recorded a spectrum of mass values on a photographic plate. A mass spectroscope is similar to a mass spectrograph except that the beam of ions is directed onto a phosphor screen. A mass spectroscope configuration was used in early instruments when it was desired that the effects of adjustments be observed. Once the instrument was properly adjusted, a photographic plate was exposed; the term mass spectroscope continued to be used though the direct illumination of a phosphor screen was replaced by indirect measurements with an oscilloscope. The use of the term mass spectroscopy is now discouraged due to the possibility of confusion with light spectroscopy. Mass spectrometry is abbreviated as mass-spec or as MS. Modern techniques of mass spectrometry were devised by Arthur Jeffrey Dempster and F.
W. Aston in 1918 and 1919 respectively. Sector mass spectrometers known as calutrons were developed by Ernest O. Lawrence and used for separating the isotopes of uranium during the Manhattan Project. Calutron mass spectrometers were used for uranium enrichment at the Oak Ridge, Tennessee Y-12 plant established during World War II. In 1989, half of the Nobel Prize in Physics was awarded to Hans Dehmelt and Wolfgang Paul for the development of the ion trap technique in the 1950s and 1960s. In 2002, the Nobel Prize in Chemistry was awarded to John Bennett Fenn for the development of electrospray ionization and Koichi Tanaka for the development of soft laser desorption and their application to the ionization of biological macromolecules proteins. A mass spectrometer consists of three components: an ion source, a mass analyzer, a detector; the ionizer converts a portion of the sample into ions. There is a wide variety of ionization techniques, depending on the phase of the sample and the efficiency of various ionization mechanisms for the unknown species.
An extraction system removes ions from the sample, which are targeted through the mass analyzer and into the detector. The differences in masses of the fragments allows the mass analyzer to sort the ions by their mass-to-charge ratio; the detector measures the value of an indicator quantity and thus provides data for calculating the abundances of each ion present. Some detectors give spatial information, e.g. a multichannel plate. The following example describes the operation of a spectrometer mass analyzer, of the sector type. Consider a sample of sodium chloride. In the ion source, the sample is ionized into sodium and chloride ions. Sodium atoms and ions are monoisotopic, with a mass of about 23 u. Chloride atoms and ions come in two isotopes with masses of 35 u and 37 u; the analyzer part of the spectrometer contains electric and magnetic fields, which exert forces on ions traveling through these fields. The speed of a charged particle may be increased or decreased while passing through the electric field, its direction may be altered by the magnetic field.
The magnitude of the deflection of the moving ion's trajectory depends on its mass-to-charge ratio. L
Sulfuric acid known as vitriol, is a mineral acid composed of the elements sulfur and hydrogen, with molecular formula H2SO4. It is a colorless and syrupy liquid, soluble in water, in a reaction, exothermic, its corrosiveness can be ascribed to its strong acidic nature, and, if at a high concentration, its dehydrating and oxidizing properties. It is hygroscopic absorbing water vapor from the air. Upon contact, sulfuric acid can cause severe chemical burns and secondary thermal burns. Sulfuric acid is a important commodity chemical, a nation's sulfuric acid production is a good indicator of its industrial strength, it is produced with different methods, such as contact process, wet sulfuric acid process, lead chamber process and some other methods. Sulfuric acid is a key substance in the chemical industry, it is most used in fertilizer manufacture, but is important in mineral processing, oil refining, wastewater processing, chemical synthesis. It has a wide range of end applications including in domestic acidic drain cleaners, as an electrolyte in lead-acid batteries, in various cleaning agents.
Although nearly 100% sulfuric acid can be made, the subsequent loss of SO3 at the boiling point brings the concentration to 98.3% acid. The 98.3% grade is more stable in storage, is the usual form of what is described as "concentrated sulfuric acid". Other concentrations are used for different purposes; some common concentrations are: "Chamber acid" and "tower acid" were the two concentrations of sulfuric acid produced by the lead chamber process, chamber acid being the acid produced in the lead chamber itself and tower acid being the acid recovered from the bottom of the Glover tower. They are now obsolete as commercial concentrations of sulfuric acid, although they may be prepared in the laboratory from concentrated sulfuric acid if needed. In particular, "10M" sulfuric acid is prepared by adding 98% sulfuric acid to an equal volume of water, with good stirring: the temperature of the mixture can rise to 80 °C or higher. Sulfuric acid reacts with its anhydride, SO3, to form H2S2O7, called pyrosulfuric acid, fuming sulfuric acid, Disulfuric acid or oleum or, less Nordhausen acid.
Concentrations of oleum are either expressed in terms of % SO3 or as % H2SO4. Pure H2S2O7 is a solid with melting point of 36 °C. Pure sulfuric acid has a vapor pressure of <0.001 mmHg at 25 °C and 1 mmHg at 145.8 °C, 98% sulfuric acid has a <1 mmHg vapor pressure at 40 °C. Pure sulfuric acid is a viscous clear liquid, like oil, this explains the old name of the acid. Commercial sulfuric acid is sold in several different purity grades. Technical grade H2SO4 is impure and colored, but is suitable for making fertilizer. Pure grades, such as United States Pharmacopeia grade, are used for making pharmaceuticals and dyestuffs. Analytical grades are available. Nine hydrates are known, but four of them were confirmed to be tetrahydrate and octahydrate. Anhydrous H2SO4 is a polar liquid, having a dielectric constant of around 100, it has a high electrical conductivity, caused by dissociation through protonating itself, a process known as autoprotolysis. 2 H2SO4 ⇌ H3SO+4 + HSO−4The equilibrium constant for the autoprotolysis is Kap = = 2.7×10−4The comparable equilibrium constant for water, Kw is 10−14, a factor of 1010 smaller.
In spite of the viscosity of the acid, the effective conductivities of the H3SO+4 and HSO−4 ions are high due to an intramolecular proton-switch mechanism, making sulfuric acid a good conductor of electricity. It is an excellent solvent for many reactions; because the hydration reaction of sulfuric acid is exothermic, dilution should always be performed by adding the acid to the water rather than the water to the acid. Because the reaction is in an equilibrium that favors the rapid protonation of water, addition of acid to the water ensures that the acid is the limiting reagent; this reaction is best thought of as the formation of hydronium ions: H2SO4 + H2O → H3O+ + HSO−4 Ka1 = 2.4×106 HSO−4 + H2O → H3O+ + SO2−4 Ka2 = 1.0×10−2 HSO−4 is the bisulfate anion and SO2−4 is the sulfate anion. Ka1 and Ka2 are the acid dissociation constants; because the hydration of sulfuric acid is thermodynamically favorable and the affinity of it for water is sufficiently strong, sulfuric acid is an excellent dehydrating agent.
Concentrated sulfuric acid has a powerful dehydrating property, removing water from other chemical compounds including sugar and other carbohydrates and producing carbon and steam. In the laboratory, this is demonstrated by mixing table sugar into sulfuric acid; the sugar changes from white to dark brown and to black as carbon is formed. A rigid column of black, porous carbon will emerge as well; the carbon will smell of caramel due to the heat generated. C 12 H 22 O 11 ⏞ sucrose → H 2 SO 4 12 C + 11 H 2