1.
Hexagonal crystal family
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In crystallography, the hexagonal crystal family is one of the 6 crystal families. In the hexagonal family, the crystal is described by a right rhombic prism unit cell with two equal axes, an included angle of 120° and a height perpendicular to the two base axes. There are 52 space groups associated with it, which are exactly those whose Bravais lattice is either hexagonal or rhombohedral, the hexagonal crystal family consists of two lattice systems, hexagonal and rhombohedral. Each lattice system consists of one Bravais lattice, hence, there are 3 lattice points per unit cell in total and the lattice is non-primitive. The Bravais lattices in the hexagonal crystal family can also be described by rhombohedral axes, the unit cell is a rhombohedron. This is a cell with parameters a = b = c, α = β = γ ≠ 90°. In practice, the description is more commonly used because it is easier to deal with a coordinate system with two 90° angles. However, the axes are often shown in textbooks because this cell reveals 3m symmetry of crystal lattice. However, such a description is rarely used, the hexagonal crystal family consists of two crystal systems, trigonal and hexagonal. A crystal system is a set of point groups in which the point groups themselves, the trigonal crystal system consists of the 5 point groups that have a single three-fold rotation axis. The crystal structures of alpha-quartz in the example are described by two of those 18 space groups associated with the hexagonal lattice system. The hexagonal crystal system consists of the seven point groups such that all their groups have the hexagonal lattice as underlying lattice. Graphite is an example of a crystal that crystallizes in the crystal system. Note that the atom in the center of the HCP unit cell in the hexagonal lattice system does not appear in the unit cell of the hexagonal lattice. It is part of the two atom motif associated with each point in the underlying lattice. The trigonal crystal system is the crystal system whose point groups have more than one lattice system associated with their space groups. The 5 point groups in this system are listed below, with their international number and notation, their space groups in name. The point groups in this system are listed below, followed by their representations in Hermann–Mauguin or international notation and Schoenflies notation
2.
Oxide minerals
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The oxide mineral class includes those minerals in which the oxide anion is bonded to one or more metal ions. The hydroxide bearing minerals are typically included in the oxide class, the minerals with complex anion groups such as the silicates, sulfates, carbonates and phosphates are classed separately. This list uses it to modify the Classification of Nickel–Strunz,00 Clinobirnessite*,00 Kleberite*,00 Chubutite*,00 Struverite
3.
Chemical formula
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These are limited to a single typographic line of symbols, which may include subscripts and superscripts. A chemical formula is not a name, and it contains no words. Although a chemical formula may imply certain simple chemical structures, it is not the same as a full chemical structural formula. Chemical formulas can fully specify the structure of only the simplest of molecules and chemical substances, the simplest types of chemical formulas are called empirical formulas, which use letters and numbers indicating the numerical proportions of atoms of each type. Molecular formulas indicate the numbers of each type of atom in a molecule. For example, the formula for glucose is CH2O, while its molecular formula is C6H12O6. This is possible if the relevant bonding is easy to show in one dimension, an example is the condensed molecular/chemical formula for ethanol, which is CH3-CH2-OH or CH3CH2OH. For reasons of structural complexity, there is no condensed chemical formula that specifies glucose, chemical formulas may be used in chemical equations to describe chemical reactions and other chemical transformations, such as the dissolving of ionic compounds into solution. A chemical formula identifies each constituent element by its chemical symbol, in empirical formulas, these proportions begin with a key element and then assign numbers of atoms of the other elements in the compound, as ratios to the key element. For molecular compounds, these numbers can all be expressed as whole numbers. For example, the formula of ethanol may be written C2H6O because the molecules of ethanol all contain two carbon atoms, six hydrogen atoms, and one oxygen atom. Some types of compounds, however, cannot be written with entirely whole-number empirical formulas. An example is boron carbide, whose formula of CBn is a variable non-whole number ratio with n ranging from over 4 to more than 6.5. When the chemical compound of the consists of simple molecules. These types of formulas are known as molecular formulas and condensed formulas. A molecular formula enumerates the number of atoms to reflect those in the molecule, so that the formula for glucose is C6H12O6 rather than the glucose empirical formula. However, except for very simple substances, molecular chemical formulas lack needed structural information, for simple molecules, a condensed formula is a type of chemical formula that may fully imply a correct structural formula. For example, ethanol may be represented by the chemical formula CH3CH2OH
4.
Iron(III) oxide
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Iron oxide or ferric oxide is the inorganic compound with the formula Fe2O3. It is one of the three main oxides of iron, the two being iron oxide, which is rare, and iron oxide, which also occurs naturally as the mineral magnetite. As the mineral known as hematite, Fe2O3 is the source of iron for the steel industry. Fe2O3 is ferromagnetic, dark red, and readily attacked by acids, Iron oxide is often called rust, and to some extent this label is useful, because rust shares several properties and has a similar composition. To a chemist, rust is considered a material, described as hydrated ferric oxide. Fe2O3 can be obtained in various polymorphs, in the main ones, α and γ, iron adopts octahedral coordination geometry. That is, each Fe center is bound to six oxygen ligands, α-Fe2O3 has the rhombohedral, corundum structure and is the most common form. It occurs naturally as the mineral hematite which is mined as the ore of iron. It is antiferromagnetic below ~260 K, and exhibits weak ferromagnetism between 260 K and the Néel temperature,950 K and it is easy to prepare using both thermal decomposition and precipitation in the liquid phase. Its magnetic properties are dependent on many factors, e. g. pressure, particle size and it is metastable and converted from the alpha phase at high temperatures. It occurs naturally as the mineral maghemite and it is ferromagnetic and finds application in recording tapes, although ultrafine particles smaller than 10 nanometers are superparamagnetic. It can be prepared by thermal dehydratation of gamma iron oxide-hydroxide, another method involves the careful oxidation of Fe3O4. The ultrafine particles can be prepared by decomposition of iron oxalate. Several other phases have been identified or claimed, the β-phase is cubic body centered, metastable, and at temperatures above 500 °C converts to alpha phase. It can be prepared by reduction of hematite by carbon, pyrolysis of iron chloride solution, the epsilon phase is rhombic, and shows properties intermediate between alpha and gamma, and may have useful magnetic properties. Preparation of the pure epsilon phase has proven challenging due to contamination with alpha. Material with a proportion of epsilon phase can be prepared by thermal transformation of the gamma phase. This phase is metastable, transforming to the alpha phase at between 500 and 750 °C
5.
Crystal system
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In crystallography, the terms crystal system, crystal family and lattice system each refer to one of several classes of space groups, lattices, point groups or crystals. Informally, two crystals are in the crystal system if they have similar symmetries, though there are many exceptions to this. Space groups and crystals are divided into seven crystal systems according to their point groups, five of the crystal systems are essentially the same as five of the lattice systems, but the hexagonal and trigonal crystal systems differ from the hexagonal and rhombohedral lattice systems. The six crystal families are formed by combining the hexagonal and trigonal crystal systems into one hexagonal family, a lattice system is a class of lattices with the same set of lattice point groups, which are subgroups of the arithmetic crystal classes. The 14 Bravais lattices are grouped into seven lattice systems, triclinic, monoclinic, orthorhombic, tetragonal, rhombohedral, hexagonal, in a crystal system, a set of point groups and their corresponding space groups are assigned to a lattice system. Of the 32 point groups that exist in three dimensions, most are assigned to only one system, in which case both the crystal and lattice systems have the same name. However, five point groups are assigned to two systems, rhombohedral and hexagonal, because both exhibit threefold rotational symmetry. These point groups are assigned to the crystal system. In total there are seven crystal systems, triclinic, monoclinic, orthorhombic, tetragonal, trigonal, hexagonal, a crystal family is determined by lattices and point groups. It is formed by combining crystal systems which have space groups assigned to a lattice system. In three dimensions, the families and systems are identical, except the hexagonal and trigonal crystal systems. In total there are six families, triclinic, monoclinic, orthorhombic, tetragonal, hexagonal. Spaces with less than three dimensions have the number of crystal systems, crystal families and lattice systems. In one-dimensional space, there is one crystal system, in 2D space, there are four crystal systems, oblique, rectangular, square and hexagonal. The relation between three-dimensional crystal families, crystal systems and lattice systems is shown in the table, Note. To avoid confusion of terminology, the term trigonal lattice is not used, if the original structure and inverted structure are identical, then the structure is centrosymmetric. Still, even for non-centrosymmetric case, inverted structure in some cases can be rotated to align with the original structure and this is the case of non-centrosymmetric achiral structure. If the inverted structure cannot be rotated to align with the structure, then the structure is chiral
6.
Crystallographic point group
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For a periodic crystal, the group must also be consistent with maintenance of the three-dimensional translational symmetry that defines crystallinity. The macroscopic properties of a crystal would look exactly the same before, in the classification of crystals, each point group is also known as a crystal class. There are infinitely many three-dimensional point groups, however, the crystallographic restriction of the infinite families of general point groups results in there being only 32 crystallographic point groups. These 32 point groups are one-and-the same as the 32 types of morphological crystalline symmetries derived in 1830 by Johann Friedrich Christian Hessel from a consideration of observed crystal forms, the point groups are denoted by their component symmetries. There are a few standard notations used by crystallographers, mineralogists, for the correspondence of the two systems below, see crystal system. In Schoenflies notation, point groups are denoted by a symbol with a subscript. The symbols used in crystallography mean the following, Cn indicates that the group has a rotation axis. Cnh is Cn with the addition of a plane perpendicular to the axis of rotation. Cnv is Cn with the addition of n mirror planes parallel to the axis of rotation, s2n denotes a group that contains only a 2n-fold rotation-reflection axis. Dn indicates that the group has a rotation axis plus n twofold axes perpendicular to that axis. Dnh has, in addition, a plane perpendicular to the n-fold axis. Dnd has, in addition to the elements of Dn, mirror planes parallel to the n-fold axis, the letter T indicates that the group has the symmetry of a tetrahedron. Td includes improper rotation operations, T excludes improper rotation operations, the letter O indicates that the group has the symmetry of an octahedron, with or without improper operations. Due to the crystallographic restriction theorem, n =1,2,3,4, d4d and D6d are actually forbidden because they contain improper rotations with n=8 and 12 respectively. The 27 point groups in the table plus T, Td, Th, O, an abbreviated form of the Hermann–Mauguin notation commonly used for space groups also serves to describe crystallographic point groups. Group names are Molecular symmetry Point group Space group Point groups in three dimensions Crystal system Point-group symbols in International Tables for Crystallography,12.1, pp. 818-820 Names and symbols of the 32 crystal classes in International Tables for Crystallography. 10.1, p.794 Pictorial overview of the 32 groups Point Groups - Flow Chart Inorganic Chemistry Group Theory Practice Problems
7.
H-M symbol
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In geometry, Hermann–Mauguin notation is used to represent the symmetry elements in point groups, plane groups and space groups. It is named after the German crystallographer Carl Hermann and the French mineralogist Charles-Victor Mauguin and this notation is sometimes called international notation, because it was adopted as standard by the International Tables For Crystallography since their first edition in 1935. Rotation axes are denoted by a number n —1,2,3,4,5,6,7,8, for improper rotations, Hermann–Mauguin symbols show rotoinversion axes, unlike Schoenflies and Shubnikov notations, where the preference is given to rotation-reflection axes. The rotoinversion axes are represented by the number with a macron. The symbol for a plane is m. The direction of the plane is defined as the direction of perpendicular to the face. Hermann–Mauguin symbols show symmetrically non-equivalent axes and planes, the direction of a symmetry element is represented by its position in the Hermann–Mauguin symbol. If a rotation axis n and a mirror plane m have the same direction, if two or more axes have the same direction, the axis with higher symmetry is shown. Higher symmetry means that the axis generates a pattern with more points, for example, rotation axes 3,4,5,6,7,8 generate 3-, 4-, 5-, 6-, 7-, 8-point patterns, respectively. Improper rotation axes 3,4,5,6,7,8 generate 6-, 4-, 10-, 6-, 14-, 8-point patterns, if both, the rotation and rotoinversion axes satisfy the previous rule, the rotation axis should be chosen. For example, 3/m combination is equivalent to 6, since 6 generates 6 points, and 3 generates only 3,6 should be written instead of 3/m. Analogously, in the case when both 3 and 3 axes are present,3 should be written, however we write 4/m, not 4/m, because both 4 and 4 generate four points. Finally, the Hermann–Mauguin symbol depends on the type of the group and these groups may contain only two-fold axes, mirror planes, and inversion center. These are the point groups 1 and 1,2, m, and 2/m, and 222, 2/m2/m2/m. If the symbol contains three positions, then they denote symmetry elements in the x, y, z direction, First position — primary direction — z direction, assigned to the higher-order axis. Second position — symmetrically equivalent secondary directions, which are perpendicular to the z-axis and these can be 2, m, or 2/m. Third position — symmetrically equivalent tertiary directions, passing between secondary directions and these can be 2, m, or 2/m. These are the crystallographic groups 3,32, 3m,3, and 32/m,4,422, 4mm,4, 42m, 4/m, and 4/m2/m2/m, and 6,622, 6mm,6, 6m2, 6/m, and 6/m2/m2/m
8.
Space group
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In mathematics, physics and chemistry, a space group is the symmetry group of a configuration in space, usually in three dimensions. In three dimensions, there are 219 distinct types, or 230 if chiral copies are considered distinct, Space groups are also studied in dimensions other than 3 where they are sometimes called Bieberbach groups, and are discrete cocompact groups of isometries of an oriented Euclidean space. In crystallography, space groups are called the crystallographic or Fedorov groups. A definitive source regarding 3-dimensional space groups is the International Tables for Crystallography, in 1879 Leonhard Sohncke listed the 65 space groups whose elements preserve the orientation. More accurately, he listed 66 groups, but Fedorov and Schönflies both noticed that two of them were really the same, the space groups in 3 dimensions were first enumerated by Fedorov, and shortly afterwards were independently enumerated by Schönflies. The correct list of 230 space groups was found by 1892 during correspondence between Fedorov and Schönflies, burckhardt describes the history of the discovery of the space groups in detail. The space groups in three dimensions are made from combinations of the 32 crystallographic point groups with the 14 Bravais lattices, the combination of all these symmetry operations results in a total of 230 different space groups describing all possible crystal symmetries. The elements of the space group fixing a point of space are rotations, reflections, the identity element, the translations form a normal abelian subgroup of rank 3, called the Bravais lattice. There are 14 possible types of Bravais lattice, the quotient of the space group by the Bravais lattice is a finite group which is one of the 32 possible point groups. Translation is defined as the moves from one point to another point. A glide plane is a reflection in a plane, followed by a parallel with that plane. This is noted by a, b or c, depending on which axis the glide is along. There is also the n glide, which is a glide along the half of a diagonal of a face, and the d glide, the latter is called the diamond glide plane as it features in the diamond structure. In 17 space groups, due to the centering of the cell, the glides occur in two directions simultaneously, i. e. the same glide plane can be called b or c, a or b. For example, group Abm2 could be also called Acm2, group Ccca could be called Cccb, in 1992, it was suggested to use symbol e for such planes. The symbols for five groups have been modified, A screw axis is a rotation about an axis. These are noted by a number, n, to describe the degree of rotation, the degree of translation is then added as a subscript showing how far along the axis the translation is, as a portion of the parallel lattice vector. So,21 is a rotation followed by a translation of 1/2 of the lattice vector
9.
Crystal structure
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In crystallography, crystal structure is a description of the ordered arrangement of atoms, ions or molecules in a crystalline material. Ordered structures occur from the nature of the constituent particles to form symmetric patterns that repeat along the principal directions of three-dimensional space in matter. The smallest group of particles in the material that constitutes the pattern is the unit cell of the structure. The unit cell completely defines the symmetry and structure of the crystal lattice. The repeating patterns are said to be located at the points of the Bravais lattice, the lengths of the principal axes, or edges, of the unit cell and the angles between them are the lattice constants, also called lattice parameters. The symmetry properties of the crystal are described by the concept of space groups, all possible symmetric arrangements of particles in three-dimensional space may be described by the 230 space groups. The crystal structure and symmetry play a role in determining many physical properties, such as cleavage, electronic band structure. The crystal structure of a material can be described in terms of its unit cell, the unit cell is a box containing one or more atoms arranged in three dimensions. The unit cells stacked in three-dimensional space describe the arrangement of atoms of the crystal. Commonly, atomic positions are represented in terms of fractional coordinates, the atom positions within the unit cell can be calculated through application of symmetry operations to the asymmetric unit. The asymmetric unit refers to the smallest possible occupation of space within the unit cell and this does not, however imply that the entirety of the asymmetric unit must lie within the boundaries of the unit cell. Symmetric transformations of atom positions are calculated from the group of the crystal structure. Vectors and planes in a lattice are described by the three-value Miller index notation. It uses the indices ℓ, m, and n as directional parameters, which are separated by 90°, by definition, the syntax denotes a plane that intercepts the three points a1/ℓ, a2/m, and a3/n, or some multiple thereof. That is, the Miller indices are proportional to the inverses of the intercepts of the plane with the unit cell, if one or more of the indices is zero, it means that the planes do not intersect that axis. A plane containing a coordinate axis is translated so that it no longer contains that axis before its Miller indices are determined, the Miller indices for a plane are integers with no common factors. Negative indices are indicated with horizontal bars, as in, in an orthogonal coordinate system for a cubic cell, the Miller indices of a plane are the Cartesian components of a vector normal to the plane. Likewise, the planes are geometric planes linking nodes
10.
Crystal habit
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In mineralogy, crystal habit is the characteristic external shape of an individual crystal or crystal group. A single crystals habit is a description of its shape and its crystallographic forms. Recognizing the habit may help in identifying a mineral, when the faces are well-developed due to uncrowded growth a crystal is called euhedral, one with partially developed faces is subhedral, and one with undeveloped crystal faces is called anhedral. The long axis of a quartz crystal typically has a six-sided prismatic habit with parallel opposite faces. Aggregates can be formed of individual crystals with euhedral to anhedral grains, the arrangement of crystals within the aggregate can be characteristic of certain minerals. For example, minerals used for asbestos insulation often grow in a fibrous habit, the terms used by mineralogists to report crystal habits describe the typical appearance of an ideal mineral. Recognizing the habit can aid in identification as some habits are characteristic, most minerals, however, do not display ideal habits due to conditions during crystallization. Minerals belonging to the crystal system do not necessarily exhibit the same habit. Some habits of a mineral are unique to its variety and locality, For example, while most sapphires form elongate barrel-shaped crystals, ordinarily, the latter habit is seen only in ruby. Sapphire and ruby are both varieties of the mineral, corundum. Some minerals may replace other existing minerals while preserving the originals habit, a classic example is tigers eye quartz, crocidolite asbestos replaced by silica. While quartz typically forms prismatic crystals, in tigers eye the original fibrous habit of crocidolite is preserved, the names of crystal habits are derived from, Predominant crystal faces. Abnormal grain growth Grain growth Crystallization
11.
Crystal twinning
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Crystal twinning occurs when two separate crystals share some of the same crystal lattice points in a symmetrical manner. The result is an intergrowth of two separate crystals in a variety of specific configurations, a twin boundary or composition surface separates the two crystals. Crystallographers classify twinned crystals by a number of twin laws and these twin laws are specific to the crystal system. The type of twinning can be a tool in mineral identification. Twinning can often be a problem in X-ray crystallography, as a crystal does not produce a simple diffraction pattern. Simple twinned crystals may be contact twins or penetration twins, contact twins share a single composition surface often appearing as mirror images across the boundary. Plagioclase, quartz, gypsum, and spinel often exhibit contact twinning, merohedral twinning occurs when the lattices of the contact twins superimpose in three dimensions, such as by relative rotation of one twin from the other. In penetration twins the individual crystals have the appearance of passing through each other in a symmetrical manner, orthoclase, staurolite, pyrite, and fluorite often show penetration twinning. If several twin crystal parts are aligned by the same twin law they are referred to as multiple or repeated twins, if these multiple twins are aligned in parallel they are called polysynthetic twins. When the multiple twins are not parallel they are cyclic twins, albite, calcite, and pyrite often show polysynthetic twinning. Closely spaced polysynthetic twinning is often observed as striations or fine lines on the crystal face. Rutile, aragonite, cerussite, and chrysoberyl often exhibit cyclic twinning, 2-normal twin, -when the twin plane and compositional plane lies noramally. 3-complex twin, -combination of parallel twinning and normal twinning on one compositional plane, there are three modes of formation of twinned crystals. Growth twins are the result of an interruption or change in the lattice during formation or growth due to a possible deformation from a larger substituting ion, deformation or gliding twins are the result of stress on the crystal after the crystal has formed. If a FCC metal like aluminum experiences extreme stresses, it will experience twinning as seen in the case of explosions, deformation twinning is a common result of regional metamorphism. Crystals that grow adjacent to each other may be aligned to resemble twinning and this parallel growth simply reduces system energy and is not twinning. Twin boundaries occur when two crystals of the same type intergrow, so only a slight misorientation exists between them. It is a highly symmetrical interface, often with one crystal the mirror image of the other, also and this is also a much lower-energy interface than the grain boundaries that form when crystals of arbitrary orientation grow together
12.
Cleavage (crystal)
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Cleavage, in mineralogy, is the tendency of crystalline materials to split along definite crystallographic structural planes. Cleavage forms parallel to planes, Basal or pinacoidal cleavage occurs when there is only one cleavage plane. Mica also has basal cleavage, this is why mica can be peeled into thin sheets, cubic cleavage occurs on when there are three cleavage planes intersecting at 90 degrees. Halite has cubic cleavage, and therefore, when halite crystals are broken, octahedral cleavage occurs when there are four cleavage planes in a crystal. Octahedral cleavage is common for semiconductors, rhombohedral cleavage occurs when there are three cleavage planes intersecting at angles that are not 90 degrees. Prismatic cleavage occurs when there are two planes in a crystal. Dodecahedral cleavage occurs when there are six cleavage planes in a crystal, crystal parting occurs when minerals break along planes of structural weakness due to external stress or along twin composition planes. Parting breaks are very similar in appearance to cleavage, but only due to stress. Examples include magnetite which shows octahedral parting, the parting of corundum. Cleavage is a property traditionally used in mineral identification, both in hand specimen and microscopic examination of rock and mineral studies. As an example, the angles between the cleavage planes for the pyroxenes and the amphiboles are diagnostic. Crystal cleavage is of importance in the electronics industry and in the cutting of gemstones. Precious stones are generally cleaved by impact, as in diamond cutting, synthetic single crystals of semiconductor materials are generally sold as thin wafers which are much easier to cleave. Elemental semiconductors are diamond cubic, a group for which octahedral cleavage is observed. This means that some orientations of wafer allow near-perfect rectangles to be cleaved, most other commercial semiconductors can be made in the related zinc blende structure, with similar cleavage planes. Cleavage Mineral galleries, Mineral properties – Cleavage
13.
Fracture (mineralogy)
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In the field of mineralogy, fracture is the texture and shape of a rocks surface formed when a mineral is fractured. Minerals often have a highly distinctive fracture, making it a feature used in their identification. Fracture differs from cleavage in that the latter involves clean splitting along the planes of the minerals crystal structure. All minerals exhibit fracture, but when very strong cleavage is present, conchoidal fracture breakage that resembles the concentric ripples of a mussel shell. It often occurs in amorphous or fine-grained minerals such as flint, opal or obsidian, subconchoidal fracture is similar to conchoidal fracture, but with less significant curvature. Earthy fracture is reminiscent of freshly broken soil and it is frequently seen in relatively soft, loosely bound minerals, such as limonite, kaolinite and aluminite. Hackly fracture is jagged, sharp and not even and it occurs when metals are torn, and so is often encountered in native metals such as copper and silver. Splintery fracture comprises sharp elongated points and it is particularly seen in fibrous minerals such as chrysotile, but may also occur in non-fibrous minerals such as kyanite. Uneven fracture is a surface or one with random irregularities. It occurs in a range of minerals including arsenopyrite, pyrite and magnetite. Rudolf Duda and Lubos Rejl, Minerals of the World http, //www. galleries. com/minerals/property/fracture. htm
14.
Mohs scale of mineral hardness
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The Mohs scale of mineral hardness is a qualitative ordinal scale characterizing scratch resistance of various minerals through the ability of harder material to scratch softer material. Created in 1812 by German geologist and mineralogist Friedrich Mohs, it is one of several definitions of hardness in materials science, while greatly facilitating the identification of minerals in the field, the Mohs scale does not show how well hard materials perform in an industrial setting. Despite its lack of precision, the Mohs scale is highly relevant for field geologists, the Mohs scale hardness of minerals can be commonly found in reference sheets. Reference materials may be expected to have a uniform Mohs hardness, the Mohs scale of mineral hardness is based on the ability of one natural sample of mineral to scratch another mineral visibly. The samples of matter used by Mohs are all different minerals, Minerals are pure substances found in nature. Rocks are made up of one or more minerals, as the hardest known naturally occurring substance when the scale was designed, diamonds are at the top of the scale. The hardness of a material is measured against the scale by finding the hardest material that the material can scratch. For example, if material is scratched by apatite but not by fluorite. Scratching a material for the purposes of the Mohs scale means creating non-elastic dislocations visible to the naked eye, frequently, materials that are lower on the Mohs scale can create microscopic, non-elastic dislocations on materials that have a higher Mohs number. The Mohs scale is an ordinal scale. For example, corundum is twice as hard as topaz, the table below shows the comparison with the absolute hardness measured by a sclerometer, with pictorial examples. On the Mohs scale, a streak plate has a hardness of 7.0, using these ordinary materials of known hardness can be a simple way to approximate the position of a mineral on the scale. The table below incorporates additional substances that may fall between levels, Comparison between Hardness and Hardness, Mohs hardness of elements is taken from G. V, samsonov in Handbook of the physicochemical properties of the elements, IFI-Plenum, New York, USA,1968. The Hardness of Minerals and Rocks
15.
Lustre (mineralogy)
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Lustre or luster is the way light interacts with the surface of a crystal, rock, or mineral. The word traces its origins back to the latin lux, meaning light, a range of terms are used to describe lustre, such as earthy, metallic, greasy, and silky. Similarly, the term refers to a glassy lustre. A list of terms is given below. Lustre varies over a continuum, and so there are no rigid boundaries between the different types of lustre. The terms are frequently combined to describe types of lustre. Some minerals exhibit unusual optical phenomena, such as asterism or chatoyancy, a list of such phenomena is given below. Adamantine minerals possess a superlative lustre, which is most notably seen in diamond, such minerals are transparent or translucent, and have a high refractive index. Minerals with an adamantine lustre are uncommon, with examples being cerussite. Minerals with a degree of lustre are referred to as subadamantine, with some examples being garnet. Dull minerals exhibit little to no lustre, due to coarse granulations which scatter light in all directions, a distinction is sometimes drawn between dull minerals and earthy minerals, with the latter being coarser, and having even less lustre. Greasy minerals resemble fat or grease, a greasy lustre often occurs in minerals containing a great abundance of microscopic inclusions, with examples including opal and cordierite. Many minerals with a greasy lustre also feel greasy to the touch, metallic minerals have the lustre of polished metal, and with ideal surfaces will work as a reflective surface. Examples include galena, pyrite and magnetite, pearly minerals consist of thin transparent co-planar sheets. Light reflecting from these layers give them a lustre reminiscent of pearls, such minerals possess perfect cleavage, with examples including muscovite and stilbite. Resinous minerals have the appearance of resin, chewing gum or plastic, a principal example is amber, which is a form of fossilized resin. Silky minerals have an arrangement of extremely fine fibres, giving them a lustre reminiscent of silk. Examples include asbestos, ulexite and the satin spar variety of gypsum, a fibrous lustre is similar, but has a coarser texture
16.
Streak (mineralogy)
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The streak of a mineral is the color of the powder produced when it is dragged across an un-weathered surface. If no streak seems to be made, the streak is said to be white or colorless. Streak is particularly important as a diagnostic for opaque and colored materials and it is less useful for silicate minerals, most of which have a white streak or are too hard to powder easily. The apparent color of a mineral can vary widely because of impurities or a disturbed macroscopic crystal structure. Small amounts of an impurity that strongly absorbs a particular wavelength can radically change the wavelengths of light that are reflected by the specimen, and thus change the apparent color. However, when the specimen is dragged to produce a streak, it is broken into randomly oriented microscopic crystals, the surface across which the mineral is dragged is called a streak plate, and is generally made of unglazed porcelain tile. In the absence of a plate, the unglazed underside of a porcelain bowl or vase or the back of a glazed tile will work. Sometimes a streak is more easily or accurately described by comparing it with the streak made by another streak plate. Because the trail left behind results from the mineral being crushed into powder, in case of harder minerals, the color of the powder can be determined by filing or crushing with a hammer a small sample, which is then usually rubbed on a streak plate. Most minerals that are harder have a white streak. Some minerals leave a similar to their natural color, such as cinnabar. Other minerals leave surprising colors, such as fluorite, which always has a streak, although it can appear in purple, blue, yellow. Hematite, which is black in appearance, leaves a red streak which accounts for its name, galena, which can be similar in appearance to hematite, is easily distinguished by its gray streak. Hamilton, W. R. Cambridge Guide to Minerals, Rocks, the Encyclopedia of Gemstones and Minerals. New York, Facts on File. p.251, physical Characteristics of Minerals, at Introduction to Mineralogy by Andrea Bangert What is Streak
17.
Transparency and translucency
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In the field of optics, transparency is the physical property of allowing light to pass through the material without being scattered. On a macroscopic scale, the photons can be said to follow Snells Law, in other words, a translucent medium allows the transport of light while a transparent medium not only allows the transport of light but allows for image formation. The opposite property of translucency is opacity, transparent materials appear clear, with the overall appearance of one color, or any combination leading up to a brilliant spectrum of every color. When light encounters a material, it can interact with it in different ways. These interactions depend on the wavelength of the light and the nature of the material, photons interact with an object by some combination of reflection, absorption and transmission. Some materials, such as glass and clean water, transmit much of the light that falls on them and reflect little of it. Many liquids and aqueous solutions are highly transparent, absence of structural defects and molecular structure of most liquids are mostly responsible for excellent optical transmission. Materials which do not transmit light are called opaque, many such substances have a chemical composition which includes what are referred to as absorption centers. Many substances are selective in their absorption of light frequencies. They absorb certain portions of the spectrum while reflecting others. The frequencies of the spectrum which are not absorbed are either reflected or transmitted for our physical observation and this is what gives rise to color. The attenuation of light of all frequencies and wavelengths is due to the mechanisms of absorption. Transparency can provide almost perfect camouflage for animals able to achieve it and this is easier in dimly-lit or turbid seawater than in good illumination. Many marine animals such as jellyfish are highly transparent, at the atomic or molecular level, physical absorption in the infrared portion of the spectrum depends on the frequencies of atomic or molecular vibrations or chemical bonds, and on selection rules. Nitrogen and oxygen are not greenhouse gases because there is no absorption because there is no molecular dipole moment. With regard to the scattering of light, the most critical factor is the scale of any or all of these structural features relative to the wavelength of the light being scattered. Primary material considerations include, Crystalline structure, whether or not the atoms or molecules exhibit the long-range order evidenced in crystalline solids, glassy structure, scattering centers include fluctuations in density or composition. Microstructure, scattering centers include internal surfaces such as boundaries, crystallographic defects
18.
Specific gravity
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This page is about the measurement using water as a reference. For a general use of gravity, see relative density. See intensive property for the property implied by specific, Apparent specific gravity is the ratio of the weight of a volume of the substance to the weight of an equal volume of the reference substance. The reference substance is always water at its densest for liquids. Nonetheless, the temperature and pressure must be specified for both the sample and the reference, pressure is nearly always 1 atm. Temperatures for both sample and reference vary from industry to industry, in British beer brewing, the practice for specific gravity as specified above is to multiply it by 1000. Being a ratio of densities, specific gravity is a dimensionless quantity, Specific gravity varies with temperature and pressure, reference and sample must be compared at the same temperature and pressure or be corrected to a standard reference temperature and pressure. Substances with a gravity of 1 are neutrally buoyant in water. Those with SG greater than 1 are denser than water and will, disregarding surface tension effects and those with an SG less than 1 are less dense than water and will float on it. In scientific work, the relationship of mass to volume is expressed directly in terms of the density of the substance under study. It is in industry where specific gravity finds wide application, often for historical reasons. True specific gravity can be expressed mathematically as, S G true = ρ sample ρ H2 O where ρ sample is the density of the sample, the density of water varies with temperature and pressure as does the density of the sample. So it is necessary to specify the temperatures and pressures at which the densities or weights were determined and it is nearly always the case that measurements are made at 1 nominal atmosphere. For true specific gravity calculations, air pressure must be considered, temperatures are specified by the notation with T s representing the temperature at which the samples density was determined and T r the temperature at which the reference density is specified. For example, SG would be understood to mean that the density of the sample was determined at 20°C and of the water at 4°C. Taking into account different sample and reference temperatures, we note that, while S G H2 O =1.000000, it is also the case that S G H2 O =0.998203 /0.999840 =0.998363. Here, temperature is being specified using the current ITS-90 scale, on the previous IPTS-68 scale, the densities at 20 °C and 4 °C are 0.9982071 and 0.9999720 respectively, resulting in an SG value for water of 0.9982343. For example, in the industry, the Plato table lists sucrose concentration by weight against true SG
19.
Refractive index
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In optics, the refractive index or index of refraction n of a material is a dimensionless number that describes how light propagates through that medium. It is defined as n = c v, where c is the speed of light in vacuum, for example, the refractive index of water is 1.333, meaning that light travels 1.333 times faster in a vacuum than it does in water. The refractive index determines how light is bent, or refracted. The refractive indices also determine the amount of light that is reflected when reaching the interface, as well as the angle for total internal reflection. This implies that vacuum has a index of 1. The refractive index varies with the wavelength of light and this is called dispersion and causes the splitting of white light into its constituent colors in prisms and rainbows, and chromatic aberration in lenses. Light propagation in absorbing materials can be described using a refractive index. The imaginary part then handles the attenuation, while the real part accounts for refraction, the concept of refractive index is widely used within the full electromagnetic spectrum, from X-rays to radio waves. It can also be used with wave phenomena such as sound, in this case the speed of sound is used instead of that of light and a reference medium other than vacuum must be chosen. Thomas Young was presumably the person who first used, and invented, at the same time he changed this value of refractive power into a single number, instead of the traditional ratio of two numbers. The ratio had the disadvantage of different appearances, newton, who called it the proportion of the sines of incidence and refraction, wrote it as a ratio of two numbers, like 529 to 396. Hauksbee, who called it the ratio of refraction, wrote it as a ratio with a fixed numerator, hutton wrote it as a ratio with a fixed denominator, like 1.3358 to 1. Young did not use a symbol for the index of refraction, in the next years, others started using different symbols, n, m, and µ. For visible light most transparent media have refractive indices between 1 and 2, a few examples are given in the adjacent table. These values are measured at the yellow doublet D-line of sodium, with a wavelength of 589 nanometers, gases at atmospheric pressure have refractive indices close to 1 because of their low density. Almost all solids and liquids have refractive indices above 1.3, aerogel is a very low density solid that can be produced with refractive index in the range from 1.002 to 1.265. Moissanite lies at the end of the range with a refractive index as high as 2.65. Most plastics have refractive indices in the range from 1.3 to 1.7, for infrared light refractive indices can be considerably higher
20.
Birefringence
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Birefringence is the optical property of a material having a refractive index that depends on the polarization and propagation direction of light. These optically anisotropic materials are said to be birefringent, the birefringence is often quantified as the maximum difference between refractive indices exhibited by the material. Crystals with non-cubic crystal structures are often birefringent, as are plastics under mechanical stress and this effect was first described by the Danish scientist Rasmus Bartholin in 1669, who observed it in calcite, a crystal having one of the strongest birefringences. A mathematical description of wave propagation in a birefringent medium is presented below, following is a qualitative explanation of the phenomenon. Thus rotating the material around this axis does not change its optical behavior and this special direction is known as the optic axis of the material. Light whose polarization is perpendicular to the axis is governed by a refractive index no. Light whose polarization is in the direction of the optic axis sees an optical index ne, for any ray direction there is a linear polarization direction perpendicular to the optic axis, and this is called an ordinary ray. The magnitude of the difference is quantified by the birefringence, Δ n = n e − n o, the propagation of the ordinary ray is simply described by no as if there were no birefringence involved. However the extraordinary ray, as its name suggests, propagates unlike any wave in an optical material. Its refraction at a surface can be using the effective refractive index. However it is in fact an inhomogeneous wave whose power flow is not exactly in the direction of the wave vector and this causes an additional shift in that beam, even when launched at normal incidence, as is popularly observed using a crystal of calcite as photographed above. Rotating the calcite crystal will cause one of the two images, that of the ray, to rotate slightly around that of the ordinary ray. When the light propagates either along or orthogonal to the optic axis, in the first case, both polarizations see the same effective refractive index, so there is no extraordinary ray. In the second case the extraordinary ray propagates at a different phase velocity but is not an inhomogeneous wave, for instance, a quarter-wave plate is commonly used to create circular polarization from a linearly polarized source. The case of so-called biaxial crystals is substantially more complex and these are characterized by three refractive indices corresponding to three principal axes of the crystal. For most ray directions, both polarizations would be classified as extraordinary rays but with different effective refractive indices, being extraordinary waves, however, the direction of power flow is not identical to the direction of the wave vector in either case. The two refractive indices can be determined using the index ellipsoids for given directions of the polarization, note that for biaxial crystals the index ellipsoid will not be an ellipsoid of revolution but is described by three unequal principle refractive indices nα, nβ and nγ. Thus there is no axis around which a rotation leaves the optical properties invariant, for this reason, birefringent materials with three distinct refractive indices are called biaxial
21.
Pleochroism
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Pleochroism is an optical phenomenon in which a substance appears to be different colors when observed at different angles, especially with polarized light. Anisotropic crystals will have properties that vary with the direction of light. The polarization of light determines the direction of the electric field and these kinds of crystals have one or two optical axes. If absorption of light varies with the relative to the optical axis in a crystal then pleochroism results. Anisotropic crystals have double refraction of light where light of different polarizations is bent different amounts by the crystal, the components of a divided light beam follow different paths within the mineral and travel at different speeds. When the mineral is observed at some angle, light following some combination of paths and polarizations will be present, at another angle, the light passing through the crystal will be composed of another combination of light paths and polarizations, each with their own color. The light passing through the mineral will therefore have different colors when it is viewed from different angles, tetragonal, trigonal and hexagonal minerals can only show two colors and are called dichroic. Orthorhombic, monoclinic and triclinic crystals can show three and are trichroic, for example, hypersthene, with two optical axes, can have red, yellow or blue appearance when oriented in three different ways in three-dimensional space. Tourmaline is notable for exhibiting strong pleochroism, gems are sometimes cut and set either to display pleochroism or to hide it, depending on the colors and their attractiveness. The pleochroic colours are at their maximum when light is polarized parallel with a crystallographic axis, the axes are designated X, Y and Z. These axes can be determined from the appearance of a crystal in an interference pattern. Where there are two axes, the acute bisection of the axes gives Z for positive minerals and X for negative minerals. Perpendicular to these is the Y axis, the colour is measured with the polarization parallel to each direction. An absorption formula records the amount of parallel to each axis in the form of X < Y < Z with the left most having the least absorption. Minerals that are very similar often have very different pleochroic color schemes. In such cases, a section of the mineral is used and examined under polarized transmitted light with a petrographic microscope. Another device using this property to identify minerals is the dichroscope
22.
American and British English spelling differences
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Many of the differences between American and British English date back to a time when spelling standards had not yet developed. For instance, some spellings seen as American today were once used in Britain. But English-language spelling reform has rarely been adopted otherwise, and thus modern English orthography varies somewhat between countries and is far from phonemic in any country, in the early 18th century, English spelling was inconsistent. These differences became noticeable after the publishing of influential dictionaries, todays British English spellings mostly follow Johnsons A Dictionary of the English Language, while many American English spellings follow Websters An American Dictionary of the English Language. Webster was a proponent of English spelling reform for reasons both philological and nationalistic, in A Companion to the American Revolution, John Algeo notes, it is often assumed that characteristically American spellings were invented by Noah Webster. He was very influential in popularizing certain spellings in America, rather he chose already existing options such as center, color and check for the simplicity, analogy or etymology. William Shakespeares first folios, for example, used spellings like center and color as much as centre, Webster did attempt to introduce some reformed spellings, as did the Simplified Spelling Board in the early 20th century, but most were not adopted. In Britain, the influence of those who preferred the Norman spellings of words proved to be decisive, later spelling adjustments in the United Kingdom had little effect on todays American spellings and vice versa. For the most part, the systems of most Commonwealth countries. Australian spelling has also strayed slightly from British spelling, with some American spellings incorporated as standard, New Zealand spelling is almost identical to British spelling, except in the word fiord. There is also an increasing use of macrons in words that originated in Māori, most words ending in an unstressed -our in British English end in -or in American English. Wherever the vowel is unreduced in pronunciation, e. g. contour, velour, paramour and troubadour the spelling is the same everywhere, most words of this kind came from Latin, where the ending was spelled -or. They were first adopted into English from early Old French, after the Norman conquest of England, the ending became -our to match the Old French spelling. The -our ending was not only used in new English borrowings, however, -or was still sometimes found, and the first three folios of Shakespeares plays used both spellings before they were standardised to -our in the Fourth Folio of 1685. After the Renaissance, new borrowings from Latin were taken up with their original -or ending, Websters 1828 dictionary had only -or and is given much of the credit for the adoption of this form in the United States. Johnson, unlike Webster, was not an advocate of spelling reform and he preferred French over Latin spellings because, as he put it, the French generally supplied us. In Jeffersons original draft it is spelled honour, Honor and honour were equally frequent in Britain until the 17th century, honor still is, in the UK, the usual spelling as a persons name and appears in Honor Oak, a district of London. In derivatives and inflected forms of the words, British usage depends on the nature of the suffix used
23.
Mineral
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A mineral is a naturally occurring chemical compound, usually of crystalline form and abiogenic in origin. A mineral has one specific chemical composition, whereas a rock can be an aggregate of different minerals or mineraloids, the study of minerals is called mineralogy. There are over 5,300 known mineral species, over 5,070 of these have been approved by the International Mineralogical Association, the silicate minerals compose over 90% of the Earths crust. The diversity and abundance of species is controlled by the Earths chemistry. Silicon and oxygen constitute approximately 75% of the Earths crust, which translates directly into the predominance of silicate minerals, minerals are distinguished by various chemical and physical properties. Differences in chemical composition and crystal structure distinguish the various species, changes in the temperature, pressure, or bulk composition of a rock mass cause changes in its minerals. Minerals can be described by their various properties, which are related to their chemical structure. Common distinguishing characteristics include crystal structure and habit, hardness, lustre, diaphaneity, colour, streak, tenacity, cleavage, fracture, parting, more specific tests for describing minerals include magnetism, taste or smell, radioactivity and reaction to acid. Minerals are classified by key chemical constituents, the two dominant systems are the Dana classification and the Strunz classification, the silicate class of minerals is subdivided into six subclasses by the degree of polymerization in the chemical structure. All silicate minerals have a unit of a 4− silica tetrahedron—that is, a silicon cation coordinated by four oxygen anions. These tetrahedra can be polymerized to give the subclasses, orthosilicates, disilicates, cyclosilicates, inosilicates, phyllosilicates, other important mineral groups include the native elements, sulfides, oxides, halides, carbonates, sulfates, and phosphates. The first criterion means that a mineral has to form by a natural process, stability at room temperature, in the simplest sense, is synonymous to the mineral being solid. More specifically, a compound has to be stable or metastable at 25 °C, modern advances have included extensive study of liquid crystals, which also extensively involve mineralogy. Minerals are chemical compounds, and as such they can be described by fixed or a variable formula, many mineral groups and species are composed of a solid solution, pure substances are not usually found because of contamination or chemical substitution. Finally, the requirement of an ordered atomic arrangement is usually synonymous with crystallinity, however, crystals are also periodic, an ordered atomic arrangement gives rise to a variety of macroscopic physical properties, such as crystal form, hardness, and cleavage. There have been recent proposals to amend the definition to consider biogenic or amorphous substances as minerals. The formal definition of an approved by the IMA in 1995, A mineral is an element or chemical compound that is normally crystalline. However, if geological processes were involved in the genesis of the compound, Mineral classification schemes and their definitions are evolving to match recent advances in mineral science
24.
Iron oxide
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Iron oxides are chemical compounds composed of iron and oxygen. All together, there are sixteen known iron oxides and oxyhydroxides, common rust is a form of iron oxide. Iron oxides are used as inexpensive, durable pigments in paints, coatings. Colors commonly available are in the end of the yellow/orange/red/brown/black range. When used as a coloring, it has E number E172. Limonite Iron oxide nanoparticles List of inorganic pigments Information from Nano-Oxides, http, //chemed. chem. purdue. edu/demos/demosheets/12.3. html http, //minerals. usgs. gov/minerals/pubs/commodity/iron_oxide/ CDC - NIOSH Pocket Guide to Chemical Hazards de
25.
Crystal
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A crystal or crystalline solid is a solid material whose constituents are arranged in a highly ordered microscopic structure, forming a crystal lattice that extends in all directions. In addition, macroscopic single crystals are usually identifiable by their geometrical shape, the scientific study of crystals and crystal formation is known as crystallography. The process of crystal formation via mechanisms of crystal growth is called crystallization or solidification, the word crystal derives from the Ancient Greek word κρύσταλλος, meaning both ice and rock crystal, from κρύος, icy cold, frost. Examples of large crystals include snowflakes, diamonds, and table salt, most inorganic solids are not crystals but polycrystals, i. e. many microscopic crystals fused together into a single solid. Examples of polycrystals include most metals, rocks, ceramics, a third category of solids is amorphous solids, where the atoms have no periodic structure whatsoever. Examples of amorphous solids include glass, wax, and many plastics, Crystals are often used in pseudoscientific practices such as crystal therapy, and, along with gemstones, are sometimes associated with spellwork in Wiccan beliefs and related religious movements. The scientific definition of a crystal is based on the arrangement of atoms inside it. A crystal is a solid where the form a periodic arrangement. For example, when liquid water starts freezing, the change begins with small ice crystals that grow until they fuse. Most macroscopic inorganic solids are polycrystalline, including almost all metals, ceramics, ice, rocks, solids that are neither crystalline nor polycrystalline, such as glass, are called amorphous solids, also called glassy, vitreous, or noncrystalline. These have no periodic order, even microscopically, there are distinct differences between crystalline solids and amorphous solids, most notably, the process of forming a glass does not release the latent heat of fusion, but forming a crystal does. A crystal structure is characterized by its cell, a small imaginary box containing one or more atoms in a specific spatial arrangement. The unit cells are stacked in three-dimensional space to form the crystal, the symmetry of a crystal is constrained by the requirement that the unit cells stack perfectly with no gaps. There are 219 possible crystal symmetries, called space groups. These are grouped into 7 crystal systems, such as cubic crystal system or hexagonal crystal system, Crystals are commonly recognized by their shape, consisting of flat faces with sharp angles. Euhedral crystals are those with obvious, well-formed flat faces, anhedral crystals do not, usually because the crystal is one grain in a polycrystalline solid. The flat faces of a crystal are oriented in a specific way relative to the underlying atomic arrangement of the crystal. This occurs because some surface orientations are more stable than others, as a crystal grows, new atoms attach easily to the rougher and less stable parts of the surface, but less easily to the flat, stable surfaces
26.
Ilmenite
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Ilmenite is the titanium-iron oxide mineral with the idealized formula FeTiO3. It is a weakly magnetic black or steel-gray solid, from the commercial perspective, ilmenite is the most important ore of titanium. Ilmenite is the source of titanium dioxide, which is used in paints, fabrics, plastics, paper, sunscreen, food. Ilmenite crystallizes in the trigonal system, containing high spin ferrous centers, ilmenite is paramagnetic. Ilmenite is commonly recognized in altered igneous rocks by the presence of an alteration product. Often ilmenites are rimmed with leucoxene, which allows ilmenite to be distinguished from magnetite, the example shown in the image at right is typical of leucoxene-rimmed ilmenite. In reflected light it may be distinguished from magnetite by more pronounced reflection pleochroism, samples of ilmenite exhibit a weak response to a hand magnet. Ilmenite most often contains appreciable quantities of magnesium and manganese and the chemical formula can be expressed as O3. Ilmenite forms a solution with geikielite and pyrophanite which are magnesian. At higher temperatures it has been demonstrated there is a solid solution between ilmenite and hematite. There is a miscibility gap at lower temperatures, resulting in a coexistence of two minerals in rocks but no solid solution. This coexistence may result in exsolution lamellae in cooled ilmenites with more iron in the system than can be accommodated in the crystal lattice. Altered ilmenite forms the mineral leucoxene, an important source of titanium in heavy mineral sands ore deposits, leucoxene is a typical component of altered gabbro and diorite and is generally indicative of ilmenite in the unaltered rock. Ilmenite is an accessory mineral found in metamorphic and igneous rocks. It is found in large concentrations in layered intrusions where it forms as part of a layer within the silicate stratigraphy of the intrusion. Ilmenite generally occurs within the portion of such intrusions. Magnesian ilmenite is indicative of kimberlitic paragenesis and forms part of the MARID association of minerals assemblage of glimmerite xenoliths, manganiferous ilmenite is found in granitic rocks and also in carbonatite intrusions where it may also contain anomalous niobium. Many mafic igneous rocks contain grains of magnetite and ilmenite
27.
Corundum
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Corundum is a crystalline form of aluminium oxide typically containing traces of iron, titanium, vanadium and chromium. It is a transparent material, but can have different colors when impurities are present. Transparent specimens are used as gems, called ruby if red, all other colors are called sapphire, e. g. green sapphire for a green specimen. The name corundum is derived from the Tamil word Kurundam which originates from the Sanskrit word Kuruvinda meaning ruby, because of corundums hardness, it can scratch almost every other mineral. It is commonly used as an abrasive on everything from sandpaper to large machines used in machining metals, plastics, some emery is a mix of corundum and other substances, and the mix is less abrasive, with an average Mohs hardness of 8.0. In addition to its hardness, corundum is unusual for its density of 4.02 g/cm3, corundum occurs as a mineral in mica schist, gneiss, and some marbles in metamorphic terranes. It also occurs in low silica igneous syenite and nepheline syenite intrusives, other occurrences are as masses adjacent to ultramafic intrusives, associated with lamprophyre dikes and as large crystals in pegmatites. It commonly occurs as a mineral in stream and beach sands because of its hardness. The largest documented crystal of corundum measured about 65×40×40 cm. The record has since surpassed by certain synthetic boules. Corundum for abrasives is mined in Zimbabwe, Russia, Sri Lanka, historically it was mined from deposits associated with dunites in North Carolina, US and from a nepheline syenite in Craigmont, Ontario. Emery-grade corundum is found on the Greek island of Naxos and near Peekskill, New York, abrasive corundum is synthetically manufactured from bauxite. Four corundum axes dating back to 2500 BCE from the Liangzhou culture have been discovered in China, in 1837, Marc Antoine Gaudin made the first synthetic rubies by fusing alumina at a high temperature with a small amount of chromium as a pigment. In 1847, Ebelmen made white synthetic sapphires by fusing alumina in boric acid, in 1877 Frenic and Freil made crystal corundum from which small stones could be cut. Frimy and Auguste Verneuil manufactured artificial ruby by fusing BaF2, in 1903, Verneuil announced he could produce synthetic rubies on a commercial scale using this flame fusion process. The Verneuil process allows the production of flawless single-crystal sapphires, rubies and it is also possible to grow gem-quality synthetic corundum by flux-growth and hydrothermal synthesis. Corundum crystallizes with trigonal symmetry in the space group R3c and has the lattice parameters a =4.75 Å and c =12.982 Å at standard conditions, the unit cell contains six formula units. In the lattice of corundum, the atoms form a slightly distorted hexagonal close packing
28.
Solid solution
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A solid solution is a solid-state solution of one or more solutes in a solvent. The solid solution needs to be distinguished from a mechanical mixtures of powdered solids like two salts, sugar and salt, etc, the mechanical mixtures have total or partial miscibility gap in solid state. Examples of solid solutions include crystallized salts from their liquid mixture, metal alloys, in the case of metal alloys intermetallic compounds occur frequently. The solute may incorporate into the solvent crystal lattice substitutionally, by replacing a solvent particle in the lattice, or interstitially, by fitting into the space between solvent particles. Both of these types of solid solution affect the properties of the material by distorting the crystal lattice, some mixtures will readily form solid solutions over a range of concentrations, while other mixtures will not form solid solutions at all. The propensity for any two substances to form a solution is a complicated matter involving the chemical, crystallographic. 1 displays an alloy of two metals which forms a solution at all relative concentrations of the two species. Solid solutions have important commercial and industrial applications, as such mixtures often have superior properties to pure materials, many metal alloys are solid solutions. Even small amounts of solute can affect the electrical and physical properties of the solvent, the binary phase diagram in Fig.2 shows the phases of a mixture of two substances in varying concentrations, A and B. The region labeled α is a solution, with B acting as the solute in a matrix of A. On the other end of the scale, the region labeled β is also a solid solution. The large solid region in between the α and β solid solutions, labeled α + β, is not a solid solution, at other proportions, the material will enter a mushy or pasty phase until it warms up to being completely melted. The mixture at the dip point of the diagram is called a eutectic alloy, lead-tin mixtures formulated at that point are useful when soldering electronic components, particularly if done manually, since the solid phase is quickly entered as the solder cools. In contrast, when lead-tin mixtures were used to solder seams in automobile bodies a pasty state enabled a shape to be formed with a paddle or tool. When a solid solution becomes unstable — due to a temperature, for example — exsolution occurs. This is mainly caused by difference in cation size, cations which have a large difference in radii are not likely to readily substitute. Take the alkali feldspar minerals for example, whose end members are albite, NaAlSi3O8 and microcline and this leads to exsolution where they will separate into two separate phases. In the case of the feldspar minerals, thin white albite layers will alternate between typically pink microcline
29.
Mining
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Mining is extraction of valuable minerals or other geological materials from the earth usually from an orebody, lode, vein, seam, reef or placer deposits. These deposits form a mineralized package that is of economic interest to the miner, ores recovered by mining include metals, coal, oil shale, gemstones, limestone, chalk, dimension stone, rock salt, potash, gravel, and clay. Mining is required to obtain any material that cannot be grown through agricultural processes, Mining in a wider sense includes extraction of any non-renewable resource such as petroleum, natural gas, or even water. Mining of stones and metal has been a human activity since pre-historic times, Mining operations usually create a negative environmental impact, both during the mining activity and after the mine has closed. Hence, most of the nations have passed regulations to decrease the impact. Work safety has long been a concern as well, and modern practices have significantly improved safety in mines, levels of metals recycling are generally low. Unless future end-of-life recycling rates are stepped up, some rare metals may become unavailable for use in a variety of consumer products, due to the low recycling rates, some landfills now contain higher concentrations of metal than mines themselves. Since the beginning of civilization, people have used stone, ceramics and, later and these were used to make early tools and weapons, for example, high quality flint found in northern France, southern England and Poland was used to create flint tools. Flint mines have been found in areas where seams of the stone were followed underground by shafts. The mines at Grimes Graves and Krzemionki are especially famous, other hard rocks mined or collected for axes included the greenstone of the Langdale axe industry based in the English Lake District. The oldest-known mine on archaeological record is the Lion Cave in Swaziland, at this site Paleolithic humans mined hematite to make the red pigment ochre. Mines of an age in Hungary are believed to be sites where Neanderthals may have mined flint for weapons. Ancient Egyptians mined malachite at Maadi, at first, Egyptians used the bright green malachite stones for ornamentations and pottery. Later, between 2613 and 2494 BC, large building projects required expeditions abroad to the area of Wadi Maghareh in order to secure minerals and other resources not available in Egypt itself. Quarries for turquoise and copper were found at Wadi Hammamat, Tura, Aswan and various other Nubian sites on the Sinai Peninsula. Mining in Egypt occurred in the earliest dynasties, the gold mines of Nubia were among the largest and most extensive of any in Ancient Egypt. These mines are described by the Greek author Diodorus Siculus, who mentions fire-setting as one used to break down the hard rock holding the gold. One of the complexes is shown in one of the earliest known maps, the miners crushed the ore and ground it to a fine powder before washing the powder for the gold dust
30.
Iron ore
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Iron ores are rocks and minerals from which metallic iron can be economically extracted. The ores are rich in iron oxides and vary in color from dark grey, bright yellow. The iron itself is found in the form of magnetite, hematite, goethite, limonite or siderite. Ores containing very high quantities of hematite or magnetite are known as ore or direct shipping ore. Iron ore is the raw material used to make pig iron, indeed, it has been argued that iron ore is more integral to the global economy than any other commodity, except perhaps oil. Metallic iron is virtually unknown on the surface of the Earth except as iron-nickel alloys from meteorites, although iron is the fourth most abundant element in the Earths crust, comprising about 5%, the vast majority is bound in silicate or more rarely carbonate minerals. Prior to the revolution, most iron was obtained from widely available goethite or bog ore, for example during the American Revolution. Prehistoric societies used laterite as a source of iron ore, historically, much of the iron ore utilized by industrialized societies has been mined from predominantly hematite deposits with grades of around 70% Fe. These deposits are referred to as direct shipping ores or natural ores. Iron-ore mining methods vary by the type of ore being mined, there are four main types of iron-ore deposits worked currently, depending on the mineralogy and geology of the ore deposits. These are magnetite, titanomagnetite, massive hematite and pisolitic ironstone deposits, banded iron formations are sedimentary rocks containing more than 15% iron composed predominantly of thinly bedded iron minerals and silica. Banded iron formations occur exclusively in Precambrian rocks, and are weakly to intensely metamorphosed. Banded iron formations may contain iron in carbonates or silicates, banded iron formations are known as taconite within North America. The mining involves moving tremendous amounts of ore and waste, the waste comes in two forms, non-ore bedrock in the mine, and unwanted minerals which are an intrinsic part of the ore rock itself. The mullock is mined and piled in dumps, and the gangue is separated during the beneficiation process and is removed as tailings. Taconite tailings are mostly the mineral quartz, which is chemically inert and this material is stored in large, regulated water settling ponds. The typical magnetite iron-ore concentrate has less than 0. 1% phosphorus, 3–7% silica, currently magnetite iron ore is mined in Minnesota and Michigan in the U. S. Direct-shipping iron-ore deposits are exploited on all continents except Antarctica, with the largest intensity in South America
31.
Pseudomorph
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The name literally means false form. Terminology for pseudomorphs is replacer after original, as in brookite after rutile, an infiltration pseudomorph, or substitution pseudomorph is a pseudomorph in which one mineral or other material is replaced by another. The original shape of the mineral remains unchanged, but color, hardness, an example of this process is the replacement of wood by silica to form petrified wood in which the substitution may be so perfect as to retain the original cellular structure of the wood. An example of substitution is replacement of aragonite twin crystals by native copper, as occurs at the Corocoro United Copper Mines of Coro Coro. A variety of infiltration or substitution pseudomorphism is called alteration, in only partial replacement occurs. This happens typically when a mineral of one composition changes by chemical reaction to another of similar composition, an example is a change from galena to anglesite. The resulting pseudomorph may contain a core of galena surrounded by anglesite that has the cubic crystal shape of galena. A paramorph is a mineral changed on the level only. It has the chemical composition, but with a different structure. The mineral looks identical to the original unaltered form and this occurs, as an example, in the aragonite to calcite change. An incrustation pseudomorph, also called perimorph, results from a process by which a mineral is coated by another, the encasing mineral remains intact, and retains the shape of the original mineral or material. Alternatively, another mineral may fill the previously occupied by some other mineral or material. Pseudomorphs are also common in paleontology, fossils are often formed by pseudomorphic replacement of the remains by mineral matter. Examples include petrified wood and pyritized gastropod shells, in biology, a pseudomorph is a cloud of mucus-rich ink released by many species of cephalopod. The name refers to the similarity in appearance between the cephalopod that released it and the cloud itself, in context meaning literally false body. This behaviour often allows the cephalopod to escape from predation unharmed, danas Manual of Mineralogy by Cornelis S. Hurlbut, Eighteenth Edition, ISBN 0-471-42225-8 Polymorphism
32.
Magnetite
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Magnetite is a mineral and one of the main iron ores. With the chemical formula Fe3O4, it is one of the oxides of iron, Magnetite is ferrimagnetic, it is attracted to a magnet and can be magnetized to become a permanent magnet itself. It is the most magnetic of all the minerals on Earth. Naturally-magnetized pieces of magnetite, called lodestone, will attract small pieces of iron, today it is mined as iron ore. Small grains of magnetite occur in almost all igneous and metamorphic rocks, Magnetite is black or brownish-black with a metallic luster, has a Mohs hardness of 5–6 and leaves a black streak. The chemical IUPAC name is iron oxide and the chemical name is ferrous-ferric oxide. In addition to rocks, magnetite also occurs in sedimentary rocks, including banded iron formations and in lake. Magnetite nanoparticles are also thought to form in soils, where they probably oxidize rapidly to maghemite, Magnetite has an inverse spinel crystal structure. As a member of the group, it can form solid solutions with similarly structured minerals, including ulvospinel. Titanomagnetite, also known as titaniferous magnetite, is a solution between magnetite and ulvospinel that crystallizes in many mafic igneous rocks. Titanomagnetite may undergo oxyexsolution during cooling, resulting in ingrowths of magnetite and ilmenite, Magnetite has been important in understanding the conditions under which rocks form. Magnetite reacts with oxygen to produce hematite, and the pair forms a buffer that can control oxygen fugacity. Commonly, igneous rocks contain solid solutions of both titanomagnetite and hemoilmenite or titanohematite, Magnetite also is produced from peridotites and dunites by serpentinization. Lodestones were used as a form of magnetic compass. At low temperatures, magnetite undergoes a crystal structure phase transition from a structure to a cubic structure known as the Verwey transition. The Verwey transition occurs around 121 K and is dependent on size, domain state. An isotropic point also occurs near the Verwey transition around 130 K, the Curie temperature of magnetite is 858 K. Magnetite is sometimes found in large quantities in beach sand. Such black sands are found in places, such as Lung Kwu Tan of Hong Kong, California of the United States
33.
Maghemite
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Maghemite is a member of the family of iron oxides. It has the same spinel ferrite structure as magnetite and is also ferrimagnetic, maghemite can be considered as an Fe-deficient magnetite with formula A B O32 where ◻ represents a vacancy, A indicates tetrahedral and B octahedral positioning. Maghemite forms by weathering or low-temperature oxidation of spinels containing iron such as magnetite or titanomagnetite, maghemite can also form through dehydration and transformation of certain iron oxyhydroxide minerals, such as lepidocrocite and ferrihydrite. It occurs as brown or yellow pigment in terrestrial sediments. It is associated with magnetite, ilmenite, anatase, pyrite, marcasite, lepidocrocite and goethite, maghemite was named in 1927 for an occurrence at the Iron Mountain mine, northwest of Redding, Shasta County, California. The name alludes to somewhat intermediate character between MAGnetite and HEMatite and it can appear blue with a grey shade, white, or brown. Maghemite is formed by the oxidation of magnetite. Maghemite is a semiconductor with a bandgap of ca.2 eV, maghemite nanoparticles are also used in biomedicine, because they are biocompatible and non-toxic to humans, while their magnetism allows remote manipulation with external fields
34.
Banded iron formation
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Banded iron formations are distinctive units of sedimentary rock that are almost always of Precambrian age. Some of the oldest known rock formations, formed over 3,700 million years ago, Banded layers rich in iron were mostly deposited between 2,400 and 1,900 mya. Phanerozoic ironstones generally have a different genesis, Banded iron beds are an important commercial source of iron ore, such as the Pilbara region of Western Australia and the Animikie Group in Minnesota. The formations are abundant around the time of the great event,2,400 million years ago. The conventional concept is that the banded iron layers were formed in sea water as the result of oxygen released by photosynthetic cyanobacteria. The oxygen then combined with dissolved iron in Earths oceans to form insoluble iron oxides, which precipitated out, forming a layer on the ocean floor. Each band is similar to a varve, to the extent that the banding is assumed to result from variations in available oxygen. It is unclear whether these banded ironstone formations were seasonal, followed some feedback oscillation in the complex system or followed some other cycle. It is assumed that initially the Earth started with vast amounts of iron, as photosynthetic organisms generated oxygen, the available iron in the Earths oceans precipitated out as iron oxides. An alternative explanation of these deposits has undergone much discussion as part of the Snowball Earth hypothesis. Several hypotheses exist for the initiation of the Snowball Earths, in a Snowball Earth state the earths continents, and possibly seas at low latitudes, were subject to an ice age. If this was the case, Earths free oxygen may have nearly or totally depleted during a severe ice age circa 750 to 580 million years ago. Dissolved iron then accumulated in the oxygen-poor oceans, following the thawing of the Earth, the seas became oxygenated once more causing the precipitation of the iron. Another mechanism for BIFs, also proposed in the context of the Snowball Earth discussion, is by deposition from metal-rich brines in the vicinity of hydrothermally active rift zones, alternatively, some geochemists suggest that BIFs could form by direct oxidation of iron by microbial anoxygenic phototrophs. Northern Minnesotas banded iron formations lie directly underneath a layer of material only recently recognized as ejecta from the Sudbury Basin impact. At the time of formation Earth had a single supercontinent called Columbia with substantial continental shelves, an asteroid slammed into waters about 1,000 m deep some 1.85 billion years ago. Computer models suggest that the tsunami would have been at least 1,000 m at the epicentre and those immense waves and large underwater landslides triggered by the impact stirred the ocean, bringing oxygenated waters from the surface down to the ocean floor. Sediments deposited on the seafloor before the impact, including BIFs contained little if any oxidized iron and this Fe to Fe ratio suggests that most parts of the ocean were relatively devoid of oxygen
35.
Hot spring
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A hot spring is a spring produced by the emergence of geothermally heated groundwater that rises from the Earths crust. There are geothermal hot springs in many locations all over the crust of the earth, while some of these springs contain water that is a safe temperature for bathing, others are so hot that immersion can result in injury or death. The water temperature of a hot spring is usually 6.5 °C or more above mean air temperature, note that by this definition, thermal spring is not synonymous with the term hot spring a spring whose hot water is brought to the surface. The water temperature of the spring is usually 8.3 °C or more above the air temperature. A spring with water above the human body temperature –36.7 °C. suggest that the phrase warm spring is not useful. In general, the temperature of rocks within the earth increases with depth, the rate of temperature increase with depth is known as the geothermal gradient. If water percolates deeply enough into the crust, it will be heated as it comes into contact with hot rocks, the water from hot springs in non-volcanic areas is heated in this manner. In active volcanic zones such as Yellowstone National Park, water may be heated by coming into contact with magma, the high temperature gradient near magma may cause water to be heated enough that it boils or becomes superheated. If the water becomes so hot that it builds steam pressure and erupts in a jet above the surface of the Earth, if the water only reaches the surface in the form of steam, it is called a fumarole. If the water is mixed with mud and clay, it is called a mud pot, note that hot springs in volcanic areas are often at or near the boiling point. People have been seriously scalded and even killed by accidentally or intentionally entering these springs, Warm springs are sometimes the result of hot and cold springs mixing. They may occur within an area or outside of one. One example of a warm spring is Warm Springs, Georgia. Hot springs range in flow rate from the tiniest seeps to veritable rivers of hot water, sometimes there is enough pressure that the water shoots upward in a geyser, or fountain. There are many claims in the literature about the rates of hot springs. It should be noted there are many more high flow non-thermal springs than geothermal springs. For example, there are 33 recognized magnitude one springs (having a flow in excess of 2,800 L/s in Florida alone, silver Springs, Florida has a flow of more than 21,000 L/s. Springs with high flow rates include, The Excelsior Geyser Crater in Yellowstone National Park yields about 4,000 U. S. gal/min
36.
Yellowstone National Park
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Yellowstone National Park is a national park located in the U. S. states of Wyoming, Montana and Idaho. It was established by the U. S. Congress and signed into law by President Ulysses S. Grant on March 1,1872. Yellowstone was the first National Park in the U. S. and is widely held to be the first national park in the world. The park is known for its wildlife and its many features, especially Old Faithful Geyser. It has many types of ecosystems, but the subalpine forest is the most abundant and it is part of the South Central Rockies forests ecoregion. Native Americans have lived in the Yellowstone region for at least 11,000 years, aside from visits by mountain men during the early-to-mid-19th century, organized exploration did not begin until the late 1860s. Management and control of the park fell under the jurisdiction of the Secretary of the Interior. However, the U. S. Army was subsequently commissioned to oversee management of Yellowstone for a 30-year period between 1886 and 1916, in 1917, administration of the park was transferred to the National Park Service, which had been created the previous year. Hundreds of structures have been built and are protected for their architectural and historical significance, Yellowstone National Park spans an area of 3,468.4 square miles, comprising lakes, canyons, rivers and mountain ranges. Yellowstone Lake is one of the largest high-elevation lakes in North America and is centered over the Yellowstone Caldera, the caldera is considered an active volcano. It has erupted with tremendous force several times in the last two million years, half of the worlds geothermal features are in Yellowstone, fueled by this ongoing volcanism. Lava flows and rocks from volcanic eruptions cover most of the area of Yellowstone. The park is the centerpiece of the Greater Yellowstone Ecosystem, the largest remaining nearly-intact ecosystem in the Earths northern temperate zone, hundreds of species of mammals, birds, fish, and reptiles have been documented, including several that are either endangered or threatened. The vast forests and grasslands also include species of plants. Yellowstone Park is the largest and most famous location in the Continental United States. Grizzly bears, wolves, and free-ranging herds of bison and elk live in the park, the Yellowstone Park bison herd is the oldest and largest public bison herd in the United States. Forest fires occur in the each year, in the large forest fires of 1988. Yellowstone has numerous opportunities, including hiking, camping, boating, fishing and sightseeing
37.
North America
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North America is a continent entirely within the Northern Hemisphere and almost all within the Western Hemisphere. It can also be considered a subcontinent of the Americas. It is bordered to the north by the Arctic Ocean, to the east by the Atlantic Ocean, to the west and south by the Pacific Ocean, and to the southeast by South America and the Caribbean Sea. North America covers an area of about 24,709,000 square kilometers, about 16. 5% of the land area. North America is the third largest continent by area, following Asia and Africa, and the fourth by population after Asia, Africa, and Europe. In 2013, its population was estimated at nearly 565 million people in 23 independent states, or about 7. 5% of the worlds population, North America was reached by its first human populations during the last glacial period, via crossing the Bering land bridge. The so-called Paleo-Indian period is taken to have lasted until about 10,000 years ago, the Classic stage spans roughly the 6th to 13th centuries. The Pre-Columbian era ended with the migrations and the arrival of European settlers during the Age of Discovery. Present-day cultural and ethnic patterns reflect different kind of interactions between European colonists, indigenous peoples, African slaves and their descendants, European influences are strongest in the northern parts of the continent while indigenous and African influences are relatively stronger in the south. Because of the history of colonialism, most North Americans speak English, Spanish or French, the Americas are usually accepted as having been named after the Italian explorer Amerigo Vespucci by the German cartographers Martin Waldseemüller and Matthias Ringmann. Vespucci, who explored South America between 1497 and 1502, was the first European to suggest that the Americas were not the East Indies, but a different landmass previously unknown by Europeans. In 1507, Waldseemüller produced a map, in which he placed the word America on the continent of South America. He explained the rationale for the name in the accompanying book Cosmographiae Introductio, for Waldseemüller, no one should object to the naming of the land after its discoverer. He used the Latinized version of Vespuccis name, but in its feminine form America, following the examples of Europa, Asia and Africa. Later, other mapmakers extended the name America to the continent, In 1538. Some argue that the convention is to use the surname for naming discoveries except in the case of royalty, a minutely explored belief that has been advanced is that America was named for a Spanish sailor bearing the ancient Visigothic name of Amairick. Another is that the name is rooted in a Native American language, the term North America maintains various definitions in accordance with location and context. In Canadian English, North America may be used to refer to the United States, alternatively, usage sometimes includes Greenland and Mexico, as well as offshore islands
38.
Precipitation (chemistry)
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Precipitation is the creation of a solid from a solution. When the reaction occurs in a solution, the solid formed is called the precipitate. The chemical that causes the solid to form is called the precipitant, without sufficient force of gravity to bring the solid particles together, the precipitate remains in suspension. After sedimentation, especially when using a centrifuge to press it into a compact mass, Precipitation can be used as a medium. The precipitate-free liquid remaining above the solid is called the supernate or supernatant, powders derived from precipitation have also historically been known as flowers. When the solid appears in the form of fibers which have been through chemical processing. Sometimes the formation of a precipitate indicates the occurrence of a chemical reaction, if silver nitrate solution is poured into a solution of sodium chloride, a chemical reaction occurs forming a white precipitate of silver chloride. When potassium iodide solution reacts with lead nitrate solution, a precipitate of lead iodide is formed. Precipitation may occur if the concentration of a compound exceeds its solubility, Precipitation may occur rapidly from a supersaturated solution. Precipitation in solids is routinely used to synthesize nanoclusters, an important stage of the precipitation process is the onset of nucleation. The creation of a solid particle includes the formation of an interface, which requires some energy based on the relative surface energy of the solid. If this energy is not available, and no suitable nucleation surface is available, Precipitation reactions can be used for making pigments, removing salts from water in water treatment, and in classical qualitative inorganic analysis. Precipitation is also useful to isolate the products of a reaction during workup, ideally, the product of the reaction is insoluble in the reaction solvent. Thus, it precipitates as it is formed, preferably forming pure crystals, an example of this would be the synthesis of porphyrins in refluxing propionic acid. Thereafter, the precipitate may easily be separated by filtration, decanting, an example would be the synthesis of chromic tetraphenylporphyrin chloride, water is added to the DMF reaction solution, and the product precipitates. Precipitation is also useful in purifying products, crude bmim-Cl is taken up in acetonitrile, and dropped into ethyl acetate, another important application of an antisolvent is in ethanol precipitation of DNA. In metallurgy, precipitation from a solution is also a useful way to strengthen alloys. An example of a reaction, Aqueous silver nitrate is added to a solution containing potassium chloride
39.
Volcano
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A volcano is a rupture in the crust of a planetary-mass object, such as Earth, that allows hot lava, volcanic ash, and gases to escape from a magma chamber below the surface. Earths volcanoes occur because its crust is broken into 17 major, therefore, on Earth, volcanoes are generally found where tectonic plates are diverging or converging. This type of volcanism falls under the umbrella of plate hypothesis volcanism, Volcanism away from plate boundaries has also been explained as mantle plumes. These so-called hotspots, for example Hawaii, are postulated to arise from upwelling diapirs with magma from the boundary,3,000 km deep in the Earth. Volcanoes are usually not created where two plates slide past one another. Erupting volcanoes can pose hazards, not only in the immediate vicinity of the eruption. Historically, so-called volcanic winters have caused catastrophic famines, the word volcano is derived from the name of Vulcano, a volcanic island in the Aeolian Islands of Italy whose name in turn comes from Vulcan, the god of fire in Roman mythology. The study of volcanoes is called volcanology, sometimes spelled vulcanology, at the mid-oceanic ridges, two tectonic plates diverge from one another as new oceanic crust is formed by the cooling and solidifying of hot molten rock. Most divergent plate boundaries are at the bottom of the oceans, therefore, most volcanic activity is submarine, black smokers are evidence of this kind of volcanic activity. Where the mid-oceanic ridge is above sea-level, volcanic islands are formed, for example, subduction zones are places where two plates, usually an oceanic plate and a continental plate, collide. In this case, the plate subducts, or submerges under the continental plate forming a deep ocean trench just offshore. In a process called flux melting, water released from the subducting plate lowers the temperature of the overlying mantle wedge. This magma tends to be very viscous due to its high content, so it often does not reach the surface. When it does reach the surface, a volcano is formed, typical examples of this kind of volcano are Mount Etna and the volcanoes in the Pacific Ring of Fire. Because tectonic plates move across them, each volcano becomes dormant and is eventually re-formed as the plate advances over the postulated plume and this theory is currently under criticism, however. The most common perception of a volcano is of a mountain, spewing lava and poisonous gases from a crater at its summit, however. The features of volcanoes are more complicated and their structure. Some volcanoes have rugged peaks formed by lava domes rather than a summit crater while others have features such as massive plateaus
40.
Clay
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Clay is a fine-grained natural rock or soil material that combines one or more clay minerals with traces of metal oxides and organic matter. Geologic clay deposits are composed of phyllosilicate minerals containing variable amounts of water trapped in the mineral structure. Clays are plastic due to water content and become hard, brittle. Depending on the content in which it is found, clay can appear in various colours from white to dull grey or brown to deep orange-red. Although many naturally occurring deposits include both silts and clay, clays are distinguished from other fine-grained soils by differences in size, silts, which are fine-grained soils that do not include clay minerals, tend to have larger particle sizes than clays. There is, however, some overlap in size and other physical properties. The distinction between silt and clay varies by discipline, geologists and soil scientists usually consider the separation to occur at a particle size of 2 µm, sedimentologists often use 4–5 μm, and colloid chemists use 1 μm. Geotechnical engineers distinguish between silts and clays based on the plasticity properties of the soil, as measured by the soils Atterberg limits, ISO14688 grades clay particles as being smaller than 2 μm and silt particles as being larger. These solvents, usually acidic, migrate through the rock after leaching through upper weathered layers. In addition to the process, some clay minerals are formed through hydrothermal activity. There are two types of deposits, primary and secondary. Primary clays form as residual deposits in soil and remain at the site of formation, secondary clays are clays that have been transported from their original location by water erosion and deposited in a new sedimentary deposit. Clay deposits are associated with very low energy depositional environments such as large lakes. Depending on the source, there are three or four main groups of clays, kaolinite, montmorillonite-smectite, illite, and chlorite. Chlorites are not always considered to be a clay, sometimes being classified as a group within the phyllosilicates. There are approximately 30 different types of clays in these categories. Varve is clay with visible annual layers, which are formed by deposition of those layers and are marked by differences in erosion. This type of deposit is common in glacial lakes
41.
Weathering
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Weathering is the breaking down of rocks, soil, and minerals as well as wood and artificial materials through contact with the Earths atmosphere, waters, and biological organisms. Two important classifications of weathering processes exist – physical and chemical weathering, mechanical or physical weathering involves the breakdown of rocks and soils through direct contact with atmospheric conditions, such as heat, water, ice and pressure. While physical weathering is accentuated in very cold or very dry environments, chemical reactions are most intense where the climate is wet, however, both types of weathering occur together, and each tends to accelerate the other. For example, physical abrasion decreases the size of particles and therefore increases their surface area, the various agents act in concert to convert primary minerals to secondary minerals and release plant nutrient elements in soluble forms. The materials left over after the rock breaks down combined with organic material creates soil, in addition, many of Earths landforms and landscapes are the result of weathering processes combined with erosion and re-deposition. Physical weathering, also recognized as mechanical weathering, is the class of processes that causes the disintegration of rocks without chemical change, the primary process in physical weathering is abrasion. However, chemical and physical weathering often go hand in hand, physical weathering can occur due to temperature, pressure, frost etc. For example, cracks exploited by physical weathering will increase the area exposed to chemical action. Abrasion by water, ice, and wind loaded with sediment can have tremendous cutting power, as is amply demonstrated by the gorges, ravines. In glacial areas, huge moving ice masses embedded with soil and rock fragments grind down rocks in their path, plant roots sometimes enter cracks in rocks and pry them apart, resulting in some disintegration, Burrowing animals may help disintegrate rock through their physical action. However, such influences are usually of importance in producing parent material when compared to the drastic physical effects of water, ice, wind. Physical weathering is called mechanical weathering or disaggregation. Thermal stress weathering results from the expansion and contraction of rock, for example, heating of rocks by sunlight or fires can cause expansion of their constituent minerals. As some minerals expand more than others, temperature changes set up differential stresses that cause the rock to crack apart. Because the outer surface of a rock is often warmer or colder than the more protected inner portions and this process may be sharply accelerated if ice forms in the surface cracks. When water freezes, it expands with a force of about 1465 Mg/m^2, disintegrating huge rock masses, thermal stress weathering comprises two main types, thermal shock and thermal fatigue. Thermal stress weathering is an important mechanism in deserts, where there is a diurnal temperature range, hot in the day. The repeated heating and cooling exerts stress on the layers of rocks
42.
Soil
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Soil is a mixture of minerals, organic matter, gases, liquids, and countless organisms that together support life on Earth. Soil is called the Skin of the Earth and interfaces with the lithosphere, the hydrosphere, the atmosphere, the term pedolith, used commonly to refer to the soil, literally translates ground stone. Soil consists of a phase of minerals and organic matter, as well as a porous phase that holds gases. Accordingly, soils are often treated as a system of solids, liquids. Soil is a product of the influence of climate, relief, organisms, Soil continually undergoes development by way of numerous physical, chemical and biological processes, which include weathering with associated erosion. Given its complexity and strong internal connectedness soil has been considered as an ecosystem by soil ecologists. Most soils have a dry bulk density between 1.1 and 1.6 g/cm3, while the particle density is much higher. Little of the soil of planet Earth is older than the Pleistocene and none is older than the Cenozoic, Soil science has two basic branches of study, edaphology and pedology. Edaphology is concerned with the influence of soils on living things, pedology is focused on the formation, description, and classification of soils in their natural environment. In engineering terms, soil is referred to as regolith, or loose material that lies above the solid geology. Soil is commonly referred to as earth or dirt, technically, as soil resources serve as a basis for food security, the international community advocates its sustainable and responsible use through different types of soil governance. Soil is a component of the Earths ecosystem. The worlds ecosystems are impacted in far-reaching ways by the carried out in the soil, from ozone depletion and global warming, to rainforest destruction. Following the atmosphere, the soil is the next largest carbon reservoir on Earth, as the planet warms, soils will add carbon dioxide to the atmosphere due to its increased biological activity at higher temperatures. Thus, soil carbon losses likely have a positive feedback response to global warming. Since soil has a range of available niches and habitats. A gram of soil can contain billions of organisms, belonging to thousands of species, mostly microbial, Soil has a mean prokaryotic density of roughly 108 organisms per gram, whereas the ocean has no more than 107 procaryotic organisms per milliliter of seawater. Since plant roots need oxygen, ventilation is an important characteristic of soil and this ventilation can be accomplished via networks of interconnected soil pores, which also absorb and hold rainwater making it readily available for plant uptake
43.
Goethite
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Goethite, is an iron bearing hydroxide mineral of the diaspore group, is found in soil and other low-temperature environments. Goethite has been known since ancient times for its use as a pigment. Evidence has been found of its use in paint pigment samples taken from the caves of Lascaux in France and it was first described in 1806 based on samples found in the Hollertszug Mine in Herdorf, Germany. The mineral was named after the German polymath and poet Johann Wolfgang von Goethe, in 2003, nanoparticulate authigenic goethite was shown to be the most common diagenetic iron oxyhydroxide in both marine and lake sediments. Goethite is an iron oxyhydroxide containing ferric iron and it is the main component of rust and bog iron ore. Goethites hardness ranges from 5.0 to 5.5 on the Mohs Scale, the mineral forms prismatic needle-like crystals, but is more typically massive. Feroxyhyte and lepidocrocite are both polymorphs of the iron oxyhydroxide FeO, although they have the same chemical formula as goethite, their different crystalline structures make them distinct minerals. Goethite often forms through the weathering of other minerals, and thus is a common component of soils. The formation of goethite is marked by the state change of Fe2+ to Fe3+. Because of this state change, goethite is commonly seen as a pseudomorph. As iron-bearing minerals are brought to the zone of oxidation within the soil and it may also be precipitated by groundwater or in other sedimentary conditions, or form as a primary mineral in hydrothermal deposits. Goethite has also found to be produced by the excretion processes of certain bacteria types. Goethite is found all over the planet, usually in the form of concretions, stalactitic formations, oolites and it is also a very common pseudomorph. It is frequently encountered in the areas at the head of spring waters, on cave floors. The boxworks or gossan resulting from the oxidation of ore deposits is formed of goethite along with other iron oxides. Significant deposits of goethite are found in England, Australia, Cuba, and Michigan, Minnesota, Missouri, Colorado, Alabama, Georgia, Virginia, and Tennessee, and Florida caves in the United States. In 2015 it was reported that limpets teeth have goethite fibres in them and its main modern use is as an iron ore, being referred to as brown iron ore. It does have some use as an earth pigment
44.
Tropics
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The tropics are a region of the Earth surrounding the equator. The tropics are also referred to as the zone and the torrid zone. The tropics include all the areas on the Earth where the Sun is at a point directly overhead at least once during the solar year. The tropics are distinguished from the climatic and biomatic regions of Earth, which are the middle latitudes. Tropical is sometimes used in a sense for a tropical climate to mean warm to hot and moist year-round. Many tropical areas have a dry and wet season, the wet season, rainy season or green season, is the time of year, ranging from one or more months, when most of the average annual rainfall in a region falls. Areas with wet seasons are disseminated across portions of the tropics and subtropics, under the Köppen climate classification, for tropical climates, a wet season month is defined as a month where average precipitation is 60 millimetres or more. Tropical rainforests technically do not have dry or wet seasons, since their rainfall is distributed through the year. When the wet season occurs during the season, or summer, precipitation falls mainly during the late afternoon. The wet season is a time when air quality improves, freshwater quality improves and vegetation grows significantly, floods cause rivers to overflow their banks, and some animals to retreat to higher ground. Soil nutrients diminish and erosion increases, the incidence of malaria increases in areas where the rainy season coincides with high temperatures. Animals have adaptation and survival strategies for the wetter regime, unfortunately, the previous dry season leads to food shortages into the wet season, as the crops have yet to mature. Regions within the tropics may well not have a tropical climate, there are alpine tundra and snow-capped peaks, including Mauna Kea, Mount Kilimanjaro, and the Andes as far south as the northernmost parts of Chile and Argentina. Under the Köppen climate classification, much of the area within the tropics is classed not as tropical but as dry including the Sahara Desert. Tropical plants and animals are those native to the tropics. Tropical ecosystems may consist of rainforests, dry forests, spiny forests, desert. There are often significant areas of biodiversity, and species present, particularly in rainforests. In biogeography, the tropics are divided into Paleotropics and Neotropics, together, they are sometimes referred to as the Pantropic
45.
Ochre
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Ochre (/ˈoʊkər/ OH-kər, from Greek, ὠχρός, ōkhrós, or ocher, is a natural earth pigment containing hydrated iron oxide, which ranges in color from yellow to deep orange or brown. It is also the name of the produced by this pigment. A variant of ochre containing an amount of hematite, or dehydrated iron oxide, has a reddish tint known as red ochre. Ochre is a family of pigments, which includes yellow ochre, red ochre, purple ochre, sienna. The major ingredient of all the ochres is iron oxide-hydroxide, known as limonite, which gives them a yellow color. Yellow ochre, FeO·nH 2O, is a hydrated iron hydroxide also called gold ochre Red ochre, Fe 2O3, takes its color from the mineral hematite. Purple ochre, is identical to red ochre chemically but of a different hue caused by different light diffraction properties associated with an average particle size. Brown ochre, also FeO, is a hydrated iron oxide. Sienna contains both limonite and an amount of manganese oxide, which makes it darker than ochre. Umber pigments contain a proportion of manganese which make them a dark brown. When natural sienna and umber pigments are heated, they are dehydrated and some of the limonite is transformed into hematite, giving them more reddish colors, called burnt sienna and burnt umber. Ochres are non-toxic, and can be used to make an oil paint that dries quickly, modern ochre pigments often are made using synthetic iron oxide. Pigments which use natural ochre pigments indicate it with the name PY-43 on the label, pieces of ochre engraved with abstract designs have been found at the site of the Blombos Cave in South Africa, dated to around 75,000 years ago. In Wales, the paleolithic burial called the Red Lady of Paviland from its coating of red ochre has been dated to around 33,000 years before present. Paintings of animals made with red and yellow ochre pigments have been found in sites at Pech Merle in France. The cave of Lascaux has an image of a horse colored with yellow estimated to be 17,300 years old. In Ancient Egypt, yellow was associated with gold, which was considered to be eternal, the skin and bones of the gods were believed to be made of gold. The Egyptians used yellow extensively in tomb painting, though occasionally they used orpiment
46.
Greek language
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Greek is an independent branch of the Indo-European family of languages, native to Greece and other parts of the Eastern Mediterranean. It has the longest documented history of any living language, spanning 34 centuries of written records and its writing system has been the Greek alphabet for the major part of its history, other systems, such as Linear B and the Cypriot syllabary, were used previously. The alphabet arose from the Phoenician script and was in turn the basis of the Latin, Cyrillic, Armenian, Coptic, Gothic and many other writing systems. Together with the Latin texts and traditions of the Roman world, during antiquity, Greek was a widely spoken lingua franca in the Mediterranean world and many places beyond. It would eventually become the official parlance of the Byzantine Empire, the language is spoken by at least 13.2 million people today in Greece, Cyprus, Italy, Albania, Turkey, and the Greek diaspora. Greek roots are used to coin new words for other languages, Greek. Greek has been spoken in the Balkan peninsula since around the 3rd millennium BC, the earliest written evidence is a Linear B clay tablet found in Messenia that dates to between 1450 and 1350 BC, making Greek the worlds oldest recorded living language. Among the Indo-European languages, its date of earliest written attestation is matched only by the now extinct Anatolian languages, the Greek language is conventionally divided into the following periods, Proto-Greek, the unrecorded but assumed last ancestor of all known varieties of Greek. The unity of Proto-Greek would have ended as Hellenic migrants entered the Greek peninsula sometime in the Neolithic era or the Bronze Age, Mycenaean Greek, the language of the Mycenaean civilisation. It is recorded in the Linear B script on tablets dating from the 15th century BC onwards, Ancient Greek, in its various dialects, the language of the Archaic and Classical periods of the ancient Greek civilisation. It was widely known throughout the Roman Empire, after the Roman conquest of Greece, an unofficial bilingualism of Greek and Latin was established in the city of Rome and Koine Greek became a first or second language in the Roman Empire. The origin of Christianity can also be traced through Koine Greek, Medieval Greek, also known as Byzantine Greek, the continuation of Koine Greek in Byzantine Greece, up to the demise of the Byzantine Empire in the 15th century. Much of the written Greek that was used as the language of the Byzantine Empire was an eclectic middle-ground variety based on the tradition of written Koine. Modern Greek, Stemming from Medieval Greek, Modern Greek usages can be traced in the Byzantine period and it is the language used by the modern Greeks, and, apart from Standard Modern Greek, there are several dialects of it. In the modern era, the Greek language entered a state of diglossia, the historical unity and continuing identity between the various stages of the Greek language is often emphasised. Greek speakers today still tend to regard literary works of ancient Greek as part of their own rather than a foreign language and it is also often stated that the historical changes have been relatively slight compared with some other languages. According to one estimation, Homeric Greek is probably closer to demotic than 12-century Middle English is to modern spoken English, Greek is spoken by about 13 million people, mainly in Greece, Albania and Cyprus, but also worldwide by the large Greek diaspora. Greek is the language of Greece, where it is spoken by almost the entire population
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Pigment
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A pigment is a material that changes the color of reflected or transmitted light as the result of wavelength-selective absorption. This physical process differs from fluorescence, phosphorescence, and other forms of luminescence, many materials selectively absorb certain wavelengths of light. Materials that humans have chosen and developed for use as pigments usually have properties that make them ideal for coloring other materials. A pigment must have a high tinting strength relative to the materials it colors and it must be stable in solid form at ambient temperatures. For industrial applications, as well as in the arts, permanence, pigments that are not permanent are called fugitive. Fugitive pigments fade over time, or with exposure to light, pigments are used for coloring paint, ink, plastic, fabric, cosmetics, food, and other materials. Most pigments used in manufacturing and the arts are dry colorants. This powder is added to a binder, a neutral or colorless material that suspends the pigment. A distinction is made between a pigment, which is insoluble in its vehicle, and a dye, which either is itself a liquid or is soluble in its vehicle. A colorant can act as either a pigment or a dye depending on the vehicle involved, in some cases, a pigment can be manufactured from a dye by precipitating a soluble dye with a metallic salt. The resulting pigment is called a lake pigment, the term biological pigment is used for all colored substances independent of their solubility. In 2006, around 7.4 million tons of inorganic, organic, asia has the highest rate on a quantity basis followed by Europe and North America. By 2020, revenues will have risen to approx, the global demand on pigments was roughly US$20.5 billion in 2009, around 1. 5-2% up from the previous year. It is predicted to increase in a growth rate in the coming years. The worldwide sales are said to increase up to US$24.5 billion in 2015, pigments appear the colors they are because they selectively reflect and absorb certain wavelengths of visible light. White light is an equal mixture of the entire spectrum of visible light with a wavelength in a range from about 375 or 400 nanometers to about 760 or 780 nm. When this light encounters a pigment, parts of the spectrum are absorbed by the molecules or ions of the pigment, in organic pigments such as diazo or phthalocyanine compounds the light is absorbed by the conjugated systems of double bonds in the molecule. Some of the inorganic pigments such as vermilion or cadmium yellow absorb light by transferring an electron from the ion to the positive ion
