1.
Electron
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The electron is a subatomic particle, symbol e− or β−, with a negative elementary electric charge. Electrons belong to the first generation of the lepton particle family, the electron has a mass that is approximately 1/1836 that of the proton. Quantum mechanical properties of the include a intrinsic angular momentum of a half-integer value, expressed in units of the reduced Planck constant. As it is a fermion, no two electrons can occupy the same state, in accordance with the Pauli exclusion principle. Like all elementary particles, electrons exhibit properties of particles and waves, they can collide with other particles and can be diffracted like light. Since an electron has charge, it has an electric field. Electromagnetic fields produced from other sources will affect the motion of an electron according to the Lorentz force law, electrons radiate or absorb energy in the form of photons when they are accelerated. Laboratory instruments are capable of trapping individual electrons as well as electron plasma by the use of electromagnetic fields, special telescopes can detect electron plasma in outer space. Electrons are involved in applications such as electronics, welding, cathode ray tubes, electron microscopes, radiation therapy, lasers, gaseous ionization detectors. Interactions involving electrons with other particles are of interest in fields such as chemistry. The Coulomb force interaction between the positive protons within atomic nuclei and the negative electrons without, allows the composition of the two known as atoms, ionization or differences in the proportions of negative electrons versus positive nuclei changes the binding energy of an atomic system. The exchange or sharing of the electrons between two or more atoms is the cause of chemical bonding. In 1838, British natural philosopher Richard Laming first hypothesized the concept of a quantity of electric charge to explain the chemical properties of atoms. Irish physicist George Johnstone Stoney named this charge electron in 1891, electrons can also participate in nuclear reactions, such as nucleosynthesis in stars, where they are known as beta particles. Electrons can be created through beta decay of isotopes and in high-energy collisions. The antiparticle of the electron is called the positron, it is identical to the electron except that it carries electrical, when an electron collides with a positron, both particles can be totally annihilated, producing gamma ray photons. The ancient Greeks noticed that amber attracted small objects when rubbed with fur, along with lightning, this phenomenon is one of humanitys earliest recorded experiences with electricity. In his 1600 treatise De Magnete, the English scientist William Gilbert coined the New Latin term electricus, both electric and electricity are derived from the Latin ēlectrum, which came from the Greek word for amber, ἤλεκτρον
2.
International Union of Pure and Applied Chemistry
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The International Union of Pure and Applied Chemistry /ˈaɪjuːpæk/ or /ˈjuːpæk/ is an international federation of National Adhering Organizations that represents chemists in individual countries. It is a member of the International Council for Science, IUPAC is registered in Zürich, Switzerland, and the administrative office, known as the IUPAC Secretariat, is in Research Triangle Park, North Carolina, United States. This administrative office is headed by IUPACs executive director, currently Lynn Soby, IUPAC was established in 1919 as the successor of the International Congress of Applied Chemistry for the advancement of chemistry. Its members, the National Adhering Organizations, can be national chemistry societies, national academies of sciences, there are fifty-four National Adhering Organizations and three Associate National Adhering Organizations. IUPACs Inter-divisional Committee on Nomenclature and Symbols is the world authority in developing standards for the naming of the chemical elements. Since its creation, IUPAC has been run by different committees with different responsibilities. These committees run different projects which include standardizing nomenclature, finding ways to bring chemistry to the world, IUPAC is best known for its works standardizing nomenclature in chemistry and other fields of science, but IUPAC has publications in many fields including chemistry, biology and physics. IUPAC is also known for standardizing the atomic weights of the elements through one of its oldest standing committees, the need for an international standard for chemistry was first addressed in 1860 by a committee headed by German scientist Friedrich August Kekulé von Stradonitz. This committee was the first international conference to create an international naming system for organic compounds, the ideas that were formulated in that conference evolved into the official IUPAC nomenclature of organic chemistry. IUPAC stands as a legacy of this meeting, making it one of the most important historical international collaborations of chemistry societies, since this time, IUPAC has been the official organization held with the responsibility of updating and maintaining official organic nomenclature. IUPAC as such was established in 1919, one notable country excluded from this early IUPAC is Germany. Germanys exclusion was a result of prejudice towards Germans by the Allied powers after World War I, Germany was finally admitted into IUPAC during 1929. However, Nazi Germany was removed from IUPAC during World War II, during World War II, IUPAC was affiliated with the Allied powers, but had little involvement during the war effort itself. After the war, East and West Germany were eventually readmitted to IUPAC, since World War II, IUPAC has been focused on standardizing nomenclature and methods in science without interruption. In 2016, IUPAC denounced the use of chlorine as a chemical weapon, the letter stated, Our organizations deplore the use of chlorine in this manner. According to the CWC, the use, stockpiling, distribution, IUPAC is governed by several committees that all have different responsibilities. Each committee is made up of members of different National Adhering Organizations from different countries, the steering committee hierarchy for IUPAC is as follows, All committees have an allotted budget to which they must adhere. Any committee may start a project, if a projects spending becomes too much for a committee to continue funding, it must take the issue to the Project Committee
3.
Ion
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An ion is an atom or a molecule in which the total number of electrons is not equal to the total number of protons, giving the atom or molecule a net positive or negative electrical charge. Ions can be created, by chemical or physical means. In chemical terms, if an atom loses one or more electrons. If an atom gains electrons, it has a net charge and is known as an anion. Ions consisting of only a single atom are atomic or monatomic ions, because of their electric charges, cations and anions attract each other and readily form ionic compounds, such as salts. In the case of ionization of a medium, such as a gas, which are known as ion pairs are created by ion impact, and each pair consists of a free electron. The word ion comes from the Greek word ἰόν, ion, going and this term was introduced by English physicist and chemist Michael Faraday in 1834 for the then-unknown species that goes from one electrode to the other through an aqueous medium. Faraday also introduced the words anion for a charged ion. In Faradays nomenclature, cations were named because they were attracted to the cathode in a galvanic device, arrhenius explanation was that in forming a solution, the salt dissociates into Faradays ions. Arrhenius proposed that ions formed even in the absence of an electric current, ions in their gas-like state are highly reactive, and do not occur in large amounts on Earth, except in flames, lightning, electrical sparks, and other plasmas. These gas-like ions rapidly interact with ions of charge to give neutral molecules or ionic salts. These stabilized species are commonly found in the environment at low temperatures. A common example is the present in seawater, which are derived from the dissolved salts. Electrons, due to their mass and thus larger space-filling properties as matter waves, determine the size of atoms. Thus, anions are larger than the parent molecule or atom, as the excess electron repel each other, as such, in general, cations are smaller than the corresponding parent atom or molecule due to the smaller size of its electron cloud. One particular cation contains no electrons, and thus consists of a single proton - very much smaller than the parent hydrogen atom. Since the electric charge on a proton is equal in magnitude to the charge on an electron, an anion, from the Greek word ἄνω, meaning up, is an ion with more electrons than protons, giving it a net negative charge. A cation, from the Greek word κατά, meaning down, is an ion with fewer electrons than protons, there are additional names used for ions with multiple charges
4.
Hydrogen
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Hydrogen is a chemical element with chemical symbol H and atomic number 1. With a standard weight of circa 1.008, hydrogen is the lightest element on the periodic table. Its monatomic form is the most abundant chemical substance in the Universe, non-remnant stars are mainly composed of hydrogen in the plasma state. The most common isotope of hydrogen, termed protium, has one proton, the universal emergence of atomic hydrogen first occurred during the recombination epoch. At standard temperature and pressure, hydrogen is a colorless, odorless, tasteless, non-toxic, nonmetallic, since hydrogen readily forms covalent compounds with most nonmetallic elements, most of the hydrogen on Earth exists in molecular forms such as water or organic compounds. Hydrogen plays an important role in acid–base reactions because most acid-base reactions involve the exchange of protons between soluble molecules. In ionic compounds, hydrogen can take the form of a charge when it is known as a hydride. The hydrogen cation is written as though composed of a bare proton, Hydrogen gas was first artificially produced in the early 16th century by the reaction of acids on metals. Industrial production is mainly from steam reforming natural gas, and less often from more energy-intensive methods such as the electrolysis of water. Most hydrogen is used near the site of its production, the two largest uses being fossil fuel processing and ammonia production, mostly for the fertilizer market, Hydrogen is a concern in metallurgy as it can embrittle many metals, complicating the design of pipelines and storage tanks. Hydrogen gas is flammable and will burn in air at a very wide range of concentrations between 4% and 75% by volume. The enthalpy of combustion is −286 kJ/mol,2 H2 + O2 →2 H2O +572 kJ Hydrogen gas forms explosive mixtures with air in concentrations from 4–74%, the explosive reactions may be triggered by spark, heat, or sunlight. The hydrogen autoignition temperature, the temperature of spontaneous ignition in air, is 500 °C, the detection of a burning hydrogen leak may require a flame detector, such leaks can be very dangerous. Hydrogen flames in other conditions are blue, resembling blue natural gas flames, the destruction of the Hindenburg airship was a notorious example of hydrogen combustion and the cause is still debated. The visible orange flames in that incident were the result of a mixture of hydrogen to oxygen combined with carbon compounds from the airship skin. H2 reacts with every oxidizing element, the ground state energy level of the electron in a hydrogen atom is −13.6 eV, which is equivalent to an ultraviolet photon of roughly 91 nm wavelength. The energy levels of hydrogen can be calculated fairly accurately using the Bohr model of the atom, however, the atomic electron and proton are held together by electromagnetic force, while planets and celestial objects are held by gravity. The most complicated treatments allow for the effects of special relativity
5.
Isotope
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Isotopes are variants of a particular chemical element which differ in neutron number. All isotopes of an element have the same number of protons in each atom. The number of protons within the nucleus is called atomic number and is equal to the number of electrons in the neutral atom. Each atomic number identifies a specific element, but not the isotope, the number of nucleons in the nucleus is the atoms mass number, and each isotope of a given element has a different mass number. For example, carbon-12, carbon-13 and carbon-14 are three isotopes of the element carbon with mass numbers 12,13 and 14 respectively. The atomic number of carbon is 6, which means that carbon atom has 6 protons. Nuclide refers to a rather than to an atom. Identical nuclei belong to one nuclide, for each nucleus of the carbon-13 nuclide is composed of 6 protons and 7 neutrons. The nuclide concept emphasizes nuclear properties over chemical properties, whereas the isotope concept emphasizes chemical over nuclear, the neutron number has large effects on nuclear properties, but its effect on chemical properties is negligible for most elements. Because isotope is the term, it is better known than nuclide. An isotope and/or nuclide is specified by the name of the particular element followed by a hyphen, when a chemical symbol is used, e. g. C for carbon, standard notation is to indicate the number with a superscript at the upper left of the chemical symbol. Because the atomic number is given by the element symbol, it is common to only the mass number in the superscript. The letter m is sometimes appended after the number to indicate a nuclear isomer. For example, 14C is a form of carbon, whereas 12C. There are about 339 naturally occurring nuclides on Earth, of which 286 are primordial nuclides, primordial nuclides include 32 nuclides with very long half-lives and 254 that are formally considered as stable nuclides, because they have not been observed to decay. In most cases, for reasons, if an element has stable isotopes. Theory predicts that many apparently stable isotopes/nuclides are radioactive, with extremely long half-lives, of the 254 nuclides never observed to decay, only 90 of these are theoretically stable to all known forms of decay
6.
Electric charge
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Electric charge is the physical property of matter that causes it to experience a force when placed in an electromagnetic field. There are two types of charges, positive and negative. Like charges repel and unlike attract, an absence of net charge is referred to as neutral. An object is charged if it has an excess of electrons. The SI derived unit of charge is the coulomb. In electrical engineering, it is common to use the ampere-hour. The symbol Q often denotes charge, early knowledge of how charged substances interact is now called classical electrodynamics, and is still accurate for problems that dont require consideration of quantum effects. The electric charge is a conserved property of some subatomic particles. Electrically charged matter is influenced by, and produces, electromagnetic fields, the interaction between a moving charge and an electromagnetic field is the source of the electromagnetic force, which is one of the four fundamental forces. 602×10−19 coulombs. The proton has a charge of +e, and the electron has a charge of −e, the study of charged particles, and how their interactions are mediated by photons, is called quantum electrodynamics. Charge is the property of forms of matter that exhibit electrostatic attraction or repulsion in the presence of other matter. Electric charge is a property of many subatomic particles. The charges of free-standing particles are integer multiples of the charge e. Michael Faraday, in his electrolysis experiments, was the first to note the discrete nature of electric charge, robert Millikans oil drop experiment demonstrated this fact directly, and measured the elementary charge. By convention, the charge of an electron is −1, while that of a proton is +1, charged particles whose charges have the same sign repel one another, and particles whose charges have different signs attract. The charge of an antiparticle equals that of the corresponding particle, quarks have fractional charges of either −1/3 or +2/3, but free-standing quarks have never been observed. The electric charge of an object is the sum of the electric charges of the particles that make it up. An ion is an atom that has lost one or more electrons, giving it a net charge, or that has gained one or more electrons
7.
Hydron (chemistry)
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Unlike other ions, the hydron consists only of a bare atomic nucleus. The hydron is too reactive to occur in many liquids, even though it is sometimes visualized to do so by students of chemistry, a free hydron would react with a molecule of the liquid to form a more complicated cation. Examples are the ion in water-based acids, and H 2F+, the unstable cation of fluoroantimonic acid. For this reason, in such liquids including liquid acids, hydrons diffuse by contact from one complex cation to another, the hydrated form of the hydrogen cation, the hydronium ion H 3O+, is a key object of Arrhenius definition of acid. Other hydrated forms, the Zundel cation H 5O+2 which is formed from a proton, the hydron itself is crucial in more general Brønsted–Lowry acid–base theory, which extends the concept of acid–base chemistry beyond aqueous solutions. The negatively charged counterpart of the hydron is the anion, H−. Proton, having the symbol p or 1H+, is the +1 ion of protium. Deuteron, having the symbol 2H+ or D+, is the +1 ion of deuterium, 2H or D. Triton, having the symbol 3H+ or T+, is the +1 ion of tritium, other isotopes of hydrogen are too unstable to be relevant in chemistry. The name proton refers to isotopically pure 1H+, on the other hand, referring to the hydron as simply hydrogen ion is not recommended because hydrogen anions also exist. The term hydron was defined by IUPAC in 1988, traditionally, the term proton was and is used in place of hydron. The latter term is only used in the context where comparisons between the various isotopes of hydrogen is important. Otherwise, referring to hydrons as protons is still considered acceptable, the transfer of H+ in an acid-base reaction is usually referred to as proton transfer. Acid and bases are referred to as proton donors and acceptors correspondingly, however, although 99. 9844% of natural hydrogen nuclei are protons, the remainder are deuterons. Deprotonation Superacid Dihydrogen cation Trihydrogen cation Hydrogen ion cluster
8.
Proton
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A proton is a subatomic particle, symbol p or p+, with a positive electric charge of +1e elementary charge and mass slightly less than that of a neutron. Protons and neutrons, each with masses of one atomic mass unit, are collectively referred to as nucleons. One or more protons are present in the nucleus of every atom, the number of protons in the nucleus is the defining property of an element, and is referred to as the atomic number. Since each element has a number of protons, each element has its own unique atomic number. The word proton is Greek for first, and this name was given to the nucleus by Ernest Rutherford in 1920. In previous years, Rutherford had discovered that the nucleus could be extracted from the nuclei of nitrogen by atomic collisions. Protons were therefore a candidate to be a particle, and hence a building block of nitrogen. In the modern Standard Model of particle physics, protons are hadrons, and like neutrons, although protons were originally considered fundamental or elementary particles, they are now known to be composed of three valence quarks, two up quarks and one down quark. The rest masses of quarks contribute only about 1% of a protons mass, the remainder of a protons mass is due to quantum chromodynamics binding energy, which includes the kinetic energy of the quarks and the energy of the gluon fields that bind the quarks together. At sufficiently low temperatures, free protons will bind to electrons, however, the character of such bound protons does not change, and they remain protons. A fast proton moving through matter will slow by interactions with electrons and nuclei, the result is a protonated atom, which is a chemical compound of hydrogen. In vacuum, when electrons are present, a sufficiently slow proton may pick up a single free electron, becoming a neutral hydrogen atom. Such free hydrogen atoms tend to react chemically with other types of atoms at sufficiently low energies. When free hydrogen atoms react with other, they form neutral hydrogen molecules. Protons are spin-½ fermions and are composed of three quarks, making them baryons. Protons have an exponentially decaying positive charge distribution with a mean square radius of about 0.8 fm. Protons and neutrons are both nucleons, which may be together by the nuclear force to form atomic nuclei. The nucleus of the most common isotope of the atom is a lone proton
9.
Hydrogen atom
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A hydrogen atom is an atom of the chemical element hydrogen. The electrically neutral atom contains a positively charged proton and a single negatively charged electron bound to the nucleus by the Coulomb force. Atomic hydrogen constitutes about 75% of the mass of the universe. In everyday life on Earth, isolated hydrogen atoms are extremely rare, instead, hydrogen tends to combine with other atoms in compounds, or with itself to form ordinary hydrogen gas, H2. Atomic hydrogen and hydrogen atom in ordinary English use have overlapping, yet distinct, for example, a water molecule contains two hydrogen atoms, but does not contain atomic hydrogen. Attempts to develop an understanding of the hydrogen atom have been important to the history of quantum mechanics. The most abundant isotope, hydrogen-1, protium, or light hydrogen, contains no neutrons and is just a proton, protium is stable and makes up 99. 9885% of naturally occurring hydrogen by absolute number. Deuterium contains one neutron and one proton, deuterium is stable and makes up 0. 0115% of naturally occurring hydrogen and is used in industrial processes like nuclear reactors and Nuclear Magnetic Resonance. Tritium contains two neutrons and one proton and is not stable, decaying with a half-life of 12.32 years, because of the short half life, Tritium does not exist in nature except in trace amounts. Higher isotopes of hydrogen are only created in artificial accelerators and reactors and have half lives around the order of 10−22 seconds, the formulas below are valid for all three isotopes of hydrogen, but slightly different values of the Rydberg constant must be used for each hydrogen isotope. Hydrogen is not found without its electron in ordinary chemistry, as ionized hydrogen is highly chemically reactive. When ionized hydrogen is written as H+ as in the solvation of classical acids such as hydrochloric acid, in that case, the acid transfers the proton to H2O to form H3O+. Ionized hydrogen without its electron, or free protons, are common in the interstellar medium, experiments by Ernest Rutherford in 1909 showed the structure of the atom to be a dense, positive nucleus with a light, negative charge orbiting around it. This immediately caused problems on how such a system could be stable, classical electromagnetism had shown that any accelerating charge radiates energy described through the Larmor formula. If this were true, all atoms would instantly collapse, however seem to be stable. Furthermore, the spiral inward would release a smear of electromagnetic frequencies as the orbit got smaller, instead, atoms were observed to only emit discrete frequencies of radiation. The resolution would lie in the development of quantum mechanics, in 1913, Niels Bohr obtained the energy levels and spectral frequencies of the hydrogen atom after making a number of simple assumptions in order to correct the failed classical model. The assumptions included, Electrons can only be in certain, discrete circular orbits or stationary states, thereby having a set of possible radii
10.
Deuterium
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Deuterium is one of two stable isotopes of hydrogen. The nucleus of deuterium, called a deuteron, contains one proton and one neutron, whereas the far more common hydrogen isotope, Deuterium has a natural abundance in Earths oceans of about one atom in 6420 of hydrogen. Thus deuterium accounts for approximately 0. 0156% of all the naturally occurring hydrogen in the oceans, the abundance of deuterium changes slightly from one kind of natural water to another. The deuterium isotopes name is formed from the Greek deuteros meaning second, Deuterium was discovered and named in 1931 by Harold Urey. When the neutron was discovered in 1932, this made the structure of deuterium obvious. Soon after deuteriums discovery, Urey and others produced samples of water in which the deuterium content had been highly concentrated. Deuterium is destroyed in the interiors of stars faster than it is produced, other natural processes are thought to produce only an insignificant amount of deuterium. Nearly all deuterium found in nature was produced in the Big Bang 13.8 billion years ago and this is the ratio found in the gas giant planets, such as Jupiter. However, other bodies are found to have different ratios of deuterium to hydrogen-1. This is thought to be as a result of natural isotope separation processes that occur from solar heating of ices in comets, like the water-cycle in Earths weather, such heating processes may enrich deuterium with respect to protium. The analysis of ratios in comets found results very similar to the mean ratio in Earths oceans. This reinforces theories that much of Earths ocean water is of cometary origin, the deuterium/protium ratio of the comet 67P/Churyumov-Gerasimenko, as measured by the Rosetta space probe, is about three times that of earth water. This figure is the highest yet measured in a comet, deuterium/protium ratios thus continue to be an active topic of research in both astronomy and climatology. Deuterium is frequently represented by the chemical symbol D, since it is an isotope of hydrogen with mass number 2, it is also represented by 2H. IUPAC allows both D and 2H, although 2H is preferred, a distinct chemical symbol is used for convenience because of the isotopes common use in various scientific processes. In quantum mechanics the energy levels of electrons in atoms depend on the mass of the system of electron. For hydrogen, this amount is about 1837/1836, or 1.000545, the energies of spectroscopic lines for deuterium and light-hydrogen therefore differ by the ratios of these two numbers, which is 1.000272. The wavelengths of all deuterium spectroscopic lines are shorter than the lines of light hydrogen
