1.
Melting
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Melting, or fusion, is a physical process that results in the phase transition of a substance from a solid to a liquid. This occurs when the energy of the solid increases, typically by the application of heat or pressure. At the melting point, the ordering of ions or molecules in the solid breaks down to an ordered state. Substances in the state generally have reduced viscosity as the temperature increases. An exception to this principle is the element sulfur, whose viscosity increases to a point due to polymerization, some organic compounds melt through mesophases, states of partial order between solid and liquid. Melting is therefore classified as a phase transition. Melting occurs when the Gibbs free energy of the liquid becomes lower than the solid for that material, the temperature at which this occurs is dependent on the ambient pressure. Low-temperature helium is the only exception to the general rule. Helium-3 has an enthalpy of fusion at temperatures below 0.3 K. Helium-4 also has a very slightly negative enthalpy of fusion below 0.8 K. This means that, at appropriate constant pressures, heat must be removed from these substances in order to melt them, among the theoretical criteria for melting, the Lindemann and of Born criteria are those most frequently used as a basis to analyse the melting conditions. The Lindemann melting criterion is supported by experimental data both for crystalline materials and for transitions in amorphous materials. The Born criterion is based on rigidity catastrophe caused by the elastic shear modulus. Under a standard set of conditions, the point of a substance is a characteristic property. The melting point is equal to the freezing point. However, under carefully created conditions, supercooling or superheating past the melting or freezing point can occur, water on a very clean glass surface will often supercool several degrees below the freezing point without freezing. Fine emulsions of pure water have been cooled to −38 degrees Celsius without nucleation to form ice, nucleation occurs due to fluctuations in the properties of the material. If the material is still there is often nothing to trigger this change. Thermodynamically, the liquid is in the metastable state with respect to the crystalline phase
2.
Freezing
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Freezing, or solidification, is a phase transition in which a liquid turns into a solid when its temperature is lowered below its freezing point. For most substances, the melting and freezing points are the temperature, however. For example, agar displays a hysteresis in its melting point and it melts at 85 °C and solidifies from 32 °C to 40 °C. Most liquids freeze by crystallization, formation of crystalline solid from the uniform liquid, because of the latent heat of fusion, the freezing is greatly slowed down and the temperature will not drop anymore once the freezing starts but will continue dropping once it finishes. Crystallization consists of two events, nucleation and crystal growth. Nucleation is the step wherein the molecules start to gather into clusters, on the scale, arranging in a defined. The crystal growth is the subsequent growth of the nuclei that succeed in achieving the critical cluster size, in spite of the second law of thermodynamics, crystallization of pure liquids usually begins at a lower temperature than the melting point, due to high activation energy of homogeneous nucleation. The creation of a nucleus implies the formation of an interface at the boundaries of the new phase, some energy is expended to form this interface, based on the surface energy of each phase. If a hypothetical nucleus is too small, the energy that would be released by forming its volume is not enough to create its surface, Freezing does not start until the temperature is low enough to provide enough energy to form stable nuclei. Under high pressure water will super cool to as low as −70 °C before freezing, Freezing is almost always an exothermic process, meaning that as liquid changes into solid, heat and pressure is released. This is often seen as counter-intuitive, since the temperature of the material does not rise during freezing, but this can be understood, since heat must be continually removed from the freezing liquid or the freezing process will stop. The energy released upon freezing is a latent heat, and is known as the enthalpy of fusion and is exactly the same as the required to melt the same amount of the solid. Low-temperature helium is the only exception to the general rule. Helium-3 has an enthalpy of fusion at temperatures below 0.3 K. Helium-4 also has a very slightly negative enthalpy of fusion below 0.8 K. This means that, at appropriate constant pressures, heat must be added to these substances in order to freeze them, certain materials, such as glass and glycerol, may harden without crystallizing, these are called amorphous solids. Amorphous materials as well as some polymers do not have a freezing point, instead, there is a gradual change in their viscoelastic properties over a range of temperatures. Such materials are characterized by a transition that occurs at a glass transition temperature. Because vitrification is a process, it does not qualify as freezing
3.
Crystallization
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Crystallization is the process where a solid forms where the atoms or molecules are highly organized in a structure known as a crystal. Some of the ways which crystals form are through precipitating from a solution, crystallization is also a chemical solid–liquid separation technique, in which mass transfer of a solute from the liquid solution to a pure solid crystalline phase occurs. In chemical engineering crystallization occurs in a crystallizer, crystallization is therefore related to precipitation, although the result is not amorphous or disordered, but a crystal. The crystallization process consists of two events, nucleation and crystal growth which are driven by thermodynamic properties as well as chemical properties. These stable clusters constitute the nuclei, therefore, the clusters need to reach a critical size in order to become stable nuclei. Such critical size is dictated by different factors. The crystal growth is the subsequent size increase of the nuclei that succeed in achieving the critical cluster size, crystal growth is a dynamic process occurring in equilibrium where solute molecules or atoms precipitate out of solution, and dissolve back into solution. Supersaturation is one of the forces of crystallization, as the solubility of a species is an equilibrium process quantified by Ksp. Depending upon the conditions, either nucleation or growth may be predominant over the other, many compounds have the ability to crystallize with some having different crystal structures, a phenomenon called polymorphism. Each polymorph is in fact a different thermodynamic solid state and crystal polymorphs of the compound exhibit different physical properties, such as dissolution rate, shape, melting point. For this reason, polymorphism is of importance in industrial manufacture of crystalline products. Additionally, crystal phases can sometimes be interconverted by varying factors such as temperature, there are many examples of natural process that involve crystallization. Geological time scale process examples include, Natural crystal formation, Stalactite/stalagmite, usual time scale process examples include, Snow flakes formation, Honey crystallization. Crystal formation can be divided into two types, where the first type of crystals are composed of a cation and anion, also known as a salt, the second type of crystals are composed of uncharged species, for example menthol. The formation of a solution does not guarantee crystal formation. A typical laboratory technique for crystal formation is to dissolve the solid in a solution in which it is partially soluble, the hot mixture is then filtered to remove any insoluble impurities. The filtrate is allowed to slowly cool, crystals that form are then filtered and washed with a solvent in which they are not soluble, but is miscible with the mother liquor. The process is repeated to increase the purity in a technique known as recrystallization
4.
State of matter
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In physics, a state of matter is one of the distinct forms that matter takes on. Four states of matter are observable in everyday life, solid, liquid, gas, some other states are believed to be possible but remain theoretical for now. For a complete list of all states of matter, see the list of states of matter. Historically, the distinction is based on qualitative differences in properties. Matter in the state maintains a fixed volume and shape, with component particles close together. Matter in the state maintains a fixed volume, but has a variable shape that adapts to fit its container. Its particles are close together but move freely. Matter in the state has both variable volume and shape, adapting both to fit its container. Its particles are close together nor fixed in place. Matter in the state has variable volume and shape, but as well as neutral atoms, it contains a significant number of ions and electrons. Plasma is the most common form of matter in the universe. The term phase is used as a synonym for state of matter. In a solid the particles are packed together. The forces between particles are strong so that the particles move freely but can only vibrate. As a result, a solid has a stable, definite shape, solids can only change their shape by force, as when broken or cut. In crystalline solids, the particles are packed in a regularly ordered, there are various different crystal structures, and the same substance can have more than one structure. For example, iron has a cubic structure at temperatures below 912 °C. Ice has fifteen known crystal structures, or fifteen solid phases, glasses and other non-crystalline, amorphous solids without long-range order are not thermal equilibrium ground states, therefore they are described below as nonclassical states of matter
5.
Solid
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Solid is one of the four fundamental states of matter. It is characterized by structural rigidity and resistance to changes of shape or volume, unlike a liquid, a solid object does not flow to take on the shape of its container, nor does it expand to fill the entire volume available to it like a gas does. The atoms in a solid are tightly bound to other, either in a regular geometric lattice or irregularly. The branch of physics deals with solids is called solid-state physics. Materials science is concerned with the physical and chemical properties of solids. Solid-state chemistry is concerned with the synthesis of novel materials, as well as the science of identification. The atoms, molecules or ions which make up solids may be arranged in a repeating pattern. Materials whose constituents are arranged in a regular pattern are known as crystals, in some cases, the regular ordering can continue unbroken over a large scale, for example diamonds, where each diamond is a single crystal. Almost all common metals, and many ceramics, are polycrystalline, in other materials, there is no long-range order in the position of the atoms. These solids are known as amorphous solids, examples include polystyrene, whether a solid is crystalline or amorphous depends on the material involved, and the conditions in which it was formed. Solids which are formed by slow cooling will tend to be crystalline, likewise, the specific crystal structure adopted by a crystalline solid depends on the material involved and on how it was formed. While many common objects, such as an ice cube or a coin, are chemically identical throughout, for example, a typical rock is an aggregate of several different minerals and mineraloids, with no specific chemical composition. Wood is an organic material consisting primarily of cellulose fibers embedded in a matrix of organic lignin. In materials science, composites of more than one constituent material can be designed to have desired properties, the forces between the atoms in a solid can take a variety of forms. For example, a crystal of sodium chloride is made up of sodium and chlorine. In diamond or silicon, the atoms share electrons and form covalent bonds, in metals, electrons are shared in metallic bonding. Some solids, particularly most organic compounds, are together with van der Waals forces resulting from the polarization of the electronic charge cloud on each molecule. The dissimilarities between the types of solid result from the differences between their bonding, metals typically are strong, dense, and good conductors of both electricity and heat
6.
Liquid
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A liquid is a nearly incompressible fluid that conforms to the shape of its container but retains a constant volume independent of pressure. As such, it is one of the four states of matter. A liquid is made up of tiny vibrating particles of matter, such as atoms, water is, by far, the most common liquid on Earth. Like a gas, a liquid is able to flow and take the shape of a container, most liquids resist compression, although others can be compressed. Unlike a gas, a liquid does not disperse to fill every space of a container, a distinctive property of the liquid state is surface tension, leading to wetting phenomena. The density of a liquid is usually close to that of a solid, therefore, liquid and solid are both termed condensed matter. On the other hand, as liquids and gases share the ability to flow, although liquid water is abundant on Earth, this state of matter is actually the least common in the known universe, because liquids require a relatively narrow temperature/pressure range to exist. Most known matter in the universe is in form as interstellar clouds or in plasma form within stars. Liquid is one of the four states of matter, with the others being solid, gas. Unlike a solid, the molecules in a liquid have a greater freedom to move. The forces that bind the molecules together in a solid are only temporary in a liquid, a liquid, like a gas, displays the properties of a fluid. A liquid can flow, assume the shape of a container, if liquid is placed in a bag, it can be squeezed into any shape. These properties make a suitable for applications such as hydraulics. Liquid particles are bound firmly but not rigidly and they are able to move around one another freely, resulting in a limited degree of particle mobility. As the temperature increases, the vibrations of the molecules causes distances between the molecules to increase. When a liquid reaches its point, the cohesive forces that bind the molecules closely together break. If the temperature is decreased, the distances between the molecules become smaller, only two elements are liquid at standard conditions for temperature and pressure, mercury and bromine. Four more elements have melting points slightly above room temperature, francium, caesium, gallium and rubidium, metal alloys that are liquid at room temperature include NaK, a sodium-potassium metal alloy, galinstan, a fusible alloy liquid, and some amalgams
7.
Supercooling
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Supercooling, also known as undercooling, is the process of lowering the temperature of a liquid or a gas below its freezing point without it becoming a solid. A liquid crossing its standard freezing point will crystalize in the presence of a crystal or nucleus around which a crystal structure can form creating a solid. Lacking any such nuclei, the phase can be maintained all the way down to the temperature at which crystal homogeneous nucleation occurs. Homogeneous nucleation can occur above the transition temperature, but if homogeneous nucleation has not occurred above that temperature. Water normally freezes at 273.15 K, but it can be supercooled at standard pressure down to its homogeneous nucleation at almost 224.8 K. If water is cooled at a rate on the order of 106 K/s, the crystal nucleation can be avoided and water becomes a glass — that is and its glass transition temperature is much colder and harder to determine, but studies estimate it at about 136 K. Glassy water can be heated up to approximately 150 K without nucleation occurring, in the range of temperatures between 231 K and 150 K, experiments find only crystal ice. Droplets of supercooled water often exist in stratiform and cumulus clouds, Freezing rain is also caused by supercooled droplets. The process opposite to supercooling, the melting of a solid above the point, is much more difficult. It is possible, at a pressure, to superheat a liquid above its boiling point without it becoming gaseous. Supercooling is often confused with freezing-point depression, supercooling is the cooling of a liquid below its freezing point without it becoming solid. Constitutional supercooling, which occurs during solidification, is due to compositional solid changes, when solidifying a liquid, the interface is often unstable, and the velocity of the solid–liquid interface must be small in order to avoid constitutional supercooling. Supercooled zones are observed when the temperature gradient at the interface is larger than the temperature gradient. Therefore, the thermal gradient necessary to create a stable solid front is as expressed below. ∂ T ∂ x < m C0 v k D For more information, the authors are confusing supercooling with freezing-point depression. The paragraphs above warn about this confusion, in order to survive extreme low temperatures in certain environments, some animals undergo forms of supercooling that allow them to remain unfrozen and avoid cell damage and death. The winter flounder is one fish that utilizes these proteins to survive in its frigid environment. Noncolligative proteins are secreted by the liver into the bloodstream, other animals use colligative antifreezes, which increases the concentration of solutes in their bodily fluids, thus lowering their freezing point
8.
Carboxylic acid
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A carboxylic acid /ˌkɑːrbɒkˈsɪlɪk/ is an organic compound that contains a carboxyl group. The general formula of an acid is R–COOH, with R referring to the rest of the molecule. Carboxylic acids occur widely and include the amino acids and acetic acid, salts and esters of carboxylic acids are called carboxylates. When a carboxyl group is deprotonated, its conjugate base forms a carboxylate anion, carboxylate ions are resonance-stabilized, and this increased stability makes carboxylic acids more acidic than alcohols. Carboxylic acids can be seen as reduced or alkylated forms of the Lewis acid carbon dioxide, carboxylic acids are commonly identified using their trivial names, and usually have the suffix -ic acid. IUPAC-recommended names also exist, in system, carboxylic acids have an -oic acid suffix. For example, butyric acid is butanoic acid by IUPAC guidelines, the -oic acid nomenclature detail is based on the name of the previously-known chemical benzoic acid. Alternately, it can be named as a carboxy or carboxylic acid substituent on another parent structure, for example, 2-carboxyfuran. The carboxylate anion of an acid is usually named with the suffix -ate, in keeping with the general pattern of -ic acid and -ate for a conjugate acid and its conjugate base. For example, the base of acetic acid is acetate. The radical •COOH has only a fleeting existence. The acid dissociation constant of •COOH has been measured using electron paramagnetic resonance spectroscopy, the carboxyl group tends to dimerise to form oxalic acid. Because they are both hydrogen-bond acceptors and hydrogen-bond donors, they participate in hydrogen bonding. Together the hydroxyl and carbonyl group forms the functional group carboxyl, carboxylic acids usually exist as dimeric pairs in nonpolar media due to their tendency to self-associate. Smaller carboxylic acids are soluble in water, whereas higher carboxylic acids are less due to the increasing hydrophobic nature of the alkyl chain. These longer chain acids tend to be soluble in less-polar solvents such as ethers. Carboxylic acids tend to have higher boiling points than water, not only because of their surface area. Carboxylic acids tend to evaporate or boil as these dimers, for boiling to occur, either the dimer bonds must be broken or the entire dimer arrangement must be vaporised, both of which increase the enthalpy of vaporization requirements significantly
9.
Mercury (element)
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Mercury is a chemical element with symbol Hg and atomic number 80. It is commonly known as quicksilver and was formerly named hydrargyrum, Mercury occurs in deposits throughout the world mostly as cinnabar. The red pigment vermilion is obtained by grinding natural cinnabar or synthetic mercuric sulfide, likewise, mechanical pressure gauges and electronic strain gauge sensors have replaced mercury sphygmomanometers. Mercury remains in use in research applications and in amalgam for dental restoration in some locales. It is used in fluorescent lighting, electricity passed through mercury vapor in a fluorescent lamp produces short-wave ultraviolet light which then causes the phosphor in the tube to fluoresce, making visible light. Mercury poisoning can result from exposure to water-soluble forms of mercury, Mercury is a heavy, silvery-white liquid metal. Compared to other metals, it is a conductor of heat. It has a point of −38.83 °C and a boiling point of 356.73 °C. Upon freezing, the volume of mercury decreases by 3. 59%, the coefficient of volume expansion is 181.59 × 10−6 at 0 °C,181.71 × 10−6 at 20 °C and 182.50 × 10−6 at 100 °C. Solid mercury is malleable and ductile and can be cut with a knife, because this configuration strongly resists removal of an electron, mercury behaves similarly to noble gases, which form weak bonds and hence melt at low temperatures. The stability of the 6s shell is due to the presence of a filled 4f shell, an f shell poorly screens the nuclear charge that increases the attractive Coulomb interaction of the 6s shell and the nucleus. Like silver, mercury reacts with hydrogen sulfide. Mercury reacts with solid sulfur flakes, which are used in mercury spill kits to absorb mercury, Mercury dissolves many other metals such as gold and silver to form amalgams. Iron is an exception, and iron flasks have traditionally used to trade mercury. Several other first row transition metals with the exception of manganese, copper, other elements that do not readily form amalgams with mercury include platinum. Sodium amalgam is a reducing agent in organic synthesis, and is also used in high-pressure sodium lamps. Mercury readily combines with aluminium to form a mercury-aluminium amalgam when the two pure metals come into contact, since the amalgam destroys the aluminium oxide layer which protects metallic aluminium from oxidizing in-depth, even small amounts of mercury can seriously corrode aluminium. For this reason, mercury is not allowed aboard an aircraft under most circumstances because of the risk of it forming an amalgam with exposed aluminium parts in the aircraft, Mercury embrittlement is the most common type of liquid metal embrittlement
10.
Kelvin
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The kelvin is a unit of measure for temperature based upon an absolute scale. It is one of the seven units in the International System of Units and is assigned the unit symbol K. The kelvin is defined as the fraction 1⁄273.16 of the temperature of the triple point of water. In other words, it is defined such that the point of water is exactly 273.16 K. The Kelvin scale is named after the Belfast-born, Glasgow University engineer and physicist William Lord Kelvin, unlike the degree Fahrenheit and degree Celsius, the kelvin is not referred to or typeset as a degree. The kelvin is the unit of temperature measurement in the physical sciences, but is often used in conjunction with the Celsius degree. The definition implies that absolute zero is equivalent to −273.15 °C, Kelvin calculated that absolute zero was equivalent to −273 °C on the air thermometers of the time. This absolute scale is known today as the Kelvin thermodynamic temperature scale, when spelled out or spoken, the unit is pluralised using the same grammatical rules as for other SI units such as the volt or ohm. When reference is made to the Kelvin scale, the word kelvin—which is normally a noun—functions adjectivally to modify the noun scale and is capitalized, as with most other SI unit symbols there is a space between the numeric value and the kelvin symbol. Before the 13th CGPM in 1967–1968, the unit kelvin was called a degree and it was distinguished from the other scales with either the adjective suffix Kelvin or with absolute and its symbol was °K. The latter term, which was the official name from 1948 until 1954, was ambiguous since it could also be interpreted as referring to the Rankine scale. Before the 13th CGPM, the form was degrees absolute. The 13th CGPM changed the name to simply kelvin. Its measured value was 7002273160280000000♠0.01028 °C with an uncertainty of 60 µK, the use of SI prefixed forms of the degree Celsius to express a temperature interval has not been widely adopted. In 2005 the CIPM embarked on a program to redefine the kelvin using a more experimentally rigorous methodology, the current definition as of 2016 is unsatisfactory for temperatures below 20 K and above 7003130000000000000♠1300 K. In particular, the committee proposed redefining the kelvin such that Boltzmanns constant takes the exact value 6977138065049999999♠1. 3806505×10−23 J/K, from a scientific point of view, this will link temperature to the rest of SI and result in a stable definition that is independent of any particular substance. From a practical point of view, the redefinition will pass unnoticed, the kelvin is often used in the measure of the colour temperature of light sources. Colour temperature is based upon the principle that a black body radiator emits light whose colour depends on the temperature of the radiator, black bodies with temperatures below about 7003400000000000000♠4000 K appear reddish, whereas those above about 7003750000000000000♠7500 K appear bluish
11.
Celsius
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Celsius, also known as centigrade, is a metric scale and unit of measurement for temperature. As an SI derived unit, it is used by most countries in the world and it is named after the Swedish astronomer Anders Celsius, who developed a similar temperature scale. The degree Celsius can refer to a temperature on the Celsius scale as well as a unit to indicate a temperature interval. Before being renamed to honour Anders Celsius in 1948, the unit was called centigrade, from the Latin centum, which means 100, and gradus, which means steps. The scale is based on 0° for the point of water. This scale is widely taught in schools today, by international agreement the unit degree Celsius and the Celsius scale are currently defined by two different temperatures, absolute zero, and the triple point of VSMOW. This definition also precisely relates the Celsius scale to the Kelvin scale, absolute zero, the lowest temperature possible, is defined as being precisely 0 K and −273.15 °C. The temperature of the point of water is defined as precisely 273.16 K at 611.657 pascals pressure. This definition fixes the magnitude of both the degree Celsius and the kelvin as precisely 1 part in 273.16 of the difference between absolute zero and the point of water. Thus, it sets the magnitude of one degree Celsius and that of one kelvin as exactly the same, additionally, it establishes the difference between the two scales null points as being precisely 273.15 degrees. In his paper Observations of two persistent degrees on a thermometer, he recounted his experiments showing that the point of ice is essentially unaffected by pressure. He also determined with precision how the boiling point of water varied as a function of atmospheric pressure. He proposed that the point of his temperature scale, being the boiling point. This pressure is known as one standard atmosphere, the BIPMs 10th General Conference on Weights and Measures later defined one standard atmosphere to equal precisely 1013250dynes per square centimetre. On 19 May 1743 he published the design of a mercury thermometer, in 1744, coincident with the death of Anders Celsius, the Swedish botanist Carolus Linnaeus reversed Celsiuss scale. In it, Linnaeus recounted the temperatures inside the orangery at the University of Uppsala Botanical Garden, since the 19th century, the scientific and thermometry communities worldwide referred to this scale as the centigrade scale. Temperatures on the scale were often reported simply as degrees or. More properly, what was defined as centigrade then would now be hectograde.2 gradians, for scientific use, Celsius is the term usually used, with centigrade otherwise continuing to be in common but decreasing use, especially in informal contexts in English-speaking countries
12.
Fahrenheit
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Fahrenheit is a temperature scale based on one proposed in 1724 by the physicist Daniel Gabriel Fahrenheit, after whom the scale is named. It uses the degree Fahrenheit as the unit, several accounts of how he originally defined his scale exist. The lower defining point,0 °F, was established as the temperature of a solution of brine made from parts of ice. Further limits were established as the point of ice and his best estimate of the average human body temperature. All other countries in the world now use the Celsius scale, defined since 1954 by absolute zero being −273.15 °C, on the Fahrenheit scale, the freezing point of water is 32 degrees Fahrenheit and the boiling point is 212 °F. This puts the boiling and freezing points of water exactly 180 degrees apart, therefore, a degree on the Fahrenheit scale is 1⁄180 of the interval between the freezing point and the boiling point. On the Celsius scale, the freezing and boiling points of water are 100 degrees apart, a temperature interval of 1 °F is equal to an interval of 5⁄9 degrees Celsius. The Fahrenheit and Celsius scales intersect at −40°, absolute zero is −273.15 °C or −459.67 °F. For an exact conversion, the formulas can be applied. Again, f is the value in Fahrenheit and c the value in Celsius, f °Fahrenheit to c °Celsius, C °Celsius to f °Fahrenheit, −40 = f. Fahrenheit proposed his temperature scale in 1724, basing it on two points of temperature. In his initial scale, the point is determined by placing the thermometer in a mixture of ice, water. This is a mixture which stabilizes its temperature automatically, that stable temperature was defined as 0 °F. The second point,96 degrees, was approximately the human bodys temperature, in any case, the definition of the Fahrenheit scale has changed since. According to a letter Fahrenheit wrote to his friend Herman Boerhaave, his scale was built on the work of Ole Rømer, whom he had met earlier. In Rømers scale, brine freezes at zero, water freezes and melts at 7.5 degrees, body temperature is 22.5, Fahrenheit multiplied each value by four in order to eliminate fractions and increase the granularity of the scale. Fahrenheit observed that water boils at about 212 degrees using this scale, under this system, the Fahrenheit scale is redefined slightly so that the freezing point of water is exactly 32 °F, and the boiling point is exactly 212 °F or 180 degrees higher. It is for this reason that human body temperature is approximately 98° on the revised scale
13.
Agar
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Agar or agar-agar is a jelly-like substance, equivalent to vegan gelatin, obtained from algae. It was discovered in the late 1650s or early 1660s, by Mino Tarōzaemon in Japan, where it is called kanten. Agar is derived from the polysaccharide agarose, which forms the structure in the cell walls of certain species of algae. These algae are known as agarophytes and belong to the Rhodophyta phylum, Agar is actually the resulting mixture of two components, the linear polysaccharide agarose, and a heterogeneous mixture of smaller molecules called agaropectin. Throughout history into modern times, agar has been used as an ingredient in desserts throughout Asia. The gelling agent in agar is an unbranched polysaccharide obtained from the walls of some species of red algae, primarily from the genera Gelidium. For commercial purposes, it is derived primarily from Gelidium amansii, in chemical terms, agar is a polymer made up of subunits of the sugar galactose. Agar was discovered in Japan in 1658 by Mino Tarōzaemon, an innkeeper who was said to have discarded surplus seaweed soup, over the following centuries, agar became a common gelling agent in several Southeast Asian cuisines. Agar was first subjected to analysis in 1859 by the French chemist Anselme Payen. Beginning in the late 19th century, agar began to be used heavily as a medium for growing various microbes. Agar was first described for use in microbiology in 1882 by the German microbiologist Walther Hesse, Agar quickly supplanted gelatin as the base of microbiological media, due to its higher melting temperature, allowing microbes to be grown at higher temperatures without the media liquefying. With its newfound use in microbiology, agar production quickly increased and this production centered on Japan which produced most of the worlds agar until World War II. However, with the outbreak of World War II many nations were forced to establish domestic agar industries in order to continue microbiological research, around the time of World War II, approximately 2,500 tons of agar were produced annually. By the mid-1970s, production worldwide had increased dramatically to approximately 10,000 tons each year, since then, production of agar has fluctuated due to unstable and sometimes over-utilized seaweed populations. The word agar comes from agar-agar, the Malay name for red algae from which the jelly is produced and it is also known as Kanten, Japanese isinglass, Ceylon moss or Jaffna moss. Gracilaria lichenoides is specifically referred to as agal-agal or Ceylon agar, Agar consists of a mixture of two polysaccharides, agarose and agaropectin, with agarose making up about 70% of the mixture. Agarose is a polymer, made up of repeating units of agarobiose. Agar exhibits hysteresis, melting at 85 °C and solidifying from 32–40 °C and this property lends a suitable balance between easy melting and good gel stability at relatively high temperatures
14.
Hysteresis
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Hysteresis is the dependence of the state of a system on its history. For example, a magnet may have more than one possible magnetic moment in a magnetic field. Plots of a component of the moment often form a loop or hysteresis curve. This history dependence is the basis of memory in a disk drive. Hysteresis occurs in ferromagnetic and ferroelectric materials, as well as in the deformation of rubber bands and shape-memory alloys, in natural systems it is often associated with irreversible thermodynamic change such as phase transitions and with internal friction, and dissipation is a common side effect. Hysteresis can be found in physics, chemistry, engineering, biology and economics and it is incorporated in many artificial systems, for example, in thermostats and Schmitt triggers, it prevents unwanted frequent switching. Hysteresis can be a lag between an input and an output that disappears if the input is varied more slowly, this is known as rate-dependent hysteresis. However, phenomena such as the magnetic hysteresis loops are mainly rate-independent, systems with hysteresis are nonlinear, and can be mathematically challenging to model. The term hysteresis is derived from ὑστέρησις, an ancient Greek word meaning deficiency or lagging behind and it was coined around 1890 by Sir James Alfred Ewing to describe the behaviour of magnetic materials. Some early work on describing hysteresis in mechanical systems was performed by James Clerk Maxwell, subsequently, hysteretic models have received significant attention in the works of Ferenc Preisach, Louis Néel and D. H. Everett in connection with magnetism and absorption. A more formal theory of systems with hysteresis was developed in the 1970s by a group of Russian mathematicians led by Mark Krasnoselskii. One type of hysteresis is a lag between input and output. A simple example is a sinusoidal input X that results in a sinusoidal output Y and this kind of hysteresis is often referred to as rate-dependent hysteresis. If the input is reduced to zero, the continues to respond for a finite time. This constitutes a memory of the past, but a limited one because it disappears as the output decays to zero, the phase lag depends on the frequency of the input, and goes to zero as the frequency decreases. When rate-dependent hysteresis is due to effects like friction, it is associated with power loss. Systems with rate-independent hysteresis have a persistent memory of the past that remains after the transients have died out, the future development of such a system depends on the history of states visited, but does not fade as the events recede into the past. If an input variable X cycles from X0 to X1 and back again, the values of Y depend on the path of values that X passes through but not on the speed at which it traverses the path
15.
Nucleation
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Nucleation is the first step in the formation of either a new thermodynamic phase or a new structure via self-assembly or self-organization. Nucleation is typically defined to be the process that determines how long an observer has to wait before the new phase or self-organized structure appears, nucleation is often found to be very sensitive to impurities in the system. Because of this, it is important to distinguish between heterogeneous nucleation and homogeneous nucleation. Heterogeneous nucleation occurs at sites on surfaces in the system. Homogeneous nucleation occurs away from a surface, nucleation is usually a stochastic process, so even in two identical systems nucleation will occur at different times. This behaviour is similar to radioactive decay, a common mechanism is illustrated in the animation to the right. This shows nucleation of a new phase in an existing phase and this nucleus of the red phase then grows and converts the system to this phase. The standard theory that describes this behaviour for the nucleation of a new phase is called classical nucleation theory. This is seen for example in the nucleation of ice in supercooled water droplets. The decay rate of the exponential gives the nucleation rate, classical nucleation theory is a widely used approximate theory for estimating these rates, and how they vary with variables such as temperature. It correctly predicts that the time you have to wait for nucleation decreases extremely rapidly when supersaturated and it is not just new phases such as liquids and crystals that form via nucleation followed by growth. The self-assembly process that forms objects like the amyloid aggregates associated with Alzheimers disease also starts with nucleation, energy consuming self-organising systems such as the microtubules in cells also show nucleation and growth. Clouds form when wet air cools and many small water droplets nucleate from the supersaturated air, the amount of water vapor that air can carry decreases with lower temperatures. The excess vapor begins to nucleate and to small water droplets which form a cloud. Nucleation of the droplets of water is heterogeneous, occurring on particles referred to as cloud condensation nuclei. Cloud seeding is the process of adding artificial condensation nuclei to quicken the formation of clouds, nucleation is the first step in crystallisation, so it determines if a crystal can form. Frequently crystals do not form even when they are thermodynamically the favored state, for example, small droplets of very pure water can remain liquid down to below -30 °C although ice is the stable state below 0 °C. Bubbles of carbon dioxide nucleate shortly after the pressure is released from a container of carbonated liquid, nucleation often occurs more easily at a pre-existing interface, as happens on boiling chips and on string used to make rock candy
16.
Water
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Water is a transparent and nearly colorless chemical substance that is the main constituent of Earths streams, lakes, and oceans, and the fluids of most living organisms. Its chemical formula is H2O, meaning that its molecule contains one oxygen, Water strictly refers to the liquid state of that substance, that prevails at standard ambient temperature and pressure, but it often refers also to its solid state or its gaseous state. It also occurs in nature as snow, glaciers, ice packs and icebergs, clouds, fog, dew, aquifers, Water covers 71% of the Earths surface. It is vital for all forms of life. Only 2. 5% of this water is freshwater, and 98. 8% of that water is in ice and groundwater. Less than 0. 3% of all freshwater is in rivers, lakes, and the atmosphere, a greater quantity of water is found in the earths interior. Water on Earth moves continually through the cycle of evaporation and transpiration, condensation, precipitation. Evaporation and transpiration contribute to the precipitation over land, large amounts of water are also chemically combined or adsorbed in hydrated minerals. Safe drinking water is essential to humans and other even though it provides no calories or organic nutrients. There is a correlation between access to safe water and gross domestic product per capita. However, some observers have estimated that by 2025 more than half of the population will be facing water-based vulnerability. A report, issued in November 2009, suggests that by 2030, in developing regions of the world. Water plays an important role in the world economy, approximately 70% of the freshwater used by humans goes to agriculture. Fishing in salt and fresh water bodies is a source of food for many parts of the world. Much of long-distance trade of commodities and manufactured products is transported by boats through seas, rivers, lakes, large quantities of water, ice, and steam are used for cooling and heating, in industry and homes. Water is an excellent solvent for a variety of chemical substances, as such it is widely used in industrial processes. Water is also central to many sports and other forms of entertainment, such as swimming, pleasure boating, boat racing, surfing, sport fishing, Water is a liquid at the temperatures and pressures that are most adequate for life. Specifically, at atmospheric pressure of 1 bar, water is a liquid between the temperatures of 273.15 K and 373.15 K
17.
Chemical element
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A chemical element or element is a species of atoms having the same number of protons in their atomic nuclei. There are 118 elements that have identified, of which the first 94 occur naturally on Earth with the remaining 24 being synthetic elements. There are 80 elements that have at least one stable isotope and 38 that have exclusively radioactive isotopes, iron is the most abundant element making up Earth, while oxygen is the most common element in the Earths crust. Chemical elements constitute all of the matter of the universe. The two lightest elements, hydrogen and helium, were formed in the Big Bang and are the most common elements in the universe. The next three elements were formed mostly by cosmic ray spallation, and are rarer than those that follow. Formation of elements with from 6 to 26 protons occurred and continues to occur in main sequence stars via stellar nucleosynthesis, the high abundance of oxygen, silicon, and iron on Earth reflects their common production in such stars. The term element is used for atoms with a number of protons as well as for a pure chemical substance consisting of a single element. A single element can form multiple substances differing in their structure, when different elements are chemically combined, with the atoms held together by chemical bonds, they form chemical compounds. Only a minority of elements are found uncombined as relatively pure minerals, among the more common of such native elements are copper, silver, gold, carbon, and sulfur. All but a few of the most inert elements, such as gases and noble metals, are usually found on Earth in chemically combined form. While about 32 of the elements occur on Earth in native uncombined forms. For example, atmospheric air is primarily a mixture of nitrogen, oxygen, and argon, the history of the discovery and use of the elements began with primitive human societies that found native elements like carbon, sulfur, copper and gold. Later civilizations extracted elemental copper, tin, lead and iron from their ores by smelting, using charcoal, alchemists and chemists subsequently identified many more, almost all of the naturally occurring elements were known by 1900. Save for unstable radioactive elements with short half-lives, all of the elements are available industrially, almost all other elements found in nature were made by various natural methods of nucleosynthesis. On Earth, small amounts of new atoms are produced in nucleogenic reactions, or in cosmogenic processes. Of the 94 naturally occurring elements, those with atomic numbers 1 through 82 each have at least one stable isotope, Isotopes considered stable are those for which no radioactive decay has yet been observed. Elements with atomic numbers 83 through 94 are unstable to the point that radioactive decay of all isotopes can be detected, the very heaviest elements undergo radioactive decay with half-lives so short that they are not found in nature and must be synthesized
18.
Tungsten
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Tungsten, also known as wolfram, is a chemical element with symbol W and atomic number 74. The word tungsten comes from the Swedish language tung sten, which translates to heavy stone. Its name in Swedish is volfram, however, in order to distinguish it from scheelite, a hard, rare metal under standard conditions when uncombined, tungsten is found naturally on Earth almost exclusively in chemical compounds. It was identified as a new element in 1781, and first isolated as a metal in 1783 and its important ores include wolframite and scheelite. The free element is remarkable for its robustness, especially the fact that it has the highest melting point of all the elements discovered, melting at 3,422 °C,6,192 °F. Its high density is 19.3 times that of water, comparable to that of uranium and gold, polycrystalline tungsten is an intrinsically brittle and hard material, making it difficult to work. However, pure single-crystalline tungsten is more ductile, and can be cut with a hard-steel hacksaw, tungstens many alloys have numerous applications, including incandescent light bulb filaments, X-ray tubes, electrodes in TIG welding, superalloys, and radiation shielding. Tungstens hardness and high density give it military applications in penetrating projectiles, tungsten compounds are also often used as industrial catalysts. Tungsten is the metal from the third transition series that is known to occur in biomolecules. It is the heaviest element known to be essential to any living organism, tungsten interferes with molybdenum and copper metabolism and is somewhat toxic to animal life. In its raw form, tungsten is a hard metal that is often brittle. If made very pure, tungsten retains its hardness, and becomes malleable enough that it can be worked easily and it is worked by forging, drawing, or extruding. Tungsten objects are commonly formed by sintering. Of all metals in pure form, tungsten has the highest melting point, lowest vapor pressure, although carbon remains solid at higher temperatures than tungsten, carbon sublimes, rather than melts, so tungsten is considered to have a higher melting point. Tungsten has the lowest coefficient of expansion of any pure metal. The low thermal expansion and high melting point and tensile strength of tungsten originate from strong covalent bonds formed between tungsten atoms by the 5d electrons, alloying small quantities of tungsten with steel greatly increases its toughness. Tungsten exists in two crystalline forms, α and β. The former has a cubic structure and is the more stable form
19.
Carbon
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Carbon is a chemical element with symbol C and atomic number 6. It is nonmetallic and tetravalent—making four electrons available to form covalent chemical bonds, three isotopes occur naturally, 12C and 13C being stable, while 14C is a radioactive isotope, decaying with a half-life of about 5,730 years. Carbon is one of the few elements known since antiquity, Carbon is the 15th most abundant element in the Earths crust, and the fourth most abundant element in the universe by mass after hydrogen, helium, and oxygen. It is the second most abundant element in the body by mass after oxygen. The atoms of carbon can bond together in different ways, termed allotropes of carbon, the best known are graphite, diamond, and amorphous carbon. The physical properties of carbon vary widely with the allotropic form, for example, graphite is opaque and black while diamond is highly transparent. Graphite is soft enough to form a streak on paper, while diamond is the hardest naturally occurring material known, graphite is a good electrical conductor while diamond has a low electrical conductivity. Under normal conditions, diamond, carbon nanotubes, and graphene have the highest thermal conductivities of all known materials, all carbon allotropes are solids under normal conditions, with graphite being the most thermodynamically stable form. They are chemically resistant and require high temperature to react even with oxygen, the most common oxidation state of carbon in inorganic compounds is +4, while +2 is found in carbon monoxide and transition metal carbonyl complexes. The largest sources of carbon are limestones, dolomites and carbon dioxide, but significant quantities occur in organic deposits of coal, peat, oil. For this reason, carbon has often referred to as the king of the elements. The allotropes of carbon graphite, one of the softest known substances, and diamond. It bonds readily with other small atoms including other carbon atoms, Carbon is known to form almost ten million different compounds, a large majority of all chemical compounds. Carbon also has the highest sublimation point of all elements, although thermodynamically prone to oxidation, carbon resists oxidation more effectively than elements such as iron and copper that are weaker reducing agents at room temperature. Carbon is the element, with a ground-state electron configuration of 1s22s22p2. Its first four ionisation energies,1086.5,2352.6,4620.5 and 6222.7 kJ/mol, are higher than those of the heavier group 14 elements. Carbons covalent radii are normally taken as 77.2 pm,66.7 pm and 60.3 pm, although these may vary depending on coordination number, in general, covalent radius decreases with lower coordination number and higher bond order. Carbon compounds form the basis of all life on Earth
20.
Sublimation (phase transition)
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Sublimation is the phase transition of a substance directly from the solid to the gas phase without passing through the intermediate liquid phase. Sublimation is a process that occurs at temperatures and pressures below a substances triple point in its phase diagram. The reverse process of sublimation is deposition or desublimation, in which a substance directly from a gas to a solid phase. Sublimation has also used as a generic term to describe a solid-to-gas transition followed by a gas-to-solid transition. At normal pressures, most chemical compounds and elements possess three different states at different temperatures, in these cases, the transition from the solid to the gaseous state requires an intermediate liquid state. The pressure referred to is the pressure of the substance. So, all solids that possess an appreciable vapor pressure at a temperature usually can sublimate in air. The term sublimation refers to a change of state and is not used to describe transformation of a solid to a gas in a chemical reaction. For example, the dissociation on heating of ammonium chloride into hydrogen chloride and ammonia is not sublimation. Similarly the combustion of candles, containing paraffin wax, to carbon dioxide and water vapor is not sublimation, sublimation requires additional energy and is an endothermic change. The enthalpy of sublimation can be calculated by adding the enthalpy of fusion, solid carbon dioxide sublimes everywhere along the line below the triple point, whereas its melting into liquid CO2 can occur only along the line at pressures and temperatures above the triple point. Snow and ice sublime, although more slowly, at temperatures below the freezing/melting point temperature line at 0 °C for most pressures, in freeze-drying, the material to be dehydrated is frozen and its water is allowed to sublime under reduced pressure or vacuum. The loss of snow from a snowfield during a spell is often caused by sunshine acting directly on the upper layers of the snow. Ablation is a process that includes sublimation and erosive wear of glacier ice, naphthalene, an organic compound commonly found in pesticide such as mothball also sublimes. It sublimes easily because it is made of molecules and has van der Waals intermolecular forces. Naphthalene is a solid that sublimes at atmospheric temperature with the sublimation point at around 80˚C or 176˚F. At low temperature, its pressure is high enough,1 mmHg at 53˚C. On the cool surface, the sublimated vapour will be solidified to form a needle-like crystal, iodine produces fumes on gentle heating
21.
Refractory
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A refractory material is a material that retains its strength at high temperatures. Refractory materials are used in linings for furnaces, kilns, incinerators and they are also used to make crucibles and moulds for casting glass and metals and for surfacing flame deflector systems for rocket launch structures. Today, the iron- and steel-industry uses approximately 70% of all refractories produced, refractory materials must be chemically and physically stable at high temperatures. Depending on the environment, they must be resistant to thermal shock, be chemically inert, and/or have specific ranges of thermal conductivity. The oxides of aluminium, silicon and magnesium are the most important materials used in the manufacturing of refractories, another oxide usually found in refractories is the oxide of calcium. Fire clays are also used in the manufacture of refractories. Refractories must be according to the conditions they face. Some applications require special refractory materials, zirconia is used when the material must withstand extremely high temperatures. Silicon carbide and carbon are two other materials used in some very severe temperature conditions, but they cannot be used in contact with oxygen, as they will oxidize. Binary compounds such as tungsten carbide or boron nitride can be very refractory, hafnium carbide is the most refractory binary compound known, with a melting point of 3890 °C. The ternary compound tantalum hafnium carbide has one of the highest melting points of all known compounds, Refractories can be classified on the basis of chemical composition, method of manufacture, physical form or according to their applications, fusion temperature. Acidic refractories consist of acidic materials like alumina and silica. They are generally not attacked or affected by acidic materials, and they include substances such as silica, alumina, and fire clay brick refractories. Notable reagents that can attack both alumina and silica are hydrofluoric acid, phosphoric acid, and fluorinated gases, at high temperatures, acidic refractories may also react with limes and basic oxides. These are used in areas where slags and atmosphere are either acidic or basic and are stable to both acids and bases. The main raw materials belong to, but are not confined to, common examples of these materials are alumina, chromia and carbon. These are used in areas where slags and atmosphere are basic, they are stable to alkaline materials, the main raw materials belong to the RO group to which magnesia is a very common example. Other examples include dolomite and chrome-magnesia, for the first half of the twentieth century, the steel making process used artificial periclase as a lining material for the furnace
22.
Helium
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Helium is a chemical element with symbol He and atomic number 2. It is a colorless, odorless, tasteless, non-toxic, inert, monatomic gas and its boiling point is the lowest among all the elements. Its abundance is similar to figure in the Sun and in Jupiter. This is due to the high nuclear binding energy of helium-4 with respect to the next three elements after helium. This helium-4 binding energy also accounts for why it is a product of nuclear fusion and radioactive decay. Most helium in the universe is helium-4, and is believed to have formed during the Big Bang. Large amounts of new helium are being created by fusion of hydrogen in stars. Helium is named for the Greek god of the Sun, Helios and it was first detected as an unknown yellow spectral line signature in sunlight during a solar eclipse in 1868 by French astronomer Jules Janssen. Janssen is jointly credited with detecting the element along with Norman Lockyer, Janssen observed during the solar eclipse of 1868 while Lockyer observed from Britain. Lockyer was the first to propose that the line was due to a new element, the formal discovery of the element was made in 1895 by two Swedish chemists, Per Teodor Cleve and Nils Abraham Langlet, who found helium emanating from the uranium ore cleveite. In 1903, large reserves of helium were found in gas fields in parts of the United States. Liquid helium is used in cryogenics, particularly in the cooling of superconducting magnets, a well-known but minor use is as a lifting gas in balloons and airships. As with any gas whose density differs from that of air, inhaling a small volume of helium temporarily changes the timbre, on Earth it is relatively rare—5.2 ppm by volume in the atmosphere. Most terrestrial helium present today is created by the radioactive decay of heavy radioactive elements. Previously, terrestrial helium—a non-renewable resource, because once released into the atmosphere it readily escapes into space—was thought to be in short supply. The first evidence of helium was observed on August 18,1868, the line was detected by French astronomer Jules Janssen during a total solar eclipse in Guntur, India. This line was assumed to be sodium. He concluded that it was caused by an element in the Sun unknown on Earth, Lockyer and English chemist Edward Frankland named the element with the Greek word for the Sun, ἥλιος
23.
Absolute zero
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Absolute zero is the lower limit of the thermodynamic temperature scale, a state at which the enthalpy and entropy of a cooled ideal gas reaches its minimum value, taken as 0. The corresponding Kelvin and Rankine temperature scales set their zero points at absolute zero by definition, in the quantum-mechanical description, matter at absolute zero is in its ground state, the point of lowest internal energy. And a system at absolute zero still possesses quantum mechanical zero-point energy, the kinetic energy of the ground state cannot be removed. Scientists and technologists routinely achieve temperatures close to zero, where matter exhibits quantum effects such as superconductivity and superfluidity. At temperatures near 0 K, nearly all molecular motion ceases and ΔS =0 for any adiabatic process, in such a circumstance, pure substances can form perfect crystals as T →0. Max Plancks strong form of the law of thermodynamics states the entropy of a perfect crystal vanishes at absolute zero. The Nernst postulate identifies the isotherm T =0 as coincident with the adiabat S =0, although other isotherms, as no two adiabats intersect, no other adiabat can intersect the T =0 isotherm. Consequently no adiabatic process initiated at nonzero temperature can lead to zero temperature, a perfect crystal is one in which the internal lattice structure extends uninterrupted in all directions. The perfect order can be represented by translational symmetry along three axes, every lattice element of the structure is in its proper place, whether it is a single atom or a molecular grouping. For substances that exist in two crystalline forms, such as diamond and graphite for carbon, there is a kind of chemical degeneracy. The question remains whether both can have zero entropy at T =0 even though each is perfectly ordered, using the Debye model, the specific heat and entropy of a pure crystal are proportional to T3, while the enthalpy and chemical potential are proportional to T4. These quantities drop toward their T =0 limiting values and approach with zero slopes, for the specific heats at least, the limiting value itself is definitely zero, as borne out by experiments to below 10 K. Even the less detailed Einstein model shows this curious drop in specific heats, in fact, all specific heats vanish at absolute zero, not just those of crystals. Likewise for the coefficient of thermal expansion, maxwells relations show that various other quantities also vanish. Since the relation between changes in Gibbs free energy, the enthalpy and the entropy is Δ G = Δ H − T Δ S thus, as T decreases, ΔG and ΔH approach each other. Experimentally, it is found that all spontaneous processes result in a decrease in G as they proceed toward equilibrium, if ΔS and/or T are small, the condition ΔG <0 may imply that ΔH <0, which would indicate an exothermic reaction. However, this is not required, endothermic reactions can proceed spontaneously if the TΔS term is large enough, moreover, the slopes of the derivatives of ΔG and ΔH converge and are equal to zero at T =0. e. An actual process is the most exothermic one, one model that estimates the properties of an electron gas at absolute zero in metals is the Fermi gas
24.
Density
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The density, or more precisely, the volumetric mass density, of a substance is its mass per unit volume. The symbol most often used for density is ρ, although the Latin letter D can also be used. Mathematically, density is defined as mass divided by volume, ρ = m V, where ρ is the density, m is the mass, and V is the volume. In some cases, density is defined as its weight per unit volume. For a pure substance the density has the numerical value as its mass concentration. Different materials usually have different densities, and density may be relevant to buoyancy, purity, osmium and iridium are the densest known elements at standard conditions for temperature and pressure but certain chemical compounds may be denser. Thus a relative density less than one means that the floats in water. The density of a material varies with temperature and pressure and this variation is typically small for solids and liquids but much greater for gases. Increasing the pressure on an object decreases the volume of the object, increasing the temperature of a substance decreases its density by increasing its volume. In most materials, heating the bottom of a results in convection of the heat from the bottom to the top. This causes it to rise relative to more dense unheated material, the reciprocal of the density of a substance is occasionally called its specific volume, a term sometimes used in thermodynamics. Density is a property in that increasing the amount of a substance does not increase its density. Archimedes knew that the irregularly shaped wreath could be crushed into a cube whose volume could be calculated easily and compared with the mass, upon this discovery, he leapt from his bath and ran naked through the streets shouting, Eureka. As a result, the term eureka entered common parlance and is used today to indicate a moment of enlightenment, the story first appeared in written form in Vitruvius books of architecture, two centuries after it supposedly took place. Some scholars have doubted the accuracy of this tale, saying among other things that the method would have required precise measurements that would have been difficult to make at the time, from the equation for density, mass density has units of mass divided by volume. As there are units of mass and volume covering many different magnitudes there are a large number of units for mass density in use. The SI unit of kilogram per metre and the cgs unit of gram per cubic centimetre are probably the most commonly used units for density.1,000 kg/m3 equals 1 g/cm3. In industry, other larger or smaller units of mass and or volume are often more practical, see below for a list of some of the most common units of density
25.
Gram
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The gram is a metric system unit of mass. Originally defined as the weight of a volume of pure water equal to the cube of the hundredth part of a metre. The only unit symbol for gram that is recognised by the International System of Units is g following the numeric value with a space, the SI does not support the use of abbreviations such as gr, gm or Gm. The word gramme was adopted by the French National Convention in its 1795 decree revising the system as replacing the gravet introduced in 1793. Its definition remained that of the weight of a centimetre of water. French gramme was taken from the Late Latin term gramma and this word, ultimately from Greek γράμμα letter had adopted a specialised meaning in Late Antiquity of one twenty-fourth part of an ounce, corresponding to about 1.14 grams. This use of the term is found in the carmen de ponderibus et mensuris composed around 400 AD, the gram was the fundamental unit of mass in the 19th-century centimetre–gram–second system of units. The gram is today the most widely used unit of measurement for non-liquid ingredients in cooking and grocery shopping worldwide. 1 gram =15.4323583529 grains 1 grain =0.06479891 grams 1 avoirdupois ounce =28.349523125 grams 1 troy ounce =31.1034768 grams 100 grams =3.527396195 ounces 1 gram =5 carats 1 gram =8. 1 gram is roughly equal to 1 small paper clip or pen cap, the Japanese 1 yen coin has a mass of one gram. Conversion of units Duella Gold gram Orders of magnitude Gram at Encyclopædia Britannica
26.
Cubic centimetre
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A cubic centimetre is a commonly used unit of volume that extends the derived SI-unit cubic metre, and corresponds to the volume of a cube that measures 1 cm ×1 cm ×1 cm. One cubic centimetre corresponds to a volume of 1/1,000,000 of a metre, or 1/1,000 of a litre, or one millilitre. The mass of one centimetre of water at 3.98 °C is closely equal to one gram. Note that SI supports only the use of symbols and deprecates the use of any abbreviations for units, hence cm3 is preferred to cc or ccm. Many scientific fields have replaced cubic centimeters with milliliters, the medical and automotive fields in the United States still use the term cubic centimetre. Much of the industry outside the U. S. has switched to litres. The United Kingdom uses millilitres in preference to cubic centimetres in the medical field, most other English-speaking countries follow the UK example. There is currently a movement within the field to discontinue the use of cc in prescriptions and on medical documents. This could cause an overdose of medication, which could be dangerous or even lethal. In the United States, such confusion accounts for 12. 6% of all associated with medical abbreviations. In automobile engines, cc refers to the volume of its engine displacement in cubic centimetres. Conversions 1 millilitre =1 cm31 litre =1000 cm31 cubic inch =16.387 cm3
27.
Boiling point
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The boiling point of a substance is the temperature at which the vapor pressure of the liquid equals the pressure surrounding the liquid and the liquid changes into a vapor. The boiling point of a liquid varies depending upon the environmental pressure. A liquid in a vacuum has a lower boiling point than when that liquid is at atmospheric pressure. A liquid at high pressure has a boiling point than when that liquid is at atmospheric pressure. For a given pressure, different liquids boil at different temperatures, for example, water boils at 100 °C at sea level, but at 93.4 °C at 2,000 metres altitude. The normal boiling point of a liquid is the case in which the vapor pressure of the liquid equals the defined atmospheric pressure at sea level,1 atmosphere. At that temperature, the pressure of the liquid becomes sufficient to overcome atmospheric pressure. The standard boiling point has been defined by IUPAC since 1982 as the temperature at which boiling occurs under a pressure of 1 bar, the heat of vaporization is the energy required to transform a given quantity of a substance from a liquid into a gas at a given pressure. Liquids may change to a vapor at temperatures below their boiling points through the process of evaporation, evaporation is a surface phenomenon in which molecules located near the liquids edge, not contained by enough liquid pressure on that side, escape into the surroundings as vapor. On the other hand, boiling is a process in which molecules anywhere in the liquid escape, a saturated liquid contains as much thermal energy as it can without boiling. The saturation temperature is the temperature for a corresponding saturation pressure at which a liquid boils into its vapor phase, the liquid can be said to be saturated with thermal energy. Any addition of energy results in a phase transition. If the pressure in a system remains constant, a vapor at saturation temperature will begin to condense into its liquid phase as thermal energy is removed, similarly, a liquid at saturation temperature and pressure will boil into its vapor phase as additional thermal energy is applied. The boiling point corresponds to the temperature at which the pressure of the liquid equals the surrounding environmental pressure. Thus, the point is dependent on the pressure. Boiling points may be published with respect to the NIST, USA standard pressure of 101.325 kPa, at higher elevations, where the atmospheric pressure is much lower, the boiling point is also lower. The boiling point increases with increased pressure up to the critical point, the boiling point cannot be increased beyond the critical point. Likewise, the point decreases with decreasing pressure until the triple point is reached
28.
Solder
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Solder is a fusible metal alloy used to create a permanent bond between metal workpieces. The word solder comes from the Middle English word soudur, via Old French solduree and soulder, from the Latin solidare, meaning to make solid. In fact, solder must be melted in order to adhere to and connect the pieces together, whenever possible, the solder should also be resistant to oxidative and corrosive effects that would degrade the joint over time. Solder that is intended for use in making connections between electronic components also usually has favorable electrical characteristics. Soft solder typically has a melting point range of 90 to 450 °C, and is used in electronics, plumbing. Manual soldering uses an iron or soldering gun. Alloys that melt between 180 and 190 °C are the most commonly used, soldering performed using alloys with a melting point above 450 °C is called hard soldering, silver soldering, or brazing. In specific proportions, some alloys can become eutectic — that is, non-eutectic alloys have markedly different solidus and liquidus temperatures, and within that range they exist as a paste of solid particles in a melt of the lower-melting phase. In electrical work, if the joint is disturbed in the pasty state before it has solidified totally, for electrical and electronics work, solder wire is available in a range of thicknesses for hand-soldering, and with cores containing flux. It is also available as a paste or as a preformed foil shaped to match the workpiece, alloys of lead and tin were commonly used in the past, and are still available, they are particularly convenient for hand-soldering. Lead-free solders have been increasing in use due to regulatory requirements plus the health and they are almost exclusively used today in consumer electronics. Plumbers often use bars of solder, much thicker than the used for electrical applications. Jewelers often use solder in thin sheets, which cut into snippets. In the US, manufacturers may receive tax benefits by reducing the use of lead-based solder, lead-free solders in commercial use may contain tin, copper, silver, bismuth, indium, zinc, antimony, and traces of other metals. Most lead-free replacements for conventional 60/40 and 63/37 Sn-Pb solder have melting points from 5 to 20 °C higher and it may be desirable to use minor modification of the solder pots used in wave-soldering, to reduce maintenance cost due to increased tin-scavenging of high-tin solder. Lead-free solder may be desirable for critical applications, such as aerospace and medical projects. Tin-Silver-Copper solders are used by two-thirds of Japanese manufacturers for reflow and wave soldering, tin-based solders readily dissolve gold, forming brittle intermetallics, for Sn-Pb alloys the critical concentration of gold to embrittle the joint is about 4%. Indium-rich solders are more suitable for soldering thicker gold layer as the rate of gold in indium is much slower
29.
Cocoa butter
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Cocoa butter, also called theobroma oil, is a pale-yellow, edible vegetable fat extracted from the cocoa bean. It is used to make chocolate, as well as some ointments, toiletries, cocoa butter has a cocoa flavor and aroma. Its best-known attribute is its point, which is just below human body temperature. Cocoa butter is obtained from whole cocoa beans, which are fermented, roasted, about 54–58% of the residue is cocoa butter. Chocolate liquor is pressed to separate the cocoa butter from the cocoa solids, the Broma process is used to extract cocoa butter from ground cacao beans. Cocoa butter is deodorized to remove strong or undesirable tastes. Cocoa butter contains a proportion of saturated fats, derived from stearic and palmitic acids. Cocoa butter, unlike cocoa solids, has no more than trace amounts of caffeine and theobromine, some food manufacturers substitute less expensive materials such as vegetable oils and fats in place of cocoa butter. Several analytical methods exist for testing for diluted cocoa butter, adulterated cocoa butter is indicated by its lighter color and its diminished fluorescence upon ultraviolet illumination. Unlike cocoa butter, adulterated fat tends to smear and have a higher non-saponifiable content, cocoa butter is becoming increasingly expensive. Substitutes have been designed to use as alternatives, in the United States, 100% cocoa butter must be used for the product to be called chocolate. The EU requires that alternative fats not exceed 5% of the fat content. Cocoa butter is an ingredient in practically all types of chocolates. This application continues to dominate consumption of cocoa butter, pharmaceutical companies heavily use cocoa butters physical properties. As a nontoxic solid at room temperature that melts at body temperature, cocoa butter is one of the most stable fats known, a quality that, coupled with natural antioxidants, prevents rancidity, giving it a storage life of two to five years. The velvety texture, pleasant fragrance and emollient properties of cocoa butter have made it a popular ingredient in products for the skin, such as soaps, cocoa butters moisturizing properties are also said to be effective for treating mouth sores. However, the largest clinical study regarding the effects of cocoa butter on stretch marks in pregnant women found that results were no different from a placebo. The most common form of cocoa butter has a point of around 34–38 °C
30.
Paraffin wax
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Paraffin wax is a white or colourless soft solid derivable from petroleum, coal or oil shale, that consists of a mixture of hydrocarbon molecules containing between twenty and forty carbon atoms. It is solid at room temperature and begins to melt above approximately 37 °C, common applications for paraffin wax include lubrication, electrical insulation, and candles, dyed paraffin wax can be made into crayons. It is distinct from kerosene, another product that is sometimes called paraffin. Paraffin candles are odorless, and bluish-white in color, paraffin wax was first created in the 1850s, and marked a major advancement in candlemaking technology, as it burned more cleanly and reliably than tallow candles, and was cheaper to produce. In chemistry, paraffin is used synonymously with alkane, indicating hydrocarbons with the general formula CnH2n+2, the name is derived from Latin parum + affinis, meaning lacking affinity or lacking reactivity, referring to paraffins unreactive nature. Paraffin wax is mostly found as a white, odorless, tasteless, waxy solid and it is insoluble in water, but soluble in ether, benzene, and certain esters. Paraffin is unaffected by most common chemical reagents but burns readily and its heat of combustion is 42 kJ/g. Paraffin wax is an excellent electrical insulator, with a resistivity of between 1013 and 1017 ohm metre and this is better than nearly all other materials except some plastics. It is a neutron moderator and was used in James Chadwicks 1932 experiments to identify the neutron. Paraffin wax is an excellent material for storing heat, with a heat capacity of 2. 14–2.9 J g−1 K−1. Paraffin wax phase-change cooling coupled with retractable radiators was used to cool the electronics of the Lunar Rover, wax expands considerably when it melts and this allows its use in wax thermostatic element thermostats for industrial, domestic and, particularly, automobile purposes. Paraffin wax was first created in the 1850s when chemists first developed the means to efficiently separate, paraffin represented a major advance in the candlemaking industry because it burned more cleanly and reliably, and was cheaper to manufacture than any other candle fuel. Paraffin wax initially suffered from having a low melting point, however, the production of paraffin wax enjoyed a boom in the early 20th century as a result of the growth of the meatpacking and oil industries, which created paraffin and stearic acid as byproducts. The feedstock for paraffin is slack wax, which is a mixture of oil and wax, the first step in making paraffin wax is to remove the oil from the slack wax. The oil is separated through crystallization, most commonly, the slack wax is heated, mixed with one or more solvents such as a ketone and then cooled. As it cools wax crystallizes out of the solution, leaving only oil in the solution and this mixture is filtered into two streams, solid and liquid. After the solvent is recovered by distillation, the products are called product wax. The lower the percentage of oil in the wax the more refined it is considered, the product wax may be further processed to remove colors and odors
31.
Hydrogen
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Hydrogen is a chemical element with chemical symbol H and atomic number 1. With a standard weight of circa 1.008, hydrogen is the lightest element on the periodic table. Its monatomic form is the most abundant chemical substance in the Universe, non-remnant stars are mainly composed of hydrogen in the plasma state. The most common isotope of hydrogen, termed protium, has one proton, the universal emergence of atomic hydrogen first occurred during the recombination epoch. At standard temperature and pressure, hydrogen is a colorless, odorless, tasteless, non-toxic, nonmetallic, since hydrogen readily forms covalent compounds with most nonmetallic elements, most of the hydrogen on Earth exists in molecular forms such as water or organic compounds. Hydrogen plays an important role in acid–base reactions because most acid-base reactions involve the exchange of protons between soluble molecules. In ionic compounds, hydrogen can take the form of a charge when it is known as a hydride. The hydrogen cation is written as though composed of a bare proton, Hydrogen gas was first artificially produced in the early 16th century by the reaction of acids on metals. Industrial production is mainly from steam reforming natural gas, and less often from more energy-intensive methods such as the electrolysis of water. Most hydrogen is used near the site of its production, the two largest uses being fossil fuel processing and ammonia production, mostly for the fertilizer market, Hydrogen is a concern in metallurgy as it can embrittle many metals, complicating the design of pipelines and storage tanks. Hydrogen gas is flammable and will burn in air at a very wide range of concentrations between 4% and 75% by volume. The enthalpy of combustion is −286 kJ/mol,2 H2 + O2 →2 H2O +572 kJ Hydrogen gas forms explosive mixtures with air in concentrations from 4–74%, the explosive reactions may be triggered by spark, heat, or sunlight. The hydrogen autoignition temperature, the temperature of spontaneous ignition in air, is 500 °C, the detection of a burning hydrogen leak may require a flame detector, such leaks can be very dangerous. Hydrogen flames in other conditions are blue, resembling blue natural gas flames, the destruction of the Hindenburg airship was a notorious example of hydrogen combustion and the cause is still debated. The visible orange flames in that incident were the result of a mixture of hydrogen to oxygen combined with carbon compounds from the airship skin. H2 reacts with every oxidizing element, the ground state energy level of the electron in a hydrogen atom is −13.6 eV, which is equivalent to an ultraviolet photon of roughly 91 nm wavelength. The energy levels of hydrogen can be calculated fairly accurately using the Bohr model of the atom, however, the atomic electron and proton are held together by electromagnetic force, while planets and celestial objects are held by gravity. The most complicated treatments allow for the effects of special relativity
32.
Beryllium
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Beryllium is a chemical element with symbol Be and atomic number 4. It is a rare element in the universe, usually occurring as a product of the spallation of larger atomic nuclei that have collided with cosmic rays. Within the cores of stars beryllium is depleted as it is fused and it is a divalent element which occurs naturally only in combination with other elements in minerals. Notable gemstones which contain beryllium include beryl and chrysoberyl, as a free element it is a steel-gray, strong, lightweight and brittle alkaline earth metal. Beryllium improves many physical properties when added as an element to aluminium, copper, iron. Beryllium does not form oxides until it reaches high temperatures. Tools made of copper alloys are strong and hard and do not create sparks when they strike a steel surface. The high thermal conductivities of beryllium and beryllium oxide have led to their use in thermal management applications, Beryllium is a steel gray and hard metalloid that is brittle at room temperature and has a close-packed hexagonal crystal structure. It has exceptional stiffness and a high melting point. The modulus of elasticity of beryllium is approximately 50% greater than that of steel, the combination of this modulus and a relatively low density results in an unusually fast sound conduction speed in beryllium – about 12.9 km/s at ambient conditions. Other significant properties are high specific heat and thermal conductivity, which make beryllium the metal with the best heat dissipation characteristics per unit weight, in combination with the relatively low coefficient of linear thermal expansion, these characteristics result in a unique stability under conditions of thermal loading. Naturally occurring beryllium, save for slight contamination by cosmogenic radioisotopes, is essentially pure beryllium-9, Beryllium has a large scattering cross section for high-energy neutrons, about 6 barns for energies above approximately 10 keV. The single primordial beryllium isotope 9Be also undergoes a neutron reaction with neutron energies over about 1.9 MeV, to produce 8Be, thus, for high-energy neutrons, beryllium is a neutron multiplier, releasing more neutrons than it absorbs. Beryllium also releases neutrons under bombardment by gamma rays.8 seconds, β− is an electron, tritium is a radioisotope of concern in nuclear reactor waste streams. As a metal, beryllium is transparent to most wavelengths of X-rays and gamma rays, making it useful for the windows of X-ray tubes. Both stable and unstable isotopes of beryllium are created in stars, primordial beryllium contains only one stable isotope, 9Be, and therefore beryllium is a monoisotopic element. Radioactive cosmogenic 10Be is produced in the atmosphere of the Earth by the cosmic ray spallation of oxygen, 10Be accumulates at the soil surface, where its relatively long half-life permits a long residence time before decaying to boron-10. The production of 10Be is inversely proportional to activity, because increased solar wind during periods of high solar activity decreases the flux of galactic cosmic rays that reach the Earth
33.
Nitrogen
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Nitrogen is a chemical element with symbol N and atomic number 7. It was first discovered and isolated by Scottish physician Daniel Rutherford in 1772, although Carl Wilhelm Scheele and Henry Cavendish had independently done so at about the same time, Rutherford is generally accorded the credit because his work was published first. Nitrogen is the lightest member of group 15 of the periodic table, the name comes from the Greek πνίγειν to choke, directly referencing nitrogens asphyxiating properties. It is an element in the universe, estimated at about seventh in total abundance in the Milky Way. At standard temperature and pressure, two atoms of the element bind to form dinitrogen, a colourless and odorless diatomic gas with the formula N2, dinitrogen forms about 78% of Earths atmosphere, making it the most abundant uncombined element. Nitrogen occurs in all organisms, primarily in amino acids, in the nucleic acids, the human body contains about 3% nitrogen by mass, the fourth most abundant element in the body after oxygen, carbon, and hydrogen. The nitrogen cycle describes movement of the element from the air, into the biosphere and organic compounds, many industrially important compounds, such as ammonia, nitric acid, organic nitrates, and cyanides, contain nitrogen. The extremely strong bond in elemental nitrogen, the second strongest bond in any diatomic molecule. Synthetically produced ammonia and nitrates are key industrial fertilisers, and fertiliser nitrates are key pollutants in the eutrophication of water systems. Apart from its use in fertilisers and energy-stores, nitrogen is a constituent of organic compounds as diverse as Kevlar used in high-strength fabric, Nitrogen is a constituent of every major pharmacological drug class, including antibiotics. Many notable nitrogen-containing drugs, such as the caffeine and morphine or the synthetic amphetamines. Nitrogen compounds have a long history, ammonium chloride having been known to Herodotus. They were well known by the Middle Ages, alchemists knew nitric acid as aqua fortis, as well as other nitrogen compounds such as ammonium salts and nitrate salts. The mixture of nitric and hydrochloric acids was known as aqua regia, celebrated for its ability to dissolve gold, the discovery of nitrogen is attributed to the Scottish physician Daniel Rutherford in 1772, who called it noxious air. Though he did not recognise it as a different chemical substance, he clearly distinguished it from Joseph Blacks fixed air. The fact that there was a component of air that does not support combustion was clear to Rutherford, Nitrogen was also studied at about the same time by Carl Wilhelm Scheele, Henry Cavendish, and Joseph Priestley, who referred to it as burnt air or phlogisticated air. Nitrogen gas was inert enough that Antoine Lavoisier referred to it as air or azote, from the Greek word άζωτικός. In an atmosphere of nitrogen, animals died and flames were extinguished
34.
Oxygen
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Oxygen is a chemical element with symbol O and atomic number 8. It is a member of the group on the periodic table and is a highly reactive nonmetal. By mass, oxygen is the third-most abundant element in the universe, after hydrogen, at standard temperature and pressure, two atoms of the element bind to form dioxygen, a colorless and odorless diatomic gas with the formula O2. This is an important part of the atmosphere and diatomic oxygen gas constitutes 20. 8% of the Earths atmosphere, additionally, as oxides the element makes up almost half of the Earths crust. Most of the mass of living organisms is oxygen as a component of water, conversely, oxygen is continuously replenished by photosynthesis, which uses the energy of sunlight to produce oxygen from water and carbon dioxide. Oxygen is too reactive to remain a free element in air without being continuously replenished by the photosynthetic action of living organisms. Another form of oxygen, ozone, strongly absorbs ultraviolet UVB radiation, but ozone is a pollutant near the surface where it is a by-product of smog. At low earth orbit altitudes, sufficient atomic oxygen is present to cause corrosion of spacecraft, the name oxygen was coined in 1777 by Antoine Lavoisier, whose experiments with oxygen helped to discredit the then-popular phlogiston theory of combustion and corrosion. One of the first known experiments on the relationship between combustion and air was conducted by the 2nd century BCE Greek writer on mechanics, Philo of Byzantium. In his work Pneumatica, Philo observed that inverting a vessel over a burning candle, Philo incorrectly surmised that parts of the air in the vessel were converted into the classical element fire and thus were able to escape through pores in the glass. Many centuries later Leonardo da Vinci built on Philos work by observing that a portion of air is consumed during combustion and respiration, Oxygen was discovered by the Polish alchemist Sendivogius, who considered it the philosophers stone. In the late 17th century, Robert Boyle proved that air is necessary for combustion, English chemist John Mayow refined this work by showing that fire requires only a part of air that he called spiritus nitroaereus. From this he surmised that nitroaereus is consumed in both respiration and combustion, Mayow observed that antimony increased in weight when heated, and inferred that the nitroaereus must have combined with it. Accounts of these and other experiments and ideas were published in 1668 in his work Tractatus duo in the tract De respiratione. Robert Hooke, Ole Borch, Mikhail Lomonosov, and Pierre Bayen all produced oxygen in experiments in the 17th and the 18th century but none of them recognized it as a chemical element. This may have been in part due to the prevalence of the philosophy of combustion and corrosion called the phlogiston theory, which was then the favored explanation of those processes. Established in 1667 by the German alchemist J. J. Becher, one part, called phlogiston, was given off when the substance containing it was burned, while the dephlogisticated part was thought to be its true form, or calx. The fact that a substance like wood gains overall weight in burning was hidden by the buoyancy of the combustion products
35.
Sodium
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Sodium is a chemical element with symbol Na and atomic number 11. It is a soft, silvery-white, highly reactive metal, Sodium is an alkali metal, being in group 1 of the periodic table, because it has a single electron in its outer shell that it readily donates, creating a positively charged atom—the Na+ cation. Its only stable isotope is 23Na, the free metal does not occur in nature, but must be prepared from compounds. Sodium is the sixth most abundant element in the Earths crust, Sodium was first isolated by Humphry Davy in 1807 by the electrolysis of sodium hydroxide. Among many other useful compounds, sodium hydroxide is used in soap manufacture, and sodium chloride is a de-icing agent. Sodium is an element for all animals and some plants. Sodium ions are the major cation in the fluid and as such are the major contributor to the ECF osmotic pressure. Loss of water from the ECF compartment increases the sodium concentration, isotonic loss of water and sodium from the ECF compartment decreases the size of that compartment in a condition called ECF hypovolemia. In nerve cells, the charge across the cell membrane enables transmission of the nerve impulse—an action potential—when the charge is dissipated. The melting and boiling points of sodium are lower than those of lithium but higher than those of the alkali metals potassium, rubidium. All of these high-pressure allotropes are insulators and electrides.3 nm, spin-orbit interactions involving the electron in the 3p orbital split the D line into two, at 589.0 and 589.6 nm, hyperfine structures involving both orbitals cause many more lines. Twenty isotopes of sodium are known, but only 23Na is stable, 23Na is created in the carbon-burning process in stars by fusing two carbon atoms together, this requires temperatures above 600 megakelvins and a star of at least three solar masses. Two nuclear isomers have been discovered, the one being 24mNa with a half-life of around 20.2 milliseconds. Sodium atoms have 11 electrons, one more than the stable configuration of the noble gas neon. This process requires so little energy that sodium is oxidized by giving up its 11th electron. In contrast, the ionization energy is very high, because the 10th electron is closer to the nucleus than the 11th electron. As a result, sodium usually forms ionic compounds involving the Na+ cation, the most common oxidation state for sodium is +1. It is generally less reactive than potassium and more reactive than lithium, Sodium metal is highly reducing, with the reduction of sodium ions requiring −2.71 volts, though potassium and lithium have even more negative potentials
36.
Magnesium
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Magnesium is a chemical element with symbol Mg and atomic number 12. Magnesium is the ninth most abundant element in the universe and it is produced in large, aging stars from the sequential addition of three helium nuclei to a carbon nucleus. When such stars explode as supernovas, much of the magnesium is expelled into the medium where it may recycle into new star systems. Magnesium is the eighth most abundant element in the Earths crust and the fourth most common element in the Earth, making up 13% of the planets mass and it is the third most abundant element dissolved in seawater, after sodium and chlorine. Magnesium occurs naturally only in combination with elements, where it invariably has a +2 oxidation state. The free element can be produced artificially, and is highly reactive, the free metal burns with a characteristic brilliant-white light. The metal is now obtained mainly by electrolysis of magnesium salts obtained from brine, Magnesium is less dense than aluminium, and the alloy is prized for its combination of lightness and strength. Magnesium is the eleventh most abundant element by mass in the body and is essential to all cells. Magnesium ions interact with polyphosphate compounds such as ATP, DNA, hundreds of enzymes require magnesium ions to function. Magnesium compounds are used medicinally as common laxatives, antacids, elemental magnesium is a gray-white lightweight metal, two-thirds the density of aluminium. Magnesium has the lowest melting and the lowest boiling point 1,363 K of all the alkaline earth metals, Magnesium reacts with water at room temperature, though it reacts much more slowly than calcium, a similar group 2 metal. When submerged in water, hydrogen bubbles form slowly on the surface of the metal—though, if powdered, the reaction occurs faster with higher temperatures. Magnesiums reversible reaction with water can be harnessed to store energy, Magnesium also reacts exothermically with most acids such as hydrochloric acid, producing the metal chloride and hydrogen gas, similar to the HCl reaction with aluminium, zinc, and many other metals. Magnesium is highly flammable, especially when powdered or shaved into thin strips, flame temperatures of magnesium and magnesium alloys can reach 3,100 °C, although flame height above the burning metal is usually less than 300 mm. Once ignited, such fires are difficult to extinguish, with combustion continuing in nitrogen, carbon dioxide, Magnesium may also be used as an igniter for thermite, a mixture of aluminium and iron oxide powder that ignites only at a very high temperature. When burning in air, magnesium produces a light that includes strong ultraviolet wavelengths. Magnesium powder was used for illumination in the early days of photography. Later, magnesium filament was used in electrically ignited single-use photography flashbulbs, Magnesium powder is used in fireworks and marine flares where a brilliant white light is required
37.
Aluminium
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Aluminium or aluminum is a chemical element in the boron group with symbol Al and atomic number 13. It is a silvery-white, soft, nonmagnetic, ductile metal, Aluminium metal is so chemically reactive that native specimens are rare and limited to extreme reducing environments. Instead, it is combined in over 270 different minerals. The chief ore of aluminium is bauxite, Aluminium is remarkable for the metals low density and its ability to resist corrosion through the phenomenon of passivation. Aluminium and its alloys are vital to the industry and important in transportation and structures, such as building facades. The oxides and sulfates are the most useful compounds of aluminium, despite its prevalence in the environment, no known form of life uses aluminium salts metabolically, but aluminium is well tolerated by plants and animals. Because of these salts abundance, the potential for a role for them is of continuing interest. Aluminium is a soft, durable, lightweight, ductile. It is nonmagnetic and does not easily ignite, a fresh film of aluminium serves as a good reflector of visible light and an excellent reflector of medium and far infrared radiation. The yield strength of aluminium is 7–11 MPa, while aluminium alloys have yield strengths ranging from 200 MPa to 600 MPa. Aluminium has about one-third the density and stiffness of steel and it is easily machined, cast, drawn and extruded. Aluminium atoms are arranged in a cubic structure. Aluminium has an energy of approximately 200 mJ/m2. Aluminium is a thermal and electrical conductor, having 59% the conductivity of copper. Aluminium is capable of superconductivity, with a critical temperature of 1.2 kelvin. Aluminium is the most common material for the fabrication of superconducting qubits, the strongest aluminium alloys are less corrosion resistant due to galvanic reactions with alloyed copper. This corrosion resistance is reduced by aqueous salts, particularly in the presence of dissimilar metals. In highly acidic solutions, aluminium reacts with water to form hydrogen, primarily because it is corroded by dissolved chlorides, such as common sodium chloride, household plumbing is never made from aluminium
38.
Sulfur
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Sulfur or sulphur is a chemical element with symbol S and atomic number 16. It is abundant, multivalent, and nonmetallic, under normal conditions, sulfur atoms form cyclic octatomic molecules with chemical formula S8. Elemental sulfur is a yellow crystalline solid at room temperature. Chemically, sulfur reacts with all elements except for gold, platinum, iridium, tellurium, though sometimes found in pure, native form, sulfur usually occurs as sulfide and sulfate minerals. Being abundant in native form, sulfur was known in ancient times, being mentioned for its uses in ancient India, ancient Greece, China, in the Bible, sulfur is called brimstone. Today, almost all elemental sulfur is produced as a byproduct of removing sulfur-containing contaminants from natural gas, the greatest commercial use of the element is the production of sulfuric acid for sulfate and phosphate fertilizers, and other chemical processes. The element sulfur is used in matches, insecticides, and fungicides, many sulfur compounds are odoriferous, and the smells of odorized natural gas, skunk scent, grapefruit, and garlic are due to organosulfur compounds. Hydrogen sulfide gives the characteristic odor to rotting eggs and other biological processes, sulfur is an essential element for all life, but almost always in the form of organosulfur compounds or metal sulfides. Three amino acids and two vitamins are organosulfur compounds, many cofactors also contain sulfur including glutathione and thioredoxin and iron–sulfur proteins. Disulfides, S–S bonds, confer mechanical strength and insolubility of the keratin, found in outer skin, hair. Sulfur is one of the chemical elements needed for biochemical functioning and is an elemental macronutrient for all organisms. Sulfur is derived from the Latin word sulpur, which was Hellenized to sulphur, the spelling sulfur appears toward the end of the Classical period. In 12th-century Anglo-French, it was sulfre, in the 14th century the Latin ph was restored, for sulphre, the parallel f~ph spellings continued in Britain until the 19th century, when the word was standardized as sulphur. Sulfur was the form chosen in the United States, whereas Canada uses both, the IUPAC adopted the spelling sulfur in 1990, as did the Nomenclature Committee of the Royal Society of Chemistry in 1992, restoring the spelling sulfur to Britain. Sulfur forms polyatomic molecules with different chemical formulas, the best-known allotrope being octasulfur, cyclo-S8. The point group of cyclo-S8 is D4d and its dipole moment is 0 D. Octasulfur is a soft, bright-yellow solid that is odorless and it melts at 115.21 °C, boils at 444.6 °C and sublimes easily. At 95.2 °C, below its melting temperature, cyclo-octasulfur changes from α-octasulfur to the β-polymorph, the structure of the S8 ring is virtually unchanged by this phase change, which affects the intermolecular interactions. At higher temperatures, the viscosity decreases as depolymerization occurs, molten sulfur assumes a dark red color above 200 °C
39.
Chlorine
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Chlorine is a chemical element with symbol Cl and atomic number 17. The second-lightest of the halogens, it appears between fluorine and bromine in the table and its properties are mostly intermediate between them. Chlorine is a gas at room temperature. It is an extremely reactive element and a strong oxidising agent, among the elements, it has the highest electron affinity, the most common compound of chlorine, sodium chloride, has been known since ancient times. Around 1630, chlorine gas was first synthesised in a chemical reaction, Carl Wilhelm Scheele wrote a description of chlorine gas in 1774, supposing it to be an oxide of a new element. In 1809, chemists suggested that the gas might be an element, and this was confirmed by Sir Humphry Davy in 1810. Because of its reactivity, all chlorine in the Earths crust is in the form of ionic chloride compounds. It is the second-most abundant halogen and twenty-first most abundant chemical element in Earths crust and these crustal deposits are nevertheless dwarfed by the huge reserves of chloride in seawater. Elemental chlorine is produced from brine by electrolysis. The high oxidising potential of chlorine led to the development of commercial bleaches and disinfectants. As a common disinfectant, elemental chlorine and chlorine-generating compounds are used directly in swimming pools to keep them clean. Elemental chlorine at high concentrations is extremely dangerous and poisonous for all living organisms, in the form of chloride ions, chlorine is necessary to all known species of life. Other types of compounds are rare in living organisms. In the upper atmosphere, chlorine-containing organic molecules such as chlorofluorocarbons have been implicated in ozone depletion, small quantities of elemental chlorine are generated by oxidation of chloride to hypochlorite in neutrophils as part of the immune response against bacteria. Its importance in food was very well known in antiquity and was sometimes used as payment for services for Roman generals. Around 1630, chlorine was recognized as a gas by the Flemish chemist, the element was first studied in detail in 1774 by Swedish chemist Carl Wilhelm Scheele, and he is credited with the discovery. He called it dephlogisticated muriatic acid air since it is a gas and he failed to establish chlorine as an element, mistakenly thinking that it was the oxide obtained from the hydrochloric acid. He named the new element within this oxide as muriaticum, in 1809, Joseph Louis Gay-Lussac and Louis-Jacques Thénard tried to decompose dephlogisticated muriatic acid air by reacting it with charcoal to release the free element muriaticum
40.
Potassium
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Potassium is a chemical element with symbol K and atomic number 19. It was first isolated from potash, the ashes of plants, in the periodic table, potassium is one of the alkali metals. Potassium in nature only in ionic salts. It is found dissolved in sea water, and is part of many minerals, naturally occurring potassium is composed of three isotopes, of which 40K is radioactive. Traces of 40K are found in all potassium, and it is the most common radioisotope in the human body, Potassium is chemically very similar to sodium, the previous element in Group 1 of the periodic table. They have a similar energy, which allows for each atom to give up its sole outer electron. That they are different elements combine with the same anions to make similar salts was suspected in 1702. Most industrial applications of potassium exploit the high solubility in water of potassium compounds, heavy crop production rapidly depletes the soil of potassium, and this can be remedied with agricultural fertilizers containing potassium, accounting for 95% of global potassium chemical production. Potassium ions are necessary for the function of all living cells, fresh fruits and vegetables are good dietary sources of potassium. Potassium is the second least dense metal after lithium and it is a soft solid with a low melting point, and can be easily cut with a knife. Freshly cut potassium is silvery in appearance, but it begins to tarnish toward gray immediately on exposure to air, in a flame test, potassium and its compounds emit a lilac color with a peak emission wavelength of 766.5 nanometers. Neutral potassium atoms have 19 electrons, one more than the stable configuration of the noble gas argon. This process requires so little energy that potassium is readily oxidized by atmospheric oxygen, in contrast, the second ionization energy is very high, because removal of two electrons breaks the stable noble gas electronic configuration. Potassium therefore does not readily form compounds with the state of +2 or higher. Potassium is an active metal that reacts violently with oxygen in water. With oxygen it forms potassium peroxide, and with water potassium forms potassium hydroxide, the reaction of potassium with water is dangerous because of its violent exothermic character and the production of hydrogen gas. Hydrogen reacts again with atmospheric oxygen, producing water, which reacts with the remaining potassium and this reaction requires only traces of water, because of this, potassium and the liquid sodium-potassium — NaK — are potent desiccants that can be used to dry solvents prior to distillation. Because of the sensitivity of potassium to water and air, reactions with other elements are only in an inert atmosphere such as argon gas using air-free techniques
41.
Titanium
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Titanium is a chemical element with symbol Ti and atomic number 22. It is a transition metal with a silver color, low density. Titanium is resistant to corrosion in sea water, aqua regia, titanium was discovered in Cornwall, Great Britain, by William Gregor in 1791, and it is named by Martin Heinrich Klaproth for the Titans of Greek mythology. The metal is extracted from its principal mineral ores by the Kroll, the most common compound, titanium dioxide, is a popular photocatalyst and is used in the manufacture of white pigments. Other compounds include titanium tetrachloride, a component of smoke screens and catalysts, and titanium trichloride, the two most useful properties of the metal are corrosion resistance and strength-to-density ratio, the highest of any metallic element. In its unalloyed condition, titanium is as strong as some steels, there are two allotropic forms and five naturally occurring isotopes of this element, 46Ti through 50Ti, with 48Ti being the most abundant. Although they have the number of valence electrons and are in the same group in the periodic table. As a metal, titanium is recognized for its high strength-to-weight ratio and it is a strong metal with low density that is quite ductile, lustrous, and metallic-white in color. The relatively high melting point makes it useful as a refractory metal and it is paramagnetic and has fairly low electrical and thermal conductivity. Commercial grades of titanium have ultimate tensile strength of about 434 MPa, equal to that of common, low-grade steel alloys, titanium is 60% denser than aluminium, but more than twice as strong as the most commonly used 6061-T6 aluminium alloy. Certain titanium alloys achieve tensile strengths of over 1400 MPa, however, titanium loses strength when heated above 430 °C. Titanium is not as hard as some grades of heat-treated steel, it is non-magnetic, machining requires precautions, because the material might gall unless sharp tools and proper cooling methods are used. Like steel structures, those made from titanium have a limit that guarantees longevity in some applications. The metal is an allotrope of an hexagonal α form that changes into a body-centered cubic β form at 882 °C. The specific heat of the α form increases dramatically as it is heated to this transition temperature but then falls, similar to zirconium and hafnium, an additional omega phase exists, which is thermodynamically stable at high pressures, but metastable at ambient pressures. This phase is usually hexagonal or trigonal and can be considered to be due to a soft longitudinal acoustic phonon of the β phase causing collapse of planes of atoms, like aluminium and magnesium, titanium metal and its alloys oxidize immediately upon exposure to air. Titanium readily reacts with oxygen at 1,200 °C in air and it is, however, slow to react with water and air at ambient temperatures because it forms a passive oxide coating that protects the bulk metal from further oxidation. When it first forms, this layer is only 1–2 nm thick but continues to grow slowly
42.
Iron
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Iron is a chemical element with symbol Fe and atomic number 26. It is a metal in the first transition series and it is by mass the most common element on Earth, forming much of Earths outer and inner core. It is the fourth most common element in the Earths crust, like the other group 8 elements, ruthenium and osmium, iron exists in a wide range of oxidation states, −2 to +6, although +2 and +3 are the most common. Elemental iron occurs in meteoroids and other low oxygen environments, but is reactive to oxygen, fresh iron surfaces appear lustrous silvery-gray, but oxidize in normal air to give hydrated iron oxides, commonly known as rust. Unlike the metals that form passivating oxide layers, iron oxides occupy more volume than the metal and thus flake off, Iron metal has been used since ancient times, although copper alloys, which have lower melting temperatures, were used even earlier in human history. Pure iron is soft, but is unobtainable by smelting because it is significantly hardened and strengthened by impurities, in particular carbon. A certain proportion of carbon steel, which may be up to 1000 times harder than pure iron. Crude iron metal is produced in blast furnaces, where ore is reduced by coke to pig iron, further refinement with oxygen reduces the carbon content to the correct proportion to make steel. Steels and iron alloys formed with metals are by far the most common industrial metals because they have a great range of desirable properties. Iron chemical compounds have many uses, Iron oxide mixed with aluminium powder can be ignited to create a thermite reaction, used in welding and purifying ores. Iron forms binary compounds with the halogens and the chalcogens, among its organometallic compounds is ferrocene, the first sandwich compound discovered. Iron plays an important role in biology, forming complexes with oxygen in hemoglobin and myoglobin. Iron is also the metal at the site of many important redox enzymes dealing with cellular respiration and oxidation and reduction in plants. A human male of average height has about 4 grams of iron in his body and this iron is distributed throughout the body in hemoglobin, tissues, muscles, bone marrow, blood proteins, enzymes, ferritin, hemosiderin, and transport in plasma. The mechanical properties of iron and its alloys can be evaluated using a variety of tests, including the Brinell test, Rockwell test, the data on iron is so consistent that it is often used to calibrate measurements or to compare tests. An increase in the content will cause a significant increase in the hardness. Maximum hardness of 65 Rc is achieved with a 0. 6% carbon content, because of the softness of iron, it is much easier to work with than its heavier congeners ruthenium and osmium. Because of its significance for planetary cores, the properties of iron at high pressures and temperatures have also been studied extensively
43.
Nickel
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Nickel is a chemical element with symbol Ni and atomic number 28. It is a silvery-white lustrous metal with a golden tinge. Nickel belongs to the metals and is hard and ductile. Meteoric nickel is found in combination with iron, a reflection of the origin of elements as major end products of supernova nucleosynthesis. An iron–nickel mixture is thought to compose Earths inner core, use of nickel has been traced as far back as 3500 BCE. Nickel was first isolated and classified as an element in 1751 by Axel Fredrik Cronstedt. The elements name comes from a mischievous sprite of German miner mythology, Nickel, an economically important source of nickel is the iron ore limonite, which often contains 1–2% nickel. Nickels other important ore minerals include garnierite, and pentlandite, major production sites include the Sudbury region in Canada, New Caledonia in the Pacific, and Norilsk in Russia. Nickel is slowly oxidized by air at room temperature and is considered corrosion-resistant, historically, it has been used for plating iron and brass, coating chemistry equipment, and manufacturing certain alloys that retain a high silvery polish, such as German silver. About 6% of world production is still used for corrosion-resistant pure-nickel plating. Nickel-plated objects sometimes provoke nickel allergy, Nickel has been widely used in coins, though its rising price has led to some replacement with cheaper metals in recent years. Nickel is one of four elements that are ferromagnetic around room temperature, alnico permanent magnets based partly on nickel are of intermediate strength between iron-based permanent magnets and rare-earth magnets. The metal is valuable in modern times chiefly in alloys, about 60% of world production is used in nickel-steels, other common alloys and some new superalloys comprise most of the remainder of world nickel use, with chemical uses for nickel compounds consuming less than 3% of production. As a compound, nickel has a number of chemical manufacturing uses. Nickel is a nutrient for some microorganisms and plants that have enzymes with nickel as an active site. Nickel is a metal with a slight golden tinge that takes a high polish. It is one of four elements that are magnetic at or near room temperature. Its Curie temperature is 355 °C, meaning that bulk nickel is non-magnetic above this temperature, the unit cell of nickel is a face-centered cube with the lattice parameter of 0.352 nm, giving an atomic radius of 0.124 nm
44.
Copper
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Copper is a chemical element with symbol Cu and atomic number 29. It is a soft, malleable, and ductile metal with high thermal and electrical conductivity. A freshly exposed surface of copper has a reddish-orange color. Copper is one of the few metals that occur in nature in directly usable metallic form as opposed to needing extraction from an ore and this led to very early human use, from c.8000 BC. Copper used in buildings, usually for roofing, oxidizes to form a green verdigris, Copper is sometimes used in decorative art, both in its elemental metal form and in compounds as pigments. Copper compounds are used as agents, fungicides, and wood preservatives. Copper is essential to all living organisms as a trace dietary mineral because it is a key constituent of the enzyme complex cytochrome c oxidase. In molluscs and crustaceans, copper is a constituent of the blood pigment hemocyanin, replaced by the hemoglobin in fish. In humans, copper is found mainly in the liver, muscle, the adult body contains between 1.4 and 2.1 mg of copper per kilogram of body weight. The filled d-shells in these elements contribute little to interatomic interactions, unlike metals with incomplete d-shells, metallic bonds in copper are lacking a covalent character and are relatively weak. This observation explains the low hardness and high ductility of single crystals of copper, at the macroscopic scale, introduction of extended defects to the crystal lattice, such as grain boundaries, hinders flow of the material under applied stress, thereby increasing its hardness. For this reason, copper is supplied in a fine-grained polycrystalline form. The softness of copper partly explains its high conductivity and high thermal conductivity. The maximum permissible current density of copper in open air is approximately 3. 1×106 A/m2 of cross-sectional area, Copper is one of a few metallic elements with a natural color other than gray or silver. Pure copper is orange-red and acquires a reddish tarnish when exposed to air, as with other metals, if copper is put in contact with another metal, galvanic corrosion will occur. A green layer of verdigris can often be seen on old structures, such as the roofing of many older buildings. Copper tarnishes when exposed to sulfur compounds, with which it reacts to form various copper sulfides. There are 29 isotopes of copper, 63Cu and 65Cu are stable, with 63Cu comprising approximately 69% of naturally occurring copper, both have a spin of 3⁄2
45.
Zinc
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Zinc is a chemical element with the symbol Zn and atomic number 30. It is the first element in group 12 of the periodic table, in some respects zinc is chemically similar to magnesium, both elements exhibit only one normal oxidation state, and the Zn2+ and Mg2+ ions are of similar size. Zinc is the 24th most abundant element in Earths crust and has five stable isotopes, the most common zinc ore is sphalerite, a zinc sulfide mineral. The largest workable lodes are in Australia, Asia, and the United States, Zinc is refined by froth flotation of the ore, roasting, and final extraction using electricity. Zinc metal was not produced on a large scale until the 12th century in India and was unknown to Europe until the end of the 16th century, the mines of Rajasthan have given definite evidence of zinc production going back to the 6th century BC. To date, the oldest evidence of pure zinc comes from Zawar, in Rajasthan, alchemists burned zinc in air to form what they called philosophers wool or white snow. The element was named by the alchemist Paracelsus after the German word Zinke. German chemist Andreas Sigismund Marggraf is credited with discovering pure metallic zinc in 1746, work by Luigi Galvani and Alessandro Volta uncovered the electrochemical properties of zinc by 1800. Corrosion-resistant zinc plating of iron is the application for zinc. Other applications are in batteries, small non-structural castings. A variety of compounds are commonly used, such as zinc carbonate and zinc gluconate, zinc chloride, zinc pyrithione, zinc sulfide. Zinc is an essential mineral perceived by the public today as being of exceptional biologic and public health importance, Zinc deficiency affects about two billion people in the developing world and is associated with many diseases. In children, deficiency causes growth retardation, delayed sexual maturation, infection susceptibility, enzymes with a zinc atom in the reactive center are widespread in biochemistry, such as alcohol dehydrogenase in humans. Consumption of excess zinc can cause ataxia, lethargy and copper deficiency, Zinc is a bluish-white, lustrous, diamagnetic metal, though most common commercial grades of the metal have a dull finish.6 pm. The metal is hard and brittle at most temperatures but becomes malleable between 100 and 150 °C, above 210 °C, the metal becomes brittle again and can be pulverized by beating. Zinc is a conductor of electricity. For a metal, zinc has relatively low melting and boiling points, the melting point is the lowest of all the transition metals aside from mercury and cadmium. Many alloys contain zinc, including brass, Other metals long known to form binary alloys with zinc are aluminium, antimony, bismuth, gold, iron, lead, mercury, silver, tin, magnesium, cobalt, nickel, tellurium, and sodium
46.
Gallium
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Gallium is a chemical element with symbol Ga and atomic number 31. It is in group 13 of the table, and thus has similarities to the other metals of the group, aluminium, indium. Gallium does not occur as an element in nature, but as gallium compounds in trace amounts in zinc ores. Elemental gallium is a soft, silvery blue metal at standard temperature and pressure, a solid at low temperatures. The melting point of gallium is used as a reference point. The alloy galinstan has a lower melting point of −19 °C. Since its discovery in 1875, gallium has been used to make alloys with low melting points and it is also used in semiconductors as a dopant in semiconductor substrates. Gallium is predominantly used in electronics, gallium arsenide, the primary chemical compound of gallium in electronics, is used in microwave circuits, high-speed switching circuits, and infrared circuits. Semiconductive gallium nitride and indium gallium nitride produce blue and violet light-emitting diodes, gallium is also used in the production of artificial gadolinium gallium garnet for jewelry. Gallium has no known role in biology. Gallium behaves in a manner to ferric salts in biological systems. Gallium is used in thermometers as a non-toxic and environmentally friendly alternative to mercury, elemental gallium is not found in nature, but it is easily obtained by smelting. Very pure gallium metal has a color and its solid metal fractures conchoidally like glass. Gallium liquid expands by 3. 1% when it solidifies, therefore, gallium shares the higher-density liquid state with a short list of other materials that includes water, silicon, germanium, antimony, bismuth, and plutonium. Gallium attacks most other metals by diffusing into the metal lattice, for example, it diffuses into the grain boundaries of aluminium-zinc alloys and steel, making them very brittle. Gallium easily alloys with metals, and is used in small quantities in the plutonium-gallium alloy in the plutonium cores of nuclear bombs to stabilize the plutonium crystal structure. The melting point of gallium, at 302.9146 K, is just above room temperature and this melting point is one of the formal temperature reference points in the International Temperature Scale of 1990 established by the International Bureau of Weights and Measures. The triple point of gallium,302.9166 K, is used by the US National Institute of Standards, the unique melting point of gallium allows it to melt in the human hand, and then refreeze if removed
47.
Silver
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Silver is a metallic element with symbol Ag and atomic number 47. The symbol Ag stems from Latin argentum, derived from the Greek ὰργὀς, a soft, white, lustrous transition metal, it exhibits the highest electrical conductivity, thermal conductivity, and reflectivity of any metal. The metal is found in the Earths crust in the pure, free form, as an alloy with gold and other metals. Most silver is produced as a byproduct of copper, gold, lead, Silver is more abundant than gold, but it is much less abundant as a native metal. Its purity is measured on a per mille basis, a 94%-pure alloy is described as 0.940 fine. As one of the seven metals of antiquity, silver has had a role in most human cultures. Silver has long valued as a precious metal. Silver metal is used in many premodern monetary systems in bullion coins, Silver is used in numerous applications other than currency, such as solar panels, water filtration, jewelry, ornaments, high-value tableware and utensils, and as an investment medium. Silver is used industrially in electrical contacts and conductors, in specialized mirrors, window coatings, Silver compounds are used in photographic film and X-rays. Dilute silver nitrate solutions and other compounds are used as disinfectants and microbiocides, added to bandages and wound-dressings, catheters. Silver is similar in its physical and chemical properties to its two neighbours in group 11 of the periodic table, copper and gold. This distinctive electron configuration, with an electron in the highest occupied s subshell over a filled d subshell. Silver is a soft, ductile and malleable transition metal. Silver crystallizes in a cubic lattice with bulk coordination number 12. Unlike metals with incomplete d-shells, metallic bonds in silver are lacking a covalent character and are relatively weak and this observation explains the low hardness and high ductility of single crystals of silver. Silver has a brilliant white metallic luster that can take a polish. Protected silver has greater optical reflectivity than aluminium at all wavelengths longer than ~450 nm, at wavelengths shorter than 450 nm, silvers reflectivity is inferior to that of aluminium and drops to zero near 310 nm. The electrical conductivity of silver is the greatest of all metals, greater even than copper, during World War II in the US,13540 tons of silver were used in electromagnets for enriching uranium, mainly because of the wartime shortage of copper
