Perlite is an amorphous volcanic glass that has a relatively high water content, typically formed by the hydration of obsidian. It occurs naturally and has the unusual property of greatly expanding when heated sufficiently. It is an industrial mineral, suitable "as ceramic flux to lower the sintering temperature", and a commercial product useful for its low density after processing.
Expanded perlite.
Perlite boulders with fireweed in foreground
Perlite mine in Owens Valley, California.
Obsidian is a naturally occurring volcanic glass formed when lava extruded from a volcano cools rapidly with minimal crystal growth. It is an igneous rock.
Obsidian
Obsidian talus at Obsidian Dome, California
Polished snowflake obsidian, formed through the inclusion of cristobalite crystals
Glass Mountain, a large obsidian flow at Medicine Lake Volcano in California