1.
Phyllosilicate
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Silicate minerals are rock-forming minerals made up of silicate groups. They are the largest and most important class of rock-forming minerals and they are classified based on the structure of their silicate groups, which contain different ratios of silicon and oxygen. Nesosilicates, or orthosilicates, have the orthosilicate ion, which constitute isolated 4− tetrahedra that are connected only by interstitial cations and these exist as 3-member 6− and 6-member 12− rings, where T stands for a tetrahedrally coordinated cation. Inosilicates, or chain silicates, have interlocking chains of silicate tetrahedra with either SiO3,1,3 ratio, for single chains or Si4O11,4,11 ratio, for double chains. Nickel–Strunz classification,09. D Pyroxene group Enstatite – orthoferrosilite series Enstatite – MgSiO3 Ferrosilite – FeSiO3 Pigeonite – Ca0.251, all phyllosilicate minerals are hydrated, with either water or hydroxyl groups attached. Serpentine subgroup Antigorite – Mg3Si2O54 Chrysotile – Mg3Si2O54 Lizardite – Mg3Si2O54 Clay minerals group Halloysite – Al2Si2O54 Kaolinite – Al2Si2O54 Illite – 24O10 Montmorillonite –0 and this group comprises nearly 75% of the crust of the Earth. Tectosilicates, with the exception of the group, are aluminosilicates. Nickel–Strunz classification,09. F and 09. G,04. A, an introduction to the rock-forming minerals. Wise, W. S. Zussman, J. Rock-forming minerals, P.982 pp. Hurlbut, Cornelius S. Danas Manual of Mineralogy. Mindat. org, Dana classification Webmineral, Danas New Silicate Classification Media related to Silicates at Wikimedia Commons
2.
Chemical formula
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These are limited to a single typographic line of symbols, which may include subscripts and superscripts. A chemical formula is not a name, and it contains no words. Although a chemical formula may imply certain simple chemical structures, it is not the same as a full chemical structural formula. Chemical formulas can fully specify the structure of only the simplest of molecules and chemical substances, the simplest types of chemical formulas are called empirical formulas, which use letters and numbers indicating the numerical proportions of atoms of each type. Molecular formulas indicate the numbers of each type of atom in a molecule. For example, the formula for glucose is CH2O, while its molecular formula is C6H12O6. This is possible if the relevant bonding is easy to show in one dimension, an example is the condensed molecular/chemical formula for ethanol, which is CH3-CH2-OH or CH3CH2OH. For reasons of structural complexity, there is no condensed chemical formula that specifies glucose, chemical formulas may be used in chemical equations to describe chemical reactions and other chemical transformations, such as the dissolving of ionic compounds into solution. A chemical formula identifies each constituent element by its chemical symbol, in empirical formulas, these proportions begin with a key element and then assign numbers of atoms of the other elements in the compound, as ratios to the key element. For molecular compounds, these numbers can all be expressed as whole numbers. For example, the formula of ethanol may be written C2H6O because the molecules of ethanol all contain two carbon atoms, six hydrogen atoms, and one oxygen atom. Some types of compounds, however, cannot be written with entirely whole-number empirical formulas. An example is boron carbide, whose formula of CBn is a variable non-whole number ratio with n ranging from over 4 to more than 6.5. When the chemical compound of the consists of simple molecules. These types of formulas are known as molecular formulas and condensed formulas. A molecular formula enumerates the number of atoms to reflect those in the molecule, so that the formula for glucose is C6H12O6 rather than the glucose empirical formula. However, except for very simple substances, molecular chemical formulas lack needed structural information, for simple molecules, a condensed formula is a type of chemical formula that may fully imply a correct structural formula. For example, ethanol may be represented by the chemical formula CH3CH2OH
3.
Crystal system
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In crystallography, the terms crystal system, crystal family and lattice system each refer to one of several classes of space groups, lattices, point groups or crystals. Informally, two crystals are in the crystal system if they have similar symmetries, though there are many exceptions to this. Space groups and crystals are divided into seven crystal systems according to their point groups, five of the crystal systems are essentially the same as five of the lattice systems, but the hexagonal and trigonal crystal systems differ from the hexagonal and rhombohedral lattice systems. The six crystal families are formed by combining the hexagonal and trigonal crystal systems into one hexagonal family, a lattice system is a class of lattices with the same set of lattice point groups, which are subgroups of the arithmetic crystal classes. The 14 Bravais lattices are grouped into seven lattice systems, triclinic, monoclinic, orthorhombic, tetragonal, rhombohedral, hexagonal, in a crystal system, a set of point groups and their corresponding space groups are assigned to a lattice system. Of the 32 point groups that exist in three dimensions, most are assigned to only one system, in which case both the crystal and lattice systems have the same name. However, five point groups are assigned to two systems, rhombohedral and hexagonal, because both exhibit threefold rotational symmetry. These point groups are assigned to the crystal system. In total there are seven crystal systems, triclinic, monoclinic, orthorhombic, tetragonal, trigonal, hexagonal, a crystal family is determined by lattices and point groups. It is formed by combining crystal systems which have space groups assigned to a lattice system. In three dimensions, the families and systems are identical, except the hexagonal and trigonal crystal systems. In total there are six families, triclinic, monoclinic, orthorhombic, tetragonal, hexagonal. Spaces with less than three dimensions have the number of crystal systems, crystal families and lattice systems. In one-dimensional space, there is one crystal system, in 2D space, there are four crystal systems, oblique, rectangular, square and hexagonal. The relation between three-dimensional crystal families, crystal systems and lattice systems is shown in the table, Note. To avoid confusion of terminology, the term trigonal lattice is not used, if the original structure and inverted structure are identical, then the structure is centrosymmetric. Still, even for non-centrosymmetric case, inverted structure in some cases can be rotated to align with the original structure and this is the case of non-centrosymmetric achiral structure. If the inverted structure cannot be rotated to align with the structure, then the structure is chiral
4.
Monoclinic crystal system
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In crystallography, the monoclinic crystal system is one of the 7 crystal systems. A crystal system is described by three vectors, in the monoclinic system, the crystal is described by vectors of unequal lengths, as in the orthorhombic system. They form a rectangular prism with a parallelogram as its base, hence two vectors are perpendicular, while the third vector meets the other two at an angle other than 90°. There is only one monoclinic Bravais lattice in two dimensions, the oblique lattice, two monoclinic Bravais lattices exist, the primitive monoclinic and the centered monoclinic lattices. In this axis setting, the primitive and base-centered lattices interchange in centering type, sphenoidal is also monoclinic hemimorphic, Domatic is also monoclinic hemihedral, Prismatic is also monoclinic normal. Crystal structure Hurlbut, Cornelius S. Klein, Cornelis, hahn, Theo, ed. International Tables for Crystallography, Volume A, Space Group Symmetry
5.
Crystallographic point group
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For a periodic crystal, the group must also be consistent with maintenance of the three-dimensional translational symmetry that defines crystallinity. The macroscopic properties of a crystal would look exactly the same before, in the classification of crystals, each point group is also known as a crystal class. There are infinitely many three-dimensional point groups, however, the crystallographic restriction of the infinite families of general point groups results in there being only 32 crystallographic point groups. These 32 point groups are one-and-the same as the 32 types of morphological crystalline symmetries derived in 1830 by Johann Friedrich Christian Hessel from a consideration of observed crystal forms, the point groups are denoted by their component symmetries. There are a few standard notations used by crystallographers, mineralogists, for the correspondence of the two systems below, see crystal system. In Schoenflies notation, point groups are denoted by a symbol with a subscript. The symbols used in crystallography mean the following, Cn indicates that the group has a rotation axis. Cnh is Cn with the addition of a plane perpendicular to the axis of rotation. Cnv is Cn with the addition of n mirror planes parallel to the axis of rotation, s2n denotes a group that contains only a 2n-fold rotation-reflection axis. Dn indicates that the group has a rotation axis plus n twofold axes perpendicular to that axis. Dnh has, in addition, a plane perpendicular to the n-fold axis. Dnd has, in addition to the elements of Dn, mirror planes parallel to the n-fold axis, the letter T indicates that the group has the symmetry of a tetrahedron. Td includes improper rotation operations, T excludes improper rotation operations, the letter O indicates that the group has the symmetry of an octahedron, with or without improper operations. Due to the crystallographic restriction theorem, n =1,2,3,4, d4d and D6d are actually forbidden because they contain improper rotations with n=8 and 12 respectively. The 27 point groups in the table plus T, Td, Th, O, an abbreviated form of the Hermann–Mauguin notation commonly used for space groups also serves to describe crystallographic point groups. Group names are Molecular symmetry Point group Space group Point groups in three dimensions Crystal system Point-group symbols in International Tables for Crystallography,12.1, pp. 818-820 Names and symbols of the 32 crystal classes in International Tables for Crystallography. 10.1, p.794 Pictorial overview of the 32 groups Point Groups - Flow Chart Inorganic Chemistry Group Theory Practice Problems
6.
H-M symbol
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In geometry, Hermann–Mauguin notation is used to represent the symmetry elements in point groups, plane groups and space groups. It is named after the German crystallographer Carl Hermann and the French mineralogist Charles-Victor Mauguin and this notation is sometimes called international notation, because it was adopted as standard by the International Tables For Crystallography since their first edition in 1935. Rotation axes are denoted by a number n —1,2,3,4,5,6,7,8, for improper rotations, Hermann–Mauguin symbols show rotoinversion axes, unlike Schoenflies and Shubnikov notations, where the preference is given to rotation-reflection axes. The rotoinversion axes are represented by the number with a macron. The symbol for a plane is m. The direction of the plane is defined as the direction of perpendicular to the face. Hermann–Mauguin symbols show symmetrically non-equivalent axes and planes, the direction of a symmetry element is represented by its position in the Hermann–Mauguin symbol. If a rotation axis n and a mirror plane m have the same direction, if two or more axes have the same direction, the axis with higher symmetry is shown. Higher symmetry means that the axis generates a pattern with more points, for example, rotation axes 3,4,5,6,7,8 generate 3-, 4-, 5-, 6-, 7-, 8-point patterns, respectively. Improper rotation axes 3,4,5,6,7,8 generate 6-, 4-, 10-, 6-, 14-, 8-point patterns, if both, the rotation and rotoinversion axes satisfy the previous rule, the rotation axis should be chosen. For example, 3/m combination is equivalent to 6, since 6 generates 6 points, and 3 generates only 3,6 should be written instead of 3/m. Analogously, in the case when both 3 and 3 axes are present,3 should be written, however we write 4/m, not 4/m, because both 4 and 4 generate four points. Finally, the Hermann–Mauguin symbol depends on the type of the group and these groups may contain only two-fold axes, mirror planes, and inversion center. These are the point groups 1 and 1,2, m, and 2/m, and 222, 2/m2/m2/m. If the symbol contains three positions, then they denote symmetry elements in the x, y, z direction, First position — primary direction — z direction, assigned to the higher-order axis. Second position — symmetrically equivalent secondary directions, which are perpendicular to the z-axis and these can be 2, m, or 2/m. Third position — symmetrically equivalent tertiary directions, passing between secondary directions and these can be 2, m, or 2/m. These are the crystallographic groups 3,32, 3m,3, and 32/m,4,422, 4mm,4, 42m, 4/m, and 4/m2/m2/m, and 6,622, 6mm,6, 6m2, 6/m, and 6/m2/m2/m
7.
Space group
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In mathematics, physics and chemistry, a space group is the symmetry group of a configuration in space, usually in three dimensions. In three dimensions, there are 219 distinct types, or 230 if chiral copies are considered distinct, Space groups are also studied in dimensions other than 3 where they are sometimes called Bieberbach groups, and are discrete cocompact groups of isometries of an oriented Euclidean space. In crystallography, space groups are called the crystallographic or Fedorov groups. A definitive source regarding 3-dimensional space groups is the International Tables for Crystallography, in 1879 Leonhard Sohncke listed the 65 space groups whose elements preserve the orientation. More accurately, he listed 66 groups, but Fedorov and Schönflies both noticed that two of them were really the same, the space groups in 3 dimensions were first enumerated by Fedorov, and shortly afterwards were independently enumerated by Schönflies. The correct list of 230 space groups was found by 1892 during correspondence between Fedorov and Schönflies, burckhardt describes the history of the discovery of the space groups in detail. The space groups in three dimensions are made from combinations of the 32 crystallographic point groups with the 14 Bravais lattices, the combination of all these symmetry operations results in a total of 230 different space groups describing all possible crystal symmetries. The elements of the space group fixing a point of space are rotations, reflections, the identity element, the translations form a normal abelian subgroup of rank 3, called the Bravais lattice. There are 14 possible types of Bravais lattice, the quotient of the space group by the Bravais lattice is a finite group which is one of the 32 possible point groups. Translation is defined as the moves from one point to another point. A glide plane is a reflection in a plane, followed by a parallel with that plane. This is noted by a, b or c, depending on which axis the glide is along. There is also the n glide, which is a glide along the half of a diagonal of a face, and the d glide, the latter is called the diamond glide plane as it features in the diamond structure. In 17 space groups, due to the centering of the cell, the glides occur in two directions simultaneously, i. e. the same glide plane can be called b or c, a or b. For example, group Abm2 could be also called Acm2, group Ccca could be called Cccb, in 1992, it was suggested to use symbol e for such planes. The symbols for five groups have been modified, A screw axis is a rotation about an axis. These are noted by a number, n, to describe the degree of rotation, the degree of translation is then added as a subscript showing how far along the axis the translation is, as a portion of the parallel lattice vector. So,21 is a rotation followed by a translation of 1/2 of the lattice vector
8.
Crystal structure
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In crystallography, crystal structure is a description of the ordered arrangement of atoms, ions or molecules in a crystalline material. Ordered structures occur from the nature of the constituent particles to form symmetric patterns that repeat along the principal directions of three-dimensional space in matter. The smallest group of particles in the material that constitutes the pattern is the unit cell of the structure. The unit cell completely defines the symmetry and structure of the crystal lattice. The repeating patterns are said to be located at the points of the Bravais lattice, the lengths of the principal axes, or edges, of the unit cell and the angles between them are the lattice constants, also called lattice parameters. The symmetry properties of the crystal are described by the concept of space groups, all possible symmetric arrangements of particles in three-dimensional space may be described by the 230 space groups. The crystal structure and symmetry play a role in determining many physical properties, such as cleavage, electronic band structure. The crystal structure of a material can be described in terms of its unit cell, the unit cell is a box containing one or more atoms arranged in three dimensions. The unit cells stacked in three-dimensional space describe the arrangement of atoms of the crystal. Commonly, atomic positions are represented in terms of fractional coordinates, the atom positions within the unit cell can be calculated through application of symmetry operations to the asymmetric unit. The asymmetric unit refers to the smallest possible occupation of space within the unit cell and this does not, however imply that the entirety of the asymmetric unit must lie within the boundaries of the unit cell. Symmetric transformations of atom positions are calculated from the group of the crystal structure. Vectors and planes in a lattice are described by the three-value Miller index notation. It uses the indices ℓ, m, and n as directional parameters, which are separated by 90°, by definition, the syntax denotes a plane that intercepts the three points a1/ℓ, a2/m, and a3/n, or some multiple thereof. That is, the Miller indices are proportional to the inverses of the intercepts of the plane with the unit cell, if one or more of the indices is zero, it means that the planes do not intersect that axis. A plane containing a coordinate axis is translated so that it no longer contains that axis before its Miller indices are determined, the Miller indices for a plane are integers with no common factors. Negative indices are indicated with horizontal bars, as in, in an orthogonal coordinate system for a cubic cell, the Miller indices of a plane are the Cartesian components of a vector normal to the plane. Likewise, the planes are geometric planes linking nodes
9.
Crystal habit
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In mineralogy, crystal habit is the characteristic external shape of an individual crystal or crystal group. A single crystals habit is a description of its shape and its crystallographic forms. Recognizing the habit may help in identifying a mineral, when the faces are well-developed due to uncrowded growth a crystal is called euhedral, one with partially developed faces is subhedral, and one with undeveloped crystal faces is called anhedral. The long axis of a quartz crystal typically has a six-sided prismatic habit with parallel opposite faces. Aggregates can be formed of individual crystals with euhedral to anhedral grains, the arrangement of crystals within the aggregate can be characteristic of certain minerals. For example, minerals used for asbestos insulation often grow in a fibrous habit, the terms used by mineralogists to report crystal habits describe the typical appearance of an ideal mineral. Recognizing the habit can aid in identification as some habits are characteristic, most minerals, however, do not display ideal habits due to conditions during crystallization. Minerals belonging to the crystal system do not necessarily exhibit the same habit. Some habits of a mineral are unique to its variety and locality, For example, while most sapphires form elongate barrel-shaped crystals, ordinarily, the latter habit is seen only in ruby. Sapphire and ruby are both varieties of the mineral, corundum. Some minerals may replace other existing minerals while preserving the originals habit, a classic example is tigers eye quartz, crocidolite asbestos replaced by silica. While quartz typically forms prismatic crystals, in tigers eye the original fibrous habit of crocidolite is preserved, the names of crystal habits are derived from, Predominant crystal faces. Abnormal grain growth Grain growth Crystallization
10.
Cleavage (crystal)
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Cleavage, in mineralogy, is the tendency of crystalline materials to split along definite crystallographic structural planes. Cleavage forms parallel to planes, Basal or pinacoidal cleavage occurs when there is only one cleavage plane. Mica also has basal cleavage, this is why mica can be peeled into thin sheets, cubic cleavage occurs on when there are three cleavage planes intersecting at 90 degrees. Halite has cubic cleavage, and therefore, when halite crystals are broken, octahedral cleavage occurs when there are four cleavage planes in a crystal. Octahedral cleavage is common for semiconductors, rhombohedral cleavage occurs when there are three cleavage planes intersecting at angles that are not 90 degrees. Prismatic cleavage occurs when there are two planes in a crystal. Dodecahedral cleavage occurs when there are six cleavage planes in a crystal, crystal parting occurs when minerals break along planes of structural weakness due to external stress or along twin composition planes. Parting breaks are very similar in appearance to cleavage, but only due to stress. Examples include magnetite which shows octahedral parting, the parting of corundum. Cleavage is a property traditionally used in mineral identification, both in hand specimen and microscopic examination of rock and mineral studies. As an example, the angles between the cleavage planes for the pyroxenes and the amphiboles are diagnostic. Crystal cleavage is of importance in the electronics industry and in the cutting of gemstones. Precious stones are generally cleaved by impact, as in diamond cutting, synthetic single crystals of semiconductor materials are generally sold as thin wafers which are much easier to cleave. Elemental semiconductors are diamond cubic, a group for which octahedral cleavage is observed. This means that some orientations of wafer allow near-perfect rectangles to be cleaved, most other commercial semiconductors can be made in the related zinc blende structure, with similar cleavage planes. Cleavage Mineral galleries, Mineral properties – Cleavage
11.
Mohs scale of mineral hardness
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The Mohs scale of mineral hardness is a qualitative ordinal scale characterizing scratch resistance of various minerals through the ability of harder material to scratch softer material. Created in 1812 by German geologist and mineralogist Friedrich Mohs, it is one of several definitions of hardness in materials science, while greatly facilitating the identification of minerals in the field, the Mohs scale does not show how well hard materials perform in an industrial setting. Despite its lack of precision, the Mohs scale is highly relevant for field geologists, the Mohs scale hardness of minerals can be commonly found in reference sheets. Reference materials may be expected to have a uniform Mohs hardness, the Mohs scale of mineral hardness is based on the ability of one natural sample of mineral to scratch another mineral visibly. The samples of matter used by Mohs are all different minerals, Minerals are pure substances found in nature. Rocks are made up of one or more minerals, as the hardest known naturally occurring substance when the scale was designed, diamonds are at the top of the scale. The hardness of a material is measured against the scale by finding the hardest material that the material can scratch. For example, if material is scratched by apatite but not by fluorite. Scratching a material for the purposes of the Mohs scale means creating non-elastic dislocations visible to the naked eye, frequently, materials that are lower on the Mohs scale can create microscopic, non-elastic dislocations on materials that have a higher Mohs number. The Mohs scale is an ordinal scale. For example, corundum is twice as hard as topaz, the table below shows the comparison with the absolute hardness measured by a sclerometer, with pictorial examples. On the Mohs scale, a streak plate has a hardness of 7.0, using these ordinary materials of known hardness can be a simple way to approximate the position of a mineral on the scale. The table below incorporates additional substances that may fall between levels, Comparison between Hardness and Hardness, Mohs hardness of elements is taken from G. V, samsonov in Handbook of the physicochemical properties of the elements, IFI-Plenum, New York, USA,1968. The Hardness of Minerals and Rocks
12.
Lustre (mineralogy)
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Lustre or luster is the way light interacts with the surface of a crystal, rock, or mineral. The word traces its origins back to the latin lux, meaning light, a range of terms are used to describe lustre, such as earthy, metallic, greasy, and silky. Similarly, the term refers to a glassy lustre. A list of terms is given below. Lustre varies over a continuum, and so there are no rigid boundaries between the different types of lustre. The terms are frequently combined to describe types of lustre. Some minerals exhibit unusual optical phenomena, such as asterism or chatoyancy, a list of such phenomena is given below. Adamantine minerals possess a superlative lustre, which is most notably seen in diamond, such minerals are transparent or translucent, and have a high refractive index. Minerals with an adamantine lustre are uncommon, with examples being cerussite. Minerals with a degree of lustre are referred to as subadamantine, with some examples being garnet. Dull minerals exhibit little to no lustre, due to coarse granulations which scatter light in all directions, a distinction is sometimes drawn between dull minerals and earthy minerals, with the latter being coarser, and having even less lustre. Greasy minerals resemble fat or grease, a greasy lustre often occurs in minerals containing a great abundance of microscopic inclusions, with examples including opal and cordierite. Many minerals with a greasy lustre also feel greasy to the touch, metallic minerals have the lustre of polished metal, and with ideal surfaces will work as a reflective surface. Examples include galena, pyrite and magnetite, pearly minerals consist of thin transparent co-planar sheets. Light reflecting from these layers give them a lustre reminiscent of pearls, such minerals possess perfect cleavage, with examples including muscovite and stilbite. Resinous minerals have the appearance of resin, chewing gum or plastic, a principal example is amber, which is a form of fossilized resin. Silky minerals have an arrangement of extremely fine fibres, giving them a lustre reminiscent of silk. Examples include asbestos, ulexite and the satin spar variety of gypsum, a fibrous lustre is similar, but has a coarser texture
13.
Streak (mineralogy)
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The streak of a mineral is the color of the powder produced when it is dragged across an un-weathered surface. If no streak seems to be made, the streak is said to be white or colorless. Streak is particularly important as a diagnostic for opaque and colored materials and it is less useful for silicate minerals, most of which have a white streak or are too hard to powder easily. The apparent color of a mineral can vary widely because of impurities or a disturbed macroscopic crystal structure. Small amounts of an impurity that strongly absorbs a particular wavelength can radically change the wavelengths of light that are reflected by the specimen, and thus change the apparent color. However, when the specimen is dragged to produce a streak, it is broken into randomly oriented microscopic crystals, the surface across which the mineral is dragged is called a streak plate, and is generally made of unglazed porcelain tile. In the absence of a plate, the unglazed underside of a porcelain bowl or vase or the back of a glazed tile will work. Sometimes a streak is more easily or accurately described by comparing it with the streak made by another streak plate. Because the trail left behind results from the mineral being crushed into powder, in case of harder minerals, the color of the powder can be determined by filing or crushing with a hammer a small sample, which is then usually rubbed on a streak plate. Most minerals that are harder have a white streak. Some minerals leave a similar to their natural color, such as cinnabar. Other minerals leave surprising colors, such as fluorite, which always has a streak, although it can appear in purple, blue, yellow. Hematite, which is black in appearance, leaves a red streak which accounts for its name, galena, which can be similar in appearance to hematite, is easily distinguished by its gray streak. Hamilton, W. R. Cambridge Guide to Minerals, Rocks, the Encyclopedia of Gemstones and Minerals. New York, Facts on File. p.251, physical Characteristics of Minerals, at Introduction to Mineralogy by Andrea Bangert What is Streak
14.
Transparency and translucency
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In the field of optics, transparency is the physical property of allowing light to pass through the material without being scattered. On a macroscopic scale, the photons can be said to follow Snells Law, in other words, a translucent medium allows the transport of light while a transparent medium not only allows the transport of light but allows for image formation. The opposite property of translucency is opacity, transparent materials appear clear, with the overall appearance of one color, or any combination leading up to a brilliant spectrum of every color. When light encounters a material, it can interact with it in different ways. These interactions depend on the wavelength of the light and the nature of the material, photons interact with an object by some combination of reflection, absorption and transmission. Some materials, such as glass and clean water, transmit much of the light that falls on them and reflect little of it. Many liquids and aqueous solutions are highly transparent, absence of structural defects and molecular structure of most liquids are mostly responsible for excellent optical transmission. Materials which do not transmit light are called opaque, many such substances have a chemical composition which includes what are referred to as absorption centers. Many substances are selective in their absorption of light frequencies. They absorb certain portions of the spectrum while reflecting others. The frequencies of the spectrum which are not absorbed are either reflected or transmitted for our physical observation and this is what gives rise to color. The attenuation of light of all frequencies and wavelengths is due to the mechanisms of absorption. Transparency can provide almost perfect camouflage for animals able to achieve it and this is easier in dimly-lit or turbid seawater than in good illumination. Many marine animals such as jellyfish are highly transparent, at the atomic or molecular level, physical absorption in the infrared portion of the spectrum depends on the frequencies of atomic or molecular vibrations or chemical bonds, and on selection rules. Nitrogen and oxygen are not greenhouse gases because there is no absorption because there is no molecular dipole moment. With regard to the scattering of light, the most critical factor is the scale of any or all of these structural features relative to the wavelength of the light being scattered. Primary material considerations include, Crystalline structure, whether or not the atoms or molecules exhibit the long-range order evidenced in crystalline solids, glassy structure, scattering centers include fluctuations in density or composition. Microstructure, scattering centers include internal surfaces such as boundaries, crystallographic defects
15.
Specific gravity
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This page is about the measurement using water as a reference. For a general use of gravity, see relative density. See intensive property for the property implied by specific, Apparent specific gravity is the ratio of the weight of a volume of the substance to the weight of an equal volume of the reference substance. The reference substance is always water at its densest for liquids. Nonetheless, the temperature and pressure must be specified for both the sample and the reference, pressure is nearly always 1 atm. Temperatures for both sample and reference vary from industry to industry, in British beer brewing, the practice for specific gravity as specified above is to multiply it by 1000. Being a ratio of densities, specific gravity is a dimensionless quantity, Specific gravity varies with temperature and pressure, reference and sample must be compared at the same temperature and pressure or be corrected to a standard reference temperature and pressure. Substances with a gravity of 1 are neutrally buoyant in water. Those with SG greater than 1 are denser than water and will, disregarding surface tension effects and those with an SG less than 1 are less dense than water and will float on it. In scientific work, the relationship of mass to volume is expressed directly in terms of the density of the substance under study. It is in industry where specific gravity finds wide application, often for historical reasons. True specific gravity can be expressed mathematically as, S G true = ρ sample ρ H2 O where ρ sample is the density of the sample, the density of water varies with temperature and pressure as does the density of the sample. So it is necessary to specify the temperatures and pressures at which the densities or weights were determined and it is nearly always the case that measurements are made at 1 nominal atmosphere. For true specific gravity calculations, air pressure must be considered, temperatures are specified by the notation with T s representing the temperature at which the samples density was determined and T r the temperature at which the reference density is specified. For example, SG would be understood to mean that the density of the sample was determined at 20°C and of the water at 4°C. Taking into account different sample and reference temperatures, we note that, while S G H2 O =1.000000, it is also the case that S G H2 O =0.998203 /0.999840 =0.998363. Here, temperature is being specified using the current ITS-90 scale, on the previous IPTS-68 scale, the densities at 20 °C and 4 °C are 0.9982071 and 0.9999720 respectively, resulting in an SG value for water of 0.9982343. For example, in the industry, the Plato table lists sucrose concentration by weight against true SG
16.
Refractive index
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In optics, the refractive index or index of refraction n of a material is a dimensionless number that describes how light propagates through that medium. It is defined as n = c v, where c is the speed of light in vacuum, for example, the refractive index of water is 1.333, meaning that light travels 1.333 times faster in a vacuum than it does in water. The refractive index determines how light is bent, or refracted. The refractive indices also determine the amount of light that is reflected when reaching the interface, as well as the angle for total internal reflection. This implies that vacuum has a index of 1. The refractive index varies with the wavelength of light and this is called dispersion and causes the splitting of white light into its constituent colors in prisms and rainbows, and chromatic aberration in lenses. Light propagation in absorbing materials can be described using a refractive index. The imaginary part then handles the attenuation, while the real part accounts for refraction, the concept of refractive index is widely used within the full electromagnetic spectrum, from X-rays to radio waves. It can also be used with wave phenomena such as sound, in this case the speed of sound is used instead of that of light and a reference medium other than vacuum must be chosen. Thomas Young was presumably the person who first used, and invented, at the same time he changed this value of refractive power into a single number, instead of the traditional ratio of two numbers. The ratio had the disadvantage of different appearances, newton, who called it the proportion of the sines of incidence and refraction, wrote it as a ratio of two numbers, like 529 to 396. Hauksbee, who called it the ratio of refraction, wrote it as a ratio with a fixed numerator, hutton wrote it as a ratio with a fixed denominator, like 1.3358 to 1. Young did not use a symbol for the index of refraction, in the next years, others started using different symbols, n, m, and µ. For visible light most transparent media have refractive indices between 1 and 2, a few examples are given in the adjacent table. These values are measured at the yellow doublet D-line of sodium, with a wavelength of 589 nanometers, gases at atmospheric pressure have refractive indices close to 1 because of their low density. Almost all solids and liquids have refractive indices above 1.3, aerogel is a very low density solid that can be produced with refractive index in the range from 1.002 to 1.265. Moissanite lies at the end of the range with a refractive index as high as 2.65. Most plastics have refractive indices in the range from 1.3 to 1.7, for infrared light refractive indices can be considerably higher
17.
Birefringence
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Birefringence is the optical property of a material having a refractive index that depends on the polarization and propagation direction of light. These optically anisotropic materials are said to be birefringent, the birefringence is often quantified as the maximum difference between refractive indices exhibited by the material. Crystals with non-cubic crystal structures are often birefringent, as are plastics under mechanical stress and this effect was first described by the Danish scientist Rasmus Bartholin in 1669, who observed it in calcite, a crystal having one of the strongest birefringences. A mathematical description of wave propagation in a birefringent medium is presented below, following is a qualitative explanation of the phenomenon. Thus rotating the material around this axis does not change its optical behavior and this special direction is known as the optic axis of the material. Light whose polarization is perpendicular to the axis is governed by a refractive index no. Light whose polarization is in the direction of the optic axis sees an optical index ne, for any ray direction there is a linear polarization direction perpendicular to the optic axis, and this is called an ordinary ray. The magnitude of the difference is quantified by the birefringence, Δ n = n e − n o, the propagation of the ordinary ray is simply described by no as if there were no birefringence involved. However the extraordinary ray, as its name suggests, propagates unlike any wave in an optical material. Its refraction at a surface can be using the effective refractive index. However it is in fact an inhomogeneous wave whose power flow is not exactly in the direction of the wave vector and this causes an additional shift in that beam, even when launched at normal incidence, as is popularly observed using a crystal of calcite as photographed above. Rotating the calcite crystal will cause one of the two images, that of the ray, to rotate slightly around that of the ordinary ray. When the light propagates either along or orthogonal to the optic axis, in the first case, both polarizations see the same effective refractive index, so there is no extraordinary ray. In the second case the extraordinary ray propagates at a different phase velocity but is not an inhomogeneous wave, for instance, a quarter-wave plate is commonly used to create circular polarization from a linearly polarized source. The case of so-called biaxial crystals is substantially more complex and these are characterized by three refractive indices corresponding to three principal axes of the crystal. For most ray directions, both polarizations would be classified as extraordinary rays but with different effective refractive indices, being extraordinary waves, however, the direction of power flow is not identical to the direction of the wave vector in either case. The two refractive indices can be determined using the index ellipsoids for given directions of the polarization, note that for biaxial crystals the index ellipsoid will not be an ellipsoid of revolution but is described by three unequal principle refractive indices nα, nβ and nγ. Thus there is no axis around which a rotation leaves the optical properties invariant, for this reason, birefringent materials with three distinct refractive indices are called biaxial
18.
Pleochroism
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Pleochroism is an optical phenomenon in which a substance appears to be different colors when observed at different angles, especially with polarized light. Anisotropic crystals will have properties that vary with the direction of light. The polarization of light determines the direction of the electric field and these kinds of crystals have one or two optical axes. If absorption of light varies with the relative to the optical axis in a crystal then pleochroism results. Anisotropic crystals have double refraction of light where light of different polarizations is bent different amounts by the crystal, the components of a divided light beam follow different paths within the mineral and travel at different speeds. When the mineral is observed at some angle, light following some combination of paths and polarizations will be present, at another angle, the light passing through the crystal will be composed of another combination of light paths and polarizations, each with their own color. The light passing through the mineral will therefore have different colors when it is viewed from different angles, tetragonal, trigonal and hexagonal minerals can only show two colors and are called dichroic. Orthorhombic, monoclinic and triclinic crystals can show three and are trichroic, for example, hypersthene, with two optical axes, can have red, yellow or blue appearance when oriented in three different ways in three-dimensional space. Tourmaline is notable for exhibiting strong pleochroism, gems are sometimes cut and set either to display pleochroism or to hide it, depending on the colors and their attractiveness. The pleochroic colours are at their maximum when light is polarized parallel with a crystallographic axis, the axes are designated X, Y and Z. These axes can be determined from the appearance of a crystal in an interference pattern. Where there are two axes, the acute bisection of the axes gives Z for positive minerals and X for negative minerals. Perpendicular to these is the Y axis, the colour is measured with the polarization parallel to each direction. An absorption formula records the amount of parallel to each axis in the form of X < Y < Z with the left most having the least absorption. Minerals that are very similar often have very different pleochroic color schemes. In such cases, a section of the mineral is used and examined under polarized transmitted light with a petrographic microscope. Another device using this property to identify minerals is the dichroscope
19.
Iron
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Iron is a chemical element with symbol Fe and atomic number 26. It is a metal in the first transition series and it is by mass the most common element on Earth, forming much of Earths outer and inner core. It is the fourth most common element in the Earths crust, like the other group 8 elements, ruthenium and osmium, iron exists in a wide range of oxidation states, −2 to +6, although +2 and +3 are the most common. Elemental iron occurs in meteoroids and other low oxygen environments, but is reactive to oxygen, fresh iron surfaces appear lustrous silvery-gray, but oxidize in normal air to give hydrated iron oxides, commonly known as rust. Unlike the metals that form passivating oxide layers, iron oxides occupy more volume than the metal and thus flake off, Iron metal has been used since ancient times, although copper alloys, which have lower melting temperatures, were used even earlier in human history. Pure iron is soft, but is unobtainable by smelting because it is significantly hardened and strengthened by impurities, in particular carbon. A certain proportion of carbon steel, which may be up to 1000 times harder than pure iron. Crude iron metal is produced in blast furnaces, where ore is reduced by coke to pig iron, further refinement with oxygen reduces the carbon content to the correct proportion to make steel. Steels and iron alloys formed with metals are by far the most common industrial metals because they have a great range of desirable properties. Iron chemical compounds have many uses, Iron oxide mixed with aluminium powder can be ignited to create a thermite reaction, used in welding and purifying ores. Iron forms binary compounds with the halogens and the chalcogens, among its organometallic compounds is ferrocene, the first sandwich compound discovered. Iron plays an important role in biology, forming complexes with oxygen in hemoglobin and myoglobin. Iron is also the metal at the site of many important redox enzymes dealing with cellular respiration and oxidation and reduction in plants. A human male of average height has about 4 grams of iron in his body and this iron is distributed throughout the body in hemoglobin, tissues, muscles, bone marrow, blood proteins, enzymes, ferritin, hemosiderin, and transport in plasma. The mechanical properties of iron and its alloys can be evaluated using a variety of tests, including the Brinell test, Rockwell test, the data on iron is so consistent that it is often used to calibrate measurements or to compare tests. An increase in the content will cause a significant increase in the hardness. Maximum hardness of 65 Rc is achieved with a 0. 6% carbon content, because of the softness of iron, it is much easier to work with than its heavier congeners ruthenium and osmium. Because of its significance for planetary cores, the properties of iron at high pressures and temperatures have also been studied extensively
20.
Potassium
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Potassium is a chemical element with symbol K and atomic number 19. It was first isolated from potash, the ashes of plants, in the periodic table, potassium is one of the alkali metals. Potassium in nature only in ionic salts. It is found dissolved in sea water, and is part of many minerals, naturally occurring potassium is composed of three isotopes, of which 40K is radioactive. Traces of 40K are found in all potassium, and it is the most common radioisotope in the human body, Potassium is chemically very similar to sodium, the previous element in Group 1 of the periodic table. They have a similar energy, which allows for each atom to give up its sole outer electron. That they are different elements combine with the same anions to make similar salts was suspected in 1702. Most industrial applications of potassium exploit the high solubility in water of potassium compounds, heavy crop production rapidly depletes the soil of potassium, and this can be remedied with agricultural fertilizers containing potassium, accounting for 95% of global potassium chemical production. Potassium ions are necessary for the function of all living cells, fresh fruits and vegetables are good dietary sources of potassium. Potassium is the second least dense metal after lithium and it is a soft solid with a low melting point, and can be easily cut with a knife. Freshly cut potassium is silvery in appearance, but it begins to tarnish toward gray immediately on exposure to air, in a flame test, potassium and its compounds emit a lilac color with a peak emission wavelength of 766.5 nanometers. Neutral potassium atoms have 19 electrons, one more than the stable configuration of the noble gas argon. This process requires so little energy that potassium is readily oxidized by atmospheric oxygen, in contrast, the second ionization energy is very high, because removal of two electrons breaks the stable noble gas electronic configuration. Potassium therefore does not readily form compounds with the state of +2 or higher. Potassium is an active metal that reacts violently with oxygen in water. With oxygen it forms potassium peroxide, and with water potassium forms potassium hydroxide, the reaction of potassium with water is dangerous because of its violent exothermic character and the production of hydrogen gas. Hydrogen reacts again with atmospheric oxygen, producing water, which reacts with the remaining potassium and this reaction requires only traces of water, because of this, potassium and the liquid sodium-potassium — NaK — are potent desiccants that can be used to dry solvents prior to distillation. Because of the sensitivity of potassium to water and air, reactions with other elements are only in an inert atmosphere such as argon gas using air-free techniques
21.
Silicate minerals
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Silicate minerals are rock-forming minerals made up of silicate groups. They are the largest and most important class of rock-forming minerals and they are classified based on the structure of their silicate groups, which contain different ratios of silicon and oxygen. Nesosilicates, or orthosilicates, have the orthosilicate ion, which constitute isolated 4− tetrahedra that are connected only by interstitial cations and these exist as 3-member 6− and 6-member 12− rings, where T stands for a tetrahedrally coordinated cation. Inosilicates, or chain silicates, have interlocking chains of silicate tetrahedra with either SiO3,1,3 ratio, for single chains or Si4O11,4,11 ratio, for double chains. Nickel–Strunz classification,09. D Pyroxene group Enstatite – orthoferrosilite series Enstatite – MgSiO3 Ferrosilite – FeSiO3 Pigeonite – Ca0.251, all phyllosilicate minerals are hydrated, with either water or hydroxyl groups attached. Serpentine subgroup Antigorite – Mg3Si2O54 Chrysotile – Mg3Si2O54 Lizardite – Mg3Si2O54 Clay minerals group Halloysite – Al2Si2O54 Kaolinite – Al2Si2O54 Illite – 24O10 Montmorillonite –0 and this group comprises nearly 75% of the crust of the Earth. Tectosilicates, with the exception of the group, are aluminosilicates. Nickel–Strunz classification,09. F and 09. G,04. A, an introduction to the rock-forming minerals. Wise, W. S. Zussman, J. Rock-forming minerals, P.982 pp. Hurlbut, Cornelius S. Danas Manual of Mineralogy. Mindat. org, Dana classification Webmineral, Danas New Silicate Classification Media related to Silicates at Wikimedia Commons
22.
Mica
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The mica group of sheet silicate minerals includes several closely related materials having nearly perfect basal cleavage. All are monoclinic, with a tendency towards pseudohexagonal crystals, and are similar in chemical composition, the nearly perfect cleavage, which is the most prominent characteristic of mica, is explained by the hexagonal sheet-like arrangement of its atoms. The word mica is derived from the Latin word mica, meaning a crumb, and probably influenced by micare, to glitter. Chemically, micas can be given the general formula X2Y4–6Z8O204 in which X is K, Na, or Ca or less commonly Ba, Rb, or Cs, Y is Al, Mg, or Fe or less commonly Mn, Cr, Ti, Li, etc. Z is chiefly Si or Al, but also may include Fe3+ or Ti, structurally, micas can be classed as dioctahedral and trioctahedral. If the X ion is K or Na, the mica is a common mica, whereas if the X ion is Ca, mica is widely distributed and occurs in igneous, metamorphic and sedimentary regimes. Large crystals of mica used for various applications are typically mined from granitic pegmatites, until the 19th century, large crystals of mica were quite rare and expensive as a result of the limited supply in Europe. However, their price dramatically dropped when large reserves were found and mined in Africa, the largest documented single crystal of mica was found in Lacey Mine, Ontario, Canada, it measured 10 ×4.3 ×4.3 m and weighed about 330 tonnes. Similar-sized crystals were found in Karelia, Russia. The British Geological Survey reported that as of 2005, Koderma district in Jharkhand state in India had the largest deposits of mica in the world. China was the top producer of mica with almost a third of the share, closely followed by the US, South Korea. Large deposits of mica were mined in New England from the 19th century to the 1970s. Large mines existed in Connecticut, New Hampshire, and Maine, scrap and flake mica is produced all over the world. In 2010, the producers were Russia, Finland, United States, South Korea, France. The total production was 350,000 t, although no data were available for China. Most sheet mica was produced in India and Russia, flake mica comes from several sources, the metamorphic rock called schist as a byproduct of processing feldspar and kaolin resources, from placer deposits, and from pegmatites. Sheet mica is considerably less abundant than flake and scrap mica, the most important sources of sheet mica are pegmatite deposits. Sheet mica prices vary with grade and can range from less than $1 per kilogram for low-quality mica to more than $2,000 per kilogram for the highest quality, the mica group represents 37 phyllosilicate minerals that have a layered or platy texture
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Mineral
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A mineral is a naturally occurring chemical compound, usually of crystalline form and abiogenic in origin. A mineral has one specific chemical composition, whereas a rock can be an aggregate of different minerals or mineraloids, the study of minerals is called mineralogy. There are over 5,300 known mineral species, over 5,070 of these have been approved by the International Mineralogical Association, the silicate minerals compose over 90% of the Earths crust. The diversity and abundance of species is controlled by the Earths chemistry. Silicon and oxygen constitute approximately 75% of the Earths crust, which translates directly into the predominance of silicate minerals, minerals are distinguished by various chemical and physical properties. Differences in chemical composition and crystal structure distinguish the various species, changes in the temperature, pressure, or bulk composition of a rock mass cause changes in its minerals. Minerals can be described by their various properties, which are related to their chemical structure. Common distinguishing characteristics include crystal structure and habit, hardness, lustre, diaphaneity, colour, streak, tenacity, cleavage, fracture, parting, more specific tests for describing minerals include magnetism, taste or smell, radioactivity and reaction to acid. Minerals are classified by key chemical constituents, the two dominant systems are the Dana classification and the Strunz classification, the silicate class of minerals is subdivided into six subclasses by the degree of polymerization in the chemical structure. All silicate minerals have a unit of a 4− silica tetrahedron—that is, a silicon cation coordinated by four oxygen anions. These tetrahedra can be polymerized to give the subclasses, orthosilicates, disilicates, cyclosilicates, inosilicates, phyllosilicates, other important mineral groups include the native elements, sulfides, oxides, halides, carbonates, sulfates, and phosphates. The first criterion means that a mineral has to form by a natural process, stability at room temperature, in the simplest sense, is synonymous to the mineral being solid. More specifically, a compound has to be stable or metastable at 25 °C, modern advances have included extensive study of liquid crystals, which also extensively involve mineralogy. Minerals are chemical compounds, and as such they can be described by fixed or a variable formula, many mineral groups and species are composed of a solid solution, pure substances are not usually found because of contamination or chemical substitution. Finally, the requirement of an ordered atomic arrangement is usually synonymous with crystallinity, however, crystals are also periodic, an ordered atomic arrangement gives rise to a variety of macroscopic physical properties, such as crystal form, hardness, and cleavage. There have been recent proposals to amend the definition to consider biogenic or amorphous substances as minerals. The formal definition of an approved by the IMA in 1995, A mineral is an element or chemical compound that is normally crystalline. However, if geological processes were involved in the genesis of the compound, Mineral classification schemes and their definitions are evolving to match recent advances in mineral science
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Crystallize
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Crystallization is the process where a solid forms where the atoms or molecules are highly organized in a structure known as a crystal. Some of the ways which crystals form are through precipitating from a solution, crystallization is also a chemical solid–liquid separation technique, in which mass transfer of a solute from the liquid solution to a pure solid crystalline phase occurs. In chemical engineering crystallization occurs in a crystallizer, crystallization is therefore related to precipitation, although the result is not amorphous or disordered, but a crystal. The crystallization process consists of two events, nucleation and crystal growth which are driven by thermodynamic properties as well as chemical properties. These stable clusters constitute the nuclei, therefore, the clusters need to reach a critical size in order to become stable nuclei. Such critical size is dictated by different factors. The crystal growth is the subsequent size increase of the nuclei that succeed in achieving the critical cluster size, crystal growth is a dynamic process occurring in equilibrium where solute molecules or atoms precipitate out of solution, and dissolve back into solution. Supersaturation is one of the forces of crystallization, as the solubility of a species is an equilibrium process quantified by Ksp. Depending upon the conditions, either nucleation or growth may be predominant over the other, many compounds have the ability to crystallize with some having different crystal structures, a phenomenon called polymorphism. Each polymorph is in fact a different thermodynamic solid state and crystal polymorphs of the compound exhibit different physical properties, such as dissolution rate, shape, melting point. For this reason, polymorphism is of importance in industrial manufacture of crystalline products. Additionally, crystal phases can sometimes be interconverted by varying factors such as temperature, there are many examples of natural process that involve crystallization. Geological time scale process examples include, Natural crystal formation, Stalactite/stalagmite, usual time scale process examples include, Snow flakes formation, Honey crystallization. Crystal formation can be divided into two types, where the first type of crystals are composed of a cation and anion, also known as a salt, the second type of crystals are composed of uncharged species, for example menthol. The formation of a solution does not guarantee crystal formation. A typical laboratory technique for crystal formation is to dissolve the solid in a solution in which it is partially soluble, the hot mixture is then filtered to remove any insoluble impurities. The filtrate is allowed to slowly cool, crystals that form are then filtered and washed with a solvent in which they are not soluble, but is miscible with the mother liquor. The process is repeated to increase the purity in a technique known as recrystallization
25.
Greek language
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Greek is an independent branch of the Indo-European family of languages, native to Greece and other parts of the Eastern Mediterranean. It has the longest documented history of any living language, spanning 34 centuries of written records and its writing system has been the Greek alphabet for the major part of its history, other systems, such as Linear B and the Cypriot syllabary, were used previously. The alphabet arose from the Phoenician script and was in turn the basis of the Latin, Cyrillic, Armenian, Coptic, Gothic and many other writing systems. Together with the Latin texts and traditions of the Roman world, during antiquity, Greek was a widely spoken lingua franca in the Mediterranean world and many places beyond. It would eventually become the official parlance of the Byzantine Empire, the language is spoken by at least 13.2 million people today in Greece, Cyprus, Italy, Albania, Turkey, and the Greek diaspora. Greek roots are used to coin new words for other languages, Greek. Greek has been spoken in the Balkan peninsula since around the 3rd millennium BC, the earliest written evidence is a Linear B clay tablet found in Messenia that dates to between 1450 and 1350 BC, making Greek the worlds oldest recorded living language. Among the Indo-European languages, its date of earliest written attestation is matched only by the now extinct Anatolian languages, the Greek language is conventionally divided into the following periods, Proto-Greek, the unrecorded but assumed last ancestor of all known varieties of Greek. The unity of Proto-Greek would have ended as Hellenic migrants entered the Greek peninsula sometime in the Neolithic era or the Bronze Age, Mycenaean Greek, the language of the Mycenaean civilisation. It is recorded in the Linear B script on tablets dating from the 15th century BC onwards, Ancient Greek, in its various dialects, the language of the Archaic and Classical periods of the ancient Greek civilisation. It was widely known throughout the Roman Empire, after the Roman conquest of Greece, an unofficial bilingualism of Greek and Latin was established in the city of Rome and Koine Greek became a first or second language in the Roman Empire. The origin of Christianity can also be traced through Koine Greek, Medieval Greek, also known as Byzantine Greek, the continuation of Koine Greek in Byzantine Greece, up to the demise of the Byzantine Empire in the 15th century. Much of the written Greek that was used as the language of the Byzantine Empire was an eclectic middle-ground variety based on the tradition of written Koine. Modern Greek, Stemming from Medieval Greek, Modern Greek usages can be traced in the Byzantine period and it is the language used by the modern Greeks, and, apart from Standard Modern Greek, there are several dialects of it. In the modern era, the Greek language entered a state of diglossia, the historical unity and continuing identity between the various stages of the Greek language is often emphasised. Greek speakers today still tend to regard literary works of ancient Greek as part of their own rather than a foreign language and it is also often stated that the historical changes have been relatively slight compared with some other languages. According to one estimation, Homeric Greek is probably closer to demotic than 12-century Middle English is to modern spoken English, Greek is spoken by about 13 million people, mainly in Greece, Albania and Cyprus, but also worldwide by the large Greek diaspora. Greek is the language of Greece, where it is spoken by almost the entire population
26.
Sand
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Sand is a naturally occurring granular material composed of finely divided rock and mineral particles. It is defined by size, being finer than gravel and coarser than silt, Sand can also refer to a textural class of soil or soil type, i. e. a soil containing more than 85% sand-sized particles by mass. The second most common type of sand is calcium carbonate, for example aragonite, for example, it is the primary form of sand apparent in areas where reefs have dominated the ecosystem for millions of years like the Caribbean. Sand is a non renewable resource over human timescales, and sand suitable for making concrete is in high demand, in terms of particle size as used by geologists, sand particles range in diameter from 0.0625 mm to 2 mm. An individual particle in this size is termed a sand grain. Sand grains are between gravel and silt, a 1953 engineering standard published by the American Association of State Highway and Transportation Officials set the minimum sand size at 0.074 mm. A1938 specification of the United States Department of Agriculture was 0.05 mm. Sand feels gritty when rubbed between the fingers. ISO14688 grades sands as fine, medium and coarse with ranges 0.063 mm to 0.2 mm to 0.63 mm to 2.0 mm. In the United States, sand is commonly divided into five sub-categories based on size, very fine sand, fine sand, medium sand, coarse sand, and very coarse sand. These sizes are based on the Krumbein phi scale, where size in Φ = -log2D, on this scale, for sand the value of Φ varies from −1 to +4, with the divisions between sub-categories at whole numbers. The composition of sand is highly variable, depending on the local rock sources. The gypsum sand dunes of the White Sands National Monument in New Mexico are famous for their bright, arkose is a sand or sandstone with considerable feldspar content, derived from weathering and erosion of a granitic rock outcrop. Some sands contain magnetite, chlorite, glauconite or gypsum, Sands rich in magnetite are dark to black in color, as are sands derived from volcanic basalts and obsidian. Chlorite-glauconite bearing sands are typically green in color, as are sands derived from basaltic with a high olivine content, many sands, especially those found extensively in Southern Europe, have iron impurities within the quartz crystals of the sand, giving a deep yellow color. Sand deposits in some areas contain garnets and other resistant minerals, the study of individual grains can reveal much historical information as to the origin and kind of transport of the grain. Quartz sand that is weathered from granite or gneiss quartz crystals will be angular. It is called grus in geology or sharp sand in the trade where it is preferred for concrete. Sand that is transported long distances by water or wind will be rounded, people who collect sand as a hobby are known as arenophiles
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Chlorite group
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The chlorites are a group of phyllosilicate minerals. Chlorites can be described by the following four endmembers based on their chemistry via substitution of the four elements in the silicate lattice, Mg, Fe, Ni. Clinochlore, O108 Chamosite, O108 Nimite, O108 Pennantite, 64O108 In addition, zinc, lithium, the great range in composition results in considerable variation in physical, optical, and X-ray properties. Similarly, the range of chemical composition allows chlorite group minerals to exist over a range of temperature and pressure conditions. For this reason chlorite minerals are ubiquitous minerals within low and medium temperature metamorphic rocks, some rocks, hydrothermal rocks. The name chlorite is from the Greek chloros, meaning green, the typical general formula is, 34O102·36. This formula emphasizes the structure of the group, chlorites have a 2,1 sandwich structure, this is often referred to as a talc layer. Unlike other 2,1 clay minerals, a chlorites interlayer space is composed of 6 and this 6 unit is more commonly referred to as the brucite-like layer, due to its closer resemblance to the mineral brucite. Therefore, chlorites structure appears as follows, -t-o-t-brucite-t-o-t-brucite, thats why they are also called 2,1,1 minerals. An older classification divided the chlorites into two subgroups, the orthochlorites and leptochlorites, the terms are seldom used and the ortho prefix is somewhat misleading as the chlorite crystal system is monoclinic and not orthorhombic. Chlorite is commonly found in rocks as an alteration product of mafic minerals such as pyroxene, amphibole. Chlorite is a common mineral associated with ore deposits and commonly occurs with epidote, sericite, adularia. Chlorite is also a metamorphic mineral, usually indicative of low-grade metamorphism. It is the species of the zeolite facies and of lower greenschist facies. It occurs in the quartz, albite, sericite, chlorite, within ultramafic rocks, metamorphism can also produce predominantly clinochlore chlorite in association with talc. Chlorite occurs naturally in a variety of locations and forms, for example, chlorite is found naturally in certain parts of Wales in mineral schists. Chlorite is found in large boulders scattered on the surface on Ring Mountain in Marin County. Clinoclore, pennantite, and chamosite are the most common varieties, several other sub-varieties have been described
28.
Clay minerals
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Clay minerals are hydrous aluminium phyllosilicates, sometimes with variable amounts of iron, magnesium, alkali metals, alkaline earths, and other cations found on or near some planetary surfaces. Clay minerals form in the presence of water and have been important to life and they are important constituents of soils, and have been useful to humans since ancient times in agriculture and manufacturing. Clays form flat hexagonal sheets similar to the micas, Clay minerals are common weathering products and low-temperature hydrothermal alteration products. Clay minerals are common in soils, in fine-grained sedimentary rocks such as shale, mudstone. Clay minerals are usually ultrafine-grained and so may require special techniques for their identification. These methods can be augmented by polarized light microscopy, a traditional technique establishing fundamental occurrences or petrologic relationships. Given the requirement of water, clay minerals are rare in the Solar System, though they occur extensively on Earth where water has interacted with other minerals. Clay minerals have been detected at several locations on Mars including Echus Chasma and Mawrth Vallis and the Memnonia quadrangle, spectrography has confirmed their presence on asteroids including the dwarf planet Ceres and Tempel 1 as well as Jupiters moon Europa. A1,1 clay would consist of one sheet and one octahedral sheet. A2,1 clay consists of an octahedral sheet sandwiched between two sheets, and examples are talc, vermiculite and montmorillonite. Smectite group which includes dioctahedral smectites such as montmorillonite, nontronite and beidellite, in 2013, analytical tests by the Curiosity rover found results consistent with the presence of smectite clay minerals on the planet Mars. Illite group which includes the clay-micas, illite is the only common mineral. Chlorite group includes a variety of similar minerals with considerable chemical variation. Other 2,1 clay types exist such as sepiolite or attapulgite, mixed layer clay variations exist for most of the above groups. Ordering is described as random or regular ordering, and is described by the term reichweite. Literature articles will refer to a R1 ordered illite-smectite, for example and this type would be ordered in an ISISIS fashion. R0 on the other hand describes random ordering, and other advanced ordering types are also found, mixed layer clay minerals which are perfect R1 types often get their own names. R1 ordered chlorite-smectite is known as corrensite, R1 illite-smectite is rectorite, knowledge of the nature of clay became better understood in the 1930s with advancements in x-ray diffraction technology necessary to analyze the molecular nature of clay particles
29.
Greensand
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Greensand or Green sand is either a sand or sandstone, which has a greenish color. This term is applied to shallow marine sediment, that contains noticeable quantities of rounded greenish grains. These grains are called glauconies and consist of a mixture of clay minerals. Greensand is also applied to any glauconitic sediment. Greensand forms in anoxic marine environments that are rich in organic detritus, having accumulated in marine environments, greensands can be fossil-rich, such as in the late-Cretaceous deposits of New Jersey, USA. Important exposures are known from northern and western Europe, North America, and north Africa. Well known and important greensands are the Upper and Lower Greensands of England and occur within Eocene and Cretaceous sedimentary strata underlying the coastal plains of New Jersey, in Great Britain, greensand usually refers to specific rock strata of Early Cretaceous age. A distinction is made between the Upper Greensand and Lower Greensand, the soil of the greensand is quite varied, ranging from fertile to fairly sterile. On the fertile soils chestnut and stands of hazel and oak are common, while Scots Pine and these Greensand Ridges are popular long distance walking routes, for instance the Greensand Way in Kent. The Lower Greensand is of Aptian age, the Upper Greensand is of Albian age. It represents a sandy lithofacies deposited in areas of stronger currents than the Gault Clay, outcrops of the Upper Greensand occur in the south-west of England including the Blackdown Hills and East Devon Plateau and the Haldon Hills, remnants of a once much wider extent. It is an ingredient as a source of potassium in organic gardening and farming fertilisers. Greensand glauconite is used as a softener for its chemical-exchange properties. It is also used as a type of rock for stone walls in areas where greensand is common, in Roman times in Britain, coarse grits derived from the lower greensand were used to line the inner surface of mortaria produced in the Oxfordshire pottery kilns
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Marl
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Marl or marlstone is a calcium carbonate or lime-rich mud or mudstone which contains variable amounts of clays and silt. The dominant carbonate mineral in most marls is calcite, but other carbonate minerals such as aragonite, dolomite and it also describes a habit of coralline red alga. The term is often used to describe indurated marine deposits. Marlstone is a rock of about the same composition as marl. It has a blocky subconchoidal fracture, and is less fissile than shale, the term marl is widely used in English-language geology, while the terms Mergel and Seekreide are used in European references. The lower stratigraphic units of the cliffs of Dover consist of a sequence of glauconitic marls followed by rhythmically banded limestone. Upper Cretaceous cyclic sequences in Germany and marl–opal-rich Tortonian-Messinian strata in the Sorbas basin related to multiple sea drawdown have been correlated with Milankovitch orbital forcing, marl as lacustrine sediment is common in post glacial lake-bed sediments, often found underlying peat bogs. It has been used as a conditioner and acid soil neutralizing agent. Marl was extensively mined in Central New Jersey as a soil conditioner in the 1800s, in 1863, the most common marl was blue marl. Marl was in demand for farms. Agricultural lime Keuper marl Schurrenberger, D. Russell, J. classification of lacustrine sediments based on sedimentary components
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Western Canada
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The capital cities of the four western provinces, from West to East, are, Victoria, Edmonton, Regina and Winnipeg. Except for Winnipeg, which is the largest city in Manitoba, Manitoba established as a province of Canada in 1870, following the enacting of the Manitoba Act. Saskatchewan, Established as province in 1905, with the implementation of the Saskatchewan Act, Alberta, In 1905, the same year as Saskatchewan, Alberta also was established as province. Just like Saskatchewan had the Saskatchewan Act, Alberta had the Alberta Act and this represents 31. 5% of Canadas population. While Vancouver serves as the largest metropolitan area in Western Canada, the following is a list of these areas and their populations as of 2011. Western Canada consists of the four westernmost provinces, British Columbia, Alberta, Saskatchewan. It covers 2.9 million square kilometres – almost 29% of Canada’s land area, British Columbia adjoins the Pacific Ocean to the west, while Manitoba has a coastline on Hudson Bay in its northeast of the province. Both Alberta and Saskatchewan are landlocked between British Columbia and Manitoba, the Canadian Prairies are part of a vast sedimentary plain covering much of Alberta, southern Saskatchewan, and southwestern Manitoba. The prairies form a significant portion of the area of Western Canada. The plains generally describes the expanses of flat, arable agricultural land which sustain extensive grain farming operations in the southern part of the provinces. Despite this, some such as the Cypress Hills and Alberta Badlands are quite hilly. In Alberta and British Columbia, the Canadian Cordillera is bounded by the Rocky Mountains to the east, the Canadian Rockies are part of a major continental divide that extends north and south through western North America and western South America. The continental divide also defines much of the border between Alberta and British Columbia, the Columbia and the Fraser Rivers have their headwaters in the Canadian Rockies and are the second- and third-largest rivers, respectively, to drain to the west coast of North America. To the west of their headwaters, across the Rocky Mountain Trench, is a belt of mountains. The coast of British Columbia enjoys an oceanic climate because of the influence of the Pacific Ocean. Winters are typically wet and summers relatively dry and these areas enjoy the mildest winter weather in all of Canada, as temperatures rarely fall much below the freezing mark. The mountainous Interior of the province is drier and has colder winters, Alberta has a dry continental climate with warm summers and cold winters. The province is open to cold Arctic weather systems from the north, winters are generally quite cold, though some areas can experience a phenomenon known as the chinook wind, wherein warm winds raise the winter temperatures temporarily
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Continental shelf
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The continental shelf is an underwater landmass which extends from a continent, resulting in an area of relatively shallow water known as a shelf sea. Much of the shelves were exposed during glacial periods and interglacial periods, the shelf surrounding an island is known as an insular shelf. The continental margin, between the shelf and the abyssal plain, comprises a steep continental slope followed by the flatter continental rise. Sediment from the continent above cascades down the slope and accumulates as a pile of sediment at the base of the slope, extending as far as 500 km from the slope, it consists of thick sediments deposited by turbidity currents from the shelf and slope. The continental rises gradient is intermediate between the slope and the shelf, on the order of 0. 5–1°, the largest shelf – the Siberian Shelf in the Arctic Ocean – stretches to 1,500 kilometers in width. The South China Sea lies over another extensive area of shelf, the Sunda Shelf, which joins Borneo, Sumatra. Other familiar bodies of water that overlie continental shelves are the North Sea, the average width of continental shelves is about 80 km. The depth of the shelf also varies, but is limited to water shallower than 150 m. The slope of the shelf is quite low, on the order of 0. 5°, vertical relief is also minimal. Though the continental shelf is treated as a province of the ocean, it is not part of the deep ocean basin proper. Passive continental margins such as most of the Atlantic coasts have wide and shallow shelves, active continental margins have narrow, relatively steep shelves, due to frequent earthquakes that move sediment to the deep sea. The shelf usually ends at a point of increasing slope, the sea floor below the break is the continental slope. Below the slope is the rise, which finally merges into the deep ocean floor. The continental shelf and the slope are part of the continental margin, the shelf area is commonly subdivided into the inner continental shelf, mid continental shelf, and outer continental shelf, each with their specific geomorphology and marine biology. The character of the shelf changes dramatically at the shelf break, with a few exceptions, the shelf break is located at a remarkably uniform depth of roughly 140 m, this is likely a hallmark of past ice ages, when sea level was lower than it is now. The continental slope is steeper than the shelf, the average angle is 3°. The slope is cut with submarine canyons. The physical mechanisms involved in forming these canyons were not well understood until the 1960s, the continental shelves are covered by terrigenous sediments, that is, those derived from erosion of the continents
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Depositional environment
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In most cases the environments associated with particular rock types or associations of rock types can be matched to existing analogues. However, the back in geological time sediments were deposited. Sedimentary Environments, Processes, Facies and Stratigraphy, sedimentary Environments Classification Charts Depositional environments on e-notes
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Jurassic
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The Jurassic is a geologic period and system that spans 56.3 million years from the end of the Triassic Period 201.3 million years ago to the beginning of the Cretaceous Period 145 Mya. The Jurassic constitutes the middle period of the Mesozoic Era, also known as the Age of Reptiles, the start of the period is marked by the major Triassic–Jurassic extinction event. The Jurassic is named after the Jura Mountains within the European Alps, by the beginning of the Jurassic, the supercontinent Pangaea had begun rifting into two landmasses, Laurasia to the north and Gondwana to the south. This created more coastlines and shifted the continental climate from dry to humid, on land, the fauna transitioned from the Triassic fauna, dominated by both dinosauromorph and crocodylomorph archosaurs, to one dominated by dinosaurs alone. The first birds also appeared during the Jurassic, having evolved from a branch of theropod dinosaurs, other major events include the appearance of the earliest lizards, and the evolution of therian mammals, including primitive placentals. Crocodilians made the transition from a terrestrial to a mode of life. The oceans were inhabited by marine reptiles such as ichthyosaurs and plesiosaurs, the chronostratigraphic term Jurassic is directly linked to the Jura Mountains. The name Jura is derived from the Celtic root jor, which was Latinised into juria, the Jurassic period is divided into the Early Jurassic, Middle, and Late Jurassic epochs. The Jurassic System, in stratigraphy, is divided into the Lower Jurassic, Middle, the separation of the term Jurassic into three sections goes back to Leopold von Buch. The Jurassic North Atlantic Ocean was relatively narrow, while the South Atlantic did not open until the following Cretaceous period, the Tethys Sea closed, and the Neotethys basin appeared. Climates were warm, with no evidence of glaciation, as in the Triassic, there was apparently no land over either pole, and no extensive ice caps existed. In contrast, the North American Jurassic record is the poorest of the Mesozoic, the Jurassic was a time of calcite sea geochemistry in which low-magnesium calcite was the primary inorganic marine precipitate of calcium carbonate. Carbonate hardgrounds were thus very common, along with calcitic ooids, calcitic cements, the first of several massive batholiths were emplaced in the northern American cordillera beginning in the mid-Jurassic, marking the Nevadan orogeny. Important Jurassic exposures are found in Russia, India, South America, Japan, Australasia. As the Jurassic proceeded, larger and more groups of dinosaurs like sauropods and ornithopods proliferated in Africa. Middle Jurassic strata are well represented nor well studied in Africa. Late Jurassic strata are also poorly represented apart from the spectacular Tendaguru fauna in Tanzania, the Late Jurassic life of Tendaguru is very similar to that found in western North Americas Morrison Formation. During the Jurassic period, the primary living in the sea were fish
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Cretaceous
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The Cretaceous is a geologic period and system that spans 79 million years from the end of the Jurassic Period 145 million years ago to the beginning of the Paleogene Period 66 Mya. It is the last period of the Mesozoic Era, the Cretaceous Period is usually abbreviated K, for its German translation Kreide. The Cretaceous was a period with a warm climate, resulting in high eustatic sea levels that created numerous shallow inland seas. These oceans and seas were populated with now-extinct marine reptiles, ammonites and rudists, during this time, new groups of mammals and birds, as well as flowering plants, appeared. The Cretaceous ended with a mass extinction, the Cretaceous–Paleogene extinction event, in which many groups, including non-avian dinosaurs, pterosaurs. The end of the Cretaceous is defined by the abrupt Cretaceous–Paleogene boundary, the name Cretaceous was derived from Latin creta, meaning chalk. The Cretaceous is divided into Early and Late Cretaceous epochs, or Lower and Upper Cretaceous series, in older literature the Cretaceous is sometimes divided into three series, Neocomian, Gallic and Senonian. A subdivision in eleven stages, all originating from European stratigraphy, is now used worldwide, in many parts of the world, alternative local subdivisions are still in use. As with other geologic periods, the rock beds of the Cretaceous are well identified. No great extinction or burst of diversity separates the Cretaceous from the Jurassic and this layer has been dated at 66.043 Ma. A140 Ma age for the Jurassic-Cretaceous boundary instead of the usually accepted 145 Ma was proposed in 2014 based on a study of Vaca Muerta Formation in Neuquén Basin. Víctor Ramos, one of the authors of the study proposing the 140 Ma boundary age sees the study as a first step toward formally changing the age in the International Union of Geological Sciences, due to the high sea level there was extensive space for such sedimentation. Because of the young age and great thickness of the system. Chalk is a type characteristic for the Cretaceous. It consists of coccoliths, microscopically small calcite skeletons of coccolithophores, the group is found in England, northern France, the low countries, northern Germany, Denmark and in the subsurface of the southern part of the North Sea. Chalk is not easily consolidated and the Chalk Group still consists of sediments in many places. The group also has other limestones and arenites, among the fossils it contains are sea urchins, belemnites, ammonites and sea reptiles such as Mosasaurus. In southern Europe, the Cretaceous is usually a marine system consisting of competent limestone beds or incompetent marls
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Limestone
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Limestone is a sedimentary rock, composed mainly of skeletal fragments of marine organisms such as coral, forams and molluscs. Its major materials are the minerals calcite and aragonite, which are different crystal forms of calcium carbonate, about 10% of sedimentary rocks are limestones. The solubility of limestone in water and weak acid solutions leads to karst landscapes, most cave systems are through limestone bedrock. The first geologist to distinguish limestone from dolomite was Belsazar Hacquet in 1778, like most other sedimentary rocks, most limestone is composed of grains. Most grains in limestone are skeletal fragments of organisms such as coral or foraminifera. Other carbonate grains comprising limestones are ooids, peloids, intraclasts and these organisms secrete shells made of aragonite or calcite, and leave these shells behind when they die. Limestone often contains variable amounts of silica in the form of chert or siliceous skeletal fragment, some limestones do not consist of grains at all, and are formed completely by the chemical precipitation of calcite or aragonite, i. e. travertine. Secondary calcite may be deposited by supersaturated meteoric waters and this produces speleothems, such as stalagmites and stalactites. Another form taken by calcite is oolitic limestone, which can be recognized by its granular appearance, the primary source of the calcite in limestone is most commonly marine organisms. Some of these organisms can construct mounds of rock known as reefs, below about 3,000 meters, water pressure and temperature conditions cause the dissolution of calcite to increase nonlinearly, so limestone typically does not form in deeper waters. Limestones may also form in lacustrine and evaporite depositional environments, calcite can be dissolved or precipitated by groundwater, depending on several factors, including the water temperature, pH, and dissolved ion concentrations. Calcite exhibits a characteristic called retrograde solubility, in which it becomes less soluble in water as the temperature increases. Impurities will cause limestones to exhibit different colors, especially with weathered surfaces, Limestone may be crystalline, clastic, granular, or massive, depending on the method of formation. Crystals of calcite, quartz, dolomite or barite may line small cavities in the rock, when conditions are right for precipitation, calcite forms mineral coatings that cement the existing rock grains together, or it can fill fractures. Travertine is a banded, compact variety of limestone formed along streams, particularly there are waterfalls. Calcium carbonate is deposited where evaporation of the leaves a solution supersaturated with the chemical constituents of calcite. Tufa, a porous or cellular variety of travertine, is found near waterfalls, coquina is a poorly consolidated limestone composed of pieces of coral or shells. During regional metamorphism that occurs during the building process, limestone recrystallizes into marble
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Chalk
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Chalk is a soft, white, porous, sedimentary carbonate rock, a form of limestone composed of the mineral calcite. Calcite is a salt called calcium carbonate or CaCO3. It forms under reasonably deep marine conditions from the accumulation of minute calcite shells shed from micro-organisms called coccolithophores. Flint is very common as bands parallel to the bedding or as embedded in chalk. It is probably derived from sponge spicules or other organisms as water is expelled upwards during compaction. Flint is often deposited around larger fossils such as Echinoidea which may be silicified, Chalk as seen in Cretaceous deposits of Western Europe is unusual among sedimentary limestones in the thickness of the beds. Most cliffs of chalk have very few obvious bedding planes unlike most thick sequences of such as the Carboniferous Limestone or the Jurassic oolitic limestones. This presumably indicates very stable conditions over tens of millions of years, Chalk has greater resistance to weathering and slumping than the clays with which it is usually associated, thus forming tall steep cliffs where chalk ridges meet the sea. Chalk hills, known as chalk downland, usually form where bands of chalk reach the surface at an angle, because chalk is well jointed it can hold a large volume of ground water, providing a natural reservoir that releases water slowly through dry seasons. Chalk is mined from chalk deposits both above ground and underground, Chalk mining boomed during the Industrial Revolution, due to the need for chalk products such as quicklime and bricks. Abandoned chalk mines remain a popular tourist attraction due to their massive expanse, the Chalk Group is a European stratigraphic unit deposited during the late Cretaceous Period. It forms the famous White Cliffs of Dover in Kent, England, the Champagne region of France is mostly underlain by chalk deposits, which contain artificial caves used for wine storage. Some of the highest chalk cliffs in the occur at Jasmund National Park in Germany. Ninety million years ago what is now the chalk downland of Northern Europe was ooze accumulating at the bottom of a great sea. Chalk was one of the earliest rocks made up of particles to be studied under the electron microscope. Their shells were made of calcite extracted from the rich sea-water, as they died, a substantial layer gradually built up over millions of years and, through the weight of overlying sediments, eventually became consolidated into rock. Later earth movements related to the formation of the Alps raised these former sea-floor deposits above sea level, the chemical composition of chalk is calcium carbonate, with minor amounts of silt and clay. It is formed in the sea by plankton, which fall to the sea floor and are then consolidated and compressed during diagenesis into chalk rock
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Diagenesis
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It does not include changes from weathering. It is any chemical, physical, or biological change undergone by a sediment after its initial deposition and this process excludes surface alteration and metamorphism. These changes happen at low temperatures and pressures and result in changes to the rocks original mineralogy. There is no boundary between diagenesis and metamorphism, but the latter occurs at higher temperatures and pressures than the former. Hydrothermal solutions, meteoric groundwater, porosity, permeability, solubility, after deposition, sediments are compacted as they are buried beneath successive layers of sediment and cemented by minerals that precipitate from solution. Grains of sediment, rock fragments and fossils can be replaced by other minerals during diagenesis, porosity usually decreases during diagenesis, except in rare cases such as dissolution of minerals and dolomitization. The study of diagenesis in rocks is used to understand the history they have undergone. From a commercial standpoint, such aid in assessing the likelihood of finding various economically viable mineral. The process of diagenesis is also important in the decomposition of bone tissue, the term diagenesis, literally meaning across generation, is extensively used in geology. However, this term has filtered into the field of anthropology, archaeology and paleontology to describe the changes, the composite nature of bone, comprising one-third organic and two thirds mineral renders its diagenesis more complex. Three general pathways of the diagenesis of bone have been identified, chemical deterioration of the mineral phase. They are as follows, The dissolution of collagen depends on time, temperature, at high temperatures, the rate of collagen loss will be accelerated and extreme pH can cause collagen swelling and accelerated hydrolysis. The hydrolytic activity plays a key role in the phase transformations that exposes the collagen to accelerated chemical-. Once an individual has been interred, microbial attack, the most common mechanism of bone deterioration, during this phase, most bone collagen is lost and porosity is increased. The dissolution of the mineral phase caused by low pH permits access to the collagen by extracellular microbial enzymes thus microbial attack, when animal or plant matter is buried during sedimentation, the constituent organic molecules break down due to the increase in temperature and pressure. This transformation occurs in the first few hundred meters of burial and it is generally accepted that hydrocarbons are formed by the thermal alteration of these kerogens. In this way, given certain conditions kerogens will break down to form hydrocarbons through a process known as cracking. These models have been studied and applied in real geological applications
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Biotite
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Biotite is a common phyllosilicate mineral within the mica group, with the approximate chemical formula K 3AlSi 3O102. Hausmann in 1847 in honor of the French physicist Jean-Baptiste Biot, iron, magnesium, aluminium, silicon, oxygen, and hydrogen form sheets that are weakly bound together by potassium ions. It is sometimes called iron mica because it is more iron-rich than phlogopite and it is also sometimes called black mica as opposed to white mica – both form in some rocks, and in some instances side-by-side. Like other mica minerals, biotite has a perfect basal cleavage, and consists of flexible sheets, or lamellae. It has a crystal system, with tabular to prismatic crystals with an obvious pinacoid termination. It has four faces and two pinacoid faces to form a pseudohexagonal crystal. Although not easily seen because of the cleavage and sheets, fracture is uneven and it appears greenish to brown or black, and even yellow when weathered. It can be transparent to opaque, has a vitreous to pearly luster, when biotite is found in large chunks, they are called “books” because it resembles a book with pages of many sheets. The color of biotite is usually black and the mineral has a hardness of 2. 5-3 on the Mohs scale of mineral hardness, biotite dissolves in both acid and alkaline aqueous solutions, with the highest dissolution rates at low pH. However, biotite dissolution is highly anisotropic with crystal edge surfaces reacting 45 to 132 times faster than basal surfaces, under cross-polarized light biotite can generally be identified by the gnarled birds eye extinction. Biotite is found in a variety of igneous and metamorphic rocks. For instance, biotite occurs in the lava of Mount Vesuvius, biotite in granite tends to be poorer in magnesium than the biotite found in its volcanic equivalent, rhyolite. Biotite is an essential phenocryst in some varieties of lamprophyre, biotite is occasionally found in large cleavable crystals, especially in pegmatite veins, as in New England, Virginia and North Carolina. Other notable occurrences include Bancroft and Sudbury, Ontario and it is an essential constituent of many metamorphic schists, and it forms in suitable compositions over a wide range of pressure and temperature. It has been estimated that biotite comprises up to 7% of the continental crust. The largest documented single crystals of biotite were approximately 7 m2 sheets found in Iveland, biotite is used extensively to constrain ages of rocks, by either potassium-argon dating or argon-argon dating. Because argon escapes readily from the crystal structure at high temperatures. Biotite is also useful in assessing temperature histories of metamorphic rocks, because the partitioning of iron and magnesium between biotite and garnet is sensitive to temperature
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Mediterranean Sea
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The sea is sometimes considered a part of the Atlantic Ocean, although it is usually identified as a separate body of water. The name Mediterranean is derived from the Latin mediterraneus, meaning inland or in the middle of land and it covers an approximate area of 2.5 million km2, but its connection to the Atlantic is only 14 km wide. The Strait of Gibraltar is a strait that connects the Atlantic Ocean to the Mediterranean Sea and separates Gibraltar. In oceanography, it is called the Eurafrican Mediterranean Sea or the European Mediterranean Sea to distinguish it from mediterranean seas elsewhere. The Mediterranean Sea has a depth of 1,500 m. The sea is bordered on the north by Europe, the east by Asia and it is located between latitudes 30° and 46° N and longitudes 6° W and 36° E. Its west-east length, from the Strait of Gibraltar to the Gulf of Iskenderun, the seas average north-south length, from Croatia’s southern shore to Libya, is approximately 800 km. The Mediterranean Sea, including the Sea of Marmara, has an area of approximately 2,510,000 square km. The sea was an important route for merchants and travelers of ancient times that allowed for trade, the history of the Mediterranean region is crucial to understanding the origins and development of many modern societies. In addition, the Gaza Strip and the British Overseas Territories of Gibraltar and Akrotiri, the term Mediterranean derives from the Latin word mediterraneus, meaning amid the earth or between land, as it is between the continents of Africa, Asia and Europe. The Ancient Greek name Mesogeios, is similarly from μέσο, between + γη, land, earth) and it can be compared with the Ancient Greek name Mesopotamia, meaning between rivers. The Mediterranean Sea has historically had several names, for example, the Carthaginians called it the Syrian Sea and latter Romans commonly called it Mare Nostrum, and occasionally Mare Internum. Another name was the Sea of the Philistines, from the people inhabiting a large portion of its shores near the Israelites, the sea is also called the Great Sea in the General Prologue by Geoffrey Chaucer. In Ottoman Turkish, it has also been called Bahr-i Sefid, in Modern Hebrew, it has been called HaYam HaTikhon, the Middle Sea, reflecting the Seas name in ancient Greek, Latin, and modern languages in both Europe and the Middle East. Similarly, in Modern Arabic, it is known as al-Baḥr al-Mutawassiṭ, in Turkish, it is known as Akdeniz, the White Sea since among Turks the white colour represents the west. Several ancient civilisations were located around the Mediterranean shores, and were influenced by their proximity to the sea. It provided routes for trade, colonisation, and war, as well as food for numerous communities throughout the ages, due to the shared climate, geology, and access to the sea, cultures centered on the Mediterranean tended to have some extent of intertwined culture and history. Two of the most notable Mediterranean civilisations in classical antiquity were the Greek city states, later, when Augustus founded the Roman Empire, the Romans referred to the Mediterranean as Mare Nostrum
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Black Sea
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The Black Sea is a body of water between Eastern Europe and Western Asia, bounded by Bulgaria, Georgia, Romania, Russia, Turkey, and Ukraine. It is supplied by a number of rivers, such as the Danube, Dnieper, Rioni, Southern Bug. The Black Sea has an area of 436,400 km2, a depth of 2,212 m. It is constrained by the Pontic Mountains to the south and by the Caucasus Mountains to the east, the longest east-west extent is about 1,175 km. The Black Sea has a water balance, that is, a net outflow of water 300 km3 per year through the Bosphorus. Mediterranean water flows into the Black Sea as part of a two-way hydrological exchange, the Black Sea drains into the Mediterranean Sea and then the Atlantic Ocean, via the Aegean Sea and various straits. The Bosphorus Strait connects it to the Sea of Marmara, and these waters separate Eastern Europe and Western Asia. The Black Sea is also connected to the Sea of Azov by the Strait of Kerch, the water level has varied significantly. Due to these variations in the level in the basin. At certain critical water levels it is possible for connections with surrounding water bodies to become established and it is through the most active of these connective routes, the Turkish Straits, that the Black Sea joins the world ocean. When this hydrological link is not present, the Black Sea is a basin, operating independently of the global ocean system. Currently the Black Sea water level is high, thus water is being exchanged with the Mediterranean. The Turkish Straits connect the Black Sea with the Aegean Sea, and comprise the Bosphorus, the Sea of Marmara, the International Hydrographic Organization defines the limits of the Black Sea as follows, On the Southwest. The Northeastern limit of the Sea of Marmara, a line joining Cape Takil and Cape Panaghia. Strabos Geographica reports that in antiquity, the Black Sea was often just called the Sea, for the most part, Graeco-Roman tradition refers to the Black Sea as the Hospitable sea, Εὔξεινος Πόντος Eúxeinos Póntos. This is a euphemism replacing an earlier Inhospitable Sea, Πόντος Ἄξεινος Póntos Áxeinos, strabo thinks that the Black Sea was called inhospitable before Greek colonization because it was difficult to navigate, and because its shores were inhabited by savage tribes. The name was changed to hospitable after the Milesians had colonized the southern shoreline and it is also possible that the epithet Áxeinos arose by popular etymology from a Scythian word axšaina- unlit, dark, the designation Black Sea may thus date from antiquity. A map of Asia dating to 1570, entitled Asiae Nova Descriptio, from Abraham Orteliuss Theatrum Orbis Terrarum, english-language writers of the 18th century often used the name Euxine Sea to refer to the Black Sea
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Pigment
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A pigment is a material that changes the color of reflected or transmitted light as the result of wavelength-selective absorption. This physical process differs from fluorescence, phosphorescence, and other forms of luminescence, many materials selectively absorb certain wavelengths of light. Materials that humans have chosen and developed for use as pigments usually have properties that make them ideal for coloring other materials. A pigment must have a high tinting strength relative to the materials it colors and it must be stable in solid form at ambient temperatures. For industrial applications, as well as in the arts, permanence, pigments that are not permanent are called fugitive. Fugitive pigments fade over time, or with exposure to light, pigments are used for coloring paint, ink, plastic, fabric, cosmetics, food, and other materials. Most pigments used in manufacturing and the arts are dry colorants. This powder is added to a binder, a neutral or colorless material that suspends the pigment. A distinction is made between a pigment, which is insoluble in its vehicle, and a dye, which either is itself a liquid or is soluble in its vehicle. A colorant can act as either a pigment or a dye depending on the vehicle involved, in some cases, a pigment can be manufactured from a dye by precipitating a soluble dye with a metallic salt. The resulting pigment is called a lake pigment, the term biological pigment is used for all colored substances independent of their solubility. In 2006, around 7.4 million tons of inorganic, organic, asia has the highest rate on a quantity basis followed by Europe and North America. By 2020, revenues will have risen to approx, the global demand on pigments was roughly US$20.5 billion in 2009, around 1. 5-2% up from the previous year. It is predicted to increase in a growth rate in the coming years. The worldwide sales are said to increase up to US$24.5 billion in 2015, pigments appear the colors they are because they selectively reflect and absorb certain wavelengths of visible light. White light is an equal mixture of the entire spectrum of visible light with a wavelength in a range from about 375 or 400 nanometers to about 760 or 780 nm. When this light encounters a pigment, parts of the spectrum are absorbed by the molecules or ions of the pigment, in organic pigments such as diazo or phthalocyanine compounds the light is absorbed by the conjugated systems of double bonds in the molecule. Some of the inorganic pigments such as vermilion or cadmium yellow absorb light by transferring an electron from the ion to the positive ion
43.
Icon
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An icon is a religious work of art, most commonly a painting, from Eastern Christianity and certain Eastern Catholic churches. The most common subjects include Christ, Mary, saints and/or angels, icons may also be cast in metal, carved in stone, embroidered on cloth, painted on wood, done in mosaic or fresco work, printed on paper or metal, etc. Comparable images from Western Christianity are generally not described as icons, Eastern Orthodox tradition holds that the creation of Christian images dates back to the very early days of Christianity, and there is has been a continuous tradition since then. The icons of later centuries can be linked, often closely, to images from the 5th century onwards, there was enormous destruction of images during the Byzantine Iconoclasm of 726-842, although this did settle for good the question of the appropriateness of images. Since then icons have had a continuity of style and subject. At the same time there has been change and development, Christian tradition dating from the 8th century identifies Luke the Evangelist as the first icon painter. Aside from the legend that Pilate had made an image of Christ and he relates that King Abgar of Edessa sent a letter to Jesus at Jerusalem, asking Jesus to come and heal him of an illness. In this version there is no image, further legends relate that the cloth remained in Edessa until the 10th century, when it was taken to Constantinople. It went missing in 1204 when Crusaders sacked Constantinople, but by then numerous copies had firmly established its iconic type. They crown these images, and set them up along with the images of the philosophers of the world that is to say, with the images of Pythagoras, and Plato, and Aristotle, and the rest. They have also other modes of honouring these images, after the manner of the Gentiles. And he called him and said, Lycomedes, what do you mean by this matter of the portrait, can it be one of thy gods that is painted here. For I see that you are living in heathen fashion. Later in the passage John says, But this that you have now done is childish and imperfect, at least some of the hierarchy of the Christian churches still strictly opposed icons in the early 4th century. At the Spanish non-ecumenical Synod of Elvira bishops concluded, Pictures are not to be placed in churches, so that they do not become objects of worship and adoration. to our religion. After the emperor Constantine I extended official toleration of Christianity within the Roman Empire in 313 and this period of Christianization probably saw the use of Christian images became very widespread among the faithful, though with great differences from pagan habits. Robin Lane Fox states By the early century, we know of the ownership of private icons of saints. 480-500, we can be sure that the inside of a saints shrine would be adorned with images and votive portraits, when Constantine himself apparently converted to Christianity, the majority of his subjects remained pagans
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Roman Gaul
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Roman Gaul refers to Gaul under provincial rule in the Roman Empire from the 1st century BC to the 5th century AD. The Roman Republic began its takeover of Celtic Gaul in 121 BC, julius Caesar significantly advanced the task by defeating the Celtic tribes in the Gallic Wars of 58-51 BC. In 22 BC, imperial administration of Gaul was reorganized, establishing the provinces of Gallia Aquitania, Gallia Belgica, parts of eastern Gaul were incorporated into the provinces Raetia and Germania Superior. During Late Antiquity, Gaulish and Roman culture amalgamated into a hybrid Gallo-Roman culture, the Gaulish language was marginalized and eventually extinct, being replaced by regional forms of Late Latin which in the medieval period developed into the group of Gallo-Romance languages. Roman control over the provinces deteriorated in the 4th and 5th centuries, the last vestiges of any Roman control over parts of Gaul were effaced with the defeat of Syagrius at the Battle of Soissons. Gaul had three divisions, one of which was divided into multiple Roman provinces, Gallia Cisalpina or Gaul this side of the Alps. Gallia Narbonensis, formerly Gallia Transalpina or Gaul across the Alps was originally conquered and annexed in 121 BC in an attempt to solidify communications between Rome and the Iberian peninsula. It comprised the region of Provence-Alpes-Côte dAzur, most of Languedoc-Roussillon. Gallia Comata, or long haired Gaul, encompassed the remainder of present-day France, Belgium, and westernmost Germany, gauls continued writing some inscriptions in the Gaulish language, but switched from the Greek alphabet to the Latin alphabet during the Roman period. The Roman influence was most apparent in the areas of religion and administration. The Druidic religion was suppressed by Emperor Claudius I, and in later centuries Christianity was introduced, the prohibition of Druids and the syncretic nature of the Roman religion led to disappearance of the Celtic religion. It remains to this day poorly understood, current knowledge of the Celtic religion is based on archeology and via literary sources from several isolated areas such as Ireland, the Romans easily imposed their administrative, economic, artistic and literary culture. They wore the Roman tunic instead of their traditional clothing, the Romano-Gauls generally lived in the vici, small villages similar to those in Italy, or in villae, for the richest. Surviving Celtic influences also infiltrated back into the Roman Imperial culture in the 3rd century, for example, the Gaulish tunic—which gave Emperor Caracalla his surname—had not been replaced by Roman fashion. Similarly, certain Gaulish artisan techniques, such as the barrel, the Celtic heritage also continued in the spoken language. Gaulish spelling and pronunciation of Latin are apparent in several 5th century poets, the last pockets of Gaulish speakers appear to have lingered until the 6th or 7th century. Germanic placenames were first attested in border areas settled by Germanic colonizers, from the 4th to 5th centuries, the Franks settled in northern France and Belgium, the Alemanni in Alsace and Switzerland, and the Burgundians in Savoie. The Roman administration finally collapsed as remaining Roman troops withdrew southeast to protect Italy, between 455 and 476 the Visigoths, the Burgundians, and the Franks assumed control in Gaul
