1.
Wax
–
Waxes are a diverse class of organic compounds that are hydrophobic, malleable solids near ambient temperatures. They include higher alkanes and lipids, typically with melting points above about 40 °C, waxes are insoluble in water but soluble in organic, nonpolar solvents. Natural waxes of different types are produced by plants and animals, waxes are organic compounds that characteristically consist of long alkyl chains. They may also include various groups such as fatty acids, primary and secondary long chain alcohols, unsaturated bonds, aromatics, amides, ketones. They frequently contain fatty acid esters as well, synthetic waxes are often long-chain hydrocarbons that lack functional groups. Waxes are synthesized by plants and animals. Those of animal origin typically consist of wax esters derived from a variety of carboxylic acids, in waxes of plant origin characteristic mixtures of unesterified hydrocarbons may predominate over esters. The composition depends not only on species, but also on location of the organism. The most commonly known animal wax is beeswax, but other insects secrete waxes, a major component of the beeswax used in constructing honeycombs is the ester myricyl palmitate which is an ester of triacontanol and palmitic acid. Its melting point is 62-65 °C, spermaceti occurs in large amounts in the head oil of the sperm whale. One of its constituents is cetyl palmitate, another ester of a fatty acid. Lanolin is a wax obtained from wool, consisting of esters of sterols, plants secrete waxes into and on the surface of their cuticles as a way to control evaporation, wettability and hydration. From the commercial perspective, the most important plant wax is carnauba wax, containing the ester myricyl cerotate, it has many applications, such as confectionery and other food coatings, car and furniture polish, floss coating, and surfboard wax. Other more specialized vegetable waxes include candelilla wax and ouricury wax, plant and animal based waxes or oils can undergo selective chemical modifications to produce waxes with more desirable properties than are available in the unmodified starting material. This approach has relied on green chemistry approaches including olefin metathesis and enzymatic reactions, although many natural waxes contain esters, paraffin waxes are hydrocarbons, mixtures of alkanes usually in a homologous series of chain lengths. These materials represent a significant fraction of petroleum and they are refined by vacuum distillation. Paraffin waxes are mixtures of saturated n- and iso- alkanes, naphthenes, a typical alkane paraffin wax chemical composition comprises hydrocarbons with the general formula CnH2n+2, such as Hentriacontane, C31H64. The degree of branching has an important influence on the properties, millions of tons of paraffin waxes are produced annually
2.
Relief
–
Relief is a sculptural technique where the sculpted elements remain attached to a solid background of the same material. The term relief is from the Latin verb relevo, to raise, to create a sculpture in relief is to give the impression that the sculpted material has been raised above the background plane. What is actually performed when a relief is cut in from a surface of stone or wood is a lowering of the field. The technique involves considerable chiselling away of the background, which is a time-consuming exercise. In other materials such as metal, clay, plaster stucco, ceramics or papier-mâché the form can be just added to or raised up from the background, and monumental bronze reliefs are made by casting. There are different degrees of relief depending on the degree of projection of the form from the field. There is also sunk relief, which was restricted to Ancient Egypt. However the distinction between high relief and low relief is the clearest and most important, and these two are generally the only used to discuss most work. Hyphens may or may not be used in all these terms, works in the technique are described as in relief, and, especially in monumental sculpture, the work itself is a relief. Reliefs are common throughout the world on the walls of buildings and a variety of settings. Relief is more suitable for depicting complicated subjects with figures and very active poses, such as battles. Most ancient architectural reliefs were painted, which helped to define forms in low relief. Rock reliefs are carved into solid rock in the open air. This type is found in cultures, in particular those of the Ancient Near East and Buddhist countries. A stele is a standing stone, many of these carry reliefs. The distinction between high and low relief is somewhat subjective, and the two are often combined in a single work. In particular, most later high reliefs contain sections in low relief, a low relief or bas-relief is a projecting image with a shallow overall depth, for example used on coins, on which all images are in low relief. Other versions distort depth much less and it is a technique which requires less work, and is therefore cheaper to produce, as less of the background needs to be removed in a carving, or less modelling is required
3.
Irish people
–
The Irish people are a nation and ethnic group native to the island of Ireland, who share a common Irish ancestry, identity and culture. Ireland has been inhabited for about 9,000 years according to archaeological studies, for most of Irelands recorded history, the Irish have been primarily a Gaelic people. Today, Ireland is made up of the Republic of Ireland, the people of Northern Ireland hold various national identities, including Irish, Northern Irish, British, or some combination thereof. The Irish have their own customs, language, music, dance, sports, cuisine, although Irish was their main language in the past, today the huge majority of Irish people speak English as their first language. Historically, the Irish nation was made up of kin groups or clans, there have been many notable Irish people throughout history. After Irelands conversion to Christianity, Irish missionaries and scholars exerted great influence on Western Europe, the 6th-century Irish monk and missionary Columbanus is regarded as one of the fathers of Europe, followed by saints Cillian and Fergal. The scientist Robert Boyle is considered the father of chemistry, famous Irish writers include Oscar Wilde, W. B. Yeats, George Bernard Shaw, Bram Stoker and James Joyce, notable Irish explorers include Brendan the Navigator, Robert McClure, Ernest Shackleton and Tom Crean. By some accounts, the first European child born in North America had Irish descent on both sides, many presidents of the United States have had some Irish ancestry. The population of Ireland is about 6.3 million, but it is estimated that 50 to 80 million people around the world have Irish forebears, historically, emigration from Ireland has been the result of conflict, famine and economic issues. People of Irish descent are mainly in English-speaking countries, especially the United Kingdom. There are also significant numbers in Argentina, Mexico and New Zealand, the United States has the most people of Irish descent, while in Australia those of Irish descent are a higher percentage of the population than in any other country. Many Icelanders have Irish and Scottish Gaelic forebears, in its summary of their article Who were the Celts. The National Museum Wales notes It is possible that genetic studies of ancient. However, early studies have, so far, tended to produce implausible conclusions from very small numbers of people and using outdated assumptions about linguistics, nineteenth century anthropology studied the physical characteristics of Irish people in minute detail. During the past 10,000 years of inhabitation, Ireland has witnessed some different peoples arrive on its shores, the ancient peoples of Ireland—such as the creators of the Céide Fields and Newgrange—are almost unknown. Neither their languages nor terms they used to describe themselves have survived, as late as the middle centuries of the 1st millennium the inhabitants of Ireland did not appear to have a collective name for themselves. Ireland itself was known by a number of different names, including Banba, Fódla, Ériu by the islanders, Iouerne and Hiverne to the Greeks, other Latin names for people from Ireland in Classic and Mediaeval sources include Attacotti and Gael
4.
Architect
–
An architect is someone who plans, designs, and reviews the construction of buildings. Etymologically, architect derives from the Latin architectus, which derives from the Greek, practical, technical, and academic requirements for becoming an architect vary by jurisdiction. The terms architect and architecture are used in the disciplines of landscape architecture, naval architecture. In most jurisdictions, the professional and commercial uses of the terms architect, throughout ancient and medieval history, most architectural design and construction was carried out by artisans—such as stone masons and carpenters, rising to the role of master builder. Until modern times, there was no distinction between architect and engineer. In Europe, the architect and engineer were primarily geographical variations that referred to the same person. It is suggested that various developments in technology and mathematics allowed the development of the gentleman architect. Paper was not used in Europe for drawing until the 15th century, pencils were used more often for drawing by 1600. The availability of both allowed pre-construction drawings to be made by professionals, until the 18th-century, buildings continued to be designed and set out by craftsmen with the exception of high-status projects. In most developed countries, only qualified people with appropriate license, certification, or registration with a relevant body, such licensure usually requires an accredited university degree, successful completion of exams, and a training period. To practice architecture implies the ability to independently of supervision. In many places, independent, non-licensed individuals may perform design services outside the professional restrictions, such design houses, in the architectural profession, technical and environmental knowledge, design and construction management, and an understanding of business are as important as design. However, design is the force throughout the project and beyond. An architect accepts a commission from a client, the commission might involve preparing feasibility reports, building audits, the design of a building or of several buildings, structures, and the spaces among them. The architect participates in developing the requirements the client wants in the building, throughout the project, the architect co-ordinates a design team. Structural, mechanical, and electrical engineers and other specialists, are hired by the client or the architect, the architect hired by a client is responsible for creating a design concept that meets the requirements of that client and provides a facility suitable to the required use. In that, the architect must meet with and question the client to ascertain all the requirements, often the full brief is not entirely clear at the beginning, entailing a degree of risk in the design undertaking. The architect may make proposals to the client which may rework the terms of the brief
5.
White House
–
The White House is the official residence and principal workplace of the President of the United States, located at 1600 Pennsylvania Avenue NW in Washington, D. C. It has been the residence of every U. S. president since John Adams in 1800, the term White House is often used to refer to actions of the president and his advisers, as in The White House announced that. The residence was designed by Irish-born architect James Hoban in the Neoclassical style, construction took place between 1792 and 1800 using Aquia Creek sandstone painted white. When Thomas Jefferson moved into the house in 1801, he added low colonnades on each wing that concealed stables and storage. In 1814, during the War of 1812, the mansion was set ablaze by the British Army in the Burning of Washington, destroying the interior, reconstruction began almost immediately, and President James Monroe moved into the partially reconstructed Executive Residence in October 1817. Exterior construction continued with the addition of the semi-circular South portico in 1824, because of crowding within the executive mansion itself, President Theodore Roosevelt had all work offices relocated to the newly constructed West Wing in 1901. Eight years later in 1909, President William Howard Taft expanded the West Wing and created the first Oval Office, in the main mansion, the third-floor attic was converted to living quarters in 1927 by augmenting the existing hip roof with long shed dormers. A newly constructed East Wing was used as an area for social events. East Wing alterations were completed in 1946, creating additional office space, by 1948, the houses load-bearing exterior walls and internal wood beams were found to be close to failure. Under Harry S. Truman, the rooms were completely dismantled. Once this work was completed, the rooms were rebuilt. The Executive Residence is made up of six stories—the Ground Floor, State Floor, Second Floor, the property is a National Heritage Site owned by the National Park Service and is part of the Presidents Park. In 2007, it was ranked second on the American Institute of Architects list of Americas Favorite Architecture, in May 1790, New York began construction of Government House for his official residence, but he never occupied it. The national capital moved to Philadelphia in December 1790, the July 1790 Residence Act named Philadelphia, Pennsylvania the temporary national capital for a 10-year period while the Federal City was under construction. The City of Philadelphia rented Robert Morriss city house at 190 High Street for Washingtons presidential residence, the first president occupied the Market Street mansion from November 1790 to March 1797, and altered it in ways that may have influenced the design of the White House. As part of an effort to have Philadelphia named the permanent national capital, Pennsylvania built a much grander presidential mansion several blocks away. President John Adams also occupied the Market Street mansion from March 1797 to May 1800, on Saturday, November 1,1800, he became the first president to occupy the White House. The Presidents House in Philadelphia became a hotel and was demolished in 1832, the Presidents House was a major feature of Pierre Charles LEnfants plan for the newly established federal city, Washington, D. C
6.
Washington, D.C.
–
Washington, D. C. formally the District of Columbia and commonly referred to as Washington, the District, or simply D. C. is the capital of the United States. The signing of the Residence Act on July 16,1790, Constitution provided for a federal district under the exclusive jurisdiction of the Congress and the District is therefore not a part of any state. The states of Maryland and Virginia each donated land to form the federal district, named in honor of President George Washington, the City of Washington was founded in 1791 to serve as the new national capital. In 1846, Congress returned the land ceded by Virginia, in 1871. Washington had an population of 681,170 as of July 2016. Commuters from the surrounding Maryland and Virginia suburbs raise the population to more than one million during the workweek. The Washington metropolitan area, of which the District is a part, has a population of over 6 million, the centers of all three branches of the federal government of the United States are in the District, including the Congress, President, and Supreme Court. Washington is home to national monuments and museums, which are primarily situated on or around the National Mall. The city hosts 176 foreign embassies as well as the headquarters of international organizations, trade unions, non-profit organizations, lobbying groups. A locally elected mayor and a 13‑member council have governed the District since 1973, However, the Congress maintains supreme authority over the city and may overturn local laws. D. C. residents elect a non-voting, at-large congressional delegate to the House of Representatives, the District receives three electoral votes in presidential elections as permitted by the Twenty-third Amendment to the United States Constitution, ratified in 1961. Various tribes of the Algonquian-speaking Piscataway people inhabited the lands around the Potomac River when Europeans first visited the area in the early 17th century, One group known as the Nacotchtank maintained settlements around the Anacostia River within the present-day District of Columbia. Conflicts with European colonists and neighboring tribes forced the relocation of the Piscataway people, some of whom established a new settlement in 1699 near Point of Rocks, Maryland. 43, published January 23,1788, James Madison argued that the new government would need authority over a national capital to provide for its own maintenance. Five years earlier, a band of unpaid soldiers besieged Congress while its members were meeting in Philadelphia, known as the Pennsylvania Mutiny of 1783, the event emphasized the need for the national government not to rely on any state for its own security. However, the Constitution does not specify a location for the capital, on July 9,1790, Congress passed the Residence Act, which approved the creation of a national capital on the Potomac River. The exact location was to be selected by President George Washington, formed from land donated by the states of Maryland and Virginia, the initial shape of the federal district was a square measuring 10 miles on each side, totaling 100 square miles. Two pre-existing settlements were included in the territory, the port of Georgetown, Maryland, founded in 1751, many of the stones are still standing
7.
Earl of Desart
–
Earl of Desart was a title in the Peerage of Ireland. It was created in 1793 for Otway Cuffe, 1st Viscount Desart and he had already succeeded his elder brother as third Baron Desart in 1767 and been created Viscount Desart, in the County of Kilkenny, in the Peerage of Ireland in 1781. He was also made Viscount Castlecuffe in the Peerage of Ireland at the time as he was granted the earldom. He later sat in the House of Lords between 1800 and 1804 as one of the 28 original Irish Representative Peers, lord Desart was the younger son of John Cuffe, who represented Thomastown in the Irish House of Commons between 1715 and 1727. In 1733 he was raised to the Peerage of Ireland as Baron Desart, the first Earl was succeeded by his son, the second Earl. He sat as Member of Parliament for Bossiney between 1809 and 1817, on his early death the titles passed to his son, the third Earl. He served as Under-Secretary of State for War and the Colonies between March and December 1852 in the Earl of Derbys first administration, in 1909 he was created Baron Desart, of Desart in the County of Kilkenny, in the Peerage of the United Kingdom. Lord Desart had no sons and on his death in 1934 all his titles became extinct and his daughter Lady Sybil Cuffe was the mother of the writer Iris Origo through her first husband William Bayard Cutting. The family seat was Desart Court, County Kilkenny, in the Republic of Ireland, the manor house itself was burnt down in the early 1920s as a result of an IRA attack. The title should not be confused with the title Earl of Dysart, created in the Peerage of Scotland
8.
Thomas Ivory (Irish architect)
–
Thomas Ivory was an Irish architect, one of the significant figures in the building of Georgian Dublin. He is often called Thomas Ivory of Cork, and is to be distinguished from his contemporary Thomas Ivory of Norwich, said to have been a carpenters apprentice self-educated, and from Cork, Ivory worked in Dublin under the gunsmith Thomas Trulock. He then studied under the draughtsman Jonas Blaymire, Ivory practised in Dublin, and was appointed master of architectural drawing in the schools of the Royal Dublin Society in 1759. He held the post till his death, and among his pupils were Henry Aaron Baker, James Hoban, Thomas Roberts was articled to him. Ivory died in Dublin in December 1786, in 1765 Ivory prepared designs and an estimate for additional buildings to the Royal Dublin Society premises in Shaws Court, but these were not executed. Ivorys major work was the Kings Hospital in Blackhall Place, in the classic style, the first stone was laid on 16 June 1773, but from want of money the central cupola was not finished. Ivory designed Lord Newcomens bank, built in 1781, at the corner of Castle Street and Cork Street, the Hibernian Marine School, often attributed to him, was more probably the work of Thomas Cooley. He made a drawing of the Casino at Marino, near Dublin, in the board-room of the Kings Hospital was a picture said to represent Ivory and eight others sitting at or standing round a table on which are spread plans of the new building. Attribution This article incorporates text from a now in the public domain, Lee, Sidney, ed. Ivory
9.
Duke of Leinster
–
Duke of Leinster is a title in the Peerage of Ireland and the premier dukedom in that peerage. The viscounty of Leinster is in the Peerage of Great Britain, the barony of Kildare in the Peerage of the United Kingdom, the courtesy title of the eldest son and heir of the Duke of Leinster is Marquess of Kildare. The family seat now is Oakley Park, near Abingdon, Oxfordshire and this branch of the Welsh-Norman FitzGerald dynasty, which came to Ireland in 1169, were initially created Earls of Kildare. The earldom was created in 1316 for John FitzGerald, Two senior FitzGeralds, Garret Mór FitzGerald and his son, Garret Óg FitzGerald served as Lords Deputy of Ireland. The tenth Earl, Thomas FitzGerald, known as Silken Thomas, was attainted, in 1554, Thomass half-brother and only male heir, Gerald FitzGerald, was created Earl of Kildare in the Peerage of Ireland. He was subsequently restored to the original Patent in 1569, as 11th earl, the second earldom became extinct in 1599, although the original earldom survived. The family was based in Maynooth Castle in Maynooth in County Kildare. In later centuries the family owned estates in Waterford with their country residence being a Georgian house called Carton House which had replaced the castle in County Kildare, in Dublin, the Earl built a large townhouse residence on the southside of Dublin called Kildare House. When the Earl was awarded a dukedom and became Duke of Leinster, one of its occupants was Lord Edward FitzGerald, who became an icon for Irish nationalism through his involvement with the Irish Rebellion of 1798, which ultimately cost him his life. Leinster House was sold by the Leinsters in 1815, in 1924 it bought the building for parliamentary use. It has remained the parliament house of the Irish state, the Dukes of Leinster had by the early 20th century lost all their property and wealth. Their Carton House seat was sold, as later on was their residence in Waterford. The family now live in a property in Ramsden, Oxfordshire. A controversial claim by the descendants of the 5th Duke was made and failed. Paul FitzGerald and his supporters claimed that Lord Desmond faked his death, instead, it was passed down through her fathers brothers family. It was alleged that an archivist had acknowledged the package had once existed, the Baron Falconer of Thoroton, Lord Chancellor, and Harriet Harman, Minister of State in the Department for Constitutional Affairs, gave due consideration to this claim. The claim was dismissed by Lord Falconer despite a 30-year campaign by Paul FitzGeralds family reputedly costing £1.3 million, the Lord Chancellor adjudicated that the title was to remain with the existing holder, the 9th Duke, Maurice FitzGerald. Paul FitzGerald has a right of appeal against the Lord Chancellors verdict by petitioning Her Majesty The Queen, in 2010, however, DNA evidence was presented that indicates that Paul FitzGerald is related to the wife of the 5th Duke, the former Lady Hermione Duncombe
10.
American Revolutionary War
–
From about 1765 the American Revolution had led to increasing philosophical and political differences between Great Britain and its American colonies. The war represented a culmination of these differences in armed conflict between Patriots and the authority which they increasingly resisted. This resistance became particularly widespread in the New England Colonies, especially in the Province of Massachusetts Bay. On December 16,1773, Massachusetts members of the Patriot group Sons of Liberty destroyed a shipment of tea in Boston Harbor in an event that became known as the Boston Tea Party. Named the Coercive Acts by Parliament, these became known as the Intolerable Acts in America. The Massachusetts colonists responded with the Suffolk Resolves, establishing a government that removed control of the province from the Crown outside of Boston. Twelve colonies formed a Continental Congress to coordinate their resistance, and established committees, British attempts to seize the munitions of Massachusetts colonists in April 1775 led to the first open combat between Crown forces and Massachusetts militia, the Battles of Lexington and Concord. Militia forces proceeded to besiege the British forces in Boston, forcing them to evacuate the city in March 1776, the Continental Congress appointed George Washington to take command of the militia. Concurrent to the Boston campaign, an American attempt to invade Quebec, on July 2,1776, the Continental Congress formally voted for independence, issuing its Declaration on July 4. Sir William Howe began a British counterattack, focussing on recapturing New York City, Howe outmaneuvered and defeated Washington, leaving American confidence at a low ebb. Washington captured a Hessian force at Trenton and drove the British out of New Jersey, in 1777 the British sent a new army under John Burgoyne to move south from Canada and to isolate the New England colonies. However, instead of assisting Burgoyne, Howe took his army on a campaign against the revolutionary capital of Philadelphia. Burgoyne outran his supplies, was surrounded and surrendered at Saratoga in October 1777, the British defeat in the Saratoga Campaign had drastic consequences. Giving up on the North, the British decided to salvage their former colonies in the South, British forces under Lieutenant-General Charles Cornwallis seized Georgia and South Carolina, capturing an American army at Charleston, South Carolina. British strategy depended upon an uprising of large numbers of armed Loyalists, in 1779 Spain joined the war as an ally of France under the Pacte de Famille, intending to capture Gibraltar and British colonies in the Caribbean. Britain declared war on the Dutch Republic in December 1780, in 1781, after the British and their allies had suffered two decisive defeats at Kings Mountain and Cowpens, Cornwallis retreated to Virginia, intending on evacuation. A decisive French naval victory in September deprived the British of an escape route, a joint Franco-American army led by Count Rochambeau and Washington, laid siege to the British forces at Yorktown. With no sign of relief and the situation untenable, Cornwallis surrendered in October 1781, Whigs in Britain had long opposed the pro-war Tory majority in Parliament, but the defeat at Yorktown gave the Whigs the upper hand
_HABS361451pv.jpg)
