The 8×50mmR Lebel rifle cartridge was the first smokeless powder cartridge to be made and adopted by any country. It was introduced by France in 1886. Formed by necking down the 11×59mmR Gras black powder cartridge, the smokeless 8mm Lebel cartridge started a revolution in military rifle ammunition. Standard 8mm Lebel military ammunition was also the first rifle ammunition to feature a spitzer boat tail bullet, which was adopted in 1898. The long-range ballistic performance of the 8mm Lebel bullet itself was exceptional for its time. For use in the magazine tube-fed early Lebel rifle, the 8 mm case was designed to protect against accidental percussion inside the tube magazine by a circular groove around the primer cup which caught the tip of the following pointed bullet. However, the shape of its rimmed bottle-necked case, having been designed for the Lebel rifle's tube magazine, also precluded truly efficient vertical stacking inside a vertical magazine. The bolt thrust of the 8mm Lebel is relatively high compared to many other service rounds used in the early 20th century. Although it was once revolutionary, the 8mm Lebel was declared obsolete after World War I and was soon after replaced with the 7.5×54mm French round.

Smokeless powder is a type of propellant used in firearms and artillery that produces less smoke and less fouling when fired compared to black powder. Because of their similar use, both the original black powder formulation and the smokeless propellant which replaced it are commonly described as gunpowder. The combustion products of smokeless powder are mainly gaseous, compared to around 55% solid products for black powder. In addition, smokeless powder does not leave the thick, heavy fouling of hygroscopic material associated with black powder that causes rusting of the barrel.