1.
Oxide minerals
–
The oxide mineral class includes those minerals in which the oxide anion is bonded to one or more metal ions. The hydroxide bearing minerals are typically included in the oxide class, the minerals with complex anion groups such as the silicates, sulfates, carbonates and phosphates are classed separately. This list uses it to modify the Classification of Nickel–Strunz,00 Clinobirnessite*,00 Kleberite*,00 Chubutite*,00 Struverite
2.
Chemical formula
–
These are limited to a single typographic line of symbols, which may include subscripts and superscripts. A chemical formula is not a name, and it contains no words. Although a chemical formula may imply certain simple chemical structures, it is not the same as a full chemical structural formula. Chemical formulas can fully specify the structure of only the simplest of molecules and chemical substances, the simplest types of chemical formulas are called empirical formulas, which use letters and numbers indicating the numerical proportions of atoms of each type. Molecular formulas indicate the numbers of each type of atom in a molecule. For example, the formula for glucose is CH2O, while its molecular formula is C6H12O6. This is possible if the relevant bonding is easy to show in one dimension, an example is the condensed molecular/chemical formula for ethanol, which is CH3-CH2-OH or CH3CH2OH. For reasons of structural complexity, there is no condensed chemical formula that specifies glucose, chemical formulas may be used in chemical equations to describe chemical reactions and other chemical transformations, such as the dissolving of ionic compounds into solution. A chemical formula identifies each constituent element by its chemical symbol, in empirical formulas, these proportions begin with a key element and then assign numbers of atoms of the other elements in the compound, as ratios to the key element. For molecular compounds, these numbers can all be expressed as whole numbers. For example, the formula of ethanol may be written C2H6O because the molecules of ethanol all contain two carbon atoms, six hydrogen atoms, and one oxygen atom. Some types of compounds, however, cannot be written with entirely whole-number empirical formulas. An example is boron carbide, whose formula of CBn is a variable non-whole number ratio with n ranging from over 4 to more than 6.5. When the chemical compound of the consists of simple molecules. These types of formulas are known as molecular formulas and condensed formulas. A molecular formula enumerates the number of atoms to reflect those in the molecule, so that the formula for glucose is C6H12O6 rather than the glucose empirical formula. However, except for very simple substances, molecular chemical formulas lack needed structural information, for simple molecules, a condensed formula is a type of chemical formula that may fully imply a correct structural formula. For example, ethanol may be represented by the chemical formula CH3CH2OH
3.
Crystal system
–
In crystallography, the terms crystal system, crystal family and lattice system each refer to one of several classes of space groups, lattices, point groups or crystals. Informally, two crystals are in the crystal system if they have similar symmetries, though there are many exceptions to this. Space groups and crystals are divided into seven crystal systems according to their point groups, five of the crystal systems are essentially the same as five of the lattice systems, but the hexagonal and trigonal crystal systems differ from the hexagonal and rhombohedral lattice systems. The six crystal families are formed by combining the hexagonal and trigonal crystal systems into one hexagonal family, a lattice system is a class of lattices with the same set of lattice point groups, which are subgroups of the arithmetic crystal classes. The 14 Bravais lattices are grouped into seven lattice systems, triclinic, monoclinic, orthorhombic, tetragonal, rhombohedral, hexagonal, in a crystal system, a set of point groups and their corresponding space groups are assigned to a lattice system. Of the 32 point groups that exist in three dimensions, most are assigned to only one system, in which case both the crystal and lattice systems have the same name. However, five point groups are assigned to two systems, rhombohedral and hexagonal, because both exhibit threefold rotational symmetry. These point groups are assigned to the crystal system. In total there are seven crystal systems, triclinic, monoclinic, orthorhombic, tetragonal, trigonal, hexagonal, a crystal family is determined by lattices and point groups. It is formed by combining crystal systems which have space groups assigned to a lattice system. In three dimensions, the families and systems are identical, except the hexagonal and trigonal crystal systems. In total there are six families, triclinic, monoclinic, orthorhombic, tetragonal, hexagonal. Spaces with less than three dimensions have the number of crystal systems, crystal families and lattice systems. In one-dimensional space, there is one crystal system, in 2D space, there are four crystal systems, oblique, rectangular, square and hexagonal. The relation between three-dimensional crystal families, crystal systems and lattice systems is shown in the table, Note. To avoid confusion of terminology, the term trigonal lattice is not used, if the original structure and inverted structure are identical, then the structure is centrosymmetric. Still, even for non-centrosymmetric case, inverted structure in some cases can be rotated to align with the original structure and this is the case of non-centrosymmetric achiral structure. If the inverted structure cannot be rotated to align with the structure, then the structure is chiral
4.
Cubic crystal system
–
In crystallography, the cubic crystal system is a crystal system where the unit cell is in the shape of a cube. This is one of the most common and simplest shapes found in crystals and minerals, there are three main varieties of these crystals, Primitive cubic Body-centered cubic, Face-centered cubic Each is subdivided into other variants listed below. Note that although the cell in these crystals is conventionally taken to be a cube. This is related to the fact that in most cubic crystal systems, a classic isometric crystal has square or pentagonal faces. The three Bravais lattices in the crystal system are, The primitive cubic system consists of one lattice point on each corner of the cube. Each atom at a point is then shared equally between eight adjacent cubes, and the unit cell therefore contains in total one atom. The body-centered cubic system has one point in the center of the unit cell in addition to the eight corner points. It has a net total of 2 lattice points per unit cell, Each sphere in a cF lattice has coordination number 12. The face-centered cubic system is related to the hexagonal close packed system. The plane of a cubic system is a hexagonal grid. Attempting to create a C-centered cubic crystal system would result in a simple tetragonal Bravais lattice, there are a total 36 cubic space groups. Other terms for hexoctahedral are, normal class, holohedral, ditesseral central class, a simple cubic unit cell has a single cubic void in the center. Additionally, there are 24 tetrahedral voids located in a square spacing around each octahedral void and these tetrahedral voids are not local maxima and are not technically voids, but they do occasionally appear in multi-atom unit cells. A face-centered cubic unit cell has eight tetrahedral voids located midway between each corner and the center of the cell, for a total of eight net tetrahedral voids. One important characteristic of a structure is its atomic packing factor. This is calculated by assuming all the atoms are identical spheres. The atomic packing factor is the proportion of space filled by these spheres, assuming one atom per lattice point, in a primitive cubic lattice with cube side length a, the sphere radius would be a⁄2 and the atomic packing factor turns out to be about 0.524. Similarly, in a bcc lattice, the atomic packing factor is 0.680, as a rule, since atoms in a solid attract each other, the more tightly packed arrangements of atoms tend to be more common
5.
Crystallographic point group
–
For a periodic crystal, the group must also be consistent with maintenance of the three-dimensional translational symmetry that defines crystallinity. The macroscopic properties of a crystal would look exactly the same before, in the classification of crystals, each point group is also known as a crystal class. There are infinitely many three-dimensional point groups, however, the crystallographic restriction of the infinite families of general point groups results in there being only 32 crystallographic point groups. These 32 point groups are one-and-the same as the 32 types of morphological crystalline symmetries derived in 1830 by Johann Friedrich Christian Hessel from a consideration of observed crystal forms, the point groups are denoted by their component symmetries. There are a few standard notations used by crystallographers, mineralogists, for the correspondence of the two systems below, see crystal system. In Schoenflies notation, point groups are denoted by a symbol with a subscript. The symbols used in crystallography mean the following, Cn indicates that the group has a rotation axis. Cnh is Cn with the addition of a plane perpendicular to the axis of rotation. Cnv is Cn with the addition of n mirror planes parallel to the axis of rotation, s2n denotes a group that contains only a 2n-fold rotation-reflection axis. Dn indicates that the group has a rotation axis plus n twofold axes perpendicular to that axis. Dnh has, in addition, a plane perpendicular to the n-fold axis. Dnd has, in addition to the elements of Dn, mirror planes parallel to the n-fold axis, the letter T indicates that the group has the symmetry of a tetrahedron. Td includes improper rotation operations, T excludes improper rotation operations, the letter O indicates that the group has the symmetry of an octahedron, with or without improper operations. Due to the crystallographic restriction theorem, n =1,2,3,4, d4d and D6d are actually forbidden because they contain improper rotations with n=8 and 12 respectively. The 27 point groups in the table plus T, Td, Th, O, an abbreviated form of the Hermann–Mauguin notation commonly used for space groups also serves to describe crystallographic point groups. Group names are Molecular symmetry Point group Space group Point groups in three dimensions Crystal system Point-group symbols in International Tables for Crystallography,12.1, pp. 818-820 Names and symbols of the 32 crystal classes in International Tables for Crystallography. 10.1, p.794 Pictorial overview of the 32 groups Point Groups - Flow Chart Inorganic Chemistry Group Theory Practice Problems
6.
H-M symbol
–
In geometry, Hermann–Mauguin notation is used to represent the symmetry elements in point groups, plane groups and space groups. It is named after the German crystallographer Carl Hermann and the French mineralogist Charles-Victor Mauguin and this notation is sometimes called international notation, because it was adopted as standard by the International Tables For Crystallography since their first edition in 1935. Rotation axes are denoted by a number n —1,2,3,4,5,6,7,8, for improper rotations, Hermann–Mauguin symbols show rotoinversion axes, unlike Schoenflies and Shubnikov notations, where the preference is given to rotation-reflection axes. The rotoinversion axes are represented by the number with a macron. The symbol for a plane is m. The direction of the plane is defined as the direction of perpendicular to the face. Hermann–Mauguin symbols show symmetrically non-equivalent axes and planes, the direction of a symmetry element is represented by its position in the Hermann–Mauguin symbol. If a rotation axis n and a mirror plane m have the same direction, if two or more axes have the same direction, the axis with higher symmetry is shown. Higher symmetry means that the axis generates a pattern with more points, for example, rotation axes 3,4,5,6,7,8 generate 3-, 4-, 5-, 6-, 7-, 8-point patterns, respectively. Improper rotation axes 3,4,5,6,7,8 generate 6-, 4-, 10-, 6-, 14-, 8-point patterns, if both, the rotation and rotoinversion axes satisfy the previous rule, the rotation axis should be chosen. For example, 3/m combination is equivalent to 6, since 6 generates 6 points, and 3 generates only 3,6 should be written instead of 3/m. Analogously, in the case when both 3 and 3 axes are present,3 should be written, however we write 4/m, not 4/m, because both 4 and 4 generate four points. Finally, the Hermann–Mauguin symbol depends on the type of the group and these groups may contain only two-fold axes, mirror planes, and inversion center. These are the point groups 1 and 1,2, m, and 2/m, and 222, 2/m2/m2/m. If the symbol contains three positions, then they denote symmetry elements in the x, y, z direction, First position — primary direction — z direction, assigned to the higher-order axis. Second position — symmetrically equivalent secondary directions, which are perpendicular to the z-axis and these can be 2, m, or 2/m. Third position — symmetrically equivalent tertiary directions, passing between secondary directions and these can be 2, m, or 2/m. These are the crystallographic groups 3,32, 3m,3, and 32/m,4,422, 4mm,4, 42m, 4/m, and 4/m2/m2/m, and 6,622, 6mm,6, 6m2, 6/m, and 6/m2/m2/m
7.
Space group
–
In mathematics, physics and chemistry, a space group is the symmetry group of a configuration in space, usually in three dimensions. In three dimensions, there are 219 distinct types, or 230 if chiral copies are considered distinct, Space groups are also studied in dimensions other than 3 where they are sometimes called Bieberbach groups, and are discrete cocompact groups of isometries of an oriented Euclidean space. In crystallography, space groups are called the crystallographic or Fedorov groups. A definitive source regarding 3-dimensional space groups is the International Tables for Crystallography, in 1879 Leonhard Sohncke listed the 65 space groups whose elements preserve the orientation. More accurately, he listed 66 groups, but Fedorov and Schönflies both noticed that two of them were really the same, the space groups in 3 dimensions were first enumerated by Fedorov, and shortly afterwards were independently enumerated by Schönflies. The correct list of 230 space groups was found by 1892 during correspondence between Fedorov and Schönflies, burckhardt describes the history of the discovery of the space groups in detail. The space groups in three dimensions are made from combinations of the 32 crystallographic point groups with the 14 Bravais lattices, the combination of all these symmetry operations results in a total of 230 different space groups describing all possible crystal symmetries. The elements of the space group fixing a point of space are rotations, reflections, the identity element, the translations form a normal abelian subgroup of rank 3, called the Bravais lattice. There are 14 possible types of Bravais lattice, the quotient of the space group by the Bravais lattice is a finite group which is one of the 32 possible point groups. Translation is defined as the moves from one point to another point. A glide plane is a reflection in a plane, followed by a parallel with that plane. This is noted by a, b or c, depending on which axis the glide is along. There is also the n glide, which is a glide along the half of a diagonal of a face, and the d glide, the latter is called the diamond glide plane as it features in the diamond structure. In 17 space groups, due to the centering of the cell, the glides occur in two directions simultaneously, i. e. the same glide plane can be called b or c, a or b. For example, group Abm2 could be also called Acm2, group Ccca could be called Cccb, in 1992, it was suggested to use symbol e for such planes. The symbols for five groups have been modified, A screw axis is a rotation about an axis. These are noted by a number, n, to describe the degree of rotation, the degree of translation is then added as a subscript showing how far along the axis the translation is, as a portion of the parallel lattice vector. So,21 is a rotation followed by a translation of 1/2 of the lattice vector
8.
Crystal structure
–
In crystallography, crystal structure is a description of the ordered arrangement of atoms, ions or molecules in a crystalline material. Ordered structures occur from the nature of the constituent particles to form symmetric patterns that repeat along the principal directions of three-dimensional space in matter. The smallest group of particles in the material that constitutes the pattern is the unit cell of the structure. The unit cell completely defines the symmetry and structure of the crystal lattice. The repeating patterns are said to be located at the points of the Bravais lattice, the lengths of the principal axes, or edges, of the unit cell and the angles between them are the lattice constants, also called lattice parameters. The symmetry properties of the crystal are described by the concept of space groups, all possible symmetric arrangements of particles in three-dimensional space may be described by the 230 space groups. The crystal structure and symmetry play a role in determining many physical properties, such as cleavage, electronic band structure. The crystal structure of a material can be described in terms of its unit cell, the unit cell is a box containing one or more atoms arranged in three dimensions. The unit cells stacked in three-dimensional space describe the arrangement of atoms of the crystal. Commonly, atomic positions are represented in terms of fractional coordinates, the atom positions within the unit cell can be calculated through application of symmetry operations to the asymmetric unit. The asymmetric unit refers to the smallest possible occupation of space within the unit cell and this does not, however imply that the entirety of the asymmetric unit must lie within the boundaries of the unit cell. Symmetric transformations of atom positions are calculated from the group of the crystal structure. Vectors and planes in a lattice are described by the three-value Miller index notation. It uses the indices ℓ, m, and n as directional parameters, which are separated by 90°, by definition, the syntax denotes a plane that intercepts the three points a1/ℓ, a2/m, and a3/n, or some multiple thereof. That is, the Miller indices are proportional to the inverses of the intercepts of the plane with the unit cell, if one or more of the indices is zero, it means that the planes do not intersect that axis. A plane containing a coordinate axis is translated so that it no longer contains that axis before its Miller indices are determined, the Miller indices for a plane are integers with no common factors. Negative indices are indicated with horizontal bars, as in, in an orthogonal coordinate system for a cubic cell, the Miller indices of a plane are the Cartesian components of a vector normal to the plane. Likewise, the planes are geometric planes linking nodes
9.
Crystal habit
–
In mineralogy, crystal habit is the characteristic external shape of an individual crystal or crystal group. A single crystals habit is a description of its shape and its crystallographic forms. Recognizing the habit may help in identifying a mineral, when the faces are well-developed due to uncrowded growth a crystal is called euhedral, one with partially developed faces is subhedral, and one with undeveloped crystal faces is called anhedral. The long axis of a quartz crystal typically has a six-sided prismatic habit with parallel opposite faces. Aggregates can be formed of individual crystals with euhedral to anhedral grains, the arrangement of crystals within the aggregate can be characteristic of certain minerals. For example, minerals used for asbestos insulation often grow in a fibrous habit, the terms used by mineralogists to report crystal habits describe the typical appearance of an ideal mineral. Recognizing the habit can aid in identification as some habits are characteristic, most minerals, however, do not display ideal habits due to conditions during crystallization. Minerals belonging to the crystal system do not necessarily exhibit the same habit. Some habits of a mineral are unique to its variety and locality, For example, while most sapphires form elongate barrel-shaped crystals, ordinarily, the latter habit is seen only in ruby. Sapphire and ruby are both varieties of the mineral, corundum. Some minerals may replace other existing minerals while preserving the originals habit, a classic example is tigers eye quartz, crocidolite asbestos replaced by silica. While quartz typically forms prismatic crystals, in tigers eye the original fibrous habit of crocidolite is preserved, the names of crystal habits are derived from, Predominant crystal faces. Abnormal grain growth Grain growth Crystallization
10.
Crystal twinning
–
Crystal twinning occurs when two separate crystals share some of the same crystal lattice points in a symmetrical manner. The result is an intergrowth of two separate crystals in a variety of specific configurations, a twin boundary or composition surface separates the two crystals. Crystallographers classify twinned crystals by a number of twin laws and these twin laws are specific to the crystal system. The type of twinning can be a tool in mineral identification. Twinning can often be a problem in X-ray crystallography, as a crystal does not produce a simple diffraction pattern. Simple twinned crystals may be contact twins or penetration twins, contact twins share a single composition surface often appearing as mirror images across the boundary. Plagioclase, quartz, gypsum, and spinel often exhibit contact twinning, merohedral twinning occurs when the lattices of the contact twins superimpose in three dimensions, such as by relative rotation of one twin from the other. In penetration twins the individual crystals have the appearance of passing through each other in a symmetrical manner, orthoclase, staurolite, pyrite, and fluorite often show penetration twinning. If several twin crystal parts are aligned by the same twin law they are referred to as multiple or repeated twins, if these multiple twins are aligned in parallel they are called polysynthetic twins. When the multiple twins are not parallel they are cyclic twins, albite, calcite, and pyrite often show polysynthetic twinning. Closely spaced polysynthetic twinning is often observed as striations or fine lines on the crystal face. Rutile, aragonite, cerussite, and chrysoberyl often exhibit cyclic twinning, 2-normal twin, -when the twin plane and compositional plane lies noramally. 3-complex twin, -combination of parallel twinning and normal twinning on one compositional plane, there are three modes of formation of twinned crystals. Growth twins are the result of an interruption or change in the lattice during formation or growth due to a possible deformation from a larger substituting ion, deformation or gliding twins are the result of stress on the crystal after the crystal has formed. If a FCC metal like aluminum experiences extreme stresses, it will experience twinning as seen in the case of explosions, deformation twinning is a common result of regional metamorphism. Crystals that grow adjacent to each other may be aligned to resemble twinning and this parallel growth simply reduces system energy and is not twinning. Twin boundaries occur when two crystals of the same type intergrow, so only a slight misorientation exists between them. It is a highly symmetrical interface, often with one crystal the mirror image of the other, also and this is also a much lower-energy interface than the grain boundaries that form when crystals of arbitrary orientation grow together
11.
Cleavage (crystal)
–
Cleavage, in mineralogy, is the tendency of crystalline materials to split along definite crystallographic structural planes. Cleavage forms parallel to planes, Basal or pinacoidal cleavage occurs when there is only one cleavage plane. Mica also has basal cleavage, this is why mica can be peeled into thin sheets, cubic cleavage occurs on when there are three cleavage planes intersecting at 90 degrees. Halite has cubic cleavage, and therefore, when halite crystals are broken, octahedral cleavage occurs when there are four cleavage planes in a crystal. Octahedral cleavage is common for semiconductors, rhombohedral cleavage occurs when there are three cleavage planes intersecting at angles that are not 90 degrees. Prismatic cleavage occurs when there are two planes in a crystal. Dodecahedral cleavage occurs when there are six cleavage planes in a crystal, crystal parting occurs when minerals break along planes of structural weakness due to external stress or along twin composition planes. Parting breaks are very similar in appearance to cleavage, but only due to stress. Examples include magnetite which shows octahedral parting, the parting of corundum. Cleavage is a property traditionally used in mineral identification, both in hand specimen and microscopic examination of rock and mineral studies. As an example, the angles between the cleavage planes for the pyroxenes and the amphiboles are diagnostic. Crystal cleavage is of importance in the electronics industry and in the cutting of gemstones. Precious stones are generally cleaved by impact, as in diamond cutting, synthetic single crystals of semiconductor materials are generally sold as thin wafers which are much easier to cleave. Elemental semiconductors are diamond cubic, a group for which octahedral cleavage is observed. This means that some orientations of wafer allow near-perfect rectangles to be cleaved, most other commercial semiconductors can be made in the related zinc blende structure, with similar cleavage planes. Cleavage Mineral galleries, Mineral properties – Cleavage
12.
Fracture (mineralogy)
–
In the field of mineralogy, fracture is the texture and shape of a rocks surface formed when a mineral is fractured. Minerals often have a highly distinctive fracture, making it a feature used in their identification. Fracture differs from cleavage in that the latter involves clean splitting along the planes of the minerals crystal structure. All minerals exhibit fracture, but when very strong cleavage is present, conchoidal fracture breakage that resembles the concentric ripples of a mussel shell. It often occurs in amorphous or fine-grained minerals such as flint, opal or obsidian, subconchoidal fracture is similar to conchoidal fracture, but with less significant curvature. Earthy fracture is reminiscent of freshly broken soil and it is frequently seen in relatively soft, loosely bound minerals, such as limonite, kaolinite and aluminite. Hackly fracture is jagged, sharp and not even and it occurs when metals are torn, and so is often encountered in native metals such as copper and silver. Splintery fracture comprises sharp elongated points and it is particularly seen in fibrous minerals such as chrysotile, but may also occur in non-fibrous minerals such as kyanite. Uneven fracture is a surface or one with random irregularities. It occurs in a range of minerals including arsenopyrite, pyrite and magnetite. Rudolf Duda and Lubos Rejl, Minerals of the World http, //www. galleries. com/minerals/property/fracture. htm
13.
Mohs scale of mineral hardness
–
The Mohs scale of mineral hardness is a qualitative ordinal scale characterizing scratch resistance of various minerals through the ability of harder material to scratch softer material. Created in 1812 by German geologist and mineralogist Friedrich Mohs, it is one of several definitions of hardness in materials science, while greatly facilitating the identification of minerals in the field, the Mohs scale does not show how well hard materials perform in an industrial setting. Despite its lack of precision, the Mohs scale is highly relevant for field geologists, the Mohs scale hardness of minerals can be commonly found in reference sheets. Reference materials may be expected to have a uniform Mohs hardness, the Mohs scale of mineral hardness is based on the ability of one natural sample of mineral to scratch another mineral visibly. The samples of matter used by Mohs are all different minerals, Minerals are pure substances found in nature. Rocks are made up of one or more minerals, as the hardest known naturally occurring substance when the scale was designed, diamonds are at the top of the scale. The hardness of a material is measured against the scale by finding the hardest material that the material can scratch. For example, if material is scratched by apatite but not by fluorite. Scratching a material for the purposes of the Mohs scale means creating non-elastic dislocations visible to the naked eye, frequently, materials that are lower on the Mohs scale can create microscopic, non-elastic dislocations on materials that have a higher Mohs number. The Mohs scale is an ordinal scale. For example, corundum is twice as hard as topaz, the table below shows the comparison with the absolute hardness measured by a sclerometer, with pictorial examples. On the Mohs scale, a streak plate has a hardness of 7.0, using these ordinary materials of known hardness can be a simple way to approximate the position of a mineral on the scale. The table below incorporates additional substances that may fall between levels, Comparison between Hardness and Hardness, Mohs hardness of elements is taken from G. V, samsonov in Handbook of the physicochemical properties of the elements, IFI-Plenum, New York, USA,1968. The Hardness of Minerals and Rocks
14.
Lustre (mineralogy)
–
Lustre or luster is the way light interacts with the surface of a crystal, rock, or mineral. The word traces its origins back to the latin lux, meaning light, a range of terms are used to describe lustre, such as earthy, metallic, greasy, and silky. Similarly, the term refers to a glassy lustre. A list of terms is given below. Lustre varies over a continuum, and so there are no rigid boundaries between the different types of lustre. The terms are frequently combined to describe types of lustre. Some minerals exhibit unusual optical phenomena, such as asterism or chatoyancy, a list of such phenomena is given below. Adamantine minerals possess a superlative lustre, which is most notably seen in diamond, such minerals are transparent or translucent, and have a high refractive index. Minerals with an adamantine lustre are uncommon, with examples being cerussite. Minerals with a degree of lustre are referred to as subadamantine, with some examples being garnet. Dull minerals exhibit little to no lustre, due to coarse granulations which scatter light in all directions, a distinction is sometimes drawn between dull minerals and earthy minerals, with the latter being coarser, and having even less lustre. Greasy minerals resemble fat or grease, a greasy lustre often occurs in minerals containing a great abundance of microscopic inclusions, with examples including opal and cordierite. Many minerals with a greasy lustre also feel greasy to the touch, metallic minerals have the lustre of polished metal, and with ideal surfaces will work as a reflective surface. Examples include galena, pyrite and magnetite, pearly minerals consist of thin transparent co-planar sheets. Light reflecting from these layers give them a lustre reminiscent of pearls, such minerals possess perfect cleavage, with examples including muscovite and stilbite. Resinous minerals have the appearance of resin, chewing gum or plastic, a principal example is amber, which is a form of fossilized resin. Silky minerals have an arrangement of extremely fine fibres, giving them a lustre reminiscent of silk. Examples include asbestos, ulexite and the satin spar variety of gypsum, a fibrous lustre is similar, but has a coarser texture
15.
Streak (mineralogy)
–
The streak of a mineral is the color of the powder produced when it is dragged across an un-weathered surface. If no streak seems to be made, the streak is said to be white or colorless. Streak is particularly important as a diagnostic for opaque and colored materials and it is less useful for silicate minerals, most of which have a white streak or are too hard to powder easily. The apparent color of a mineral can vary widely because of impurities or a disturbed macroscopic crystal structure. Small amounts of an impurity that strongly absorbs a particular wavelength can radically change the wavelengths of light that are reflected by the specimen, and thus change the apparent color. However, when the specimen is dragged to produce a streak, it is broken into randomly oriented microscopic crystals, the surface across which the mineral is dragged is called a streak plate, and is generally made of unglazed porcelain tile. In the absence of a plate, the unglazed underside of a porcelain bowl or vase or the back of a glazed tile will work. Sometimes a streak is more easily or accurately described by comparing it with the streak made by another streak plate. Because the trail left behind results from the mineral being crushed into powder, in case of harder minerals, the color of the powder can be determined by filing or crushing with a hammer a small sample, which is then usually rubbed on a streak plate. Most minerals that are harder have a white streak. Some minerals leave a similar to their natural color, such as cinnabar. Other minerals leave surprising colors, such as fluorite, which always has a streak, although it can appear in purple, blue, yellow. Hematite, which is black in appearance, leaves a red streak which accounts for its name, galena, which can be similar in appearance to hematite, is easily distinguished by its gray streak. Hamilton, W. R. Cambridge Guide to Minerals, Rocks, the Encyclopedia of Gemstones and Minerals. New York, Facts on File. p.251, physical Characteristics of Minerals, at Introduction to Mineralogy by Andrea Bangert What is Streak
16.
Transparency and translucency
–
In the field of optics, transparency is the physical property of allowing light to pass through the material without being scattered. On a macroscopic scale, the photons can be said to follow Snells Law, in other words, a translucent medium allows the transport of light while a transparent medium not only allows the transport of light but allows for image formation. The opposite property of translucency is opacity, transparent materials appear clear, with the overall appearance of one color, or any combination leading up to a brilliant spectrum of every color. When light encounters a material, it can interact with it in different ways. These interactions depend on the wavelength of the light and the nature of the material, photons interact with an object by some combination of reflection, absorption and transmission. Some materials, such as glass and clean water, transmit much of the light that falls on them and reflect little of it. Many liquids and aqueous solutions are highly transparent, absence of structural defects and molecular structure of most liquids are mostly responsible for excellent optical transmission. Materials which do not transmit light are called opaque, many such substances have a chemical composition which includes what are referred to as absorption centers. Many substances are selective in their absorption of light frequencies. They absorb certain portions of the spectrum while reflecting others. The frequencies of the spectrum which are not absorbed are either reflected or transmitted for our physical observation and this is what gives rise to color. The attenuation of light of all frequencies and wavelengths is due to the mechanisms of absorption. Transparency can provide almost perfect camouflage for animals able to achieve it and this is easier in dimly-lit or turbid seawater than in good illumination. Many marine animals such as jellyfish are highly transparent, at the atomic or molecular level, physical absorption in the infrared portion of the spectrum depends on the frequencies of atomic or molecular vibrations or chemical bonds, and on selection rules. Nitrogen and oxygen are not greenhouse gases because there is no absorption because there is no molecular dipole moment. With regard to the scattering of light, the most critical factor is the scale of any or all of these structural features relative to the wavelength of the light being scattered. Primary material considerations include, Crystalline structure, whether or not the atoms or molecules exhibit the long-range order evidenced in crystalline solids, glassy structure, scattering centers include fluctuations in density or composition. Microstructure, scattering centers include internal surfaces such as boundaries, crystallographic defects
17.
Specific gravity
–
This page is about the measurement using water as a reference. For a general use of gravity, see relative density. See intensive property for the property implied by specific, Apparent specific gravity is the ratio of the weight of a volume of the substance to the weight of an equal volume of the reference substance. The reference substance is always water at its densest for liquids. Nonetheless, the temperature and pressure must be specified for both the sample and the reference, pressure is nearly always 1 atm. Temperatures for both sample and reference vary from industry to industry, in British beer brewing, the practice for specific gravity as specified above is to multiply it by 1000. Being a ratio of densities, specific gravity is a dimensionless quantity, Specific gravity varies with temperature and pressure, reference and sample must be compared at the same temperature and pressure or be corrected to a standard reference temperature and pressure. Substances with a gravity of 1 are neutrally buoyant in water. Those with SG greater than 1 are denser than water and will, disregarding surface tension effects and those with an SG less than 1 are less dense than water and will float on it. In scientific work, the relationship of mass to volume is expressed directly in terms of the density of the substance under study. It is in industry where specific gravity finds wide application, often for historical reasons. True specific gravity can be expressed mathematically as, S G true = ρ sample ρ H2 O where ρ sample is the density of the sample, the density of water varies with temperature and pressure as does the density of the sample. So it is necessary to specify the temperatures and pressures at which the densities or weights were determined and it is nearly always the case that measurements are made at 1 nominal atmosphere. For true specific gravity calculations, air pressure must be considered, temperatures are specified by the notation with T s representing the temperature at which the samples density was determined and T r the temperature at which the reference density is specified. For example, SG would be understood to mean that the density of the sample was determined at 20°C and of the water at 4°C. Taking into account different sample and reference temperatures, we note that, while S G H2 O =1.000000, it is also the case that S G H2 O =0.998203 /0.999840 =0.998363. Here, temperature is being specified using the current ITS-90 scale, on the previous IPTS-68 scale, the densities at 20 °C and 4 °C are 0.9982071 and 0.9999720 respectively, resulting in an SG value for water of 0.9982343. For example, in the industry, the Plato table lists sucrose concentration by weight against true SG
18.
Refractive index
–
In optics, the refractive index or index of refraction n of a material is a dimensionless number that describes how light propagates through that medium. It is defined as n = c v, where c is the speed of light in vacuum, for example, the refractive index of water is 1.333, meaning that light travels 1.333 times faster in a vacuum than it does in water. The refractive index determines how light is bent, or refracted. The refractive indices also determine the amount of light that is reflected when reaching the interface, as well as the angle for total internal reflection. This implies that vacuum has a index of 1. The refractive index varies with the wavelength of light and this is called dispersion and causes the splitting of white light into its constituent colors in prisms and rainbows, and chromatic aberration in lenses. Light propagation in absorbing materials can be described using a refractive index. The imaginary part then handles the attenuation, while the real part accounts for refraction, the concept of refractive index is widely used within the full electromagnetic spectrum, from X-rays to radio waves. It can also be used with wave phenomena such as sound, in this case the speed of sound is used instead of that of light and a reference medium other than vacuum must be chosen. Thomas Young was presumably the person who first used, and invented, at the same time he changed this value of refractive power into a single number, instead of the traditional ratio of two numbers. The ratio had the disadvantage of different appearances, newton, who called it the proportion of the sines of incidence and refraction, wrote it as a ratio of two numbers, like 529 to 396. Hauksbee, who called it the ratio of refraction, wrote it as a ratio with a fixed numerator, hutton wrote it as a ratio with a fixed denominator, like 1.3358 to 1. Young did not use a symbol for the index of refraction, in the next years, others started using different symbols, n, m, and µ. For visible light most transparent media have refractive indices between 1 and 2, a few examples are given in the adjacent table. These values are measured at the yellow doublet D-line of sodium, with a wavelength of 589 nanometers, gases at atmospheric pressure have refractive indices close to 1 because of their low density. Almost all solids and liquids have refractive indices above 1.3, aerogel is a very low density solid that can be produced with refractive index in the range from 1.002 to 1.265. Moissanite lies at the end of the range with a refractive index as high as 2.65. Most plastics have refractive indices in the range from 1.3 to 1.7, for infrared light refractive indices can be considerably higher
19.
Iron
–
Iron is a chemical element with symbol Fe and atomic number 26. It is a metal in the first transition series and it is by mass the most common element on Earth, forming much of Earths outer and inner core. It is the fourth most common element in the Earths crust, like the other group 8 elements, ruthenium and osmium, iron exists in a wide range of oxidation states, −2 to +6, although +2 and +3 are the most common. Elemental iron occurs in meteoroids and other low oxygen environments, but is reactive to oxygen, fresh iron surfaces appear lustrous silvery-gray, but oxidize in normal air to give hydrated iron oxides, commonly known as rust. Unlike the metals that form passivating oxide layers, iron oxides occupy more volume than the metal and thus flake off, Iron metal has been used since ancient times, although copper alloys, which have lower melting temperatures, were used even earlier in human history. Pure iron is soft, but is unobtainable by smelting because it is significantly hardened and strengthened by impurities, in particular carbon. A certain proportion of carbon steel, which may be up to 1000 times harder than pure iron. Crude iron metal is produced in blast furnaces, where ore is reduced by coke to pig iron, further refinement with oxygen reduces the carbon content to the correct proportion to make steel. Steels and iron alloys formed with metals are by far the most common industrial metals because they have a great range of desirable properties. Iron chemical compounds have many uses, Iron oxide mixed with aluminium powder can be ignited to create a thermite reaction, used in welding and purifying ores. Iron forms binary compounds with the halogens and the chalcogens, among its organometallic compounds is ferrocene, the first sandwich compound discovered. Iron plays an important role in biology, forming complexes with oxygen in hemoglobin and myoglobin. Iron is also the metal at the site of many important redox enzymes dealing with cellular respiration and oxidation and reduction in plants. A human male of average height has about 4 grams of iron in his body and this iron is distributed throughout the body in hemoglobin, tissues, muscles, bone marrow, blood proteins, enzymes, ferritin, hemosiderin, and transport in plasma. The mechanical properties of iron and its alloys can be evaluated using a variety of tests, including the Brinell test, Rockwell test, the data on iron is so consistent that it is often used to calibrate measurements or to compare tests. An increase in the content will cause a significant increase in the hardness. Maximum hardness of 65 Rc is achieved with a 0. 6% carbon content, because of the softness of iron, it is much easier to work with than its heavier congeners ruthenium and osmium. Because of its significance for planetary cores, the properties of iron at high pressures and temperatures have also been studied extensively
20.
Chromium
–
Chromium is a chemical element with symbol Cr and atomic number 24. It is the first element in Group 6 and it is a steely-grey, lustrous, hard and brittle metal which takes a high polish, resists tarnishing, and has a high melting point. The name of the element is derived from the Greek word χρῶμα, chrōma, meaning color, Chromium metal is of high value for its high corrosion resistance and hardness. A major development was the discovery that steel could be highly resistant to corrosion and discoloration by adding metallic chromium to form stainless steel. Stainless steel and chrome plating together comprise 85% of the commercial use, trivalent chromium ion is an essential nutrient in trace amounts in humans for insulin, sugar and lipid metabolism, although the issue is debated. While chromium metal and Cr ions are not considered toxic, hexavalent chromium is toxic and carcinogenic, abandoned chromium production sites often require environmental cleanup. Chromium is remarkable for its properties, it is the only elemental solid which shows antiferromagnetic ordering at room temperature. Above 38 °C, it changes to paramagnetic, Chromium metal left standing in air is passivated by oxidation, forming a thin, protective, surface layer. This layer is a structure only a few molecules thick. It is very dense, and prevents the diffusion of oxygen into the underlying metal and this is different from the oxide that forms on iron and carbon steel, through which elemental oxygen continues to migrate, reaching the underlying material to cause incessant rusting. Passivation can be enhanced by short contact with oxidizing acids like nitric acid, passivated chromium is stable against acids. Passivation can be removed with a reducing agent that destroys the protective oxide layer on the metal. Chromium metal treated in this way readily dissolves in weak acids, Chromium, unlike such metals as iron and nickel, does not suffer from hydrogen embrittlement. However, it suffer from nitrogen embrittlement, reacting with nitrogen from air. Chromium is the 22nd most abundant element in Earths crust with a concentration of 100 ppm. Chromium compounds are found in the environment from the erosion of chromium-containing rocks, Chromium is mined as chromite ore. About two-fifths of the ores and concentrates in the world are produced in South Africa, while Kazakhstan, India, Russia. Untapped chromite deposits are plentiful, but geographically concentrated in Kazakhstan, although rare, deposits of native chromium exist
21.
Oxide
–
An oxide /ˈɒksaɪd/ is a chemical compound that contains at least one oxygen atom and one other element in its chemical formula. Oxide itself is the dianion of oxygen, an O2– atom, Metal oxides thus typically contain an anion of oxygen in the oxidation state of −2. Most of the Earths crust consists of oxides, the result of elements being oxidized by the oxygen in air or in water. Hydrocarbon combustion affords the two principal carbon oxides, carbon monoxide and carbon dioxide, even materials considered pure elements often develop an oxide coating. For example, aluminium foil develops a skin of Al2O3 that protects the foil from further corrosion. Individual elements can form multiple oxides, each containing different amounts of the element. Certain elements can form many different oxides, such those of nitrogen, due to its electronegativity, oxygen forms stable chemical bonds with almost all elements to give the corresponding oxides. Noble metals are prized because they resist direct chemical combination with oxygen, two independent pathways for corrosion of elements are hydrolysis and oxidation by oxygen. The combination of water and oxygen is even more corrosive, virtually all elements burn in an atmosphere of oxygen, or an oxygen rich environment. In the presence of water and oxygen, some elements— sodium—react rapidly, even dangerously, in part for this reason, alkali and alkaline earth metals are not found in nature in their metallic, i. e. native, form. Caesium is so reactive with oxygen that it is used as a getter in vacuum tubes, the surface of most metals consists of oxides and hydroxides in the presence of air. A well-known example is aluminium foil, which is coated with a film of aluminium oxide that passivates the metal. The aluminium oxide layer can be built to greater thickness by the process of electrolytic anodising, though solid magnesium and aluminium react slowly with oxygen at STP—they, like most metals, burn in air, generating very high temperatures. Finely grained powders of most metals can be explosive in air. Consequently, they are used in Solid-fuel rockets. In dry oxygen, iron forms iron oxide, but the formation of the hydrated ferric oxides, Fe2O3−x2x. Free oxygen production by photosynthetic bacteria some 3.5 billion years ago precipitated iron out of solution in the oceans as Fe2O3 in the important iron ore hematite. Oxides have a range of different structures, from molecules to polymeric
22.
Solid solution
–
A solid solution is a solid-state solution of one or more solutes in a solvent. The solid solution needs to be distinguished from a mechanical mixtures of powdered solids like two salts, sugar and salt, etc, the mechanical mixtures have total or partial miscibility gap in solid state. Examples of solid solutions include crystallized salts from their liquid mixture, metal alloys, in the case of metal alloys intermetallic compounds occur frequently. The solute may incorporate into the solvent crystal lattice substitutionally, by replacing a solvent particle in the lattice, or interstitially, by fitting into the space between solvent particles. Both of these types of solid solution affect the properties of the material by distorting the crystal lattice, some mixtures will readily form solid solutions over a range of concentrations, while other mixtures will not form solid solutions at all. The propensity for any two substances to form a solution is a complicated matter involving the chemical, crystallographic. 1 displays an alloy of two metals which forms a solution at all relative concentrations of the two species. Solid solutions have important commercial and industrial applications, as such mixtures often have superior properties to pure materials, many metal alloys are solid solutions. Even small amounts of solute can affect the electrical and physical properties of the solvent, the binary phase diagram in Fig.2 shows the phases of a mixture of two substances in varying concentrations, A and B. The region labeled α is a solution, with B acting as the solute in a matrix of A. On the other end of the scale, the region labeled β is also a solid solution. The large solid region in between the α and β solid solutions, labeled α + β, is not a solid solution, at other proportions, the material will enter a mushy or pasty phase until it warms up to being completely melted. The mixture at the dip point of the diagram is called a eutectic alloy, lead-tin mixtures formulated at that point are useful when soldering electronic components, particularly if done manually, since the solid phase is quickly entered as the solder cools. In contrast, when lead-tin mixtures were used to solder seams in automobile bodies a pasty state enabled a shape to be formed with a paddle or tool. When a solid solution becomes unstable — due to a temperature, for example — exsolution occurs. This is mainly caused by difference in cation size, cations which have a large difference in radii are not likely to readily substitute. Take the alkali feldspar minerals for example, whose end members are albite, NaAlSi3O8 and microcline and this leads to exsolution where they will separate into two separate phases. In the case of the feldspar minerals, thin white albite layers will alternate between typically pink microcline
23.
Chromite
–
Chromite is an iron chromium oxide, FeCr2O4. It is a mineral belonging to the spinel group. Magnesium can substitute for iron in variable amounts as it forms a solution with magnesiochromite. It is by far the most industrially important mineral for the production of chromium, used as an alloying ingredient in stainless. Chromite is found as orthocumulate lenses of chromitite in peridotite from the Earths mantle and it also occurs in layered ultramafic intrusive rocks. In addition, it is found in rocks such as some serpentinites. Ore deposits of chromite form as early magmatic differentiates and it is commonly associated with olivine, magnetite, serpentine, and corundum. The vast Bushveld igneous complex of South Africa is a layered mafic to ultramafic igneous body with some layers consisting of 90% chromite making the rare rock type. The Stillwater igneous complex in Montana also contains significant chromite, the only ores of chromium are the minerals chromite and magnesiochromite. Most of the time, economic geology names chromite the whole chromite-magnesiochromite series, the two main products of chromite refining are ferrochromium and metallic chromium, for those products the ore smelter process differs considerably. Chromite is also used as a material, because it has a high heat stability. The chromium extracted from chromite is used in plating and alloying for production of corrosion resistant superalloys, nichrome. Chromium is used as a pigment for glass, glazes, and paint and it is also sometimes used as a gemstone. In 200214,600,000 metric tons of chromite were mined, the largest producers were South Africa, India, Kazakhstan, Zimbabwe, Finland, Iran, and Brazil with several other countries producing the rest of less than 10% of the world production. Afghanistan has significant deposits of high grade ore, which is mined illegally in Khost Province. In Pakistan, chromite is mined from the rocks in mainly the Muslimbagh killa Saifullah District. Most of the chromite is of metallurgical grade with Cr2O3 averaging 54%, recently, the biggest user of chromite ore has been China, importing large quantities from South Africa, Pakistan, and other countries. The concentrate is used to make ferrochrome, which is in used to make stainless steel
24.
Aluminium
–
Aluminium or aluminum is a chemical element in the boron group with symbol Al and atomic number 13. It is a silvery-white, soft, nonmagnetic, ductile metal, Aluminium metal is so chemically reactive that native specimens are rare and limited to extreme reducing environments. Instead, it is combined in over 270 different minerals. The chief ore of aluminium is bauxite, Aluminium is remarkable for the metals low density and its ability to resist corrosion through the phenomenon of passivation. Aluminium and its alloys are vital to the industry and important in transportation and structures, such as building facades. The oxides and sulfates are the most useful compounds of aluminium, despite its prevalence in the environment, no known form of life uses aluminium salts metabolically, but aluminium is well tolerated by plants and animals. Because of these salts abundance, the potential for a role for them is of continuing interest. Aluminium is a soft, durable, lightweight, ductile. It is nonmagnetic and does not easily ignite, a fresh film of aluminium serves as a good reflector of visible light and an excellent reflector of medium and far infrared radiation. The yield strength of aluminium is 7–11 MPa, while aluminium alloys have yield strengths ranging from 200 MPa to 600 MPa. Aluminium has about one-third the density and stiffness of steel and it is easily machined, cast, drawn and extruded. Aluminium atoms are arranged in a cubic structure. Aluminium has an energy of approximately 200 mJ/m2. Aluminium is a thermal and electrical conductor, having 59% the conductivity of copper. Aluminium is capable of superconductivity, with a critical temperature of 1.2 kelvin. Aluminium is the most common material for the fabrication of superconducting qubits, the strongest aluminium alloys are less corrosion resistant due to galvanic reactions with alloyed copper. This corrosion resistance is reduced by aqueous salts, particularly in the presence of dissimilar metals. In highly acidic solutions, aluminium reacts with water to form hydrogen, primarily because it is corroded by dissolved chlorides, such as common sodium chloride, household plumbing is never made from aluminium
25.
Hercynite
–
Hercynite is a spinel mineral with the formula FeAl2O4. It occurs in high-grade metamorphosed iron rich argillaceous sediments as well as in mafic and ultramafic igneous rocks, due to its hardness it also is found in placers. It was first described in 1847 and its name originates from the Latin name for the Harz, Silva Hercynia, hercynite is a spinel of regular symmetry and normal cation distribution, but some disorder occurs in its structure. It consists of ions and aluminium ions, however some Fe3+ may be located in the structure of hercynite
26.
Stainless steel
–
In metallurgy, stainless steel, also known as inox steel or inox from French inoxydable, is a steel alloy with a minimum of 10. 5% chromium content by mass. Stainless steel is notable for its resistance, and it is widely used for food handling. Stainless steel does not readily corrode, rust or stain with water as ordinary steel does, however, it is not fully stain-proof in low-oxygen, high-salinity, or poor air-circulation environments. There are various grades and surface finishes of stainless steel to suit the environment the alloy must endure, Stainless steel is used where both the properties of steel and corrosion resistance are required. Stainless steel differs from carbon steel by the amount of chromium present, unprotected carbon steel rusts readily when exposed to air and moisture. This iron oxide film is active and accelerates corrosion by making it easier for more iron oxide to form, since iron oxide has lower density than steel, the film expands and tends to flake and fall away. In comparison, stainless steels contain sufficient chromium to undergo passivation and this layer prevents further corrosion by blocking oxygen diffusion to the steel surface and stops corrosion from spreading into the bulk of the metal. Passivation occurs only if the proportion of chromium is high enough, Stainless steel’s resistance to corrosion and staining, low maintenance, and familiar lustre make it an ideal material for many applications. Storage tanks and tankers used to transport orange juice and other food are made of stainless steel. This also influences its use in kitchens and food processing plants, as it can be steam-cleaned and sterilized. High oxidation resistance in air at ambient temperature is achieved with addition of a minimum of 13% chromium. The chromium forms a layer of chromium oxide when exposed to oxygen. The layer is too thin to be visible, and the metal remains lustrous, the layer is impervious to water and air, protecting the metal beneath, and this layer quickly reforms when the surface is scratched. This phenomenon is called passivation and is seen in other metals, corrosion resistance can be adversely affected if the component is used in a non-oxygenated environment, a typical example being underwater keel bolts buried in timber. When stainless steel parts such as nuts and bolts are forced together, when forcibly disassembled, the welded material may be torn and pitted, a destructive effect known as galling. Galling can be avoided by the use of materials for the parts forced together, for example bronze and stainless steel. However, two different alloys electrically connected in a humid, even mildly acidic environment may act as a voltaic pile, nitronic alloys, made by selective alloying with manganese and nitrogen, may have a reduced tendency to gall. Additionally, threaded joints may be lubricated to provide a film between the two parts and prevent galling, low-temperature carburizing is another option that virtually eliminates galling and allows the use of similar materials without the risk of corrosion and the need for lubrication
27.
Tool steel
–
Tool steel refers to a variety of carbon and alloy steels that are particularly well-suited to be made into tools. Their suitability comes from their distinctive hardness, resistance to abrasion and deformation, as a result, tool steels are suited for their use in the shaping of other materials. With a carbon content between 0. 5% and 1. 5%, tool steels are manufactured under controlled conditions to produce the required quality. The presence of carbides in their plays the dominant role in the qualities of tool steel. The four major alloying elements in tool steel that form carbides are, tungsten, the rate of dissolution of the different carbides into the austenite form of the iron determines the high temperature performance of steel. Proper heat treatment of these steels is important for adequate performance, the manganese content is often kept low to minimize the possibility of cracking during water quenching. There are six groups of tool steels, water-hardening, cold-work, shock-resistant, high-speed, hot-work, the choice of group to select depends on cost, working temperature, required surface hardness, strength, shock resistance, and toughness requirements. The more severe the service condition, the higher the content and consequent amount of carbides required for the tool steel. Tool steels are used for cutting, pressing, extruding, and coining of metals, the AISI-SAE grades of tool steel is the most common scale used to identify various grades of tool steel. Individual alloys within a grade are given a number, for example, A2, O1, W-group tool steel gets its name from its defining property of having to be water quenched. W-grade steel is essentially high carbon plain-carbon steel and this group of tool steel is the most commonly used tool steel because of its low cost compared to others. They work well for parts and applications where high temperatures are not encountered. Its hardenability is low, so W-group tool steels must be subjected to a rapid quenching, requiring the use of water and these steels can attain high hardness and are rather brittle compared to other tool steels. W-steels are still sold, especially for springs, but are less widely used than they were in the 19th. This is partly because W-steels warp and crack much more during quench than oil-quenched or air hardening steels, the toughness of W-group tool steels are increased by alloying with manganese, silicon and molybdenum. Up to 0. 20% of vanadium is used to fine grain sizes during heat treating. 0. 76–0. 90% carbon, forging dies, hammers,0. 91–1. 10% carbon, general purpose tooling applications that require a good balance of wear resistance and toughness, such as rasps, drills, cutters, and shear blades. 1. 11–1. 30% carbon, files, small drills, lathe tools, razor blades, and other light-duty applications where more wear resistance is required without great toughness
28.
Yukon
–
Yukon is the smallest and westernmost of Canadas three federal territories. The territory has the smallest population of any province or territory in Canada, Whitehorse is the territorial capital and Yukons only city. The territory was split from the Northwest Territories in 1898 and was named the Yukon Territory, though officially bilingual, the Yukon Government also recognizes First Nations languages. At 5,959 m, Yukons Mount Logan, in Kluane National Park and Reserve, is the highest mountain in Canada, most of Yukon has a subarctic climate, characterized by long cold winters and brief warm summers. The Arctic Ocean coast has a tundra climate, notable rivers include the Yukon River, after which the territory was named, as well as the Pelly, Stewart, Peel, White and Tatshenshini rivers. Long before the arrival of Europeans, central and southern Yukon was populated by First Nations people, sites of archeological significance in Yukon hold some of the earliest evidence of the presence of human occupation in North America. The sites safeguard the history of the first people and the earliest First Nations of the Yukon, the volcanic eruption of Mount Churchill in approximately 800 AD in what is now the U. S. Coastal and inland First Nations had extensive trading networks, European incursions into the area only began early in the 19th century with the fur trade, followed by missionaries. By the 1870s and 1880s gold miners began to arrive and this drove a population increase that justified the establishment of a police force, just in time for the start of the Klondike Gold Rush in 1897. The increased population coming with the gold led to the separation of the Yukon district from the Northwest Territories. Its northern coast is on the Beaufort Sea and its ragged eastern boundary mostly follows the divide between the Yukon Basin and the Mackenzie River drainage basin to the east in the Mackenzie mountains. Most of the territory is in the watershed of its namesake, the southern Yukon is dotted with a large number of large, long and narrow glacier-fed alpine lakes, most of which flow into the Yukon River system. The larger lakes include Teslin Lake, Atlin Lake, Tagish Lake, Marsh Lake, Lake Laberge, Kusawa Lake, bennett Lake on the Klondike Gold Rush trail is a lake flowing into Nares Lake, with the greater part of its area within Yukon. Canadas highest point, Mount Logan, is in the territorys southwest, Mount Logan and a large part of the Yukons southwest are in Kluane National Park and Reserve, a UNESCO World Heritage Site. Other national parks include Ivvavik National Park and Vuntut National Park in the north, other watersheds include the Mackenzie River, the Peel Watershed and the Alsek–Tatshenshini, and a number of rivers flowing directly into the Beaufort Sea. The two main Yukon rivers flowing into the Mackenzie in the Northwest Territories are the Liard River in the southeast, notable widespread tree species within Yukon are the black spruce and white spruce. Many trees are stunted because of the growing season and severe climate. The capital, Whitehorse, is also the largest city, with about three-quarters of the population, the second largest is Dawson City, which was the capital until 1952
29.
Platinum group
–
The platinum-group metals are six noble, precious metallic elements clustered together in the periodic table. These elements are all transition metals in the d-block, the six platinum-group metals are ruthenium, rhodium, palladium, osmium, iridium, and platinum. They have similar physical and chemical properties, and tend to occur together in the mineral deposits. However they can be subdivided into the iridium-group platinum-group elements. The three elements above the group in the periodic table are all ferromagnetic, these being the only known transition metals with this property. Naturally occurring platinum and platinum-rich alloys were known by pre-Columbian Americans for many years, the Spaniards named the metal platina when they first encountered it in Colombia. They regarded platinum as an impurity in the silver they were mining. The platinum metals have many useful catalytic properties and they are highly resistant to wear and tarnish, making platinum, in particular, well suited for fine jewelry. Other distinctive properties include resistance to attack, excellent high-temperature characteristics. All these properties have been exploited for industrial applications, generally, ultramafic and mafic igneous rocks have relatively high, and granites low, PGE trace content. Geochemically anomalous traces occur predominantly in chromian spinels and sulfides, mafic and ultramafic igneous rocks host practically all primary PGM ore of the world. Mafic layered intrusions, including the Bushveld Complex, outweigh by far all other settings of platinum deposits. Other economically significant PGE deposits include mafic intrusions related to flood basalts, typical ores for PGMs contain ca.10 g PGM/ton ore, thus the identity of the particular mineral is unknown. Sperrylite ore is a source of this metal. A naturally occurring platinum-iridium alloy, platiniridium, is found in the mineral cooperite, platinum is also produced commercially as a by-product of nickel ore processing. The huge quantities of ore processed makes up for the fact that platinum makes up only two parts per million of the ore. South Africa, with vast platinum ore deposits in the Merensky Reef of the Bushveld complex, is the worlds largest producer of platinum, platinum and palladium are also mined commercially from the Stillwater igneous complex in Montana, USA. Leaders of primary production are South Africa and Russia, followed by Canada, Zimbabwe
30.
Ultramafic rock
–
Ultramafic are igneous and meta-igneous rocks with a very low silica content, generally >18% MgO, high FeO, low potassium, and are composed of usually greater than 90% mafic minerals. The Earths mantle is composed of ultramafic rocks, ultrabasic is a more inclusive term that includes igneous rocks with low silica content that may not be extremely enriched in Fe and Mg, such as carbonatites and ultrapotassic igneous rocks. Intrusive ultramafic rocks are found in large, layered ultramafic intrusions where differentiated rock types often occur in layers. Such cumulate rock types do not represent the chemistry of the magma from which they crystallized, the ultramafic intrusives include the dunites, peridotites and pyroxenites. Other rare varieties include troctolite which has a percentage of calcic plagioclase. Gabbro and norite often occur in the portions of the layered ultramafic sequences. Hornblendite and, rarely phlogopite, are also found, subvolcanic ultramafic rocks and dykes persist longer, but are also rare. Many of the lavas being produced on Io may be ultramafic, mercury also appears to have ultramafic volcanic rock. Examples include komatiite and picritic basalt, komatiites can be host to ore deposits of nickel. Ultrapotassic, ultramafic rocks such as lamprophyre, lamproite and kimberlite are known to have reached the surface of the Earth. Although no modern eruptions have been observed, analogues are preserved, most of these rocks occur as dikes, diatremes, lopoliths or laccoliths, and very rarely, intrusions. Most kimberlite and lampproite occurrences occur as volcanic and subvolcanic diatremes and maars, vents of Proterozoic lamproite, and Cenozoic lamproite are known, as are vents of Devonian lamprophyre. Kimberlite pipes in Canada, Russia and South Africa have incompletely preserved tephra and these are generally diatreme events and as such are not lava flows although tephra and ash deposits are partially preserved. These represent low-volume volatile melts and attain their ultramafic chemistry via a different process to typical ultramafic rocks, metamorphism of ultramafic rocks in the presence of water and/or carbon dioxide results in two main classes of metamorphic ultramafic rock, talc carbonate and serpentinite. When such metamorphic fluids have less than 10% molar proportion of CO2, reactions favor serpentinisation, the majority of ultramafic rocks are exposed in orogenic belts, and predominate in Archaean and Proterozoic terranes. Ultramafic magmas in the Phanerozoic are rarer, and there are very few recognised true ultramafic lavas in the Phanerozoic, many surface exposures of ultramafic rocks occur in ophiolite complexes where deep mantle-derived rocks have been obducted onto continental crust along and above subduction zones. Serpentine soil is a rich, calcium, potassium and phosphorus poor soil that develops on the regolith derived from ultramafic rocks. Ultramafic rocks also contain elevated amounts of chromium and nickel which may be toxic to plants, as a result, a distinctive type of vegetation develops on these soils
31.
Peridotite
–
Peridotite is a dense, coarse-grained igneous rock consisting mostly of the minerals olivine and pyroxene. Peridotite is ultramafic, as the rock contains less than 45% silica and it is high in magnesium, reflecting the high proportions of magnesium-rich olivine, with appreciable iron. Peridotite is derived from the Earths mantle, either as solid blocks and fragments, the compositions of peridotites from these layered igneous complexes vary widely, reflecting the relative proportions of pyroxenes, chromite, plagioclase, and amphibole. Peridotite is the dominant rock of the part of the Earths mantle. The word peridotite comes from the gemstone peridot, which consists of pale green olivine, classic peridotite is bright green with some specks of black, although most hand samples tend to be darker green. Peridotitic outcrops typically range from bright yellow to dark green in color. While green and yellow are the most common colors, peridotitic rocks may exhibit a range of colors such as blue, brown. Dunite, more than 90% olivine, typically with Mg/Fe ratio of about 9,1, wehrlite, mostly composed of olivine plus clinopyroxene. Harzburgite, mostly composed of olivine plus orthopyroxene, and relatively low proportions of basaltic ingredients, lherzolite, most common form of peridotite, mostly composed of olivine, orthopyroxene, and clinopyroxene, and have relatively high proportions of basaltic ingredients. Partial fusion of lherzolite and extraction of the melt fraction can leave a residue of harzburgite. Magnesium-rich olivine forms a proportion of peridotite, and so magnesium content is high. Layered igneous complexes have more varied compositions, depending on the fractions of pyroxenes, chromite, plagioclase. Minor minerals and mineral groups in peridotite include plagioclase, spinel, garnet, amphibole, in peridotite, plagioclase is stable at relatively low pressures, aluminous spinel at higher pressures, and garnet at yet higher pressures. Peridotite is the dominant rock of the Earths mantle above a depth of about 400 km, below that depth, olivine is converted to the higher-pressure mineral wadsleyite. Oceanic plates consist of up to about 100 km of peridotite covered by a thin crust, the crust, commonly about 6 km thick, consists of basalt, gabbro, and minor sediments. The peridotite below the ocean crust, abyssal peridotite, is found on the walls of rifts in the sea floor. Oceanic plates are usually subducted back into the mantle in subduction zones, peridotites also occur as fragments carried up by magmas from the mantle. Among the rocks that commonly include peridotite xenoliths are basalt and kimberlite, certain volcanic rocks, sometimes called komatiites, are so rich in olivine and pyroxene that they also can be termed peridotite
32.
Mantle (geology)
–
The mantle is a layer inside a terrestrial planet and some other rocky planetary bodies. For a mantle to form, the body must be large enough to have undergone the process of planetary differentiation by density. The mantle surrounds the planetary core, the mantle is surrounded by the crust. The terrestrial planets, the Moon, two of Jupiters moons and the asteroid Vesta each have a made of silicate rock. Interpretation of spacecraft data suggests that at least two moons of Jupiter, as well as Titan and Triton each have a mantle made of ice or other solid volatile substances. The interior of Earth, similar to the terrestrial planets, is divided into layers of different composition. The mantle is a layer between the crust and the outer core, Earths mantle is a silicate rocky shell with an average thickness of 2,886 kilometres. The mantle makes up about 84% of Earths volume and it is predominantly solid but in geological time it behaves as a very viscous fluid. The mantle encloses the hot core rich in iron and nickel, past episodes of melting and volcanism at the shallower levels of the mantle have produced a thin crust of crystallized melt products near the surface. A thin crust, the part of the lithosphere, surrounds the mantle and is about 5 to 75 km thick. In some places under the ocean the mantle is exposed on the surface of Earth. The mantle is divided into sections which are based upon results from seismology and these layers are the following, the upper mantle, the transition zone, the lower mantle, and anomalous core–mantle boundary with a variable thickness. The uppermost mantle plus overlying crust are relatively rigid and form the lithosphere, below the lithosphere the upper mantle becomes notably more plastic. In some regions below the lithosphere, the shear velocity is reduced. Inge Lehmann discovered a seismic discontinuity at about 220 km depth, although this discontinuity has been found in other studies, the transition zone is an area of great complexity, it physically separates the upper and lower mantle. Very little is known about the lower mantle apart from that it appears to be relatively seismically homogeneous, the D layer at the core–mantle boundary separates the mantle from the core. A principal source of the heat that drives plate tectonics is the decay of uranium, thorium. The mantle differs substantially from the crust in its properties as the direct consequence of the difference in composition
33.
Layered intrusion
–
A layered intrusion is a large sill-like body of igneous rock which exhibits vertical layering or differences in composition and texture. These intrusions typically are many kilometres in area covering from around 100 km2 to over 50,000 km2, while most are Archean to Proterozoic in age they may be any age such as the Cenozoic Skaergaard intrusion of east Greenland or the Rum layered intrusion in Scotland. Although most are ultramafic to mafic in composition, the Ilimaussaq complex of Greenland is an alkalic intrusion, layered intrusions are found in typically ancient cratons and are rare but worldwide in distribution. The intrusive complexes exhibit evidence of fractional crystallization and crystal segregation by settling or floating of minerals from a melt, some include diorite and granophyre near the top of the bodies. Orebodies of platinum group elements, chromite, magnetite and ilmenite are often associated with these rare intrusions, mafic-ultramafic layered intrusions occur at all levels within the crust, from depths in excess of 50 km to depths of as little as 1.5 to 5 km. The depth at which an intrusion is formed is dependent on several factors, magmas with high magnesium and iron contents are denser and are therefore less likely to be able to reach the surface. As an ascending magma rises and cools, it becomes thicker and this then restricts the magma from rising further because more energy is required to push it upwards. Conversely, thicker magma is more efficient at forcing apart the wall rocks. It is difficult to determine what causes large ultramafic – mafic intrusives to be emplaced within the crust. For instance, in most Archaean cratons, greenstone belts correlate with voluminous dyke injection as well as some form of larger intrusive episodes into the crust. This is particularly true of a series of ultramafic-mafic layered intrusions in the Yilgarn Craton of ~2.8 Ga and associated komatiite volcanism, plume magmatism is an effective mechanism for explaining the large volumes of magmatism required to inflate an intrusion to several kilometres thickness. Plumes also tend to create warping of the crust, weaken it thermally so that it is easier to intrude magma, the presence of large layered complexes in Greenland such as the Skaergaard intrusion which is not related to mantle plumes indicate other processes can form these intrusions. Here, the large volumes which are created by mid-ocean ridge spreading allow the accumulation of large volumes of cumulate rocks. Plume magmatism is supported in some intrusions by geochemistry, in particular the Norilsk-Talnakh intrusions are considered to be created by plume magmatism and other large intrusions have been suggested as created by mantle plumes. The causes of layering in large ultramafic intrusions include convection, thermal diffusion, settling of phenocrysts, assimilation of wall rocks, the primary mechanism for forming cumulate layers is of course the accumulation of layers of mineral crystals on the floor or roof of the intrusion. Rarely, plagioclase is found in layers at the top of intrusions. Here it can form anorthosite layers, accumulation occurs as crystals are formed by fractional crystallisation and, if they are dense enough, precipitate out from the magma. The Skaergaard intrusion in Greenland is an example of these quasi-sedimentary structures
34.
Serpentinite
–
Serpentinite is a rock composed of one or more serpentine group minerals. Minerals in this group are formed by serpentinization, a hydration, the mineral alteration is particularly important at the sea floor at tectonic plate boundaries. Serpentinization is a geological low-temperature metamorphic process involving heat and water in which low-silica mafic and ultramafic rocks are oxidized and hydrolyzed with water into serpentinite. Peridotite, including dunite, at and near the seafloor and in mountain belts is converted to serpentine, brucite, magnetite, and other minerals — some rare, such as awaruite, and even native iron. In the process large amounts of water are absorbed into the increasing the volume. The density changes from 3.3 to 2.7 g/cm3 with a concurrent volume increase on the order of 30-40%, the reaction is highly exothermic and rock temperatures can be raised by about 260 °C, providing an energy source for formation of non-volcanic hydrothermal vents. The magnetite-forming chemical reactions produce hydrogen gas under anaerobic conditions prevailing deep in the mantle, carbonates and sulfates are subsequently reduced by hydrogen and form methane and hydrogen sulfide. The hydrogen, methane, and hydrogen sulfide provide energy sources for deep sea chemotroph microorganisms, serpentinite is formed from olivine via several reactions, some of which are complementary. Olivine is a solution between the magnesium-endmember forsterite and the iron-endmember fayalite. Serpentinite reaction 1a and 1b, below, exchange silica between forsterite and fayalite to form serpentine group minerals and magnetite, Reaction 1c describes the hydration of olivine with water only to yield serpentine and Mg2. Talc and magnesian chlorite are possible products, together with the serpentine minerals antigorite, lizardite, the final mineralogy depends both on rock and fluid compositions, temperature, and pressure. Antigorite forms in reactions at temperatures that can exceed 600 °C during metamorphism, lizardite and chrysotile can form at low temperatures very near the Earths surface. In the presence of carbon dioxide, however, serpentinitization may form either magnesite or generate methane and it is thought that some hydrocarbon gases may be produced by serpentinite reactions within the oceanic crust. Or, in balanced form, Reaction 2a is favored if the serpentinite is Mg-poor or if there isnt enough carbon dioxide to promote talc formation, Reaction 2b is favored in highly magnesian compositions and low partial pressure of carbon dioxide. If an olivine composition contains sufficient fayalite, then olivine plus water can completely metamorphose to serpentine, serpentinitization of a mass of peridotite usually destroys all previous textural evidence because the serpentine minerals are weak and behave in a very ductile fashion. Serpentine is the product of the reaction between water and fayalites ferrous ions, the process is effected by bacteria under anaerobic conditions. The two unoxidised ferrous ions still available in the three units of fayalite finally combine with the four ferric cations and oxide anions to form two formula units of magnetite. Serpentinization has been proposed as an alternative source for the observed methane traces
35.
Ore
–
An ore is a type of rock that contains sufficient minerals with important elements including metals that can be economically extracted from the rock. The ores are extracted from the earth through mining, they are refined to extract the valuable element. The grade or concentration of an ore mineral, or metal, as well as its form of occurrence, will directly affect the costs associated with mining the ore. The cost of extraction must thus be weighed against the value contained in the rock to determine what ore can be processed. Metal ores are generally oxides, sulfides, silicates, or native metals that are not commonly concentrated in the Earths crust, the ores must be processed to extract the metals of interest from the waste rock and from the ore minerals. Ore bodies are formed by a variety of geological processes, the process of ore formation is called ore genesis. An ore deposit is an accumulation of ore and this is distinct from a mineral resource as defined by the mineral resource classification criteria. An ore deposit is one occurrence of a particular ore type, Ore deposits are classified according to various criteria developed via the study of economic geology, or ore genesis. Stratiform arkose-hosted and shale-hosted copper, typified by the Zambian copperbelt and this identifies, early on, whether further investment in estimation and engineering studies is warranted and identifies key risks and areas for further work. This is because the distribution of ores is unequal and dislocated from locations of peak demand. Other, lesser, commodities do not have international clearing houses and benchmark prices and this generally makes determining the price of ores of this nature opaque and difficult. Such metals include lithium, niobium-tantalum, bismuth, antimony and rare earths, most of these commodities are also dominated by one or two major suppliers with >60% of the worlds reserves. The London Metal Exchange aims to add uranium to its list of metals on warrant, the World Bank reports that China was the top importer of ores and metals in 2005 followed by the USA and Japan. Economic geology Mineral resource classification Ore genesis Petrology Froth Flotation Extractive metallurgy DILL, the “chessboard” classification scheme of mineral deposits, Mineralogy and geology from aluminum to zirconium, Earth-Science Reviews, Volume 100, Issue 1-4, June 2010, Pages 1-420
36.
Olivine
–
The mineral olivine is a magnesium iron silicate with the formula 2SiO4. Thus it is a type of nesosilicate or orthosilicate and it is a common mineral in the Earths subsurface but weathers quickly on the surface. The ratio of magnesium and iron varies between the two endmembers of the solid solution series, forsterite and fayalite, compositions of olivine are commonly expressed as molar percentages of forsterite and fayalite. Forsterite has a high melting temperature at atmospheric pressure, almost 1,900 °C. The melting temperature varies smoothly between the two endmembers, as do other properties, olivine incorporates only minor amounts of elements other than oxygen, silicon, magnesium and iron. Manganese and nickel commonly are the elements present in highest concentrations. Olivine gives its name to the group of minerals with a structure which includes tephroite, monticellite and kirschsteinite. It has a structure similar to magnetite but uses one quadravalent. Olivine gemstones are called peridot and chrysolite, olivine is named for its typically olive-green color, though it may alter to a reddish color from the oxidation of iron. Translucent olivine is sometimes used as a gemstone called peridot, some of the finest gem-quality olivine has been obtained from a body of mantle rocks on Zabargad island in the Red Sea. Olivine occurs in mafic and ultramafic igneous rocks and as a primary mineral in certain metamorphic rocks. Mg-rich olivine crystallizes from magma that is rich in magnesium and low in silica and that magma crystallizes to mafic rocks such as gabbro and basalt. Ultramafic rocks such as peridotite and dunite can be left after extraction of magmas. Olivine and high pressure structural variants constitute over 50% of the Earths upper mantle, the metamorphism of impure dolomite or other sedimentary rocks with high magnesium and low silica content also produces Mg-rich olivine, or forsterite. In contrast, Mg-rich olivine does not occur stably with silica minerals, Mg-rich olivine is stable to pressures equivalent to a depth of about 410 km within Earth. Mg-rich olivine has also discovered in meteorites, on the Moon and Mars, falling into infant stars. Such meteorites include chondrites, collections of debris from the early Solar System, the spectral signature of olivine has been seen in the dust disks around young stars. The tails of comets often have the signature of olivine
37.
Magnetite
–
Magnetite is a mineral and one of the main iron ores. With the chemical formula Fe3O4, it is one of the oxides of iron, Magnetite is ferrimagnetic, it is attracted to a magnet and can be magnetized to become a permanent magnet itself. It is the most magnetic of all the minerals on Earth. Naturally-magnetized pieces of magnetite, called lodestone, will attract small pieces of iron, today it is mined as iron ore. Small grains of magnetite occur in almost all igneous and metamorphic rocks, Magnetite is black or brownish-black with a metallic luster, has a Mohs hardness of 5–6 and leaves a black streak. The chemical IUPAC name is iron oxide and the chemical name is ferrous-ferric oxide. In addition to rocks, magnetite also occurs in sedimentary rocks, including banded iron formations and in lake. Magnetite nanoparticles are also thought to form in soils, where they probably oxidize rapidly to maghemite, Magnetite has an inverse spinel crystal structure. As a member of the group, it can form solid solutions with similarly structured minerals, including ulvospinel. Titanomagnetite, also known as titaniferous magnetite, is a solution between magnetite and ulvospinel that crystallizes in many mafic igneous rocks. Titanomagnetite may undergo oxyexsolution during cooling, resulting in ingrowths of magnetite and ilmenite, Magnetite has been important in understanding the conditions under which rocks form. Magnetite reacts with oxygen to produce hematite, and the pair forms a buffer that can control oxygen fugacity. Commonly, igneous rocks contain solid solutions of both titanomagnetite and hemoilmenite or titanohematite, Magnetite also is produced from peridotites and dunites by serpentinization. Lodestones were used as a form of magnetic compass. At low temperatures, magnetite undergoes a crystal structure phase transition from a structure to a cubic structure known as the Verwey transition. The Verwey transition occurs around 121 K and is dependent on size, domain state. An isotropic point also occurs near the Verwey transition around 130 K, the Curie temperature of magnetite is 858 K. Magnetite is sometimes found in large quantities in beach sand. Such black sands are found in places, such as Lung Kwu Tan of Hong Kong, California of the United States
38.
Serpentine subgroup
–
The serpentine subgroup are greenish, brownish, or spotted minerals commonly found in serpentinite rocks. They are used as a source of magnesium and asbestos, the name is thought to come from the greenish color being that of a serpent. In mineralogy and gemology, serpentine may refer to any of 20 varieties belonging to the serpentine group, owing to admixture, these varieties are not always easy to individualize, and distinctions are not usually made. There are three important mineral polymorphs of serpentine, antigorite, chrysotile and lizardite, the serpentine group of minerals are polymorphous, meaning that they have the same chemical formulae, but the atoms are arranged into different structures, or crystal lattices. Chrysotile, which has a habit, is one polymorph of serpentine and is an important component of asbestos. Other polymorphs in the group may have a platy habit. Antigorite and lizardite are the polymorphs with platy habit, many types of serpentine have been used for jewellery and hardstone carving, sometimes under the name false jade or Teton jade. Their olive green colour and smooth or scaly appearance is the basis of the name from the Latin serpentinus, meaning serpent rock and they have their origins in metamorphic alterations of peridotite and pyroxene. Serpentines may also pseudomorphously replace other magnesium silicates, alterations may be incomplete, causing physical properties of serpentines to vary widely. Where they form a significant part of the surface, the soil is unusually high in clay. Antigorite is the polymorph of serpentine that most commonly forms during metamorphism of wet ultramafic rocks and is stable at the highest temperatures—to over 600 °C at depths of 60 km or so. In contrast, lizardite and chrysotile typically form near the Earths surface and break down at low temperatures. It has been suggested that chrysotile is never stable relative to either of the other two serpentine polymorphs, samples of the oceanic crust and uppermost mantle from ocean basins document that ultramafic rocks there commonly contain abundant serpentine. Antigorite contains water in its structure, about 13 percent by weight, the flora is generally very distinctive, with specialised, slow-growing species. Areas of serpentine-derived soil will show as strips of shrubland and open, scattered small trees within otherwise forested areas, most serpentines are opaque to translucent, light, soft, infusible and susceptible to acids. All are microcrystalline and massive in habit, never being found as single crystals, lustre may be vitreous, greasy or silky. Colours range from white to grey, yellow to green, and brown to black, many are intergrown with other minerals, such as calcite and dolomite. Occurrence is worldwide, New Caledonia, Canada, US, Afghanistan, Britain, Greece, China, Ural Mountains, France, Korea, Austria, India, Myanmar, New Zealand, Norway and Italy are notable localities
39.
Corundum
–
Corundum is a crystalline form of aluminium oxide typically containing traces of iron, titanium, vanadium and chromium. It is a transparent material, but can have different colors when impurities are present. Transparent specimens are used as gems, called ruby if red, all other colors are called sapphire, e. g. green sapphire for a green specimen. The name corundum is derived from the Tamil word Kurundam which originates from the Sanskrit word Kuruvinda meaning ruby, because of corundums hardness, it can scratch almost every other mineral. It is commonly used as an abrasive on everything from sandpaper to large machines used in machining metals, plastics, some emery is a mix of corundum and other substances, and the mix is less abrasive, with an average Mohs hardness of 8.0. In addition to its hardness, corundum is unusual for its density of 4.02 g/cm3, corundum occurs as a mineral in mica schist, gneiss, and some marbles in metamorphic terranes. It also occurs in low silica igneous syenite and nepheline syenite intrusives, other occurrences are as masses adjacent to ultramafic intrusives, associated with lamprophyre dikes and as large crystals in pegmatites. It commonly occurs as a mineral in stream and beach sands because of its hardness. The largest documented crystal of corundum measured about 65×40×40 cm. The record has since surpassed by certain synthetic boules. Corundum for abrasives is mined in Zimbabwe, Russia, Sri Lanka, historically it was mined from deposits associated with dunites in North Carolina, US and from a nepheline syenite in Craigmont, Ontario. Emery-grade corundum is found on the Greek island of Naxos and near Peekskill, New York, abrasive corundum is synthetically manufactured from bauxite. Four corundum axes dating back to 2500 BCE from the Liangzhou culture have been discovered in China, in 1837, Marc Antoine Gaudin made the first synthetic rubies by fusing alumina at a high temperature with a small amount of chromium as a pigment. In 1847, Ebelmen made white synthetic sapphires by fusing alumina in boric acid, in 1877 Frenic and Freil made crystal corundum from which small stones could be cut. Frimy and Auguste Verneuil manufactured artificial ruby by fusing BaF2, in 1903, Verneuil announced he could produce synthetic rubies on a commercial scale using this flame fusion process. The Verneuil process allows the production of flawless single-crystal sapphires, rubies and it is also possible to grow gem-quality synthetic corundum by flux-growth and hydrothermal synthesis. Corundum crystallizes with trigonal symmetry in the space group R3c and has the lattice parameters a =4.75 Å and c =12.982 Å at standard conditions, the unit cell contains six formula units. In the lattice of corundum, the atoms form a slightly distorted hexagonal close packing
40.
Bushveld Igneous Complex
–
Located in South Africa, the BIC contains some of the richest ore deposits on Earth. Gabbro or norite is also quarried from parts of the Complex, the site was discovered around 1897 by Gustaaf Molengraaff. The Bushveld Igneous Complex covers an area in the central Transvaal. It is divided into an eastern and western lobe, with a northern extension. All three sections of the system were formed around the same time—about 2 billion years ago—and are remarkably similar and these intrusions are thought to predate the nearby Vredefort impact to the south, by some 30 million years. Large portions of the area are covered by younger rocks. The extrusions were emplaced over an early diabasic sill, outcrops of which are visible on the side of the Complex. These are typically greenish in colour and composed of clinopyroxene, altered to hornblende and plagioclase, the Complex includes layered mafic intrusions and a felsic phase. The complex has its centre located north of Pretoria in South Africa at about 25° S. It covers over 66,000 km2, an area the size of Ireland, the complex varies in thickness, in places reaching 9 kilometres thick. The orebodies within the complex include the UG2 reef containing up to 43. 5% chromite, the Merensky Reef varies from 30 to 90 cm in thickness. It is a norite with extensive chromitite and sulfide layers or zones containing the ore, the Reef contains an average of 10 ppm platinum group metals in pyrrhotite, pentlandite, and pyrite as well as in rare platinum group minerals and alloys. The Merensky and UG-2 reefs contain approximately 90% of the worlds known PGM reserves, about 80% of the platinum and 20% of the palladium mined each year are produced from these horizons. Richardson, Stephen H. Shirey, Steven B, continental mantle signature of Bushveld magmas and coeval diamonds. Viljoen, M. J. Schürmann, L. W. Platinum-group metals, council for Geoscience Handbook 16, Mineral Resources of South Africa
41.
South Africa
–
South Africa, officially the Republic of South Africa, is the southernmost country in Africa. South Africa is the 25th-largest country in the world by land area and it is the southernmost country on the mainland of the Old World or the Eastern Hemisphere. About 80 percent of South Africans are of Sub-Saharan African ancestry, divided among a variety of ethnic groups speaking different Bantu languages, the remaining population consists of Africas largest communities of European, Asian, and multiracial ancestry. South Africa is a multiethnic society encompassing a variety of cultures, languages. Its pluralistic makeup is reflected in the recognition of 11 official languages. The country is one of the few in Africa never to have had a coup détat, however, the vast majority of black South Africans were not enfranchised until 1994. During the 20th century, the black majority sought to recover its rights from the dominant white minority, with this struggle playing a role in the countrys recent history. The National Party imposed apartheid in 1948, institutionalising previous racial segregation, since 1994, all ethnic and linguistic groups have held political representation in the countrys democracy, which comprises a parliamentary republic and nine provinces. South Africa is often referred to as the Rainbow Nation to describe the multicultural diversity. The World Bank classifies South Africa as an economy. Its economy is the second-largest in Africa, and the 34th-largest in the world, in terms of purchasing power parity, South Africa has the seventh-highest per capita income in Africa. However, poverty and inequality remain widespread, with about a quarter of the population unemployed, nevertheless, South Africa has been identified as a middle power in international affairs, and maintains significant regional influence. The name South Africa is derived from the geographic location at the southern tip of Africa. Upon formation the country was named the Union of South Africa in English, since 1961 the long form name in English has been the Republic of South Africa. In Dutch the country was named Republiek van Zuid-Afrika, replaced in 1983 by the Afrikaans Republiek van Suid-Afrika, since 1994 the Republic has had an official name in each of its 11 official languages. Mzansi, derived from the Xhosa noun umzantsi meaning south, is a name for South Africa. South Africa contains some of the oldest archaeological and human fossil sites in the world, extensive fossil remains have been recovered from a series of caves in Gauteng Province. The area is a UNESCO World Heritage site and has termed the Cradle of Humankind
42.
Mafic
–
Mafic is an adjective describing a silicate mineral or igneous rock that is rich in magnesium and iron, and is thus a portmanteau of magnesium and ferric. Most mafic minerals are dark in color, and common rock-forming mafic minerals include olivine, pyroxene, amphibole, common mafic rocks include basalt, dolerite and gabbro. Mafic rocks often also contain calcium-rich varieties of plagioclase feldspar, chemically, mafic rocks are on the other side of the rock spectrum from the felsic rocks. The term roughly corresponds to the basic rock class. Mafic lava, before cooling, has a low viscosity, in comparison to felsic lava, water and other volatiles can more easily and gradually escape from mafic lava. As a result, eruptions of volcanoes made of mafic lavas are less violent than felsic-lava eruptions. Most mafic-lava volcanoes are shield volcanoes, like those in Hawaii, QAPF diagram List of minerals List of rock types
43.
Stillwater igneous complex
–
The Stillwater igneous complex is a large layered mafic intrusion located in southern Montana in Stillwater, Sweet Grass and Park Counties. The complex is exposed across 30 miles of the flank of the Beartooth Mountain Range. The complex has extensive reserves of ore and has a history of being mined for chromium. More recent mining activity has produced palladium and other group elements. The Stillwater complex is a layered intrusion with many similarities to the Bushveld igneous complex of South Africa. The complex was intruded into existing gneisses during the Archean at about 2700 Mya, the region was subsequently intruded by a quartz monzonite stocks and underwent extensive metamorphism, faulting and folding during the Archean at about 2500 Mya. The area was intruded by north trending mafic dikes before being covered by a middle-Cambrian sedimentary rock sequence. The intrusion forms a linear body stretching some 30 miles and striking roughly N60 °W, the exposed thickness is around 18,000 feet with an additional estimated 5000 to 15,000 feet having been removed from the top by pre-Cambrian erosion. The cumulate stratigraphy comprises three zones, The basal zone consists of a chilled fine grained gabbro overlain by gabbro, norite. The ultramafic zone is composed of a lower member consisting of alternating dunite, chromitite, harzburgite and bronzite pyroxenite. The upper third is massive bronzite pyroxenite, the ultramafic zone averages around 3500 feet in thickness. The banded zone is composed of alternating norite, gabbro and anorthosite, the banded zone has a maximum thickness of 14,000 feet. The chromium orebodies are restricted to the member of the ultramafic zone. The platinum group orebodies are located in the part of the banded zone within a horizon referred to as the J-M reef. The J-M Reef is similar to the Merensky Reef of the Bushveld complex of South Africa and it is a continuous layer near the base of the banded zone. It consists of one to three meter thick pegmatitic peridotite and troctolite with disseminated sulfide minerals, common sulfides include pyrrhotite, pentlandite, and chalcopyrite along with lesser amounts of moncheite, cooperite, braggite, kotulskite and platinum-iron alloys. Overall the reef contains an average of 20-25 ppm platinum plus palladium in a two meter thickness. It has a Pd/Pt ratio of about 3.6, Stillwater Mining Company Stillwater Complex rocks and ores gallery, photos with detailed geologic descriptions
44.
Montana
–
Montana /mɒnˈtænə/ is a state in the Western region of the United States. The states name is derived from the Spanish word montaña, Montana has several nicknames, although none official, including Big Sky Country and The Treasure State, and slogans that include Land of the Shining Mountains and more recently The Last Best Place. Montana has a 545-mile border with three Canadian provinces, British Columbia, Alberta, and Saskatchewan, the state to do so. It also borders North Dakota and South Dakota to the east, Wyoming to the south, Montana is ranked 4th in size, but 44th in population and 48th in population density of the 50 United States. The western third of Montana contains numerous mountain ranges, smaller island ranges are found throughout the state. In total,77 named ranges are part of the Rocky Mountains, the eastern half of Montana is characterized by western prairie terrain and badlands. The economy is based on agriculture, including ranching and cereal grain farming. Other significant economic activities include oil, gas, coal and hard rock mining, lumber, the health care, service, and government sectors also are significant to the states economy. Millions of tourists annually visit Glacier National Park, the Little Bighorn Battlefield National Monument, the name Montana comes from the Spanish word Montaña and the Latin word Montana, meaning mountain, or more broadly, mountainous country. Montaña del Norte was the name given by early Spanish explorers to the mountainous region of the west. The name was changed by Representatives Henry Wilson and Benjamin F. Harding, when Ashley presented a bill to establish a temporary government in 1864 for a new territory to be carved out of Idaho, he again chose Montana Territory. This time Rep. Samuel Cox, also of Ohio, objected to the name, Cox complained that the name was a misnomer given most of the territory was not mountainous and that a Native American name would be more appropriate than a Spanish one. Other names such as Shoshone were suggested, but it was decided that the Committee on Territories could name it whatever they wanted, with an area of 147,040 square miles, Montana is slightly larger than Japan. It is the fourth largest state in the United States after Alaska, Texas, and California, the largest landlocked U. S. state, and the worlds 56th largest national state/province subdivision. To the north, Montana shares a 545-mile border with three Canadian provinces, British Columbia, Alberta, and Saskatchewan, the state to do so. It borders North Dakota and South Dakota to the east, Wyoming to the south, the states topography is roughly defined by the Continental Divide, which splits much of the state into distinct eastern and western regions. Most of Montanas 100 or more named mountain ranges are in the western half. The Absaroka and Beartooth ranges in the states south-central part are part of the Central Rocky Mountains
45.
Ferrochrome
–
Ferrochrome is an alloy of chromium and iron containing 50% to 70% chromium by weight. Ferrochrome is produced by electric arc carbothermic reduction of chromite, most of the worlds ferrochrome is produced in South Africa, Kazakhstan and India, which have large domestic chromite resources. Increasing amounts are coming from Russia and China, the production of steel is the largest consumer of ferrochrome, especially the production of stainless steel with chromium content of 10 to 20% is the main application of ferrochrome. Chromium is an element of the Periodic Table, over 80% of the worlds ferrochrome is utilised in the production of stainless steel. In 200628 Mt of stainless steel were produced, stainless steel depends on chromium for its appearance and its resistance to corrosion. The average chrome content in steel is approximately 18%. It is also used when it is desired to add chromium to carbon steel, FeCr from Southern Africa, known as charge chrome and produced from a Cr containing ore with a low carbon content, is most commonly used in stainless steel production. Ferrochrome production is essentially a carbothermic reduction operation taking place at high temperatures, Cr Ore is reduced by coal and coke to form the iron-chromium alloy. The heat for this reaction can come from several forms, and this arc creates temperatures of about 2,800 °C. In the process of smelting, huge amounts of electricity are consumed, tapping of the material from the furnace takes place intermittently. When enough smelted ferrochrome has accumulated in the hearth of the furnace, the tap hole is drilled open, the ferrochrome solidifies in large castings, which are crushed for sale or further processed. Ferrochrome is often classified by the amount of carbon and chrome it contains, the vast majority of FeCr produced is charge chrome from Southern Africa. With high carbon being the second largest segment followed by the sectors of low carbon
