Doune is a burgh within Perthshire. The town is administered by Stirling Council. Doune is assigned Falkirk postcodes starting "FK". The village lies within the parish of Kilmadock and mainly within the area surrounded by the River Teith and Ardoch Burn.

Perthshire, officially the County of Perth, is a historic county and registration county in central Scotland. Geographically it extends from Strathmore in the east, to the Pass of Drumochter in the north, Rannoch Moor and Ben Lui in the west, and Aberfoyle in the south; it borders the counties of Inverness-shire and Aberdeenshire to the north, Angus to the east, Fife, Kinross-shire, Clackmannanshire, Stirlingshire and Dunbartonshire to the south and Argyllshire to the west. It was a local government county from 1890 to 1930.