1.
Nesosilicates
–
Silicate minerals are rock-forming minerals made up of silicate groups. They are the largest and most important class of rock-forming minerals and they are classified based on the structure of their silicate groups, which contain different ratios of silicon and oxygen. Nesosilicates, or orthosilicates, have the orthosilicate ion, which constitute isolated 4− tetrahedra that are connected only by interstitial cations and these exist as 3-member 6− and 6-member 12− rings, where T stands for a tetrahedrally coordinated cation. Inosilicates, or chain silicates, have interlocking chains of silicate tetrahedra with either SiO3,1,3 ratio, for single chains or Si4O11,4,11 ratio, for double chains. Nickel–Strunz classification,09. D Pyroxene group Enstatite – orthoferrosilite series Enstatite – MgSiO3 Ferrosilite – FeSiO3 Pigeonite – Ca0.251, all phyllosilicate minerals are hydrated, with either water or hydroxyl groups attached. Serpentine subgroup Antigorite – Mg3Si2O54 Chrysotile – Mg3Si2O54 Lizardite – Mg3Si2O54 Clay minerals group Halloysite – Al2Si2O54 Kaolinite – Al2Si2O54 Illite – 24O10 Montmorillonite –0 and this group comprises nearly 75% of the crust of the Earth. Tectosilicates, with the exception of the group, are aluminosilicates. Nickel–Strunz classification,09. F and 09. G,04. A, an introduction to the rock-forming minerals. Wise, W. S. Zussman, J. Rock-forming minerals, P.982 pp. Hurlbut, Cornelius S. Danas Manual of Mineralogy. Mindat. org, Dana classification Webmineral, Danas New Silicate Classification Media related to Silicates at Wikimedia Commons
Nesosilicates
–
Copper silicate mineral
chrysocolla
Nesosilicates
–
Nesosilicate specimens at the Museum of Geology in South Dakota
Nesosilicates
–
Kyanite crystals (unknown scale)
Nesosilicates
–
Sorosilicate exhibit at Museum of Geology in South Dakota
2.
Chemical formula
–
These are limited to a single typographic line of symbols, which may include subscripts and superscripts. A chemical formula is not a name, and it contains no words. Although a chemical formula may imply certain simple chemical structures, it is not the same as a full chemical structural formula. Chemical formulas can fully specify the structure of only the simplest of molecules and chemical substances, the simplest types of chemical formulas are called empirical formulas, which use letters and numbers indicating the numerical proportions of atoms of each type. Molecular formulas indicate the numbers of each type of atom in a molecule. For example, the formula for glucose is CH2O, while its molecular formula is C6H12O6. This is possible if the relevant bonding is easy to show in one dimension, an example is the condensed molecular/chemical formula for ethanol, which is CH3-CH2-OH or CH3CH2OH. For reasons of structural complexity, there is no condensed chemical formula that specifies glucose, chemical formulas may be used in chemical equations to describe chemical reactions and other chemical transformations, such as the dissolving of ionic compounds into solution. A chemical formula identifies each constituent element by its chemical symbol, in empirical formulas, these proportions begin with a key element and then assign numbers of atoms of the other elements in the compound, as ratios to the key element. For molecular compounds, these numbers can all be expressed as whole numbers. For example, the formula of ethanol may be written C2H6O because the molecules of ethanol all contain two carbon atoms, six hydrogen atoms, and one oxygen atom. Some types of compounds, however, cannot be written with entirely whole-number empirical formulas. An example is boron carbide, whose formula of CBn is a variable non-whole number ratio with n ranging from over 4 to more than 6.5. When the chemical compound of the consists of simple molecules. These types of formulas are known as molecular formulas and condensed formulas. A molecular formula enumerates the number of atoms to reflect those in the molecule, so that the formula for glucose is C6H12O6 rather than the glucose empirical formula. However, except for very simple substances, molecular chemical formulas lack needed structural information, for simple molecules, a condensed formula is a type of chemical formula that may fully imply a correct structural formula. For example, ethanol may be represented by the chemical formula CH3CH2OH
Chemical formula
–
Al 2 (SO 4) 3
3.
Crystal system
–
In crystallography, the terms crystal system, crystal family and lattice system each refer to one of several classes of space groups, lattices, point groups or crystals. Informally, two crystals are in the crystal system if they have similar symmetries, though there are many exceptions to this. Space groups and crystals are divided into seven crystal systems according to their point groups, five of the crystal systems are essentially the same as five of the lattice systems, but the hexagonal and trigonal crystal systems differ from the hexagonal and rhombohedral lattice systems. The six crystal families are formed by combining the hexagonal and trigonal crystal systems into one hexagonal family, a lattice system is a class of lattices with the same set of lattice point groups, which are subgroups of the arithmetic crystal classes. The 14 Bravais lattices are grouped into seven lattice systems, triclinic, monoclinic, orthorhombic, tetragonal, rhombohedral, hexagonal, in a crystal system, a set of point groups and their corresponding space groups are assigned to a lattice system. Of the 32 point groups that exist in three dimensions, most are assigned to only one system, in which case both the crystal and lattice systems have the same name. However, five point groups are assigned to two systems, rhombohedral and hexagonal, because both exhibit threefold rotational symmetry. These point groups are assigned to the crystal system. In total there are seven crystal systems, triclinic, monoclinic, orthorhombic, tetragonal, trigonal, hexagonal, a crystal family is determined by lattices and point groups. It is formed by combining crystal systems which have space groups assigned to a lattice system. In three dimensions, the families and systems are identical, except the hexagonal and trigonal crystal systems. In total there are six families, triclinic, monoclinic, orthorhombic, tetragonal, hexagonal. Spaces with less than three dimensions have the number of crystal systems, crystal families and lattice systems. In one-dimensional space, there is one crystal system, in 2D space, there are four crystal systems, oblique, rectangular, square and hexagonal. The relation between three-dimensional crystal families, crystal systems and lattice systems is shown in the table, Note. To avoid confusion of terminology, the term trigonal lattice is not used, if the original structure and inverted structure are identical, then the structure is centrosymmetric. Still, even for non-centrosymmetric case, inverted structure in some cases can be rotated to align with the original structure and this is the case of non-centrosymmetric achiral structure. If the inverted structure cannot be rotated to align with the structure, then the structure is chiral
Crystal system
–
Hexagonal
hanksite crystal, with three-fold c-axis symmetry
Crystal system
–
The
diamond crystal structure belongs to the face-centered
cubic lattice, with a repeated 2-atom pattern.
4.
Orthorhombic
–
In crystallography, the orthorhombic crystal system is one of the 7 crystal systems. All three bases intersect at 90° angles, so the three lattice vectors remain mutually orthogonal, there are two orthorhombic Bravais lattices in two dimensions, Primitive rectangular and centered rectangular. The primitive rectangular lattice can also be described by a centered rhombic unit cell, there are four orthorhombic Bravais lattices, primitive orthorhombic, base-centered orthorhombic, body-centered orthorhombic, and face-centered orthorhombic. In this axis setting, the primitive and base-centered lattices interchange in centering type, crystal structure Overview of all space groups Hurlbut, Cornelius S. Klein, Cornelis. Hahn, Theo, ed. International Tables for Crystallography, Volume A, Space Group Symmetry
Orthorhombic
–
Unit cell
5.
Crystal class
–
For a periodic crystal, the group must also be consistent with maintenance of the three-dimensional translational symmetry that defines crystallinity. The macroscopic properties of a crystal would look exactly the same before, in the classification of crystals, each point group is also known as a crystal class. There are infinitely many three-dimensional point groups, however, the crystallographic restriction of the infinite families of general point groups results in there being only 32 crystallographic point groups. These 32 point groups are one-and-the same as the 32 types of morphological crystalline symmetries derived in 1830 by Johann Friedrich Christian Hessel from a consideration of observed crystal forms, the point groups are denoted by their component symmetries. There are a few standard notations used by crystallographers, mineralogists, for the correspondence of the two systems below, see crystal system. In Schoenflies notation, point groups are denoted by a symbol with a subscript. The symbols used in crystallography mean the following, Cn indicates that the group has a rotation axis. Cnh is Cn with the addition of a plane perpendicular to the axis of rotation. Cnv is Cn with the addition of n mirror planes parallel to the axis of rotation, s2n denotes a group that contains only a 2n-fold rotation-reflection axis. Dn indicates that the group has a rotation axis plus n twofold axes perpendicular to that axis. Dnh has, in addition, a plane perpendicular to the n-fold axis. Dnd has, in addition to the elements of Dn, mirror planes parallel to the n-fold axis, the letter T indicates that the group has the symmetry of a tetrahedron. Td includes improper rotation operations, T excludes improper rotation operations, the letter O indicates that the group has the symmetry of an octahedron, with or without improper operations. Due to the crystallographic restriction theorem, n =1,2,3,4, d4d and D6d are actually forbidden because they contain improper rotations with n=8 and 12 respectively. The 27 point groups in the table plus T, Td, Th, O, an abbreviated form of the Hermann–Mauguin notation commonly used for space groups also serves to describe crystallographic point groups. Group names are Molecular symmetry Point group Space group Point groups in three dimensions Crystal system Point-group symbols in International Tables for Crystallography,12.1, pp. 818-820 Names and symbols of the 32 crystal classes in International Tables for Crystallography. 10.1, p.794 Pictorial overview of the 32 groups Point Groups - Flow Chart Inorganic Chemistry Group Theory Practice Problems
Crystal class
–
Class
6.
H-M symbol
–
In geometry, Hermann–Mauguin notation is used to represent the symmetry elements in point groups, plane groups and space groups. It is named after the German crystallographer Carl Hermann and the French mineralogist Charles-Victor Mauguin and this notation is sometimes called international notation, because it was adopted as standard by the International Tables For Crystallography since their first edition in 1935. Rotation axes are denoted by a number n —1,2,3,4,5,6,7,8, for improper rotations, Hermann–Mauguin symbols show rotoinversion axes, unlike Schoenflies and Shubnikov notations, where the preference is given to rotation-reflection axes. The rotoinversion axes are represented by the number with a macron. The symbol for a plane is m. The direction of the plane is defined as the direction of perpendicular to the face. Hermann–Mauguin symbols show symmetrically non-equivalent axes and planes, the direction of a symmetry element is represented by its position in the Hermann–Mauguin symbol. If a rotation axis n and a mirror plane m have the same direction, if two or more axes have the same direction, the axis with higher symmetry is shown. Higher symmetry means that the axis generates a pattern with more points, for example, rotation axes 3,4,5,6,7,8 generate 3-, 4-, 5-, 6-, 7-, 8-point patterns, respectively. Improper rotation axes 3,4,5,6,7,8 generate 6-, 4-, 10-, 6-, 14-, 8-point patterns, if both, the rotation and rotoinversion axes satisfy the previous rule, the rotation axis should be chosen. For example, 3/m combination is equivalent to 6, since 6 generates 6 points, and 3 generates only 3,6 should be written instead of 3/m. Analogously, in the case when both 3 and 3 axes are present,3 should be written, however we write 4/m, not 4/m, because both 4 and 4 generate four points. Finally, the Hermann–Mauguin symbol depends on the type of the group and these groups may contain only two-fold axes, mirror planes, and inversion center. These are the point groups 1 and 1,2, m, and 2/m, and 222, 2/m2/m2/m. If the symbol contains three positions, then they denote symmetry elements in the x, y, z direction, First position — primary direction — z direction, assigned to the higher-order axis. Second position — symmetrically equivalent secondary directions, which are perpendicular to the z-axis and these can be 2, m, or 2/m. Third position — symmetrically equivalent tertiary directions, passing between secondary directions and these can be 2, m, or 2/m. These are the crystallographic groups 3,32, 3m,3, and 32/m,4,422, 4mm,4, 42m, 4/m, and 4/m2/m2/m, and 6,622, 6mm,6, 6m2, 6/m, and 6/m2/m2/m
H-M symbol
–
Contents
7.
Space group
–
In mathematics, physics and chemistry, a space group is the symmetry group of a configuration in space, usually in three dimensions. In three dimensions, there are 219 distinct types, or 230 if chiral copies are considered distinct, Space groups are also studied in dimensions other than 3 where they are sometimes called Bieberbach groups, and are discrete cocompact groups of isometries of an oriented Euclidean space. In crystallography, space groups are called the crystallographic or Fedorov groups. A definitive source regarding 3-dimensional space groups is the International Tables for Crystallography, in 1879 Leonhard Sohncke listed the 65 space groups whose elements preserve the orientation. More accurately, he listed 66 groups, but Fedorov and Schönflies both noticed that two of them were really the same, the space groups in 3 dimensions were first enumerated by Fedorov, and shortly afterwards were independently enumerated by Schönflies. The correct list of 230 space groups was found by 1892 during correspondence between Fedorov and Schönflies, burckhardt describes the history of the discovery of the space groups in detail. The space groups in three dimensions are made from combinations of the 32 crystallographic point groups with the 14 Bravais lattices, the combination of all these symmetry operations results in a total of 230 different space groups describing all possible crystal symmetries. The elements of the space group fixing a point of space are rotations, reflections, the identity element, the translations form a normal abelian subgroup of rank 3, called the Bravais lattice. There are 14 possible types of Bravais lattice, the quotient of the space group by the Bravais lattice is a finite group which is one of the 32 possible point groups. Translation is defined as the moves from one point to another point. A glide plane is a reflection in a plane, followed by a parallel with that plane. This is noted by a, b or c, depending on which axis the glide is along. There is also the n glide, which is a glide along the half of a diagonal of a face, and the d glide, the latter is called the diamond glide plane as it features in the diamond structure. In 17 space groups, due to the centering of the cell, the glides occur in two directions simultaneously, i. e. the same glide plane can be called b or c, a or b. For example, group Abm2 could be also called Acm2, group Ccca could be called Cccb, in 1992, it was suggested to use symbol e for such planes. The symbols for five groups have been modified, A screw axis is a rotation about an axis. These are noted by a number, n, to describe the degree of rotation, the degree of translation is then added as a subscript showing how far along the axis the translation is, as a portion of the parallel lattice vector. So,21 is a rotation followed by a translation of 1/2 of the lattice vector
Space group
–
The space group of hexagonal H 2 O ice is P6 3 / mmc. The first m indicates the mirror plane perpendicular to the c-axis (a), the second m indicates the mirror planes parallel to the c-axis (b) and the c indicates the glide planes (b) and (c). The black boxes outline the unit cell.
8.
Crystal structure
–
In crystallography, crystal structure is a description of the ordered arrangement of atoms, ions or molecules in a crystalline material. Ordered structures occur from the nature of the constituent particles to form symmetric patterns that repeat along the principal directions of three-dimensional space in matter. The smallest group of particles in the material that constitutes the pattern is the unit cell of the structure. The unit cell completely defines the symmetry and structure of the crystal lattice. The repeating patterns are said to be located at the points of the Bravais lattice, the lengths of the principal axes, or edges, of the unit cell and the angles between them are the lattice constants, also called lattice parameters. The symmetry properties of the crystal are described by the concept of space groups, all possible symmetric arrangements of particles in three-dimensional space may be described by the 230 space groups. The crystal structure and symmetry play a role in determining many physical properties, such as cleavage, electronic band structure. The crystal structure of a material can be described in terms of its unit cell, the unit cell is a box containing one or more atoms arranged in three dimensions. The unit cells stacked in three-dimensional space describe the arrangement of atoms of the crystal. Commonly, atomic positions are represented in terms of fractional coordinates, the atom positions within the unit cell can be calculated through application of symmetry operations to the asymmetric unit. The asymmetric unit refers to the smallest possible occupation of space within the unit cell and this does not, however imply that the entirety of the asymmetric unit must lie within the boundaries of the unit cell. Symmetric transformations of atom positions are calculated from the group of the crystal structure. Vectors and planes in a lattice are described by the three-value Miller index notation. It uses the indices ℓ, m, and n as directional parameters, which are separated by 90°, by definition, the syntax denotes a plane that intercepts the three points a1/ℓ, a2/m, and a3/n, or some multiple thereof. That is, the Miller indices are proportional to the inverses of the intercepts of the plane with the unit cell, if one or more of the indices is zero, it means that the planes do not intersect that axis. A plane containing a coordinate axis is translated so that it no longer contains that axis before its Miller indices are determined, the Miller indices for a plane are integers with no common factors. Negative indices are indicated with horizontal bars, as in, in an orthogonal coordinate system for a cubic cell, the Miller indices of a plane are the Cartesian components of a vector normal to the plane. Likewise, the planes are geometric planes linking nodes
Crystal structure
–
Quartz is one of the several thermodynamically stable
crystalline forms of
silica, SiO 2. The most important forms of silica include:
α-quartz,
β-quartz,
tridymite,
cristobalite,
coesite, and
stishovite.
Crystal structure
9.
Crystal habit
–
In mineralogy, crystal habit is the characteristic external shape of an individual crystal or crystal group. A single crystals habit is a description of its shape and its crystallographic forms. Recognizing the habit may help in identifying a mineral, when the faces are well-developed due to uncrowded growth a crystal is called euhedral, one with partially developed faces is subhedral, and one with undeveloped crystal faces is called anhedral. The long axis of a quartz crystal typically has a six-sided prismatic habit with parallel opposite faces. Aggregates can be formed of individual crystals with euhedral to anhedral grains, the arrangement of crystals within the aggregate can be characteristic of certain minerals. For example, minerals used for asbestos insulation often grow in a fibrous habit, the terms used by mineralogists to report crystal habits describe the typical appearance of an ideal mineral. Recognizing the habit can aid in identification as some habits are characteristic, most minerals, however, do not display ideal habits due to conditions during crystallization. Minerals belonging to the crystal system do not necessarily exhibit the same habit. Some habits of a mineral are unique to its variety and locality, For example, while most sapphires form elongate barrel-shaped crystals, ordinarily, the latter habit is seen only in ruby. Sapphire and ruby are both varieties of the mineral, corundum. Some minerals may replace other existing minerals while preserving the originals habit, a classic example is tigers eye quartz, crocidolite asbestos replaced by silica. While quartz typically forms prismatic crystals, in tigers eye the original fibrous habit of crocidolite is preserved, the names of crystal habits are derived from, Predominant crystal faces. Abnormal grain growth Grain growth Crystallization
Crystal habit
–
Pyrite sun (or dollar) in laminated shale matrix. Between tightly spaced layers of shale, the aggregate was forced to grow in a laterally compressed, radiating manner. Under normal conditions, pyrite would form cubes or pyritohedrons.
Crystal habit
–
Goethite replacing
pyrite cubes
Crystal habit
–
Acicular
Crystal habit
–
Amygdaloidal
10.
Crystal twinning
–
Crystal twinning occurs when two separate crystals share some of the same crystal lattice points in a symmetrical manner. The result is an intergrowth of two separate crystals in a variety of specific configurations, a twin boundary or composition surface separates the two crystals. Crystallographers classify twinned crystals by a number of twin laws and these twin laws are specific to the crystal system. The type of twinning can be a tool in mineral identification. Twinning can often be a problem in X-ray crystallography, as a crystal does not produce a simple diffraction pattern. Simple twinned crystals may be contact twins or penetration twins, contact twins share a single composition surface often appearing as mirror images across the boundary. Plagioclase, quartz, gypsum, and spinel often exhibit contact twinning, merohedral twinning occurs when the lattices of the contact twins superimpose in three dimensions, such as by relative rotation of one twin from the other. In penetration twins the individual crystals have the appearance of passing through each other in a symmetrical manner, orthoclase, staurolite, pyrite, and fluorite often show penetration twinning. If several twin crystal parts are aligned by the same twin law they are referred to as multiple or repeated twins, if these multiple twins are aligned in parallel they are called polysynthetic twins. When the multiple twins are not parallel they are cyclic twins, albite, calcite, and pyrite often show polysynthetic twinning. Closely spaced polysynthetic twinning is often observed as striations or fine lines on the crystal face. Rutile, aragonite, cerussite, and chrysoberyl often exhibit cyclic twinning, 2-normal twin, -when the twin plane and compositional plane lies noramally. 3-complex twin, -combination of parallel twinning and normal twinning on one compositional plane, there are three modes of formation of twinned crystals. Growth twins are the result of an interruption or change in the lattice during formation or growth due to a possible deformation from a larger substituting ion, deformation or gliding twins are the result of stress on the crystal after the crystal has formed. If a FCC metal like aluminum experiences extreme stresses, it will experience twinning as seen in the case of explosions, deformation twinning is a common result of regional metamorphism. Crystals that grow adjacent to each other may be aligned to resemble twinning and this parallel growth simply reduces system energy and is not twinning. Twin boundaries occur when two crystals of the same type intergrow, so only a slight misorientation exists between them. It is a highly symmetrical interface, often with one crystal the mirror image of the other, also and this is also a much lower-energy interface than the grain boundaries that form when crystals of arbitrary orientation grow together
Crystal twinning
–
Quartz - Japan twin
Crystal twinning
–
Diagram of twinned crystals of
Albite. On the more perfect cleavage, which is parallel to the
basal plane (P), is a system of fine striations, parallel to the second cleavage (M).
Crystal twinning
–
Twinned pyrite crystal group
Crystal twinning
–
Galvanized surface with macroscopic crystalline features. Twin boundaries are visible as striations within each
crystallite, most prominently in the bottom-left and top-right.
11.
Cleavage (crystal)
–
Cleavage, in mineralogy, is the tendency of crystalline materials to split along definite crystallographic structural planes. Cleavage forms parallel to planes, Basal or pinacoidal cleavage occurs when there is only one cleavage plane. Mica also has basal cleavage, this is why mica can be peeled into thin sheets, cubic cleavage occurs on when there are three cleavage planes intersecting at 90 degrees. Halite has cubic cleavage, and therefore, when halite crystals are broken, octahedral cleavage occurs when there are four cleavage planes in a crystal. Octahedral cleavage is common for semiconductors, rhombohedral cleavage occurs when there are three cleavage planes intersecting at angles that are not 90 degrees. Prismatic cleavage occurs when there are two planes in a crystal. Dodecahedral cleavage occurs when there are six cleavage planes in a crystal, crystal parting occurs when minerals break along planes of structural weakness due to external stress or along twin composition planes. Parting breaks are very similar in appearance to cleavage, but only due to stress. Examples include magnetite which shows octahedral parting, the parting of corundum. Cleavage is a property traditionally used in mineral identification, both in hand specimen and microscopic examination of rock and mineral studies. As an example, the angles between the cleavage planes for the pyroxenes and the amphiboles are diagnostic. Crystal cleavage is of importance in the electronics industry and in the cutting of gemstones. Precious stones are generally cleaved by impact, as in diamond cutting, synthetic single crystals of semiconductor materials are generally sold as thin wafers which are much easier to cleave. Elemental semiconductors are diamond cubic, a group for which octahedral cleavage is observed. This means that some orientations of wafer allow near-perfect rectangles to be cleaved, most other commercial semiconductors can be made in the related zinc blende structure, with similar cleavage planes. Cleavage Mineral galleries, Mineral properties – Cleavage
Cleavage (crystal)
–
Green
fluorite with prominent cleavage.
Cleavage (crystal)
–
Biotite with basal cleavage.
12.
Fracture (mineralogy)
–
In the field of mineralogy, fracture is the texture and shape of a rocks surface formed when a mineral is fractured. Minerals often have a highly distinctive fracture, making it a feature used in their identification. Fracture differs from cleavage in that the latter involves clean splitting along the planes of the minerals crystal structure. All minerals exhibit fracture, but when very strong cleavage is present, conchoidal fracture breakage that resembles the concentric ripples of a mussel shell. It often occurs in amorphous or fine-grained minerals such as flint, opal or obsidian, subconchoidal fracture is similar to conchoidal fracture, but with less significant curvature. Earthy fracture is reminiscent of freshly broken soil and it is frequently seen in relatively soft, loosely bound minerals, such as limonite, kaolinite and aluminite. Hackly fracture is jagged, sharp and not even and it occurs when metals are torn, and so is often encountered in native metals such as copper and silver. Splintery fracture comprises sharp elongated points and it is particularly seen in fibrous minerals such as chrysotile, but may also occur in non-fibrous minerals such as kyanite. Uneven fracture is a surface or one with random irregularities. It occurs in a range of minerals including arsenopyrite, pyrite and magnetite. Rudolf Duda and Lubos Rejl, Minerals of the World http, //www. galleries. com/minerals/property/fracture. htm
Fracture (mineralogy)
–
Obsidian
Fracture (mineralogy)
–
Limonite
Fracture (mineralogy)
–
Native copper
Fracture (mineralogy)
–
Chrysotile
13.
Mohs scale of mineral hardness
–
The Mohs scale of mineral hardness is a qualitative ordinal scale characterizing scratch resistance of various minerals through the ability of harder material to scratch softer material. Created in 1812 by German geologist and mineralogist Friedrich Mohs, it is one of several definitions of hardness in materials science, while greatly facilitating the identification of minerals in the field, the Mohs scale does not show how well hard materials perform in an industrial setting. Despite its lack of precision, the Mohs scale is highly relevant for field geologists, the Mohs scale hardness of minerals can be commonly found in reference sheets. Reference materials may be expected to have a uniform Mohs hardness, the Mohs scale of mineral hardness is based on the ability of one natural sample of mineral to scratch another mineral visibly. The samples of matter used by Mohs are all different minerals, Minerals are pure substances found in nature. Rocks are made up of one or more minerals, as the hardest known naturally occurring substance when the scale was designed, diamonds are at the top of the scale. The hardness of a material is measured against the scale by finding the hardest material that the material can scratch. For example, if material is scratched by apatite but not by fluorite. Scratching a material for the purposes of the Mohs scale means creating non-elastic dislocations visible to the naked eye, frequently, materials that are lower on the Mohs scale can create microscopic, non-elastic dislocations on materials that have a higher Mohs number. The Mohs scale is an ordinal scale. For example, corundum is twice as hard as topaz, the table below shows the comparison with the absolute hardness measured by a sclerometer, with pictorial examples. On the Mohs scale, a streak plate has a hardness of 7.0, using these ordinary materials of known hardness can be a simple way to approximate the position of a mineral on the scale. The table below incorporates additional substances that may fall between levels, Comparison between Hardness and Hardness, Mohs hardness of elements is taken from G. V, samsonov in Handbook of the physicochemical properties of the elements, IFI-Plenum, New York, USA,1968. The Hardness of Minerals and Rocks
Mohs scale of mineral hardness
Mohs scale of mineral hardness
Mohs scale of mineral hardness
Mohs scale of mineral hardness
14.
Lustre (mineralogy)
–
Lustre or luster is the way light interacts with the surface of a crystal, rock, or mineral. The word traces its origins back to the latin lux, meaning light, a range of terms are used to describe lustre, such as earthy, metallic, greasy, and silky. Similarly, the term refers to a glassy lustre. A list of terms is given below. Lustre varies over a continuum, and so there are no rigid boundaries between the different types of lustre. The terms are frequently combined to describe types of lustre. Some minerals exhibit unusual optical phenomena, such as asterism or chatoyancy, a list of such phenomena is given below. Adamantine minerals possess a superlative lustre, which is most notably seen in diamond, such minerals are transparent or translucent, and have a high refractive index. Minerals with an adamantine lustre are uncommon, with examples being cerussite. Minerals with a degree of lustre are referred to as subadamantine, with some examples being garnet. Dull minerals exhibit little to no lustre, due to coarse granulations which scatter light in all directions, a distinction is sometimes drawn between dull minerals and earthy minerals, with the latter being coarser, and having even less lustre. Greasy minerals resemble fat or grease, a greasy lustre often occurs in minerals containing a great abundance of microscopic inclusions, with examples including opal and cordierite. Many minerals with a greasy lustre also feel greasy to the touch, metallic minerals have the lustre of polished metal, and with ideal surfaces will work as a reflective surface. Examples include galena, pyrite and magnetite, pearly minerals consist of thin transparent co-planar sheets. Light reflecting from these layers give them a lustre reminiscent of pearls, such minerals possess perfect cleavage, with examples including muscovite and stilbite. Resinous minerals have the appearance of resin, chewing gum or plastic, a principal example is amber, which is a form of fossilized resin. Silky minerals have an arrangement of extremely fine fibres, giving them a lustre reminiscent of silk. Examples include asbestos, ulexite and the satin spar variety of gypsum, a fibrous lustre is similar, but has a coarser texture
Lustre (mineralogy)
–
Cut diamonds.
Lustre (mineralogy)
–
Kaolinite
Lustre (mineralogy)
–
Moss
opal
Lustre (mineralogy)
–
Pyrite
15.
Streak (mineralogy)
–
The streak of a mineral is the color of the powder produced when it is dragged across an un-weathered surface. If no streak seems to be made, the streak is said to be white or colorless. Streak is particularly important as a diagnostic for opaque and colored materials and it is less useful for silicate minerals, most of which have a white streak or are too hard to powder easily. The apparent color of a mineral can vary widely because of impurities or a disturbed macroscopic crystal structure. Small amounts of an impurity that strongly absorbs a particular wavelength can radically change the wavelengths of light that are reflected by the specimen, and thus change the apparent color. However, when the specimen is dragged to produce a streak, it is broken into randomly oriented microscopic crystals, the surface across which the mineral is dragged is called a streak plate, and is generally made of unglazed porcelain tile. In the absence of a plate, the unglazed underside of a porcelain bowl or vase or the back of a glazed tile will work. Sometimes a streak is more easily or accurately described by comparing it with the streak made by another streak plate. Because the trail left behind results from the mineral being crushed into powder, in case of harder minerals, the color of the powder can be determined by filing or crushing with a hammer a small sample, which is then usually rubbed on a streak plate. Most minerals that are harder have a white streak. Some minerals leave a similar to their natural color, such as cinnabar. Other minerals leave surprising colors, such as fluorite, which always has a streak, although it can appear in purple, blue, yellow. Hematite, which is black in appearance, leaves a red streak which accounts for its name, galena, which can be similar in appearance to hematite, is easily distinguished by its gray streak. Hamilton, W. R. Cambridge Guide to Minerals, Rocks, the Encyclopedia of Gemstones and Minerals. New York, Facts on File. p.251, physical Characteristics of Minerals, at Introduction to Mineralogy by Andrea Bangert What is Streak
Streak (mineralogy)
–
Streak plates with
pyrite (left) and
rhodochrosite (right)
16.
Transparency and translucency
–
In the field of optics, transparency is the physical property of allowing light to pass through the material without being scattered. On a macroscopic scale, the photons can be said to follow Snells Law, in other words, a translucent medium allows the transport of light while a transparent medium not only allows the transport of light but allows for image formation. The opposite property of translucency is opacity, transparent materials appear clear, with the overall appearance of one color, or any combination leading up to a brilliant spectrum of every color. When light encounters a material, it can interact with it in different ways. These interactions depend on the wavelength of the light and the nature of the material, photons interact with an object by some combination of reflection, absorption and transmission. Some materials, such as glass and clean water, transmit much of the light that falls on them and reflect little of it. Many liquids and aqueous solutions are highly transparent, absence of structural defects and molecular structure of most liquids are mostly responsible for excellent optical transmission. Materials which do not transmit light are called opaque, many such substances have a chemical composition which includes what are referred to as absorption centers. Many substances are selective in their absorption of light frequencies. They absorb certain portions of the spectrum while reflecting others. The frequencies of the spectrum which are not absorbed are either reflected or transmitted for our physical observation and this is what gives rise to color. The attenuation of light of all frequencies and wavelengths is due to the mechanisms of absorption. Transparency can provide almost perfect camouflage for animals able to achieve it and this is easier in dimly-lit or turbid seawater than in good illumination. Many marine animals such as jellyfish are highly transparent, at the atomic or molecular level, physical absorption in the infrared portion of the spectrum depends on the frequencies of atomic or molecular vibrations or chemical bonds, and on selection rules. Nitrogen and oxygen are not greenhouse gases because there is no absorption because there is no molecular dipole moment. With regard to the scattering of light, the most critical factor is the scale of any or all of these structural features relative to the wavelength of the light being scattered. Primary material considerations include, Crystalline structure, whether or not the atoms or molecules exhibit the long-range order evidenced in crystalline solids, glassy structure, scattering centers include fluctuations in density or composition. Microstructure, scattering centers include internal surfaces such as boundaries, crystallographic defects
Transparency and translucency
–
Dichroic filters are created using optically transparent materials.
Transparency and translucency
–
Translucency of a material being used to highlight the structure of a photographic subject
Transparency and translucency
–
Meiningen Catholic Church, 20th century glass
Transparency and translucency
–
A laser beam bouncing down an
acrylic rod, illustrating the total internal reflection of light in a multimode optical fiber
17.
Specific gravity
–
This page is about the measurement using water as a reference. For a general use of gravity, see relative density. See intensive property for the property implied by specific, Apparent specific gravity is the ratio of the weight of a volume of the substance to the weight of an equal volume of the reference substance. The reference substance is always water at its densest for liquids. Nonetheless, the temperature and pressure must be specified for both the sample and the reference, pressure is nearly always 1 atm. Temperatures for both sample and reference vary from industry to industry, in British beer brewing, the practice for specific gravity as specified above is to multiply it by 1000. Being a ratio of densities, specific gravity is a dimensionless quantity, Specific gravity varies with temperature and pressure, reference and sample must be compared at the same temperature and pressure or be corrected to a standard reference temperature and pressure. Substances with a gravity of 1 are neutrally buoyant in water. Those with SG greater than 1 are denser than water and will, disregarding surface tension effects and those with an SG less than 1 are less dense than water and will float on it. In scientific work, the relationship of mass to volume is expressed directly in terms of the density of the substance under study. It is in industry where specific gravity finds wide application, often for historical reasons. True specific gravity can be expressed mathematically as, S G true = ρ sample ρ H2 O where ρ sample is the density of the sample, the density of water varies with temperature and pressure as does the density of the sample. So it is necessary to specify the temperatures and pressures at which the densities or weights were determined and it is nearly always the case that measurements are made at 1 nominal atmosphere. For true specific gravity calculations, air pressure must be considered, temperatures are specified by the notation with T s representing the temperature at which the samples density was determined and T r the temperature at which the reference density is specified. For example, SG would be understood to mean that the density of the sample was determined at 20°C and of the water at 4°C. Taking into account different sample and reference temperatures, we note that, while S G H2 O =1.000000, it is also the case that S G H2 O =0.998203 /0.999840 =0.998363. Here, temperature is being specified using the current ITS-90 scale, on the previous IPTS-68 scale, the densities at 20 °C and 4 °C are 0.9982071 and 0.9999720 respectively, resulting in an SG value for water of 0.9982343. For example, in the industry, the Plato table lists sucrose concentration by weight against true SG
Specific gravity
–
Testing specific gravity of fuel.
18.
Refractive index
–
In optics, the refractive index or index of refraction n of a material is a dimensionless number that describes how light propagates through that medium. It is defined as n = c v, where c is the speed of light in vacuum, for example, the refractive index of water is 1.333, meaning that light travels 1.333 times faster in a vacuum than it does in water. The refractive index determines how light is bent, or refracted. The refractive indices also determine the amount of light that is reflected when reaching the interface, as well as the angle for total internal reflection. This implies that vacuum has a index of 1. The refractive index varies with the wavelength of light and this is called dispersion and causes the splitting of white light into its constituent colors in prisms and rainbows, and chromatic aberration in lenses. Light propagation in absorbing materials can be described using a refractive index. The imaginary part then handles the attenuation, while the real part accounts for refraction, the concept of refractive index is widely used within the full electromagnetic spectrum, from X-rays to radio waves. It can also be used with wave phenomena such as sound, in this case the speed of sound is used instead of that of light and a reference medium other than vacuum must be chosen. Thomas Young was presumably the person who first used, and invented, at the same time he changed this value of refractive power into a single number, instead of the traditional ratio of two numbers. The ratio had the disadvantage of different appearances, newton, who called it the proportion of the sines of incidence and refraction, wrote it as a ratio of two numbers, like 529 to 396. Hauksbee, who called it the ratio of refraction, wrote it as a ratio with a fixed numerator, hutton wrote it as a ratio with a fixed denominator, like 1.3358 to 1. Young did not use a symbol for the index of refraction, in the next years, others started using different symbols, n, m, and µ. For visible light most transparent media have refractive indices between 1 and 2, a few examples are given in the adjacent table. These values are measured at the yellow doublet D-line of sodium, with a wavelength of 589 nanometers, gases at atmospheric pressure have refractive indices close to 1 because of their low density. Almost all solids and liquids have refractive indices above 1.3, aerogel is a very low density solid that can be produced with refractive index in the range from 1.002 to 1.265. Moissanite lies at the end of the range with a refractive index as high as 2.65. Most plastics have refractive indices in the range from 1.3 to 1.7, for infrared light refractive indices can be considerably higher
Refractive index
–
Thomas Young coined the term index of refraction.
Refractive index
–
A
ray of light being
refracted in a plastic block.
Refractive index
–
Diamonds have a very high refractive index of 2.42.
Refractive index
–
A
split-ring resonator array arranged to produce a negative index of refraction for
microwaves.
19.
Birefringence
–
Birefringence is the optical property of a material having a refractive index that depends on the polarization and propagation direction of light. These optically anisotropic materials are said to be birefringent, the birefringence is often quantified as the maximum difference between refractive indices exhibited by the material. Crystals with non-cubic crystal structures are often birefringent, as are plastics under mechanical stress and this effect was first described by the Danish scientist Rasmus Bartholin in 1669, who observed it in calcite, a crystal having one of the strongest birefringences. A mathematical description of wave propagation in a birefringent medium is presented below, following is a qualitative explanation of the phenomenon. Thus rotating the material around this axis does not change its optical behavior and this special direction is known as the optic axis of the material. Light whose polarization is perpendicular to the axis is governed by a refractive index no. Light whose polarization is in the direction of the optic axis sees an optical index ne, for any ray direction there is a linear polarization direction perpendicular to the optic axis, and this is called an ordinary ray. The magnitude of the difference is quantified by the birefringence, Δ n = n e − n o, the propagation of the ordinary ray is simply described by no as if there were no birefringence involved. However the extraordinary ray, as its name suggests, propagates unlike any wave in an optical material. Its refraction at a surface can be using the effective refractive index. However it is in fact an inhomogeneous wave whose power flow is not exactly in the direction of the wave vector and this causes an additional shift in that beam, even when launched at normal incidence, as is popularly observed using a crystal of calcite as photographed above. Rotating the calcite crystal will cause one of the two images, that of the ray, to rotate slightly around that of the ordinary ray. When the light propagates either along or orthogonal to the optic axis, in the first case, both polarizations see the same effective refractive index, so there is no extraordinary ray. In the second case the extraordinary ray propagates at a different phase velocity but is not an inhomogeneous wave, for instance, a quarter-wave plate is commonly used to create circular polarization from a linearly polarized source. The case of so-called biaxial crystals is substantially more complex and these are characterized by three refractive indices corresponding to three principal axes of the crystal. For most ray directions, both polarizations would be classified as extraordinary rays but with different effective refractive indices, being extraordinary waves, however, the direction of power flow is not identical to the direction of the wave vector in either case. The two refractive indices can be determined using the index ellipsoids for given directions of the polarization, note that for biaxial crystals the index ellipsoid will not be an ellipsoid of revolution but is described by three unequal principle refractive indices nα, nβ and nγ. Thus there is no axis around which a rotation leaves the optical properties invariant, for this reason, birefringent materials with three distinct refractive indices are called biaxial
Birefringence
–
A
calcite crystal laid upon a graph paper with blue lines showing the double refraction
Birefringence
–
Incoming light in the parallel (s) polarization sees a different effective
index of refraction than light in the perpendicular (p) polarization, and is thus
refracted at a different angle.
Birefringence
–
Urate crystals, with the crystals with their long axis seen as horizontal in this view being parallel to that of a red compensator filter. These appear as yellow, and are thereby of negative birefringence.
Birefringence
–
Color pattern of a plastic box with "frozen in"
mechanical stress placed between two crossed
polarizers.
20.
Pleochroism
–
Pleochroism is an optical phenomenon in which a substance appears to be different colors when observed at different angles, especially with polarized light. Anisotropic crystals will have properties that vary with the direction of light. The polarization of light determines the direction of the electric field and these kinds of crystals have one or two optical axes. If absorption of light varies with the relative to the optical axis in a crystal then pleochroism results. Anisotropic crystals have double refraction of light where light of different polarizations is bent different amounts by the crystal, the components of a divided light beam follow different paths within the mineral and travel at different speeds. When the mineral is observed at some angle, light following some combination of paths and polarizations will be present, at another angle, the light passing through the crystal will be composed of another combination of light paths and polarizations, each with their own color. The light passing through the mineral will therefore have different colors when it is viewed from different angles, tetragonal, trigonal and hexagonal minerals can only show two colors and are called dichroic. Orthorhombic, monoclinic and triclinic crystals can show three and are trichroic, for example, hypersthene, with two optical axes, can have red, yellow or blue appearance when oriented in three different ways in three-dimensional space. Tourmaline is notable for exhibiting strong pleochroism, gems are sometimes cut and set either to display pleochroism or to hide it, depending on the colors and their attractiveness. The pleochroic colours are at their maximum when light is polarized parallel with a crystallographic axis, the axes are designated X, Y and Z. These axes can be determined from the appearance of a crystal in an interference pattern. Where there are two axes, the acute bisection of the axes gives Z for positive minerals and X for negative minerals. Perpendicular to these is the Y axis, the colour is measured with the polarization parallel to each direction. An absorption formula records the amount of parallel to each axis in the form of X < Y < Z with the left most having the least absorption. Minerals that are very similar often have very different pleochroic color schemes. In such cases, a section of the mineral is used and examined under polarized transmitted light with a petrographic microscope. Another device using this property to identify minerals is the dichroscope
Pleochroism
–
Cordierite
Pleochroism
–
Tourmaline
21.
Dispersion (optics)
–
In optics, dispersion is the phenomenon in which the phase velocity of a wave depends on its frequency. Media having this property may be termed dispersive media. Sometimes the term chromatic dispersion is used for specificity, the most familiar example of dispersion is probably a rainbow, in which dispersion causes the spatial separation of a white light into components of different wavelengths. Most often, chromatic dispersion refers to material dispersion, that is. However, in a waveguide there is also the phenomenon of waveguide dispersion, more generally, waveguide dispersion can occur for waves propagating through any inhomogeneous structure, whether or not the waves are confined to some region. In a waveguide, both types of dispersion will generally be present, although they are not strictly additive, for example, in fiber optics the material and waveguide dispersion can effectively cancel each other out to produce a zero-dispersion wavelength, important for fast fiber-optic communication. Material dispersion can be a desirable or undesirable effect in optical applications, the dispersion of light by glass prisms is used to construct spectrometers and spectroradiometers. Holographic gratings are used, as they allow more accurate discrimination of wavelengths. However, in lenses, dispersion causes chromatic aberration, an effect that may degrade images in microscopes, telescopes. The phase velocity, v, of a wave in a uniform medium is given by v = c n where c is the speed of light in a vacuum. In general, the index is some function of the frequency f of the light, thus n = n, or alternatively. The wavelength dependence of a refractive index is usually quantified by its Abbe number or its coefficients in an empirical formula such as the Cauchy or Sellmeier equations. In particular, for materials, the susceptibility χ that appears in the Kramers–Kronig relations is the electric susceptibility χe = n2 −1. The most commonly seen consequence of dispersion in optics is the separation of light into a color spectrum by a prism. From Snells law it can be seen that the angle of refraction of light in a prism depends on the index of the prism material. For visible light, refraction indices n of most transparent materials decrease with increasing wavelength λ,1 < n < n < n, or alternatively, in this case, the medium is said to have normal dispersion. Whereas, if the index increases with increasing wavelength, the medium is said to have anomalous dispersion, at the interface of such a material with air or vacuum, Snells law predicts that light incident at an angle θ to the normal will be refracted at an angle arcsin. Thus, blue light, with a refractive index, will be bent more strongly than red light
Dispersion (optics)
–
A
compact fluorescent lamp seen through an
Amici prism
Dispersion (optics)
–
In a
dispersive prism, material dispersion (a
wavelength -dependent
refractive index) causes different colors to
refract at different angles, splitting white light into a
rainbow.
22.
Ultraviolet
–
Ultraviolet is an electromagnetic radiation with a wavelength from 10 nm to 400 nm, shorter than that of visible light but longer than X-rays. UV radiation constitutes about 10% of the light output of the Sun. It is also produced by electric arcs and specialized lights, such as lamps, tanning lamps. Consequently, the effects of UV are greater than simple heating effects. Suntan, freckling and sunburn are familiar effects of over-exposure, along with risk of skin cancer. Living things on dry land would be damaged by ultraviolet radiation from the Sun if most of it were not filtered out by the Earths atmosphere. More-energetic, shorter-wavelength extreme UV below 121 nm ionizes air so strongly that it is absorbed before it reaches the ground, Ultraviolet is also responsible for the formation of bone-strengthening vitamin D in most land vertebrates, including humans. The UV spectrum thus has both beneficial and harmful to human health. Ultraviolet rays are invisible to most humans, the lens in a human eye ordinarily filters out UVB frequencies or higher, and humans lack color receptor adaptations for ultraviolet rays. Under some conditions, children and young adults can see ultraviolet down to wavelengths of about 310 nm, near-UV radiation is visible to some insects, mammals, and birds. Small birds have a fourth color receptor for ultraviolet rays, this gives birds true UV vision, reindeer use near-UV radiation to see polar bears, who are poorly visible in regular light because they blend in with the snow. UV also allows mammals to see urine trails, which is helpful for animals to find food in the wild. The males and females of some species look identical to the human eye. Ultraviolet means beyond violet, violet being the color of the highest frequencies of visible light, Ultraviolet has a higher frequency than violet light. He called them oxidizing rays to emphasize chemical reactivity and to them from heat rays. The terms chemical and heat rays were eventually dropped in favour of ultraviolet and infrared radiation, in 1878 the effect of short-wavelength light on sterilizing bacteria was discovered. By 1903 it was known the most effective wavelengths were around 250 nm, in 1960, the effect of ultraviolet radiation on DNA was established. The discovery of the ultraviolet radiation below 200 nm, named vacuum ultraviolet because it is absorbed by air, was made in 1893 by the German physicist Victor Schumann
Ultraviolet
–
(left) Portable ultraviolet lamp. (right) UV light is also produced by
electric arcs.
Arc welders must wear
eye protection to prevent
welder's flash.
Ultraviolet
Ultraviolet
–
Two black light fluorescent tubes, showing use. The longer tube is a F15T8/BLB 18 inch, 15 watt tube, shown in the bottom image in a standard plug-in fluorescent fixture. The shorter is an F8T5/BLB 12 inch, 8 watt tube, used in a portable battery-powered black light sold as a pet urine detector.
Ultraviolet
23.
Fluorescence
–
Fluorescence is the emission of light by a substance that has absorbed light or other electromagnetic radiation. It is a form of luminescence, in most cases, the emitted light has a longer wavelength, and therefore lower energy, than the absorbed radiation. Fluorescent materials cease to glow immediately when the radiation source stops, unlike phosphorescence, Fluorescence also occurs frequently in nature in some minerals and in various biological states in many branches of the animal kingdom. An early observation of fluorescence was described in 1560 by Bernardino de Sahagún and it was derived from the wood of two tree species, Pterocarpus indicus and Eysenhardtia polystachya. The chemical compound responsible for this fluorescence is matlaline, which is the product of one of the flavonoids found in this wood. The name was derived from the fluorite, some examples of which contain traces of divalent europium. In a key experiment he used a prism to isolate ultraviolet radiation from sunlight, the specific frequencies of exciting and emitted light are dependent on the particular system. S0 is called the state of the fluorophore, and S1 is its first excited singlet state. A molecule in S1 can relax by various competing pathways and it can undergo non-radiative relaxation in which the excitation energy is dissipated as heat to the solvent. Excited organic molecules can also relax via conversion to a triplet state, relaxation from S1 can also occur through interaction with a second molecule through fluorescence quenching. Molecular oxygen is an extremely efficient quencher of fluorescence just because of its unusual triplet ground state, in most cases, the emitted light has a longer wavelength, and therefore lower energy, than the absorbed radiation, this phenomenon is known as the Stokes shift. The emitted radiation may also be of the wavelength as the absorbed radiation. Molecules that are excited through light absorption or via a different process can transfer energy to a second sensitized molecule, the fluorescence quantum yield gives the efficiency of the fluorescence process. It is defined as the ratio of the number of photons emitted to the number of photons absorbed, Φ = Number of photons emitted Number of photons absorbed The maximum fluorescence quantum yield is 1.0, each photon absorbed results in a photon emitted. Compounds with quantum yields of 0.10 are still considered quite fluorescent, thus, if the rate of any pathway changes, both the excited state lifetime and the fluorescence quantum yield will be affected. Fluorescence quantum yields are measured by comparison to a standard, the quinine salt quinine sulfate in a sulfuric acid solution is a common fluorescence standard. The fluorescence lifetime refers to the time the molecule stays in its excited state before emitting a photon. This is an instance of exponential decay, various radiative and non-radiative processes can de-populate the excited state
Fluorescence
–
Fluorescent minerals emit visible light when exposed to
ultraviolet light
Fluorescence
–
Lignum nephriticum cup made from the wood of the narra tree (
Pterocarpus indicus), and a flask containing its fluorescent
solution
Fluorescence
–
Matlaline, the fluorescent substance in the wood of the tree Eysenhardtia polystachya
Fluorescence
–
Aequoria victoria, biofluorescent jellyfish known for GFP.
24.
Kyanite
–
Kyanite is a typically blue silicate mineral, commonly found in aluminium-rich metamorphic pegmatites and/or sedimentary rock. Kyanite in metamorphic rocks generally indicates pressures higher than four kilobars, kyanite is also known as disthene, rhaeticite and cyanite. Kyanite is a member of the series, which also includes the polymorph andalusite. Kyanite is strongly anisotropic, in that its hardness varies depending on its crystallographic direction, in kyanite, this anisotropism can be considered an identifying characteristic. At temperatures above 1100 °C kyanite decomposes into mullite and vitreous silica via the reaction,3 → 3Al2O3·2SiO2 + SiO2. This transformation results in an expansion and its name comes from the same origin as that of the color cyan, being derived from the Ancient Greek word κύανος. This is generally rendered into English as kyanos or kuanos and means dark blue, kyanite is used primarily in refractory and ceramic products, including porcelain plumbing fixtures and dishware. It is also used in electronics, electrical insulators and abrasives, kyanite has been used as a semiprecious gemstone, which may display cats eye chatoyancy, though this use is limited by its anisotropism and perfect cleavage. Color varieties include recently discovered orange kyanite from Tanzania, the orange color is due to inclusion of small amounts of manganese in the structure. Kyanite is one of the minerals that are used to estimate the temperature, depth. Kyanites elongated, columnar crystals are usually a good first indication of the mineral, associated minerals are useful as well, especially the presence of the polymorphs of staurolite, which occur frequently with kyanite. However, the most useful characteristic in identifying kyanite is its anisotropism, kyanite occurs in gneiss, schist, pegmatite, and quartz veins resulting from high pressure regional metamorphism of principally pelitic rocks. It occurs as detrital grains in sedimentary rocks and it occurs associated with staurolite, andalusite, sillimanite, talc, hornblende, gedrite, mullite and corundum. Kyanite occurs in Manhattan schist, formed under extreme pressure as a result of the two landmasses that formed supercontinent Pangaea
Kyanite
–
Kyanite
Kyanite
–
Deep blue kyanite
25.
Sillimanite
–
Sillimanite is an aluminosilicate mineral with the chemical formula Al2SiO5. Sillimanite is named after the American chemist Benjamin Silliman and it was first described in 1824 for an occurrence in Chester, Middlesex County, Connecticut, US. Sillimanite is one of three aluminosilicate polymorphs, the two being andalusite and kyanite. A common variety of sillimanite is known as fibrolite, so named because the mineral appears like a bunch of fibres twisted together when viewed in section or even by the naked eye. Both the fibrous and traditional forms of sillimanite are common in metamorphosed sedimentary rocks and it is an index mineral indicating high temperature but variable pressure. Example rocks include gneiss and granulite and it occurs with andalusite, kyanite, potassium feldspar, almandine, cordierite, biotite and quartz in schist, gneiss, hornfels and also rarely in pegmatites. Natural sillimanite rocks cut into the shape and size are used mainly in glass industries. Sillimanite is the best raw material for the manufacture of high alumina refractories or 55-60% alumina bricks, but its use on large scale is not possible due to its fine grading and high cost. Dumortierite and mullite are similar species found in porcelain. Sillimanite has been found in Brandywine Springs, New Castle County and it was named by the State Legislature in 1977 as the state mineral of Delaware by suggestion the Delaware Mineralogical Society. List of minerals List of minerals named after people
Sillimanite
–
Lustrous crystals of sillimanite (to 3 cm) embedded in schist matrix from Norwich, New London County, Connecticut
26.
Nesosilicate
–
Silicate minerals are rock-forming minerals made up of silicate groups. They are the largest and most important class of rock-forming minerals and they are classified based on the structure of their silicate groups, which contain different ratios of silicon and oxygen. Nesosilicates, or orthosilicates, have the orthosilicate ion, which constitute isolated 4− tetrahedra that are connected only by interstitial cations and these exist as 3-member 6− and 6-member 12− rings, where T stands for a tetrahedrally coordinated cation. Inosilicates, or chain silicates, have interlocking chains of silicate tetrahedra with either SiO3,1,3 ratio, for single chains or Si4O11,4,11 ratio, for double chains. Nickel–Strunz classification,09. D Pyroxene group Enstatite – orthoferrosilite series Enstatite – MgSiO3 Ferrosilite – FeSiO3 Pigeonite – Ca0.251, all phyllosilicate minerals are hydrated, with either water or hydroxyl groups attached. Serpentine subgroup Antigorite – Mg3Si2O54 Chrysotile – Mg3Si2O54 Lizardite – Mg3Si2O54 Clay minerals group Halloysite – Al2Si2O54 Kaolinite – Al2Si2O54 Illite – 24O10 Montmorillonite –0 and this group comprises nearly 75% of the crust of the Earth. Tectosilicates, with the exception of the group, are aluminosilicates. Nickel–Strunz classification,09. F and 09. G,04. A, an introduction to the rock-forming minerals. Wise, W. S. Zussman, J. Rock-forming minerals, P.982 pp. Hurlbut, Cornelius S. Danas Manual of Mineralogy. Mindat. org, Dana classification Webmineral, Danas New Silicate Classification Media related to Silicates at Wikimedia Commons
Nesosilicate
–
Copper silicate mineral
chrysocolla
Nesosilicate
–
Nesosilicate specimens at the Museum of Geology in South Dakota
Nesosilicate
–
Kyanite crystals (unknown scale)
Nesosilicate
–
Sorosilicate exhibit at Museum of Geology in South Dakota
27.
Aluminium
–
Aluminium or aluminum is a chemical element in the boron group with symbol Al and atomic number 13. It is a silvery-white, soft, nonmagnetic, ductile metal, Aluminium metal is so chemically reactive that native specimens are rare and limited to extreme reducing environments. Instead, it is combined in over 270 different minerals. The chief ore of aluminium is bauxite, Aluminium is remarkable for the metals low density and its ability to resist corrosion through the phenomenon of passivation. Aluminium and its alloys are vital to the industry and important in transportation and structures, such as building facades. The oxides and sulfates are the most useful compounds of aluminium, despite its prevalence in the environment, no known form of life uses aluminium salts metabolically, but aluminium is well tolerated by plants and animals. Because of these salts abundance, the potential for a role for them is of continuing interest. Aluminium is a soft, durable, lightweight, ductile. It is nonmagnetic and does not easily ignite, a fresh film of aluminium serves as a good reflector of visible light and an excellent reflector of medium and far infrared radiation. The yield strength of aluminium is 7–11 MPa, while aluminium alloys have yield strengths ranging from 200 MPa to 600 MPa. Aluminium has about one-third the density and stiffness of steel and it is easily machined, cast, drawn and extruded. Aluminium atoms are arranged in a cubic structure. Aluminium has an energy of approximately 200 mJ/m2. Aluminium is a thermal and electrical conductor, having 59% the conductivity of copper. Aluminium is capable of superconductivity, with a critical temperature of 1.2 kelvin. Aluminium is the most common material for the fabrication of superconducting qubits, the strongest aluminium alloys are less corrosion resistant due to galvanic reactions with alloyed copper. This corrosion resistance is reduced by aqueous salts, particularly in the presence of dissimilar metals. In highly acidic solutions, aluminium reacts with water to form hydrogen, primarily because it is corroded by dissolved chlorides, such as common sodium chloride, household plumbing is never made from aluminium
Aluminium
–
Aluminium, 13 Al
Aluminium
–
Spectral lines of aluminium
Aluminium
–
"
Red mud " storage facility in
Stade,
Germany. The aluminium industry generates about 70 million tons of this waste annually.
Aluminium
–
Bauxite, a major aluminium ore. The red-brown color is due to the presence of
iron minerals.
28.
Silicate minerals
–
Silicate minerals are rock-forming minerals made up of silicate groups. They are the largest and most important class of rock-forming minerals and they are classified based on the structure of their silicate groups, which contain different ratios of silicon and oxygen. Nesosilicates, or orthosilicates, have the orthosilicate ion, which constitute isolated 4− tetrahedra that are connected only by interstitial cations and these exist as 3-member 6− and 6-member 12− rings, where T stands for a tetrahedrally coordinated cation. Inosilicates, or chain silicates, have interlocking chains of silicate tetrahedra with either SiO3,1,3 ratio, for single chains or Si4O11,4,11 ratio, for double chains. Nickel–Strunz classification,09. D Pyroxene group Enstatite – orthoferrosilite series Enstatite – MgSiO3 Ferrosilite – FeSiO3 Pigeonite – Ca0.251, all phyllosilicate minerals are hydrated, with either water or hydroxyl groups attached. Serpentine subgroup Antigorite – Mg3Si2O54 Chrysotile – Mg3Si2O54 Lizardite – Mg3Si2O54 Clay minerals group Halloysite – Al2Si2O54 Kaolinite – Al2Si2O54 Illite – 24O10 Montmorillonite –0 and this group comprises nearly 75% of the crust of the Earth. Tectosilicates, with the exception of the group, are aluminosilicates. Nickel–Strunz classification,09. F and 09. G,04. A, an introduction to the rock-forming minerals. Wise, W. S. Zussman, J. Rock-forming minerals, P.982 pp. Hurlbut, Cornelius S. Danas Manual of Mineralogy. Mindat. org, Dana classification Webmineral, Danas New Silicate Classification Media related to Silicates at Wikimedia Commons
Silicate minerals
–
Copper silicate mineral
chrysocolla
Silicate minerals
–
Nesosilicate specimens at the Museum of Geology in South Dakota
Silicate minerals
–
Kyanite crystals (unknown scale)
Silicate minerals
–
Sorosilicate exhibit at Museum of Geology in South Dakota
29.
Mineral
–
A mineral is a naturally occurring chemical compound, usually of crystalline form and abiogenic in origin. A mineral has one specific chemical composition, whereas a rock can be an aggregate of different minerals or mineraloids, the study of minerals is called mineralogy. There are over 5,300 known mineral species, over 5,070 of these have been approved by the International Mineralogical Association, the silicate minerals compose over 90% of the Earths crust. The diversity and abundance of species is controlled by the Earths chemistry. Silicon and oxygen constitute approximately 75% of the Earths crust, which translates directly into the predominance of silicate minerals, minerals are distinguished by various chemical and physical properties. Differences in chemical composition and crystal structure distinguish the various species, changes in the temperature, pressure, or bulk composition of a rock mass cause changes in its minerals. Minerals can be described by their various properties, which are related to their chemical structure. Common distinguishing characteristics include crystal structure and habit, hardness, lustre, diaphaneity, colour, streak, tenacity, cleavage, fracture, parting, more specific tests for describing minerals include magnetism, taste or smell, radioactivity and reaction to acid. Minerals are classified by key chemical constituents, the two dominant systems are the Dana classification and the Strunz classification, the silicate class of minerals is subdivided into six subclasses by the degree of polymerization in the chemical structure. All silicate minerals have a unit of a 4− silica tetrahedron—that is, a silicon cation coordinated by four oxygen anions. These tetrahedra can be polymerized to give the subclasses, orthosilicates, disilicates, cyclosilicates, inosilicates, phyllosilicates, other important mineral groups include the native elements, sulfides, oxides, halides, carbonates, sulfates, and phosphates. The first criterion means that a mineral has to form by a natural process, stability at room temperature, in the simplest sense, is synonymous to the mineral being solid. More specifically, a compound has to be stable or metastable at 25 °C, modern advances have included extensive study of liquid crystals, which also extensively involve mineralogy. Minerals are chemical compounds, and as such they can be described by fixed or a variable formula, many mineral groups and species are composed of a solid solution, pure substances are not usually found because of contamination or chemical substitution. Finally, the requirement of an ordered atomic arrangement is usually synonymous with crystallinity, however, crystals are also periodic, an ordered atomic arrangement gives rise to a variety of macroscopic physical properties, such as crystal form, hardness, and cleavage. There have been recent proposals to amend the definition to consider biogenic or amorphous substances as minerals. The formal definition of an approved by the IMA in 1995, A mineral is an element or chemical compound that is normally crystalline. However, if geological processes were involved in the genesis of the compound, Mineral classification schemes and their definitions are evolving to match recent advances in mineral science
Mineral
–
Amethyst, a variety of
quartz
Mineral
–
Schist is a
metamorphic rock characterized by an abundance of platy minerals. In this example, the rock has prominent
sillimanite porphyroblasts as large as 3 cm (1.2 in).
Mineral
–
Hübnerite, the manganese-rich end-member of the
wolframite series, with minor quartz in the background
Mineral
–
When minerals react, the products will sometimes assume the shape of the reagent; the product mineral is termed to be a pseudomorph of (or after) the reagent. Illustrated here is a pseudomorph of
kaolinite after
orthoclase. Here, the pseudomorph preserved the Carlsbad
twinning common in orthoclase.
30.
Aluminosilicate
–
Aluminosilicate minerals are minerals composed of aluminium, silicon, and oxygen, plus countercations. They are a component of kaolin and other clay minerals. Andalusite, kyanite, and sillimanite are naturally occurring minerals that have the composition Al2SiO5. The triple point of the three polymorphs is located at a temperature of 500 °C and a pressure of 0.4 GPa and these three minerals are commonly used as index minerals in metamorphic rocks. Hydrated aluminosilicate minerals are referred to as zeolites and are porous structures that are naturally occurring materials, the catalyst silica-alumina is an amorphous substance which is not an aluminosilicate compound. There exist a variety of glass types. The characteristics of different types depend on the chemical composition of the glass with a special focus on the oxide composition. Glasses can be categorized into different groups, one of them including the so-called aluminosilicate glasses. This glass type can be differentiated, Characteristically, these glasses are free of alkali oxides and contain 15-25% AI2O3, 52-60% SiO2. Very high transformation temperatures and softening points are typical features, main fields of application are glass bulbs for halogen lamps, high-temperature thermometers and thermally and electrically highly loadable film resistors. The AI2O3 content of alkali aluminosilicate glasses is typically 10-25% and the content over 10%. The high alkali content prepares the glass for ion exchange with bigger alkali ions in order to improve the surface compressive strength, due to this particular feature, this glass type is especially suitable for the use in touch displays, solar cells cover glass and laminated safety glass. High transformation temperatures and outstanding properties, e. g. hardness. Aluminium silicate Silicate minerals Calcium aluminosilicate Sodium aluminosilicate
Aluminosilicate
–
Kyanite
31.
Chiastolite
–
Chiastolite is a variety of the mineral andalusite with the chemical composition Al2SiO5. It is noted for distinctive cross-shaped black inclusions of graphite, in areas around Georgetown, California, metamorphosed sediments contained andalusite and chiastolite in a graphite rich metasediment. The chiastolite crystals have been altered by a mixture of muscovite, paragonite and margarite. The calcium rich margarite tends to form along the graphite rich crosses or bands within the chiastolite, mineralogically the occurrence is important because all three white mica phases are present in an equilibrium assemblage. As the concentration of these increases, the growth of the crystal is slowed. This concentrated impurity deposit forms a re-entrant as it is absorbed by the growth of the andalusite porphyroblast, the cycle of growth-retardation-growth then repeats itself, creating a featherlike pattern of graphite along four radiating arms. Mindat with location data Margarite pseudomorphs after chiastolite in the Georgetown area, California, Am
Chiastolite
–
This article includes a
list of references, related reading or
external links, but its sources remain unclear because it lacks
inline citations. Please
improve this article by introducing more precise citations. (August 2012)
32.
Cruciform
–
Cruciform means having the shape of a cross or Christian cross. Christian churches are described as having a cruciform architecture. In the Western churches, a cruciform architecture usually, though not exclusively and this layout comprises the following, An east end, containing an altar and often with an elaborate, decorated window, through which light will shine in the early part of the day. A west end, which contains a baptismal font, being a large decorated bowl, in which water can be firstly, blessed. North and south transepts, being arms of the cross and often containing rooms for gathering, small chapels, or in many cases other necessities such as an organ. The crossing, which in later designs often was under a tower or dome, in churches that are not oriented with the altar at the geographical east end, it is usual to refer to the altar end as liturgical east and so forth. Another example of ancient cruciform architecture can be found in Herods temple, DNA can undergo transitions to form a cruciform shape, otherwise known as a Holliday junction. This structure is important for the biological processes of DNA recombination. A cruciform joint is a joint in which 4 spaces are created by the welding of 3 plates of metal at right angles. A cruciform manuscript was a form of Anglo-Saxon / Insular manuscript written with the words in a block shaped like a cross. In music, a melody of four pitches where a line drawn between the outer pair bisects a straight line drawn between the inner pair, thus forming a cross. In its simplest form, the melody is a changing tone. Often representative of the Christian cross, such melodies are cruciform in their retrogrades or inversions, johann Sebastian Bach, whose last name may be represented in tones through a musical cryptogram known as the BACH motif that is a cruciform melody, employed the device extensively. The subject of the fugue in c-sharp minor from The Well-Tempered Clavier Book I is cruciform, the plain sword used by knights, distinctive due to the flat bar used as a guard. The overall shape of the sword when held point down is that of a cross and it is believed this shape was encouraged by the church to remind Knights of their religion. It was however very popular due to the protection it offered to the hand, some airplanes use a cruciform tail design, wherein the horizontal stabilizer is positioned midway up the vertical stabilizer, forming a cruciform shape when viewed from the front or rear. Some examples are the F-9 Cougar, the F-10 Skyknight and the Sud Aviation Caravelle, cruciform web designs use a cross-shaped web page that expands to fill the width and height of the web browser window. There are a number of different approaches to implementing them, in addition to common cross-shaped products, such as key chains and magnets, certain designers have gone so far as to create cruciform devices and accessories
Cruciform
–
Peterborough Cathedral
Cruciform
–
Holliday Junction
Cruciform
–
librarian
Humfrey Wanley holding a cruciform Anglo-Saxon manuscript
Cruciform
–
Swiss
longsword, 15th or 16th century
33.
Andalusia
–
Andalusia is an autonomous community in southern Spain. It is the most populated and the second largest in area of the communities in the country. The Andalusian autonomous community is recognised as historical nationality. The territory is divided into eight provinces, Almería, Cádiz, Córdoba, Granada, Huelva, Jaén, Málaga and its capital is the city of Seville. Andalusia is the only European region with both Mediterranean and Atlantic coastlines, the small British overseas territory of Gibraltar shares a three-quarter-mile land border with the Andalusian province of Cádiz at the eastern end of the Strait of Gibraltar. The main mountain ranges of Andalusia are the Sierra Morena and the Baetic System, consisting of the Subbaetic and Penibaetic Mountains, in the north, the Sierra Morena separates Andalusia from the plains of Extremadura and Castile–La Mancha on Spains Meseta Central. To the south the geographic subregion of Upper Andalusia lies mostly within the Baetic System, the name Andalusia is derived from the Arabic word Al-Andalus. Including an intense relationship with Naples, Italy, Andalusia has been a traditionally agricultural region, compared to the rest of Spain and the rest of Europe. However, the growth of the community especially in the sectors of industry and services was above average in Spain, the region has, however, a rich culture and a strong cultural identity. Many cultural phenomena that are seen internationally as distinctively Spanish are largely or entirely Andalusian in origin and these include flamenco and, to a lesser extent, bullfighting and Hispano-Moorish architectural styles. Andalusias hinterland is the hottest area of Europe, with cities like Córdoba, Late evening temperatures can sometimes stay around 35 °C until close to midnight, with daytime highs of over 40 °C common. Seville also has the highest average temperature in mainland Spain and mainland Europe. Its present form is derived from the Arabic name for Muslim Iberia. However, the etymology of the name Al-Andalus is disputed, the Spanish place name Andalucía was introduced into the Spanish languages in the 13th century under the form el Andalucía. This was a Castilianization of Al-Andalusiya, the form of the Arabic language al-Andalus. The etymology of al-Andalus is itself somewhat debated, but in fact it entered the Arabic language before this came under Muslim rule. Like the Arabic term al-Andalus, in historical contexts the Spanish term Andalucía or the English term Andalusia do not necessarily refer to the territory designated by these terms today. To designate the territories the Christians had regained by that time in the Guadalquivir valley and in the Kingdoms of Granada, in a document from 1253, Alfonso X styled himself Rey de Castilla, León y de toda Andalucía
Andalusia
–
Map of the
Iberian peninsula dated 1770. The Kingdoms of
Jaén,
Córdoba and
Seville are collectively referred to under the name Andalucía, while the
Kingdom of Granada appears under its individual name.
Andalusia
–
Flag
Andalusia
–
Portrait of
Blas Infante, executed in
azulejos, located on the avenue in
Jerez de la Frontera named in his honor.
Andalusia
–
Andalusian firs,
Sierra de las Nieves
34.
Spain
–
By population, Spain is the sixth largest in Europe and the fifth in the European Union. Spains capital and largest city is Madrid, other urban areas include Barcelona, Valencia, Seville, Bilbao. Modern humans first arrived in the Iberian Peninsula around 35,000 years ago, in the Middle Ages, the area was conquered by Germanic tribes and later by the Moors. Spain is a democracy organised in the form of a government under a constitutional monarchy. It is a power and a major developed country with the worlds fourteenth largest economy by nominal GDP. Jesús Luis Cunchillos argues that the root of the span is the Phoenician word spy. Therefore, i-spn-ya would mean the land where metals are forged, two 15th-century Spanish Jewish scholars, Don Isaac Abravanel and Solomon ibn Verga, gave an explanation now considered folkloric. Both men wrote in two different published works that the first Jews to reach Spain were brought by ship by Phiros who was confederate with the king of Babylon when he laid siege to Jerusalem. This man was a Grecian by birth, but who had given a kingdom in Spain. He became related by marriage to Espan, the nephew of king Heracles, Heracles later renounced his throne in preference for his native Greece, leaving his kingdom to his nephew, Espan, from whom the country of España took its name. Based upon their testimonies, this eponym would have already been in use in Spain by c.350 BCE, Iberia enters written records as a land populated largely by the Iberians, Basques and Celts. Early on its coastal areas were settled by Phoenicians who founded Western Europe´s most ancient cities Cadiz, Phoenician influence expanded as much of the Peninsula was eventually incorporated into the Carthaginian Empire, becoming a major theater of the Punic Wars against the expanding Roman Empire. After an arduous conquest, the peninsula came fully under Roman Rule, during the early Middle Ages it came under Germanic rule but later, much of it was conquered by Moorish invaders from North Africa. In a process took centuries, the small Christian kingdoms in the north gradually regained control of the peninsula. The last Moorish kingdom fell in the same year Columbus reached the Americas, a global empire began which saw Spain become the strongest kingdom in Europe, the leading world power for a century and a half, and the largest overseas empire for three centuries. Continued wars and other problems led to a diminished status. The Napoleonic invasions of Spain led to chaos, triggering independence movements that tore apart most of the empire, eventually democracy was peacefully restored in the form of a parliamentary constitutional monarchy. Spain joined the European Union, experiencing a renaissance and steady economic growth
Spain
–
Lady of Elche
Spain
–
Flag
Spain
–
Altamira Cave paintings, in
Cantabria.
Spain
–
Celtic castro in
A Guarda,
Galicia.
35.
Iridescence
–
Iridescence is the phenomenon of certain surfaces that appear to gradually change colour as the angle of view or the angle of illumination changes. Examples of iridescence include soap bubbles, butterfly wings and sea shells and it is often created by structural coloration. The word iridescence is derived in part from the Greek word ἶρις îris, meaning rainbow, Iris in turn derives from the goddess Iris of Greek mythology, who is the personification of the rainbow and acted as a messenger of the gods. Goniochromism is derived from the Greek words gonia, meaning angle, iridescence is an optical phenomenon of surfaces in which hue changes with the angle of observation and the angle of illumination. It is often caused by reflections from two or more semi-transparent surfaces in which phase shift and interference of the reflections modulates the incidental light. The thickness of the layers of the material determines the interference pattern, iridescence is also found in plants, animals and many other items. The range of colours of natural iridescent objects can be narrow, iridescence can also be created by diffraction. This is found in items like CDs, DVDs, or cloud iridescence, in the case of diffraction, the entire rainbow of colours will typically be observed as the viewing angle changes. In biology, this type of results from the formation of diffraction gratings on the surface. In biological uses, colours produced other than with pigments or dyes are called structural coloration and it was later found that iridescence in the peacock is due to a complex photonic crystal. The feathers of birds such as kingfishers, Birds-of-paradise, hummingbirds, parrots, starlings, grackles, ducks, the lateral line on the Neon tetra is also iridescent. A single iridescent species of gecko, Cnemaspis kolhapurensis, was identified in India in 2009, the tapetum lucidum, present in the eyes of many vertebrates, is also iridescent. Many groups of plants have developed iridescence as an adaptation to use light in dark environments such as the lower levels of tropical forests. Nanocellulose is sometimes iridescent, as are films of gasoline and some other hydrocarbons. Iridescent products in the cosmetic and clothing industries are often referred as being holographic
Iridescence
–
Iridescence in
soap bubbles
Iridescence
–
Iridescent nightscape over
La Silla Observatory.
Iridescence
–
Fuel on top of water creates a thin film, which interferes with the light, producing different colours. The different bands represent different thicknesses in the film.
Iridescence
–
An iridescent
biofilm on the surface of a fishtank diffracts the reflected light, displaying the entire spectrum of colours. Red is seen from longer angles of incidence than blue.
36.
Mica schist
–
Schist is a medium-grade metamorphic rock with medium to large, flat, sheet-like grains in a preferred orientation. It is defined by having more than 50% platy and elongated minerals, often finely interleaved with quartz and these lamellar minerals include micas, chlorite, talc, hornblende, graphite, and others. Quartz often occurs in drawn-out grains to such an extent that a form called quartz schist is produced. Schist forms at a temperature and has larger grains than phyllite. Geological foliation with medium to large grained flakes in a preferred orientation is called schistosity. The names of various schists are derived from their mineral constituents, for example, schists rich in mica are called mica schists and include biotite or muscovite. Most schists are mica schists, but graphite and chlorite schists are also common, Schists are also named for their prominent or perhaps unusual mineral constituents, as in the case of garnet schist, tourmaline schist, and glaucophane schist. The individual mineral grains in schist, drawn out into flaky scales by heat and pressure, Schist is characteristically foliated, meaning that the individual mineral grains split off easily into flakes or slabs. Most schists are derived from clays and muds that have passed through a series of processes involving the production of shales, slates and phyllites as intermediate steps. Certain schists are derived from fine-grained igneous rocks such as basalts, before the mid-18th century, the terms slate, shale and schist were not sharply differentiated by those involved with mining. In the context of underground mining, shale was frequently referred to as slate well into the 20th century. During metamorphism, rocks which were originally sedimentary, igneous or metamorphic are converted into schists, if the composition of the rocks was originally similar, they may be very difficult to distinguish from one another if the metamorphism has been great. A quartz-porphyry, for example, and a fine grained feldspathic sandstone, usually, however, it is possible to distinguish between sedimentary and igneous schists and gneisses. If, for example, the district occupied by these rocks has traces of bedding, clastic structure, or unconformability. In other cases intrusive junctions, chilled edges, contact alteration or porphyritic structure may prove that in its original condition a metamorphic gneiss was an igneous rock. Such rocks as limestones, dolomites, quartzites and aluminous shales have very definite chemical characteristics which distinguish them even when completely recrystallized, the schists are classified principally according to the minerals they consist of and on their chemical composition. For example, many metamorphic limestones, marbles, and calc-schists, with crystalline dolomites, contain silicate minerals such as mica, tremolite, diopside, scapolite, quartz and they are derived from calcareous sediments of different degrees of purity. Another group is rich in quartz, with amounts of white and black mica, garnet, feldspar, zoisite
Mica schist
–
Schist specimen showing the characteristic "scaly" schistose texture, caused by platy micas
Mica schist
–
Microscopic view of garnet-mica-schist in
thin section under polarized light with a large garnet crystal (black) in a matrix of quartz and feldspar (white and gray grains) and parallel strands of mica (red, purple and brown).
Mica schist
–
View of cut garnet-mica-schist
Mica schist
–
Manhattan schist from southeastern New York State
37.
South Africa
–
South Africa, officially the Republic of South Africa, is the southernmost country in Africa. South Africa is the 25th-largest country in the world by land area and it is the southernmost country on the mainland of the Old World or the Eastern Hemisphere. About 80 percent of South Africans are of Sub-Saharan African ancestry, divided among a variety of ethnic groups speaking different Bantu languages, the remaining population consists of Africas largest communities of European, Asian, and multiracial ancestry. South Africa is a multiethnic society encompassing a variety of cultures, languages. Its pluralistic makeup is reflected in the recognition of 11 official languages. The country is one of the few in Africa never to have had a coup détat, however, the vast majority of black South Africans were not enfranchised until 1994. During the 20th century, the black majority sought to recover its rights from the dominant white minority, with this struggle playing a role in the countrys recent history. The National Party imposed apartheid in 1948, institutionalising previous racial segregation, since 1994, all ethnic and linguistic groups have held political representation in the countrys democracy, which comprises a parliamentary republic and nine provinces. South Africa is often referred to as the Rainbow Nation to describe the multicultural diversity. The World Bank classifies South Africa as an economy. Its economy is the second-largest in Africa, and the 34th-largest in the world, in terms of purchasing power parity, South Africa has the seventh-highest per capita income in Africa. However, poverty and inequality remain widespread, with about a quarter of the population unemployed, nevertheless, South Africa has been identified as a middle power in international affairs, and maintains significant regional influence. The name South Africa is derived from the geographic location at the southern tip of Africa. Upon formation the country was named the Union of South Africa in English, since 1961 the long form name in English has been the Republic of South Africa. In Dutch the country was named Republiek van Zuid-Afrika, replaced in 1983 by the Afrikaans Republiek van Suid-Afrika, since 1994 the Republic has had an official name in each of its 11 official languages. Mzansi, derived from the Xhosa noun umzantsi meaning south, is a name for South Africa. South Africa contains some of the oldest archaeological and human fossil sites in the world, extensive fossil remains have been recovered from a series of caves in Gauteng Province. The area is a UNESCO World Heritage site and has termed the Cradle of Humankind
South Africa
–
Mapungubwe Hill, the site of the former capital of the
Kingdom of Mapungubwe
South Africa
–
Flag
South Africa
–
Arrival of
Jan van Riebeeck, the first European to settle in South Africa, with
Devil's Peak in the background
South Africa
–
Depiction of a
Zulu attack on a Boer camp in February 1838
38.
Metamorphism
–
Metamorphism is the change of minerals or geologic texture in pre-existing rocks, without the protolith melting into liquid magma. The change occurs primarily due to heat, pressure, and the introduction of chemically active fluids, the chemical components and crystal structures of the minerals making up the rock may change even though the rock remains a solid. Changes at or just beneath Earths surface due to weathering and/or diagenesis are not classified as metamorphism, Metamorphism typically occurs between diagenesis, and melting. Three types of metamorphism exist, contact, dynamic, and regional, Metamorphism produced with increasing pressure and temperature conditions is known as prograde metamorphism. Conversely, decreasing temperatures and pressure characterize retrograde metamorphism, Metamorphic rocks can change without melting. When pressure is applied, somewhat flattened grains that orient in the same direction have a stable configuration. The upper boundary of metamorphic conditions is related to the onset of melting processes in the rock, the maximum temperature for metamorphism is typically 700 –900 °C, depending on the pressure and on the composition of the rock. Migmatites are rocks formed at this limit, which contain pods. Since the 1980s it has recognized that rocks are rarely dry enough. Conditions producing widespread regionally metamorphosed rocks occur during an orogenic event, the collision of two continental plates or island arcs with continental plates produce the extreme compressional forces required for the metamorphic changes typical of regional metamorphism. These orogenic mountains are eroded, exposing the intensely deformed rocks typical of their cores. The conditions within the slab as it plunges toward the mantle in a subduction zone also produce regional metamorphic effects. The techniques of structural geology are used to unravel the collisional history, regional metamorphism can be described and classified into metamorphic facies or metamorphic zones of temperature/pressure conditions throughout the orogenic terrane. Contact metamorphism occurs typically around intrusive igneous rocks as a result of the increase caused by the intrusion of magma into cooler country rock. The area surrounding the intrusion where the contact metamorphism effects are present is called the metamorphic aureole, contact metamorphic rocks are usually known as hornfels. Rocks formed by contact metamorphism may not present signs of deformation and are often fine-grained. Contact metamorphism is greater adjacent to the intrusion and dissipates with distance from the contact, the size of the aureole depends on the heat of the intrusion, its size, and the temperature difference with the wall rocks. Dikes generally have small aureoles with minimal metamorphism whereas large ultramafic intrusions can have significantly thick, the metamorphic grade of an aureole is measured by the peak metamorphic mineral which forms in the aureole
Metamorphism
–
A metamorphic aureole in the Henry Mountains, Utah. The greyish rock on top is the igneous intrusion, consisting of porphyritic granodiorite from the
Henry Mountains laccolith, and the pinkish rock on the bottom is the sedimentary country rock, a siltstone. In between, the metamorphosed siltstone is visible as both the dark layer (~5cm thick) and the pale layer below it.
Metamorphism
–
Schematic representation of a metamorphic reaction. Abbreviations of minerals: act =
actinolite; chl =
chlorite; ep =
epidote; gt =
garnet; hbl =
hornblende; plag =
plagioclase. Two minerals represented in the figure do not participate in the reaction, they can be
quartz and
K-feldspar. This reaction takes place in nature when a rock goes from
amphibolite facies to
greenschist facies.
Metamorphism
–
Metamorphic Facies with regard to temperature and pressure
39.
Polymorphism (materials science)
–
In materials science, polymorphism is the ability of a solid material to exist in more than one form or crystal structure. Polymorphism can potentially be found in any crystalline material including polymers, minerals, and metals, and is related to allotropy, the complete morphology of a material is described by polymorphism and other variables such as crystal habit, amorphous fraction or crystallographic defects. Polymorphism is relevant to the fields of pharmaceuticals, agrochemicals, pigments, dyestuffs, foods, when polymorphism exists as a result of a difference in crystal packing, it is called packing polymorphism. Polymorphism can also result from the existence of different conformers of the molecule in conformational polymorphism. In pseudopolymorphism the different crystal types are the result of hydration or solvation and this is more correctly referred to as solvomorphism as different solvates have different chemical formulae. An example of an organic polymorph is glycine, which is able to form monoclinic, silica is known to form many polymorphs, the most important of which are, α-quartz, β-quartz, tridymite, cristobalite, coesite, and stishovite. A classical example is the pair of minerals, calcite and aragonite, an analogous phenomenon for amorphous materials is polyamorphism, when a substance can take on several different amorphous modifications. In terms of thermodynamics, there are two types of polymorphic behaviour, for an enantiotropic system, a plot of the free energy against temperature shows a crossing point threshold before the various melting points. It may also be possible to revert interchangeably between the two polymorphs by heating or cooling, or through contact with a lower energy polymorph. Present-day analysis identifies three polymorphs for benzamide, the least stable one, formed by flash cooling is the orthorhombic form II and this type is followed by the monoclinic form III. The most stable form is monoclinic form I, the hydrogen bonding mechanisms are the same for all three phases, however, they differ strongly in their pi-pi interactions. Polymorphs have different stabilities and may spontaneously convert from a form to the stable form at a particular temperature. Most polymorphs of organic molecules only differ by a few kJ/mol in lattice energy, approximately 50% of known polymorph pairs differ by less than 2 kJ/mol and stability differences of more than 10 kJ/mol are rare. They also exhibit different melting points, solubilities, X-ray crystal, various conditions in the crystallisation process is the main reason responsible for the development of different polymorphic forms. In 2006 a new form of maleic acid was discovered 124 years after the first crystal form was studied. Maleic acid is a manufactured on a very large scale in the chemical industry and is a salt forming component in medicine. The new crystal type is produced when a co-crystal of caffeine and maleic acid is dissolved in chloroform, whereas form I has monoclinic space group P21/c, the new form has space group Pc. 1,3, 5-Trinitrobenzene is more than 125 years old and was used as an explosive before the arrival of the safer 2,4, only one crystal form of 1,3, 5-trinitrobenzene was known in the space group Pbca
Polymorphism (materials science)
40.
Hornfels
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Hornfels is called so because of its exceptional toughness and texture both reminiscent of animal horns. These properties are due to fine grained non-aligned crystals with platy or prismatic habits, Hornfels rocks were referred to by miners in northern England as whetstones. Though they may show banding, due to bedding, etc. they break across this as readily as along it, in fact, the most common hornfels are dark-brown to black with a somewhat velvety luster owing to the abundance of small crystals of shining black mica. The lime hornfels are often white, yellow, pale-green, brown, green and dark-green are the prevalent tints of the hornfels produced by the alteration of igneous rocks. The structure of the hornfels is very characteristic, very rarely do any of the minerals show crystalline form, but the small grains fit closely together like the fragments of a mosaic, they are usually of nearly equal dimensions. This has been called pflaster or pavement structure from the resemblance to rough pavement work, each mineral may also enclose particles of the others, in the quartz, for example, small crystals of graphite, biotite, iron oxides, sillimanite or feldspar may appear in great numbers. Often the whole of the grains are rendered semi-opaque in this way, the minutest crystals may show traces of crystalline outlines, undoubtedly they are of new formation and have originated in situ. The regeneration of the rock has been sufficient to efface most of the original structures, but crystallization has been hampered by the solid condition of the mass and the new minerals are formless and have been unable to reject impurities, but have grown around them. There is also quartz, and often a considerable amount of feldspar, while graphite, tourmaline, the andalusite may be pink and is then often pleochroic in thin sections, or it may be white with the cross-shaped dark enclosures of the matrix that are characteristic of chiastolite. Sillimanite usually forms exceedingly minute needles embedded in quartz, in the rocks of this group cordierite also occurs, not rarely, and may have the outlines of imperfect hexagonal prisms that are divided up into six sectors when seen in polarized light. In biotite hornfels, a faint striping may indicate the original bedding of the unaltered rock, more commonly there is a distinct spotting, visible on the surfaces of the hand specimens. The spots are round or elliptical, and may be paler or darker than the rest of the rock. In some cases they are rich in graphite or carbonaceous matter, in others they are full of brown mica, tourmaline hornfels are found sometimes near the margins of tourmaline granites, they are black with small needles of schorl that under the microscope are dark brown and richly pleochroic. As the tourmaline contains boron, there must have been some permeation of vapors from the granite into the sediments, rocks of this group are often seen in the Cornish tin-mining districts, especially near the ludes. A second great group of hornfels are the calc–silicate hornfels that arise from the alteration of impure limestone. These rocks are fine-grained, and though often banded, are tough and they are excessively variable in their mineralogical composition, and very often alternate in thin seams with biotite hornfels and indurated quartzites. When perfused with boric and fluoric vapors from the granite they may contain much axinite, fluorite and datolite, from diabases, basalts, andesites and other igneous rocks a third type of hornfels is produced. They consist essentially of feldspar with hornblende and pale pyroxene, sphene, biotite and iron oxides are the other common constituents, but these rocks show much variety of composition and structure
Hornfels
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A sample of banded hornfels, formed by contact metamorphism of
sandstones and
shales by a
granite intrusion
41.
Gemological Institute of America
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The Gemological Institute of America, or GIA, is a nonprofit institute dedicated to research and education in the field of gemology and the jewelry arts. Founded in 1931, GIAs mission is to all buyers and sellers of gemstones by setting and maintaining the standards used to evaluate gemstone quality. The institute does so through research, gem identification and diamond grading services, through its world-renowned library and subject experts, GIA acts as a resource of gem and jewelry information for the trade, the public and worldwide media outlets. In 1953 the GIA developed its International Diamond Grading System and the Four Cs as a standard to compare, today, the institute is headquartered in Carlsbad, California and operates out of 13 countries, with 11 campuses,9 laboratories and 4 research centers worldwide. The story of the GIA starts back in the 1920s with a man named Robert M. Shipley and he therefore took it upon himself to bring change to the jeweler’s trade, and restore the public’s trust therein. After traveling to Europe and completing the Great Britain National Association of Goldsmiths gemological correspondence course and it was here that he launched his own preliminary course in gemology on September 16,1930, seeking to train and certify jewelers. The jewelers he certified would eventually serve to form a guild of jewelers, dedicated to providing the public with a superior sense of professionalism within the gem. The first GIA gemological laboratory was established in Los Angeles in 1931, the jewelers profession was quickly transformed, with the introduction of the Certified Gemologist professional designation and the legitimization of gemology as a recognized science. Over the years, the group has many significant new developments to the industry, including the following,1934. 1937, GIA patents the world’s first gemological microscope, allowing gemologists to properly examine the insides of gemstones,1953, The diamond grading system based on Shipley’s Four C’s becomes an international standard for determining diamond quality. 1955, GIA issues the first diamond grading reports, which are accepted as a benchmark for the jewelry industry. 1956, GIA finds a way to detect diamonds that have been irradiated to artificially enhance their color. 1960, The GIA Diamond Dictionary is published, becoming an international industry reference,1987, The Liddicoat Gemological Library and Information Center amasses the largest collection of books on gemology in the world. 1991, GIA hosts its first annual Career Fair, which becomes the industry’s most significant recruiting event,1999, GIA identifies a way to detect diamonds that have been decolorized by high pressure and high temperatures. 2003, GIA identifies a way to detect sapphires made from beryllium-diffusion techniques,2005, GIA creates a system for grading the cut of round brilliant diamonds in the D-to-Z color range. 2007, GIA introduces a Synthetic Diamond Grading Report,2014, GIA introduces DiamondCheck, which is capable of differentiating between natural and treated or synthetic diamonds. GIA is actively engaged in research to advance the science of gemology, historically, research has focused on developing methods and technologies to accurately identify and characterize gems. This research has produced significant advances in the ability to differentiate gems, GIA was also responsible for the first modern diamond grading reports, where it introduced grading methodologies for diamond color and diamond clarity
Gemological Institute of America
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Gemological Institute of America (GIA)
42.
International Standard Book Number
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The International Standard Book Number is a unique numeric commercial book identifier. An ISBN is assigned to each edition and variation of a book, for example, an e-book, a paperback and a hardcover edition of the same book would each have a different ISBN. The ISBN is 13 digits long if assigned on or after 1 January 2007, the method of assigning an ISBN is nation-based and varies from country to country, often depending on how large the publishing industry is within a country. The initial ISBN configuration of recognition was generated in 1967 based upon the 9-digit Standard Book Numbering created in 1966, the 10-digit ISBN format was developed by the International Organization for Standardization and was published in 1970 as international standard ISO2108. Occasionally, a book may appear without a printed ISBN if it is printed privately or the author does not follow the usual ISBN procedure, however, this can be rectified later. Another identifier, the International Standard Serial Number, identifies periodical publications such as magazines, the ISBN configuration of recognition was generated in 1967 in the United Kingdom by David Whitaker and in 1968 in the US by Emery Koltay. The 10-digit ISBN format was developed by the International Organization for Standardization and was published in 1970 as international standard ISO2108, the United Kingdom continued to use the 9-digit SBN code until 1974. The ISO on-line facility only refers back to 1978, an SBN may be converted to an ISBN by prefixing the digit 0. For example, the edition of Mr. J. G. Reeder Returns, published by Hodder in 1965, has SBN340013818 -340 indicating the publisher,01381 their serial number. This can be converted to ISBN 0-340-01381-8, the check digit does not need to be re-calculated, since 1 January 2007, ISBNs have contained 13 digits, a format that is compatible with Bookland European Article Number EAN-13s. An ISBN is assigned to each edition and variation of a book, for example, an ebook, a paperback, and a hardcover edition of the same book would each have a different ISBN. The ISBN is 13 digits long if assigned on or after 1 January 2007, a 13-digit ISBN can be separated into its parts, and when this is done it is customary to separate the parts with hyphens or spaces. Separating the parts of a 10-digit ISBN is also done with either hyphens or spaces, figuring out how to correctly separate a given ISBN number is complicated, because most of the parts do not use a fixed number of digits. ISBN issuance is country-specific, in that ISBNs are issued by the ISBN registration agency that is responsible for country or territory regardless of the publication language. Some ISBN registration agencies are based in national libraries or within ministries of culture, in other cases, the ISBN registration service is provided by organisations such as bibliographic data providers that are not government funded. In Canada, ISBNs are issued at no cost with the purpose of encouraging Canadian culture. In the United Kingdom, United States, and some countries, where the service is provided by non-government-funded organisations. Australia, ISBNs are issued by the library services agency Thorpe-Bowker
International Standard Book Number
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A 13-digit ISBN, 978-3-16-148410-0, as represented by an
EAN-13 bar code
