1.
Melting point
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The melting point of a solid is the temperature at which it changes state from solid to liquid at atmospheric pressure. At the melting point the solid and liquid phase exist in equilibrium, the melting point of a substance depends on pressure and is usually specified at standard pressure. When considered as the temperature of the change from liquid to solid. Because of the ability of some substances to supercool, the point is not considered as a characteristic property of a substance. For most substances, melting and freezing points are approximately equal, for example, the melting point and freezing point of mercury is 234.32 kelvins. However, certain substances possess differing solid-liquid transition temperatures, for example, agar melts at 85 °C and solidifies from 31 °C to 40 °C, such direction dependence is known as hysteresis. The melting point of ice at 1 atmosphere of pressure is close to 0 °C. In the presence of nucleating substances the freezing point of water is the same as the melting point, the chemical element with the highest melting point is tungsten, at 3687 K, this property makes tungsten excellent for use as filaments in light bulbs. Many laboratory techniques exist for the determination of melting points, a Kofler bench is a metal strip with a temperature gradient. Any substance can be placed on a section of the strip revealing its thermal behaviour at the temperature at that point, differential scanning calorimetry gives information on melting point together with its enthalpy of fusion. A basic melting point apparatus for the analysis of crystalline solids consists of an oil bath with a transparent window, the several grains of a solid are placed in a thin glass tube and partially immersed in the oil bath. The oil bath is heated and with the aid of the melting of the individual crystals at a certain temperature can be observed. In large/small devices, the sample is placed in a heating block, the measurement can also be made continuously with an operating process. For instance, oil refineries measure the point of diesel fuel online, meaning that the sample is taken from the process. This allows for more frequent measurements as the sample does not have to be manually collected, for refractory materials the extremely high melting point may be determined by heating the material in a black body furnace and measuring the black-body temperature with an optical pyrometer. For the highest melting materials, this may require extrapolation by several hundred degrees, the spectral radiance from an incandescent body is known to be a function of its temperature. An optical pyrometer matches the radiance of a body under study to the radiance of a source that has been previously calibrated as a function of temperature, in this way, the measurement of the absolute magnitude of the intensity of radiation is unnecessary. However, known temperatures must be used to determine the calibration of the pyrometer, for temperatures above the calibration range of the source, an extrapolation technique must be employed
2.
Winemaking
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Winemaking or vinification, is the production of wine, starting with selection of the grapes or other produce and ending with bottling the finished wine. Although most wine is made from grapes, it may also be made from fruits or plants. Mead is a wine that is made with honey being the primary ingredient after water, Winemaking can be divided into two general categories, still wine production and sparkling wine production. The science of wine and winemaking is known as oenology, a person who makes wine is traditionally called a winemaker or vintner. After the harvest, the grapes are taken into a winery, at this stage red wine making diverges from white wine making. Red wine is made from the must of red or black grapes and fermentation occurs together with the grape skins, white wine is made by fermenting juice which is made by pressing crushed grapes to extract a juice, the skins are removed and play no further role. Occasionally white wine is made from red grapes, this is done by extracting their juice with minimal contact with the grapes skins. Rosé wines are made from red grapes where the juice is allowed to stay in contact with the dark skins long enough to pick up a pinkish color or by blending red wine with white wine. White and rosé wines extract little of the contained in the skins. To start primary fermentation yeast may be added to the must for red wine or may occur naturally as ambient yeast on the grapes or in the air, yeast may be added to the juice for white wine. During this fermentation, which takes between one and two weeks, the yeast converts most of the sugars in the grape juice into ethanol. The carbon dioxide is lost to the atmosphere, after the primary fermentation of red grapes the free run wine is pumped off into tanks and the skins are pressed to extract the remaining juice and wine. The press wine is blended with the free run wine at the winemakers discretion, the wine is kept warm and the remaining sugars are converted into alcohol and carbon dioxide. The next process in the making of red wine is malo-lactic conversion and this is a bacterial process which converts crisp, green apple malic acid to soft, creamy lactic acid softening the taste of the wine. Red wine is transferred to oak barrels to mature for a period of weeks or months. The wine must be settled or clarified and adjustments made prior to bottling, the time from harvest to drinking can vary from a few months for Beaujolais nouveau wines to over twenty years for wine of good structure with high levels of acid, tannin or sugar. However, only about 10% of all red and 5% of white wine will taste better after five years than it will after just one year. Depending on the quality of grape and the wine style
3.
Potassium
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Potassium is a chemical element with symbol K and atomic number 19. It was first isolated from potash, the ashes of plants, in the periodic table, potassium is one of the alkali metals. Potassium in nature only in ionic salts. It is found dissolved in sea water, and is part of many minerals, naturally occurring potassium is composed of three isotopes, of which 40K is radioactive. Traces of 40K are found in all potassium, and it is the most common radioisotope in the human body, Potassium is chemically very similar to sodium, the previous element in Group 1 of the periodic table. They have a similar energy, which allows for each atom to give up its sole outer electron. That they are different elements combine with the same anions to make similar salts was suspected in 1702. Most industrial applications of potassium exploit the high solubility in water of potassium compounds, heavy crop production rapidly depletes the soil of potassium, and this can be remedied with agricultural fertilizers containing potassium, accounting for 95% of global potassium chemical production. Potassium ions are necessary for the function of all living cells, fresh fruits and vegetables are good dietary sources of potassium. Potassium is the second least dense metal after lithium and it is a soft solid with a low melting point, and can be easily cut with a knife. Freshly cut potassium is silvery in appearance, but it begins to tarnish toward gray immediately on exposure to air, in a flame test, potassium and its compounds emit a lilac color with a peak emission wavelength of 766.5 nanometers. Neutral potassium atoms have 19 electrons, one more than the stable configuration of the noble gas argon. This process requires so little energy that potassium is readily oxidized by atmospheric oxygen, in contrast, the second ionization energy is very high, because removal of two electrons breaks the stable noble gas electronic configuration. Potassium therefore does not readily form compounds with the state of +2 or higher. Potassium is an active metal that reacts violently with oxygen in water. With oxygen it forms potassium peroxide, and with water potassium forms potassium hydroxide, the reaction of potassium with water is dangerous because of its violent exothermic character and the production of hydrogen gas. Hydrogen reacts again with atmospheric oxygen, producing water, which reacts with the remaining potassium and this reaction requires only traces of water, because of this, potassium and the liquid sodium-potassium — NaK — are potent desiccants that can be used to dry solvents prior to distillation. Because of the sensitivity of potassium to water and air, reactions with other elements are only in an inert atmosphere such as argon gas using air-free techniques
4.
Sulfuric acid
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Sulfuric acid is a highly corrosive strong mineral acid with the molecular formula H2SO4 and molecular weight 98.079 g/mol. It is a pungent-ethereal, colorless to slightly yellow liquid that is soluble in water at all concentrations. Sometimes, it is dyed dark brown during production to alert people to its hazards, the historical name of this acid is oil of vitriol. Sulfuric acid is an acid and shows different properties depending upon its concentration. Its corrosiveness on other materials, like metals, living tissues or even stones, can be ascribed to its strong acidic nature and, if concentrated. It is also hygroscopic, readily absorbing water vapour from the air, Sulfuric acid at a high concentration can cause very serious damage upon contact, since not only does it cause chemical burns via hydrolysis, but also secondary thermal burns through dehydration. It can lead to permanent blindness if splashed onto eyes and irreversible damage if swallowed, Sulfuric acid has a wide range of applications including in domestic acidic drain cleaners, as an electrolyte in lead-acid batteries and in various cleaning agents. It is also a central substance in the chemical industry, principal uses include mineral processing, fertilizer manufacturing, oil refining, wastewater processing, and chemical synthesis. It is widely produced with different methods, such as process, wet sulfuric acid process, lead chamber process. The study of vitriol, a category of glassy minerals from which the acid can be derived, sumerians had a list of types of vitriol that they classified according to the substances color. Some of the earliest discussions on the origin and properties of vitriol is in the works of the Greek physician Dioscorides, galen also discussed its medical use. Ibn Sina focused on its uses and different varieties of vitriol. Sulfuric acid was called oil of vitriol by medieval European alchemists because it was prepared by roasting green vitriol in an iron retort, there are references to it in the works of Vincent of Beauvais and in the Compositum de Compositis ascribed to Saint Albertus Magnus. A passage from Pseudo-Geber´s Summa Perfectionis was long considered to be the first recipe for sulfuric acid, in the seventeenth century, the German-Dutch chemist Johann Glauber prepared sulfuric acid by burning sulfur together with saltpeter, in the presence of steam. As saltpeter decomposes, it oxidizes the sulfur to SO3, in 1736, Joshua Ward, a London pharmacist, used this method to begin the first large-scale production of sulfuric acid. This process allowed the effective industrialization of sulfuric acid production, after several refinements, this method, called the lead chamber process or chamber process, remained the standard for sulfuric acid production for almost two centuries. Sulfuric acid created by John Roebucks process approached a 65% concentration, later refinements to the lead chamber process by French chemist Joseph Louis Gay-Lussac and British chemist John Glover improved concentration to 78%. However, the manufacture of dyes and other chemical processes require a more concentrated product
5.
Mineralogy
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Mineralogy is a subject of geology specializing in the scientific study of chemistry, crystal structure, and physical properties of minerals and mineralized artifacts. Specific studies within mineralogy include the processes of mineral origin and formation, classification of minerals, their geographical distribution, the German Renaissance specialist Georgius Agricola wrote works such as De re metallica and De Natura Fossilium which began the scientific approach to the subject. Systematic scientific studies of minerals and rocks developed in post-Renaissance Europe, the modern study of mineralogy was founded on the principles of crystallography and to the microscopic study of rock sections with the invention of the microscope in the 17th century. Nicholas Steno first observed the law of constancy of interfacial angles in quartz crystals in 1669 and this was later generalized and established experimentally by Jean-Baptiste L. Romé de lIslee in 1783. In 1814, Jöns Jacob Berzelius introduced a classification of minerals based on their chemistry rather than their crystal structure, james D. Dana published his first edition of A System of Mineralogy in 1837, and in a later edition introduced a chemical classification that is still the standard. It, however, retains a focus on the structures commonly encountered in rock-forming minerals. An initial step in identifying a mineral is to examine its physical properties and these can be classified into density, measures of mechanical cohesion, macroscopic visual properties, magnetic and electric properties, radioactivity and solubility in hydrogen chloride. If the mineral is crystallized, it will also have a distinctive crystal habit that reflects the crystal structure or internal arrangement of atoms. It is also affected by crystal defects and twinning. Many crystals are polymorphic, having more than one crystal structure depending on factors such as pressure and temperature. ”Examples of polymorphs are calcite and aragonite - two minerals with identical chemical composition, distinguished by their crystallography, calcite is rhombohedral and aragonite is orthorhombic. The crystal structure is the arrangement of atoms in a crystal and it is represented by a lattice of points which repeats a basic pattern, called a unit cell, in three dimensions. The lattice can be characterized by its symmetries and by the dimensions of the unit cell and these dimensions are represented by three Miller indices. The lattice remains unchanged by certain symmetry operations about any point in the lattice, reflection, rotation, inversion, and rotary inversion. Together, they make up an object called a crystallographic point group or crystal class. There are 32 possible crystal classes, in addition, there are operations that displace all the points, translation, screw axis, and glide plane. In combination with the point symmetries, they form 230 possible space groups, most geology departments have X-ray powder diffraction equipment to analyze the crystal structures of minerals. X-rays have wavelengths that are the order of magnitude as the distances between atoms. In a sample that is ground to a powder, the X-rays sample a random distribution of all crystal orientations, powder diffraction can distinguish between minerals that may appear the same in a hand sample, for example quartz and its polymorphs tridymite and cristobalite
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