1.
Carburetor
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A carburetor, or carburettor, or carburator, or carburetter is a device that blends air and fuel for an internal combustion engine in the proper ratio for combustion. It is sometimes shortened to carb in North America or carby in Australia. To carburate or carburet is to blend the air and fuel or to equip with a carburetor for that purpose, carburetors have largely been supplanted in the automotive and, to a lesser extent, aviation industries by fuel injection. They are still common on engines for lawn mowers, rototillers. The word carburetor comes from the French carbure meaning carbide, carburer means to combine with carbon. In fuel chemistry, the term has the specific meaning of increasing the carbon content of a fluid by mixing it with a volatile hydrocarbon. The first carburetor was invented by Samuel Morey in 1826, a carburetor was invented by an Italian, Luigi De Cristoforis, in 1876. Another carburetor was developed by Enrico Bernardi at the University of Padua in 1882, for his Motrice Pia, a carburetor was among the early patents by Karl Benz as he developed internal combustion engines and their components. Early carburetors were the surface type, in which air is charged with fuel by being passed over the surface of gasoline. In 1885, Wilhelm Maybach and Gottlieb Daimler developed a float carburetor for their engine based on the atomizer nozzle, hungarian engineers János Csonka and Donát Bánki patented a carburetor for a stationary engine in 1893. Frederick William Lanchester of Birmingham, England, experimented with the wick carburetor in cars, in 1896, Frederick and his brother built the first gasoline-driven car in England, a single cylinder 5 hp internal combustion engine with chain drive. Unhappy with the performance and power, they re-built the engine the next year into a horizontally opposed version using his new wick carburetor design. Carburetors were the method of fuel delivery for most US-made gasoline-fueled engines up until the late 1980s. 1991, Jeep Grand Wagoneer with the AMC360 cu in V8 engine, low-cost commercial vans and 4WDs in Australia continued with carburetors even into the 2000s, the last being the Mitsubishi Express van in 2003. Elsewhere, certain Lada cars used carburetors until 2006, many motorcycles still use carburetors for simplicitys sake, since a carburetor does not require an electrical system to function. EEC legislation required all vehicles sold and produced in countries to have a catalytic converter after December 1992. This legislation had been in the pipeline for some time, with cars becoming available with catalytic converters or fuel injection from around 1990. Fords first fuel-injected car was the Ford Capri RS2600 in 1970, general Motors launched its first fuel-injected car around the same time, when began to introduce fuel-injected engines to its Vauxhall Cavalier/Opel Ascona range
2.
Heat treating
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Heat treating is a group of industrial and metalworking processes used to alter the physical, and sometimes chemical, properties of a material. The most common application is metallurgical, Heat treatments are also used in the manufacture of many other materials, such as glass. Heat treatment involves the use of heating or chilling, normally to extreme temperatures, Heat treatment techniques include annealing, case hardening, precipitation strengthening, tempering, normalizing and quenching. Metallic materials consist of a microstructure of small crystals called grains or crystallites, the nature of the grains is one of the most effective factors that can determine the overall mechanical behavior of the metal. Heat treatment provides an efficient way to manipulate the properties of the metal by controlling the rate of diffusion, Heat treating is often used to alter the mechanical properties of a metallic alloy, manipulating properties such as the hardness, strength, toughness, ductility, and elasticity. The crystal structure consists of atoms that are grouped in a specific arrangement. In most elements, this order will rearrange itself, depending on conditions like temperature and pressure and this rearrangement, called allotropy or polymorphism, may occur several times, at many different temperatures for a particular metal. When in the state, the process of diffusion causes the atoms of the dissolved element to spread out. If the alloy is cooled to a state, the atoms of the dissolved constituents may migrate out of the solution. This type of diffusion, called precipitation, leads to nucleation and this forms a microstructure generally consisting of two or more distinct phases. Steel that has been cooled slowly, for instance, forms a structure composed of alternating layers of ferrite and cementite. After heating the steel to the phase and then quenching it in water. This is due to the fact that the steel will change from the phase to the martensite phase after quenching. It should be noted that some pearlite or ferrite may be present if the quench did not rapidly cool off all the steel, unlike iron-based alloys, most heat treatable alloys do not experience a ferrite transformation. In these alloys, the nucleation at the grain-boundaries often reinforces the structure of the crystal matrix, typically a slow process, depending on temperature, this is often referred to as age hardening. Many metals and non-metals exhibit a transformation when cooled quickly. When a metal is cooled quickly, the insoluble atoms may not be able to migrate out of the solution in time. This is called a diffusionless transformation, when the crystal matrix changes to its low temperature arrangement, the atoms of the solute become trapped within the lattice
3.
Iron
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Iron is a chemical element with symbol Fe and atomic number 26. It is a metal in the first transition series and it is by mass the most common element on Earth, forming much of Earths outer and inner core. It is the fourth most common element in the Earths crust, like the other group 8 elements, ruthenium and osmium, iron exists in a wide range of oxidation states, −2 to +6, although +2 and +3 are the most common. Elemental iron occurs in meteoroids and other low oxygen environments, but is reactive to oxygen, fresh iron surfaces appear lustrous silvery-gray, but oxidize in normal air to give hydrated iron oxides, commonly known as rust. Unlike the metals that form passivating oxide layers, iron oxides occupy more volume than the metal and thus flake off, Iron metal has been used since ancient times, although copper alloys, which have lower melting temperatures, were used even earlier in human history. Pure iron is soft, but is unobtainable by smelting because it is significantly hardened and strengthened by impurities, in particular carbon. A certain proportion of carbon steel, which may be up to 1000 times harder than pure iron. Crude iron metal is produced in blast furnaces, where ore is reduced by coke to pig iron, further refinement with oxygen reduces the carbon content to the correct proportion to make steel. Steels and iron alloys formed with metals are by far the most common industrial metals because they have a great range of desirable properties. Iron chemical compounds have many uses, Iron oxide mixed with aluminium powder can be ignited to create a thermite reaction, used in welding and purifying ores. Iron forms binary compounds with the halogens and the chalcogens, among its organometallic compounds is ferrocene, the first sandwich compound discovered. Iron plays an important role in biology, forming complexes with oxygen in hemoglobin and myoglobin. Iron is also the metal at the site of many important redox enzymes dealing with cellular respiration and oxidation and reduction in plants. A human male of average height has about 4 grams of iron in his body and this iron is distributed throughout the body in hemoglobin, tissues, muscles, bone marrow, blood proteins, enzymes, ferritin, hemosiderin, and transport in plasma. The mechanical properties of iron and its alloys can be evaluated using a variety of tests, including the Brinell test, Rockwell test, the data on iron is so consistent that it is often used to calibrate measurements or to compare tests. An increase in the content will cause a significant increase in the hardness. Maximum hardness of 65 Rc is achieved with a 0. 6% carbon content, because of the softness of iron, it is much easier to work with than its heavier congeners ruthenium and osmium. Because of its significance for planetary cores, the properties of iron at high pressures and temperatures have also been studied extensively
4.
Steel
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Steel is an alloy of iron and other elements, primarily carbon, that is widely used in construction and other applications because of its high tensile strength and low cost. Steels base metal is iron, which is able to take on two forms, body centered cubic and face centered cubic, depending on its temperature. It is the interaction of those allotropes with the elements, primarily carbon. In the body-centred cubic arrangement, there is an atom in the centre of each cube. Carbon, other elements, and inclusions within iron act as hardening agents that prevent the movement of dislocations that otherwise occur in the lattices of iron atoms. The carbon in steel alloys may contribute up to 2. 1% of its weight. Steels strength compared to pure iron is possible at the expense of irons ductility. With the invention of the Bessemer process in the mid-19th century and this was followed by Siemens-Martin process and then Gilchrist-Thomas process that refined the quality of steel. With their introductions, mild steel replaced wrought iron, further refinements in the process, such as basic oxygen steelmaking, largely replaced earlier methods by further lowering the cost of production and increasing the quality of the product. Today, steel is one of the most common materials in the world and it is a major component in buildings, infrastructure, tools, ships, automobiles, machines, appliances, and weapons. Modern steel is generally identified by various grades defined by assorted standards organizations, the noun steel originates from the Proto-Germanic adjective stakhlijan, which is related to stakhla. The carbon content of steel is between 0. 002% and 2. 1% by weight for plain iron–carbon alloys and these values vary depending on alloying elements such as manganese, chromium, nickel, iron, tungsten, carbon and so on. Basically, steel is an alloy that does not undergo eutectic reaction. In contrast, cast iron does undergo eutectic reaction, too little carbon content leaves iron quite soft, ductile, and weak. Carbon contents higher than those of steel make an alloy, commonly called pig iron, while iron alloyed with carbon is called carbon steel, alloy steel is steel to which other alloying elements have been intentionally added to modify the characteristics of steel. Common alloying elements include, manganese, nickel, chromium, molybdenum, boron, titanium, vanadium, tungsten, cobalt, and niobium. Additional elements are important in steel, phosphorus, sulfur, silicon, and traces of oxygen, nitrogen, and copper. Alloys with a higher than 2. 1% carbon content, depending on other element content, cast iron is not malleable even when hot, but it can be formed by casting as it has a lower melting point than steel and good castability properties
5.
Carbon
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Carbon is a chemical element with symbol C and atomic number 6. It is nonmetallic and tetravalent—making four electrons available to form covalent chemical bonds, three isotopes occur naturally, 12C and 13C being stable, while 14C is a radioactive isotope, decaying with a half-life of about 5,730 years. Carbon is one of the few elements known since antiquity, Carbon is the 15th most abundant element in the Earths crust, and the fourth most abundant element in the universe by mass after hydrogen, helium, and oxygen. It is the second most abundant element in the body by mass after oxygen. The atoms of carbon can bond together in different ways, termed allotropes of carbon, the best known are graphite, diamond, and amorphous carbon. The physical properties of carbon vary widely with the allotropic form, for example, graphite is opaque and black while diamond is highly transparent. Graphite is soft enough to form a streak on paper, while diamond is the hardest naturally occurring material known, graphite is a good electrical conductor while diamond has a low electrical conductivity. Under normal conditions, diamond, carbon nanotubes, and graphene have the highest thermal conductivities of all known materials, all carbon allotropes are solids under normal conditions, with graphite being the most thermodynamically stable form. They are chemically resistant and require high temperature to react even with oxygen, the most common oxidation state of carbon in inorganic compounds is +4, while +2 is found in carbon monoxide and transition metal carbonyl complexes. The largest sources of carbon are limestones, dolomites and carbon dioxide, but significant quantities occur in organic deposits of coal, peat, oil. For this reason, carbon has often referred to as the king of the elements. The allotropes of carbon graphite, one of the softest known substances, and diamond. It bonds readily with other small atoms including other carbon atoms, Carbon is known to form almost ten million different compounds, a large majority of all chemical compounds. Carbon also has the highest sublimation point of all elements, although thermodynamically prone to oxidation, carbon resists oxidation more effectively than elements such as iron and copper that are weaker reducing agents at room temperature. Carbon is the element, with a ground-state electron configuration of 1s22s22p2. Its first four ionisation energies,1086.5,2352.6,4620.5 and 6222.7 kJ/mol, are higher than those of the heavier group 14 elements. Carbons covalent radii are normally taken as 77.2 pm,66.7 pm and 60.3 pm, although these may vary depending on coordination number, in general, covalent radius decreases with lower coordination number and higher bond order. Carbon compounds form the basis of all life on Earth
6.
Charcoal
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Charcoal is a lightweight, black residue, consisting of carbon and any remaining ash, obtained by removing water and other volatile constituents from animal and vegetation substances. Charcoal is usually produced by slow pyrolysis- the heating of wood or other substances in the absence of oxygen, the whole pile is covered with turf or moistened clay. The firing is begun at the bottom of the flue, the success of the operation depends upon the rate of the combustion. The operation is so delicate that it was left to colliers. They often lived alone in small huts in order to tend their wood piles, for example, in the Harz Mountains of Germany, charcoal burners lived in conical huts called Köten which are still much in evidence today. The massive production of charcoal was a cause of deforestation. The increasing scarcity of easily harvested wood was a factor behind the switch to fossil fuel equivalents, mainly coal. Charcoal made at 300 °C is brown, soft and friable, and readily inflames at 380 °C, made at higher temperatures it is hard and brittle, in Finland and Scandinavia, the charcoal was considered the by-product of wood tar production. The best tar came from pine, thus pinewoods were cut down for tar pyrolysis, the residual charcoal was widely used as substitute for metallurgical coke in blast furnaces for smelting. Tar production led to deforestation, it has been estimated all Finnish forests are younger than 300 years. The end of tar production at the end of the 19th century resulted in rapid re-forestation, the charcoal briquette was first invented and patented by Ellsworth B. A. Zwoyer of Pennsylvania in 1897 and was produced by the Zwoyer Fuel Company. The process was popularized by Henry Ford, who used wood. Ford Charcoal went on to become the Kingsford Company, Charcoal has been made by various methods. The traditional method in Britain used a clamp and this is essentially a pile of wooden logs leaning against a chimney. The chimney consists of 4 wooden stakes held up by some rope, the logs are completely covered with soil and straw allowing no air to enter. It must be lit by introducing some burning fuel into the chimney, if the soil covering gets torn by the fire, additional soil is placed on the cracks. Once the burn is complete, the chimney is plugged to prevent air from entering, the true art of this production method is in managing the sufficient generation of heat, and its transfer to wood parts in the process of being carbonised. A strong disadvantage of this method is the huge amount of emissions that are harmful to human health
7.
Furnace
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A furnace is a device used for high-temperature heating. The name derives from Greek word fornax, which means oven, the heat energy to fuel a furnace may be supplied directly by fuel combustion, by electricity such as the electric arc furnace, or through induction heating in induction furnaces. Furnace may also be a synonym for kiln, a used in the production of ceramics. Furnaces can be classified into four categories, based on efficiency. The first category would be natural draft, atmospheric burner furnaces and these furnaces consisted of cast-iron or riveted-steel heat exchangers built within an outer shell of brick, masonry, or steel. The heat exchangers were vented through brick or masonry chimneys, air circulation depended on large, upwardly pitched pipes constructed of wood or metal The pipes would channel the warm air into floor or wall vents inside the home. This method of heating worked because warm air rises, the system was simple, had few controls, a single automatic gas valve, and no blower. These furnaces could be made to work with any fuel simply by adapting the burner area and they have been operated with wood, coke, coal, trash, paper, natural gas, and fuel oil. Furnaces that used solid fuels required daily maintenance to remove ash, in later years, these furnaces were adapted with electric blowers to aid air distribution and speed moving heat into the home. The second category of furnace is the forced-air, atmospheric burner style with a cast-iron or sectional steel heat exchanger. Through the 1950s and 1960s, this style of furnace was used to replace the big, natural draft systems, the heated air was moved by blowers which were belt driven and designed for a wide range of speeds. These furnaces were still big and bulky compared to modern furnaces, energy efficiency would range anywhere from just over 50% to upward of 65% AFUE. This style furnace still used large, masonry or brick chimneys for flues and was designed to accommodate air-conditioning systems. The third category of furnace is the draft, mid-efficiency furnace with a steel heat exchanger. These furnaces were physically much more compact than the previous styles and they were equipped with combustion air blowers that would pull air through the heat exchanger which greatly increased fuel efficiency while allowing the heat exchangers to become smaller. These furnaces may have multi-speed blowers and were designed to work with central air-conditioning systems, the fourth category of furnace is the high-efficiency, or condensing furnace. High-efficiency furnaces can achieve from 89% to 98% fuel efficiency and this style of furnace includes a sealed combustion area, combustion draft inducer and a secondary heat exchanger. Because the heat exchanger removes most of the heat from the exhaust gas, it actually condenses water vapor, the vent pipes are normally installed with PVC pipe versus metal vent pipe to prevent corrosion
8.
Vacuum
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Vacuum is space void of matter. The word stems from the Latin adjective vacuus for vacant or void, an approximation to such vacuum is a region with a gaseous pressure much less than atmospheric pressure. In engineering and applied physics on the hand, vacuum refers to any space in which the pressure is lower than atmospheric pressure. The Latin term in vacuo is used to describe an object that is surrounded by a vacuum, the quality of a partial vacuum refers to how closely it approaches a perfect vacuum. Other things equal, lower gas pressure means higher-quality vacuum, for example, a typical vacuum cleaner produces enough suction to reduce air pressure by around 20%. Ultra-high vacuum chambers, common in chemistry, physics, and engineering, operate below one trillionth of atmospheric pressure, outer space is an even higher-quality vacuum, with the equivalent of just a few hydrogen atoms per cubic meter on average. In the electromagnetism in the 19th century, vacuum was thought to be filled with a medium called aether, in modern particle physics, the vacuum state is considered the ground state of matter. Vacuum has been a frequent topic of debate since ancient Greek times. Evangelista Torricelli produced the first laboratory vacuum in 1643, and other techniques were developed as a result of his theories of atmospheric pressure. A torricellian vacuum is created by filling a glass container closed at one end with mercury. Vacuum became an industrial tool in the 20th century with the introduction of incandescent light bulbs and vacuum tubes. The recent development of human spaceflight has raised interest in the impact of vacuum on human health, the word vacuum comes from Latin an empty space, void, noun use of neuter of vacuus, meaning empty, related to vacare, meaning be empty. Vacuum is one of the few words in the English language that contains two consecutive letters u. Historically, there has been dispute over whether such a thing as a vacuum can exist. Ancient Greek philosophers debated the existence of a vacuum, or void, in the context of atomism, Aristotle believed that no void could occur naturally, because the denser surrounding material continuum would immediately fill any incipient rarity that might give rise to a void. Almost two thousand years after Plato, René Descartes also proposed a geometrically based alternative theory of atomism, without the problematic nothing–everything dichotomy of void, by the ancient definition however, directional information and magnitude were conceptually distinct. The explanation of a clepsydra or water clock was a topic in the Middle Ages. Although a simple wine skin sufficed to demonstrate a partial vacuum, in principle and he concluded that airs volume can expand to fill available space, and he suggested that the concept of perfect vacuum was incoherent. However, according to Nader El-Bizri, the physicist Ibn al-Haytham and the Mutazili theologians disagreed with Aristotle and Al-Farabi, using geometry, Ibn al-Haytham mathematically demonstrated that place is the imagined three-dimensional void between the inner surfaces of a containing body
9.
Corrosion
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Corrosion is a natural process, which converts a refined metal to a more chemically-stable form, such as its oxide, hydroxide, or sulfide. It is the destruction of materials by chemical and/or electrochemical reaction with their environment. Corrosion engineering is the dedicated to controlling and stopping corrosion. In the most common use of the word, this means electrochemical oxidation of metal in reaction with an oxidant such as oxygen or sulfur, rusting, the formation of iron oxides, is a well-known example of electrochemical corrosion. This type of damage typically produces oxide or salt of the original metal, corrosion can also occur in materials other than metals, such as ceramics or polymers, although in this context, the term degradation is more common. Corrosion degrades the useful properties of materials and structures including strength, appearance and permeability to liquids, many structural alloys corrode merely from exposure to moisture in air, but the process can be strongly affected by exposure to certain substances. Corrosion can be concentrated locally to form a pit or crack, because corrosion is a diffusion-controlled process, it occurs on exposed surfaces. As a result, methods to reduce the activity of the surface, such as passivation and chromate conversion. However, some corrosion mechanisms are less visible and less predictable, in a galvanic couple, the more active metal corrodes at an accelerated rate and the more noble metal corrodes at a slower rate. When immersed separately, each metal corrodes at its own rate, what type of metal to use is readily determined by following the galvanic series. For example, zinc is used as a sacrificial anode for steel structures. Galvanic corrosion is of major interest to the industry and also anywhere water contacts pipes or metal structures. Factors such as size of anode, types of metal. The surface area ratio of the anode and cathode directly affects the corrosion rates of the materials, galvanic corrosion is often prevented by the use of sacrificial anodes. In any given environment, one metal will be more noble or more active than others. Two metals in electrical contact share the same electrons, so that the tug-of-war at each surface is analogous to competition for free electrons between the two materials. Using the electrolyte as a host for the flow of ions in the same direction, the resulting mass flow or electric current can be measured to establish a hierarchy of materials in the medium of interest. This hierarchy is called a series and is useful in predicting and understanding corrosion
10.
Stainless steel
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In metallurgy, stainless steel, also known as inox steel or inox from French inoxydable, is a steel alloy with a minimum of 10. 5% chromium content by mass. Stainless steel is notable for its resistance, and it is widely used for food handling. Stainless steel does not readily corrode, rust or stain with water as ordinary steel does, however, it is not fully stain-proof in low-oxygen, high-salinity, or poor air-circulation environments. There are various grades and surface finishes of stainless steel to suit the environment the alloy must endure, Stainless steel is used where both the properties of steel and corrosion resistance are required. Stainless steel differs from carbon steel by the amount of chromium present, unprotected carbon steel rusts readily when exposed to air and moisture. This iron oxide film is active and accelerates corrosion by making it easier for more iron oxide to form, since iron oxide has lower density than steel, the film expands and tends to flake and fall away. In comparison, stainless steels contain sufficient chromium to undergo passivation and this layer prevents further corrosion by blocking oxygen diffusion to the steel surface and stops corrosion from spreading into the bulk of the metal. Passivation occurs only if the proportion of chromium is high enough, Stainless steel’s resistance to corrosion and staining, low maintenance, and familiar lustre make it an ideal material for many applications. Storage tanks and tankers used to transport orange juice and other food are made of stainless steel. This also influences its use in kitchens and food processing plants, as it can be steam-cleaned and sterilized. High oxidation resistance in air at ambient temperature is achieved with addition of a minimum of 13% chromium. The chromium forms a layer of chromium oxide when exposed to oxygen. The layer is too thin to be visible, and the metal remains lustrous, the layer is impervious to water and air, protecting the metal beneath, and this layer quickly reforms when the surface is scratched. This phenomenon is called passivation and is seen in other metals, corrosion resistance can be adversely affected if the component is used in a non-oxygenated environment, a typical example being underwater keel bolts buried in timber. When stainless steel parts such as nuts and bolts are forced together, when forcibly disassembled, the welded material may be torn and pitted, a destructive effect known as galling. Galling can be avoided by the use of materials for the parts forced together, for example bronze and stainless steel. However, two different alloys electrically connected in a humid, even mildly acidic environment may act as a voltaic pile, nitronic alloys, made by selective alloying with manganese and nitrogen, may have a reduced tendency to gall. Additionally, threaded joints may be lubricated to provide a film between the two parts and prevent galling, low-temperature carburizing is another option that virtually eliminates galling and allows the use of similar materials without the risk of corrosion and the need for lubrication
