Bolívar is one of the 23 states of Venezuela. The state capital city is Ciudad Bolívar and the largest city is Ciudad Guayana. Bolívar State covers a total surface area of 242,801 km2 (93,746 sq mi) and as of the 2011 census, had a population of 1,410,964. The state contains Angel Falls.

The Bolivarian Republic of Venezuela is a federation made up of twenty-three states, a Capital District and the Federal Dependencies, which consist of many islands and islets in the Caribbean Sea. Venezuela claims the disputed Essequibo territory as one of its states, which it calls Guayana Esequiba, but the territory is controlled by Guyana as part of six of its regions.