A synthetic rubber is an artificial elastomer. They are polymers synthesized from petroleum byproducts. About 32 million metric tons of rubbers are produced annually in the United States, and of that amount two thirds are synthetic. Synthetic rubber, just like natural rubber, has many uses in the automotive industry for tires, door and window profiles, seals such as O-rings and gaskets, hoses, belts, matting, and flooring. They offer a different range of physical and chemical properties which can improve the reliability of a given product or application. Synthetic rubbers are superior to natural rubbers in two major respects: thermal stability, and resistance to oils and related compounds. They are more resistant to oxidizing agents, such as oxygen and ozone which can reduce the life of products like tires.
John Boyd Dunlop (c. 1915)
Sheet of synthetic rubber coming off the rolling mill at the plant of Goodrich (1941)
World War II poster about synthetic rubber tires
A polymer
is a substance or material consisting of very large molecules called macromolecules, composed of many repeating subunits. Due to their broad spectrum of properties, both synthetic and natural polymers play essential and ubiquitous roles in everyday life. Polymers range from familiar synthetic plastics such as polystyrene to natural biopolymers such as DNA and proteins that are fundamental to biological structure and function. Polymers, both natural and synthetic, are created via polymerization of many small molecules, known as monomers. Their consequently large molecular mass, relative to small molecule compounds, produces unique physical properties including toughness, high elasticity, viscoelasticity, and a tendency to form amorphous and semicrystalline structures rather than crystals.
Appearance of real linear polymer chains as recorded using an atomic force microscope on a surface, under liquid medium. Chain contour length for this polymer is ~204 nm; thickness is ~0.4 nm.
A polyethylene sample that has necked under tension
A plastic item with thirty years of exposure to heat and cold, brake fluid, and sunlight. Notice the discoloration and crazing of the material (compared with replacement item in foreground).
Chlorine attack of acetal resin plumbing joint