In chemistry, Le Chatelier's principle is a principle used to predict the effect of a change in conditions on chemical equilibrium. Other names include Chatelier's principle, Braun–Le Chatelier princi
The reversible reaction 2NO2(g) ⇌ N2O4(g) is exothermic, so the equilibrium position can be shifted by changing the temperature. When heat is removed and the temperature decreases, the reaction shifts to the right and the flask turns colorless due to an increase in N2O4. This demonstrates Le Chatelier's principle: the equilibrium shifts in the direction that releases energy. When heat is added and the temperature increases, the reaction shifts to the left and the flask turns reddish brown due to an increase in NO