The fourth season of Chuck was announced on May 13, 2010. Having initially ordered 13 episodes, NBC ordered an additional 11 on October 19, 2010 for a total of 24 episodes. Throughout the season, Chuck faced individual villains: Alexei Volkoff, head of Volkoff Industries, and Volkoff's daughter, Vivian McArthur.

Chuck is an American action comedy spy drama television series created by Josh Schwartz and Chris Fedak. The series is about an "average computer-whiz-next-door" named Chuck Bartowski, played by Zachary Levi, who receives an encoded email from an old college friend now working for the CIA. The message embeds the only remaining copy of a software program containing the United States' greatest spy secrets into Chuck's brain, leading the CIA and the NSA to assign him handlers and use him on top-secret missions. Produced by Fake Empire, Wonderland Sound and Vision, and Warner Bros. Television, the series premiered on September 24, 2007, on NBC, airing on Monday nights at 8:00 p.m./7:00 p.m. Central. The opening theme song is a wordless edit of "Short Skirt/Long Jacket" by the American rock band Cake.