1.
Aegirine
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Aegirine is a member of the clinopyroxene group of inosilicates. Aegirine is the sodium endmember of the aegirine-augite series, aegirine has the chemical formula NaFeSi2O6 in which the iron is present as Fe3+. In the aegirine-augite series the sodium is replaced by calcium with iron. Aluminium also substitutes for the iron and it is also known as acmite, which is a fibrous, green-colored variety. Aegirine occurs as dark green prismatic crystals. It has a glassy luster and perfect cleavage, the Mohs hardness varies from 5 to 6 and the specific gravity is 3.2 to 3.4. Commonly occurs in igneous rocks, nepheline syenites, carbonatites and pegmatites. Also in regionally metamorphosed schists, gneisses, and iron formations, in blueschist facies rocks and it may occur as an authigenic mineral in shales and marls. It occurs in association with potassic feldspar, nepheline, riebeckite, arfvedsonite, aenigmatite, astrophyllite, catapleiite, eudialyte, serandite and apophyllite. Localities include Mont Saint-Hilaire, Quebec, Canada, Kongsberg, Norway, Narsarssuk, Greenland, Kola Peninsula, Russia, Magnet Cove, Arkansas, US, Kenya, Scotland and it was first described in 1835 for an occurrence in Rundemyr, Øvre Eiker, Buskerud, Norway. Aegirine was named after Ægir, the Teutonic god of the sea, a synonym for the mineral is acmite in reference to the typical pointed crystals. It is sometimes used as a gemstone
2.
Natrolite
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Natrolite is a tectosilicate mineral species belonging to the zeolite group. It is a hydrated sodium and aluminium silicate with the formula Na2Al2Si3O10 · 2H2O, the type locality is Hohentwiel, Hegau, Germany. It was named natrolite by Martin Heinrich Klaproth in 1803, the name is derived from νατρών natron, the Greek word for soda, in reference to the sodium content and λίθος lithos, meaning stone. Needle stone or needle-zeolite are other names, alluding to the common acicular habit of the crystals. The crystals are frequently epitaxial overgrowths of natrolite, mesolite, larger crystals most commonly have the form of a square prism terminated by a low pyramid, the prism angle being nearly a right angle. The crystals are tetragonal in appearance, though actually orthorhombic, there are perfect cleavages parallel to the faces of the prism. The mineral also occurs in compact fibrous aggregates, the fibers having a divergent or radial arrangement. Natrolite is readily distinguished from other fibrous zeolites by its optical characteristics, between crossed nicols the fibers extinguish parallel to their length, and they do not show an optic figure in convergent polarized light. Natrolite is usually white or colorless, but sometimes reddish or yellowish, the luster is vitreous, or, in finely fibrous specimens, silky. The specific gravity is 2.2, and the hardness is 5.5, the mineral is readily fusible, melting in a candle-flame to which it imparts a yellow color owing to the presence of sodium. It is decomposed by hydrochloric acid with separation of gelatinous silica, natrolite occurs with other zeolites in the amygdaloidal cavities of basaltic igneous rocks. It is also common in nepheline syenites, excellent specimens of diverging groups of white prismatic crystals are found in compact basalt at the Puy-deMarman, Puy-de-Dôme, France. Huge crystals have found on the Kola Peninsula, Russia. Mont St. Hilaire, Quebec has produced large crystals associated with many rare minerals, the Bay of Fundy in Nova Scotia, New Jersey, Oregon, and British Columbia have also produced excellent specimens. Several varieties of natrolite have been distinguished by special names, fargite is a red natrolite from Glenfarg in Perthshire. Bergmannite, or Spreustein, is a variety which has resulted by the alteration of other minerals, chiefly sodalite. Structure type NAT Mineral Galleries Mindat Webmineral This article incorporates text from a now in the public domain, Chisholm, Hugh
3.
Quebec
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Quebec is the second-most populous province of Canada and the only one to have a predominantly French-speaking population, with French as the sole provincial official language. Quebec is Canadas largest province by area and its second-largest administrative division and it also shares maritime borders with Nunavut, Prince Edward Island, and Nova Scotia. Quebec is Canadas second-most populous province, after Ontario, most inhabitants live in urban areas near the Saint Lawrence River between Montreal and Quebec City, the capital. Approximately half of Quebec residents live in the Greater Montreal Area, the Nord-du-Québec region, occupying the northern half of the province, is sparsely populated and inhabited primarily by Aboriginal peoples. Even in central Quebec at comparatively southerly latitudes winters are severe in inland areas, Quebec independence debates have played a large role in the politics of the province. Parti Québécois governments held referendums on sovereignty in 1980 and 1995, in 2006, the House of Commons of Canada passed a symbolic motion recognizing the Québécois as a nation within a united Canada. These many industries have all contributed to helping Quebec become an economically influential province within Canada, early variations in the spelling of the name included Québecq and Kébec. French explorer Samuel de Champlain chose the name Québec in 1608 for the colonial outpost he would use as the seat for the French colony of New France. The province is sometimes referred to as La belle province, the Province of Quebec was founded in the Royal Proclamation of 1763 after the Treaty of Paris formally transferred the French colony of Canada to Britain after the Seven Years War. The proclamation restricted the province to an area along the banks of the Saint Lawrence River, the Treaty of Versailles ceded territories south of the Great Lakes to the United States. After the Constitutional Act of 1791, the territory was divided between Lower Canada and Upper Canada, with each being granted an elected legislative assembly, in 1840, these become Canada East and Canada West after the British Parliament unified Upper and Lower Canada into the Province of Canada. This territory was redivided into the Provinces of Quebec and Ontario at Confederation in 1867, each became one of the first four provinces. In 1898, the Canadian Parliament passed the first Quebec Boundary Extension Act that expanded the provincial boundaries northward to include the lands of the aboriginal peoples. This was followed by the addition of the District of Ungava through the Quebec Boundaries Extension Act of 1912 that added the northernmost lands of the Inuit to create the modern Province of Quebec. In 1927, the border between Quebec and Newfoundland and Labrador was established by the British Judicial Committee of the Privy Council. Located in the part of Canada, and part of Central Canada. Its topography is very different from one region to another due to the composition of the ground, the climate. The Saint Lawrence Lowland and the Canadian Shield are the two main regions, and are radically different
4.
Zeolite
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Zeolites are microporous, aluminosilicate minerals commonly used as commercial adsorbents and catalysts. Based on this, he called the material zeolite, from the Greek ζέω, meaning to boil and λίθος, the classic reference for the field has been Zeolite molecular sieves, structure, chemistry, and use by Donald W. Breck. Zeolites occur naturally but are produced industrially on a large scale. As of September 2016,232 unique zeolite frameworks have been identified, every new zeolite structure that is obtained has to be approved by the International Zeolite Association Structure Commission and receives a three letter designation. Zeolites have a structure that can accommodate a wide variety of cations, such as Na+, K+, Ca2+, Mg2+. These positive ions are rather loosely held and can readily be exchanged for others in a contact solution, some of the more common mineral zeolites are analcime, chabazite, clinoptilolite, heulandite, natrolite, phillipsite, and stilbite. An example of the formula of a zeolite is, Na2Al2Si3O10·2H2O. Natural zeolites form where volcanic rocks and ash layers react with alkaline groundwater, Zeolites also crystallize in post-depositional environments over periods ranging from thousands to millions of years in shallow marine basins. Naturally occurring zeolites are rarely pure and are contaminated to varying degrees by other minerals, metals, quartz, for this reason, naturally occurring zeolites are excluded from many important commercial applications where uniformity and purity are essential. Zeolites are the members of the family of microporous solids known as molecular sieves mainly consisting of Si, Al, O, and metals including Ti, Sn, Zn. The term molecular sieve refers to a property of these materials. This is due to a very regular structure of molecular dimensions. The maximum size of the molecular or ionic species that can enter the pores of a zeolite is controlled by the dimensions of the channels, therefore, the pores in many zeolites are not cylindrical. Zeolites transform to other minerals under weathering, hydrothermal alteration or metamorphic conditions, the sequence of silica-poor volcanic rocks commonly progresses from, Cowlesite → levyne–offretite → analcime → thomsonite–mesolite-scolecite → chabazite → calcite. Industrially important zeolites are produced synthetically, typical procedures entail heating aqueous solutions of alumina and silica with sodium hydroxide. Equivalent reagents include sodium aluminate and sodium silicate, further variations include changes in the cations to include quaternary ammonium cations. Synthetic zeolites hold some key advantages over their natural analogues, the synthetic materials are manufactured in a uniform, phase-pure state. It is also possible to produce zeolite structures that do not appear in nature, Zeolite A is a well-known example
5.
Chemical formula
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These are limited to a single typographic line of symbols, which may include subscripts and superscripts. A chemical formula is not a name, and it contains no words. Although a chemical formula may imply certain simple chemical structures, it is not the same as a full chemical structural formula. Chemical formulas can fully specify the structure of only the simplest of molecules and chemical substances, the simplest types of chemical formulas are called empirical formulas, which use letters and numbers indicating the numerical proportions of atoms of each type. Molecular formulas indicate the numbers of each type of atom in a molecule. For example, the formula for glucose is CH2O, while its molecular formula is C6H12O6. This is possible if the relevant bonding is easy to show in one dimension, an example is the condensed molecular/chemical formula for ethanol, which is CH3-CH2-OH or CH3CH2OH. For reasons of structural complexity, there is no condensed chemical formula that specifies glucose, chemical formulas may be used in chemical equations to describe chemical reactions and other chemical transformations, such as the dissolving of ionic compounds into solution. A chemical formula identifies each constituent element by its chemical symbol, in empirical formulas, these proportions begin with a key element and then assign numbers of atoms of the other elements in the compound, as ratios to the key element. For molecular compounds, these numbers can all be expressed as whole numbers. For example, the formula of ethanol may be written C2H6O because the molecules of ethanol all contain two carbon atoms, six hydrogen atoms, and one oxygen atom. Some types of compounds, however, cannot be written with entirely whole-number empirical formulas. An example is boron carbide, whose formula of CBn is a variable non-whole number ratio with n ranging from over 4 to more than 6.5. When the chemical compound of the consists of simple molecules. These types of formulas are known as molecular formulas and condensed formulas. A molecular formula enumerates the number of atoms to reflect those in the molecule, so that the formula for glucose is C6H12O6 rather than the glucose empirical formula. However, except for very simple substances, molecular chemical formulas lack needed structural information, for simple molecules, a condensed formula is a type of chemical formula that may fully imply a correct structural formula. For example, ethanol may be represented by the chemical formula CH3CH2OH
6.
Crystal system
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In crystallography, the terms crystal system, crystal family and lattice system each refer to one of several classes of space groups, lattices, point groups or crystals. Informally, two crystals are in the crystal system if they have similar symmetries, though there are many exceptions to this. Space groups and crystals are divided into seven crystal systems according to their point groups, five of the crystal systems are essentially the same as five of the lattice systems, but the hexagonal and trigonal crystal systems differ from the hexagonal and rhombohedral lattice systems. The six crystal families are formed by combining the hexagonal and trigonal crystal systems into one hexagonal family, a lattice system is a class of lattices with the same set of lattice point groups, which are subgroups of the arithmetic crystal classes. The 14 Bravais lattices are grouped into seven lattice systems, triclinic, monoclinic, orthorhombic, tetragonal, rhombohedral, hexagonal, in a crystal system, a set of point groups and their corresponding space groups are assigned to a lattice system. Of the 32 point groups that exist in three dimensions, most are assigned to only one system, in which case both the crystal and lattice systems have the same name. However, five point groups are assigned to two systems, rhombohedral and hexagonal, because both exhibit threefold rotational symmetry. These point groups are assigned to the crystal system. In total there are seven crystal systems, triclinic, monoclinic, orthorhombic, tetragonal, trigonal, hexagonal, a crystal family is determined by lattices and point groups. It is formed by combining crystal systems which have space groups assigned to a lattice system. In three dimensions, the families and systems are identical, except the hexagonal and trigonal crystal systems. In total there are six families, triclinic, monoclinic, orthorhombic, tetragonal, hexagonal. Spaces with less than three dimensions have the number of crystal systems, crystal families and lattice systems. In one-dimensional space, there is one crystal system, in 2D space, there are four crystal systems, oblique, rectangular, square and hexagonal. The relation between three-dimensional crystal families, crystal systems and lattice systems is shown in the table, Note. To avoid confusion of terminology, the term trigonal lattice is not used, if the original structure and inverted structure are identical, then the structure is centrosymmetric. Still, even for non-centrosymmetric case, inverted structure in some cases can be rotated to align with the original structure and this is the case of non-centrosymmetric achiral structure. If the inverted structure cannot be rotated to align with the structure, then the structure is chiral
7.
Orthorhombic crystal system
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In crystallography, the orthorhombic crystal system is one of the 7 crystal systems. All three bases intersect at 90° angles, so the three lattice vectors remain mutually orthogonal, there are two orthorhombic Bravais lattices in two dimensions, Primitive rectangular and centered rectangular. The primitive rectangular lattice can also be described by a centered rhombic unit cell, there are four orthorhombic Bravais lattices, primitive orthorhombic, base-centered orthorhombic, body-centered orthorhombic, and face-centered orthorhombic. In this axis setting, the primitive and base-centered lattices interchange in centering type, crystal structure Overview of all space groups Hurlbut, Cornelius S. Klein, Cornelis. Hahn, Theo, ed. International Tables for Crystallography, Volume A, Space Group Symmetry
8.
Crystallographic point group
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For a periodic crystal, the group must also be consistent with maintenance of the three-dimensional translational symmetry that defines crystallinity. The macroscopic properties of a crystal would look exactly the same before, in the classification of crystals, each point group is also known as a crystal class. There are infinitely many three-dimensional point groups, however, the crystallographic restriction of the infinite families of general point groups results in there being only 32 crystallographic point groups. These 32 point groups are one-and-the same as the 32 types of morphological crystalline symmetries derived in 1830 by Johann Friedrich Christian Hessel from a consideration of observed crystal forms, the point groups are denoted by their component symmetries. There are a few standard notations used by crystallographers, mineralogists, for the correspondence of the two systems below, see crystal system. In Schoenflies notation, point groups are denoted by a symbol with a subscript. The symbols used in crystallography mean the following, Cn indicates that the group has a rotation axis. Cnh is Cn with the addition of a plane perpendicular to the axis of rotation. Cnv is Cn with the addition of n mirror planes parallel to the axis of rotation, s2n denotes a group that contains only a 2n-fold rotation-reflection axis. Dn indicates that the group has a rotation axis plus n twofold axes perpendicular to that axis. Dnh has, in addition, a plane perpendicular to the n-fold axis. Dnd has, in addition to the elements of Dn, mirror planes parallel to the n-fold axis, the letter T indicates that the group has the symmetry of a tetrahedron. Td includes improper rotation operations, T excludes improper rotation operations, the letter O indicates that the group has the symmetry of an octahedron, with or without improper operations. Due to the crystallographic restriction theorem, n =1,2,3,4, d4d and D6d are actually forbidden because they contain improper rotations with n=8 and 12 respectively. The 27 point groups in the table plus T, Td, Th, O, an abbreviated form of the Hermann–Mauguin notation commonly used for space groups also serves to describe crystallographic point groups. Group names are Molecular symmetry Point group Space group Point groups in three dimensions Crystal system Point-group symbols in International Tables for Crystallography,12.1, pp. 818-820 Names and symbols of the 32 crystal classes in International Tables for Crystallography. 10.1, p.794 Pictorial overview of the 32 groups Point Groups - Flow Chart Inorganic Chemistry Group Theory Practice Problems
9.
H-M symbol
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In geometry, Hermann–Mauguin notation is used to represent the symmetry elements in point groups, plane groups and space groups. It is named after the German crystallographer Carl Hermann and the French mineralogist Charles-Victor Mauguin and this notation is sometimes called international notation, because it was adopted as standard by the International Tables For Crystallography since their first edition in 1935. Rotation axes are denoted by a number n —1,2,3,4,5,6,7,8, for improper rotations, Hermann–Mauguin symbols show rotoinversion axes, unlike Schoenflies and Shubnikov notations, where the preference is given to rotation-reflection axes. The rotoinversion axes are represented by the number with a macron. The symbol for a plane is m. The direction of the plane is defined as the direction of perpendicular to the face. Hermann–Mauguin symbols show symmetrically non-equivalent axes and planes, the direction of a symmetry element is represented by its position in the Hermann–Mauguin symbol. If a rotation axis n and a mirror plane m have the same direction, if two or more axes have the same direction, the axis with higher symmetry is shown. Higher symmetry means that the axis generates a pattern with more points, for example, rotation axes 3,4,5,6,7,8 generate 3-, 4-, 5-, 6-, 7-, 8-point patterns, respectively. Improper rotation axes 3,4,5,6,7,8 generate 6-, 4-, 10-, 6-, 14-, 8-point patterns, if both, the rotation and rotoinversion axes satisfy the previous rule, the rotation axis should be chosen. For example, 3/m combination is equivalent to 6, since 6 generates 6 points, and 3 generates only 3,6 should be written instead of 3/m. Analogously, in the case when both 3 and 3 axes are present,3 should be written, however we write 4/m, not 4/m, because both 4 and 4 generate four points. Finally, the Hermann–Mauguin symbol depends on the type of the group and these groups may contain only two-fold axes, mirror planes, and inversion center. These are the point groups 1 and 1,2, m, and 2/m, and 222, 2/m2/m2/m. If the symbol contains three positions, then they denote symmetry elements in the x, y, z direction, First position — primary direction — z direction, assigned to the higher-order axis. Second position — symmetrically equivalent secondary directions, which are perpendicular to the z-axis and these can be 2, m, or 2/m. Third position — symmetrically equivalent tertiary directions, passing between secondary directions and these can be 2, m, or 2/m. These are the crystallographic groups 3,32, 3m,3, and 32/m,4,422, 4mm,4, 42m, 4/m, and 4/m2/m2/m, and 6,622, 6mm,6, 6m2, 6/m, and 6/m2/m2/m
10.
Space group
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In mathematics, physics and chemistry, a space group is the symmetry group of a configuration in space, usually in three dimensions. In three dimensions, there are 219 distinct types, or 230 if chiral copies are considered distinct, Space groups are also studied in dimensions other than 3 where they are sometimes called Bieberbach groups, and are discrete cocompact groups of isometries of an oriented Euclidean space. In crystallography, space groups are called the crystallographic or Fedorov groups. A definitive source regarding 3-dimensional space groups is the International Tables for Crystallography, in 1879 Leonhard Sohncke listed the 65 space groups whose elements preserve the orientation. More accurately, he listed 66 groups, but Fedorov and Schönflies both noticed that two of them were really the same, the space groups in 3 dimensions were first enumerated by Fedorov, and shortly afterwards were independently enumerated by Schönflies. The correct list of 230 space groups was found by 1892 during correspondence between Fedorov and Schönflies, burckhardt describes the history of the discovery of the space groups in detail. The space groups in three dimensions are made from combinations of the 32 crystallographic point groups with the 14 Bravais lattices, the combination of all these symmetry operations results in a total of 230 different space groups describing all possible crystal symmetries. The elements of the space group fixing a point of space are rotations, reflections, the identity element, the translations form a normal abelian subgroup of rank 3, called the Bravais lattice. There are 14 possible types of Bravais lattice, the quotient of the space group by the Bravais lattice is a finite group which is one of the 32 possible point groups. Translation is defined as the moves from one point to another point. A glide plane is a reflection in a plane, followed by a parallel with that plane. This is noted by a, b or c, depending on which axis the glide is along. There is also the n glide, which is a glide along the half of a diagonal of a face, and the d glide, the latter is called the diamond glide plane as it features in the diamond structure. In 17 space groups, due to the centering of the cell, the glides occur in two directions simultaneously, i. e. the same glide plane can be called b or c, a or b. For example, group Abm2 could be also called Acm2, group Ccca could be called Cccb, in 1992, it was suggested to use symbol e for such planes. The symbols for five groups have been modified, A screw axis is a rotation about an axis. These are noted by a number, n, to describe the degree of rotation, the degree of translation is then added as a subscript showing how far along the axis the translation is, as a portion of the parallel lattice vector. So,21 is a rotation followed by a translation of 1/2 of the lattice vector
11.
Crystal habit
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In mineralogy, crystal habit is the characteristic external shape of an individual crystal or crystal group. A single crystals habit is a description of its shape and its crystallographic forms. Recognizing the habit may help in identifying a mineral, when the faces are well-developed due to uncrowded growth a crystal is called euhedral, one with partially developed faces is subhedral, and one with undeveloped crystal faces is called anhedral. The long axis of a quartz crystal typically has a six-sided prismatic habit with parallel opposite faces. Aggregates can be formed of individual crystals with euhedral to anhedral grains, the arrangement of crystals within the aggregate can be characteristic of certain minerals. For example, minerals used for asbestos insulation often grow in a fibrous habit, the terms used by mineralogists to report crystal habits describe the typical appearance of an ideal mineral. Recognizing the habit can aid in identification as some habits are characteristic, most minerals, however, do not display ideal habits due to conditions during crystallization. Minerals belonging to the crystal system do not necessarily exhibit the same habit. Some habits of a mineral are unique to its variety and locality, For example, while most sapphires form elongate barrel-shaped crystals, ordinarily, the latter habit is seen only in ruby. Sapphire and ruby are both varieties of the mineral, corundum. Some minerals may replace other existing minerals while preserving the originals habit, a classic example is tigers eye quartz, crocidolite asbestos replaced by silica. While quartz typically forms prismatic crystals, in tigers eye the original fibrous habit of crocidolite is preserved, the names of crystal habits are derived from, Predominant crystal faces. Abnormal grain growth Grain growth Crystallization
12.
Crystal twinning
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Crystal twinning occurs when two separate crystals share some of the same crystal lattice points in a symmetrical manner. The result is an intergrowth of two separate crystals in a variety of specific configurations, a twin boundary or composition surface separates the two crystals. Crystallographers classify twinned crystals by a number of twin laws and these twin laws are specific to the crystal system. The type of twinning can be a tool in mineral identification. Twinning can often be a problem in X-ray crystallography, as a crystal does not produce a simple diffraction pattern. Simple twinned crystals may be contact twins or penetration twins, contact twins share a single composition surface often appearing as mirror images across the boundary. Plagioclase, quartz, gypsum, and spinel often exhibit contact twinning, merohedral twinning occurs when the lattices of the contact twins superimpose in three dimensions, such as by relative rotation of one twin from the other. In penetration twins the individual crystals have the appearance of passing through each other in a symmetrical manner, orthoclase, staurolite, pyrite, and fluorite often show penetration twinning. If several twin crystal parts are aligned by the same twin law they are referred to as multiple or repeated twins, if these multiple twins are aligned in parallel they are called polysynthetic twins. When the multiple twins are not parallel they are cyclic twins, albite, calcite, and pyrite often show polysynthetic twinning. Closely spaced polysynthetic twinning is often observed as striations or fine lines on the crystal face. Rutile, aragonite, cerussite, and chrysoberyl often exhibit cyclic twinning, 2-normal twin, -when the twin plane and compositional plane lies noramally. 3-complex twin, -combination of parallel twinning and normal twinning on one compositional plane, there are three modes of formation of twinned crystals. Growth twins are the result of an interruption or change in the lattice during formation or growth due to a possible deformation from a larger substituting ion, deformation or gliding twins are the result of stress on the crystal after the crystal has formed. If a FCC metal like aluminum experiences extreme stresses, it will experience twinning as seen in the case of explosions, deformation twinning is a common result of regional metamorphism. Crystals that grow adjacent to each other may be aligned to resemble twinning and this parallel growth simply reduces system energy and is not twinning. Twin boundaries occur when two crystals of the same type intergrow, so only a slight misorientation exists between them. It is a highly symmetrical interface, often with one crystal the mirror image of the other, also and this is also a much lower-energy interface than the grain boundaries that form when crystals of arbitrary orientation grow together
13.
Cleavage (crystal)
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Cleavage, in mineralogy, is the tendency of crystalline materials to split along definite crystallographic structural planes. Cleavage forms parallel to planes, Basal or pinacoidal cleavage occurs when there is only one cleavage plane. Mica also has basal cleavage, this is why mica can be peeled into thin sheets, cubic cleavage occurs on when there are three cleavage planes intersecting at 90 degrees. Halite has cubic cleavage, and therefore, when halite crystals are broken, octahedral cleavage occurs when there are four cleavage planes in a crystal. Octahedral cleavage is common for semiconductors, rhombohedral cleavage occurs when there are three cleavage planes intersecting at angles that are not 90 degrees. Prismatic cleavage occurs when there are two planes in a crystal. Dodecahedral cleavage occurs when there are six cleavage planes in a crystal, crystal parting occurs when minerals break along planes of structural weakness due to external stress or along twin composition planes. Parting breaks are very similar in appearance to cleavage, but only due to stress. Examples include magnetite which shows octahedral parting, the parting of corundum. Cleavage is a property traditionally used in mineral identification, both in hand specimen and microscopic examination of rock and mineral studies. As an example, the angles between the cleavage planes for the pyroxenes and the amphiboles are diagnostic. Crystal cleavage is of importance in the electronics industry and in the cutting of gemstones. Precious stones are generally cleaved by impact, as in diamond cutting, synthetic single crystals of semiconductor materials are generally sold as thin wafers which are much easier to cleave. Elemental semiconductors are diamond cubic, a group for which octahedral cleavage is observed. This means that some orientations of wafer allow near-perfect rectangles to be cleaved, most other commercial semiconductors can be made in the related zinc blende structure, with similar cleavage planes. Cleavage Mineral galleries, Mineral properties – Cleavage
14.
Fracture (mineralogy)
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In the field of mineralogy, fracture is the texture and shape of a rocks surface formed when a mineral is fractured. Minerals often have a highly distinctive fracture, making it a feature used in their identification. Fracture differs from cleavage in that the latter involves clean splitting along the planes of the minerals crystal structure. All minerals exhibit fracture, but when very strong cleavage is present, conchoidal fracture breakage that resembles the concentric ripples of a mussel shell. It often occurs in amorphous or fine-grained minerals such as flint, opal or obsidian, subconchoidal fracture is similar to conchoidal fracture, but with less significant curvature. Earthy fracture is reminiscent of freshly broken soil and it is frequently seen in relatively soft, loosely bound minerals, such as limonite, kaolinite and aluminite. Hackly fracture is jagged, sharp and not even and it occurs when metals are torn, and so is often encountered in native metals such as copper and silver. Splintery fracture comprises sharp elongated points and it is particularly seen in fibrous minerals such as chrysotile, but may also occur in non-fibrous minerals such as kyanite. Uneven fracture is a surface or one with random irregularities. It occurs in a range of minerals including arsenopyrite, pyrite and magnetite. Rudolf Duda and Lubos Rejl, Minerals of the World http, //www. galleries. com/minerals/property/fracture. htm
15.
Mohs scale of mineral hardness
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The Mohs scale of mineral hardness is a qualitative ordinal scale characterizing scratch resistance of various minerals through the ability of harder material to scratch softer material. Created in 1812 by German geologist and mineralogist Friedrich Mohs, it is one of several definitions of hardness in materials science, while greatly facilitating the identification of minerals in the field, the Mohs scale does not show how well hard materials perform in an industrial setting. Despite its lack of precision, the Mohs scale is highly relevant for field geologists, the Mohs scale hardness of minerals can be commonly found in reference sheets. Reference materials may be expected to have a uniform Mohs hardness, the Mohs scale of mineral hardness is based on the ability of one natural sample of mineral to scratch another mineral visibly. The samples of matter used by Mohs are all different minerals, Minerals are pure substances found in nature. Rocks are made up of one or more minerals, as the hardest known naturally occurring substance when the scale was designed, diamonds are at the top of the scale. The hardness of a material is measured against the scale by finding the hardest material that the material can scratch. For example, if material is scratched by apatite but not by fluorite. Scratching a material for the purposes of the Mohs scale means creating non-elastic dislocations visible to the naked eye, frequently, materials that are lower on the Mohs scale can create microscopic, non-elastic dislocations on materials that have a higher Mohs number. The Mohs scale is an ordinal scale. For example, corundum is twice as hard as topaz, the table below shows the comparison with the absolute hardness measured by a sclerometer, with pictorial examples. On the Mohs scale, a streak plate has a hardness of 7.0, using these ordinary materials of known hardness can be a simple way to approximate the position of a mineral on the scale. The table below incorporates additional substances that may fall between levels, Comparison between Hardness and Hardness, Mohs hardness of elements is taken from G. V, samsonov in Handbook of the physicochemical properties of the elements, IFI-Plenum, New York, USA,1968. The Hardness of Minerals and Rocks
16.
Lustre (mineralogy)
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Lustre or luster is the way light interacts with the surface of a crystal, rock, or mineral. The word traces its origins back to the latin lux, meaning light, a range of terms are used to describe lustre, such as earthy, metallic, greasy, and silky. Similarly, the term refers to a glassy lustre. A list of terms is given below. Lustre varies over a continuum, and so there are no rigid boundaries between the different types of lustre. The terms are frequently combined to describe types of lustre. Some minerals exhibit unusual optical phenomena, such as asterism or chatoyancy, a list of such phenomena is given below. Adamantine minerals possess a superlative lustre, which is most notably seen in diamond, such minerals are transparent or translucent, and have a high refractive index. Minerals with an adamantine lustre are uncommon, with examples being cerussite. Minerals with a degree of lustre are referred to as subadamantine, with some examples being garnet. Dull minerals exhibit little to no lustre, due to coarse granulations which scatter light in all directions, a distinction is sometimes drawn between dull minerals and earthy minerals, with the latter being coarser, and having even less lustre. Greasy minerals resemble fat or grease, a greasy lustre often occurs in minerals containing a great abundance of microscopic inclusions, with examples including opal and cordierite. Many minerals with a greasy lustre also feel greasy to the touch, metallic minerals have the lustre of polished metal, and with ideal surfaces will work as a reflective surface. Examples include galena, pyrite and magnetite, pearly minerals consist of thin transparent co-planar sheets. Light reflecting from these layers give them a lustre reminiscent of pearls, such minerals possess perfect cleavage, with examples including muscovite and stilbite. Resinous minerals have the appearance of resin, chewing gum or plastic, a principal example is amber, which is a form of fossilized resin. Silky minerals have an arrangement of extremely fine fibres, giving them a lustre reminiscent of silk. Examples include asbestos, ulexite and the satin spar variety of gypsum, a fibrous lustre is similar, but has a coarser texture
17.
Streak (mineralogy)
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The streak of a mineral is the color of the powder produced when it is dragged across an un-weathered surface. If no streak seems to be made, the streak is said to be white or colorless. Streak is particularly important as a diagnostic for opaque and colored materials and it is less useful for silicate minerals, most of which have a white streak or are too hard to powder easily. The apparent color of a mineral can vary widely because of impurities or a disturbed macroscopic crystal structure. Small amounts of an impurity that strongly absorbs a particular wavelength can radically change the wavelengths of light that are reflected by the specimen, and thus change the apparent color. However, when the specimen is dragged to produce a streak, it is broken into randomly oriented microscopic crystals, the surface across which the mineral is dragged is called a streak plate, and is generally made of unglazed porcelain tile. In the absence of a plate, the unglazed underside of a porcelain bowl or vase or the back of a glazed tile will work. Sometimes a streak is more easily or accurately described by comparing it with the streak made by another streak plate. Because the trail left behind results from the mineral being crushed into powder, in case of harder minerals, the color of the powder can be determined by filing or crushing with a hammer a small sample, which is then usually rubbed on a streak plate. Most minerals that are harder have a white streak. Some minerals leave a similar to their natural color, such as cinnabar. Other minerals leave surprising colors, such as fluorite, which always has a streak, although it can appear in purple, blue, yellow. Hematite, which is black in appearance, leaves a red streak which accounts for its name, galena, which can be similar in appearance to hematite, is easily distinguished by its gray streak. Hamilton, W. R. Cambridge Guide to Minerals, Rocks, the Encyclopedia of Gemstones and Minerals. New York, Facts on File. p.251, physical Characteristics of Minerals, at Introduction to Mineralogy by Andrea Bangert What is Streak
18.
Specific gravity
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This page is about the measurement using water as a reference. For a general use of gravity, see relative density. See intensive property for the property implied by specific, Apparent specific gravity is the ratio of the weight of a volume of the substance to the weight of an equal volume of the reference substance. The reference substance is always water at its densest for liquids. Nonetheless, the temperature and pressure must be specified for both the sample and the reference, pressure is nearly always 1 atm. Temperatures for both sample and reference vary from industry to industry, in British beer brewing, the practice for specific gravity as specified above is to multiply it by 1000. Being a ratio of densities, specific gravity is a dimensionless quantity, Specific gravity varies with temperature and pressure, reference and sample must be compared at the same temperature and pressure or be corrected to a standard reference temperature and pressure. Substances with a gravity of 1 are neutrally buoyant in water. Those with SG greater than 1 are denser than water and will, disregarding surface tension effects and those with an SG less than 1 are less dense than water and will float on it. In scientific work, the relationship of mass to volume is expressed directly in terms of the density of the substance under study. It is in industry where specific gravity finds wide application, often for historical reasons. True specific gravity can be expressed mathematically as, S G true = ρ sample ρ H2 O where ρ sample is the density of the sample, the density of water varies with temperature and pressure as does the density of the sample. So it is necessary to specify the temperatures and pressures at which the densities or weights were determined and it is nearly always the case that measurements are made at 1 nominal atmosphere. For true specific gravity calculations, air pressure must be considered, temperatures are specified by the notation with T s representing the temperature at which the samples density was determined and T r the temperature at which the reference density is specified. For example, SG would be understood to mean that the density of the sample was determined at 20°C and of the water at 4°C. Taking into account different sample and reference temperatures, we note that, while S G H2 O =1.000000, it is also the case that S G H2 O =0.998203 /0.999840 =0.998363. Here, temperature is being specified using the current ITS-90 scale, on the previous IPTS-68 scale, the densities at 20 °C and 4 °C are 0.9982071 and 0.9999720 respectively, resulting in an SG value for water of 0.9982343. For example, in the industry, the Plato table lists sucrose concentration by weight against true SG
19.
Refractive index
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In optics, the refractive index or index of refraction n of a material is a dimensionless number that describes how light propagates through that medium. It is defined as n = c v, where c is the speed of light in vacuum, for example, the refractive index of water is 1.333, meaning that light travels 1.333 times faster in a vacuum than it does in water. The refractive index determines how light is bent, or refracted. The refractive indices also determine the amount of light that is reflected when reaching the interface, as well as the angle for total internal reflection. This implies that vacuum has a index of 1. The refractive index varies with the wavelength of light and this is called dispersion and causes the splitting of white light into its constituent colors in prisms and rainbows, and chromatic aberration in lenses. Light propagation in absorbing materials can be described using a refractive index. The imaginary part then handles the attenuation, while the real part accounts for refraction, the concept of refractive index is widely used within the full electromagnetic spectrum, from X-rays to radio waves. It can also be used with wave phenomena such as sound, in this case the speed of sound is used instead of that of light and a reference medium other than vacuum must be chosen. Thomas Young was presumably the person who first used, and invented, at the same time he changed this value of refractive power into a single number, instead of the traditional ratio of two numbers. The ratio had the disadvantage of different appearances, newton, who called it the proportion of the sines of incidence and refraction, wrote it as a ratio of two numbers, like 529 to 396. Hauksbee, who called it the ratio of refraction, wrote it as a ratio with a fixed numerator, hutton wrote it as a ratio with a fixed denominator, like 1.3358 to 1. Young did not use a symbol for the index of refraction, in the next years, others started using different symbols, n, m, and µ. For visible light most transparent media have refractive indices between 1 and 2, a few examples are given in the adjacent table. These values are measured at the yellow doublet D-line of sodium, with a wavelength of 589 nanometers, gases at atmospheric pressure have refractive indices close to 1 because of their low density. Almost all solids and liquids have refractive indices above 1.3, aerogel is a very low density solid that can be produced with refractive index in the range from 1.002 to 1.265. Moissanite lies at the end of the range with a refractive index as high as 2.65. Most plastics have refractive indices in the range from 1.3 to 1.7, for infrared light refractive indices can be considerably higher
20.
Greek language
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Greek is an independent branch of the Indo-European family of languages, native to Greece and other parts of the Eastern Mediterranean. It has the longest documented history of any living language, spanning 34 centuries of written records and its writing system has been the Greek alphabet for the major part of its history, other systems, such as Linear B and the Cypriot syllabary, were used previously. The alphabet arose from the Phoenician script and was in turn the basis of the Latin, Cyrillic, Armenian, Coptic, Gothic and many other writing systems. Together with the Latin texts and traditions of the Roman world, during antiquity, Greek was a widely spoken lingua franca in the Mediterranean world and many places beyond. It would eventually become the official parlance of the Byzantine Empire, the language is spoken by at least 13.2 million people today in Greece, Cyprus, Italy, Albania, Turkey, and the Greek diaspora. Greek roots are used to coin new words for other languages, Greek. Greek has been spoken in the Balkan peninsula since around the 3rd millennium BC, the earliest written evidence is a Linear B clay tablet found in Messenia that dates to between 1450 and 1350 BC, making Greek the worlds oldest recorded living language. Among the Indo-European languages, its date of earliest written attestation is matched only by the now extinct Anatolian languages, the Greek language is conventionally divided into the following periods, Proto-Greek, the unrecorded but assumed last ancestor of all known varieties of Greek. The unity of Proto-Greek would have ended as Hellenic migrants entered the Greek peninsula sometime in the Neolithic era or the Bronze Age, Mycenaean Greek, the language of the Mycenaean civilisation. It is recorded in the Linear B script on tablets dating from the 15th century BC onwards, Ancient Greek, in its various dialects, the language of the Archaic and Classical periods of the ancient Greek civilisation. It was widely known throughout the Roman Empire, after the Roman conquest of Greece, an unofficial bilingualism of Greek and Latin was established in the city of Rome and Koine Greek became a first or second language in the Roman Empire. The origin of Christianity can also be traced through Koine Greek, Medieval Greek, also known as Byzantine Greek, the continuation of Koine Greek in Byzantine Greece, up to the demise of the Byzantine Empire in the 15th century. Much of the written Greek that was used as the language of the Byzantine Empire was an eclectic middle-ground variety based on the tradition of written Koine. Modern Greek, Stemming from Medieval Greek, Modern Greek usages can be traced in the Byzantine period and it is the language used by the modern Greeks, and, apart from Standard Modern Greek, there are several dialects of it. In the modern era, the Greek language entered a state of diglossia, the historical unity and continuing identity between the various stages of the Greek language is often emphasised. Greek speakers today still tend to regard literary works of ancient Greek as part of their own rather than a foreign language and it is also often stated that the historical changes have been relatively slight compared with some other languages. According to one estimation, Homeric Greek is probably closer to demotic than 12-century Middle English is to modern spoken English, Greek is spoken by about 13 million people, mainly in Greece, Albania and Cyprus, but also worldwide by the large Greek diaspora. Greek is the language of Greece, where it is spoken by almost the entire population
21.
Silicate minerals
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Silicate minerals are rock-forming minerals made up of silicate groups. They are the largest and most important class of rock-forming minerals and they are classified based on the structure of their silicate groups, which contain different ratios of silicon and oxygen. Nesosilicates, or orthosilicates, have the orthosilicate ion, which constitute isolated 4− tetrahedra that are connected only by interstitial cations and these exist as 3-member 6− and 6-member 12− rings, where T stands for a tetrahedrally coordinated cation. Inosilicates, or chain silicates, have interlocking chains of silicate tetrahedra with either SiO3,1,3 ratio, for single chains or Si4O11,4,11 ratio, for double chains. Nickel–Strunz classification,09. D Pyroxene group Enstatite – orthoferrosilite series Enstatite – MgSiO3 Ferrosilite – FeSiO3 Pigeonite – Ca0.251, all phyllosilicate minerals are hydrated, with either water or hydroxyl groups attached. Serpentine subgroup Antigorite – Mg3Si2O54 Chrysotile – Mg3Si2O54 Lizardite – Mg3Si2O54 Clay minerals group Halloysite – Al2Si2O54 Kaolinite – Al2Si2O54 Illite – 24O10 Montmorillonite –0 and this group comprises nearly 75% of the crust of the Earth. Tectosilicates, with the exception of the group, are aluminosilicates. Nickel–Strunz classification,09. F and 09. G,04. A, an introduction to the rock-forming minerals. Wise, W. S. Zussman, J. Rock-forming minerals, P.982 pp. Hurlbut, Cornelius S. Danas Manual of Mineralogy. Mindat. org, Dana classification Webmineral, Danas New Silicate Classification Media related to Silicates at Wikimedia Commons
22.
Mineral
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A mineral is a naturally occurring chemical compound, usually of crystalline form and abiogenic in origin. A mineral has one specific chemical composition, whereas a rock can be an aggregate of different minerals or mineraloids, the study of minerals is called mineralogy. There are over 5,300 known mineral species, over 5,070 of these have been approved by the International Mineralogical Association, the silicate minerals compose over 90% of the Earths crust. The diversity and abundance of species is controlled by the Earths chemistry. Silicon and oxygen constitute approximately 75% of the Earths crust, which translates directly into the predominance of silicate minerals, minerals are distinguished by various chemical and physical properties. Differences in chemical composition and crystal structure distinguish the various species, changes in the temperature, pressure, or bulk composition of a rock mass cause changes in its minerals. Minerals can be described by their various properties, which are related to their chemical structure. Common distinguishing characteristics include crystal structure and habit, hardness, lustre, diaphaneity, colour, streak, tenacity, cleavage, fracture, parting, more specific tests for describing minerals include magnetism, taste or smell, radioactivity and reaction to acid. Minerals are classified by key chemical constituents, the two dominant systems are the Dana classification and the Strunz classification, the silicate class of minerals is subdivided into six subclasses by the degree of polymerization in the chemical structure. All silicate minerals have a unit of a 4− silica tetrahedron—that is, a silicon cation coordinated by four oxygen anions. These tetrahedra can be polymerized to give the subclasses, orthosilicates, disilicates, cyclosilicates, inosilicates, phyllosilicates, other important mineral groups include the native elements, sulfides, oxides, halides, carbonates, sulfates, and phosphates. The first criterion means that a mineral has to form by a natural process, stability at room temperature, in the simplest sense, is synonymous to the mineral being solid. More specifically, a compound has to be stable or metastable at 25 °C, modern advances have included extensive study of liquid crystals, which also extensively involve mineralogy. Minerals are chemical compounds, and as such they can be described by fixed or a variable formula, many mineral groups and species are composed of a solid solution, pure substances are not usually found because of contamination or chemical substitution. Finally, the requirement of an ordered atomic arrangement is usually synonymous with crystallinity, however, crystals are also periodic, an ordered atomic arrangement gives rise to a variety of macroscopic physical properties, such as crystal form, hardness, and cleavage. There have been recent proposals to amend the definition to consider biogenic or amorphous substances as minerals. The formal definition of an approved by the IMA in 1995, A mineral is an element or chemical compound that is normally crystalline. However, if geological processes were involved in the genesis of the compound, Mineral classification schemes and their definitions are evolving to match recent advances in mineral science
23.
Sodium
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Sodium is a chemical element with symbol Na and atomic number 11. It is a soft, silvery-white, highly reactive metal, Sodium is an alkali metal, being in group 1 of the periodic table, because it has a single electron in its outer shell that it readily donates, creating a positively charged atom—the Na+ cation. Its only stable isotope is 23Na, the free metal does not occur in nature, but must be prepared from compounds. Sodium is the sixth most abundant element in the Earths crust, Sodium was first isolated by Humphry Davy in 1807 by the electrolysis of sodium hydroxide. Among many other useful compounds, sodium hydroxide is used in soap manufacture, and sodium chloride is a de-icing agent. Sodium is an element for all animals and some plants. Sodium ions are the major cation in the fluid and as such are the major contributor to the ECF osmotic pressure. Loss of water from the ECF compartment increases the sodium concentration, isotonic loss of water and sodium from the ECF compartment decreases the size of that compartment in a condition called ECF hypovolemia. In nerve cells, the charge across the cell membrane enables transmission of the nerve impulse—an action potential—when the charge is dissipated. The melting and boiling points of sodium are lower than those of lithium but higher than those of the alkali metals potassium, rubidium. All of these high-pressure allotropes are insulators and electrides.3 nm, spin-orbit interactions involving the electron in the 3p orbital split the D line into two, at 589.0 and 589.6 nm, hyperfine structures involving both orbitals cause many more lines. Twenty isotopes of sodium are known, but only 23Na is stable, 23Na is created in the carbon-burning process in stars by fusing two carbon atoms together, this requires temperatures above 600 megakelvins and a star of at least three solar masses. Two nuclear isomers have been discovered, the one being 24mNa with a half-life of around 20.2 milliseconds. Sodium atoms have 11 electrons, one more than the stable configuration of the noble gas neon. This process requires so little energy that sodium is oxidized by giving up its 11th electron. In contrast, the ionization energy is very high, because the 10th electron is closer to the nucleus than the 11th electron. As a result, sodium usually forms ionic compounds involving the Na+ cation, the most common oxidation state for sodium is +1. It is generally less reactive than potassium and more reactive than lithium, Sodium metal is highly reducing, with the reduction of sodium ions requiring −2.71 volts, though potassium and lithium have even more negative potentials
24.
Aluminium
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Aluminium or aluminum is a chemical element in the boron group with symbol Al and atomic number 13. It is a silvery-white, soft, nonmagnetic, ductile metal, Aluminium metal is so chemically reactive that native specimens are rare and limited to extreme reducing environments. Instead, it is combined in over 270 different minerals. The chief ore of aluminium is bauxite, Aluminium is remarkable for the metals low density and its ability to resist corrosion through the phenomenon of passivation. Aluminium and its alloys are vital to the industry and important in transportation and structures, such as building facades. The oxides and sulfates are the most useful compounds of aluminium, despite its prevalence in the environment, no known form of life uses aluminium salts metabolically, but aluminium is well tolerated by plants and animals. Because of these salts abundance, the potential for a role for them is of continuing interest. Aluminium is a soft, durable, lightweight, ductile. It is nonmagnetic and does not easily ignite, a fresh film of aluminium serves as a good reflector of visible light and an excellent reflector of medium and far infrared radiation. The yield strength of aluminium is 7–11 MPa, while aluminium alloys have yield strengths ranging from 200 MPa to 600 MPa. Aluminium has about one-third the density and stiffness of steel and it is easily machined, cast, drawn and extruded. Aluminium atoms are arranged in a cubic structure. Aluminium has an energy of approximately 200 mJ/m2. Aluminium is a thermal and electrical conductor, having 59% the conductivity of copper. Aluminium is capable of superconductivity, with a critical temperature of 1.2 kelvin. Aluminium is the most common material for the fabrication of superconducting qubits, the strongest aluminium alloys are less corrosion resistant due to galvanic reactions with alloyed copper. This corrosion resistance is reduced by aqueous salts, particularly in the presence of dissimilar metals. In highly acidic solutions, aluminium reacts with water to form hydrogen, primarily because it is corroded by dissolved chlorides, such as common sodium chloride, household plumbing is never made from aluminium
25.
Silicate
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A silicate is a compound containing an anionic silicon compound. The great majority of the silicates are oxides, but hexafluorosilicate, orthosilicate is the anion SiO4−4 or its compounds. Related to orthosilicate are families of anions with the formula 2n−, important members are the cyclic and single chain silicates n and the sheet-forming silicates n. Silicates constitute the majority of Earths crust, as well as the terrestrial planets, rocky moons. Sand, Portland cement, and thousands of minerals are examples of silicates, silicate compounds, including the minerals, consist of silicate anions whose charge is balanced by various cations. Myriad silicate anions can exist, and each can form compounds with many different cations, hence this class of compounds is very large. Both minerals and synthetic materials fit in this class, in the vast majority of silicates, including silicate minerals, the Si occupies a tetrahedral environment, being surrounded by 4 oxygen centres. In these structures, the bonds to silicon conform to the octet rule. These tetrahedra sometimes occur as isolated SiO4−4 centres, but most commonly, commonly the silicate anions are chains, double chains, sheets, and three-dimensional frameworks. All these such species have negligible solubility in water at normal conditions, silicates are well characterized as solids, but are less commonly observed in solution. The anion SiO4−4 is the base of silicic acid, Si4. Instead, solutions of silicates are usually observed as mixtures of condensed, the nature of soluble silicates is relevant to understanding biomineralization and the synthesis of aluminosilicates, such as the industrially important catalysts called zeolites. Although the tetrahedron is the coordination geometry for silicon compounds. A well-known example of such a high number is hexafluorosilicate. Octahedral coordination by 6 oxygen centres is observed, at very high pressure, even SiO2 adopts this geometry in the mineral stishovite, a dense polymorph of silica found in the lower mantle of the Earth. This structure is formed by shock during meteorite impacts. In geology and astronomy, the silicate is used to denote types of rock that consist predominantly of silicate minerals. On Earth, a variety of silicate minerals occur in an even wider range of combinations as a result of the processes that form
26.
Crystal
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A crystal or crystalline solid is a solid material whose constituents are arranged in a highly ordered microscopic structure, forming a crystal lattice that extends in all directions. In addition, macroscopic single crystals are usually identifiable by their geometrical shape, the scientific study of crystals and crystal formation is known as crystallography. The process of crystal formation via mechanisms of crystal growth is called crystallization or solidification, the word crystal derives from the Ancient Greek word κρύσταλλος, meaning both ice and rock crystal, from κρύος, icy cold, frost. Examples of large crystals include snowflakes, diamonds, and table salt, most inorganic solids are not crystals but polycrystals, i. e. many microscopic crystals fused together into a single solid. Examples of polycrystals include most metals, rocks, ceramics, a third category of solids is amorphous solids, where the atoms have no periodic structure whatsoever. Examples of amorphous solids include glass, wax, and many plastics, Crystals are often used in pseudoscientific practices such as crystal therapy, and, along with gemstones, are sometimes associated with spellwork in Wiccan beliefs and related religious movements. The scientific definition of a crystal is based on the arrangement of atoms inside it. A crystal is a solid where the form a periodic arrangement. For example, when liquid water starts freezing, the change begins with small ice crystals that grow until they fuse. Most macroscopic inorganic solids are polycrystalline, including almost all metals, ceramics, ice, rocks, solids that are neither crystalline nor polycrystalline, such as glass, are called amorphous solids, also called glassy, vitreous, or noncrystalline. These have no periodic order, even microscopically, there are distinct differences between crystalline solids and amorphous solids, most notably, the process of forming a glass does not release the latent heat of fusion, but forming a crystal does. A crystal structure is characterized by its cell, a small imaginary box containing one or more atoms in a specific spatial arrangement. The unit cells are stacked in three-dimensional space to form the crystal, the symmetry of a crystal is constrained by the requirement that the unit cells stack perfectly with no gaps. There are 219 possible crystal symmetries, called space groups. These are grouped into 7 crystal systems, such as cubic crystal system or hexagonal crystal system, Crystals are commonly recognized by their shape, consisting of flat faces with sharp angles. Euhedral crystals are those with obvious, well-formed flat faces, anhedral crystals do not, usually because the crystal is one grain in a polycrystalline solid. The flat faces of a crystal are oriented in a specific way relative to the underlying atomic arrangement of the crystal. This occurs because some surface orientations are more stable than others, as a crystal grows, new atoms attach easily to the rougher and less stable parts of the surface, but less easily to the flat, stable surfaces
27.
Silicon
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Silicon is a chemical element with symbol Si and atomic number 14. A hard and brittle crystalline solid with a metallic luster. It is a member of group 14 in the table, along with carbon above it and germanium, tin, lead. It is not very reactive, although more reactive than germanium, Silicon is the eighth most common element in the universe by mass, but very rarely occurs as the pure element in the Earths crust. It is most widely distributed in dusts, sands, planetoids, over 90% of the Earths crust is composed of silicate minerals, making silicon the second most abundant element in the Earths crust after oxygen. Most silicon is used commercially without being separated, and often with little processing of the natural minerals, such use includes industrial construction with clays, silica sand, and stone. Silicate is used in Portland cement for mortar and stucco, and mixed with sand and gravel to make concrete for walkways, foundations. Silicates are used in whiteware ceramics such as porcelain, and in traditional quartz-based soda-lime glass, Silicon compounds such as silicon carbide are used as abrasives and components of high-strength ceramics. Elemental silicon also has an impact on the modern world economy. Most free silicon is used in the refining, aluminium-casting. Silicon is the basis of the widely used synthetic polymers called silicones, Silicon is an essential element in biology, although only tiny traces are required by animals. However, various sea sponges and microorganisms, such as diatoms and radiolaria, silica is deposited in many plant tissues, such as in the bark and wood of Chrysobalanaceae and the silica cells and silicified trichomes of Cannabis sativa, horsetails and many grasses. Silicon is a solid at room temperature, with a point of 1,414 °C. Like water, it has a density in a liquid state than in a solid state and it expands when it freezes. With a relatively high conductivity of 149 W·m−1·K−1, silicon conducts heat well. In its crystalline form, pure silicon has a gray color, like germanium, silicon is rather strong, very brittle, and prone to chipping. Silicon, like carbon and germanium, crystallizes in a cubic crystal structure with a lattice spacing of 0.5430710 nm. The outer electron orbital of silicon, like that of carbon, has four valence electrons, the 1s, 2s, 2p and 3s subshells are completely filled while the 3p subshell contains two electrons out of a possible six
28.
Oxygen
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Oxygen is a chemical element with symbol O and atomic number 8. It is a member of the group on the periodic table and is a highly reactive nonmetal. By mass, oxygen is the third-most abundant element in the universe, after hydrogen, at standard temperature and pressure, two atoms of the element bind to form dioxygen, a colorless and odorless diatomic gas with the formula O2. This is an important part of the atmosphere and diatomic oxygen gas constitutes 20. 8% of the Earths atmosphere, additionally, as oxides the element makes up almost half of the Earths crust. Most of the mass of living organisms is oxygen as a component of water, conversely, oxygen is continuously replenished by photosynthesis, which uses the energy of sunlight to produce oxygen from water and carbon dioxide. Oxygen is too reactive to remain a free element in air without being continuously replenished by the photosynthetic action of living organisms. Another form of oxygen, ozone, strongly absorbs ultraviolet UVB radiation, but ozone is a pollutant near the surface where it is a by-product of smog. At low earth orbit altitudes, sufficient atomic oxygen is present to cause corrosion of spacecraft, the name oxygen was coined in 1777 by Antoine Lavoisier, whose experiments with oxygen helped to discredit the then-popular phlogiston theory of combustion and corrosion. One of the first known experiments on the relationship between combustion and air was conducted by the 2nd century BCE Greek writer on mechanics, Philo of Byzantium. In his work Pneumatica, Philo observed that inverting a vessel over a burning candle, Philo incorrectly surmised that parts of the air in the vessel were converted into the classical element fire and thus were able to escape through pores in the glass. Many centuries later Leonardo da Vinci built on Philos work by observing that a portion of air is consumed during combustion and respiration, Oxygen was discovered by the Polish alchemist Sendivogius, who considered it the philosophers stone. In the late 17th century, Robert Boyle proved that air is necessary for combustion, English chemist John Mayow refined this work by showing that fire requires only a part of air that he called spiritus nitroaereus. From this he surmised that nitroaereus is consumed in both respiration and combustion, Mayow observed that antimony increased in weight when heated, and inferred that the nitroaereus must have combined with it. Accounts of these and other experiments and ideas were published in 1668 in his work Tractatus duo in the tract De respiratione. Robert Hooke, Ole Borch, Mikhail Lomonosov, and Pierre Bayen all produced oxygen in experiments in the 17th and the 18th century but none of them recognized it as a chemical element. This may have been in part due to the prevalence of the philosophy of combustion and corrosion called the phlogiston theory, which was then the favored explanation of those processes. Established in 1667 by the German alchemist J. J. Becher, one part, called phlogiston, was given off when the substance containing it was burned, while the dephlogisticated part was thought to be its true form, or calx. The fact that a substance like wood gains overall weight in burning was hidden by the buoyancy of the combustion products
29.
Potassium
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Potassium is a chemical element with symbol K and atomic number 19. It was first isolated from potash, the ashes of plants, in the periodic table, potassium is one of the alkali metals. Potassium in nature only in ionic salts. It is found dissolved in sea water, and is part of many minerals, naturally occurring potassium is composed of three isotopes, of which 40K is radioactive. Traces of 40K are found in all potassium, and it is the most common radioisotope in the human body, Potassium is chemically very similar to sodium, the previous element in Group 1 of the periodic table. They have a similar energy, which allows for each atom to give up its sole outer electron. That they are different elements combine with the same anions to make similar salts was suspected in 1702. Most industrial applications of potassium exploit the high solubility in water of potassium compounds, heavy crop production rapidly depletes the soil of potassium, and this can be remedied with agricultural fertilizers containing potassium, accounting for 95% of global potassium chemical production. Potassium ions are necessary for the function of all living cells, fresh fruits and vegetables are good dietary sources of potassium. Potassium is the second least dense metal after lithium and it is a soft solid with a low melting point, and can be easily cut with a knife. Freshly cut potassium is silvery in appearance, but it begins to tarnish toward gray immediately on exposure to air, in a flame test, potassium and its compounds emit a lilac color with a peak emission wavelength of 766.5 nanometers. Neutral potassium atoms have 19 electrons, one more than the stable configuration of the noble gas argon. This process requires so little energy that potassium is readily oxidized by atmospheric oxygen, in contrast, the second ionization energy is very high, because removal of two electrons breaks the stable noble gas electronic configuration. Potassium therefore does not readily form compounds with the state of +2 or higher. Potassium is an active metal that reacts violently with oxygen in water. With oxygen it forms potassium peroxide, and with water potassium forms potassium hydroxide, the reaction of potassium with water is dangerous because of its violent exothermic character and the production of hydrogen gas. Hydrogen reacts again with atmospheric oxygen, producing water, which reacts with the remaining potassium and this reaction requires only traces of water, because of this, potassium and the liquid sodium-potassium — NaK — are potent desiccants that can be used to dry solvents prior to distillation. Because of the sensitivity of potassium to water and air, reactions with other elements are only in an inert atmosphere such as argon gas using air-free techniques
30.
Calcium
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Calcium is a chemical element with symbol Ca and atomic number 20. Calcium is a soft grayish-yellow alkaline earth metal, fifth-most-abundant element by mass in the Earths crust, the ion Ca2+ is also the fifth-most-abundant dissolved ion in seawater by both molarity and mass, after sodium, chloride, magnesium, and sulfate. Free calcium metal is too reactive to occur in nature, Calcium is produced in supernova nucleosynthesis. Calcium is a trace element in living organisms. It is the most abundant metal by mass in animals, and it is an important constituent of bone, teeth. In cell biology, the movement of the calcium ion into, Calcium carbonate and calcium citrate are often taken as dietary supplements. Calcium is on the World Health Organizations List of Essential Medicines, Calcium has a wide variety of applications, almost all of which are associated with calcium compounds and salts. Calcium metal is used as a deoxidizer, desulfurizer, and decarbonizer for production of ferrous and nonferrous alloys. In steelmaking and production of iron, Ca reacts with oxygen, Calcium carbonate is used in manufacturing cement and mortar, lime, limestone and aids in production in the glass industry. It also has chemical and optical uses as mineral specimens in toothpastes, Calcium hydroxide solution is used to detect the presence of carbon dioxide in a gas sample bubbled through a solution. The solution turns cloudy where CO2 is present, Calcium arsenate is used in insecticides. Calcium carbide is used to make acetylene gas and various plastics, Calcium chloride is used in ice removal and dust control on dirt roads, as a conditioner for concrete, as an additive in canned tomatoes, and to provide body for automobile tires. Calcium citrate is used as a food preservative, Calcium cyclamate is used as a sweetening agent in several countries. In the United States, it has been outlawed as a suspected carcinogen, Calcium gluconate is used as a food additive and in vitamin pills. Calcium hypochlorite is used as a swimming pool disinfectant, as an agent, as an ingredient in deodorant. Calcium permanganate is used in rocket propellant, textile production, as a water sterilizing agent. Calcium phosphate is used as a supplement for animal feed, fertilizer, in production for dough and yeast products, in the manufacture of glass. Calcium phosphide is used in fireworks, rodenticide, torpedoes, Calcium sulfate is used as common blackboard chalk, as well as, in its hemihydrate form, Plaster of Paris
31.
Silver
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Silver is a metallic element with symbol Ag and atomic number 47. The symbol Ag stems from Latin argentum, derived from the Greek ὰργὀς, a soft, white, lustrous transition metal, it exhibits the highest electrical conductivity, thermal conductivity, and reflectivity of any metal. The metal is found in the Earths crust in the pure, free form, as an alloy with gold and other metals. Most silver is produced as a byproduct of copper, gold, lead, Silver is more abundant than gold, but it is much less abundant as a native metal. Its purity is measured on a per mille basis, a 94%-pure alloy is described as 0.940 fine. As one of the seven metals of antiquity, silver has had a role in most human cultures. Silver has long valued as a precious metal. Silver metal is used in many premodern monetary systems in bullion coins, Silver is used in numerous applications other than currency, such as solar panels, water filtration, jewelry, ornaments, high-value tableware and utensils, and as an investment medium. Silver is used industrially in electrical contacts and conductors, in specialized mirrors, window coatings, Silver compounds are used in photographic film and X-rays. Dilute silver nitrate solutions and other compounds are used as disinfectants and microbiocides, added to bandages and wound-dressings, catheters. Silver is similar in its physical and chemical properties to its two neighbours in group 11 of the periodic table, copper and gold. This distinctive electron configuration, with an electron in the highest occupied s subshell over a filled d subshell. Silver is a soft, ductile and malleable transition metal. Silver crystallizes in a cubic lattice with bulk coordination number 12. Unlike metals with incomplete d-shells, metallic bonds in silver are lacking a covalent character and are relatively weak and this observation explains the low hardness and high ductility of single crystals of silver. Silver has a brilliant white metallic luster that can take a polish. Protected silver has greater optical reflectivity than aluminium at all wavelengths longer than ~450 nm, at wavelengths shorter than 450 nm, silvers reflectivity is inferior to that of aluminium and drops to zero near 310 nm. The electrical conductivity of silver is the greatest of all metals, greater even than copper, during World War II in the US,13540 tons of silver were used in electromagnets for enriching uranium, mainly because of the wartime shortage of copper
32.
Basalt
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Basalt is a common extrusive igneous rock formed from the rapid cooling of basaltic lava exposed at or very near the surface of a planet or moon. Flood basalt describes the formation in a series of basalt flows. By definition, basalt is an igneous rock with generally 45-55% silica and less than 10% feldspathoid by volume. Basalt commonly features a very fine-grained or glassy matrix interspersed with visible mineral grains, the average density is 3.0 gm/cm3. Basalt is defined by its content and texture, and physical descriptions without mineralogical context may be unreliable in some circumstances. Basalt is usually grey to black in colour, but rapidly weathers to brown or rust-red due to oxidation of its mafic minerals into hematite, although usually characterized as dark, basaltic rocks exhibit a wide range of shading due to regional geochemical processes. Due to weathering or high concentrations of plagioclase, some basalts can be quite light-coloured and these phenocrysts usually are of olivine or a calcium-rich plagioclase, which have the highest melting temperatures of the typical minerals that can crystallize from the melt. Basalt with a texture is called vesicular basalt, when the bulk of the rock is mostly solid. Gabbro is often marketed commercially as black granite and these ultramafic volcanic rocks, with silica contents below 45% are usually classified as komatiites. Agricola applied basalt to the black rock of the Schloßberg at Stolpen. Tholeiitic basalt is relatively rich in silica and poor in sodium, included in this category are most basalts of the ocean floor, most large oceanic islands, and continental flood basalts such as the Columbia River Plateau. Basalt rocks are in some cases classified after their content in High-Ti and Low-Ti varieties. High-Ti and Low-Ti basalts have been distinguished in the Paraná and Etendeka traps and it has greater than 17% alumina and is intermediate in composition between tholeiite and alkali basalt, the relatively alumina-rich composition is based on rocks without phenocrysts of plagioclase. Alkali basalt is relatively poor in silica and rich in sodium and it is silica-undersaturated and may contain feldspathoids, alkali feldspar and phlogopite. Boninite is a form of basalt that is erupted generally in back-arc basins. Ocean island basalt Lunar basalt On Earth, most basalt magmas have formed by melting of the mantle. Basalt commonly erupts on Io, the third largest moon of Jupiter, and has formed on the Moon, Mars, Venus. The crustal portions of oceanic tectonic plates are composed predominantly of basalt, produced from upwelling mantle below, the mineralogy of basalt is characterized by a preponderance of calcic plagioclase feldspar and pyroxene
33.
Igneous rock
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Igneous rock, or magmatic rock, is one of the three main rock types, the others being sedimentary and metamorphic. Igneous rock is formed through the cooling and solidification of magma or lava, the magma can be derived from partial melts of existing rocks in either a planets mantle or crust. Typically, the melting is caused by one or more of three processes, an increase in temperature, a decrease in pressure, or a change in composition, solidification into rock occurs either below the surface as intrusive rocks or on the surface as extrusive rocks. Igneous rock may form with crystallization to form granular, crystalline rocks, Igneous and metamorphic rocks make up 90–95% of the top 16 km of the Earths crust by volume. Igneous rocks form about 15% of the Earths current land surface, most of the Earths oceanic crust is made of igneous rock. In terms of modes of occurrence, igneous rocks can be either intrusive or extrusive, the mineral grains in such rocks can generally be identified with the naked eye. Intrusive rocks can also be classified according to the shape and size of the intrusive body, typical intrusive formations are batholiths, stocks, laccoliths, sills and dikes. When the magma solidifies within the earths crust, it cools slowly forming coarse textured rocks, such as granite, gabbro, the central cores of major mountain ranges consist of intrusive igneous rocks, usually granite. When exposed by erosion, these cores may occupy huge areas of the Earths surface, intrusive igneous rocks that form at depth within the crust are termed plutonic rocks and are usually coarse-grained. Intrusive igneous rocks that form near the surface are termed subvolcanic or hypabyssal rocks, hypabyssal rocks are less common than plutonic or volcanic rocks and often form dikes, sills, laccoliths, lopoliths, or phacoliths. Extrusive igneous rocks, also known as rocks, are formed at the crusts surface as a result of the partial melting of rocks within the mantle. Extrusive igneous rocks cool and solidify quicker than intrusive igneous rocks and they are formed by the cooling of molten magma on the earths surface. The magma, which is brought to the surface through fissures or volcanic eruptions, hence such rocks are smooth, crystalline and fine-grained. Basalt is an extrusive igneous rock and forms lava flows, lava sheets. Some kinds of basalt solidify to form long polygonal columns, the Giants Causeway in Antrim, Northern Ireland is an example. The molten rock, with or without suspended crystals and gas bubbles, is called magma and it rises because it is less dense than the rock from which it was created. When magma reaches the surface from beneath water or air, it is called lava, eruptions of volcanoes into air are termed subaerial, whereas those occurring underneath the ocean are termed submarine. Black smokers and mid-ocean ridge basalt are examples of volcanic activity
34.
Prehnite
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Prehnite is an inosilicate of calcium and aluminium with the formula, Ca2Al2. Limited Fe3+ substitutes for aluminium in the structure, very rarely will it form distinct, well-individualized crystals showing a square-like cross-section, including those found at the Jeffrey Mine in Asbestos, Quebec, Canada. Prehnite is brittle with a fracture and a vitreous to pearly luster. Its hardness is 6-6.5, its gravity is 2. 80-2.90 and its color varies from light green to yellow. In April 2000, rare orange prehnite was discovered in the Kalahari Manganese Fields, prehnite is mostly translucent, and rarely transparent. It is a mineral of the prehnite-pumpellyite metamorphic facies. It was first described in 1788 for an occurrence in the Karoo dolerites of Cradock, Eastern Cape Province and it was named for Colonel Hendrik Von Prehn, commander of the military forces of the Dutch colony at the Cape of Good Hope from 1768 to 1780. It is used as a gemstone, extensive deposits of gem quality prehnite occur in the basalt tableland surrounding Wave Hill Station in the central Northern Territory, of Australia. List of minerals List of minerals named after people
35.
Calcite
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Calcite is a carbonate mineral and the most stable polymorph of calcium carbonate. The Mohs scale of hardness, based on scratch hardness comparison. Other polymorphs of calcium carbonate are the minerals aragonite and vaterite, aragonite will change to calcite at 380–470 °C, and vaterite is even less stable. Calcite is derived from the German Calcit, a term coined in the 19th century from the Latin word for lime and it is thus etymologically related to chalk. Calcite crystals are trigonal-rhombohedral, though actual calcite rhombohedra are rare as natural crystals, however, they show a remarkable variety of habits including acute to obtuse rhombohedra, tabular forms, prisms, or various scalenohedra. Calcite exhibits several twinning types adding to the variety of observed forms and it may occur as fibrous, granular, lamellar, or compact. Cleavage is usually in three directions parallel to the rhombohedron form and its fracture is conchoidal, but difficult to obtain. It has a defining Mohs hardness of 3, a gravity of 2.71. Color is white or none, though shades of gray, red, orange, yellow, green, blue, violet, brown, calcite is transparent to opaque and may occasionally show phosphorescence or fluorescence. A transparent variety called Iceland spar is used for optical purposes, acute scalenohedral crystals are sometimes referred to as dogtooth spar while the rhombohedral form is sometimes referred to as nailhead spar. Single calcite crystals display an optical property called birefringence and this strong birefringence causes objects viewed through a clear piece of calcite to appear doubled. The birefringent effect was first described by the Danish scientist Rasmus Bartholin in 1669, at a wavelength of ~590 nm calcite has ordinary and extraordinary refractive indices of 1.658 and 1.486, respectively. Between 190 and 1700 nm, the refractive index varies roughly between 1.9 and 1.5, while the extraordinary refractive index varies between 1.6 and 1.4. Calcite, like most carbonates, will dissolve with most forms of acid, calcite can be either dissolved by groundwater or precipitated by groundwater, depending on several factors including the water temperature, pH, and dissolved ion concentrations. Although calcite is fairly insoluble in water, acidity can cause dissolution of calcite. Ambient carbon dioxide, due to its acidity, has a slight solubilizing effect on calcite, calcite exhibits an unusual characteristic called retrograde solubility in which it becomes less soluble in water as the temperature increases. When conditions are right for precipitation, calcite forms mineral coatings that cement the existing rock grains together or it can fill fractures. On a landscape scale, continued dissolution of calcium carbonate-rich rocks can lead to the expansion and eventual collapse of cave systems, high-grade optical calcite was used in World War II for gun sights, specifically in bomb sights and anti-aircraft weaponry
36.
Leicestershire
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Leicestershire is a landlocked county in the English Midlands. The border with most of Warwickshire is Watling Street, the county has a population of just under 1 million with over half the population living in Leicesters built-up area. Leicestershire was recorded in the Domesday Book in four wapentakes, Guthlaxton, Framland, Goscote and these later became hundreds, with the division of Goscote into West Goscote and East Goscote, and the addition of Sparkenhoe hundred. In 1087, the first recorded use of the name was as Laegrecastrescir, Leicestershires external boundaries have changed little since the Domesday Survey. These actions were reversed on 1 April 1997, when Rutland, Rutland became a distinct Ceremonial County once again, although it continues to be policed by Leicestershire Constabulary. The symbol of the county council, Leicestershire County Cricket Club, Leicestershire is considered to be the birthplace of fox hunting as it is known today. Hugo Meynell, who lived in Quorn, is known as the father of fox hunting, Melton Mowbray and Market Harborough have associations with fox hunting, as has neighbouring Rutland. A large part of the north-west of the county, around Coalville, the highest point of the county is Bardon Hill at 278 metres, which is also a Marilyn. The lowest point is about 24. 8m, north of Bottesford where the River Devon leaves Leicestershire, the population of Leicestershire is 609,578 people. The county covers an area of 2,084 km2 and its largest population centre is the city of Leicester, followed by the town of Loughborough. Other large towns include Ashby-de-la-Zouch, Coalville, Hinckley, Market Harborough, Melton Mowbray, Oadby, Wigston, some of the larger of villages are, Burbage Birstall, Broughton Astley, Castle Donington, Kibworth Beauchamp, Great Glen, Ibstock, Countesthorpe and Kegworth. One of the most rapidly expanding villages is Anstey, which has seen a large number of development schemes. The United Kingdom Census 2001 showed a resident population for Leicester of 279,921. Approximately 62,000 were aged under 16,199,000 were aged 16–74,76. 9% of Leicesters population claim they have been born in the UK, according to the 2001 UK Census. Mid-year estimates for 2006 indicate that the population of the City of Leicester stood at 289,700 making Leicester the most populous city in East Midlands, the population density is 3, 814/km2 and for every 100 females, there were 92.9 males. Of those aged 16–74 in Leicester,38. 5% had no academic qualifications,23. 0% of Leicesters residents were born outside of the United Kingdom, more than double than the English average of 9. 2%. Engineering has long been an important part of the economy of Leicestershire, John Taylor Bellfounders continues a history of bellfounding in Loughborough since the 14th century. In 1881 John Taylors cast the largest bell in Britain, Great Paul, snibston Discovery Park is built on one of three coal mines that operated in Coalville from the 1820s until 1986
37.
Cyclopean Isles
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The Cyclopean Isles, noted for their rows of basaltic columns piled one above another, lie not far from Mount Etna off the eastern coast of Sicily in the Mediterranean Sea. The Cyclopean Isles are of volcanic origin, and may at one time have been attached to Sicily, the lava forming the basaltic columns was consolidated under great pressure, probably at the bottom of the sea. The Cyclopean Isles strongly resemble the Giants Causeway on the northern coast of Ireland, the latter, closest in appearance to the Cyclopean pair, differ mainly in having the columns piled in terraces, one above another. There is an ancient tradition that the islands at one time formed part of the mainland of Sicily, homer has a curious story about the manner in which they became detached, towards the end of the ninth book of the Odyssey. When Odysseus visited Sicily it was inhabited by the Cyclopes, said to have had one eye. Odysseus encounters one of their number, Polyphemus, on his home to Ithaca. Polyphemus opens the cave boulder and the Greeks escape to their ship, Polyphemus calls to the other Cyclopes for help and Odysseus, from the distance of his ship, begins to taunt and to jeer at him. Homer says, These words the Cyclops burning rage provoke, From the tall hill he rends a pointed rock, High oer the billows flew the massy load and it almost brushed the helm, and fell before, The whole sea shook, and refluent beat the shore. Odysseus boasts that it was Odysseus. Son of Laertes who had burnt out Polyphemuss eye
38.
Sicily
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Sicily is the largest island in the Mediterranean Sea. It is an autonomous Region of Italy, along with surrounding minor islands, Sicily is located in the central Mediterranean Sea, south of the Italian Peninsula, from which it is separated by the narrow Strait of Messina. Its most prominent landmark is Mount Etna, the tallest active volcano in Europe, the island has a typical Mediterranean climate. The earliest archaeological evidence of activity on the island dates from as early as 12,000 BC. It became part of Italy in 1860 following the Expedition of the Thousand, a revolt led by Giuseppe Garibaldi during the Italian unification, Sicily was given special status as an autonomous region after the Italian constitutional referendum of 1946. Sicily has a rich and unique culture, especially regard to the arts, music, literature, cuisine. It is also home to important archaeological and ancient sites, such as the Necropolis of Pantalica, the Valley of the Temples, Sicily has a roughly triangular shape, earning it the name Trinacria. To the east, it is separated from the Italian mainland by the Strait of Messina, about 3 km wide in the north, and about 16 km wide in the southern part. The northern and southern coasts are each about 280 km long measured as a line, while the eastern coast measures around 180 km. The total area of the island is 25,711 km2, the terrain of inland Sicily is mostly hilly and is intensively cultivated wherever possible. Along the northern coast, the ranges of Madonie,2,000 m, Nebrodi,1,800 m. The cone of Mount Etna dominates the eastern coast, in the southeast lie the lower Hyblaean Mountains,1,000 m. The mines of the Enna and Caltanissetta districts were part of a leading sulphur-producing area throughout the 19th century, Sicily and its surrounding small islands have some highly active volcanoes. Mount Etna is the largest active volcano in Europe and still casts black ash over the island with its ever-present eruptions and it currently stands 3,329 metres high, though this varies with summit eruptions, the mountain is 21 m lower now than it was in 1981. It is the highest mountain in Italy south of the Alps, Etna covers an area of 1,190 km2 with a basal circumference of 140 km. This makes it by far the largest of the three volcanoes in Italy, being about two and a half times the height of the next largest, Mount Vesuvius. In Greek Mythology, the deadly monster Typhon was trapped under the mountain by Zeus, Mount Etna is widely regarded as a cultural symbol and icon of Sicily. The Aeolian Islands in the Tyrrhenian Sea, to the northeast of mainland Sicily form a volcanic complex, the three volcanoes of Vulcano, Vulcanello and Lipari are also currently active, although the latter is usually dormant
39.
Trentino
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Trentino, officially the Autonomous Province of Trento, is an autonomous province of Italy, in the countrys far north. Trentino is, along with South Tyrol, one of the two provinces making up the region of Trentino-Alto Adige/Südtirol, which is designated a region under the constitution. The province is divided into 178 comuni and its capital is the city of Trento. The province covers an area of more than 6,000 km2, Trentino is renowned for its mountains, such as the Dolomites, which are part of the Alps. The province is known as Trentino. The name derives from Trento, the city of the province. Originally, the term was used by the population only to refer to the city. In its wider sense, Trentino was first used around 1848 in an article by a member of the Frankfurt National Assembly, since the new 1972 autonomous status, the administrative name of the province is Autonomous Province of Trento. The history of Trentino begins in the mid-Stone Age, the valleys of what is now Trentino were already inhabited by man, the main settlements being in the valley of the Adige River, thanks to its milder climate. In the early Middle Ages, this area was included within the Kingdom of Italy, in 1027, the Bishopric of Trent was established as a State of the Holy Roman Empire by Emperor Conrad II. It was a territory, roughly corresponding to the present-day Trentino. The Council of Trent, held in three sessions from 1545 to 1563, with the first at Trento, was one of the important councils in the history of the Roman Catholic Church. It was an articulation of Roman Catholic doctrine in response to the Protestant Reformation, and specified doctrine on salvation, the sacraments, after the Napoleonic Wars of the early 19th century, the bishopric was secularized and absorbed into the Austrian County of Tyrol. It was governed by the House of Habsburg-Lorraine, the region was the location of heavy fighting during World War I, as it was directly on the front lines between Austria-Hungary and Italy. Trentino remained a part of Austria-Hungary until after the end of the war in 1919, since this treaty, Trentino enjoys considerable autonomy from the Italian central government in Rome. It has its own elected government and legislative assembly, in 1996, the Euroregion Tyrol-South Tyrol-Trentino was formed between the Austrian state of Tyrol and the Italian provinces of South Tyrol and Trentino. The boundaries of the association correspond to the old County of Tyrol, the aim is to promote regional peace, understanding and cooperation in many areas. The regions assemblies meet together as one on various occasions and have set up a liaison office to the European Union in Brussels
40.
Victoria (Australia)
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Victoria is a state in southeast Australia. Victoria is Australias most densely populated state and its second-most populous state overall, most of its population is concentrated in the area surrounding Port Phillip Bay, which includes the metropolitan area of its state capital and largest city, Melbourne, Australias second-largest city. Prior to British European settlement, the area now constituting Victoria was inhabited by a number of Aboriginal peoples. With Great Britain having claimed the entire Australian continent east of the 135th meridian east in 1788, Victoria was included in the wider colony of New South Wales. The first settlement in the area occurred in 1803 at Sullivan Bay, and much of what is now Victoria was included in the Port Phillip District in 1836, Victoria was officially created as a separate colony in 1851, and achieved self-government in 1855. Politically, Victoria has 37 seats in the Australian House of Representatives and 12 seats in the Australian Senate, at state level, the Parliament of Victoria consists of the Legislative Assembly and the Legislative Council. Victoria is currently governed by the Labor Party, with Daniel Andrews the current Premier, the personal representative of the Queen of Australia in the state is the Governor of Victoria, currently Linda Dessau. Local government is concentrated in 79 municipal districts, including 33 cities, although a number of unincorporated areas still exist, Victorias total gross state product is ranked second in Australia, although Victoria is ranked fourth in terms of GSP per capita because of its limited mining activity. Culturally, Melbourne is home to a number of museums, art galleries and theatres and is described as the sporting capital of Australia. The Melbourne Cricket Ground is the largest stadium in Australia, and the host of the 1956 Summer Olympics, Victoria has eight public universities, with the oldest, the University of Melbourne, having been founded in 1853. Victoria, like Queensland, was named after Queen Victoria, who had been on the British throne for 14 years when the colony was established in 1851. The first British settlement in the later known as Victoria was established in October 1803 under Lieutenant-Governor David Collins at Sullivan Bay on Port Phillip. In the year 1826 Colonel Stewart, Captain S. Wright, fly and the brigs Dragon and Amity, took a number of convicts and a small force composed of detachments of the 3rd and 93rd regiments. Victorias next settlement was at Portland, on the south west coast of what is now Victoria, edward Henty settled Portland Bay in 1834. Melbourne was founded in 1835 by John Batman, who set up a base in Indented Head, from settlement the region around Melbourne was known as the Port Phillip District, a separately administered part of New South Wales. Shortly after the now known as Geelong was surveyed by Assistant Surveyor W. H. Smythe. And in 1838 Geelong was officially declared a town, despite earlier white settlements dating back to 1826, days later, still in 1851 gold was discovered near Ballarat, and subsequently at Bendigo. Later discoveries occurred at sites across Victoria
41.
Kerguelen Islands
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The Kerguelen Islands, also known as the Desolation Islands, are a group of islands in the southern Indian Ocean constituting one of the two exposed parts of the mostly submerged Kerguelen Plateau. They are among the most isolated places on Earth, located 450 km northwest of the uninhabited Heard Island and McDonald Islands and more than 3,300 km from Madagascar, the nearest populated location. The main island, Grande Terre, is 6,675 km2 in area and is surrounded by a further 300 smaller islands and islets, the climate is raw and chilly with frequent high winds throughout the year. The surrounding seas are generally rough and they remain ice-free year-round, there are no indigenous inhabitants, but France maintains a permanent presence of 45 to 100 scientists, engineers and researchers. There are no airports on the islands, so all travel, Kerguelen Islands appear as the Ile de Nachtegal on Philippe Buaches map from 1754 before the island was officially discovered in 1772. It is possible this early name was after Tasmans ship De Zeeuwsche Nachtegaal, on the Buache map, Ile de Nachtegal is located at 43°S, 72°E, about 6 degrees north and 2 degrees east of the accepted location of Grande Terre. The islands were discovered by the French navigator Yves-Joseph de Kerguelen-Trémarec on 12 February 1772. The next day Charles de Boisguehenneuc landed and claimed the island for the French crown, yves de Kerguelen organised a second expedition in 1773 and arrived at the baie de lOiseau by December of the same year. On 6 January 1774 he commanded his lieutenant, Henri Pascal de Rochegude, since the end of the whaling and sealing era, most of the islands species have been able to increase their population again. In 1800, Hillsborough spent eight months sealing and whaling around the islands, during this time Captain Robert Rhodes, her master, prepared a chart of the islands. In 1825, the British sealer John Nunn and three members from Favourite, were shipwrecked on Kerguelen until they were rescued in 1827 by Captain Alexander Distant during his hunting campaign. The islands were not completely surveyed until the Ross expedition of 1840, for the 1874 transit of Venus, George Biddell Airy at the Royal Observatory of the UK organised and equipped five expeditions to different parts of the world. Three of these were sent to the Kerguelen Islands, the Reverend Stephen Joseph Perry led the British expeditions to the Kerguelen Islands. He set up his main station at Observatory Bay and two auxiliary stations, one at Thumb Peak led by Sommerville Goodridge, and the second at Supply Bay led by Cyril Corbet. Observatory Bay was also used by the German Antarctic Expedition led by Erich Dagobert von Drygalski in 1902–03, in January 2007, an archaeological excavation of this site was carried out. In 1874–1875, British, German and U. S. expeditions visited Kerguelen to observe the transit of Venus, in 1877 the French started a coal mining operation, however, this was abandoned soon after. The German auxiliary cruiser Atlantis called at Kerguelen during December 1940, during their stay the crew performed maintenance and replenished their water supplies. This ships first fatality of the war occurred when a sailor, Bernhard Herrmann and he is buried in what is sometimes referred to as the most southerly German war grave of World War II
42.
Indian Ocean
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The Indian Ocean is the third largest of the worlds oceanic divisions, covering 70,560,000 km2. It is bounded by Asia on the north, on the west by Africa, on the east by Australia, the Indian Ocean is known as Ratnākara, the mine of gems in ancient Sanskrit literature, and as Hind Mahāsāgar, in Hindi. The northernmost extent of the Indian Ocean is approximately 30° north in the Persian Gulf, the oceans continental shelves are narrow, averaging 200 kilometres in width. An exception is found off Australias western coast, where the width exceeds 1,000 kilometres. The average depth of the ocean is 3,890 m and its deepest point is Diamantina Deep in Diamantina Trench, at 8,047 m deep, Sunda Trench has a depth of 7, 258–7,725 m. North of 50° south latitude, 86% of the basin is covered by pelagic sediments. The remaining 14% is layered with terrigenous sediments, glacial outwash dominates the extreme southern latitudes. The major choke points include Bab el Mandeb, Strait of Hormuz, the Lombok Strait, the Strait of Malacca, the Indian Ocean is artificially connected to the Mediterranean Sea through the Suez Canal, which is accessible via the Red Sea. All of the Indian Ocean is in the Eastern Hemisphere and the centre of the Eastern Hemisphere is in this ocean, marginal seas, gulfs, bays and straits of the Indian Ocean include, The climate north of the equator is affected by a monsoon climate. Strong north-east winds blow from October until April, from May until October south, in the Arabian Sea the violent Monsoon brings rain to the Indian subcontinent. In the southern hemisphere, the winds are milder. When the monsoon winds change, cyclones sometimes strike the shores of the Arabian Sea, the Indian Ocean is the warmest ocean in the world. Long-term ocean temperature records show a rapid, continuous warming in the Indian Ocean, Indian Ocean warming is the largest among the tropical oceans, and about 3 times faster than the warming observed in the Pacific. Research indicates that human induced greenhouse warming, and changes in the frequency, among the few large rivers flowing into the Indian Ocean are the Zambezi, Shatt al-Arab, Indus, Godavari, Krishna, Narmada, Ganges, Brahmaputra, Jubba and Irrawaddy River. The oceans currents are controlled by the monsoon. Two large gyres, one in the northern hemisphere flowing clockwise and one south of the equator moving anticlockwise, during the winter monsoon, however, currents in the north are reversed. Deep water circulation is controlled primarily by inflows from the Atlantic Ocean, the Red Sea, north of 20° south latitude the minimum surface temperature is 22 °C, exceeding 28 °C to the east. Southward of 40° south latitude, temperatures drop quickly, surface water salinity ranges from 32 to 37 parts per 1000, the highest occurring in the Arabian Sea and in a belt between southern Africa and south-western Australia
43.
Lake Superior
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Lake Superior is the largest of the Great Lakes of North America. The lake is shared by the Canadian province of Ontario to the north, the US state of Minnesota to the west and it is generally considered the largest freshwater lake in the world by surface area. It is the worlds third-largest freshwater lake by volume and the largest by volume in North America, the Ojibwe call the lake gichi-gami, meaning be a great sea. Henry Wadsworth Longfellow wrote the name as Gitche Gumee in The Song of Hiawatha, as did Gordon Lightfoot in his song, according to other sources the actual Ojibwe name is Ojibwe Gichigami or Anishinaabe Gichigami. The 1878 dictionary by Father Frederic Baraga, the first one written for the Ojibway language, the first French explorers approaching the great inland sea by way of the Ottawa River and Lake Huron during the 17th century referred to their discovery as le lac supérieur. Properly translated, the expression means Upper Lake, that is, the lake was also called Lac Tracy by 17th century Jesuit missionaries. Lake Superior empties into Lake Huron via the St. Marys River, Lake Superior is the largest freshwater lake in the world in area, and the third largest in volume, behind Lake Baikal in Siberia and Lake Tanganyika in East Africa. Lake Superior has an area of 31,700 square miles. It has a length of 350 statute miles and maximum breadth of 160 statute miles. Its average depth is 80.5 fathoms with a depth of 222.17 fathoms. Lake Superior contains 2,900 cubic miles of water, there is enough water in Lake Superior to cover the entire land mass of North and South America to a depth of 30 centimetres. The shoreline of the lake stretches 2,726 miles, while the temperature of the surface of Lake Superior varies seasonally, the temperature below 110 fathoms is an almost constant 39 °F. This variation in temperature makes the lake seasonally stratigraphic, twice per year, however, the water column reaches a uniform temperature of 39 °F from top to bottom, and the lake waters thoroughly mix. This feature makes the lake dimictic, because of its volume, Lake Superior has a retention time of 191 years. Annual storms on Lake Superior regularly feature wave heights of over 20 feet, waves well over 30 feet have been recorded. The lake is fed by over 200 rivers, the largest include the Nipigon River, the St. Louis River, the Pigeon River, the Pic River, the White River, the Michipicoten River, the Bois Brule River and the Kaministiquia River. Lake Superior drains into Lake Huron via the St. Marys River, there are rapids at the rivers upper end where the river bed has a relatively steep gradient. The Soo Locks were built to enable ships to bypass the rapids, the lakes average surface elevation is 600 feet above sea level
44.
Michigan
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Michigan /ˈmɪʃᵻɡən/ is a state in the Great Lakes and Midwestern regions of the United States. The name Michigan is the French form of the Ojibwa word mishigamaa, Michigan is the tenth most populous of the 50 United States, with the 11th most extensive total area. Its capital is Lansing, and its largest city is Detroit, Michigan is the only state to consist of two peninsulas. The Lower Peninsula, to which the name Michigan was originally applied, is noted to be shaped like a mitten. The Upper Peninsula is separated from the Lower Peninsula by the Straits of Mackinac, the two peninsulas are connected by the Mackinac Bridge. The state has the longest freshwater coastline of any political subdivision in the world, being bounded by four of the five Great Lakes, as a result, it is one of the leading U. S. states for recreational boating. Michigan also has 64,980 inland lakes and ponds, a person in the state is never more than six miles from a natural water source or more than 85 miles from a Great Lakes shoreline. What is now the state of Michigan was first settled by Native American tribes before being colonized by French explorers in the 17th century, the area was organized as part of the larger Northwest Territory until 1800, when western Michigan became part of the Indiana Territory. Eventually, in 1805, the Michigan Territory was formed, which lasted until it was admitted into the Union on January 26,1837, the state of Michigan soon became an important center of industry and trade in the Great Lakes region and a popular immigrant destination. Though Michigan has come to develop an economy, it is widely known as the center of the U. S. automotive industry. When the first European explorers arrived, the most populous tribes were Algonquian peoples, which include the Anishinaabe groups of Ojibwe, Odaawaa/Odawa, the three nations co-existed peacefully as part of a loose confederation called the Council of Three Fires. The Ojibwe, whose numbers are estimated to have been between 25,000 and 35,000, were the largest, French voyageurs and coureurs des bois explored and settled in Michigan in the 17th century. The first Europeans to reach what became Michigan were those of Étienne Brûlés expedition in 1622, the first permanent European settlement was founded in 1668 on the site where Père Jacques Marquette established Sault Ste. Marie, Michigan as a base for Catholic missions, missionaries in 1671–75 founded outlying stations at Saint Ignace and Marquette. Jesuit missionaries were received by the areas Indian populations, with relatively few difficulties or hostilities. In 1679, Robert Cavelier, Sieur de la Salle built Fort Miami at present-day St. Joseph, in 1691, the French established a trading post and Fort St. Joseph along the St. Joseph River at the present day city of Niles. The hundred soldiers and workers who accompanied Cadillac built a fort enclosing one arpent, cadillacs wife, Marie Thérèse Guyon, soon moved to Detroit, becoming one of the first European women to settle in the Michigan wilderness. The town quickly became a major fur-trading and shipping post, the Église de Saint-Anne was founded the same year
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New Jersey
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New Jersey is a state in the Northeastern and mid-Atlantic regions of the United States. It is bordered on the north and east by New York, on the southeast and south by the Atlantic Ocean, on the west by Pennsylvania, New Jersey is the fourth-smallest state but the 11th-most populous and the most densely populated of the 50 United States. New Jersey lies entirely within the statistical areas of New York City. New Jersey was inhabited by Native Americans for more than 2,800 years, in the early 17th century, the Dutch and the Swedes made the first European settlements. New Jersey was the site of decisive battles during the American Revolutionary War in the 18th century. In the 19th century, factories in cities such as Camden, Paterson, Newark, Trenton, around 180 million years ago, during the Jurassic Period, New Jersey bordered North Africa. The pressure of the collision between North America and Africa gave rise to the Appalachian Mountains, around 18,000 years ago, the Ice Age resulted in glaciers that reached New Jersey. As the glaciers retreated, they left behind Lake Passaic, as well as rivers, swamps. New Jersey was originally settled by Native Americans, with the Lenni-Lenape being dominant at the time of contact, scheyichbi is the Lenape name for the land that is now New Jersey. The Lenape society was divided into clans that were based upon common female ancestors. These clans were organized into three distinct phratries identified by their animal sign, Turtle, Turkey, and Wolf and they first encountered the Dutch in the early 17th century, and their primary relationship with the Europeans was through fur trade. The Dutch became the first Europeans to lay claim to lands in New Jersey, the Dutch colony of New Netherland consisted of parts of modern Middle Atlantic states. Although the European principle of ownership was not recognized by the Lenape. The first to do so was Michiel Pauw who established a patronship called Pavonia in 1630 along the North River which eventually became the Bergen, peter Minuits purchase of lands along the Delaware River established the colony of New Sweden. During the English Civil War, the Channel Island of Jersey remained loyal to the British Crown and it was from the Royal Square in St. Helier that Charles II of England was proclaimed King in 1649, following the execution of his father, Charles I. The North American lands were divided by Charles II, who gave his brother, the Duke of York, the region between New England and Maryland as a proprietary colony. James then granted the land between the Hudson River and the Delaware River to two friends who had remained loyal through the English Civil War, Sir George Carteret and Lord Berkeley of Stratton, the area was named the Province of New Jersey. Since the states inception, New Jersey has been characterized by ethnic, New England Congregationalists settled alongside Scots Presbyterians and Dutch Reformed migrants
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Golden, Colorado
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Golden is the Home Rule Municipality that is the county seat of Jefferson County, Colorado, United States. Golden lies along Clear Creek at the base of the Front Range of the Rocky Mountains, founded during the Pikes Peak Gold Rush on 16 June 1859, the mining camp was originally named Golden City in honor of Thomas L. Golden. Golden City served as the capital of the provisional Territory of Jefferson from 1860 to 1861, in 1867, the territorial capital was moved about 12 miles east to Denver City. The United States Census Bureau estimates that the city population was 18,867 in 2010, the Colorado School of Mines, offering programs in engineering and science, is located in Golden. It is the birthplace of the Jolly Rancher, a candy bought out by the Hershey Foods Corporation, Buffalo Bill Cody is buried nearby on Lookout Mountain. Golden City was established on 16 June 1859 along Clear Creek west of Denver, important businessmen and prospectors such as William A. H. Loveland and George West were among the first to settle in Golden. By the end of 1860, Golden City had been elected the seat of Jefferson County and was capital of the provisional Jefferson Territory. Golden City was temporarily removed from the status of capital as a result of an act passed on 5 November 1861 by the territorial government. Colorado City, a town to the south of Denver became the new temporary territorial capital. This status was revoked, however, as on 4 August 1862. It was the period between 1862 and the early 1870s that a fierce railroad competition developed between Denver, ten miles to the east, and Golden. By the mid-1860s, Golden held only a status as territorial capital rather than serve as the legitimate source of territorial power. Loveland founded the Colorado Central Railroad on 9 February 1865 to do just this, with Golden beginning talk of creating a railroad, prominent Denver residents raced to do the same. If we defeat those bonds, all hope of a railroad for the two years is gone… Gentlemen of Denver, what will you do. The fate of city is in your own hands. ”The residents of Denver voted for the bonds. By 1869, the race to Cheyenne was becoming less and less of a race. Golden, having then sidetracked into servicing various close-by mountain communities, continued to fall behind the set by the Denver railroad. However, The Colorado Central Railroad connected directly with Cheyenne seven years later, in 1877, but by that point, during the 1870s, it became home to three institutions of higher education, the Colorado University Schools, of which the Colorado School of Mines remains today
