Obsidian is a naturally occurring volcanic glass formed when lava extruded from a volcano cools rapidly with minimal crystal growth. It is an igneous rock.
Obsidian
Obsidian talus at Obsidian Dome, California
Polished snowflake obsidian, formed through the inclusion of cristobalite crystals
Glass Mountain, a large obsidian flow at Medicine Lake Volcano in California
Volcanic glass is the amorphous (uncrystallized) product of rapidly cooling magma. Like all types of glass, it is a state of matter intermediate between the closely packed, highly ordered array of a crystal and the highly disordered array of liquid. Volcanic glass may refer to the interstitial material, or matrix, in an aphanitic (fine-grained) volcanic rock, or to any of several types of vitreous igneous rocks.
A sand grain of volcanic glass under the petrographic microscope. Its amorphous nature makes it disappear in cross-polarized light (bottom frame). The scale box is in millimeters.