1.
The Petrified Forest
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The Petrified Forest is a 1936 American film, directed by Archie Mayo starring Leslie Howard, Bette Davis, and Humphrey Bogart. A precursor of film noir, it was adapted from Robert E. Sherwoods stage play of the same name, the screenplay was written by Delmer Daves and Charles Kenyon, and adaptations were later performed on radio and television as well. She now sends poetry to Gabrielle, who dreams of moving to Bourges, Alan tells his story—how he wrote one novel, then lived in France for eight years with his publishers wife, trying to write another—and Gabrielle is instantly smitten with him. Gabrielle shows Alan her paintings—the first time she has them to anyone—and reads him a favorite François Villon poem. Boze Hertzlinger, a beefy diner employee who has wooed Gabrielle in vain, grows jealous of Alan, Duke and his gang seize the Chisholms car and drive to the diner, where Duke has arranged to rendezvous with his girlfriend, Doris, on their way to Mexico. Alan, the Chisholms, and their chauffeur soon make their way back to the diner as well, Alan, indifferent to the hostage situation, engages Duke in lively conversation and toasts him as the last great apostle of rugged individualism. Boze snatches a rifle and gets the drop on Duke, but during a momentary distraction Duke draws his pistol and shoots Boze in the hand, Duke learns that Doris has been captured, and has revealed their rendezvous location to the police. As police and federal agents converge on the diner, Duke prepares to flee, announcing that he will take Mr. then he asks Duke to kill him, so that Gabrielle can use the insurance money to realize her dream of moving to France. Duke obliges, then leaves with his human shields, Alan dies in Gabrielles arms, secure in the knowledge that she, unlike the rest, will escape her dead-end existence to pursue her dreams. Bogart, who won the role in part because of his physical resemblance to Dillinger, studied film footage of the gangster. The film made Bogart a star, and he remained grateful to Howard for the rest of his life. In 1952, Bogart and Lauren Bacall named their daughter Leslie Howard Bogart in honor of Howard, in 1948, Robinson portrayed a character very similar to Duke—a famous gangster holding a disparate group of people hostage in a Florida hotel—in Key Largo. That films hero was played by Bogart, in his penultimate film, The Desperate Hours, Bogart played another gangster holding a suburban family hostage. He described that character as Duke Mantee grown up, another radio adaptation starring Joan Bennett, Tyrone Power, and Bogart aired on The Screen Guild Theater on January 7,1940. In 1955, a television version was performed as an installment of Producers Showcase, a weekly dramatic anthology, featuring Bogart as Mantee, Henry Fonda as Alan. Jack Klugman, Richard Jaeckel, and Jack Warden played supporting roles, in the late 1990s Bacall donated the only known kinescope of the 1955 performance to the Museum Of Television & Radio, where it remains archived for viewing in New York City and Los Angeles. In 1972, a take-off of the film entitled The Putrified Forest was seen as a sketch on The Carol Burnett Show, featuring Steve Lawrence, the Warner Brothers sound stage on which the movie was filmed is currently the home of Conan OBriens TBS television program. The film is recognized by American Film Institute in these lists,2003, AFIs 100 Years
2.
Arizona
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Arizona is a state in the southwestern region of the United States. It is also part of the Western United States and the Mountain West states and it is the sixth largest and the 14th most populous of the 50 states. Its capital and largest city is Phoenix, Arizona is one of the Four Corners states. It has borders with New Mexico, Utah, Nevada, California, and Mexico, Arizonas border with Mexico is 389 miles long, on the northern border of the Mexican states of Sonora and Baja California. Arizona is the 48th state and last of the states to be admitted to the Union. Historically part of the territory of Alta California in New Spain, after being defeated in the Mexican–American War, Mexico ceded much of this territory to the United States in 1848. The southernmost portion of the state was acquired in 1853 through the Gadsden Purchase, Southern Arizona is known for its desert climate, with very hot summers and mild winters. There are ski resorts in the areas of Flagstaff, Alpine, in addition to the Grand Canyon National Park, there are several national forests, national parks, and national monuments. To the European settlers, their pronunciation sounded like Arissona, the area is still known as alĭ ṣonak in the Oodham language. Another possible origin is the Basque phrase haritz ona, as there were numerous Basque sheepherders in the area, There is a misconception that the states name originated from the Spanish term Árida Zona. See also lists of counties, islands, rivers, lakes, state parks, national parks, Arizona is in the Southwestern United States as one of the Four Corners states. Arizona is the sixth largest state by area, ranked after New Mexico, of the states 113,998 square miles, approximately 15% is privately owned. The remaining area is public forest and park land, state trust land, Arizona is well known for its desert Basin and Range region in the states southern portions, which is rich in a landscape of xerophyte plants such as the cactus. This regions topography was shaped by volcanism, followed by the cooling-off. Its climate has hot summers and mild winters. The state is well known for its pine-covered north-central portion of the high country of the Colorado Plateau. Like other states of the Southwest United States, Arizona has an abundance of mountains, despite the states aridity, 27% of Arizona is forest, a percentage comparable to modern-day France or Germany. The worlds largest stand of pine trees is in Arizona
3.
Petrified Forest National Park
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Petrified Forest National Park is a United States national park in Navajo and Apache counties in northeastern Arizona. Named for its deposits of petrified wood, the fee area of the park covers about 230 square miles, encompassing semi-desert shrub steppe as well as highly eroded. The site, the part of which extends into the Painted Desert, was declared a national monument in 1906. The park received 643,274 recreational visitors in 2016, representing a decrease of 19% from the prior year, typical visitor activities include sightseeing, photography, hiking, and backpacking. Averaging about 5,400 feet in elevation, the park has a dry climate with temperatures that vary from summer highs of about 100 °F to winter lows well below freezing. More than 400 species of plants, dominated by such as bunchgrass, blue grama. About half of the park is designated wilderness, the Petrified Forest is known for its fossils, especially fallen trees that lived in the Late Triassic Period, about 225 million years ago. The sediments containing the logs are part of the widespread and colorful Chinle Formation. Beginning about 60 million years ago, the Colorado Plateau, of which the park is part, was pushed upward by tectonic forces and exposed to increased erosion. All of the rock layers above the Chinle, except geologically recent ones found in parts of the park, have been removed by wind. Paleontologists have been unearthing and studying the parks fossils since the early 20th century, the parks earliest human inhabitants arrived at least 8,000 years ago. By about 2,000 years ago, they were growing corn in the area, later inhabitants built above-ground dwellings called pueblos. Although a changing climate caused the last of the parks pueblos to be abandoned by about 1400 CE, more than 600 archeological sites, including petroglyphs, have been discovered in the park. Later, roads and a railway followed similar routes and gave rise to tourism and, before the park was protected, theft of petrified wood remains a problem in the 21st century. Petrified Forest National Park straddles the border between Apache County and Navajo County in northeastern Arizona, I-40, former U. S. Route 66, the BNSF Railway, and the Puerco River bisect the park generally east–west along a similar route. Adamana, a ghost town, is about 1 mile west of the park along the BNSF tracks, Holbrook, about 26 miles west of park headquarters along I-40, is the nearest city. Bisecting the park north–south is Park Road, which runs between I-40 near park headquarters on the north and U. S. Route 180 on the south, Historic Highway 180, an earlier alignment of the modern route, crosses the southern edge of the park. Like Route 66, it has deteriorated and is closed, many unpaved maintenance roads, closed to the public, intersect Park Road at various points
4.
Welwitschia
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Welwitschia is a monotypic gymnosperm genus, comprising solely the distinctive Welwitschia mirabilis. The plant is known simply as welwitschia in English. It is called kharos or khurub in Nama, tweeblaarkanniedood in Afrikaans, nyanka in Damara, Welwitschia is the only living genus of the family Welwitschiaceae and order Welwitschiales, in the division Gnetophyta. Informal sources commonly refer to the plant as a living fossil, Welwitschia mirabilis is endemic to the Namib desert within Namibia and Angola. Welwitschia is named after the Austrian botanist and doctor Friedrich Welwitsch, Welwitsch was so overwhelmed by the plant that he, could do nothing but kneel down and gaze at it, half in fear lest a touch should prove it a figment of the imagination. Welwitsch proposed calling the genus Tumboa after what he believed to be the local name, Hooker asked Welwitsch for permission to name the genus Welwitschia instead. Welwitsch concurred and supplied some well-preserved material from which Hooker was able to make progress in determining its botanical affinities. The taxonomy of Welwitschia subsequently changed intermittently with the development of new systems, however. Most botanists have treated Welwitschia as a monotypic genus in a monotypic family or even order. Most recent systems place Welwitschia mirabilis in its own family Welwitschiaceae in the gymnosperm order Gnetales, after germination, the seedling produces two cotyledons which grow to 25–35 mm in length, and possess reticulate venation. Subsequently, two leaves are produced at the edge of a woody bilobed crown. The permanent leaves are opposite, amphistomatic, parallel-veined and ribbon-shaped, shortly after the appearance of the foliage leaves, the apical meristem dies and meristematic activity is transferred to the periphery of the crown. The two foliage leaves consequently grow continuously from a basal meristem reaching lengths up to 4 m, the largest specimens may be no more than 1.5 m tall above ground, but the circumference of the leaves at contact with the sand may exceed 8 m. The roots extend to a roughly equal to the span of the living leaves from tip to tip. The main stem consists of an unbranched woody crown roughly shaped like an inverted cone, the only branching in the shoot system occurs in the reproductive branches, which bear strobili. The species is dioecious, with male and female plants. Fertilization is carried out by insects, the insects responsible include flies and true bugs. The commonest of the true bugs attending Welwitschia is a member of the family Pyrrhocoridae, the genus is also known as Probergrothius and the matter of which name is correct is still under discussion
5.
Namibia
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Namibia, officially the Republic of Namibia, is a country in southern Africa whose western border is the Atlantic Ocean. It shares land borders with Zambia and Angola to the north, Botswana to the east and South Africa to the south, although it does not border Zimbabwe, a part of less than 200 metres of the Zambezi River separates the two countries. Namibia gained independence from South Africa on 21 March 1990, following the Namibian War of Independence. Its capital and largest city is Windhoek, and it is a state of the United Nations, the Southern African Development Community, the African Union. The dry lands of Namibia were inhabited since early times by the San, Damara, since about the 14th century, immigrating Bantu peoples arrived as part of the Bantu expansion. Since then the Bantu groups in total, known as the Ovambo people, have dominated the population of the country, in the late 19th century during European colonization, the German Empire established rule over most of the territory as a protectorate in 1884. It began to develop infrastructure and farming, and maintained this German colony until 1915, after the end of World War I, in 1920 the League of Nations mandated the country to the United Kingdom, under administration by South Africa. It imposed its laws, including racial classifications and rules, from 1948, with the National Party elected to power, South Africa applied apartheid also to what was known as South West Africa. In 1878 the Cape of Good Hope had annexed the port of Walvis Bay and the offshore Penguin Islands, following continued guerrilla warfare, South Africa installed an interim administration in Namibia in 1985. Namibia obtained full independence from South Africa in 1990, but Walvis Bay and the Penguin Islands remained under South African control until 1994. Namibia has a population of 2.1 million people and a stable multi-party parliamentary democracy, Agriculture, herding, tourism and the mining industry – including mining for gem diamonds, uranium, gold, silver, and base metals – form the basis of its economy. The large, arid Namib Desert has resulted in Namibia being overall one of the least densely populated countries in the world, Namibia enjoys high political, economic and social stability. The name of the country is derived from the Namib Desert, before its independence in 1990, the area was known first as German South-West Africa, then as South-West Africa, reflecting the colonial occupation by the Germans and the South Africans. The dry lands of Namibia were inhabited since early times by San, Damara, from about the 14th century, immigrating Bantu peoples arrived during the Bantu expansion from central Africa. From the late 18th century onwards, Oorlam people from Cape Colony crossed the Orange River and their encounters with the nomadic Nama tribes were largely peaceful. The missionaries accompanying the Oorlam were well received by them, the right to use waterholes, on their way further northwards, however, the Oorlam encountered clans of the Herero at Windhoek, Gobabis, and Okahandja, who resisted their encroachment. The Nama-Herero War broke out in 1880, with hostilities ebbing only after the German Empire deployed troops to the places and cemented the status quo among the Nama, Oorlam. The first Europeans to disembark and explore the region were the Portuguese navigators Diogo Cão in 1485 and Bartolomeu Dias in 1486, like most of interior Sub-Saharan Africa, Namibia was not extensively explored by Europeans until the 19th century
6.
Fossil
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Fossils are the preserved remains or traces of animals, plants, and other organisms from the remote past. The totality of fossils, both discovered and undiscovered, and their placement in fossiliferous rock formations and sedimentary layers is known as the fossil record. The study of fossils across geological time, how they were formed, such a preserved specimen is called a fossil if it is older than some minimum age, most often the arbitrary date of 10,000 years. The observation that fossils were associated with certain rock strata led early geologists to recognize a geological timescale in the 19th century. The development of dating techniques in the early 20th century allowed geologists to determine the numerical or absolute age of the various strata. Like extant organisms, fossils vary in size from microscopic, even single bacterial cells one micrometer in diameter, to gigantic, such as dinosaurs, Fossils may also consist of the marks left behind by the organism while it was alive, such as animal tracks or feces. These types of fossil are called trace fossils, as opposed to body fossils, finally, past life leaves some markers that cannot be seen but can be detected in the form of biochemical signals, these are known as chemofossils or biosignatures. The process of fossilization varies according to type and external conditions. Permineralization is a process of fossilization that occurs when an organism is buried, the empty spaces within an organism become filled with mineral-rich groundwater. Minerals precipitate from the groundwater, occupying the empty spaces and this process can occur in very small spaces, such as within the cell wall of a plant cell. Small scale permineralization can produce very detailed fossils, for permineralization to occur, the organism must become covered by sediment soon after death or soon after the initial decay process. The degree to which the remains are decayed when covered determines the later details of the fossil, some fossils consist only of skeletal remains or teeth, other fossils contain traces of skin, feathers or even soft tissues. This is a form of diagenesis, in some cases the original remains of the organism completely dissolve or are otherwise destroyed. The remaining organism-shaped hole in the rock is called an external mold, if this hole is later filled with other minerals, it is a cast. An endocast or internal mold is formed when sediments or minerals fill the cavity of an organism. This is a form of cast and mold formation. If the chemistry is right, the organism can act as a nucleus for the precipitation of minerals such as siderite, if this happens rapidly before significant decay to the organic tissue, very fine three-dimensional morphological detail can be preserved. Nodules from the Carboniferous Mazon Creek fossil beds of Illinois, USA, are among the best documented examples of such mineralization, replacement occurs when the shell, bone or other tissue is replaced with another mineral
7.
Tree
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In botany, a tree is a perennial plant with an elongated stem, or trunk, supporting branches and leaves in most species. In some usages, the definition of a tree may be narrower, including only woody plants with secondary growth, plants that are usable as lumber or plants above a specified height. Trees are not a group but include a variety of plant species that have independently evolved a woody trunk. In looser senses, the palms, the tree ferns, bananas. Trees tend to be long-lived, some reaching several thousand years old, the tallest known tree, a coast redwood named Hyperion, stands 115.6 m high. Trees have been in existence for 370 million years and it is estimated that there are just over 3 trillion mature trees in the world. A tree typically has many secondary branches supported clear of the ground by the trunk and this trunk typically contains woody tissue for strength, and vascular tissue to carry materials from one part of the tree to another. For most trees it is surrounded by a layer of bark which serves as a protective barrier, below the ground, the roots branch and spread out widely, they serve to anchor the tree and extract moisture and nutrients from the soil. Above ground, the divide into smaller branches and shoots. The shoots typically bear leaves, which light energy and convert it into sugars by photosynthesis, providing the food for the trees growth. Flowers and fruit may also be present, but some trees, such as conifers, instead have pollen cones and seed cones, others, such as tree ferns, trees play a significant role in reducing erosion and moderating the climate. They remove carbon dioxide from the atmosphere and store large quantities of carbon in their tissues, trees and forests provide a habitat for many species of animals and plants. Tropical rainforests are one of the most biodiverse habitats in the world, trees provide shade and shelter, timber for construction, fuel for cooking and heating, and fruit for food as well as having many other uses. In parts of the world, forests are shrinking as trees are cleared to increase the amount of available for agriculture. Because of their longevity and usefulness, trees have always revered, with sacred groves in various cultures. Although tree is a term of common parlance, there is no universally recognised precise definition of what a tree is, either botanically or in common language. In its broadest sense, a tree is any plant with the form of an elongated stem, or trunk. Trees are also defined by height, with smaller plants from 0.5 to 10 m being called shrubs
8.
Mineral
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A mineral is a naturally occurring chemical compound, usually of crystalline form and abiogenic in origin. A mineral has one specific chemical composition, whereas a rock can be an aggregate of different minerals or mineraloids, the study of minerals is called mineralogy. There are over 5,300 known mineral species, over 5,070 of these have been approved by the International Mineralogical Association, the silicate minerals compose over 90% of the Earths crust. The diversity and abundance of species is controlled by the Earths chemistry. Silicon and oxygen constitute approximately 75% of the Earths crust, which translates directly into the predominance of silicate minerals, minerals are distinguished by various chemical and physical properties. Differences in chemical composition and crystal structure distinguish the various species, changes in the temperature, pressure, or bulk composition of a rock mass cause changes in its minerals. Minerals can be described by their various properties, which are related to their chemical structure. Common distinguishing characteristics include crystal structure and habit, hardness, lustre, diaphaneity, colour, streak, tenacity, cleavage, fracture, parting, more specific tests for describing minerals include magnetism, taste or smell, radioactivity and reaction to acid. Minerals are classified by key chemical constituents, the two dominant systems are the Dana classification and the Strunz classification, the silicate class of minerals is subdivided into six subclasses by the degree of polymerization in the chemical structure. All silicate minerals have a unit of a 4− silica tetrahedron—that is, a silicon cation coordinated by four oxygen anions. These tetrahedra can be polymerized to give the subclasses, orthosilicates, disilicates, cyclosilicates, inosilicates, phyllosilicates, other important mineral groups include the native elements, sulfides, oxides, halides, carbonates, sulfates, and phosphates. The first criterion means that a mineral has to form by a natural process, stability at room temperature, in the simplest sense, is synonymous to the mineral being solid. More specifically, a compound has to be stable or metastable at 25 °C, modern advances have included extensive study of liquid crystals, which also extensively involve mineralogy. Minerals are chemical compounds, and as such they can be described by fixed or a variable formula, many mineral groups and species are composed of a solid solution, pure substances are not usually found because of contamination or chemical substitution. Finally, the requirement of an ordered atomic arrangement is usually synonymous with crystallinity, however, crystals are also periodic, an ordered atomic arrangement gives rise to a variety of macroscopic physical properties, such as crystal form, hardness, and cleavage. There have been recent proposals to amend the definition to consider biogenic or amorphous substances as minerals. The formal definition of an approved by the IMA in 1995, A mineral is an element or chemical compound that is normally crystalline. However, if geological processes were involved in the genesis of the compound, Mineral classification schemes and their definitions are evolving to match recent advances in mineral science
9.
Quartz
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Quartz is the second most abundant mineral in Earths continental crust, behind feldspar. There are many different varieties of quartz, several of which are semi-precious gemstones, since antiquity, varieties of quartz have been the most commonly used minerals in the making of jewelry and hardstone carvings, especially in Eurasia. The word quartz is derived from the German word Quarz and its Middle High German ancestor twarc, the Ancient Greeks referred to quartz as κρύσταλλος derived from the Ancient Greek κρύος meaning icy cold, because some philosophers apparently believed the mineral to be a form of supercooled ice. Today, the rock crystal is sometimes used as an alternative name for the purest form of quartz. Quartz belongs to the crystal system. The ideal crystal shape is a six-sided prism terminating with six-sided pyramids at each end, well-formed crystals typically form in a bed that has unconstrained growth into a void, usually the crystals are attached at the other end to a matrix and only one termination pyramid is present. However, doubly terminated crystals do occur where they develop freely without attachment, a quartz geode is such a situation where the void is approximately spherical in shape, lined with a bed of crystals pointing inward. α-quartz crystallizes in the crystal system, space group P3121 and P3221 respectively. β-quartz belongs to the system, space group P6222 and P6422. These space groups are truly chiral, both α-quartz and β-quartz are examples of chiral crystal structures composed of achiral building blocks. The transformation between α- and β-quartz only involves a comparatively minor rotation of the tetrahedra with respect to one another, although many of the varietal names historically arose from the color of the mineral, current scientific naming schemes refer primarily to the microstructure of the mineral. Color is an identifier for the cryptocrystalline minerals, although it is a primary identifier for the macrocrystalline varieties. Pure quartz, traditionally called rock crystal or clear quartz, is colorless and transparent or translucent, common colored varieties include citrine, rose quartz, amethyst, smoky quartz, milky quartz, and others. The most important distinction between types of quartz is that of macrocrystalline and the microcrystalline or cryptocrystalline varieties, the cryptocrystalline varieties are either translucent or mostly opaque, while the transparent varieties tend to be macrocrystalline. Chalcedony is a form of silica consisting of fine intergrowths of both quartz, and its monoclinic polymorph moganite. Other opaque gemstone varieties of quartz, or mixed rocks including quartz, often including contrasting bands or patterns of color, are agate, carnelian or sard, onyx, heliotrope, amethyst is a form of quartz that ranges from a bright to dark or dull purple color. The worlds largest deposits of amethysts can be found in Brazil, Mexico, Uruguay, Russia, France, Namibia, sometimes amethyst and citrine are found growing in the same crystal. It is then referred to as ametrine, an amethyst is formed when there is iron in the area where it was formed
10.
Sediment
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For sediment in beverages, see dregs. For example, sand and silt can be carried in suspension in water and on reaching the sea be deposited by sedimentation. Sediments are most often transported by water, but also wind, beach sands and river channel deposits are examples of fluvial transport and deposition, though sediment also often settles out of slow-moving or standing water in lakes and oceans. Desert sand dunes and loess are examples of transport and deposition. Glacial moraine deposits and till are ice-transported sediments, sediment can be classified based on its grain size and/or its composition. Sediment size is measured on a log base 2 scale, called the Phi scale, composition of sediment can be measured in terms of, parent rock lithology mineral composition chemical make-up. This leads to an ambiguity in which clay can be used as both a size-range and a composition, sediment is transported based on the strength of the flow that carries it and its own size, volume, density, and shape. Stronger flows will increase the lift and drag on the particle, causing it to rise, rivers and streams carry sediment in their flows. This sediment can be in a variety of locations within the flow and these relationships are shown in the following table for the Rouse number, which is a ratio of sediment fall velocity to upwards velocity. If the upwards velocity is less than the settling velocity, but still high enough for the sediment to move, it will move along the bed as bed load by rolling, sliding. If the upwards velocity is higher than the velocity, the sediment will be transported high in the flow as wash load. As there are generally a range of different particle sizes in the flow, sediment motion can create self-organized structures such as ripples, dunes, antidunes on the river or stream bed. These bedforms are often preserved in rocks and can be used to estimate the direction. Overland flow can erode soil particles and transport them downslope, the erosion associated with overland flow may occur through different methods depending on meteorological and flow conditions. If the initial impact of rain droplets dislodges soil, the phenomenon is called rainsplash erosion, if overland flow is directly responsible for sediment entrainment but does not form gullies, it is called sheet erosion. If the flow and the substrate permit channelization, gullies may form, glaciers carry a wide range of sediment sizes, and deposit it in moraines. The overall balance between sediment in transport and sediment being deposited on the bed is given by the Exner equation and this expression states that the rate of increase in bed elevation due to deposition is proportional to the amount of sediment that falls out of the flow. This can be localized, and simply due to obstacles, examples are scour holes behind boulders, where flow accelerates
11.
Volcanic ash
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Volcanic ash consists of fragments of pulverized rock, minerals and volcanic glass, created during volcanic eruptions and measuring less than 2 mm in diameter. The term volcanic ash is often loosely used to refer to all explosive eruption products. Volcanic ash is formed during volcanic eruptions when dissolved gases in magma expand. The force of the escaping gas shatters the magma and propels it into the atmosphere where it solidifies into fragments of volcanic rock and glass. Ash is also produced when magma comes into contact with water during phreatomagmatic eruptions, once in the air, ash is transported by wind up to thousands of kilometers away. Volcanic ash is formed during volcanic eruptions, phreatomagmatic eruptions. Explosive eruptions occur when magma decompresses as it rises, allowing dissolved volatiles to exsolve into gas bubbles, as more bubbles nucleate a foam is produced, which decreases the density of the magma, accelerating it up the conduit. Fragmentation occurs when bubbles occupy ~70-80 vol% of the erupting mixture, when fragmentation occurs, violently expanding bubbles tear the magma apart into fragments which are ejected into the atmosphere where they solidify into ash particles. Fragmentation is an efficient process of ash formation and is capable of generating very fine ash even without the addition of water. Volcanic ash is produced during phreatomagmatic eruptions. During these eruptions fragmentation occurs when magma comes into contact with bodies of water groundwater, as the magma, which is significantly hotter than the boiling point of water, comes into contact with water an insulating vapor film forms. Eventually this vapor film will collapse leading to direct coupling of the cold water and this increases the heat transfer which leads to the rapid expansion of water and fragmentation of the magma into small particles which are subsequently ejected from the volcanic vent. Fragmentation causes an increase in area between magma and water creating a feedback mechanism, leading to further fragmentation and production of fine ash particles. Pyroclastic density currents can also produce ash particles and these are typically produced by lava dome collapse or collapse of the eruption column. Within pyroclastic density currents particle abrasion occurs as particles interact with each resulting in a reduction in grain size. In addition, ash can be produced during secondary fragmentation of pumice fragments and these processes produce large quantities of very fine grained ash which is removed from pyroclastic density currents in co-ignimbrite ash plumes. Physical and chemical characteristics of volcanic ash are primarily controlled by the style of volcanic eruption, another parameter controlling the amount of ash produced is the duration of the eruption, the longer the eruption is sustained, the more ash will be produced. The types of minerals present in volcanic ash are dependent on the chemistry of the magma from which it erupted, low energy eruptions of basalt produce a characteristically dark coloured ash containing ~45 - 55% silica that is generally rich in iron and magnesium
12.
Oxygen
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Oxygen is a chemical element with symbol O and atomic number 8. It is a member of the group on the periodic table and is a highly reactive nonmetal. By mass, oxygen is the third-most abundant element in the universe, after hydrogen, at standard temperature and pressure, two atoms of the element bind to form dioxygen, a colorless and odorless diatomic gas with the formula O2. This is an important part of the atmosphere and diatomic oxygen gas constitutes 20. 8% of the Earths atmosphere, additionally, as oxides the element makes up almost half of the Earths crust. Most of the mass of living organisms is oxygen as a component of water, conversely, oxygen is continuously replenished by photosynthesis, which uses the energy of sunlight to produce oxygen from water and carbon dioxide. Oxygen is too reactive to remain a free element in air without being continuously replenished by the photosynthetic action of living organisms. Another form of oxygen, ozone, strongly absorbs ultraviolet UVB radiation, but ozone is a pollutant near the surface where it is a by-product of smog. At low earth orbit altitudes, sufficient atomic oxygen is present to cause corrosion of spacecraft, the name oxygen was coined in 1777 by Antoine Lavoisier, whose experiments with oxygen helped to discredit the then-popular phlogiston theory of combustion and corrosion. One of the first known experiments on the relationship between combustion and air was conducted by the 2nd century BCE Greek writer on mechanics, Philo of Byzantium. In his work Pneumatica, Philo observed that inverting a vessel over a burning candle, Philo incorrectly surmised that parts of the air in the vessel were converted into the classical element fire and thus were able to escape through pores in the glass. Many centuries later Leonardo da Vinci built on Philos work by observing that a portion of air is consumed during combustion and respiration, Oxygen was discovered by the Polish alchemist Sendivogius, who considered it the philosophers stone. In the late 17th century, Robert Boyle proved that air is necessary for combustion, English chemist John Mayow refined this work by showing that fire requires only a part of air that he called spiritus nitroaereus. From this he surmised that nitroaereus is consumed in both respiration and combustion, Mayow observed that antimony increased in weight when heated, and inferred that the nitroaereus must have combined with it. Accounts of these and other experiments and ideas were published in 1668 in his work Tractatus duo in the tract De respiratione. Robert Hooke, Ole Borch, Mikhail Lomonosov, and Pierre Bayen all produced oxygen in experiments in the 17th and the 18th century but none of them recognized it as a chemical element. This may have been in part due to the prevalence of the philosophy of combustion and corrosion called the phlogiston theory, which was then the favored explanation of those processes. Established in 1667 by the German alchemist J. J. Becher, one part, called phlogiston, was given off when the substance containing it was burned, while the dephlogisticated part was thought to be its true form, or calx. The fact that a substance like wood gains overall weight in burning was hidden by the buoyancy of the combustion products
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