The Matterhorn is a mountain of the Alps, straddling the main watershed and border between Italy and Switzerland. It is a large, near-symmetric pyramidal peak in the extended Monte Rosa area of the Pennine Alps, whose summit is 4,478 metres (14,692 ft) above sea level, making it one of the highest summits in the Alps and Europe. The four steep faces, rising above the surrounding glaciers, face the four compass points and are split by the Hörnli, Furggen, Leone/Lion, and Zmutt ridges. The mountain overlooks the Swiss town of Zermatt, in the canton of Valais, to the northeast; and the Italian town of Breuil-Cervinia in the Aosta Valley to the south. Just east of the Matterhorn is Theodul Pass, the main passage between the two valleys on its north and south sides, which has been a trade route since the Roman Era.

The main chain of the Alps, also called the Alpine divide is the central line of mountains that forms the drainage divide of the range. Main chains of mountain ranges are traditionally designated in this way, and generally include the highest peaks of a range. The Alps are something of an unusual case in that several significant groups of mountains are separated from the main chain by sizable distances. Among these groups are the Dauphine Alps, the Eastern and Western Graians, the entire Bernese Alps, the Tödi, Albula and Silvretta groups, the Ortler and Adamello ranges, and the Dolomites of South Tyrol, as well as the lower Alps of Vorarlberg, Bavaria, and Salzburg.