"Chuck Versus the Seduction Impossible" is the fourteenth episode of the fourth season of Chuck. It originally aired on February 7, 2011. This episode followed the intended season finale, "Chuck Versus the Push Mix", making it the first of an additional eleven episodes ordered. Chuck Bartowski, Sarah Walker, and John Casey are sent to Morocco to rescue old friend Roan Montgomery, while Morgan Grimes meets Alex Hugh's mother and Mary Elizabeth Bartowski tries to reconnect with her family.

The fourth season of Chuck was announced on May 13, 2010. Having initially ordered 13 episodes, NBC ordered an additional 11 on October 19, 2010 for a total of 24 episodes. Throughout the season, Chuck faced individual villains: Alexei Volkoff, head of Volkoff Industries, and Volkoff's daughter, Vivian McArthur.