1.
Hydrothermal synthesis
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Hydrothermal synthesis includes the various techniques of crystallizing substances from high-temperature aqueous solutions at high vapor pressures, also termed hydrothermal method. The term hydrothermal is of geologic origin, geochemists and mineralogists have studied hydrothermal phase equilibria since the beginning of the twentieth century. The crystal growth is performed in an apparatus consisting of a pressure vessel called an autoclave. A temperature gradient is maintained between the ends of the growth chamber. At the hotter end the nutrient solute dissolves, while at the end it is deposited on a seed crystal. Advantages of the method over other types of crystal growth include the ability to create crystalline phases which are not stable at the melting point. Also, materials which have a vapour pressure near their melting points can be grown by the hydrothermal method. The method is particularly suitable for the growth of large good-quality crystals while maintaining control over their composition. Disadvantages of the include the need of expensive autoclaves. The first report of the growth of crystals was by German geologist Karl Emil von Schafhäutl in 1845. In 1848, Robert Bunsen reported growing crystals of barium and strontium carbonate at 200 °C and at pressures of 15 atmospheres, using sealed glass tubes, in 1849 and 1851, French crystallographer Henri Hureau de Sénarmont produced crystals of various minerals via hydrothermal synthesis. Later Giorgio Spezia published reports on the growth of macroscopic crystals and he used solutions of sodium silicate, natural crystals as seeds and supply, and a silver-lined vessel. By heating the supply end of his vessel to 320-350 °C, unlike modern practice, the hotter part of the vessel was at the top. C. Walker and Ernie Buehler in 1950 at Bell Laboratories, other notable contributions have been made by Nacken, Hale, Brown, and Kohman. Hydrothermal synthesis is used to grow synthetic quartz, gems. Some of the crystals that have been grown are emeralds, rubies, quartz, alexandrite. The crystallization vessels used are autoclaves and these are usually thick-walled steel cylinders with a hermetic seal which must withstand high temperatures and pressures for prolonged periods of time. Furthermore, the material must be inert with respect to the solvent
2.
Ancient Greek
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Ancient Greek includes the forms of Greek used in ancient Greece and the ancient world from around the 9th century BC to the 6th century AD. It is often divided into the Archaic period, Classical period. It is antedated in the second millennium BC by Mycenaean Greek, the language of the Hellenistic phase is known as Koine. Koine is regarded as a historical stage of its own, although in its earliest form it closely resembled Attic Greek. Prior to the Koine period, Greek of the classic and earlier periods included several regional dialects, Ancient Greek was the language of Homer and of fifth-century Athenian historians, playwrights, and philosophers. It has contributed many words to English vocabulary and has been a subject of study in educational institutions of the Western world since the Renaissance. This article primarily contains information about the Epic and Classical phases of the language, Ancient Greek was a pluricentric language, divided into many dialects. The main dialect groups are Attic and Ionic, Aeolic, Arcadocypriot, some dialects are found in standardized literary forms used in literature, while others are attested only in inscriptions. There are also several historical forms, homeric Greek is a literary form of Archaic Greek used in the epic poems, the Iliad and Odyssey, and in later poems by other authors. Homeric Greek had significant differences in grammar and pronunciation from Classical Attic, the origins, early form and development of the Hellenic language family are not well understood because of a lack of contemporaneous evidence. Several theories exist about what Hellenic dialect groups may have existed between the divergence of early Greek-like speech from the common Proto-Indo-European language and the Classical period and they have the same general outline, but differ in some of the detail. The invasion would not be Dorian unless the invaders had some relationship to the historical Dorians. The invasion is known to have displaced population to the later Attic-Ionic regions, the Greeks of this period believed there were three major divisions of all Greek people—Dorians, Aeolians, and Ionians, each with their own defining and distinctive dialects. Often non-west is called East Greek, Arcadocypriot apparently descended more closely from the Mycenaean Greek of the Bronze Age. Boeotian had come under a strong Northwest Greek influence, and can in some respects be considered a transitional dialect, thessalian likewise had come under Northwest Greek influence, though to a lesser degree. Most of the dialect sub-groups listed above had further subdivisions, generally equivalent to a city-state and its surrounding territory, Doric notably had several intermediate divisions as well, into Island Doric, Southern Peloponnesus Doric, and Northern Peloponnesus Doric. The Lesbian dialect was Aeolic Greek and this dialect slowly replaced most of the older dialects, although Doric dialect has survived in the Tsakonian language, which is spoken in the region of modern Sparta. Doric has also passed down its aorist terminations into most verbs of Demotic Greek, by about the 6th century AD, the Koine had slowly metamorphosized into Medieval Greek
3.
Crust (geology)
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In geology, the crust is the outermost solid shell of a rocky planet or natural satellite, which is chemically distinct from the underlying mantle. The crust of the Earth is composed of a variety of igneous, metamorphic. The crust is underlain by the mantle, the upper part of the mantle is composed mostly of peridotite, a rock denser than rocks common in the overlying crust. The boundary between the crust and mantle is conventionally placed at the Mohorovičić discontinuity, a boundary defined by a contrast in seismic velocity, the crust occupies less than 1% of Earths volume. The crust of the Earth is of two types, oceanic and continental. The oceanic crust is 5 km to 10 km thick and is composed primarily of basalt, diabase, the continental crust is typically from 30 km to 50 km thick and is mostly composed of slightly less dense rocks than those of the oceanic crust. Some of these less dense rocks, such as granite, are common in the continental crust, both the continental and oceanic crust float on the mantle. Because the continental crust is thicker, it both to greater elevations and greater depth than the oceanic crust. The slightly lower density of continental rock compared to basaltic oceanic rock contributes to the higher relative elevation of the top of the continental crust. As the top of the continental crust reaches elevations higher than that of the oceanic, the temperature of the crust increases with depth, reaching values typically in the range from about 200 °C to 400 °C at the boundary with the underlying mantle. The crust and underlying relatively rigid uppermost mantle make up the lithosphere, because of convection in the underlying plastic upper mantle and asthenosphere, the lithosphere is broken into tectonic plates that move. The temperature increases by as much as 30 °C for every kilometer locally in the part of the crust. Earth has probably always had some form of basaltic crust, in contrast, the bulk of the continental crust is much older. The oldest continental crustal rocks on Earth have ages in the range from about 3.7 to 4, some zircon with age as great as 4.3 billion years has been found in the Narryer Gneiss Terrane. The average age of the current Earths continental crust has been estimated to be about 2.0 billion years, most crustal rocks formed before 2.5 billion years ago are located in cratons. Such old continental crust and the underlying mantle asthenosphere are less dense than elsewhere in Earth, formation of new continental crust is linked to periods of intense orogeny, these periods coincide with the formation of the supercontinents such as Rodinia, Pangaea and Gondwana. The continental crust has a composition similar to that of andesite. The most abundant minerals in Earths continental crust are feldspars, which make up about 41% of the crust by weight, followed by quartz at 12%, Continental crust is enriched in incompatible elements compared to the basaltic ocean crust and much enriched compared to the underlying mantle
4.
Volcano
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A volcano is a rupture in the crust of a planetary-mass object, such as Earth, that allows hot lava, volcanic ash, and gases to escape from a magma chamber below the surface. Earths volcanoes occur because its crust is broken into 17 major, therefore, on Earth, volcanoes are generally found where tectonic plates are diverging or converging. This type of volcanism falls under the umbrella of plate hypothesis volcanism, Volcanism away from plate boundaries has also been explained as mantle plumes. These so-called hotspots, for example Hawaii, are postulated to arise from upwelling diapirs with magma from the boundary,3,000 km deep in the Earth. Volcanoes are usually not created where two plates slide past one another. Erupting volcanoes can pose hazards, not only in the immediate vicinity of the eruption. Historically, so-called volcanic winters have caused catastrophic famines, the word volcano is derived from the name of Vulcano, a volcanic island in the Aeolian Islands of Italy whose name in turn comes from Vulcan, the god of fire in Roman mythology. The study of volcanoes is called volcanology, sometimes spelled vulcanology, at the mid-oceanic ridges, two tectonic plates diverge from one another as new oceanic crust is formed by the cooling and solidifying of hot molten rock. Most divergent plate boundaries are at the bottom of the oceans, therefore, most volcanic activity is submarine, black smokers are evidence of this kind of volcanic activity. Where the mid-oceanic ridge is above sea-level, volcanic islands are formed, for example, subduction zones are places where two plates, usually an oceanic plate and a continental plate, collide. In this case, the plate subducts, or submerges under the continental plate forming a deep ocean trench just offshore. In a process called flux melting, water released from the subducting plate lowers the temperature of the overlying mantle wedge. This magma tends to be very viscous due to its high content, so it often does not reach the surface. When it does reach the surface, a volcano is formed, typical examples of this kind of volcano are Mount Etna and the volcanoes in the Pacific Ring of Fire. Because tectonic plates move across them, each volcano becomes dormant and is eventually re-formed as the plate advances over the postulated plume and this theory is currently under criticism, however. The most common perception of a volcano is of a mountain, spewing lava and poisonous gases from a crater at its summit, however. The features of volcanoes are more complicated and their structure. Some volcanoes have rugged peaks formed by lava domes rather than a summit crater while others have features such as massive plateaus
5.
Granite
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Granite is a common type of felsic intrusive igneous rock that is granular and phaneritic in texture. Granites can be white, pink, or gray in color. The word granite comes from the Latin granum, a grain, in reference to the structure of such a holocrystalline rock. By definition, granite is a rock with at least 20% quartz. The term granitic means granite-like and is applied to granite and a group of igneous rocks with similar textures and slight variations in composition. Occasionally some individual crystals are larger than the groundmass, in case the texture is known as porphyritic. A granitic rock with a texture is known as a granite porphyry. Granitoid is a general, descriptive field term for lighter-colored, coarse-grained igneous rocks, petrographic examination is required for identification of specific types of granitoids. The extrusive igneous rock equivalent of granite is rhyolite, Granite is nearly always massive, hard and tough, and therefore it has gained widespread use throughout human history, and more recently as a construction stone. The average density of granite is between 2.65 and 2.75 g/cm3, its compressive strength usually lies above 200 MPa, and its viscosity near STP is 3–6 •1019 Pa·s. The melting temperature of dry granite at ambient pressure is 1215–1260 °C, it is reduced in the presence of water. Granite has poor primary permeability, but strong secondary permeability, true granite according to modern petrologic convention contains both plagioclase and alkali feldspars. When a granitoid is devoid or nearly devoid of plagioclase, the rock is referred to as alkali feldspar granite, when a granitoid contains less than 10% orthoclase, it is called tonalite, pyroxene and amphibole are common in tonalite. A granite containing both muscovite and biotite micas is called a binary or two-mica granite, two-mica granites are typically high in potassium and low in plagioclase, and are usually S-type granites or A-type granites. A worldwide average of the composition of granite, by weight percent, based on 2485 analyses. Much of it was intruded during the Precambrian age, it is the most abundant basement rock that underlies the relatively thin veneer of the continents. Outcrops of granite tend to form tors and rounded massifs, granites sometimes occur in circular depressions surrounded by a range of hills, formed by the metamorphic aureole or hornfels. Granite often occurs as small, less than 100 km² stock masses
6.
Orogeny
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An Orogeny is an event that leads to a large structural deformation of the Earths lithosphere due to the interaction between tectonic plates. Orogens or orogenic belts develop when a plate is crumpled and is pushed upwards to form mountain ranges. Orogeny is the mechanism by which mountains are built on continents. The word orogeny comes from Ancient Greek, though it was used before him, the term was employed by the American geologist G. K. Gilbert in 1890 to describe the process of mountain building as distinguished from epeirogeny. Formation of an orogen is accomplished in part by the processes of subduction or convergence of two or more continents. Orogeny usually produces long arcuate structures, known as orogenic belts, generally, orogenic belts consist of long parallel strips of rock exhibiting similar characteristics along the length of the belt. Orogenic belts are associated with zones, which consume crust, produce volcanoes. Geologists attribute the arcuate structure to the rigidity of the descending plate and these island arcs may be added to a continent during an orogenic event. The processes of orogeny can take tens of millions of years, frequently, rock formations that undergo orogeny are severely deformed and undergo metamorphism. Orogenic processes may push deeply buried rocks to the surface, sea-bottom and near-shore material may cover some or all of the orogenic area. If the orogeny is due to two continents colliding, very high mountains can result, an orogenic event may be studied, as a tectonic structural event, as a geographical event, and as a chronological event. The foreland basin forms ahead of the orogen due mainly to loading and resulting flexure of the lithosphere by the mountain belt. The basin migrates with the front and early deposited foreland basin sediments become progressively involved in folding and thrusting. Sediments deposited in the basin are mainly derived from the erosion of the actively uplifting rocks of the mountain range. The fill of many such shows an change in time from deepwater marine through shallow water to continental sediments. Although orogeny involves plate tectonics, the tectonic forces result in a variety of associated phenomena, including magmatism, metamorphism, crustal melting, what exactly happens in a specific orogen depends upon the strength and rheology of the continental lithosphere, and how these properties change during orogenesis. In addition to orogeny, the orogen is subject to other processes, for example, the Caledonian Orogeny refers to the Silurian and Devonian events that resulted from the collision of Laurentia with Eastern Avalonia and other former fragments of Gondwana. The Caledonian Orogen resulted from events and various others that are part of its peculiar orogenic cycle
7.
Metamorphism
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Metamorphism is the change of minerals or geologic texture in pre-existing rocks, without the protolith melting into liquid magma. The change occurs primarily due to heat, pressure, and the introduction of chemically active fluids, the chemical components and crystal structures of the minerals making up the rock may change even though the rock remains a solid. Changes at or just beneath Earths surface due to weathering and/or diagenesis are not classified as metamorphism, Metamorphism typically occurs between diagenesis, and melting. Three types of metamorphism exist, contact, dynamic, and regional, Metamorphism produced with increasing pressure and temperature conditions is known as prograde metamorphism. Conversely, decreasing temperatures and pressure characterize retrograde metamorphism, Metamorphic rocks can change without melting. When pressure is applied, somewhat flattened grains that orient in the same direction have a stable configuration. The upper boundary of metamorphic conditions is related to the onset of melting processes in the rock, the maximum temperature for metamorphism is typically 700 –900 °C, depending on the pressure and on the composition of the rock. Migmatites are rocks formed at this limit, which contain pods. Since the 1980s it has recognized that rocks are rarely dry enough. Conditions producing widespread regionally metamorphosed rocks occur during an orogenic event, the collision of two continental plates or island arcs with continental plates produce the extreme compressional forces required for the metamorphic changes typical of regional metamorphism. These orogenic mountains are eroded, exposing the intensely deformed rocks typical of their cores. The conditions within the slab as it plunges toward the mantle in a subduction zone also produce regional metamorphic effects. The techniques of structural geology are used to unravel the collisional history, regional metamorphism can be described and classified into metamorphic facies or metamorphic zones of temperature/pressure conditions throughout the orogenic terrane. Contact metamorphism occurs typically around intrusive igneous rocks as a result of the increase caused by the intrusion of magma into cooler country rock. The area surrounding the intrusion where the contact metamorphism effects are present is called the metamorphic aureole, contact metamorphic rocks are usually known as hornfels. Rocks formed by contact metamorphism may not present signs of deformation and are often fine-grained. Contact metamorphism is greater adjacent to the intrusion and dissipates with distance from the contact, the size of the aureole depends on the heat of the intrusion, its size, and the temperature difference with the wall rocks. Dikes generally have small aureoles with minimal metamorphism whereas large ultramafic intrusions can have significantly thick, the metamorphic grade of an aureole is measured by the peak metamorphic mineral which forms in the aureole
8.
Ocean
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An ocean is a body of saline water that composes much of a planets hydrosphere. On Earth, an ocean is one of the major divisions of the World Ocean. These are, in descending order by area, the Pacific, Atlantic, Indian, Southern, the word sea is often used interchangeably with ocean in American English but, strictly speaking, a sea is a body of saline water partly or fully enclosed by land. The ocean contains 97% of Earths water, and oceanographers have stated that less than 5% of the World Ocean has been explored, the total volume is approximately 1.35 billion cubic kilometers with an average depth of nearly 3,700 meters. As the world ocean is the component of Earths hydrosphere, it is integral to all known life, forms part of the carbon cycle. The world ocean is the habitat of 230,000 known species, but because much of it is unexplored, the origin of Earths oceans remains unknown, oceans are thought to have formed in the Hadean period and may have been the impetus for the emergence of life. Extraterrestrial oceans may be composed of water or other elements and compounds, the only confirmed large stable bodies of extraterrestrial surface liquids are the lakes of Titan, although there is evidence for the existence of oceans elsewhere in the Solar System. Early in their histories, Mars and Venus are theorized to have had large water oceans. The Mars ocean hypothesis suggests that nearly a third of the surface of Mars was once covered by water, compounds such as salts and ammonia dissolved in water lower its freezing point so that water might exist in large quantities in extraterrestrial environments as brine or convecting ice. Unconfirmed oceans are speculated beneath the surface of many planets and natural satellites, notably. The Solar Systems giant planets are thought to have liquid atmospheric layers of yet to be confirmed compositions. Oceans may also exist on exoplanets and exomoons, including surface oceans of water within a circumstellar habitable zone. Ocean planets are a type of planet with a surface completely covered with liquid. The concept of Ōkeanós has an Indo-European connection, Greek Ōkeanós has been compared to the Vedic epithet ā-śáyāna-, predicated of the dragon Vṛtra-, who captured the cows/rivers. Related to this notion, the Okeanos is represented with a dragon-tail on some early Greek vases, though generally described as several separate oceans, these waters comprise one global, interconnected body of salt water sometimes referred to as the World Ocean or global ocean. This concept of a body of water with relatively free interchange among its parts is of fundamental importance to oceanography. The major oceanic divisions – listed below in descending order of area and volume – are defined in part by the continents, various archipelagos, Oceans are fringed by smaller, adjoining bodies of water such as seas, gulfs, bays, bights, and straits. The Mid-Oceanic Ridge of the World are connected and form the Ocean Ridge, the continuous mountain range is 65,000 km long, and the total length of the oceanic ridge system is 80,000 km long
9.
Mid-ocean ridge
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A mid-ocean ridge is an underwater mountain system formed by plate tectonics. It consists of various mountains linked in chains, typically having a known as a rift running along its spine. This type of mountain ridge is characteristic of what is known as an oceanic spreading center. The production of new results from mantle upwelling in response to plate spreading. The buoyant melt rises as magma at a linear weakness in the oceanic crust, a mid-ocean ridge demarcates the boundary between two tectonic plates, and consequently is termed a divergent plate boundary. Mid-ocean ridges are geologically active, with new magma constantly emerging onto the floor and into the crust at. The crystallized magma forms new crust of basalt and gabbro and they are formed by two oceanic plates moving away from each other. The rocks making up the crust below the seafloor are youngest along the axis of the ridge and age with increasing distance from that axis, new magma of basalt composition emerges at and near the axis because of decompression melting in the underlying Earths mantle. The oceanic crust is made up of much younger than the Earth itself. Most oceanic crust in the basins is less than 200 million years old. The crust is in a constant state of renewal at the ocean ridges, moving away from the mid-ocean ridge, ocean depth progressively increases, the greatest depths are in ocean trenches. As the oceanic crust moves away from the axis, the peridotite in the underlying mantle cools. The crust and the relatively rigid peridotite below it make up the oceanic lithosphere, by contrast, fast spreading ridges like the East Pacific Rise are narrow, sharp incisions surrounded by generally flat topography that slopes away from the ridge over many hundreds of miles. The overall shape of ridges results from Pratt isostacy, close to the ridge there is hot. As the oceanic plates cool, away from the axes, the oceanic mantle lithosphere thickens. Thus older seafloor is underlain by denser material and sits lower, there are two processes, ridge-push and slab pull, thought to be responsible for the spreading seen at mid-ocean ridges, and there is some uncertainty as to which is dominant. Ridge-push occurs when the bulk of the ridge pushes the rest of the tectonic plate away from the ridge. At the subduction zone, slab-pull comes into effect and this is simply the weight of the tectonic plate being subducted below the overlying plate dragging the rest of the plate along behind it
10.
Diffusion
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Diffusion is the net movement of molecules or atoms from a region of high concentration to a region of low concentration. This is also referred to as the movement of a substance down a concentration gradient, a gradient is the change in the value of a quantity with the change in another variable. The word diffusion derives from the Latin word, diffundere, which means to spread out, a distinguishing feature of diffusion is that it results in mixing or mass transport, without requiring bulk motion. Thus, diffusion should not be confused with convection, or advection, an example of a situation in which bulk flow and diffusion can be differentiated is the mechanism by which oxygen enters the body during external respiration. The lungs are located in the cavity, which expands as the first step in external respiration. This expansion leads to an increase in volume of the alveoli in the lungs and this creates a pressure gradient between the air outside the body and the alveoli. The air moves down the gradient through the airways of the lungs and into the alveoli until the pressure of the air. The air arriving in the alveoli has a concentration of oxygen than the “stale” air in the alveoli. The increase in oxygen concentration creates a concentration gradient for oxygen between the air in the alveoli and the blood in the capillaries that surround the alveoli, oxygen then moves by diffusion, down the concentration gradient, into the blood. The other consequence of the air arriving in alveoli is that the concentration of carbon dioxide in the alveoli decreases and this creates a concentration gradient for carbon dioxide to diffuse from the blood into the alveoli. The pumping action of the heart then transports the blood around the body, as the left ventricle of the heart contracts, the volume decreases, which increases the pressure in the ventricle. This creates a gradient between the heart and the capillaries, and blood moves through blood vessels by bulk flow. The concept of diffusion is widely used in, physics, chemistry, biology, sociology, economics, however, in each case, the object that is undergoing diffusion is “spreading out” from a point or location at which there is a higher concentration of that object. In the phenomenological approach, diffusion is the movement of a substance from a region of high concentration to a region of low concentration without bulk motion, according to Ficks laws, the diffusion flux is proportional to the negative gradient of concentrations. It goes from regions of higher concentration to regions of lower concentration, some time later, various generalizations of Ficks laws were developed in the frame of thermodynamics and non-equilibrium thermodynamics. From the atomistic point of view, diffusion is considered as a result of the walk of the diffusing particles. In molecular diffusion, the molecules are self-propelled by thermal energy. Random walk of small particles in suspension in a fluid was discovered in 1827 by Robert Brown, the theory of the Brownian motion and the atomistic backgrounds of diffusion were developed by Albert Einstein
