1.
Melting point
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The melting point of a solid is the temperature at which it changes state from solid to liquid at atmospheric pressure. At the melting point the solid and liquid phase exist in equilibrium, the melting point of a substance depends on pressure and is usually specified at standard pressure. When considered as the temperature of the change from liquid to solid. Because of the ability of some substances to supercool, the point is not considered as a characteristic property of a substance. For most substances, melting and freezing points are approximately equal, for example, the melting point and freezing point of mercury is 234.32 kelvins. However, certain substances possess differing solid-liquid transition temperatures, for example, agar melts at 85 °C and solidifies from 31 °C to 40 °C, such direction dependence is known as hysteresis. The melting point of ice at 1 atmosphere of pressure is close to 0 °C. In the presence of nucleating substances the freezing point of water is the same as the melting point, the chemical element with the highest melting point is tungsten, at 3687 K, this property makes tungsten excellent for use as filaments in light bulbs. Many laboratory techniques exist for the determination of melting points, a Kofler bench is a metal strip with a temperature gradient. Any substance can be placed on a section of the strip revealing its thermal behaviour at the temperature at that point, differential scanning calorimetry gives information on melting point together with its enthalpy of fusion. A basic melting point apparatus for the analysis of crystalline solids consists of an oil bath with a transparent window, the several grains of a solid are placed in a thin glass tube and partially immersed in the oil bath. The oil bath is heated and with the aid of the melting of the individual crystals at a certain temperature can be observed. In large/small devices, the sample is placed in a heating block, the measurement can also be made continuously with an operating process. For instance, oil refineries measure the point of diesel fuel online, meaning that the sample is taken from the process. This allows for more frequent measurements as the sample does not have to be manually collected, for refractory materials the extremely high melting point may be determined by heating the material in a black body furnace and measuring the black-body temperature with an optical pyrometer. For the highest melting materials, this may require extrapolation by several hundred degrees, the spectral radiance from an incandescent body is known to be a function of its temperature. An optical pyrometer matches the radiance of a body under study to the radiance of a source that has been previously calibrated as a function of temperature, in this way, the measurement of the absolute magnitude of the intensity of radiation is unnecessary. However, known temperatures must be used to determine the calibration of the pyrometer, for temperatures above the calibration range of the source, an extrapolation technique must be employed
2.
Hexagonal crystal family
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In crystallography, the hexagonal crystal family is one of the 6 crystal families. In the hexagonal family, the crystal is described by a right rhombic prism unit cell with two equal axes, an included angle of 120° and a height perpendicular to the two base axes. There are 52 space groups associated with it, which are exactly those whose Bravais lattice is either hexagonal or rhombohedral, the hexagonal crystal family consists of two lattice systems, hexagonal and rhombohedral. Each lattice system consists of one Bravais lattice, hence, there are 3 lattice points per unit cell in total and the lattice is non-primitive. The Bravais lattices in the hexagonal crystal family can also be described by rhombohedral axes, the unit cell is a rhombohedron. This is a cell with parameters a = b = c, α = β = γ ≠ 90°. In practice, the description is more commonly used because it is easier to deal with a coordinate system with two 90° angles. However, the axes are often shown in textbooks because this cell reveals 3m symmetry of crystal lattice. However, such a description is rarely used, the hexagonal crystal family consists of two crystal systems, trigonal and hexagonal. A crystal system is a set of point groups in which the point groups themselves, the trigonal crystal system consists of the 5 point groups that have a single three-fold rotation axis. The crystal structures of alpha-quartz in the example are described by two of those 18 space groups associated with the hexagonal lattice system. The hexagonal crystal system consists of the seven point groups such that all their groups have the hexagonal lattice as underlying lattice. Graphite is an example of a crystal that crystallizes in the crystal system. Note that the atom in the center of the HCP unit cell in the hexagonal lattice system does not appear in the unit cell of the hexagonal lattice. It is part of the two atom motif associated with each point in the underlying lattice. The trigonal crystal system is the crystal system whose point groups have more than one lattice system associated with their space groups. The 5 point groups in this system are listed below, with their international number and notation, their space groups in name. The point groups in this system are listed below, followed by their representations in Hermann–Mauguin or international notation and Schoenflies notation
3.
Occupational safety and health
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These terms of course also refer to the goals of this field, so their use in the sense of this article was originally an abbreviation of occupational safety and health program/department etc. The goals of occupational safety and health programs include to foster a safe, OSH may also protect co-workers, family members, employers, customers, and many others who might be affected by the workplace environment. In the United States, the occupational health and safety is referred to as occupational health and occupational and non-occupational safety. In common-law jurisdictions, employers have a common law duty to take care of the safety of their employees. As defined by the World Health Organization occupational health deals with all aspects of health, Health has been defined as a state of complete physical, mental and social well-being and not merely the absence of disease or infirmity. Occupational health is a field of healthcare concerned with enabling an individual to undertake their occupation. Health has been defined as It contrasts, for example, with the promotion of health and safety at work, since 1950, the International Labour Organization and the World Health Organization have shared a common definition of occupational health. It was adopted by the Joint ILO/WHO Committee on Occupational Health at its first session in 1950, the concept of working culture is intended in this context to mean a reflection of the essential value systems adopted by the undertaking concerned. Such a culture is reflected in practice in the systems, personnel policy, principles for participation, training policies. Professionals advise on a range of occupational health matters. The research and regulation of safety and health are a relatively recent phenomenon. As labor movements arose in response to concerns in the wake of the industrial revolution. The initial remit of the Inspectorate was to police restrictions on the hours in the textile industry of children. The commission sparked public outrage resulted in the Mines Act of 1842. Otto von Bismarck inaugurated the first social insurance legislation in 1883, similar acts followed in other countries, partly in response to labor unrest. Although work provides many economic and other benefits, an array of workplace hazards also present risks to the health. Personal protective equipment can protect against many of these hazards. Physical hazards affect many people in the workplace, Falls are also a common cause of occupational injuries and fatalities, especially in construction, extraction, transportation, healthcare, and building cleaning and maintenance
4.
Nitrogen
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Nitrogen is a chemical element with symbol N and atomic number 7. It was first discovered and isolated by Scottish physician Daniel Rutherford in 1772, although Carl Wilhelm Scheele and Henry Cavendish had independently done so at about the same time, Rutherford is generally accorded the credit because his work was published first. Nitrogen is the lightest member of group 15 of the periodic table, the name comes from the Greek πνίγειν to choke, directly referencing nitrogens asphyxiating properties. It is an element in the universe, estimated at about seventh in total abundance in the Milky Way. At standard temperature and pressure, two atoms of the element bind to form dinitrogen, a colourless and odorless diatomic gas with the formula N2, dinitrogen forms about 78% of Earths atmosphere, making it the most abundant uncombined element. Nitrogen occurs in all organisms, primarily in amino acids, in the nucleic acids, the human body contains about 3% nitrogen by mass, the fourth most abundant element in the body after oxygen, carbon, and hydrogen. The nitrogen cycle describes movement of the element from the air, into the biosphere and organic compounds, many industrially important compounds, such as ammonia, nitric acid, organic nitrates, and cyanides, contain nitrogen. The extremely strong bond in elemental nitrogen, the second strongest bond in any diatomic molecule. Synthetically produced ammonia and nitrates are key industrial fertilisers, and fertiliser nitrates are key pollutants in the eutrophication of water systems. Apart from its use in fertilisers and energy-stores, nitrogen is a constituent of organic compounds as diverse as Kevlar used in high-strength fabric, Nitrogen is a constituent of every major pharmacological drug class, including antibiotics. Many notable nitrogen-containing drugs, such as the caffeine and morphine or the synthetic amphetamines. Nitrogen compounds have a long history, ammonium chloride having been known to Herodotus. They were well known by the Middle Ages, alchemists knew nitric acid as aqua fortis, as well as other nitrogen compounds such as ammonium salts and nitrate salts. The mixture of nitric and hydrochloric acids was known as aqua regia, celebrated for its ability to dissolve gold, the discovery of nitrogen is attributed to the Scottish physician Daniel Rutherford in 1772, who called it noxious air. Though he did not recognise it as a different chemical substance, he clearly distinguished it from Joseph Blacks fixed air. The fact that there was a component of air that does not support combustion was clear to Rutherford, Nitrogen was also studied at about the same time by Carl Wilhelm Scheele, Henry Cavendish, and Joseph Priestley, who referred to it as burnt air or phlogisticated air. Nitrogen gas was inert enough that Antoine Lavoisier referred to it as air or azote, from the Greek word άζωτικός. In an atmosphere of nitrogen, animals died and flames were extinguished
5.
Hydrogen
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Hydrogen is a chemical element with chemical symbol H and atomic number 1. With a standard weight of circa 1.008, hydrogen is the lightest element on the periodic table. Its monatomic form is the most abundant chemical substance in the Universe, non-remnant stars are mainly composed of hydrogen in the plasma state. The most common isotope of hydrogen, termed protium, has one proton, the universal emergence of atomic hydrogen first occurred during the recombination epoch. At standard temperature and pressure, hydrogen is a colorless, odorless, tasteless, non-toxic, nonmetallic, since hydrogen readily forms covalent compounds with most nonmetallic elements, most of the hydrogen on Earth exists in molecular forms such as water or organic compounds. Hydrogen plays an important role in acid–base reactions because most acid-base reactions involve the exchange of protons between soluble molecules. In ionic compounds, hydrogen can take the form of a charge when it is known as a hydride. The hydrogen cation is written as though composed of a bare proton, Hydrogen gas was first artificially produced in the early 16th century by the reaction of acids on metals. Industrial production is mainly from steam reforming natural gas, and less often from more energy-intensive methods such as the electrolysis of water. Most hydrogen is used near the site of its production, the two largest uses being fossil fuel processing and ammonia production, mostly for the fertilizer market, Hydrogen is a concern in metallurgy as it can embrittle many metals, complicating the design of pipelines and storage tanks. Hydrogen gas is flammable and will burn in air at a very wide range of concentrations between 4% and 75% by volume. The enthalpy of combustion is −286 kJ/mol,2 H2 + O2 →2 H2O +572 kJ Hydrogen gas forms explosive mixtures with air in concentrations from 4–74%, the explosive reactions may be triggered by spark, heat, or sunlight. The hydrogen autoignition temperature, the temperature of spontaneous ignition in air, is 500 °C, the detection of a burning hydrogen leak may require a flame detector, such leaks can be very dangerous. Hydrogen flames in other conditions are blue, resembling blue natural gas flames, the destruction of the Hindenburg airship was a notorious example of hydrogen combustion and the cause is still debated. The visible orange flames in that incident were the result of a mixture of hydrogen to oxygen combined with carbon compounds from the airship skin. H2 reacts with every oxidizing element, the ground state energy level of the electron in a hydrogen atom is −13.6 eV, which is equivalent to an ultraviolet photon of roughly 91 nm wavelength. The energy levels of hydrogen can be calculated fairly accurately using the Bohr model of the atom, however, the atomic electron and proton are held together by electromagnetic force, while planets and celestial objects are held by gravity. The most complicated treatments allow for the effects of special relativity
6.
Oxygen
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Oxygen is a chemical element with symbol O and atomic number 8. It is a member of the group on the periodic table and is a highly reactive nonmetal. By mass, oxygen is the third-most abundant element in the universe, after hydrogen, at standard temperature and pressure, two atoms of the element bind to form dioxygen, a colorless and odorless diatomic gas with the formula O2. This is an important part of the atmosphere and diatomic oxygen gas constitutes 20. 8% of the Earths atmosphere, additionally, as oxides the element makes up almost half of the Earths crust. Most of the mass of living organisms is oxygen as a component of water, conversely, oxygen is continuously replenished by photosynthesis, which uses the energy of sunlight to produce oxygen from water and carbon dioxide. Oxygen is too reactive to remain a free element in air without being continuously replenished by the photosynthetic action of living organisms. Another form of oxygen, ozone, strongly absorbs ultraviolet UVB radiation, but ozone is a pollutant near the surface where it is a by-product of smog. At low earth orbit altitudes, sufficient atomic oxygen is present to cause corrosion of spacecraft, the name oxygen was coined in 1777 by Antoine Lavoisier, whose experiments with oxygen helped to discredit the then-popular phlogiston theory of combustion and corrosion. One of the first known experiments on the relationship between combustion and air was conducted by the 2nd century BCE Greek writer on mechanics, Philo of Byzantium. In his work Pneumatica, Philo observed that inverting a vessel over a burning candle, Philo incorrectly surmised that parts of the air in the vessel were converted into the classical element fire and thus were able to escape through pores in the glass. Many centuries later Leonardo da Vinci built on Philos work by observing that a portion of air is consumed during combustion and respiration, Oxygen was discovered by the Polish alchemist Sendivogius, who considered it the philosophers stone. In the late 17th century, Robert Boyle proved that air is necessary for combustion, English chemist John Mayow refined this work by showing that fire requires only a part of air that he called spiritus nitroaereus. From this he surmised that nitroaereus is consumed in both respiration and combustion, Mayow observed that antimony increased in weight when heated, and inferred that the nitroaereus must have combined with it. Accounts of these and other experiments and ideas were published in 1668 in his work Tractatus duo in the tract De respiratione. Robert Hooke, Ole Borch, Mikhail Lomonosov, and Pierre Bayen all produced oxygen in experiments in the 17th and the 18th century but none of them recognized it as a chemical element. This may have been in part due to the prevalence of the philosophy of combustion and corrosion called the phlogiston theory, which was then the favored explanation of those processes. Established in 1667 by the German alchemist J. J. Becher, one part, called phlogiston, was given off when the substance containing it was burned, while the dephlogisticated part was thought to be its true form, or calx. The fact that a substance like wood gains overall weight in burning was hidden by the buoyancy of the combustion products
7.
Agriculture
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Agriculture is the cultivation and breeding of animals, plants and fungi for food, fiber, biofuel, medicinal plants and other products used to sustain and enhance human life. Agriculture was the key development in the rise of human civilization. The study of agriculture is known as agricultural science, the history of agriculture dates back thousands of years, and its development has been driven and defined by greatly different climates, cultures, and technologies. Industrial agriculture based on large-scale monoculture farming has become the dominant agricultural methodology, genetically modified organisms are an increasing component of agriculture, although they are banned in several countries. Agricultural food production and water management are increasingly becoming global issues that are fostering debate on a number of fronts, the major agricultural products can be broadly grouped into foods, fibers, fuels, and raw materials. Specific foods include cereals, vegetables, fruits, oils, meats, fibers include cotton, wool, hemp, silk and flax. Raw materials include lumber and bamboo, other useful materials are also produced by plants, such as resins, dyes, drugs, perfumes, biofuels and ornamental products such as cut flowers and nursery plants. The word agriculture is a late Middle English adaptation of Latin agricultūra, from ager, field, Agriculture usually refers to human activities, although it is also observed in certain species of ant, termite and ambrosia beetle. To practice agriculture means to use resources to produce commodities which maintain life, including food, fiber, forest products, horticultural crops. This definition includes arable farming or agronomy, and horticulture, all terms for the growing of plants, even then, it is acknowledged that there is a large amount of knowledge transfer and overlap between silviculture and agriculture. In traditional farming, the two are often combined even on small landholdings, leading to the term agroforestry, Agriculture began independently in different parts of the globe, and included a diverse range of taxa. At least 11 separate regions of the Old and New World were involved as independent centers of origin, wild grains were collected and eaten from at least 105,000 years ago. Pigs were domesticated in Mesopotamia around 15,000 years ago, rice was domesticated in China between 13,500 and 8,200 years ago, followed by mung, soy and azuki beans. Sheep were domesticated in Mesopotamia between 13,000 and 11,000 years ago. From around 11,500 years ago, the eight Neolithic founder crops, emmer and einkorn wheat, hulled barley, peas, lentils, bitter vetch, chick peas and flax were cultivated in the Levant. Cattle were domesticated from the aurochs in the areas of modern Turkey. In the Andes of South America, the potato was domesticated between 10,000 and 7,000 years ago, along with beans, coca, llamas, alpacas, sugarcane and some root vegetables were domesticated in New Guinea around 9,000 years ago. Sorghum was domesticated in the Sahel region of Africa by 7,000 years ago, cotton was domesticated in Peru by 5,600 years ago, and was independently domesticated in Eurasia at an unknown time
8.
Fertilizer
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A fertilizer or fertiliser is any material of natural or synthetic origin that is applied to soils or to plant tissues to supply one or more plant nutrients essential to the growth of plants. Fertilizers enhance the growth of plants and this goal is met in two ways, the traditional one being additives that provide nutrients. The second mode by which some fertilizers act is to enhance the effectiveness of the soil by modifying its water retention and aeration and this article, like many on fertilizers, emphasises the nutritional aspect. The nutrients required for plant life are classified according to the elements. Instead compounds containing these elements are the basis of fertilizers, the macronutrients are consumed in larger quantities and are present in plant tissue in quantities from 0. 15% to 6. 0% on a dry matter basis. Plants are made up of four elements, hydrogen, oxygen, carbon. Carbon, hydrogen and oxygen are widely available as water and carbon dioxide, although nitrogen makes up most of the atmosphere, it is in a form that is unavailable to plants. Nitrogen is the most important fertilizer since nitrogen is present in proteins, DNA, to be nutritious to plants, nitrogen must be made available in a fixed form. Only some bacteria and their host plants can fix atmospheric nitrogen by converting it to ammonia, phosphate is required for the production of DNA and ATP, the main energy carrier in cells, as well as certain lipids. Micronutrients are consumed in quantities and are present in plant tissue on the order of parts-per-million, ranging from 0.15 to 400 ppm DM. These elements are present at the active sites of enzymes that carry out the plants metabolism. Because these elements enable catalysts their impact far exceeds their weight percentage, Fertilizers are classified in several ways. They are classified according to whether they provide a single nutrient, multinutrient fertilizers provide two or more nutrients, for example N and P. Fertilizers are also sometimes classified as inorganic versus organic. Inorganic fertilizers exclude carbon-containing materials except ureas, organic fertilizers are usually plant- or animal-derived matter. Inorganic are sometimes called synthetic fertilizers since various chemical treatments are required for their manufacture, the main nitrogen-based straight fertilizer is ammonia or its solutions. Ammonium nitrate is widely used. Urea is another source of nitrogen, having the advantage that it is solid and non-explosive, unlike ammonia and ammonium nitrate. A few percent of the fertilizer market has been met by calcium ammonium nitrate
9.
Jmol
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Jmol is computer software for molecular modelling chemical structures in 3-dimensions. Jmol returns a 3D representation of a molecule that may be used as a teaching tool and it is written in the programming language Java, so it can run on the operating systems Windows, macOS, Linux, and Unix, if Java is installed. It is free and open-source software released under a GNU Lesser General Public License version 2.0, a standalone application and a software development kit exist that can be integrated into other Java applications, such as Bioclipse and Taverna. A popular feature is an applet that can be integrated into web pages to display molecules in a variety of ways, for example, molecules can be displayed as ball-and-stick models, space-filling models, ribbon diagrams, etc. Jmol supports a range of chemical file formats, including Protein Data Bank, Crystallographic Information File, MDL Molfile. There is also a JavaScript-only version, JSmol, that can be used on computers with no Java, the Jmol applet, among other abilities, offers an alternative to the Chime plug-in, which is no longer under active development. While Jmol has many features that Chime lacks, it does not claim to reproduce all Chime functions, most notably, Chime requires plug-in installation and Internet Explorer 6.0 or Firefox 2.0 on Microsoft Windows, or Netscape Communicator 4.8 on Mac OS9. Jmol requires Java installation and operates on a variety of platforms. For example, Jmol is fully functional in Mozilla Firefox, Internet Explorer, Opera, Google Chrome, fast and Scriptable Molecular Graphics in Web Browsers without Java3D
10.
Sodium nitrate
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Sodium nitrate is the chemical compound with the formula NaNO3. This alkali metal salt is also known as Peru saltpeter to distinguish it from ordinary saltpeter. The mineral form is known as nitratine, nitratite or soda niter. Sodium nitrate is a solid very soluble in water. It has been mined extensively for these purposes, with time, however, the mining of South American saltpeter became a profitable business. Chile fought against the allies Peru and Bolivia in the War of the Pacific 1879-1884, in 1919, Ralph Walter Graystone Wyckoff determined its crystal structure using X-ray crystallography. The largest accumulations of naturally occurring sodium nitrate are found in Chile and Peru, by the 1940s, this conversion process resulted in a dramatic decline in demand for sodium nitrate procured from natural sources. Chile still has the largest reserves of caliche, with mines in such locations as Pedro de Valdivia, María Elena and Pampa Blanca. Sodium nitrate, potassium nitrate, sodium sulfate and iodine are all obtained by the processing of caliche, the former Chilean saltpeter mining communities of Humberstone and Santa Laura were declared Unesco World Heritage sites in 2005. It can be combined with iron hydroxide to make a synthetic resin, sodium nitrate can be combined with sulfuric acid and nitric acid distilled off. At lower pressure the temperature needed results in less decomposition. The theoretical 2 moles of nitric acid per 1 mole of sulfuric acid results in a high end temperature, much decomposition. When this reaction was important industrially, it was practice to operate with sulfuric acid in excess to end on a mostly bisulfate product poured molten out of the retort. Hobbyist gold refiners use sodium nitrate to make a hybrid aqua regia that dissolves gold, sodium nitrate is also a food additive used as a preservative and color fixative in cured meats and poultry, it is listed under its INS number 251 or E number E251. It is approved for use in the EU, USA and Australia, sodium nitrate should not be confused with sodium nitrite, which is also a common food additive and preservative used, for example, in deli meats. Less common applications include as an oxidizer in fireworks, replacing potassium nitrate commonly found in black powder, sodium nitrate is used together with potassium nitrate and calcium nitrate for heat storage and, more recently, for heat transfer in solar power plants. A mixture of sodium nitrate, calcium nitrate and potassium nitrate is used as material in prototype plants, such as Andasol Solar Power Station. It is also used in the industry for facultative microorganism respiration
11.
European Chemicals Agency
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ECHA is the driving force among regulatory authorities in implementing the EUs chemicals legislation. ECHA helps companies to comply with the legislation, advances the safe use of chemicals, provides information on chemicals and it is located in Helsinki, Finland. The Agency, headed by Executive Director Geert Dancet, started working on 1 June 2007, the REACH Regulation requires companies to provide information on the hazards, risks and safe use of chemical substances that they manufacture or import. Companies register this information with ECHA and it is freely available on their website. So far, thousands of the most hazardous and the most commonly used substances have been registered, the information is technical but gives detail on the impact of each chemical on people and the environment. This also gives European consumers the right to ask whether the goods they buy contain dangerous substances. The Classification, Labelling and Packaging Regulation introduces a globally harmonised system for classifying and labelling chemicals into the EU. This worldwide system makes it easier for workers and consumers to know the effects of chemicals, companies need to notify ECHA of the classification and labelling of their chemicals. So far, ECHA has received over 5 million notifications for more than 100000 substances, the information is freely available on their website. Consumers can check chemicals in the products they use, Biocidal products include, for example, insect repellents and disinfectants used in hospitals. The Biocidal Products Regulation ensures that there is information about these products so that consumers can use them safely. ECHA is responsible for implementing the regulation, the law on Prior Informed Consent sets guidelines for the export and import of hazardous chemicals. Through this mechanism, countries due to hazardous chemicals are informed in advance and have the possibility of rejecting their import. Substances that may have effects on human health and the environment are identified as Substances of Very High Concern 1. These are mainly substances which cause cancer, mutation or are toxic to reproduction as well as substances which persist in the body or the environment, other substances considered as SVHCs include, for example, endocrine disrupting chemicals. Companies manufacturing or importing articles containing these substances in a concentration above 0 and they are required to inform users about the presence of the substance and therefore how to use it safely. Consumers have the right to ask the retailer whether these substances are present in the products they buy, once a substance has been officially identified in the EU as being of very high concern, it will be added to a list. This list is available on ECHA’s website and shows consumers and industry which chemicals are identified as SVHCs, Substances placed on the Candidate List can then move to another list
12.
Ammonium nitrite
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Ammonium nitrite, NH4NO2, is the ammonia salt of nitrous acid. It is not used in isolated form, since it is highly unstable and decomposes into water. Ammonium nitrite forms naturally in the air and can be prepared by the absorption of equal parts nitrogen dioxide, the precipitate is filtered off and the solution concentrated. It forms colorless crystals which are soluble in water, but decomposes when heated or in the presence of acid into water, Ammonium nitrite solution is stable at higher pH and lower temperature. If there is any decrease in pH lower than 7.0, a safe pH can be maintained by adding an ammonia solution. The mole ratio of ammonium nitrite to ammonia must be above 10%, NH4NO2 → N2 +2 H2O Ammonium nitrite may explode at a temperature of 60–70 °C, and will decompose quicker when dissolved in a concentrated aqueous solution, than in the form of a dry crystal
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