Clathrate hydrates, or gas hydrates, clathrates, or hydrates, are crystalline water-based solids physically resembling ice, in which small non-polar molecules or polar molecules with large hydrophobic moieties are trapped inside "cages" of hydrogen bonded, frozen water molecules. In other words, clathrate hydrates are clathrate compounds in which the host molecule is water and the guest molecule is typically a gas or liquid. Without the support of the trapped molecules, the lattice structure of hydrate clathrates would collapse into conventional ice crystal structure or liquid water. Most low molecular weight gases, including O2, H2, N2, CO2, CH4, H2S, Ar, Kr, and Xe, as well as some higher hydrocarbons and freons, will form hydrates at suitable temperatures and pressures. Clathrate hydrates are not officially chemical compounds, as the enclathrated guest molecules are never bonded to the lattice. The formation and decomposition of clathrate hydrates are first order phase transitions, not chemical reactions. Their detailed formation and decomposition mechanisms on a molecular level are still not well understood.
Clathrate hydrates were first documented in 1810 by Sir Humphry Davy who found that water was a primary component of what was earlier thought to be solidified chlorine.
Methane clathrate block embedded in the sediment of hydrate ridge, off Oregon, USA
Cages building the different gas hydrate structures
Ice is water that is frozen into a solid state, typically forming at or below temperatures of 0 °C, 32 °F, or 273.15 K. As a naturally occurring crystalline inorganic solid with an ordered structure, ice is considered to be a mineral. Depending on the presence of impurities such as particles of soil or bubbles of air, it can appear transparent or a more or less opaque bluish-white color.
An ice block, photographed at the Duluth Canal Park in Minnesota
This iceberg can stay afloat in spite of its size because it is less dense than water
So-called feather ice on the plateau near Alta, Norway. The crystals form at temperatures below −30 °C (−22 °F) and contain a lot of trapped air, making them light enough to be supported by the thin branch
Frozen waterfall in southeast New York