1.
Tectosilicate
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Silicate minerals are rock-forming minerals made up of silicate groups. They are the largest and most important class of rock-forming minerals and they are classified based on the structure of their silicate groups, which contain different ratios of silicon and oxygen. Nesosilicates, or orthosilicates, have the orthosilicate ion, which constitute isolated 4− tetrahedra that are connected only by interstitial cations and these exist as 3-member 6− and 6-member 12− rings, where T stands for a tetrahedrally coordinated cation. Inosilicates, or chain silicates, have interlocking chains of silicate tetrahedra with either SiO3,1,3 ratio, for single chains or Si4O11,4,11 ratio, for double chains. Nickel–Strunz classification,09. D Pyroxene group Enstatite – orthoferrosilite series Enstatite – MgSiO3 Ferrosilite – FeSiO3 Pigeonite – Ca0.251, all phyllosilicate minerals are hydrated, with either water or hydroxyl groups attached. Serpentine subgroup Antigorite – Mg3Si2O54 Chrysotile – Mg3Si2O54 Lizardite – Mg3Si2O54 Clay minerals group Halloysite – Al2Si2O54 Kaolinite – Al2Si2O54 Illite – 24O10 Montmorillonite –0 and this group comprises nearly 75% of the crust of the Earth. Tectosilicates, with the exception of the group, are aluminosilicates. Nickel–Strunz classification,09. F and 09. G,04. A, an introduction to the rock-forming minerals. Wise, W. S. Zussman, J. Rock-forming minerals, P.982 pp. Hurlbut, Cornelius S. Danas Manual of Mineralogy. Mindat. org, Dana classification Webmineral, Danas New Silicate Classification Media related to Silicates at Wikimedia Commons
2.
Chemical formula
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These are limited to a single typographic line of symbols, which may include subscripts and superscripts. A chemical formula is not a name, and it contains no words. Although a chemical formula may imply certain simple chemical structures, it is not the same as a full chemical structural formula. Chemical formulas can fully specify the structure of only the simplest of molecules and chemical substances, the simplest types of chemical formulas are called empirical formulas, which use letters and numbers indicating the numerical proportions of atoms of each type. Molecular formulas indicate the numbers of each type of atom in a molecule. For example, the formula for glucose is CH2O, while its molecular formula is C6H12O6. This is possible if the relevant bonding is easy to show in one dimension, an example is the condensed molecular/chemical formula for ethanol, which is CH3-CH2-OH or CH3CH2OH. For reasons of structural complexity, there is no condensed chemical formula that specifies glucose, chemical formulas may be used in chemical equations to describe chemical reactions and other chemical transformations, such as the dissolving of ionic compounds into solution. A chemical formula identifies each constituent element by its chemical symbol, in empirical formulas, these proportions begin with a key element and then assign numbers of atoms of the other elements in the compound, as ratios to the key element. For molecular compounds, these numbers can all be expressed as whole numbers. For example, the formula of ethanol may be written C2H6O because the molecules of ethanol all contain two carbon atoms, six hydrogen atoms, and one oxygen atom. Some types of compounds, however, cannot be written with entirely whole-number empirical formulas. An example is boron carbide, whose formula of CBn is a variable non-whole number ratio with n ranging from over 4 to more than 6.5. When the chemical compound of the consists of simple molecules. These types of formulas are known as molecular formulas and condensed formulas. A molecular formula enumerates the number of atoms to reflect those in the molecule, so that the formula for glucose is C6H12O6 rather than the glucose empirical formula. However, except for very simple substances, molecular chemical formulas lack needed structural information, for simple molecules, a condensed formula is a type of chemical formula that may fully imply a correct structural formula. For example, ethanol may be represented by the chemical formula CH3CH2OH
3.
Crystal system
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In crystallography, the terms crystal system, crystal family and lattice system each refer to one of several classes of space groups, lattices, point groups or crystals. Informally, two crystals are in the crystal system if they have similar symmetries, though there are many exceptions to this. Space groups and crystals are divided into seven crystal systems according to their point groups, five of the crystal systems are essentially the same as five of the lattice systems, but the hexagonal and trigonal crystal systems differ from the hexagonal and rhombohedral lattice systems. The six crystal families are formed by combining the hexagonal and trigonal crystal systems into one hexagonal family, a lattice system is a class of lattices with the same set of lattice point groups, which are subgroups of the arithmetic crystal classes. The 14 Bravais lattices are grouped into seven lattice systems, triclinic, monoclinic, orthorhombic, tetragonal, rhombohedral, hexagonal, in a crystal system, a set of point groups and their corresponding space groups are assigned to a lattice system. Of the 32 point groups that exist in three dimensions, most are assigned to only one system, in which case both the crystal and lattice systems have the same name. However, five point groups are assigned to two systems, rhombohedral and hexagonal, because both exhibit threefold rotational symmetry. These point groups are assigned to the crystal system. In total there are seven crystal systems, triclinic, monoclinic, orthorhombic, tetragonal, trigonal, hexagonal, a crystal family is determined by lattices and point groups. It is formed by combining crystal systems which have space groups assigned to a lattice system. In three dimensions, the families and systems are identical, except the hexagonal and trigonal crystal systems. In total there are six families, triclinic, monoclinic, orthorhombic, tetragonal, hexagonal. Spaces with less than three dimensions have the number of crystal systems, crystal families and lattice systems. In one-dimensional space, there is one crystal system, in 2D space, there are four crystal systems, oblique, rectangular, square and hexagonal. The relation between three-dimensional crystal families, crystal systems and lattice systems is shown in the table, Note. To avoid confusion of terminology, the term trigonal lattice is not used, if the original structure and inverted structure are identical, then the structure is centrosymmetric. Still, even for non-centrosymmetric case, inverted structure in some cases can be rotated to align with the original structure and this is the case of non-centrosymmetric achiral structure. If the inverted structure cannot be rotated to align with the structure, then the structure is chiral
4.
Orthorhombic crystal system
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In crystallography, the orthorhombic crystal system is one of the 7 crystal systems. All three bases intersect at 90° angles, so the three lattice vectors remain mutually orthogonal, there are two orthorhombic Bravais lattices in two dimensions, Primitive rectangular and centered rectangular. The primitive rectangular lattice can also be described by a centered rhombic unit cell, there are four orthorhombic Bravais lattices, primitive orthorhombic, base-centered orthorhombic, body-centered orthorhombic, and face-centered orthorhombic. In this axis setting, the primitive and base-centered lattices interchange in centering type, crystal structure Overview of all space groups Hurlbut, Cornelius S. Klein, Cornelis. Hahn, Theo, ed. International Tables for Crystallography, Volume A, Space Group Symmetry
5.
Crystallographic point group
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For a periodic crystal, the group must also be consistent with maintenance of the three-dimensional translational symmetry that defines crystallinity. The macroscopic properties of a crystal would look exactly the same before, in the classification of crystals, each point group is also known as a crystal class. There are infinitely many three-dimensional point groups, however, the crystallographic restriction of the infinite families of general point groups results in there being only 32 crystallographic point groups. These 32 point groups are one-and-the same as the 32 types of morphological crystalline symmetries derived in 1830 by Johann Friedrich Christian Hessel from a consideration of observed crystal forms, the point groups are denoted by their component symmetries. There are a few standard notations used by crystallographers, mineralogists, for the correspondence of the two systems below, see crystal system. In Schoenflies notation, point groups are denoted by a symbol with a subscript. The symbols used in crystallography mean the following, Cn indicates that the group has a rotation axis. Cnh is Cn with the addition of a plane perpendicular to the axis of rotation. Cnv is Cn with the addition of n mirror planes parallel to the axis of rotation, s2n denotes a group that contains only a 2n-fold rotation-reflection axis. Dn indicates that the group has a rotation axis plus n twofold axes perpendicular to that axis. Dnh has, in addition, a plane perpendicular to the n-fold axis. Dnd has, in addition to the elements of Dn, mirror planes parallel to the n-fold axis, the letter T indicates that the group has the symmetry of a tetrahedron. Td includes improper rotation operations, T excludes improper rotation operations, the letter O indicates that the group has the symmetry of an octahedron, with or without improper operations. Due to the crystallographic restriction theorem, n =1,2,3,4, d4d and D6d are actually forbidden because they contain improper rotations with n=8 and 12 respectively. The 27 point groups in the table plus T, Td, Th, O, an abbreviated form of the Hermann–Mauguin notation commonly used for space groups also serves to describe crystallographic point groups. Group names are Molecular symmetry Point group Space group Point groups in three dimensions Crystal system Point-group symbols in International Tables for Crystallography,12.1, pp. 818-820 Names and symbols of the 32 crystal classes in International Tables for Crystallography. 10.1, p.794 Pictorial overview of the 32 groups Point Groups - Flow Chart Inorganic Chemistry Group Theory Practice Problems
6.
H-M symbol
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In geometry, Hermann–Mauguin notation is used to represent the symmetry elements in point groups, plane groups and space groups. It is named after the German crystallographer Carl Hermann and the French mineralogist Charles-Victor Mauguin and this notation is sometimes called international notation, because it was adopted as standard by the International Tables For Crystallography since their first edition in 1935. Rotation axes are denoted by a number n —1,2,3,4,5,6,7,8, for improper rotations, Hermann–Mauguin symbols show rotoinversion axes, unlike Schoenflies and Shubnikov notations, where the preference is given to rotation-reflection axes. The rotoinversion axes are represented by the number with a macron. The symbol for a plane is m. The direction of the plane is defined as the direction of perpendicular to the face. Hermann–Mauguin symbols show symmetrically non-equivalent axes and planes, the direction of a symmetry element is represented by its position in the Hermann–Mauguin symbol. If a rotation axis n and a mirror plane m have the same direction, if two or more axes have the same direction, the axis with higher symmetry is shown. Higher symmetry means that the axis generates a pattern with more points, for example, rotation axes 3,4,5,6,7,8 generate 3-, 4-, 5-, 6-, 7-, 8-point patterns, respectively. Improper rotation axes 3,4,5,6,7,8 generate 6-, 4-, 10-, 6-, 14-, 8-point patterns, if both, the rotation and rotoinversion axes satisfy the previous rule, the rotation axis should be chosen. For example, 3/m combination is equivalent to 6, since 6 generates 6 points, and 3 generates only 3,6 should be written instead of 3/m. Analogously, in the case when both 3 and 3 axes are present,3 should be written, however we write 4/m, not 4/m, because both 4 and 4 generate four points. Finally, the Hermann–Mauguin symbol depends on the type of the group and these groups may contain only two-fold axes, mirror planes, and inversion center. These are the point groups 1 and 1,2, m, and 2/m, and 222, 2/m2/m2/m. If the symbol contains three positions, then they denote symmetry elements in the x, y, z direction, First position — primary direction — z direction, assigned to the higher-order axis. Second position — symmetrically equivalent secondary directions, which are perpendicular to the z-axis and these can be 2, m, or 2/m. Third position — symmetrically equivalent tertiary directions, passing between secondary directions and these can be 2, m, or 2/m. These are the crystallographic groups 3,32, 3m,3, and 32/m,4,422, 4mm,4, 42m, 4/m, and 4/m2/m2/m, and 6,622, 6mm,6, 6m2, 6/m, and 6/m2/m2/m
7.
Space group
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In mathematics, physics and chemistry, a space group is the symmetry group of a configuration in space, usually in three dimensions. In three dimensions, there are 219 distinct types, or 230 if chiral copies are considered distinct, Space groups are also studied in dimensions other than 3 where they are sometimes called Bieberbach groups, and are discrete cocompact groups of isometries of an oriented Euclidean space. In crystallography, space groups are called the crystallographic or Fedorov groups. A definitive source regarding 3-dimensional space groups is the International Tables for Crystallography, in 1879 Leonhard Sohncke listed the 65 space groups whose elements preserve the orientation. More accurately, he listed 66 groups, but Fedorov and Schönflies both noticed that two of them were really the same, the space groups in 3 dimensions were first enumerated by Fedorov, and shortly afterwards were independently enumerated by Schönflies. The correct list of 230 space groups was found by 1892 during correspondence between Fedorov and Schönflies, burckhardt describes the history of the discovery of the space groups in detail. The space groups in three dimensions are made from combinations of the 32 crystallographic point groups with the 14 Bravais lattices, the combination of all these symmetry operations results in a total of 230 different space groups describing all possible crystal symmetries. The elements of the space group fixing a point of space are rotations, reflections, the identity element, the translations form a normal abelian subgroup of rank 3, called the Bravais lattice. There are 14 possible types of Bravais lattice, the quotient of the space group by the Bravais lattice is a finite group which is one of the 32 possible point groups. Translation is defined as the moves from one point to another point. A glide plane is a reflection in a plane, followed by a parallel with that plane. This is noted by a, b or c, depending on which axis the glide is along. There is also the n glide, which is a glide along the half of a diagonal of a face, and the d glide, the latter is called the diamond glide plane as it features in the diamond structure. In 17 space groups, due to the centering of the cell, the glides occur in two directions simultaneously, i. e. the same glide plane can be called b or c, a or b. For example, group Abm2 could be also called Acm2, group Ccca could be called Cccb, in 1992, it was suggested to use symbol e for such planes. The symbols for five groups have been modified, A screw axis is a rotation about an axis. These are noted by a number, n, to describe the degree of rotation, the degree of translation is then added as a subscript showing how far along the axis the translation is, as a portion of the parallel lattice vector. So,21 is a rotation followed by a translation of 1/2 of the lattice vector
8.
Crystal structure
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In crystallography, crystal structure is a description of the ordered arrangement of atoms, ions or molecules in a crystalline material. Ordered structures occur from the nature of the constituent particles to form symmetric patterns that repeat along the principal directions of three-dimensional space in matter. The smallest group of particles in the material that constitutes the pattern is the unit cell of the structure. The unit cell completely defines the symmetry and structure of the crystal lattice. The repeating patterns are said to be located at the points of the Bravais lattice, the lengths of the principal axes, or edges, of the unit cell and the angles between them are the lattice constants, also called lattice parameters. The symmetry properties of the crystal are described by the concept of space groups, all possible symmetric arrangements of particles in three-dimensional space may be described by the 230 space groups. The crystal structure and symmetry play a role in determining many physical properties, such as cleavage, electronic band structure. The crystal structure of a material can be described in terms of its unit cell, the unit cell is a box containing one or more atoms arranged in three dimensions. The unit cells stacked in three-dimensional space describe the arrangement of atoms of the crystal. Commonly, atomic positions are represented in terms of fractional coordinates, the atom positions within the unit cell can be calculated through application of symmetry operations to the asymmetric unit. The asymmetric unit refers to the smallest possible occupation of space within the unit cell and this does not, however imply that the entirety of the asymmetric unit must lie within the boundaries of the unit cell. Symmetric transformations of atom positions are calculated from the group of the crystal structure. Vectors and planes in a lattice are described by the three-value Miller index notation. It uses the indices ℓ, m, and n as directional parameters, which are separated by 90°, by definition, the syntax denotes a plane that intercepts the three points a1/ℓ, a2/m, and a3/n, or some multiple thereof. That is, the Miller indices are proportional to the inverses of the intercepts of the plane with the unit cell, if one or more of the indices is zero, it means that the planes do not intersect that axis. A plane containing a coordinate axis is translated so that it no longer contains that axis before its Miller indices are determined, the Miller indices for a plane are integers with no common factors. Negative indices are indicated with horizontal bars, as in, in an orthogonal coordinate system for a cubic cell, the Miller indices of a plane are the Cartesian components of a vector normal to the plane. Likewise, the planes are geometric planes linking nodes
9.
Crystal habit
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In mineralogy, crystal habit is the characteristic external shape of an individual crystal or crystal group. A single crystals habit is a description of its shape and its crystallographic forms. Recognizing the habit may help in identifying a mineral, when the faces are well-developed due to uncrowded growth a crystal is called euhedral, one with partially developed faces is subhedral, and one with undeveloped crystal faces is called anhedral. The long axis of a quartz crystal typically has a six-sided prismatic habit with parallel opposite faces. Aggregates can be formed of individual crystals with euhedral to anhedral grains, the arrangement of crystals within the aggregate can be characteristic of certain minerals. For example, minerals used for asbestos insulation often grow in a fibrous habit, the terms used by mineralogists to report crystal habits describe the typical appearance of an ideal mineral. Recognizing the habit can aid in identification as some habits are characteristic, most minerals, however, do not display ideal habits due to conditions during crystallization. Minerals belonging to the crystal system do not necessarily exhibit the same habit. Some habits of a mineral are unique to its variety and locality, For example, while most sapphires form elongate barrel-shaped crystals, ordinarily, the latter habit is seen only in ruby. Sapphire and ruby are both varieties of the mineral, corundum. Some minerals may replace other existing minerals while preserving the originals habit, a classic example is tigers eye quartz, crocidolite asbestos replaced by silica. While quartz typically forms prismatic crystals, in tigers eye the original fibrous habit of crocidolite is preserved, the names of crystal habits are derived from, Predominant crystal faces. Abnormal grain growth Grain growth Crystallization
10.
Crystal twinning
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Crystal twinning occurs when two separate crystals share some of the same crystal lattice points in a symmetrical manner. The result is an intergrowth of two separate crystals in a variety of specific configurations, a twin boundary or composition surface separates the two crystals. Crystallographers classify twinned crystals by a number of twin laws and these twin laws are specific to the crystal system. The type of twinning can be a tool in mineral identification. Twinning can often be a problem in X-ray crystallography, as a crystal does not produce a simple diffraction pattern. Simple twinned crystals may be contact twins or penetration twins, contact twins share a single composition surface often appearing as mirror images across the boundary. Plagioclase, quartz, gypsum, and spinel often exhibit contact twinning, merohedral twinning occurs when the lattices of the contact twins superimpose in three dimensions, such as by relative rotation of one twin from the other. In penetration twins the individual crystals have the appearance of passing through each other in a symmetrical manner, orthoclase, staurolite, pyrite, and fluorite often show penetration twinning. If several twin crystal parts are aligned by the same twin law they are referred to as multiple or repeated twins, if these multiple twins are aligned in parallel they are called polysynthetic twins. When the multiple twins are not parallel they are cyclic twins, albite, calcite, and pyrite often show polysynthetic twinning. Closely spaced polysynthetic twinning is often observed as striations or fine lines on the crystal face. Rutile, aragonite, cerussite, and chrysoberyl often exhibit cyclic twinning, 2-normal twin, -when the twin plane and compositional plane lies noramally. 3-complex twin, -combination of parallel twinning and normal twinning on one compositional plane, there are three modes of formation of twinned crystals. Growth twins are the result of an interruption or change in the lattice during formation or growth due to a possible deformation from a larger substituting ion, deformation or gliding twins are the result of stress on the crystal after the crystal has formed. If a FCC metal like aluminum experiences extreme stresses, it will experience twinning as seen in the case of explosions, deformation twinning is a common result of regional metamorphism. Crystals that grow adjacent to each other may be aligned to resemble twinning and this parallel growth simply reduces system energy and is not twinning. Twin boundaries occur when two crystals of the same type intergrow, so only a slight misorientation exists between them. It is a highly symmetrical interface, often with one crystal the mirror image of the other, also and this is also a much lower-energy interface than the grain boundaries that form when crystals of arbitrary orientation grow together
11.
Cleavage (crystal)
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Cleavage, in mineralogy, is the tendency of crystalline materials to split along definite crystallographic structural planes. Cleavage forms parallel to planes, Basal or pinacoidal cleavage occurs when there is only one cleavage plane. Mica also has basal cleavage, this is why mica can be peeled into thin sheets, cubic cleavage occurs on when there are three cleavage planes intersecting at 90 degrees. Halite has cubic cleavage, and therefore, when halite crystals are broken, octahedral cleavage occurs when there are four cleavage planes in a crystal. Octahedral cleavage is common for semiconductors, rhombohedral cleavage occurs when there are three cleavage planes intersecting at angles that are not 90 degrees. Prismatic cleavage occurs when there are two planes in a crystal. Dodecahedral cleavage occurs when there are six cleavage planes in a crystal, crystal parting occurs when minerals break along planes of structural weakness due to external stress or along twin composition planes. Parting breaks are very similar in appearance to cleavage, but only due to stress. Examples include magnetite which shows octahedral parting, the parting of corundum. Cleavage is a property traditionally used in mineral identification, both in hand specimen and microscopic examination of rock and mineral studies. As an example, the angles between the cleavage planes for the pyroxenes and the amphiboles are diagnostic. Crystal cleavage is of importance in the electronics industry and in the cutting of gemstones. Precious stones are generally cleaved by impact, as in diamond cutting, synthetic single crystals of semiconductor materials are generally sold as thin wafers which are much easier to cleave. Elemental semiconductors are diamond cubic, a group for which octahedral cleavage is observed. This means that some orientations of wafer allow near-perfect rectangles to be cleaved, most other commercial semiconductors can be made in the related zinc blende structure, with similar cleavage planes. Cleavage Mineral galleries, Mineral properties – Cleavage
12.
Fracture (mineralogy)
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In the field of mineralogy, fracture is the texture and shape of a rocks surface formed when a mineral is fractured. Minerals often have a highly distinctive fracture, making it a feature used in their identification. Fracture differs from cleavage in that the latter involves clean splitting along the planes of the minerals crystal structure. All minerals exhibit fracture, but when very strong cleavage is present, conchoidal fracture breakage that resembles the concentric ripples of a mussel shell. It often occurs in amorphous or fine-grained minerals such as flint, opal or obsidian, subconchoidal fracture is similar to conchoidal fracture, but with less significant curvature. Earthy fracture is reminiscent of freshly broken soil and it is frequently seen in relatively soft, loosely bound minerals, such as limonite, kaolinite and aluminite. Hackly fracture is jagged, sharp and not even and it occurs when metals are torn, and so is often encountered in native metals such as copper and silver. Splintery fracture comprises sharp elongated points and it is particularly seen in fibrous minerals such as chrysotile, but may also occur in non-fibrous minerals such as kyanite. Uneven fracture is a surface or one with random irregularities. It occurs in a range of minerals including arsenopyrite, pyrite and magnetite. Rudolf Duda and Lubos Rejl, Minerals of the World http, //www. galleries. com/minerals/property/fracture. htm
13.
Mohs scale of mineral hardness
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The Mohs scale of mineral hardness is a qualitative ordinal scale characterizing scratch resistance of various minerals through the ability of harder material to scratch softer material. Created in 1812 by German geologist and mineralogist Friedrich Mohs, it is one of several definitions of hardness in materials science, while greatly facilitating the identification of minerals in the field, the Mohs scale does not show how well hard materials perform in an industrial setting. Despite its lack of precision, the Mohs scale is highly relevant for field geologists, the Mohs scale hardness of minerals can be commonly found in reference sheets. Reference materials may be expected to have a uniform Mohs hardness, the Mohs scale of mineral hardness is based on the ability of one natural sample of mineral to scratch another mineral visibly. The samples of matter used by Mohs are all different minerals, Minerals are pure substances found in nature. Rocks are made up of one or more minerals, as the hardest known naturally occurring substance when the scale was designed, diamonds are at the top of the scale. The hardness of a material is measured against the scale by finding the hardest material that the material can scratch. For example, if material is scratched by apatite but not by fluorite. Scratching a material for the purposes of the Mohs scale means creating non-elastic dislocations visible to the naked eye, frequently, materials that are lower on the Mohs scale can create microscopic, non-elastic dislocations on materials that have a higher Mohs number. The Mohs scale is an ordinal scale. For example, corundum is twice as hard as topaz, the table below shows the comparison with the absolute hardness measured by a sclerometer, with pictorial examples. On the Mohs scale, a streak plate has a hardness of 7.0, using these ordinary materials of known hardness can be a simple way to approximate the position of a mineral on the scale. The table below incorporates additional substances that may fall between levels, Comparison between Hardness and Hardness, Mohs hardness of elements is taken from G. V, samsonov in Handbook of the physicochemical properties of the elements, IFI-Plenum, New York, USA,1968. The Hardness of Minerals and Rocks
14.
Lustre (mineralogy)
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Lustre or luster is the way light interacts with the surface of a crystal, rock, or mineral. The word traces its origins back to the latin lux, meaning light, a range of terms are used to describe lustre, such as earthy, metallic, greasy, and silky. Similarly, the term refers to a glassy lustre. A list of terms is given below. Lustre varies over a continuum, and so there are no rigid boundaries between the different types of lustre. The terms are frequently combined to describe types of lustre. Some minerals exhibit unusual optical phenomena, such as asterism or chatoyancy, a list of such phenomena is given below. Adamantine minerals possess a superlative lustre, which is most notably seen in diamond, such minerals are transparent or translucent, and have a high refractive index. Minerals with an adamantine lustre are uncommon, with examples being cerussite. Minerals with a degree of lustre are referred to as subadamantine, with some examples being garnet. Dull minerals exhibit little to no lustre, due to coarse granulations which scatter light in all directions, a distinction is sometimes drawn between dull minerals and earthy minerals, with the latter being coarser, and having even less lustre. Greasy minerals resemble fat or grease, a greasy lustre often occurs in minerals containing a great abundance of microscopic inclusions, with examples including opal and cordierite. Many minerals with a greasy lustre also feel greasy to the touch, metallic minerals have the lustre of polished metal, and with ideal surfaces will work as a reflective surface. Examples include galena, pyrite and magnetite, pearly minerals consist of thin transparent co-planar sheets. Light reflecting from these layers give them a lustre reminiscent of pearls, such minerals possess perfect cleavage, with examples including muscovite and stilbite. Resinous minerals have the appearance of resin, chewing gum or plastic, a principal example is amber, which is a form of fossilized resin. Silky minerals have an arrangement of extremely fine fibres, giving them a lustre reminiscent of silk. Examples include asbestos, ulexite and the satin spar variety of gypsum, a fibrous lustre is similar, but has a coarser texture
15.
Streak (mineralogy)
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The streak of a mineral is the color of the powder produced when it is dragged across an un-weathered surface. If no streak seems to be made, the streak is said to be white or colorless. Streak is particularly important as a diagnostic for opaque and colored materials and it is less useful for silicate minerals, most of which have a white streak or are too hard to powder easily. The apparent color of a mineral can vary widely because of impurities or a disturbed macroscopic crystal structure. Small amounts of an impurity that strongly absorbs a particular wavelength can radically change the wavelengths of light that are reflected by the specimen, and thus change the apparent color. However, when the specimen is dragged to produce a streak, it is broken into randomly oriented microscopic crystals, the surface across which the mineral is dragged is called a streak plate, and is generally made of unglazed porcelain tile. In the absence of a plate, the unglazed underside of a porcelain bowl or vase or the back of a glazed tile will work. Sometimes a streak is more easily or accurately described by comparing it with the streak made by another streak plate. Because the trail left behind results from the mineral being crushed into powder, in case of harder minerals, the color of the powder can be determined by filing or crushing with a hammer a small sample, which is then usually rubbed on a streak plate. Most minerals that are harder have a white streak. Some minerals leave a similar to their natural color, such as cinnabar. Other minerals leave surprising colors, such as fluorite, which always has a streak, although it can appear in purple, blue, yellow. Hematite, which is black in appearance, leaves a red streak which accounts for its name, galena, which can be similar in appearance to hematite, is easily distinguished by its gray streak. Hamilton, W. R. Cambridge Guide to Minerals, Rocks, the Encyclopedia of Gemstones and Minerals. New York, Facts on File. p.251, physical Characteristics of Minerals, at Introduction to Mineralogy by Andrea Bangert What is Streak
16.
Transparency and translucency
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In the field of optics, transparency is the physical property of allowing light to pass through the material without being scattered. On a macroscopic scale, the photons can be said to follow Snells Law, in other words, a translucent medium allows the transport of light while a transparent medium not only allows the transport of light but allows for image formation. The opposite property of translucency is opacity, transparent materials appear clear, with the overall appearance of one color, or any combination leading up to a brilliant spectrum of every color. When light encounters a material, it can interact with it in different ways. These interactions depend on the wavelength of the light and the nature of the material, photons interact with an object by some combination of reflection, absorption and transmission. Some materials, such as glass and clean water, transmit much of the light that falls on them and reflect little of it. Many liquids and aqueous solutions are highly transparent, absence of structural defects and molecular structure of most liquids are mostly responsible for excellent optical transmission. Materials which do not transmit light are called opaque, many such substances have a chemical composition which includes what are referred to as absorption centers. Many substances are selective in their absorption of light frequencies. They absorb certain portions of the spectrum while reflecting others. The frequencies of the spectrum which are not absorbed are either reflected or transmitted for our physical observation and this is what gives rise to color. The attenuation of light of all frequencies and wavelengths is due to the mechanisms of absorption. Transparency can provide almost perfect camouflage for animals able to achieve it and this is easier in dimly-lit or turbid seawater than in good illumination. Many marine animals such as jellyfish are highly transparent, at the atomic or molecular level, physical absorption in the infrared portion of the spectrum depends on the frequencies of atomic or molecular vibrations or chemical bonds, and on selection rules. Nitrogen and oxygen are not greenhouse gases because there is no absorption because there is no molecular dipole moment. With regard to the scattering of light, the most critical factor is the scale of any or all of these structural features relative to the wavelength of the light being scattered. Primary material considerations include, Crystalline structure, whether or not the atoms or molecules exhibit the long-range order evidenced in crystalline solids, glassy structure, scattering centers include fluctuations in density or composition. Microstructure, scattering centers include internal surfaces such as boundaries, crystallographic defects
17.
Specific gravity
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This page is about the measurement using water as a reference. For a general use of gravity, see relative density. See intensive property for the property implied by specific, Apparent specific gravity is the ratio of the weight of a volume of the substance to the weight of an equal volume of the reference substance. The reference substance is always water at its densest for liquids. Nonetheless, the temperature and pressure must be specified for both the sample and the reference, pressure is nearly always 1 atm. Temperatures for both sample and reference vary from industry to industry, in British beer brewing, the practice for specific gravity as specified above is to multiply it by 1000. Being a ratio of densities, specific gravity is a dimensionless quantity, Specific gravity varies with temperature and pressure, reference and sample must be compared at the same temperature and pressure or be corrected to a standard reference temperature and pressure. Substances with a gravity of 1 are neutrally buoyant in water. Those with SG greater than 1 are denser than water and will, disregarding surface tension effects and those with an SG less than 1 are less dense than water and will float on it. In scientific work, the relationship of mass to volume is expressed directly in terms of the density of the substance under study. It is in industry where specific gravity finds wide application, often for historical reasons. True specific gravity can be expressed mathematically as, S G true = ρ sample ρ H2 O where ρ sample is the density of the sample, the density of water varies with temperature and pressure as does the density of the sample. So it is necessary to specify the temperatures and pressures at which the densities or weights were determined and it is nearly always the case that measurements are made at 1 nominal atmosphere. For true specific gravity calculations, air pressure must be considered, temperatures are specified by the notation with T s representing the temperature at which the samples density was determined and T r the temperature at which the reference density is specified. For example, SG would be understood to mean that the density of the sample was determined at 20°C and of the water at 4°C. Taking into account different sample and reference temperatures, we note that, while S G H2 O =1.000000, it is also the case that S G H2 O =0.998203 /0.999840 =0.998363. Here, temperature is being specified using the current ITS-90 scale, on the previous IPTS-68 scale, the densities at 20 °C and 4 °C are 0.9982071 and 0.9999720 respectively, resulting in an SG value for water of 0.9982343. For example, in the industry, the Plato table lists sucrose concentration by weight against true SG
18.
Silicate minerals
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Silicate minerals are rock-forming minerals made up of silicate groups. They are the largest and most important class of rock-forming minerals and they are classified based on the structure of their silicate groups, which contain different ratios of silicon and oxygen. Nesosilicates, or orthosilicates, have the orthosilicate ion, which constitute isolated 4− tetrahedra that are connected only by interstitial cations and these exist as 3-member 6− and 6-member 12− rings, where T stands for a tetrahedrally coordinated cation. Inosilicates, or chain silicates, have interlocking chains of silicate tetrahedra with either SiO3,1,3 ratio, for single chains or Si4O11,4,11 ratio, for double chains. Nickel–Strunz classification,09. D Pyroxene group Enstatite – orthoferrosilite series Enstatite – MgSiO3 Ferrosilite – FeSiO3 Pigeonite – Ca0.251, all phyllosilicate minerals are hydrated, with either water or hydroxyl groups attached. Serpentine subgroup Antigorite – Mg3Si2O54 Chrysotile – Mg3Si2O54 Lizardite – Mg3Si2O54 Clay minerals group Halloysite – Al2Si2O54 Kaolinite – Al2Si2O54 Illite – 24O10 Montmorillonite –0 and this group comprises nearly 75% of the crust of the Earth. Tectosilicates, with the exception of the group, are aluminosilicates. Nickel–Strunz classification,09. F and 09. G,04. A, an introduction to the rock-forming minerals. Wise, W. S. Zussman, J. Rock-forming minerals, P.982 pp. Hurlbut, Cornelius S. Danas Manual of Mineralogy. Mindat. org, Dana classification Webmineral, Danas New Silicate Classification Media related to Silicates at Wikimedia Commons
19.
Mineral
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A mineral is a naturally occurring chemical compound, usually of crystalline form and abiogenic in origin. A mineral has one specific chemical composition, whereas a rock can be an aggregate of different minerals or mineraloids, the study of minerals is called mineralogy. There are over 5,300 known mineral species, over 5,070 of these have been approved by the International Mineralogical Association, the silicate minerals compose over 90% of the Earths crust. The diversity and abundance of species is controlled by the Earths chemistry. Silicon and oxygen constitute approximately 75% of the Earths crust, which translates directly into the predominance of silicate minerals, minerals are distinguished by various chemical and physical properties. Differences in chemical composition and crystal structure distinguish the various species, changes in the temperature, pressure, or bulk composition of a rock mass cause changes in its minerals. Minerals can be described by their various properties, which are related to their chemical structure. Common distinguishing characteristics include crystal structure and habit, hardness, lustre, diaphaneity, colour, streak, tenacity, cleavage, fracture, parting, more specific tests for describing minerals include magnetism, taste or smell, radioactivity and reaction to acid. Minerals are classified by key chemical constituents, the two dominant systems are the Dana classification and the Strunz classification, the silicate class of minerals is subdivided into six subclasses by the degree of polymerization in the chemical structure. All silicate minerals have a unit of a 4− silica tetrahedron—that is, a silicon cation coordinated by four oxygen anions. These tetrahedra can be polymerized to give the subclasses, orthosilicates, disilicates, cyclosilicates, inosilicates, phyllosilicates, other important mineral groups include the native elements, sulfides, oxides, halides, carbonates, sulfates, and phosphates. The first criterion means that a mineral has to form by a natural process, stability at room temperature, in the simplest sense, is synonymous to the mineral being solid. More specifically, a compound has to be stable or metastable at 25 °C, modern advances have included extensive study of liquid crystals, which also extensively involve mineralogy. Minerals are chemical compounds, and as such they can be described by fixed or a variable formula, many mineral groups and species are composed of a solid solution, pure substances are not usually found because of contamination or chemical substitution. Finally, the requirement of an ordered atomic arrangement is usually synonymous with crystallinity, however, crystals are also periodic, an ordered atomic arrangement gives rise to a variety of macroscopic physical properties, such as crystal form, hardness, and cleavage. There have been recent proposals to amend the definition to consider biogenic or amorphous substances as minerals. The formal definition of an approved by the IMA in 1995, A mineral is an element or chemical compound that is normally crystalline. However, if geological processes were involved in the genesis of the compound, Mineral classification schemes and their definitions are evolving to match recent advances in mineral science
20.
Zeolite
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Zeolites are microporous, aluminosilicate minerals commonly used as commercial adsorbents and catalysts. Based on this, he called the material zeolite, from the Greek ζέω, meaning to boil and λίθος, the classic reference for the field has been Zeolite molecular sieves, structure, chemistry, and use by Donald W. Breck. Zeolites occur naturally but are produced industrially on a large scale. As of September 2016,232 unique zeolite frameworks have been identified, every new zeolite structure that is obtained has to be approved by the International Zeolite Association Structure Commission and receives a three letter designation. Zeolites have a structure that can accommodate a wide variety of cations, such as Na+, K+, Ca2+, Mg2+. These positive ions are rather loosely held and can readily be exchanged for others in a contact solution, some of the more common mineral zeolites are analcime, chabazite, clinoptilolite, heulandite, natrolite, phillipsite, and stilbite. An example of the formula of a zeolite is, Na2Al2Si3O10·2H2O. Natural zeolites form where volcanic rocks and ash layers react with alkaline groundwater, Zeolites also crystallize in post-depositional environments over periods ranging from thousands to millions of years in shallow marine basins. Naturally occurring zeolites are rarely pure and are contaminated to varying degrees by other minerals, metals, quartz, for this reason, naturally occurring zeolites are excluded from many important commercial applications where uniformity and purity are essential. Zeolites are the members of the family of microporous solids known as molecular sieves mainly consisting of Si, Al, O, and metals including Ti, Sn, Zn. The term molecular sieve refers to a property of these materials. This is due to a very regular structure of molecular dimensions. The maximum size of the molecular or ionic species that can enter the pores of a zeolite is controlled by the dimensions of the channels, therefore, the pores in many zeolites are not cylindrical. Zeolites transform to other minerals under weathering, hydrothermal alteration or metamorphic conditions, the sequence of silica-poor volcanic rocks commonly progresses from, Cowlesite → levyne–offretite → analcime → thomsonite–mesolite-scolecite → chabazite → calcite. Industrially important zeolites are produced synthetically, typical procedures entail heating aqueous solutions of alumina and silica with sodium hydroxide. Equivalent reagents include sodium aluminate and sodium silicate, further variations include changes in the cations to include quaternary ammonium cations. Synthetic zeolites hold some key advantages over their natural analogues, the synthetic materials are manufactured in a uniform, phase-pure state. It is also possible to produce zeolite structures that do not appear in nature, Zeolite A is a well-known example
21.
Sodium
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Sodium is a chemical element with symbol Na and atomic number 11. It is a soft, silvery-white, highly reactive metal, Sodium is an alkali metal, being in group 1 of the periodic table, because it has a single electron in its outer shell that it readily donates, creating a positively charged atom—the Na+ cation. Its only stable isotope is 23Na, the free metal does not occur in nature, but must be prepared from compounds. Sodium is the sixth most abundant element in the Earths crust, Sodium was first isolated by Humphry Davy in 1807 by the electrolysis of sodium hydroxide. Among many other useful compounds, sodium hydroxide is used in soap manufacture, and sodium chloride is a de-icing agent. Sodium is an element for all animals and some plants. Sodium ions are the major cation in the fluid and as such are the major contributor to the ECF osmotic pressure. Loss of water from the ECF compartment increases the sodium concentration, isotonic loss of water and sodium from the ECF compartment decreases the size of that compartment in a condition called ECF hypovolemia. In nerve cells, the charge across the cell membrane enables transmission of the nerve impulse—an action potential—when the charge is dissipated. The melting and boiling points of sodium are lower than those of lithium but higher than those of the alkali metals potassium, rubidium. All of these high-pressure allotropes are insulators and electrides.3 nm, spin-orbit interactions involving the electron in the 3p orbital split the D line into two, at 589.0 and 589.6 nm, hyperfine structures involving both orbitals cause many more lines. Twenty isotopes of sodium are known, but only 23Na is stable, 23Na is created in the carbon-burning process in stars by fusing two carbon atoms together, this requires temperatures above 600 megakelvins and a star of at least three solar masses. Two nuclear isomers have been discovered, the one being 24mNa with a half-life of around 20.2 milliseconds. Sodium atoms have 11 electrons, one more than the stable configuration of the noble gas neon. This process requires so little energy that sodium is oxidized by giving up its 11th electron. In contrast, the ionization energy is very high, because the 10th electron is closer to the nucleus than the 11th electron. As a result, sodium usually forms ionic compounds involving the Na+ cation, the most common oxidation state for sodium is +1. It is generally less reactive than potassium and more reactive than lithium, Sodium metal is highly reducing, with the reduction of sodium ions requiring −2.71 volts, though potassium and lithium have even more negative potentials
22.
Aluminium
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Aluminium or aluminum is a chemical element in the boron group with symbol Al and atomic number 13. It is a silvery-white, soft, nonmagnetic, ductile metal, Aluminium metal is so chemically reactive that native specimens are rare and limited to extreme reducing environments. Instead, it is combined in over 270 different minerals. The chief ore of aluminium is bauxite, Aluminium is remarkable for the metals low density and its ability to resist corrosion through the phenomenon of passivation. Aluminium and its alloys are vital to the industry and important in transportation and structures, such as building facades. The oxides and sulfates are the most useful compounds of aluminium, despite its prevalence in the environment, no known form of life uses aluminium salts metabolically, but aluminium is well tolerated by plants and animals. Because of these salts abundance, the potential for a role for them is of continuing interest. Aluminium is a soft, durable, lightweight, ductile. It is nonmagnetic and does not easily ignite, a fresh film of aluminium serves as a good reflector of visible light and an excellent reflector of medium and far infrared radiation. The yield strength of aluminium is 7–11 MPa, while aluminium alloys have yield strengths ranging from 200 MPa to 600 MPa. Aluminium has about one-third the density and stiffness of steel and it is easily machined, cast, drawn and extruded. Aluminium atoms are arranged in a cubic structure. Aluminium has an energy of approximately 200 mJ/m2. Aluminium is a thermal and electrical conductor, having 59% the conductivity of copper. Aluminium is capable of superconductivity, with a critical temperature of 1.2 kelvin. Aluminium is the most common material for the fabrication of superconducting qubits, the strongest aluminium alloys are less corrosion resistant due to galvanic reactions with alloyed copper. This corrosion resistance is reduced by aqueous salts, particularly in the presence of dissimilar metals. In highly acidic solutions, aluminium reacts with water to form hydrogen, primarily because it is corroded by dissolved chlorides, such as common sodium chloride, household plumbing is never made from aluminium
23.
Silicate
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A silicate is a compound containing an anionic silicon compound. The great majority of the silicates are oxides, but hexafluorosilicate, orthosilicate is the anion SiO4−4 or its compounds. Related to orthosilicate are families of anions with the formula 2n−, important members are the cyclic and single chain silicates n and the sheet-forming silicates n. Silicates constitute the majority of Earths crust, as well as the terrestrial planets, rocky moons. Sand, Portland cement, and thousands of minerals are examples of silicates, silicate compounds, including the minerals, consist of silicate anions whose charge is balanced by various cations. Myriad silicate anions can exist, and each can form compounds with many different cations, hence this class of compounds is very large. Both minerals and synthetic materials fit in this class, in the vast majority of silicates, including silicate minerals, the Si occupies a tetrahedral environment, being surrounded by 4 oxygen centres. In these structures, the bonds to silicon conform to the octet rule. These tetrahedra sometimes occur as isolated SiO4−4 centres, but most commonly, commonly the silicate anions are chains, double chains, sheets, and three-dimensional frameworks. All these such species have negligible solubility in water at normal conditions, silicates are well characterized as solids, but are less commonly observed in solution. The anion SiO4−4 is the base of silicic acid, Si4. Instead, solutions of silicates are usually observed as mixtures of condensed, the nature of soluble silicates is relevant to understanding biomineralization and the synthesis of aluminosilicates, such as the industrially important catalysts called zeolites. Although the tetrahedron is the coordination geometry for silicon compounds. A well-known example of such a high number is hexafluorosilicate. Octahedral coordination by 6 oxygen centres is observed, at very high pressure, even SiO2 adopts this geometry in the mineral stishovite, a dense polymorph of silica found in the lower mantle of the Earth. This structure is formed by shock during meteorite impacts. In geology and astronomy, the silicate is used to denote types of rock that consist predominantly of silicate minerals. On Earth, a variety of silicate minerals occur in an even wider range of combinations as a result of the processes that form
24.
Silicon
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Silicon is a chemical element with symbol Si and atomic number 14. A hard and brittle crystalline solid with a metallic luster. It is a member of group 14 in the table, along with carbon above it and germanium, tin, lead. It is not very reactive, although more reactive than germanium, Silicon is the eighth most common element in the universe by mass, but very rarely occurs as the pure element in the Earths crust. It is most widely distributed in dusts, sands, planetoids, over 90% of the Earths crust is composed of silicate minerals, making silicon the second most abundant element in the Earths crust after oxygen. Most silicon is used commercially without being separated, and often with little processing of the natural minerals, such use includes industrial construction with clays, silica sand, and stone. Silicate is used in Portland cement for mortar and stucco, and mixed with sand and gravel to make concrete for walkways, foundations. Silicates are used in whiteware ceramics such as porcelain, and in traditional quartz-based soda-lime glass, Silicon compounds such as silicon carbide are used as abrasives and components of high-strength ceramics. Elemental silicon also has an impact on the modern world economy. Most free silicon is used in the refining, aluminium-casting. Silicon is the basis of the widely used synthetic polymers called silicones, Silicon is an essential element in biology, although only tiny traces are required by animals. However, various sea sponges and microorganisms, such as diatoms and radiolaria, silica is deposited in many plant tissues, such as in the bark and wood of Chrysobalanaceae and the silica cells and silicified trichomes of Cannabis sativa, horsetails and many grasses. Silicon is a solid at room temperature, with a point of 1,414 °C. Like water, it has a density in a liquid state than in a solid state and it expands when it freezes. With a relatively high conductivity of 149 W·m−1·K−1, silicon conducts heat well. In its crystalline form, pure silicon has a gray color, like germanium, silicon is rather strong, very brittle, and prone to chipping. Silicon, like carbon and germanium, crystallizes in a cubic crystal structure with a lattice spacing of 0.5430710 nm. The outer electron orbital of silicon, like that of carbon, has four valence electrons, the 1s, 2s, 2p and 3s subshells are completely filled while the 3p subshell contains two electrons out of a possible six
25.
Oxygen
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Oxygen is a chemical element with symbol O and atomic number 8. It is a member of the group on the periodic table and is a highly reactive nonmetal. By mass, oxygen is the third-most abundant element in the universe, after hydrogen, at standard temperature and pressure, two atoms of the element bind to form dioxygen, a colorless and odorless diatomic gas with the formula O2. This is an important part of the atmosphere and diatomic oxygen gas constitutes 20. 8% of the Earths atmosphere, additionally, as oxides the element makes up almost half of the Earths crust. Most of the mass of living organisms is oxygen as a component of water, conversely, oxygen is continuously replenished by photosynthesis, which uses the energy of sunlight to produce oxygen from water and carbon dioxide. Oxygen is too reactive to remain a free element in air without being continuously replenished by the photosynthetic action of living organisms. Another form of oxygen, ozone, strongly absorbs ultraviolet UVB radiation, but ozone is a pollutant near the surface where it is a by-product of smog. At low earth orbit altitudes, sufficient atomic oxygen is present to cause corrosion of spacecraft, the name oxygen was coined in 1777 by Antoine Lavoisier, whose experiments with oxygen helped to discredit the then-popular phlogiston theory of combustion and corrosion. One of the first known experiments on the relationship between combustion and air was conducted by the 2nd century BCE Greek writer on mechanics, Philo of Byzantium. In his work Pneumatica, Philo observed that inverting a vessel over a burning candle, Philo incorrectly surmised that parts of the air in the vessel were converted into the classical element fire and thus were able to escape through pores in the glass. Many centuries later Leonardo da Vinci built on Philos work by observing that a portion of air is consumed during combustion and respiration, Oxygen was discovered by the Polish alchemist Sendivogius, who considered it the philosophers stone. In the late 17th century, Robert Boyle proved that air is necessary for combustion, English chemist John Mayow refined this work by showing that fire requires only a part of air that he called spiritus nitroaereus. From this he surmised that nitroaereus is consumed in both respiration and combustion, Mayow observed that antimony increased in weight when heated, and inferred that the nitroaereus must have combined with it. Accounts of these and other experiments and ideas were published in 1668 in his work Tractatus duo in the tract De respiratione. Robert Hooke, Ole Borch, Mikhail Lomonosov, and Pierre Bayen all produced oxygen in experiments in the 17th and the 18th century but none of them recognized it as a chemical element. This may have been in part due to the prevalence of the philosophy of combustion and corrosion called the phlogiston theory, which was then the favored explanation of those processes. Established in 1667 by the German alchemist J. J. Becher, one part, called phlogiston, was given off when the substance containing it was burned, while the dephlogisticated part was thought to be its true form, or calx. The fact that a substance like wood gains overall weight in burning was hidden by the buoyancy of the combustion products
26.
Water of crystallization
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In chemistry, water of crystallization or water of hydration or crystallization water is water that occurs inside crystals. Water is often incorporated in the formation of crystals from aqueous solutions, in some contexts, water of crystallization is the total weight of water in a substance at a given temperature and is mostly present in a definite ratio. Classically, water of crystallization refers to water that is found in the framework of a metal complex or a salt. Upon crystallization from water or moist solvents, many compounds incorporate water molecules in their crystalline frameworks, water of crystallization can generally be removed by heating a sample but the crystalline properties are often lost. For example, in the case of chloride, the dihydrate is unstable at room temperature. Compared to inorganic salts, proteins crystallize with large amounts of water in the crystal lattice, the water content of 50% is not uncommon for proteins. For example Calcium chloride, CaCl2·2H2O hydrated compoundn A hydrate with coordinated water, for example Zinc chloride, ZnCl24 Both notations can be combined as for example in copper sulfate, SO4·H2O A salt with associated water of crystallization is known as a hydrate. The structure of hydrates can be elaborate, because of the existence of hydrogen bonds that define polymeric structures. Historically, the structures of many hydrates were unknown, and the dot in the formula of a hydrate was employed to specify the composition without indicating how the water is bound, for example, an aqueous solution prepared from CuSO4•5H2O and anhydrous CuSO4 behave identically. Therefore, knowledge of the degree of hydration is important only for determining the equivalent weight, in some cases, the degree of hydration can be critical to the resulting chemical properties. For example, anhydrous RhCl3 is not soluble in water and is useless in organometallic chemistry whereas RhCl3•3H2O is versatile. Similarly, hydrated AlCl3 is a poor Lewis acid and thus inactive as a catalyst for Friedel-Crafts reactions, samples of AlCl3 must therefore be protected from atmospheric moisture to preclude the formation of hydrates. Crystals of the aforementioned hydrated copper sulfate consist of 2+ centers linked to SO42− ions, copper is surrounded by six oxygen atoms, provided by two different sulfate groups and four molecules of water. A fifth water resides elsewhere in the framework but does not bind directly to copper, the cobalt chloride mentioned above occurs as 2+ and Cl−. In tin chloride, each Sn center is pyramidal being bound to two chloride ions and one water, the second water in the formula unit is hydrogen-bonded to the chloride and to the coordinated water molecule. Water of crystallization is stabilized by electrostatic attractions, consequently hydrates are common for salts that contain +2, in some cases, the majority of the weight of a compound arises from water. Glaubers salt, Na2SO410, is a crystalline solid with greater than 50% water by weight. Consider the case of nickel chloride hexahydrate and this species has the formula NiCl26
27.
Germany
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Germany, officially the Federal Republic of Germany, is a federal parliamentary republic in central-western Europe. It includes 16 constituent states, covers an area of 357,021 square kilometres, with about 82 million inhabitants, Germany is the most populous member state of the European Union. After the United States, it is the second most popular destination in the world. Germanys capital and largest metropolis is Berlin, while its largest conurbation is the Ruhr, other major cities include Hamburg, Munich, Cologne, Frankfurt, Stuttgart, Düsseldorf and Leipzig. Various Germanic tribes have inhabited the northern parts of modern Germany since classical antiquity, a region named Germania was documented before 100 AD. During the Migration Period the Germanic tribes expanded southward, beginning in the 10th century, German territories formed a central part of the Holy Roman Empire. During the 16th century, northern German regions became the centre of the Protestant Reformation, in 1871, Germany became a nation state when most of the German states unified into the Prussian-dominated German Empire. After World War I and the German Revolution of 1918–1919, the Empire was replaced by the parliamentary Weimar Republic, the establishment of the national socialist dictatorship in 1933 led to World War II and the Holocaust. After a period of Allied occupation, two German states were founded, the Federal Republic of Germany and the German Democratic Republic, in 1990, the country was reunified. In the 21st century, Germany is a power and has the worlds fourth-largest economy by nominal GDP. As a global leader in industrial and technological sectors, it is both the worlds third-largest exporter and importer of goods. Germany is a country with a very high standard of living sustained by a skilled. It upholds a social security and universal health system, environmental protection. Germany was a member of the European Economic Community in 1957. It is part of the Schengen Area, and became a co-founder of the Eurozone in 1999, Germany is a member of the United Nations, NATO, the G8, the G20, and the OECD. The national military expenditure is the 9th highest in the world, the English word Germany derives from the Latin Germania, which came into use after Julius Caesar adopted it for the peoples east of the Rhine. This in turn descends from Proto-Germanic *þiudiskaz popular, derived from *þeudō, descended from Proto-Indo-European *tewtéh₂- people, the discovery of the Mauer 1 mandible shows that ancient humans were present in Germany at least 600,000 years ago. The oldest complete hunting weapons found anywhere in the world were discovered in a mine in Schöningen where three 380, 000-year-old wooden javelins were unearthed
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Martin Heinrich Klaproth
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Martin Heinrich Klaproth was a German chemist who discovered uranium, zirconium, and cerium. During a large portion of his life he followed the profession of an apothecary, in 1787 he was appointed lecturer in chemistry to the Prussian Royal Artillery, and when the university was founded in 1810 he was selected to be the professor of chemistry. He died in Berlin on New Years Day in 1817, Klaproth was the leading chemist of his time in Germany. He was the first to discover uranium while studying the mineral pitchblende and his papers, over 200 in number, were collected by himself in Beiträge zur chemischen Kenntnis der Mineralkörper and Chemische Abhandlungen gemischten Inhalts. He also published a Chemisches Wörterbuch, and edited an edition of F. A. C. Klaproth was elected a Fellow of the Royal Society in 1795, the crater Klaproth on the Moon is named after him. His son Julius was a famous orientalist, Beiträge Zur Chemischen Kenntniss Der Mineralkörper. Rottmann, Berlin 1795-1810 Digital edition by the University and State Library Düsseldorf Chemisches Wörterbuch, voss, Berlin 1807-1819 Digital edition by the University and State Library Düsseldorf Chemische Abhandlungen gemischten Inhalts. Nicolai, Berlin 1815 Digital edition by the University and State Library Düsseldorf German inventors and discoverers Publication list of Klaproth
29.
Acicular (crystal habit)
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Acicular, in mineralogy, refers to a crystal habit composed of slender, needle-like crystals. Crystals with this habit tend to be fragile, complete, undamaged acicular specimens are uncommon. The term acicular derives from the Late Latin acicula meaning little needle, strictly speaking, the word refers to a growth habit that is slender and tapering to a point. Prismatic crystals are not acicular, however, colloquial usage has altered the commonly understood meaning of the word, when writing for mineralogical publications, authors should restrict their usage of acicular to crystals with the tapering growth habit. To add to the confusion, some minerals are described with various morphological terms, for example, natrolite is often described as slender prismatic and millerite is often described as filiform or capillary. Minerals with an acicular habit include mesolite, natrolite, malachite, gypsum, rutile, crystals of dimethyltryptamine have an acicular habit, but this substance is not regarded as a mineral by the International Mineralogical Association
30.
Crystal
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A crystal or crystalline solid is a solid material whose constituents are arranged in a highly ordered microscopic structure, forming a crystal lattice that extends in all directions. In addition, macroscopic single crystals are usually identifiable by their geometrical shape, the scientific study of crystals and crystal formation is known as crystallography. The process of crystal formation via mechanisms of crystal growth is called crystallization or solidification, the word crystal derives from the Ancient Greek word κρύσταλλος, meaning both ice and rock crystal, from κρύος, icy cold, frost. Examples of large crystals include snowflakes, diamonds, and table salt, most inorganic solids are not crystals but polycrystals, i. e. many microscopic crystals fused together into a single solid. Examples of polycrystals include most metals, rocks, ceramics, a third category of solids is amorphous solids, where the atoms have no periodic structure whatsoever. Examples of amorphous solids include glass, wax, and many plastics, Crystals are often used in pseudoscientific practices such as crystal therapy, and, along with gemstones, are sometimes associated with spellwork in Wiccan beliefs and related religious movements. The scientific definition of a crystal is based on the arrangement of atoms inside it. A crystal is a solid where the form a periodic arrangement. For example, when liquid water starts freezing, the change begins with small ice crystals that grow until they fuse. Most macroscopic inorganic solids are polycrystalline, including almost all metals, ceramics, ice, rocks, solids that are neither crystalline nor polycrystalline, such as glass, are called amorphous solids, also called glassy, vitreous, or noncrystalline. These have no periodic order, even microscopically, there are distinct differences between crystalline solids and amorphous solids, most notably, the process of forming a glass does not release the latent heat of fusion, but forming a crystal does. A crystal structure is characterized by its cell, a small imaginary box containing one or more atoms in a specific spatial arrangement. The unit cells are stacked in three-dimensional space to form the crystal, the symmetry of a crystal is constrained by the requirement that the unit cells stack perfectly with no gaps. There are 219 possible crystal symmetries, called space groups. These are grouped into 7 crystal systems, such as cubic crystal system or hexagonal crystal system, Crystals are commonly recognized by their shape, consisting of flat faces with sharp angles. Euhedral crystals are those with obvious, well-formed flat faces, anhedral crystals do not, usually because the crystal is one grain in a polycrystalline solid. The flat faces of a crystal are oriented in a specific way relative to the underlying atomic arrangement of the crystal. This occurs because some surface orientations are more stable than others, as a crystal grows, new atoms attach easily to the rougher and less stable parts of the surface, but less easily to the flat, stable surfaces
31.
Mesolite
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Mesolite is a tectosilicate mineral with formula Na2Ca23·8H2O. It is a member of the group and is closely related to natrolite which it also resembles in appearance. Mesolite crystallizes in the system and typically forms fibrous, acicular prismatic crystals or masses. Radiating sprays of crystals are not uncommon. It is vitreous in luster and clear to white in color and it has a Mohs hardness of 5 to 5.5 and a low specific gravity of 2.2 to 2.4. The refractive indices are nα=1.505 nβ=1.505 nγ=1.506 and it was first described in 1816 for an occurrence in the Cyclopean Islands near Catania, Sicily. From the Greek mesos, middle, as its composition lies between natrolite and scolecite, like other zeolites, mesolite occurs as void fillings in amygdaloidal basalt also in andesites and hydrothermal veins
32.
Gonnardite
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Gonnardite is a comparatively rare, fibrous zeolite, natrolite subgroup. Older papers claim that a solid solution exists between tetranatrolite and gonnardite, but tetranatrolite was discredited as a separate species in 1999. A series, based on the disorder of the silicon-aluminum in the framework, gonnardite was named in 1896 after Ferdinand Pierre Joseph Gonnard, who was Professor of Mining Engineering at the University of Lyon, France. Orthorhombic-bipyramidal class 2/m 2/m 2/m and tetragonal-scalenoidal class 42m. Unit Cell Parameters, a = b =13.21 Å, c =6.622 Å, Z =2 Space Group, I42d Crystals are prismatic, bounded by and as well as and, and gonnardite also occurs as radial hemispheres. Commonly found as zoned prisms or aggregates with thomsonite, natrolite and paranatrolite, gonnardite is a tectosilicate belonging to the natrolite group. The natrolite minerals are composed of chains of AlO4 and SiO4 tetrahedra that link to form frameworks, gonnardite has the same framework structure as natrolite, but a disordered Si, Al distribution on the tetrahedral sites. Some of the sites in the disordered natrolite structure of gonnardite are empty. Gonnardite has been found in silica-poor volcanics and pegmatites and it is also found in nepheline-syenite in the Grenville Geological Province, which is part of the Canadian Shield.1930,166
33.
Nicol prism
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A Nicol prism is a type of polarizer, an optical device used to produce a polarized beam of light. It is made in such a way that it one of the rays by total internal reflection, i. e the ordinary ray is eliminated. It was the first type of polarizing prism, invented in 1828 by William Nicol of Edinburgh and it passes out the top side of the upper half of the prism with some refraction, as shown. The extraordinary ray, or e-ray, experiences a lower index in the calcite and is not totally reflected at the interface because it strikes the interface at a sub-critical angle. The e-ray merely undergoes a slight refraction, or bending, as it passes through the interface into the half of the prism. It finally leaves the prism as a ray of plane-polarized light, undergoing another refraction, in most instruments, however, Nicol prisms have been replaced by other types of polarizers such as Polaroid sheets and Glan–Thompson prisms. Nomarski prism Glan–Thompson prism Glan–Foucault prism Sénarmont prism Rochon prism Wollaston prism
34.
Polarization (waves)
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Polarization is a parameter applying to transverse waves that specifies the geometrical orientation of the oscillations. In a transverse wave the direction of the oscillation is transverse to the direction of motion of the wave, a simple example of a polarized transverse wave is vibrations traveling along a taut string for example in a musical instrument like a guitar string. Depending on how the string is plucked, the vibrations can be in a direction, horizontal direction. Transverse waves that exhibit polarization include electromagnetic waves such as light and radio waves, gravitational waves, in some types of transverse waves the wave displacement is limited to a single direction, so these also dont exhibit polarization. For example, in waves in liquids the wave displacement of the particles is always in a vertical plane. In linear polarization the fields oscillate in a single direction, in circular or elliptical polarization the fields rotate at a constant rate in a plane as the wave travels. Polarized light can be produced by passing unpolarized light through a polarizing filter, some of these are used to make polarizing filters. Light is also partially polarized when it reflects from a surface, according to quantum mechanics, electromagnetic waves consist of particles called photons. When viewed in this way, the polarization of a wave is determined by a quantum mechanical property of photons called their spin. A photon has one of two spins, it can either spin in a right hand sense or a left hand sense about its direction of travel. Circularly polarized electromagnetic waves are composed of photons with one type of spin. Linearly polarized waves consist of numbers of right and left hand spinning photons. Polarization is an important parameter in areas of science dealing with transverse waves, such as optics, seismology, radio, especially impacted are technologies such as lasers, wireless and optical fiber telecommunications, and radar. And incoherent states can be modeled stochastically as a combination of such uncorrelated waves with some distribution of frequencies, phases. Considering a monochromatic wave of optical frequency f, let us take the direction of propagation as the z axis. Being a transverse wave the E and H fields must then contain components only in the x and y directions whereas Ez=Hz=0. Using complex notation, we understand the instantaneous electric and magnetic fields to be given by the real parts of the complex quantities occurring in the following equations. Here ex, ey, hx, and hy are complex numbers, in the second more compact form, as these equations are customarily expressed, these factors are described using the wavenumber k =2 π n / λ and angular frequency ω =2 π f
35.
Hardness
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Hardness is a measure of how resistant solid matter is to various kinds of permanent shape change when a compressive force is applied. Some materials are harder than others, Hardness is dependent on ductility, elastic stiffness, plasticity, strain, strength, toughness, viscoelasticity, and viscosity. Common examples of matter are ceramics, concrete, certain metals, and superhard materials. There are three types of hardness measurements, scratch, indentation, and rebound. Within each of these classes of measurement there are individual measurement scales, for practical reasons conversion tables are used to convert between one scale and another. Scratch hardness is the measure of how resistant a sample is to fracture or permanent plastic deformation due to friction from a sharp object, the principle is that an object made of a harder material will scratch an object made of a softer material. When testing coatings, scratch hardness refers to the necessary to cut through the film to the substrate. The most common test is Mohs scale, which is used in mineralogy, one tool to make this measurement is the sclerometer. Another tool used to make these tests is the pocket hardness tester and this tool consists of a scale arm with graduated markings attached to a four-wheeled carriage. A scratch tool with a rim is mounted at a predetermined angle to the testing surface. In order to use it a weight of mass is added to the scale arm at one of the graduated markings. The use of the weight and markings allows a known pressure to be applied without the need for complicated machinery. Indentation hardness measures the resistance of a sample to material deformation due to a constant compression load from an object, they are primarily used in engineering. The tests work on the premise of measuring the critical dimensions of an indentation left by a specifically dimensioned and loaded indenter. Common indentation hardness scales are Rockwell, Vickers, Shore, rebound hardness, also known as dynamic hardness, measures the height of the bounce of a diamond-tipped hammer dropped from a fixed height onto a material. This type of hardness is related to elasticity, the device used to take this measurement is known as a scleroscope. Two scales that measures rebound hardness are the Leeb rebound hardness test, there are five hardening processes, Hall-Petch strengthening, work hardening, solid solution strengthening, precipitation hardening, and martensitic transformation. Hardness in the elastic range—a small temporary change in shape for a given force—is known as stiffness in the case of a given object and they exhibit plasticity—the ability to permanently change shape in response to the force, but remain in one piece
36.
Hydrochloric acid
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Hydrochloric acid is a corrosive, strong mineral acid with many industrial uses. A colorless, highly pungent solution of chloride in water. Free hydrochloric acid was first formally described in the 16th century by Libavius, later, it was used by chemists such as Glauber, Priestley, and Davy in their scientific research. It has numerous applications, including household cleaning, production of gelatin and other food additives, descaling. About 20 million tonnes of acid are produced worldwide annually. It is also found naturally in gastric acid, Hydrochloric acid was known to European alchemists as spirits of salt or acidum salis. Both names are used, especially in other languages, such as German, Salzsäure, Dutch, Zoutzuur, Swedish, Saltsyra, Turkish, Tuz Ruhu, Polish, kwas solny and Chinese. Gaseous HCl was called marine acid air, the old name muriatic acid has the same origin, and this name is still sometimes used. The name hydrochloric acid was coined by the French chemist Joseph Louis Gay-Lussac in 1814, aqua regia, a mixture consisting of hydrochloric and nitric acids, prepared by dissolving sal ammoniac in nitric acid, was described in the works of Pseudo-Geber, a 13th-century European alchemist. Other references suggest that the first mention of aqua regia is in Byzantine manuscripts dating to the end of the 13th century, free hydrochloric acid was first formally described in the 16th century by Libavius, who prepared it by heating salt in clay crucibles. Joseph Priestley of Leeds, England prepared pure hydrogen chloride in 1772, during the Industrial Revolution in Europe, demand for alkaline substances increased. A new industrial process developed by Nicolas Leblanc of Issoundun, France enabled cheap large-scale production of sodium carbonate, in this Leblanc process, common salt is converted to soda ash, using sulfuric acid, limestone, and coal, releasing hydrogen chloride as a by-product. Until the British Alkali Act 1863 and similar legislation in other countries, after the passage of the act, soda ash producers were obliged to absorb the waste gas in water, producing hydrochloric acid on an industrial scale. In the 20th century, the Leblanc process was replaced by the Solvay process without a hydrochloric acid by-product. Since hydrochloric acid was already settled as an important chemical in numerous applications. After the year 2000, hydrochloric acid is made by absorbing by-product hydrogen chloride from industrial organic compounds production. Hydrochloric acid is the salt of hydronium ion, H3O+ and chloride and it is usually prepared by treating HCl with water. H C l + H2 O ⟶ H3 O + + C l − Hydrochloric acid can therefore be used to prepare salts called chlorides, Hydrochloric acid is a strong acid, since it is completely dissociated in water
37.
Basalt
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Basalt is a common extrusive igneous rock formed from the rapid cooling of basaltic lava exposed at or very near the surface of a planet or moon. Flood basalt describes the formation in a series of basalt flows. By definition, basalt is an igneous rock with generally 45-55% silica and less than 10% feldspathoid by volume. Basalt commonly features a very fine-grained or glassy matrix interspersed with visible mineral grains, the average density is 3.0 gm/cm3. Basalt is defined by its content and texture, and physical descriptions without mineralogical context may be unreliable in some circumstances. Basalt is usually grey to black in colour, but rapidly weathers to brown or rust-red due to oxidation of its mafic minerals into hematite, although usually characterized as dark, basaltic rocks exhibit a wide range of shading due to regional geochemical processes. Due to weathering or high concentrations of plagioclase, some basalts can be quite light-coloured and these phenocrysts usually are of olivine or a calcium-rich plagioclase, which have the highest melting temperatures of the typical minerals that can crystallize from the melt. Basalt with a texture is called vesicular basalt, when the bulk of the rock is mostly solid. Gabbro is often marketed commercially as black granite and these ultramafic volcanic rocks, with silica contents below 45% are usually classified as komatiites. Agricola applied basalt to the black rock of the Schloßberg at Stolpen. Tholeiitic basalt is relatively rich in silica and poor in sodium, included in this category are most basalts of the ocean floor, most large oceanic islands, and continental flood basalts such as the Columbia River Plateau. Basalt rocks are in some cases classified after their content in High-Ti and Low-Ti varieties. High-Ti and Low-Ti basalts have been distinguished in the Paraná and Etendeka traps and it has greater than 17% alumina and is intermediate in composition between tholeiite and alkali basalt, the relatively alumina-rich composition is based on rocks without phenocrysts of plagioclase. Alkali basalt is relatively poor in silica and rich in sodium and it is silica-undersaturated and may contain feldspathoids, alkali feldspar and phlogopite. Boninite is a form of basalt that is erupted generally in back-arc basins. Ocean island basalt Lunar basalt On Earth, most basalt magmas have formed by melting of the mantle. Basalt commonly erupts on Io, the third largest moon of Jupiter, and has formed on the Moon, Mars, Venus. The crustal portions of oceanic tectonic plates are composed predominantly of basalt, produced from upwelling mantle below, the mineralogy of basalt is characterized by a preponderance of calcic plagioclase feldspar and pyroxene
38.
Igneous rock
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Igneous rock, or magmatic rock, is one of the three main rock types, the others being sedimentary and metamorphic. Igneous rock is formed through the cooling and solidification of magma or lava, the magma can be derived from partial melts of existing rocks in either a planets mantle or crust. Typically, the melting is caused by one or more of three processes, an increase in temperature, a decrease in pressure, or a change in composition, solidification into rock occurs either below the surface as intrusive rocks or on the surface as extrusive rocks. Igneous rock may form with crystallization to form granular, crystalline rocks, Igneous and metamorphic rocks make up 90–95% of the top 16 km of the Earths crust by volume. Igneous rocks form about 15% of the Earths current land surface, most of the Earths oceanic crust is made of igneous rock. In terms of modes of occurrence, igneous rocks can be either intrusive or extrusive, the mineral grains in such rocks can generally be identified with the naked eye. Intrusive rocks can also be classified according to the shape and size of the intrusive body, typical intrusive formations are batholiths, stocks, laccoliths, sills and dikes. When the magma solidifies within the earths crust, it cools slowly forming coarse textured rocks, such as granite, gabbro, the central cores of major mountain ranges consist of intrusive igneous rocks, usually granite. When exposed by erosion, these cores may occupy huge areas of the Earths surface, intrusive igneous rocks that form at depth within the crust are termed plutonic rocks and are usually coarse-grained. Intrusive igneous rocks that form near the surface are termed subvolcanic or hypabyssal rocks, hypabyssal rocks are less common than plutonic or volcanic rocks and often form dikes, sills, laccoliths, lopoliths, or phacoliths. Extrusive igneous rocks, also known as rocks, are formed at the crusts surface as a result of the partial melting of rocks within the mantle. Extrusive igneous rocks cool and solidify quicker than intrusive igneous rocks and they are formed by the cooling of molten magma on the earths surface. The magma, which is brought to the surface through fissures or volcanic eruptions, hence such rocks are smooth, crystalline and fine-grained. Basalt is an extrusive igneous rock and forms lava flows, lava sheets. Some kinds of basalt solidify to form long polygonal columns, the Giants Causeway in Antrim, Northern Ireland is an example. The molten rock, with or without suspended crystals and gas bubbles, is called magma and it rises because it is less dense than the rock from which it was created. When magma reaches the surface from beneath water or air, it is called lava, eruptions of volcanoes into air are termed subaerial, whereas those occurring underneath the ocean are termed submarine. Black smokers and mid-ocean ridge basalt are examples of volcanic activity
39.
France
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France, officially the French Republic, is a country with territory in western Europe and several overseas regions and territories. The European, or metropolitan, area of France extends from the Mediterranean Sea to the English Channel and the North Sea, Overseas France include French Guiana on the South American continent and several island territories in the Atlantic, Pacific and Indian oceans. France spans 643,801 square kilometres and had a population of almost 67 million people as of January 2017. It is a unitary republic with the capital in Paris. Other major urban centres include Marseille, Lyon, Lille, Nice, Toulouse, during the Iron Age, what is now metropolitan France was inhabited by the Gauls, a Celtic people. The area was annexed in 51 BC by Rome, which held Gaul until 486, France emerged as a major European power in the Late Middle Ages, with its victory in the Hundred Years War strengthening state-building and political centralisation. During the Renaissance, French culture flourished and a colonial empire was established. The 16th century was dominated by civil wars between Catholics and Protestants. France became Europes dominant cultural, political, and military power under Louis XIV, in the 19th century Napoleon took power and established the First French Empire, whose subsequent Napoleonic Wars shaped the course of continental Europe. Following the collapse of the Empire, France endured a succession of governments culminating with the establishment of the French Third Republic in 1870. Following liberation in 1944, a Fourth Republic was established and later dissolved in the course of the Algerian War, the Fifth Republic, led by Charles de Gaulle, was formed in 1958 and remains to this day. Algeria and nearly all the colonies became independent in the 1960s with minimal controversy and typically retained close economic. France has long been a centre of art, science. It hosts Europes fourth-largest number of cultural UNESCO World Heritage Sites and receives around 83 million foreign tourists annually, France is a developed country with the worlds sixth-largest economy by nominal GDP and ninth-largest by purchasing power parity. In terms of household wealth, it ranks fourth in the world. France performs well in international rankings of education, health care, life expectancy, France remains a great power in the world, being one of the five permanent members of the United Nations Security Council with the power to veto and an official nuclear-weapon state. It is a member state of the European Union and the Eurozone. It is also a member of the Group of 7, North Atlantic Treaty Organization, Organisation for Economic Co-operation and Development, the World Trade Organization, originally applied to the whole Frankish Empire, the name France comes from the Latin Francia, or country of the Franks
40.
Giant's Causeway
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The Giants Causeway is an area of about 40,000 interlocking basalt columns, the result of an ancient volcanic eruption. It is also known as Clochán an Aifir or Clochán na bhFomhórach in Irish and it is located in County Antrim on the north coast of Northern Ireland, about three miles northeast of the town of Bushmills. It was declared a World Heritage Site by UNESCO in 1986, in a 2005 poll of Radio Times readers, the Giants Causeway was named as the fourth greatest natural wonder in the United Kingdom. The tops of the columns form stepping stones that lead from the cliff foot, most of the columns are hexagonal, although there are also some with four, five, seven or eight sides. The tallest are about 12 metres high, and the lava in the cliffs is 28 metres thick in places. Much of the Giants Causeway and Causeway Coast World Heritage Site is today owned and managed by the National Trust, the remainder of the site is owned by the Crown Estate and a number of private landowners. As the lava cooled, contraction occurred, in many cases the horizontal fracture has resulted in a bottom face that is convex while the upper face of the lower segment is concave, producing what are called ball and socket joints. The size of the columns is primarily determined by the speed at which lava from a volcanic eruption cools, the extensive fracture network produced the distinctive columns seen today. The basalts were originally part of a volcanic plateau called the Thulean Plateau which formed during the Paleocene. According to legend, the columns are the remains of a built by a giant. The story goes that the Irish giant Fionn mac Cumhaill, from the Fenian Cycle of Gaelic mythology, was challenged to a fight by the Scottish giant Benandonner, Fionn accepted the challenge and built the causeway across the North Channel so that the two giants could meet. In one version of the story, Fionn defeats Benandonner, in another, Fionn hides from Benandonner when he realises that his foe is much bigger than he. Fionns wife, Oonagh, disguises Fionn as a baby and tucks him in a cradle, when Benandonner sees the size of the baby, he reckons that its father, Fionn, must be a giant among giants. He flees back to Scotland in fright, destroying the causeway behind him so that Fionn could not follow, across the sea, there are identical basalt columns at Fingals Cave on the Scottish isle of Staffa, and it is possible that the story was influenced by this. In overall Irish mythology, Fionn mac Cumhaill is not a giant, the Fomhóraigh are a race of supernatural beings in Irish mythology who were sometimes described as giants and who may have originally been part of a pre-Christian pantheon. In the caption to the plates French geologist Nicolas Desmarest suggested, for the first time in print, visitors can walk over the basalt columns which are at the edge of the sea, a half-mile walk from the entrance to the site. The Causeway was without a permanent visitors centre between 2000 and 2012, as the building, built in 1986, burned down in 2000. A privately financed proposal was given approval in 2007 by the Environment Minister
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County Antrim
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County Antrim ) is one of six counties that form Northern Ireland and one of the nine counties of the province of Ulster, situated in the north-east of the island of Ireland. Adjoined to the north-east shore of Lough Neagh, the county covers an area of 3,046 square kilometres and has a population of about 618,000, County Antrim has a population density of 203 people per square kilometer /526 people per square mile. The majority of Belfast, the city of Northern Ireland, is in County Antrim. It is currently one of two counties of Ireland to have a majority of the population from a Protestant background, according to the 2001 census. The other is County Down to the south, a large portion of Antrim is hilly, especially in the east, where the highest elevations are attained. The range runs north and south, and, following this direction, the most remarkable cliffs are those formed of perpendicular basaltic columns, extending for many miles, and most strikingly displayed in Fair Head and the celebrated Giants Causeway. From the eastern coast the hills rise instantly but less abruptly, all are somewhat exposed to the easterly winds prevalent in spring. It is partially arable, and supports a small population, islandmagee is a peninsula separating Larne Lough from the North Channel. The valleys of the Bann and Lagan, with the shores of Lough Neagh. These two rivers, both rising in County Down, are the ones of importance. The latter flows to Belfast Lough, the former drains Lough Neagh, the fisheries of the Bann and of Lough Neagh are of value both commercially and to sportsmen, the small town of Toome, at the outflow of the river, being the centre. Immediately below this point lies Lough Beg, the Small Lake, County Antrim has a number of air, rail and sea links. Northern Irelands main airport, Belfast International Airport, at Aldergrove is in County Antrim, Belfast International shares its runways with the Royal Air Force base RAF Aldergrove, which otherwise has its own facilities. It is the fifth-largest regional air cargo centre in the UK, there are regular services to Great Britain, Europe and North America. The region is served by George Best Belfast City Airport, a mile east of Belfast city centre on the County Down side of the city. Two of Northern Irelands main ports are in County Antrim, Larne, ferries sail from Larne Harbour to destinations including Cairnryan and Troon in Scotland, and Fleetwood in England. The Port of Belfast is Northern Irelands principal maritime gateway, serving the Northern Ireland economy and it is a major centre of industry and commerce and has become established as the focus of logistics activity for Northern Ireland. Around two-thirds of Northern Irelands seaborne trade, and a quarter of that for Ireland as a whole, is handled at the port, the population of County Antrim was 615,384 according to recent census information, making it the most populous county in Northern Ireland
42.
Phonolite
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Phonolite is an uncommon extrusive igneous rock, volcanic rock, of intermediate chemical composition between felsic and mafic, with texture ranging from aphanitic to porphyritic. The name phonolite comes from the Ancient Greek meaning sounding stone because of the sound it produces if an unfractured plate is hit. Melting of such rocks to a low degree promotes the liberation of aluminium, potassium, sodium and calcium via melting of feldspar. Because the rock is silica undersaturated, it has no quartz or other silica crystals, a few geological processes and tectonic events can melt the necessary precursor rocks to form phonolite. These include intracontinental hotspot volcanism, such as may form above mantle plumes covered by continental crust. A-type granites and alkaline igneous provinces usually occur alongside phonolites, low-degree partial melting of underplates of granitic material in collisional orogenic belts may also produce phonolites. Phonolite is an equivalent of nepheline syenite. They are products of partial melting, are silica undersaturated, and have feldspathoids in their normative mineralogy, mineral assemblages in phonolite occurrences are usually abundant feldspathoids and alkali feldspar, and rare sodic plagioclase. Biotite, sodium-rich amphiboles and pyroxenes along with iron-rich olivine are common minor minerals, accessory phases include titanite, apatite, corundum, zircon, magnetite and ilmenite. Nepheline-normative rocks occur in association with the Bushveld Igneous Complex. Phonolite occurs in the related Pilanesberg Complex and Pienaars River Complex, phonolite tuff was used as a source of flint for adze heads and such by prehistoric man from Hohentwiel and Hegau, Germany. Phonolites can be separated into slabs of appropriate dimensions to be used as roofing tiles in place of roofing slate, one such occurrence is in the French Massif Central region such as the Haute Loire département. Alkaline rocks and carbonatites of the world
43.
Bohemia
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Bohemia is the westernmost and largest historical region of the Czech lands in the present-day Czech Republic. Bohemia was a duchy of Great Moravia, later an independent principality, a kingdom in the Holy Roman Empire, and subsequently a part of the Habsburg Monarchy, after World War I and the establishment of an independent Czechoslovak state, Bohemia became a part of Czechoslovakia. Between 1938 and 1945, border regions with sizeable German-speaking minorities of all three Czech lands were joined to Nazi Germany as the Sudetenland, in 1990, the name was changed to the Czech Republic, which become a separate state in 1993 with the dissolution of Czechoslovakia. Until 1948, Bohemia was a unit of Czechoslovakia as one of its lands. Bohemia was bordered in the south by Upper and Lower Austria, in the west by Bavaria and in the north by Saxony and Lusatia, in the northeast by Silesia, and in the east by Moravia. In the 2nd century BC, the Romans were competing for dominance in northern Italy, the Romans defeated the Boii at the Battle of Placentia and the Battle of Mutina. After this, many of the Boii retreated north across the Alps, much later Roman authors refer to the area they had once occupied as Boiohaemum. The earliest mention was by Tacitus Germania 28, and later mentions of the name are in Strabo. The name appears to include the tribal name Boi- plus the Germanic element *haimaz home and this Boiohaemum was apparently isolated to the area where King Marobods kingdom was centred, within the Hercynian forest. The Czech name Čechy is derived from the name of the Slavic ethnic group, the Czechs, Bohemia, like neighbouring Bavaria, is named after the Boii, who were a large Celtic nation known to the Romans for their migrations and settlement in northern Italy and other places. Another part of the nation moved west with the Helvetii into southern France, to the south, over the Danube, the Romans extended their empire, and to the southeast in Hungaria, were Sarmatian peoples. In the area of modern Bohemia the Marcomanni and other Suebic groups were led by their king Marobodus and he took advantage of the natural defenses provided by its mountains and forests. In late classical times and the early Middle Ages, two new Suebic groupings appeared to the west of Bohemia in southern Germany, the Alemanni, many Suebic tribes from the Bohemian region took part in such movements westwards, even settling as far away as Spain and Portugal. With them were also tribes who had pushed from the east, such as the Vandals, other groups pushed southwards towards Pannonia. These are precursors of todays Czechs, though the amount of Slavic immigration is a subject of debate. The Slavic influx was divided into two or three waves, the first wave came from the southeast and east, when the Germanic Lombards left Bohemia. Soon after, from the 630s to 660s, the territory was taken by Samos tribal confederation and his death marked the end of the old Slavonic confederation, the second attempt to establish such a Slavonic union after Carantania in Carinthia. Other sources divide the population of Bohemia at this time into the Merehani, Marharaii, Beheimare, Christianity first appeared in the early 9th century, but only became dominant much later, in the 10th or 11th century
44.
Quebec
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Quebec is the second-most populous province of Canada and the only one to have a predominantly French-speaking population, with French as the sole provincial official language. Quebec is Canadas largest province by area and its second-largest administrative division and it also shares maritime borders with Nunavut, Prince Edward Island, and Nova Scotia. Quebec is Canadas second-most populous province, after Ontario, most inhabitants live in urban areas near the Saint Lawrence River between Montreal and Quebec City, the capital. Approximately half of Quebec residents live in the Greater Montreal Area, the Nord-du-Québec region, occupying the northern half of the province, is sparsely populated and inhabited primarily by Aboriginal peoples. Even in central Quebec at comparatively southerly latitudes winters are severe in inland areas, Quebec independence debates have played a large role in the politics of the province. Parti Québécois governments held referendums on sovereignty in 1980 and 1995, in 2006, the House of Commons of Canada passed a symbolic motion recognizing the Québécois as a nation within a united Canada. These many industries have all contributed to helping Quebec become an economically influential province within Canada, early variations in the spelling of the name included Québecq and Kébec. French explorer Samuel de Champlain chose the name Québec in 1608 for the colonial outpost he would use as the seat for the French colony of New France. The province is sometimes referred to as La belle province, the Province of Quebec was founded in the Royal Proclamation of 1763 after the Treaty of Paris formally transferred the French colony of Canada to Britain after the Seven Years War. The proclamation restricted the province to an area along the banks of the Saint Lawrence River, the Treaty of Versailles ceded territories south of the Great Lakes to the United States. After the Constitutional Act of 1791, the territory was divided between Lower Canada and Upper Canada, with each being granted an elected legislative assembly, in 1840, these become Canada East and Canada West after the British Parliament unified Upper and Lower Canada into the Province of Canada. This territory was redivided into the Provinces of Quebec and Ontario at Confederation in 1867, each became one of the first four provinces. In 1898, the Canadian Parliament passed the first Quebec Boundary Extension Act that expanded the provincial boundaries northward to include the lands of the aboriginal peoples. This was followed by the addition of the District of Ungava through the Quebec Boundaries Extension Act of 1912 that added the northernmost lands of the Inuit to create the modern Province of Quebec. In 1927, the border between Quebec and Newfoundland and Labrador was established by the British Judicial Committee of the Privy Council. Located in the part of Canada, and part of Central Canada. Its topography is very different from one region to another due to the composition of the ground, the climate. The Saint Lawrence Lowland and the Canadian Shield are the two main regions, and are radically different
45.
Bay of Fundy
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Some sources believe the name Fundy is a corruption of the French word Fendu, meaning split, while others believe it comes from the Portuguese funda, meaning deep. The Bay of Fundy is known for having the highest tidal range in the world. Rivaled by Ungava Bay in northern Quebec, King Sound in Western Australia, Gulf of Khambhat in India, and the Severn Estuary in the UK, it has one of the highest vertical tidal ranges in the world. Burntcoat Head in the Minas Basin, Nova Scotia, has the greatest mean spring range with 14.5 metres and a range of 16.3 metres. ”Portions of the Bay of Fundy, Shepody Bay and Minas Basin, form one of six Canadian sites in the Western Hemisphere Shorebird Reserve Network. In July 2009, the Bay of Fundy was named as a finalist for the New 7 Wonders of Nature contest that ended in November 2011 and it was not chosen as a wonder. The Bay of Fundy is known for its tidal range. The highest water level recorded in the Bay of Fundy system occurred at the head of the Minas Basin on the night of October 4–5,1869 during a tropical cyclone named the “Saxby Gale”. The water level of 21.6 meters resulted from the combination of winds, abnormally low atmospheric pressure. Leaf Basin has only been measured in recent years, whereas the Fundy system has measured for many decades. Traditional Mikmaq folklore states that the tides in the Bay of Fundy are caused by a giant whale splashing in the water, during the 12. 4-hour tidal period,115 billion tonnes of water flow in and out of the bay. The tides in the Bay of Fundy are semidiurnal, which means that they have two highs and two each day. The height that the water rises and falls to each day during these tides are approximately equal, there are approximately six hours and thirteen minutes between each high and low tide. Alternative forms of energy are being explored in depth in a number of unique areas, tidal energy harnesses the movement of ocean water to generate electricity through a number of mechanisms. Currently a process of gathering tidal energy called In-stream turbine technology is being tested in the Minas Passage and this project is being spearheaded by the Fundy Ocean Research Center for Energy or FORCE. In-stream tidal turbine technology is a simple design. An elevated turbine is submerged under water in a location that enables its movement with tidal cycles, as the blades of the turbine move they create energy that powers an electric generator at the base. From here the power travels to an attached to the seafloor. While this technology has shown to be successful in its stages of testing
This article incorporates text from a publication now in the public domain: Chisholm, Hugh, ed. (1911). "Natrolite". Encyclopædia Britannica. 19 (11th ed.). Cambridge University Press. p. 273.
