Podolia Governorate was an administrative-territorial unit (guberniya) of the Southwestern Krai of the Russian Empire. It bordered Volhynian Governorate to the north, Kiev Governorate to the east, Kherson Governorate to the southeast, Bessarabia Governorate to the south, and Austria to the west. Its administrative centre was Kamenets-Podolsky (Kamianets-Podilskyi), which later moved to Vinnitsa (Vinnytsia). The governorate covered areas of Ukraine's partially Khmelnytskyi and most of Vinnytsia Oblasts, along with the fractionally recognised state of Transnistria.

Volhynia Governorate, also known as Volyn Governorate, was an administrative-territorial unit (guberniya) of the Southwestern Krai of the Russian Empire. It consisted of an area of 71,736 square kilometres (27,697 sq mi) and a population of 2,989,482 inhabitants. The governorate bordered Grodno and Minsk Governorates to the north, Kiev Governorate to the east, Podolia Governorate to the south, Lublin and Siedlce Governorates, and after 1912, Kholm Governorate and Austria to the west. Its capital was in Novograd-Volynsky until 1804, and then Zhitomir. It corresponded to most of modern-day Volyn, Rivne and Zhytomyr Oblasts of Ukraine and some parts of Brest and Gomel Regions of Belarus.