1.
Oxide minerals
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The oxide mineral class includes those minerals in which the oxide anion is bonded to one or more metal ions. The hydroxide bearing minerals are typically included in the oxide class, the minerals with complex anion groups such as the silicates, sulfates, carbonates and phosphates are classed separately. This list uses it to modify the Classification of Nickel–Strunz,00 Clinobirnessite*,00 Kleberite*,00 Chubutite*,00 Struverite
2.
Chemical formula
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These are limited to a single typographic line of symbols, which may include subscripts and superscripts. A chemical formula is not a name, and it contains no words. Although a chemical formula may imply certain simple chemical structures, it is not the same as a full chemical structural formula. Chemical formulas can fully specify the structure of only the simplest of molecules and chemical substances, the simplest types of chemical formulas are called empirical formulas, which use letters and numbers indicating the numerical proportions of atoms of each type. Molecular formulas indicate the numbers of each type of atom in a molecule. For example, the formula for glucose is CH2O, while its molecular formula is C6H12O6. This is possible if the relevant bonding is easy to show in one dimension, an example is the condensed molecular/chemical formula for ethanol, which is CH3-CH2-OH or CH3CH2OH. For reasons of structural complexity, there is no condensed chemical formula that specifies glucose, chemical formulas may be used in chemical equations to describe chemical reactions and other chemical transformations, such as the dissolving of ionic compounds into solution. A chemical formula identifies each constituent element by its chemical symbol, in empirical formulas, these proportions begin with a key element and then assign numbers of atoms of the other elements in the compound, as ratios to the key element. For molecular compounds, these numbers can all be expressed as whole numbers. For example, the formula of ethanol may be written C2H6O because the molecules of ethanol all contain two carbon atoms, six hydrogen atoms, and one oxygen atom. Some types of compounds, however, cannot be written with entirely whole-number empirical formulas. An example is boron carbide, whose formula of CBn is a variable non-whole number ratio with n ranging from over 4 to more than 6.5. When the chemical compound of the consists of simple molecules. These types of formulas are known as molecular formulas and condensed formulas. A molecular formula enumerates the number of atoms to reflect those in the molecule, so that the formula for glucose is C6H12O6 rather than the glucose empirical formula. However, except for very simple substances, molecular chemical formulas lack needed structural information, for simple molecules, a condensed formula is a type of chemical formula that may fully imply a correct structural formula. For example, ethanol may be represented by the chemical formula CH3CH2OH
3.
Crystal system
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In crystallography, the terms crystal system, crystal family and lattice system each refer to one of several classes of space groups, lattices, point groups or crystals. Informally, two crystals are in the crystal system if they have similar symmetries, though there are many exceptions to this. Space groups and crystals are divided into seven crystal systems according to their point groups, five of the crystal systems are essentially the same as five of the lattice systems, but the hexagonal and trigonal crystal systems differ from the hexagonal and rhombohedral lattice systems. The six crystal families are formed by combining the hexagonal and trigonal crystal systems into one hexagonal family, a lattice system is a class of lattices with the same set of lattice point groups, which are subgroups of the arithmetic crystal classes. The 14 Bravais lattices are grouped into seven lattice systems, triclinic, monoclinic, orthorhombic, tetragonal, rhombohedral, hexagonal, in a crystal system, a set of point groups and their corresponding space groups are assigned to a lattice system. Of the 32 point groups that exist in three dimensions, most are assigned to only one system, in which case both the crystal and lattice systems have the same name. However, five point groups are assigned to two systems, rhombohedral and hexagonal, because both exhibit threefold rotational symmetry. These point groups are assigned to the crystal system. In total there are seven crystal systems, triclinic, monoclinic, orthorhombic, tetragonal, trigonal, hexagonal, a crystal family is determined by lattices and point groups. It is formed by combining crystal systems which have space groups assigned to a lattice system. In three dimensions, the families and systems are identical, except the hexagonal and trigonal crystal systems. In total there are six families, triclinic, monoclinic, orthorhombic, tetragonal, hexagonal. Spaces with less than three dimensions have the number of crystal systems, crystal families and lattice systems. In one-dimensional space, there is one crystal system, in 2D space, there are four crystal systems, oblique, rectangular, square and hexagonal. The relation between three-dimensional crystal families, crystal systems and lattice systems is shown in the table, Note. To avoid confusion of terminology, the term trigonal lattice is not used, if the original structure and inverted structure are identical, then the structure is centrosymmetric. Still, even for non-centrosymmetric case, inverted structure in some cases can be rotated to align with the original structure and this is the case of non-centrosymmetric achiral structure. If the inverted structure cannot be rotated to align with the structure, then the structure is chiral
4.
Tetragonal crystal system
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In crystallography, the tetragonal crystal system is one of the 7 crystal systems. Tetragonal crystal lattices result from stretching a cubic lattice along one of its vectors, so that the cube becomes a rectangular prism with a square base. There is only one tetragonal Bravais lattice in two dimensions, the square lattice, there are two tetragonal Bravais lattices, the simple tetragonal and the centered tetragonal. One might suppose stretching face-centered cubic would result in face-centered tetragonal, BCT is considered more fundamental, so that is the standard terminology. Crystal structure point groups Bravais lattices
5.
Crystallographic point group
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For a periodic crystal, the group must also be consistent with maintenance of the three-dimensional translational symmetry that defines crystallinity. The macroscopic properties of a crystal would look exactly the same before, in the classification of crystals, each point group is also known as a crystal class. There are infinitely many three-dimensional point groups, however, the crystallographic restriction of the infinite families of general point groups results in there being only 32 crystallographic point groups. These 32 point groups are one-and-the same as the 32 types of morphological crystalline symmetries derived in 1830 by Johann Friedrich Christian Hessel from a consideration of observed crystal forms, the point groups are denoted by their component symmetries. There are a few standard notations used by crystallographers, mineralogists, for the correspondence of the two systems below, see crystal system. In Schoenflies notation, point groups are denoted by a symbol with a subscript. The symbols used in crystallography mean the following, Cn indicates that the group has a rotation axis. Cnh is Cn with the addition of a plane perpendicular to the axis of rotation. Cnv is Cn with the addition of n mirror planes parallel to the axis of rotation, s2n denotes a group that contains only a 2n-fold rotation-reflection axis. Dn indicates that the group has a rotation axis plus n twofold axes perpendicular to that axis. Dnh has, in addition, a plane perpendicular to the n-fold axis. Dnd has, in addition to the elements of Dn, mirror planes parallel to the n-fold axis, the letter T indicates that the group has the symmetry of a tetrahedron. Td includes improper rotation operations, T excludes improper rotation operations, the letter O indicates that the group has the symmetry of an octahedron, with or without improper operations. Due to the crystallographic restriction theorem, n =1,2,3,4, d4d and D6d are actually forbidden because they contain improper rotations with n=8 and 12 respectively. The 27 point groups in the table plus T, Td, Th, O, an abbreviated form of the Hermann–Mauguin notation commonly used for space groups also serves to describe crystallographic point groups. Group names are Molecular symmetry Point group Space group Point groups in three dimensions Crystal system Point-group symbols in International Tables for Crystallography,12.1, pp. 818-820 Names and symbols of the 32 crystal classes in International Tables for Crystallography. 10.1, p.794 Pictorial overview of the 32 groups Point Groups - Flow Chart Inorganic Chemistry Group Theory Practice Problems
6.
H-M symbol
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In geometry, Hermann–Mauguin notation is used to represent the symmetry elements in point groups, plane groups and space groups. It is named after the German crystallographer Carl Hermann and the French mineralogist Charles-Victor Mauguin and this notation is sometimes called international notation, because it was adopted as standard by the International Tables For Crystallography since their first edition in 1935. Rotation axes are denoted by a number n —1,2,3,4,5,6,7,8, for improper rotations, Hermann–Mauguin symbols show rotoinversion axes, unlike Schoenflies and Shubnikov notations, where the preference is given to rotation-reflection axes. The rotoinversion axes are represented by the number with a macron. The symbol for a plane is m. The direction of the plane is defined as the direction of perpendicular to the face. Hermann–Mauguin symbols show symmetrically non-equivalent axes and planes, the direction of a symmetry element is represented by its position in the Hermann–Mauguin symbol. If a rotation axis n and a mirror plane m have the same direction, if two or more axes have the same direction, the axis with higher symmetry is shown. Higher symmetry means that the axis generates a pattern with more points, for example, rotation axes 3,4,5,6,7,8 generate 3-, 4-, 5-, 6-, 7-, 8-point patterns, respectively. Improper rotation axes 3,4,5,6,7,8 generate 6-, 4-, 10-, 6-, 14-, 8-point patterns, if both, the rotation and rotoinversion axes satisfy the previous rule, the rotation axis should be chosen. For example, 3/m combination is equivalent to 6, since 6 generates 6 points, and 3 generates only 3,6 should be written instead of 3/m. Analogously, in the case when both 3 and 3 axes are present,3 should be written, however we write 4/m, not 4/m, because both 4 and 4 generate four points. Finally, the Hermann–Mauguin symbol depends on the type of the group and these groups may contain only two-fold axes, mirror planes, and inversion center. These are the point groups 1 and 1,2, m, and 2/m, and 222, 2/m2/m2/m. If the symbol contains three positions, then they denote symmetry elements in the x, y, z direction, First position — primary direction — z direction, assigned to the higher-order axis. Second position — symmetrically equivalent secondary directions, which are perpendicular to the z-axis and these can be 2, m, or 2/m. Third position — symmetrically equivalent tertiary directions, passing between secondary directions and these can be 2, m, or 2/m. These are the crystallographic groups 3,32, 3m,3, and 32/m,4,422, 4mm,4, 42m, 4/m, and 4/m2/m2/m, and 6,622, 6mm,6, 6m2, 6/m, and 6/m2/m2/m
7.
Space group
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In mathematics, physics and chemistry, a space group is the symmetry group of a configuration in space, usually in three dimensions. In three dimensions, there are 219 distinct types, or 230 if chiral copies are considered distinct, Space groups are also studied in dimensions other than 3 where they are sometimes called Bieberbach groups, and are discrete cocompact groups of isometries of an oriented Euclidean space. In crystallography, space groups are called the crystallographic or Fedorov groups. A definitive source regarding 3-dimensional space groups is the International Tables for Crystallography, in 1879 Leonhard Sohncke listed the 65 space groups whose elements preserve the orientation. More accurately, he listed 66 groups, but Fedorov and Schönflies both noticed that two of them were really the same, the space groups in 3 dimensions were first enumerated by Fedorov, and shortly afterwards were independently enumerated by Schönflies. The correct list of 230 space groups was found by 1892 during correspondence between Fedorov and Schönflies, burckhardt describes the history of the discovery of the space groups in detail. The space groups in three dimensions are made from combinations of the 32 crystallographic point groups with the 14 Bravais lattices, the combination of all these symmetry operations results in a total of 230 different space groups describing all possible crystal symmetries. The elements of the space group fixing a point of space are rotations, reflections, the identity element, the translations form a normal abelian subgroup of rank 3, called the Bravais lattice. There are 14 possible types of Bravais lattice, the quotient of the space group by the Bravais lattice is a finite group which is one of the 32 possible point groups. Translation is defined as the moves from one point to another point. A glide plane is a reflection in a plane, followed by a parallel with that plane. This is noted by a, b or c, depending on which axis the glide is along. There is also the n glide, which is a glide along the half of a diagonal of a face, and the d glide, the latter is called the diamond glide plane as it features in the diamond structure. In 17 space groups, due to the centering of the cell, the glides occur in two directions simultaneously, i. e. the same glide plane can be called b or c, a or b. For example, group Abm2 could be also called Acm2, group Ccca could be called Cccb, in 1992, it was suggested to use symbol e for such planes. The symbols for five groups have been modified, A screw axis is a rotation about an axis. These are noted by a number, n, to describe the degree of rotation, the degree of translation is then added as a subscript showing how far along the axis the translation is, as a portion of the parallel lattice vector. So,21 is a rotation followed by a translation of 1/2 of the lattice vector
8.
Crystal habit
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In mineralogy, crystal habit is the characteristic external shape of an individual crystal or crystal group. A single crystals habit is a description of its shape and its crystallographic forms. Recognizing the habit may help in identifying a mineral, when the faces are well-developed due to uncrowded growth a crystal is called euhedral, one with partially developed faces is subhedral, and one with undeveloped crystal faces is called anhedral. The long axis of a quartz crystal typically has a six-sided prismatic habit with parallel opposite faces. Aggregates can be formed of individual crystals with euhedral to anhedral grains, the arrangement of crystals within the aggregate can be characteristic of certain minerals. For example, minerals used for asbestos insulation often grow in a fibrous habit, the terms used by mineralogists to report crystal habits describe the typical appearance of an ideal mineral. Recognizing the habit can aid in identification as some habits are characteristic, most minerals, however, do not display ideal habits due to conditions during crystallization. Minerals belonging to the crystal system do not necessarily exhibit the same habit. Some habits of a mineral are unique to its variety and locality, For example, while most sapphires form elongate barrel-shaped crystals, ordinarily, the latter habit is seen only in ruby. Sapphire and ruby are both varieties of the mineral, corundum. Some minerals may replace other existing minerals while preserving the originals habit, a classic example is tigers eye quartz, crocidolite asbestos replaced by silica. While quartz typically forms prismatic crystals, in tigers eye the original fibrous habit of crocidolite is preserved, the names of crystal habits are derived from, Predominant crystal faces. Abnormal grain growth Grain growth Crystallization
9.
Crystal twinning
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Crystal twinning occurs when two separate crystals share some of the same crystal lattice points in a symmetrical manner. The result is an intergrowth of two separate crystals in a variety of specific configurations, a twin boundary or composition surface separates the two crystals. Crystallographers classify twinned crystals by a number of twin laws and these twin laws are specific to the crystal system. The type of twinning can be a tool in mineral identification. Twinning can often be a problem in X-ray crystallography, as a crystal does not produce a simple diffraction pattern. Simple twinned crystals may be contact twins or penetration twins, contact twins share a single composition surface often appearing as mirror images across the boundary. Plagioclase, quartz, gypsum, and spinel often exhibit contact twinning, merohedral twinning occurs when the lattices of the contact twins superimpose in three dimensions, such as by relative rotation of one twin from the other. In penetration twins the individual crystals have the appearance of passing through each other in a symmetrical manner, orthoclase, staurolite, pyrite, and fluorite often show penetration twinning. If several twin crystal parts are aligned by the same twin law they are referred to as multiple or repeated twins, if these multiple twins are aligned in parallel they are called polysynthetic twins. When the multiple twins are not parallel they are cyclic twins, albite, calcite, and pyrite often show polysynthetic twinning. Closely spaced polysynthetic twinning is often observed as striations or fine lines on the crystal face. Rutile, aragonite, cerussite, and chrysoberyl often exhibit cyclic twinning, 2-normal twin, -when the twin plane and compositional plane lies noramally. 3-complex twin, -combination of parallel twinning and normal twinning on one compositional plane, there are three modes of formation of twinned crystals. Growth twins are the result of an interruption or change in the lattice during formation or growth due to a possible deformation from a larger substituting ion, deformation or gliding twins are the result of stress on the crystal after the crystal has formed. If a FCC metal like aluminum experiences extreme stresses, it will experience twinning as seen in the case of explosions, deformation twinning is a common result of regional metamorphism. Crystals that grow adjacent to each other may be aligned to resemble twinning and this parallel growth simply reduces system energy and is not twinning. Twin boundaries occur when two crystals of the same type intergrow, so only a slight misorientation exists between them. It is a highly symmetrical interface, often with one crystal the mirror image of the other, also and this is also a much lower-energy interface than the grain boundaries that form when crystals of arbitrary orientation grow together
10.
Cleavage (crystal)
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Cleavage, in mineralogy, is the tendency of crystalline materials to split along definite crystallographic structural planes. Cleavage forms parallel to planes, Basal or pinacoidal cleavage occurs when there is only one cleavage plane. Mica also has basal cleavage, this is why mica can be peeled into thin sheets, cubic cleavage occurs on when there are three cleavage planes intersecting at 90 degrees. Halite has cubic cleavage, and therefore, when halite crystals are broken, octahedral cleavage occurs when there are four cleavage planes in a crystal. Octahedral cleavage is common for semiconductors, rhombohedral cleavage occurs when there are three cleavage planes intersecting at angles that are not 90 degrees. Prismatic cleavage occurs when there are two planes in a crystal. Dodecahedral cleavage occurs when there are six cleavage planes in a crystal, crystal parting occurs when minerals break along planes of structural weakness due to external stress or along twin composition planes. Parting breaks are very similar in appearance to cleavage, but only due to stress. Examples include magnetite which shows octahedral parting, the parting of corundum. Cleavage is a property traditionally used in mineral identification, both in hand specimen and microscopic examination of rock and mineral studies. As an example, the angles between the cleavage planes for the pyroxenes and the amphiboles are diagnostic. Crystal cleavage is of importance in the electronics industry and in the cutting of gemstones. Precious stones are generally cleaved by impact, as in diamond cutting, synthetic single crystals of semiconductor materials are generally sold as thin wafers which are much easier to cleave. Elemental semiconductors are diamond cubic, a group for which octahedral cleavage is observed. This means that some orientations of wafer allow near-perfect rectangles to be cleaved, most other commercial semiconductors can be made in the related zinc blende structure, with similar cleavage planes. Cleavage Mineral galleries, Mineral properties – Cleavage
11.
Fracture (mineralogy)
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In the field of mineralogy, fracture is the texture and shape of a rocks surface formed when a mineral is fractured. Minerals often have a highly distinctive fracture, making it a feature used in their identification. Fracture differs from cleavage in that the latter involves clean splitting along the planes of the minerals crystal structure. All minerals exhibit fracture, but when very strong cleavage is present, conchoidal fracture breakage that resembles the concentric ripples of a mussel shell. It often occurs in amorphous or fine-grained minerals such as flint, opal or obsidian, subconchoidal fracture is similar to conchoidal fracture, but with less significant curvature. Earthy fracture is reminiscent of freshly broken soil and it is frequently seen in relatively soft, loosely bound minerals, such as limonite, kaolinite and aluminite. Hackly fracture is jagged, sharp and not even and it occurs when metals are torn, and so is often encountered in native metals such as copper and silver. Splintery fracture comprises sharp elongated points and it is particularly seen in fibrous minerals such as chrysotile, but may also occur in non-fibrous minerals such as kyanite. Uneven fracture is a surface or one with random irregularities. It occurs in a range of minerals including arsenopyrite, pyrite and magnetite. Rudolf Duda and Lubos Rejl, Minerals of the World http, //www. galleries. com/minerals/property/fracture. htm
12.
Mohs scale of mineral hardness
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The Mohs scale of mineral hardness is a qualitative ordinal scale characterizing scratch resistance of various minerals through the ability of harder material to scratch softer material. Created in 1812 by German geologist and mineralogist Friedrich Mohs, it is one of several definitions of hardness in materials science, while greatly facilitating the identification of minerals in the field, the Mohs scale does not show how well hard materials perform in an industrial setting. Despite its lack of precision, the Mohs scale is highly relevant for field geologists, the Mohs scale hardness of minerals can be commonly found in reference sheets. Reference materials may be expected to have a uniform Mohs hardness, the Mohs scale of mineral hardness is based on the ability of one natural sample of mineral to scratch another mineral visibly. The samples of matter used by Mohs are all different minerals, Minerals are pure substances found in nature. Rocks are made up of one or more minerals, as the hardest known naturally occurring substance when the scale was designed, diamonds are at the top of the scale. The hardness of a material is measured against the scale by finding the hardest material that the material can scratch. For example, if material is scratched by apatite but not by fluorite. Scratching a material for the purposes of the Mohs scale means creating non-elastic dislocations visible to the naked eye, frequently, materials that are lower on the Mohs scale can create microscopic, non-elastic dislocations on materials that have a higher Mohs number. The Mohs scale is an ordinal scale. For example, corundum is twice as hard as topaz, the table below shows the comparison with the absolute hardness measured by a sclerometer, with pictorial examples. On the Mohs scale, a streak plate has a hardness of 7.0, using these ordinary materials of known hardness can be a simple way to approximate the position of a mineral on the scale. The table below incorporates additional substances that may fall between levels, Comparison between Hardness and Hardness, Mohs hardness of elements is taken from G. V, samsonov in Handbook of the physicochemical properties of the elements, IFI-Plenum, New York, USA,1968. The Hardness of Minerals and Rocks
13.
Lustre (mineralogy)
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Lustre or luster is the way light interacts with the surface of a crystal, rock, or mineral. The word traces its origins back to the latin lux, meaning light, a range of terms are used to describe lustre, such as earthy, metallic, greasy, and silky. Similarly, the term refers to a glassy lustre. A list of terms is given below. Lustre varies over a continuum, and so there are no rigid boundaries between the different types of lustre. The terms are frequently combined to describe types of lustre. Some minerals exhibit unusual optical phenomena, such as asterism or chatoyancy, a list of such phenomena is given below. Adamantine minerals possess a superlative lustre, which is most notably seen in diamond, such minerals are transparent or translucent, and have a high refractive index. Minerals with an adamantine lustre are uncommon, with examples being cerussite. Minerals with a degree of lustre are referred to as subadamantine, with some examples being garnet. Dull minerals exhibit little to no lustre, due to coarse granulations which scatter light in all directions, a distinction is sometimes drawn between dull minerals and earthy minerals, with the latter being coarser, and having even less lustre. Greasy minerals resemble fat or grease, a greasy lustre often occurs in minerals containing a great abundance of microscopic inclusions, with examples including opal and cordierite. Many minerals with a greasy lustre also feel greasy to the touch, metallic minerals have the lustre of polished metal, and with ideal surfaces will work as a reflective surface. Examples include galena, pyrite and magnetite, pearly minerals consist of thin transparent co-planar sheets. Light reflecting from these layers give them a lustre reminiscent of pearls, such minerals possess perfect cleavage, with examples including muscovite and stilbite. Resinous minerals have the appearance of resin, chewing gum or plastic, a principal example is amber, which is a form of fossilized resin. Silky minerals have an arrangement of extremely fine fibres, giving them a lustre reminiscent of silk. Examples include asbestos, ulexite and the satin spar variety of gypsum, a fibrous lustre is similar, but has a coarser texture
14.
Streak (mineralogy)
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The streak of a mineral is the color of the powder produced when it is dragged across an un-weathered surface. If no streak seems to be made, the streak is said to be white or colorless. Streak is particularly important as a diagnostic for opaque and colored materials and it is less useful for silicate minerals, most of which have a white streak or are too hard to powder easily. The apparent color of a mineral can vary widely because of impurities or a disturbed macroscopic crystal structure. Small amounts of an impurity that strongly absorbs a particular wavelength can radically change the wavelengths of light that are reflected by the specimen, and thus change the apparent color. However, when the specimen is dragged to produce a streak, it is broken into randomly oriented microscopic crystals, the surface across which the mineral is dragged is called a streak plate, and is generally made of unglazed porcelain tile. In the absence of a plate, the unglazed underside of a porcelain bowl or vase or the back of a glazed tile will work. Sometimes a streak is more easily or accurately described by comparing it with the streak made by another streak plate. Because the trail left behind results from the mineral being crushed into powder, in case of harder minerals, the color of the powder can be determined by filing or crushing with a hammer a small sample, which is then usually rubbed on a streak plate. Most minerals that are harder have a white streak. Some minerals leave a similar to their natural color, such as cinnabar. Other minerals leave surprising colors, such as fluorite, which always has a streak, although it can appear in purple, blue, yellow. Hematite, which is black in appearance, leaves a red streak which accounts for its name, galena, which can be similar in appearance to hematite, is easily distinguished by its gray streak. Hamilton, W. R. Cambridge Guide to Minerals, Rocks, the Encyclopedia of Gemstones and Minerals. New York, Facts on File. p.251, physical Characteristics of Minerals, at Introduction to Mineralogy by Andrea Bangert What is Streak
15.
Specific gravity
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This page is about the measurement using water as a reference. For a general use of gravity, see relative density. See intensive property for the property implied by specific, Apparent specific gravity is the ratio of the weight of a volume of the substance to the weight of an equal volume of the reference substance. The reference substance is always water at its densest for liquids. Nonetheless, the temperature and pressure must be specified for both the sample and the reference, pressure is nearly always 1 atm. Temperatures for both sample and reference vary from industry to industry, in British beer brewing, the practice for specific gravity as specified above is to multiply it by 1000. Being a ratio of densities, specific gravity is a dimensionless quantity, Specific gravity varies with temperature and pressure, reference and sample must be compared at the same temperature and pressure or be corrected to a standard reference temperature and pressure. Substances with a gravity of 1 are neutrally buoyant in water. Those with SG greater than 1 are denser than water and will, disregarding surface tension effects and those with an SG less than 1 are less dense than water and will float on it. In scientific work, the relationship of mass to volume is expressed directly in terms of the density of the substance under study. It is in industry where specific gravity finds wide application, often for historical reasons. True specific gravity can be expressed mathematically as, S G true = ρ sample ρ H2 O where ρ sample is the density of the sample, the density of water varies with temperature and pressure as does the density of the sample. So it is necessary to specify the temperatures and pressures at which the densities or weights were determined and it is nearly always the case that measurements are made at 1 nominal atmosphere. For true specific gravity calculations, air pressure must be considered, temperatures are specified by the notation with T s representing the temperature at which the samples density was determined and T r the temperature at which the reference density is specified. For example, SG would be understood to mean that the density of the sample was determined at 20°C and of the water at 4°C. Taking into account different sample and reference temperatures, we note that, while S G H2 O =1.000000, it is also the case that S G H2 O =0.998203 /0.999840 =0.998363. Here, temperature is being specified using the current ITS-90 scale, on the previous IPTS-68 scale, the densities at 20 °C and 4 °C are 0.9982071 and 0.9999720 respectively, resulting in an SG value for water of 0.9982343. For example, in the industry, the Plato table lists sucrose concentration by weight against true SG
16.
Refractive index
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In optics, the refractive index or index of refraction n of a material is a dimensionless number that describes how light propagates through that medium. It is defined as n = c v, where c is the speed of light in vacuum, for example, the refractive index of water is 1.333, meaning that light travels 1.333 times faster in a vacuum than it does in water. The refractive index determines how light is bent, or refracted. The refractive indices also determine the amount of light that is reflected when reaching the interface, as well as the angle for total internal reflection. This implies that vacuum has a index of 1. The refractive index varies with the wavelength of light and this is called dispersion and causes the splitting of white light into its constituent colors in prisms and rainbows, and chromatic aberration in lenses. Light propagation in absorbing materials can be described using a refractive index. The imaginary part then handles the attenuation, while the real part accounts for refraction, the concept of refractive index is widely used within the full electromagnetic spectrum, from X-rays to radio waves. It can also be used with wave phenomena such as sound, in this case the speed of sound is used instead of that of light and a reference medium other than vacuum must be chosen. Thomas Young was presumably the person who first used, and invented, at the same time he changed this value of refractive power into a single number, instead of the traditional ratio of two numbers. The ratio had the disadvantage of different appearances, newton, who called it the proportion of the sines of incidence and refraction, wrote it as a ratio of two numbers, like 529 to 396. Hauksbee, who called it the ratio of refraction, wrote it as a ratio with a fixed numerator, hutton wrote it as a ratio with a fixed denominator, like 1.3358 to 1. Young did not use a symbol for the index of refraction, in the next years, others started using different symbols, n, m, and µ. For visible light most transparent media have refractive indices between 1 and 2, a few examples are given in the adjacent table. These values are measured at the yellow doublet D-line of sodium, with a wavelength of 589 nanometers, gases at atmospheric pressure have refractive indices close to 1 because of their low density. Almost all solids and liquids have refractive indices above 1.3, aerogel is a very low density solid that can be produced with refractive index in the range from 1.002 to 1.265. Moissanite lies at the end of the range with a refractive index as high as 2.65. Most plastics have refractive indices in the range from 1.3 to 1.7, for infrared light refractive indices can be considerably higher
17.
Manganite
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Manganite is a mineral composed of manganese oxide-hydroxide, MnO, crystallizing in the monoclinic system. Crystals of manganite are prismatic and deeply striated parallel to their length, the color is dark steel-grey to iron-black, and the luster brilliant and submetallic. The streak is dark reddish brown, the hardness is 4, and the specific gravity is 4.3. There is a cleavage parallel to the brachypinacoid, and less-perfect cleavage parallel to the prism faces. The mineral contains 89. 7% manganese sesquioxide, it dissolves in acid with evolution of chlorine. Manganite occurs with other manganese oxides in deposits formed by circulating meteoric water in the environment in clay deposits. It forms by low temperature hydrothermal action in veins in association with calcite, barite, often associated with pyrolusite, braunite, hausmannite and goethite. Manganite occurs in specimens exhibiting good crystal form at Ilfeld in the Harz Mountains of Germany, good crystals have also been found at Atikokan, Ontario and Nova Scotia, Canada. As an ore of manganese it is less abundant than pyrolusite or psilomelane. Although described with various names as early as 1772, the name manganite was first applied in a publication by W. Haidinger in 1827. The mineral was used in times as a pigment, by humans. Manganite is believed to have used in prehistoric times to start a wood fire. Manganite lowers the temperature of wood from 350 degrees Celsius to 250 degrees Celsius. Manganite powder has been a common find in Neanderthal archaeological sites, in this article Manganese oxide This article incorporates text from a publication now in the public domain, Chisholm, Hugh, ed. article name needed
18.
Mineral
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A mineral is a naturally occurring chemical compound, usually of crystalline form and abiogenic in origin. A mineral has one specific chemical composition, whereas a rock can be an aggregate of different minerals or mineraloids, the study of minerals is called mineralogy. There are over 5,300 known mineral species, over 5,070 of these have been approved by the International Mineralogical Association, the silicate minerals compose over 90% of the Earths crust. The diversity and abundance of species is controlled by the Earths chemistry. Silicon and oxygen constitute approximately 75% of the Earths crust, which translates directly into the predominance of silicate minerals, minerals are distinguished by various chemical and physical properties. Differences in chemical composition and crystal structure distinguish the various species, changes in the temperature, pressure, or bulk composition of a rock mass cause changes in its minerals. Minerals can be described by their various properties, which are related to their chemical structure. Common distinguishing characteristics include crystal structure and habit, hardness, lustre, diaphaneity, colour, streak, tenacity, cleavage, fracture, parting, more specific tests for describing minerals include magnetism, taste or smell, radioactivity and reaction to acid. Minerals are classified by key chemical constituents, the two dominant systems are the Dana classification and the Strunz classification, the silicate class of minerals is subdivided into six subclasses by the degree of polymerization in the chemical structure. All silicate minerals have a unit of a 4− silica tetrahedron—that is, a silicon cation coordinated by four oxygen anions. These tetrahedra can be polymerized to give the subclasses, orthosilicates, disilicates, cyclosilicates, inosilicates, phyllosilicates, other important mineral groups include the native elements, sulfides, oxides, halides, carbonates, sulfates, and phosphates. The first criterion means that a mineral has to form by a natural process, stability at room temperature, in the simplest sense, is synonymous to the mineral being solid. More specifically, a compound has to be stable or metastable at 25 °C, modern advances have included extensive study of liquid crystals, which also extensively involve mineralogy. Minerals are chemical compounds, and as such they can be described by fixed or a variable formula, many mineral groups and species are composed of a solid solution, pure substances are not usually found because of contamination or chemical substitution. Finally, the requirement of an ordered atomic arrangement is usually synonymous with crystallinity, however, crystals are also periodic, an ordered atomic arrangement gives rise to a variety of macroscopic physical properties, such as crystal form, hardness, and cleavage. There have been recent proposals to amend the definition to consider biogenic or amorphous substances as minerals. The formal definition of an approved by the IMA in 1995, A mineral is an element or chemical compound that is normally crystalline. However, if geological processes were involved in the genesis of the compound, Mineral classification schemes and their definitions are evolving to match recent advances in mineral science
19.
Manganese dioxide
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Manganese oxide is the inorganic compound with the formula MnO2. This blackish or brown solid occurs naturally as the mineral pyrolusite, which is the ore of manganese. The principal use for MnO2 is for dry-cell batteries, such as the alkaline battery, MnO2 is also used as a pigment and as a precursor to other manganese compounds, such as KMnO4. It is used as a reagent in organic synthesis, for example, MnO2 in the α polymorph can incorporate a variety of atoms in the tunnels or channels between the magnesium oxide octahedra. There is considerable interest in α-MnO2 as a cathode for lithium ion batteries. Several polymorphs of MnO2 are claimed, as well as a hydrated form, like many other dioxides, MnO2 crystallizes in the rutile crystal structure, with three-coordinate oxide and octahedral metal centres. MnO2 is characteristically nonstoichiometric, being deficient in oxygen, the complicated solid-state chemistry of this material is relevant to the lore of freshly prepared MnO2 in organic synthesis. The α-polymorph of MnO2 has an open structure with channels which can accommodate metal atoms such as silver or barium. α-MnO2 is often called Hollandite, after a related mineral. Naturally occurring manganese dioxide contains impurities and an amount of manganese oxide. Only a limited number of deposits contain the γ modification in purity sufficient for the battery industry, production of batteries and ferrite requires high purity manganese dioxide. Batteries require electrolytic manganese dioxide while ferrites require chemical manganese dioxide, one method starts with natural manganese dioxide and converts it using dinitrogen tetroxide and water to a manganese nitrate solution. Evaporation of the water, leaves the crystalline nitrate salt, at temperatures of 400 °C, the salt decomposes, releasing N 2O4 and leaving a residue of purified manganese dioxide. These two steps can be summarized as, MnO2 + N 2O4 ⇌ Mn 2 In another process manganese dioxide is reduced to manganese oxide which is dissolved in sulfuric acid. The filtered solution is treated with ammonium carbonate to precipitate MnCO3, the carbonate is calcined in air to give a mixture of manganese and manganese oxides. To complete the process, a suspension of this material in sulfuric acid is treated with sodium chlorate, chloric acid, which forms in situ, converts any Mn and Mn oxides to the dioxide, releasing chlorine as a by-product. A third process involves manganese heptoxide and manganese monoxide, the two reagents combine with a 1,3 ratio to form manganese dioxide, Mn 2O7 +3 MnO →5 MnO2 Lastly the action of potassium permanganate over manganese sulphate crystals produces the desired oxide. 2 KMnO4 +3 MnSO4 +2 H 2O→5 MnO2 + K 2SO4 +2 H 2SO4 Electrolytic manganese dioxide is used in zinc-carbon batteries together with zinc chloride, EMD is commonly used in zinc manganese dioxide rechargeable alkaline cells also
20.
Manganese
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Manganese is a chemical element with symbol Mn and atomic number 25. It is not found as an element in nature, it is often found in minerals in combination with iron. Manganese is a metal with important industrial metal alloy uses, particularly in stainless steels, by the mid-18th century, Swedish chemist Carl Wilhelm Scheele had used pyrolusite to produce chlorine. Scheele and others were aware that pyrolusite contained a new element, johan Gottlieb Gahn was the first to isolate an impure sample of manganese metal in 1774, which he did by reducing the dioxide with carbon. Manganese phosphating is used for rust and corrosion prevention on steel, ionized manganese is used industrially as pigments of various colors, which depend on the oxidation state of the ions. The permanganates of alkali and alkaline earth metals are powerful oxidizers, Manganese dioxide is used as the cathode material in zinc-carbon and alkaline batteries. In biology, manganese ions function as cofactors for a variety of enzymes with many functions. Manganese enzymes are essential in detoxification of superoxide free radicals in organisms that must deal with elemental oxygen. Manganese also functions in the complex of photosynthetic plants. The element is a trace mineral for all known living organisms but is a neurotoxin. In larger amounts, and apparently with far greater effectiveness through inhalation, Manganese is a silvery-gray metal that resembles iron. It is hard and very brittle, difficult to fuse, Manganese metal and its common ions are paramagnetic. Manganese tarnishes slowly in air and oxidizes like iron in water containing dissolved oxygen, naturally occurring manganese is composed of one stable isotope, 55Mn. Eighteen radioisotopes have been isolated and described, the most stable being 53Mn with a half-life of 3.7 million years, 54Mn with a half-life of 312.3 days, and 52Mn with a half-life of 5.591 days. All of the radioactive isotopes have half-lives of less than three hours, and the majority of less than one minute. Manganese also has three meta states, Manganese is part of the iron group of elements, which are thought to be synthesized in large stars shortly before the supernova explosion. 53Mn decays to 53Cr with a half-life of 3.7 million years, because of its relatively short half-life, 53Mn is relatively rare, produced by cosmic rays impact on iron. Manganese isotopic contents are combined with chromium isotopic contents and have found application in isotope geology
21.
Oxygen
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Oxygen is a chemical element with symbol O and atomic number 8. It is a member of the group on the periodic table and is a highly reactive nonmetal. By mass, oxygen is the third-most abundant element in the universe, after hydrogen, at standard temperature and pressure, two atoms of the element bind to form dioxygen, a colorless and odorless diatomic gas with the formula O2. This is an important part of the atmosphere and diatomic oxygen gas constitutes 20. 8% of the Earths atmosphere, additionally, as oxides the element makes up almost half of the Earths crust. Most of the mass of living organisms is oxygen as a component of water, conversely, oxygen is continuously replenished by photosynthesis, which uses the energy of sunlight to produce oxygen from water and carbon dioxide. Oxygen is too reactive to remain a free element in air without being continuously replenished by the photosynthetic action of living organisms. Another form of oxygen, ozone, strongly absorbs ultraviolet UVB radiation, but ozone is a pollutant near the surface where it is a by-product of smog. At low earth orbit altitudes, sufficient atomic oxygen is present to cause corrosion of spacecraft, the name oxygen was coined in 1777 by Antoine Lavoisier, whose experiments with oxygen helped to discredit the then-popular phlogiston theory of combustion and corrosion. One of the first known experiments on the relationship between combustion and air was conducted by the 2nd century BCE Greek writer on mechanics, Philo of Byzantium. In his work Pneumatica, Philo observed that inverting a vessel over a burning candle, Philo incorrectly surmised that parts of the air in the vessel were converted into the classical element fire and thus were able to escape through pores in the glass. Many centuries later Leonardo da Vinci built on Philos work by observing that a portion of air is consumed during combustion and respiration, Oxygen was discovered by the Polish alchemist Sendivogius, who considered it the philosophers stone. In the late 17th century, Robert Boyle proved that air is necessary for combustion, English chemist John Mayow refined this work by showing that fire requires only a part of air that he called spiritus nitroaereus. From this he surmised that nitroaereus is consumed in both respiration and combustion, Mayow observed that antimony increased in weight when heated, and inferred that the nitroaereus must have combined with it. Accounts of these and other experiments and ideas were published in 1668 in his work Tractatus duo in the tract De respiratione. Robert Hooke, Ole Borch, Mikhail Lomonosov, and Pierre Bayen all produced oxygen in experiments in the 17th and the 18th century but none of them recognized it as a chemical element. This may have been in part due to the prevalence of the philosophy of combustion and corrosion called the phlogiston theory, which was then the favored explanation of those processes. Established in 1667 by the German alchemist J. J. Becher, one part, called phlogiston, was given off when the substance containing it was burned, while the dephlogisticated part was thought to be its true form, or calx. The fact that a substance like wood gains overall weight in burning was hidden by the buoyancy of the combustion products
22.
Ore
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An ore is a type of rock that contains sufficient minerals with important elements including metals that can be economically extracted from the rock. The ores are extracted from the earth through mining, they are refined to extract the valuable element. The grade or concentration of an ore mineral, or metal, as well as its form of occurrence, will directly affect the costs associated with mining the ore. The cost of extraction must thus be weighed against the value contained in the rock to determine what ore can be processed. Metal ores are generally oxides, sulfides, silicates, or native metals that are not commonly concentrated in the Earths crust, the ores must be processed to extract the metals of interest from the waste rock and from the ore minerals. Ore bodies are formed by a variety of geological processes, the process of ore formation is called ore genesis. An ore deposit is an accumulation of ore and this is distinct from a mineral resource as defined by the mineral resource classification criteria. An ore deposit is one occurrence of a particular ore type, Ore deposits are classified according to various criteria developed via the study of economic geology, or ore genesis. Stratiform arkose-hosted and shale-hosted copper, typified by the Zambian copperbelt and this identifies, early on, whether further investment in estimation and engineering studies is warranted and identifies key risks and areas for further work. This is because the distribution of ores is unequal and dislocated from locations of peak demand. Other, lesser, commodities do not have international clearing houses and benchmark prices and this generally makes determining the price of ores of this nature opaque and difficult. Such metals include lithium, niobium-tantalum, bismuth, antimony and rare earths, most of these commodities are also dominated by one or two major suppliers with >60% of the worlds reserves. The London Metal Exchange aims to add uranium to its list of metals on warrant, the World Bank reports that China was the top importer of ores and metals in 2005 followed by the USA and Japan. Economic geology Mineral resource classification Ore genesis Petrology Froth Flotation Extractive metallurgy DILL, the “chessboard” classification scheme of mineral deposits, Mineralogy and geology from aluminum to zirconium, Earth-Science Reviews, Volume 100, Issue 1-4, June 2010, Pages 1-420
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Amorphous solid
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In condensed matter physics and materials science, an amorphous or non-crystalline solid is a solid that lacks the long-range order that is characteristic of a crystal. In some older books, the term has been used synonymously with glass, nowadays, glassy solid or amorphous solid is considered to be the overarching concept, and glass the more special case, A glass is an amorphous solid that exhibits a glass transition. Other types of solids include gels, thin films. Amorphous materials have a structure made of interconnected structural blocks. Even amorphous materials have some shortrange order at the length scale due to the nature of chemical bonding. Furthermore, in small crystals a large fraction of the atoms are the crystal, relaxation of the surface and interfacial effects distort the atomic positions. Amorphous phases are important constituents of thin films, which are layers of a few nm to some tens of µm thickness deposited upon a substrate. For higher values, the diffusion of deposited atomic species would allow for the formation of crystallites with long range atomic order. Regarding their applications, amorphous metallic layers played an important role in the discussion of a suspected superconductivity in amorphous metals, today, optical coatings made from TiO2, SiO2, Ta2O5 etc. and combinations of them in most cases consist of amorphous phases of these compounds. Much research is carried out into thin films as a gas separating membrane layer. Also, hydrogenated amorphous silicon, a-Si, H in short, is of significance for thin film solar cells. In case of a-Si, H the missing long-range order between silicon atoms is partly induced by the presence by hydrogen in the percent range, the occurrence of amorphous phases turned out as a phenomenon of particular interest for studying thin film growth. Remarkably, the growth of polycrystalline films is used and preceded by an initial amorphous layer. The most investigated example is represented by thin multicrystalline silicon films, an initial amorphous layer was observed in many studies. The phenomenon has been interpreted in the framework of Ostwalds rule of stages that predicts the formation of phases to proceed with increasing condensation time towards increasing stability. Experimental studies of the phenomenon require a clearly defined state of the substrate surface, the Physics of Structurally Disordered Matter, An Introduction. Amorphous Solids and the Liquid State
24.
Hausmannite
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Hausmannite is a complex oxide of manganese containing both di- and tri-valent manganese. The formula can be represented as Mn2+Mn3+2O4 and it belongs to the spinel group and forms tetragonal crystals. Hausmannite is a brown to black mineral with Mohs hardness of 5.5. The type locality is Oehrenstock, Ilmenau, Thuringian Forest, Thuringia, Germany, locations include Batesville, Arkansas, US, Ilfeld, Germany, Langban, Sweden, and the Ural Mountains, Russia. High quality samples have found in South Africa and Namibia where it is associated with other manganese oxides, pyrolusite and psilomelane. Wilhelm Haidinger named it in honour of Johann Friedrich Ludwig Hausmann, Professor of Mineralogy, University of Göttingen, Germany
25.
Braunite
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Braunite is a silicate mineral containing both di- and tri-valent manganese with the chemical formula, Mn2+Mn3+6. Common impurities include iron, calcium, boron, barium, titanium, aluminium, braunite forms grey/black tetragonal crystals and has a Mohs hardness of 6 -6.5. It was named after the Wilhelm von Braun of Gotha, Thuringia, a calcium iron bearing variant, named braunite II, was discovered and described in 1967 from Kalahari, Cape Province, South Africa
26.
Goethite
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Goethite, is an iron bearing hydroxide mineral of the diaspore group, is found in soil and other low-temperature environments. Goethite has been known since ancient times for its use as a pigment. Evidence has been found of its use in paint pigment samples taken from the caves of Lascaux in France and it was first described in 1806 based on samples found in the Hollertszug Mine in Herdorf, Germany. The mineral was named after the German polymath and poet Johann Wolfgang von Goethe, in 2003, nanoparticulate authigenic goethite was shown to be the most common diagenetic iron oxyhydroxide in both marine and lake sediments. Goethite is an iron oxyhydroxide containing ferric iron and it is the main component of rust and bog iron ore. Goethites hardness ranges from 5.0 to 5.5 on the Mohs Scale, the mineral forms prismatic needle-like crystals, but is more typically massive. Feroxyhyte and lepidocrocite are both polymorphs of the iron oxyhydroxide FeO, although they have the same chemical formula as goethite, their different crystalline structures make them distinct minerals. Goethite often forms through the weathering of other minerals, and thus is a common component of soils. The formation of goethite is marked by the state change of Fe2+ to Fe3+. Because of this state change, goethite is commonly seen as a pseudomorph. As iron-bearing minerals are brought to the zone of oxidation within the soil and it may also be precipitated by groundwater or in other sedimentary conditions, or form as a primary mineral in hydrothermal deposits. Goethite has also found to be produced by the excretion processes of certain bacteria types. Goethite is found all over the planet, usually in the form of concretions, stalactitic formations, oolites and it is also a very common pseudomorph. It is frequently encountered in the areas at the head of spring waters, on cave floors. The boxworks or gossan resulting from the oxidation of ore deposits is formed of goethite along with other iron oxides. Significant deposits of goethite are found in England, Australia, Cuba, and Michigan, Minnesota, Missouri, Colorado, Alabama, Georgia, Virginia, and Tennessee, and Florida caves in the United States. In 2015 it was reported that limpets teeth have goethite fibres in them and its main modern use is as an iron ore, being referred to as brown iron ore. It does have some use as an earth pigment
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Hematite
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Hematite, also spelled as haematite, is the mineral form of iron oxide, one of several iron oxides. Hematite crystallizes in the lattice system, and it has the same crystal structure as ilmenite. Hematite and ilmenite form a solid solution at temperatures above 950 °C. Hematite is colored black to steel or silver-gray, brown to reddish brown and it is mined as the main ore of iron. Varieties include kidney ore, martite, iron rose and specularite, while the forms of hematite vary, they all have a rust-red streak. Hematite is harder than iron, but much more brittle. Maghemite is a hematite- and magnetite-related oxide mineral, huge deposits of hematite are found in banded iron formations. Gray hematite is typically found in places that can have still standing water or mineral hot springs, the mineral can precipitate out of water and collect in layers at the bottom of a lake, spring, or other standing water. Hematite can also occur without water, however, usually as the result of volcanic activity, the name hematite is derived from the Greek word for blood αἷμα haima, due to the red coloration found in some varities of hematite. The color of hematite lends itself to use as a pigment, ochre is a clay that is colored by varying amounts of hematite, varying between 20% and 70%. Red ochre contains unhydrated hematite, whereas yellow ochre contains hydrated hematite, the principal use of ochre is for tinting with a permanent color. The red chalk writing of this mineral was one of the earliest in the history of humans, the powdery mineral was first used 164,000 years ago by the Pinnacle-Point man possibly for social purposes. Hematite residues are found in graves from 80,000 years ago. Near Rydno in Poland and Lovas in Hungary red chalk mines have been found that are from 5000 BC, rich deposits of hematite have been found on the island of Elba that have been mined since the time of the Etruscans. Adding to the surprise was a transition with a decrease in temperature at around 260 K to a phase with no net magnetic moment. The disappearance of the moment with a decrease in temperature at 260 K is caused by a change in the anisotropy which causes the moments to align along the c axis, in this configuration, spin canting does not reduce the energy. The magnetic properties of bulk hematite differ from their nanoscale counterparts, for example, the Morin transition temperature of hematite decreases with a decrease in the particle size. Two other end-members are referred to as protohematite and hydrohematite, enhanced magnetic coercivities for hematite have been achieved by dry-heating a 2-line ferrihydrite precursor prepared from solution
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Redox
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Redox is a chemical reaction in which the oxidation states of atoms are changed. Any such reaction involves both a process and a complementary oxidation process, two key concepts involved with electron transfer processes. Redox reactions include all chemical reactions in which atoms have their oxidation state changed, in general, the chemical species from which the electron is stripped is said to have been oxidized, while the chemical species to which the electron is added is said to have been reduced. It can be explained in terms, Oxidation is the loss of electrons or an increase in oxidation state by a molecule, atom. Reduction is the gain of electrons or a decrease in state by a molecule, atom. As an example, during the combustion of wood, oxygen from the air is reduced, the reaction can occur relatively slowly, as in the case of rust, or more quickly, as in the case of fire. Redox is a portmanteau of reduction and oxidation, the word oxidation originally implied reaction with oxygen to form an oxide, since dioxygen was historically the first recognized oxidizing agent. Later, the term was expanded to encompass oxygen-like substances that accomplished parallel chemical reactions, ultimately, the meaning was generalized to include all processes involving loss of electrons. The word reduction originally referred to the loss in weight upon heating a metallic ore such as an oxide to extract the metal. In other words, ore was reduced to metal, antoine Lavoisier showed that this loss of weight was due to the loss of oxygen as a gas. Later, scientists realized that the atom gains electrons in this process. The meaning of reduction then became generalized to all processes involving gain of electrons. Even though reduction seems counter-intuitive when speaking of the gain of electrons, it help to think of reduction as the loss of oxygen. Since electrons are charged, it is also helpful to think of this as reduction in electrical charge. The electrochemist John Bockris has used the words electronation and deelectronation to describe reduction and oxidation processes respectively when they occur at electrodes and these words are analogous to protonation and deprotonation, but they have not been widely adopted by chemists. The term hydrogenation could be used instead of reduction, since hydrogen is the agent in a large number of reactions. But, unlike oxidation, which has been generalized beyond its root element, the word redox was first used in 1928. The processes of oxidation and reduction occur simultaneously and cannot happen independently of one another, the oxidation alone and the reduction alone are each called a half-reaction, because two half-reactions always occur together to form a whole reaction
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Hydrothermal
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Hydrothermal circulation in its most general sense is the circulation of hot water. Hydrothermal circulation occurs most often in the vicinity of sources of heat within the Earths crust, in general, this occurs near volcanic activity, but can occur in the deep crust related to the intrusion of granite, or as the result of orogeny or metamorphism. Hydrothermal circulation in the oceans is the passage of the water through mid-oceanic ridge systems, the former circulation type is sometimes termed active, and the latter passive. The heat source for the active vents is the newly formed basalt, and, for the highest temperature vents, the heat source for the passive vents is the still-cooling older basalts. Heat flow studies of the seafloor suggest that basalts within the oceanic crust take millions of years to cool as they continue to support passive hydrothermal circulation systems. Hydrothermal vents are locations on the seafloor where hydrothermal fluids mix into the overlying ocean, perhaps the best-known vent forms are the naturally occurring chimneys referred to as black smokers. Hydrothermal circulation is not limited to ocean ridge environments, the source water for hydrothermal explosions, geysers, and hot springs is heated groundwater convecting below and lateral to the hot water vent. Hydrothermal circulating convection cells exist any place an anomalous source of heat, such as an intruding magma or volcanic vent, hydrothermal also refers to the transport and circulation of water within the deep crust, in general from areas of hot rocks to areas of cooler rocks. During the early 1900s, various geologists worked to classify hydrothermal ore deposits that they assumed formed from upward-flowing aqueous solutions, waldemar Lindgren developed a classification based on interpreted decreasing temperature and pressure conditions of the depositing fluid. His terms, hypothermal, mesothermal, epithermal and teleothermal, expressed decreasing temperature, recent studies retain only the epithermal label
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Bog
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A bog is a wetland that accumulates peat, a deposit of dead plant material—often mosses, and in a majority of cases, sphagnum moss. It is one of the four types of wetlands. Other names for bogs include mire, quagmire, and muskeg and they are frequently covered in ericaceous shrubs rooted in the sphagnum moss and peat. The gradual accumulation of decayed plant material in a bog functions as a carbon sink, Bogs occur where the water at the ground surface is acidic and low in nutrients. In some cases, the water is derived entirely from precipitation, water flowing out of bogs has a characteristic brown colour, which comes from dissolved peat tannins. In general, the low fertility and cool climate results in relatively slow plant growth, large areas of landscape can be covered many metres deep in peat. Bogs have distinctive assemblages of animal, fungal and plant species, Bogs are widely distributed in cold, temperate climes, mostly in boreal ecosystems in the Northern Hemisphere. The worlds largest wetland is the bogs of the Western Siberian Lowlands in Russia. Large peat bogs also occur in North America, particularly the Hudson Bay Lowland and they are less common in the Southern Hemisphere, with the largest being the Magellanic moorland, comprising some 44,000 square kilometres. Sphagnum bogs were widespread in northern Europe but have often been cleared and drained for agriculture, a 2014 expedition leaving from Itanga village, Republic of the Congo discovered a peat bog as big as England which stretches into neighboring Democratic Republic of Congo. There are many highly specialised animals, fungi and plants associated with bog habitat, most are capable of tolerating the combination of low nutrient levels and waterlogging. Sphagnum moss is generally abundant, along with ericaceous shrubs, the shrubs are often evergreen, which is understood to assist in conservation of nutrients. In drier locations, evergreen trees can occur, in case the bog blends into the surrounding expanses of boreal evergreen forest. Sedges are one of the more common herbaceous species, carnivorous plants such as sundews and pitcher plants have adapted to the low-nutrient conditions by using invertebrates as a nutrient source. Orchids have adapted to these conditions through the use of fungi to extract nutrients. Some shrubs such as Myrica gale have root nodules in which nitrogen fixation occurs, Bogs are recognized as a significant/specific habitat type by a number of governmental and conservation agencies. They can provide habitat for mammals, such as caribou, moose, the United Kingdom in its Biodiversity Action Plan establishes bog habitats as a priority for conservation. Russia has a reserve system in the West Siberian Lowland
31.
Sodium
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Sodium is a chemical element with symbol Na and atomic number 11. It is a soft, silvery-white, highly reactive metal, Sodium is an alkali metal, being in group 1 of the periodic table, because it has a single electron in its outer shell that it readily donates, creating a positively charged atom—the Na+ cation. Its only stable isotope is 23Na, the free metal does not occur in nature, but must be prepared from compounds. Sodium is the sixth most abundant element in the Earths crust, Sodium was first isolated by Humphry Davy in 1807 by the electrolysis of sodium hydroxide. Among many other useful compounds, sodium hydroxide is used in soap manufacture, and sodium chloride is a de-icing agent. Sodium is an element for all animals and some plants. Sodium ions are the major cation in the fluid and as such are the major contributor to the ECF osmotic pressure. Loss of water from the ECF compartment increases the sodium concentration, isotonic loss of water and sodium from the ECF compartment decreases the size of that compartment in a condition called ECF hypovolemia. In nerve cells, the charge across the cell membrane enables transmission of the nerve impulse—an action potential—when the charge is dissipated. The melting and boiling points of sodium are lower than those of lithium but higher than those of the alkali metals potassium, rubidium. All of these high-pressure allotropes are insulators and electrides.3 nm, spin-orbit interactions involving the electron in the 3p orbital split the D line into two, at 589.0 and 589.6 nm, hyperfine structures involving both orbitals cause many more lines. Twenty isotopes of sodium are known, but only 23Na is stable, 23Na is created in the carbon-burning process in stars by fusing two carbon atoms together, this requires temperatures above 600 megakelvins and a star of at least three solar masses. Two nuclear isomers have been discovered, the one being 24mNa with a half-life of around 20.2 milliseconds. Sodium atoms have 11 electrons, one more than the stable configuration of the noble gas neon. This process requires so little energy that sodium is oxidized by giving up its 11th electron. In contrast, the ionization energy is very high, because the 10th electron is closer to the nucleus than the 11th electron. As a result, sodium usually forms ionic compounds involving the Na+ cation, the most common oxidation state for sodium is +1. It is generally less reactive than potassium and more reactive than lithium, Sodium metal is highly reducing, with the reduction of sodium ions requiring −2.71 volts, though potassium and lithium have even more negative potentials
32.
Magnesium
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Magnesium is a chemical element with symbol Mg and atomic number 12. Magnesium is the ninth most abundant element in the universe and it is produced in large, aging stars from the sequential addition of three helium nuclei to a carbon nucleus. When such stars explode as supernovas, much of the magnesium is expelled into the medium where it may recycle into new star systems. Magnesium is the eighth most abundant element in the Earths crust and the fourth most common element in the Earth, making up 13% of the planets mass and it is the third most abundant element dissolved in seawater, after sodium and chlorine. Magnesium occurs naturally only in combination with elements, where it invariably has a +2 oxidation state. The free element can be produced artificially, and is highly reactive, the free metal burns with a characteristic brilliant-white light. The metal is now obtained mainly by electrolysis of magnesium salts obtained from brine, Magnesium is less dense than aluminium, and the alloy is prized for its combination of lightness and strength. Magnesium is the eleventh most abundant element by mass in the body and is essential to all cells. Magnesium ions interact with polyphosphate compounds such as ATP, DNA, hundreds of enzymes require magnesium ions to function. Magnesium compounds are used medicinally as common laxatives, antacids, elemental magnesium is a gray-white lightweight metal, two-thirds the density of aluminium. Magnesium has the lowest melting and the lowest boiling point 1,363 K of all the alkaline earth metals, Magnesium reacts with water at room temperature, though it reacts much more slowly than calcium, a similar group 2 metal. When submerged in water, hydrogen bubbles form slowly on the surface of the metal—though, if powdered, the reaction occurs faster with higher temperatures. Magnesiums reversible reaction with water can be harnessed to store energy, Magnesium also reacts exothermically with most acids such as hydrochloric acid, producing the metal chloride and hydrogen gas, similar to the HCl reaction with aluminium, zinc, and many other metals. Magnesium is highly flammable, especially when powdered or shaved into thin strips, flame temperatures of magnesium and magnesium alloys can reach 3,100 °C, although flame height above the burning metal is usually less than 300 mm. Once ignited, such fires are difficult to extinguish, with combustion continuing in nitrogen, carbon dioxide, Magnesium may also be used as an igniter for thermite, a mixture of aluminium and iron oxide powder that ignites only at a very high temperature. When burning in air, magnesium produces a light that includes strong ultraviolet wavelengths. Magnesium powder was used for illumination in the early days of photography. Later, magnesium filament was used in electrically ignited single-use photography flashbulbs, Magnesium powder is used in fireworks and marine flares where a brilliant white light is required
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Aluminium
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Aluminium or aluminum is a chemical element in the boron group with symbol Al and atomic number 13. It is a silvery-white, soft, nonmagnetic, ductile metal, Aluminium metal is so chemically reactive that native specimens are rare and limited to extreme reducing environments. Instead, it is combined in over 270 different minerals. The chief ore of aluminium is bauxite, Aluminium is remarkable for the metals low density and its ability to resist corrosion through the phenomenon of passivation. Aluminium and its alloys are vital to the industry and important in transportation and structures, such as building facades. The oxides and sulfates are the most useful compounds of aluminium, despite its prevalence in the environment, no known form of life uses aluminium salts metabolically, but aluminium is well tolerated by plants and animals. Because of these salts abundance, the potential for a role for them is of continuing interest. Aluminium is a soft, durable, lightweight, ductile. It is nonmagnetic and does not easily ignite, a fresh film of aluminium serves as a good reflector of visible light and an excellent reflector of medium and far infrared radiation. The yield strength of aluminium is 7–11 MPa, while aluminium alloys have yield strengths ranging from 200 MPa to 600 MPa. Aluminium has about one-third the density and stiffness of steel and it is easily machined, cast, drawn and extruded. Aluminium atoms are arranged in a cubic structure. Aluminium has an energy of approximately 200 mJ/m2. Aluminium is a thermal and electrical conductor, having 59% the conductivity of copper. Aluminium is capable of superconductivity, with a critical temperature of 1.2 kelvin. Aluminium is the most common material for the fabrication of superconducting qubits, the strongest aluminium alloys are less corrosion resistant due to galvanic reactions with alloyed copper. This corrosion resistance is reduced by aqueous salts, particularly in the presence of dissimilar metals. In highly acidic solutions, aluminium reacts with water to form hydrogen, primarily because it is corroded by dissolved chlorides, such as common sodium chloride, household plumbing is never made from aluminium
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Electrolysis
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In chemistry and manufacturing, electrolysis is a technique that uses a direct electric current to drive an otherwise non-spontaneous chemical reaction. Electrolysis is commercially important as a stage in the separation of elements from naturally occurring sources such as using an electrolytic cell. The voltage that is needed for electrolysis to occur is called the decomposition potential, nevertheless, electrolysis, as a tool to study chemical reactions and obtain pure elements, precedes the coinage of the term and formal description by Faraday. 1785 – Martinus van Marums electrostatic generator was used to reduce tin, zinc,1800 – William Nicholson and Anthony Carlisle, decomposed water into hydrogen and oxygen. 1808 – Potassium, sodium, barium, calcium and magnesium were discovered by Sir Humphry Davy using electrolysis,1821 – Lithium was discovered by the English chemist William Thomas Brande, who obtained it by electrolysis of lithium oxide. 1833 – Michael Faraday develops his two laws of electrolysis, and provides an explanation of his laws. 1875 – Paul Émile Lecoq de Boisbaudran discovered gallium using electrolysis,1886 – Fluorine was discovered by Henri Moissan using electrolysis. The main components required to achieve electrolysis are, An electrolyte, a substance, frequently an ion-conducting polymer that contains free ions, if the ions are not mobile, as in a solid salt then electrolysis cannot occur. A direct current electrical supply, provides the necessary to create or discharge the ions in the electrolyte. Electric current is carried by electrons in the external circuit, two electrodes, electrical conductors that provide the physical interface between the electrolyte and the electrical circuit that provides the energy. Electrodes of metal, graphite and semiconductor material are widely used, choice of suitable electrode depends on chemical reactivity between the electrode and electrolyte and manufacturing cost. The key process of electrolysis is the interchange of atoms and ions by the removal or addition of electrons from the external circuit, the desired products of electrolysis are often in a different physical state from the electrolyte and can be removed by some physical processes. For example, in the electrolysis of brine to produce hydrogen and chlorine and these gaseous products bubble from the electrolyte and are collected. Each electrode attracts ions that are of the opposite charge, positively charged ions move towards the electron-providing cathode. Negatively charged ions move towards the electron-extracting anode, in this process electrons are either absorbed or released. Neutral atoms gain or lose electrons and become charged ions that pass into the electrolyte. The formation of uncharged atoms from ions is called discharging, when an ion gains or loses enough electrons to become uncharged atoms, the newly formed atoms separate from the electrolyte. Positive metal ions like Cu++ deposit onto the cathode in a layer, the terms for this are electroplating, electrowinning, and electrorefining
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Spiegeleisen
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Spiegeleisen is a ferromanganese alloy containing approximately 15% manganese and small quantities of carbon and silicon. Spiegeleisen is sometimes referred to as specular pig iron, Spiegel iron, just Spiegel. Historically, this was the form in which manganese was traded and used in steel making. Manganese is useful in steel manufacture because it binds with phosphorus, sulfur and it was much used in conjunction with the Bessemer process both to introduce carbon and manganese, and also to reduce impurities
36.
Ferromanganese
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The oxides undergo carbothermal reduction in the furnaces, producing the ferromanganese. Ferromanganese is used as a deoxidizer for steel, henry Bessemer invented the use of ferromanganese as a method of introducing manganese in controlled proportions during the production of steel. The advantage of combining powdered iron oxide and manganese oxide together is the melting point of the combined alloy compared to pure manganese oxide. A North American standard specification is ASTM A99, in 1872 Lambert von Pantz produced ferromanganese in a blast furnace, with significantly higher manganese content than was previously possible. This won his company international recognition, including a medal at the 1873 World Exposition in Vienna. Jorgenson, John D. Corathers, Lisa A. Gambogi, Joseph, Kuck, Peter H. Magyar, Michael J. Papp, John F. Shedd, Kim B
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Bronze
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These additions produce a range of alloys that may be harder than copper alone, or have other useful properties, such as stiffness, ductility, or machinability. The archeological period where bronze was the hardest metal in use is known as the Bronze Age. In the ancient Near East this began with the rise of Sumer in the 4th millennium BC, with India and China starting to use bronze around the same time, everywhere it gradually spread across regions. The Bronze Age was followed by the Iron Age starting from about 1300 BC and reaching most of Eurasia by about 500 BC, the discovery of bronze enabled people to create metal objects which were harder and more durable than previously possible. Bronze tools, weapons, armor, and building such as decorative tiles were harder and more durable than their stone. It was only later that tin was used, becoming the major ingredient of bronze in the late 3rd millennium BC. Tin bronze was superior to arsenic bronze in that the process could be more easily controlled. Also, unlike arsenic, metallic tin and fumes from tin refining are not toxic, the earliest tin-alloy bronze dates to 4500 BCE in a Vinča culture site in Pločnik. Other early examples date to the late 4th millennium BC in Africa, Susa and some ancient sites in China, Luristan, ores of copper and the far rarer tin are not often found together, so serious bronze work has always involved trade. Tin sources and trade in ancient times had a influence on the development of cultures. In Europe, a source of tin was the British deposits of ore in Cornwall. In many parts of the world, large hoards of bronze artefacts are found, suggesting that bronze also represented a store of value, in Europe, large hoards of bronze tools, typically socketed axes, are found, which mostly show no signs of wear. With Chinese ritual bronzes, which are documented in the inscriptions they carry and from other sources and these were made in enormous quantities for elite burials, and also used by the living for ritual offerings. Pure iron is soft, and the process of beating and folding sponge iron to wrought iron removes from the metal carbon. Careful control of the alloying and tempering eventually allowed for wrought iron with properties comparable to modern steel, Bronze was still used during the Iron Age, and has continued in use for many purposes to the modern day. Among other advantages, it does not rust, the weaker wrought iron was found to be sufficiently strong for many uses. Archaeologists suspect that a disruption of the tin trade precipitated the transition. The population migrations around 1200–1100 BC reduced the shipping of tin around the Mediterranean, limiting supplies, there are many different bronze alloys, but typically modern bronze is 88% copper and 12% tin
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Chlorine
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Chlorine is a chemical element with symbol Cl and atomic number 17. The second-lightest of the halogens, it appears between fluorine and bromine in the table and its properties are mostly intermediate between them. Chlorine is a gas at room temperature. It is an extremely reactive element and a strong oxidising agent, among the elements, it has the highest electron affinity, the most common compound of chlorine, sodium chloride, has been known since ancient times. Around 1630, chlorine gas was first synthesised in a chemical reaction, Carl Wilhelm Scheele wrote a description of chlorine gas in 1774, supposing it to be an oxide of a new element. In 1809, chemists suggested that the gas might be an element, and this was confirmed by Sir Humphry Davy in 1810. Because of its reactivity, all chlorine in the Earths crust is in the form of ionic chloride compounds. It is the second-most abundant halogen and twenty-first most abundant chemical element in Earths crust and these crustal deposits are nevertheless dwarfed by the huge reserves of chloride in seawater. Elemental chlorine is produced from brine by electrolysis. The high oxidising potential of chlorine led to the development of commercial bleaches and disinfectants. As a common disinfectant, elemental chlorine and chlorine-generating compounds are used directly in swimming pools to keep them clean. Elemental chlorine at high concentrations is extremely dangerous and poisonous for all living organisms, in the form of chloride ions, chlorine is necessary to all known species of life. Other types of compounds are rare in living organisms. In the upper atmosphere, chlorine-containing organic molecules such as chlorofluorocarbons have been implicated in ozone depletion, small quantities of elemental chlorine are generated by oxidation of chloride to hypochlorite in neutrophils as part of the immune response against bacteria. Its importance in food was very well known in antiquity and was sometimes used as payment for services for Roman generals. Around 1630, chlorine was recognized as a gas by the Flemish chemist, the element was first studied in detail in 1774 by Swedish chemist Carl Wilhelm Scheele, and he is credited with the discovery. He called it dephlogisticated muriatic acid air since it is a gas and he failed to establish chlorine as an element, mistakenly thinking that it was the oxide obtained from the hydrochloric acid. He named the new element within this oxide as muriaticum, in 1809, Joseph Louis Gay-Lussac and Louis-Jacques Thénard tried to decompose dephlogisticated muriatic acid air by reacting it with charcoal to release the free element muriaticum
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Carl Wilhelm Scheele
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Carl Wilhelm Scheele was a Swedish Pomeranian and pharmaceutical chemist. Isaac Asimov called him hard-luck Scheele because he made a number of discoveries before others who are generally given the credit. For example, Scheele discovered oxygen, and identified molybdenum, tungsten, barium, hydrogen, Scheele discovered organic acids tartaric, oxalic, uric, lactic, and citric, as well as hydrofluoric, hydrocyanic, and arsenic acids. He preferred speaking German to Swedish his whole life, as German was commonly spoken among Swedish pharmacists, Scheele was born in Stralsund, in western Pomerania, which at the time was a Swedish Dominion inside the Holy Roman Empire. Scheeles father Joachim Christian Scheele, was a dealer and brewer from a respected German family. His mother was Margaretha Eleanore Warnekros, friends of Scheeles parents taught him the art of reading prescriptions and the meaning of chemical and pharmaceutical signs. Then, in 1757, at age fourteen Carl was sent to Gothenburg as an apprentice pharmacist with another family friend, Scheele retained this position for eight years. During this time he ran experiments late into the night and read the works of Nicolas Lemery, Caspar Neumann, Johann von Löwenstern-Kunckel, much of Scheeles later theoretical speculations were based upon Stahl. Scheele arrived in Stockholm between 1767 and 1769 and worked as a pharmacist, during this period he discovered tartaric acid and with his friend, Retzius, studied the relation of quicklime to calcium carbonate. While in the capital, he became acquainted with many luminaries, such as, Abraham Bäck, Peter Jonas Bergius, Bengt Bergius. In the fall of 1770 Scheele became director of the laboratory of the pharmacy of Locke. The laboratory supplied chemicals to Professor of Chemistry Torbern Bergman, a friendship developed between Scheele and Bergman after Scheele analyzed a reaction which Bergman and his assistant Johan Gottlieb Gahn could not resolve. The reaction was between melted saltpetre and acetic acid produced a red vapor. Further study of this later led to Scheeles discovery of oxygen. Based upon this friendship and respect Scheele was given use of Bergmans laboratory. Both men were profiting from their working relationship, in 1774 Scheele was nominated by Peter Jonas Bergius to be a member of the Royal Swedish Academy of Sciences and was elected February 4,1775. In 1775 Scheele also managed for a time a pharmacy in Köping. Between the end of 1776 and the beginning of 1777 Scheele established his own business there, after his return to Köping he devoted himself, outside of his business, to scientific researches which resulted in a long series of important papers
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Hydrochloric acid
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Hydrochloric acid is a corrosive, strong mineral acid with many industrial uses. A colorless, highly pungent solution of chloride in water. Free hydrochloric acid was first formally described in the 16th century by Libavius, later, it was used by chemists such as Glauber, Priestley, and Davy in their scientific research. It has numerous applications, including household cleaning, production of gelatin and other food additives, descaling. About 20 million tonnes of acid are produced worldwide annually. It is also found naturally in gastric acid, Hydrochloric acid was known to European alchemists as spirits of salt or acidum salis. Both names are used, especially in other languages, such as German, Salzsäure, Dutch, Zoutzuur, Swedish, Saltsyra, Turkish, Tuz Ruhu, Polish, kwas solny and Chinese. Gaseous HCl was called marine acid air, the old name muriatic acid has the same origin, and this name is still sometimes used. The name hydrochloric acid was coined by the French chemist Joseph Louis Gay-Lussac in 1814, aqua regia, a mixture consisting of hydrochloric and nitric acids, prepared by dissolving sal ammoniac in nitric acid, was described in the works of Pseudo-Geber, a 13th-century European alchemist. Other references suggest that the first mention of aqua regia is in Byzantine manuscripts dating to the end of the 13th century, free hydrochloric acid was first formally described in the 16th century by Libavius, who prepared it by heating salt in clay crucibles. Joseph Priestley of Leeds, England prepared pure hydrogen chloride in 1772, during the Industrial Revolution in Europe, demand for alkaline substances increased. A new industrial process developed by Nicolas Leblanc of Issoundun, France enabled cheap large-scale production of sodium carbonate, in this Leblanc process, common salt is converted to soda ash, using sulfuric acid, limestone, and coal, releasing hydrogen chloride as a by-product. Until the British Alkali Act 1863 and similar legislation in other countries, after the passage of the act, soda ash producers were obliged to absorb the waste gas in water, producing hydrochloric acid on an industrial scale. In the 20th century, the Leblanc process was replaced by the Solvay process without a hydrochloric acid by-product. Since hydrochloric acid was already settled as an important chemical in numerous applications. After the year 2000, hydrochloric acid is made by absorbing by-product hydrogen chloride from industrial organic compounds production. Hydrochloric acid is the salt of hydronium ion, H3O+ and chloride and it is usually prepared by treating HCl with water. H C l + H2 O ⟶ H3 O + + C l − Hydrochloric acid can therefore be used to prepare salts called chlorides, Hydrochloric acid is a strong acid, since it is completely dissociated in water
41.
Permanganate
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A permanganate is the general name for a chemical compound containing the manganate ion. Because manganese is in the +7 oxidation state, the ion is a strong oxidizing agent. Permanganate solutions are purple in color and are stable in neutral or slightly alkaline media, the exact chemical reaction is dependent upon the organic contaminants present and the oxidant utilized. For example, trichloroethene is oxidized by sodium permanganate to form carbon dioxide, manganese dioxide, sodium ions, hydronium ions, in an acidic solution, permanganate is reduced to the colourless +2 oxidation state of the manganese ion. 8 H+ + MnO−4 +5 e− → Mn2+ +4 H2O In a strongly basic solution, permanganate is reduced to the green +6 oxidation state of the manganate ion, MnO2−4. MnO−4 + e− → MnO2−4 In a neutral medium, however, permanganates are salts of permanganic acid. They have a purple colour, due to a charge transfer transition. Permanganate is an oxidizer, and similar to perchlorate. It is therefore in common use in analysis that involves redox reactions. According to theory, permanganate is strong enough to oxidize water and it is a useful reagent, though with organic compounds, not very selective. Manganates are not very stable thermally
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Iron
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Iron is a chemical element with symbol Fe and atomic number 26. It is a metal in the first transition series and it is by mass the most common element on Earth, forming much of Earths outer and inner core. It is the fourth most common element in the Earths crust, like the other group 8 elements, ruthenium and osmium, iron exists in a wide range of oxidation states, −2 to +6, although +2 and +3 are the most common. Elemental iron occurs in meteoroids and other low oxygen environments, but is reactive to oxygen, fresh iron surfaces appear lustrous silvery-gray, but oxidize in normal air to give hydrated iron oxides, commonly known as rust. Unlike the metals that form passivating oxide layers, iron oxides occupy more volume than the metal and thus flake off, Iron metal has been used since ancient times, although copper alloys, which have lower melting temperatures, were used even earlier in human history. Pure iron is soft, but is unobtainable by smelting because it is significantly hardened and strengthened by impurities, in particular carbon. A certain proportion of carbon steel, which may be up to 1000 times harder than pure iron. Crude iron metal is produced in blast furnaces, where ore is reduced by coke to pig iron, further refinement with oxygen reduces the carbon content to the correct proportion to make steel. Steels and iron alloys formed with metals are by far the most common industrial metals because they have a great range of desirable properties. Iron chemical compounds have many uses, Iron oxide mixed with aluminium powder can be ignited to create a thermite reaction, used in welding and purifying ores. Iron forms binary compounds with the halogens and the chalcogens, among its organometallic compounds is ferrocene, the first sandwich compound discovered. Iron plays an important role in biology, forming complexes with oxygen in hemoglobin and myoglobin. Iron is also the metal at the site of many important redox enzymes dealing with cellular respiration and oxidation and reduction in plants. A human male of average height has about 4 grams of iron in his body and this iron is distributed throughout the body in hemoglobin, tissues, muscles, bone marrow, blood proteins, enzymes, ferritin, hemosiderin, and transport in plasma. The mechanical properties of iron and its alloys can be evaluated using a variety of tests, including the Brinell test, Rockwell test, the data on iron is so consistent that it is often used to calibrate measurements or to compare tests. An increase in the content will cause a significant increase in the hardness. Maximum hardness of 65 Rc is achieved with a 0. 6% carbon content, because of the softness of iron, it is much easier to work with than its heavier congeners ruthenium and osmium. Because of its significance for planetary cores, the properties of iron at high pressures and temperatures have also been studied extensively
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Amber (color)
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The color amber is a pure chroma color, located on the color wheel midway between the colors of gold and orange. In English the first recorded use of the term as a color name, Amber is one of several technically defined colors used in automotive signal lamps. In North America, SAE standard J578 governs the colorimetry of vehicle lights, both standards designate a range of orange-yellow hues in the CIE color space as amber. In the past, the ECE amber definition was more restrictive than the SAE definition, the SAE formally uses the term yellow amber, though the color is most often referred to as yellow. This is not the same as selective yellow, a used in some fog lamps and headlamps. The color box shown above is an approximation, created by taking the centroid of the standard definition and moving it towards the D65 white point. Computers VT220 computer terminals were available with amber phosphors on their CRTs, interior design The original Amber Room in the Catherine Palace of Tsarskoye Selo near Saint Petersburg was a complete chamber decoration of amber panels backed with gold leaf and mirrors. Due to its beauty, it was sometimes dubbed the Eighth Wonder of the World. Sports In Gaelic games Armagh play in a darker Amber color, Offaly play in the colors of the Irish flag and Kilkenny also play in black and amber. Amber is a worn by English Football Clubs Hull City AFC, Bradford City AFC, Barnet FC, Shrewsbury Town FC, Mansfield Town, Cambridge United FC. The color is worn by the Scottish football club Motherwell FC. Traffic engineering Amber is used in traffic lights and turn signals, business management Amber is used in business management to indicate a status of work, as in RAG status. R stands for Red, A stands for Amber, usually represented as the color Yellow in the reports, spectral color List of colors UNECE Regulation No. 6, Uniform Provisions Concerning the Approval of Direction Indicators for Motor Vehicles,48, Uniform Provisions Concerning the Approval of Vehicles with Regard to the Installation of Lighting and Light-Signalling Devices
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Dendrite (crystal)
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A crystal dendrite is a crystal that develops with a typical multi-branching tree-like form. Dendritic crystal growth is common and illustrated by snowflake formation. Dendritic crystallization forms a natural fractal pattern, Dendritic crystals can grow into a supercooled pure liquid or form from growth instabilities that occur when the growth rate is limited by the rate of diffusion of solute atoms to the interface. In the latter case, there must be a concentration gradient from the value in the solution to the concentration in equilibrium with the crystal at the surface. Any protuberance that develops is accompanied by a concentration gradients at its tip. This increases the rate to the tip. In opposition to this is the action of the surface tension tending to flatten the protuberance, however, overall, the protuberance becomes amplified. This process occurs again and again until a dendrite is produced, the term dendrite comes from the Greek word dendron, which means tree. In paleontology, dendritic mineral crystal forms are often mistaken for fossils and these pseudofossils form as naturally occurring fissures in the rock are filled by percolating mineral solutions. They form when water rich in manganese and iron flows along fractures, a variety of manganese oxides and hydroxides are involved, including, birnessite coronadite cryptomelane hollandite romanechite todorokite and others. A three-dimensional form of dendrite develops in fissures in quartz, forming moss agate, in chemistry, a dendrite is a crystal that branches into two parts during growth. Dendritic solidification is one of the most common forms of solidifying metals, when materials crystallize or solidify under certain conditions, they freeze unstably, resulting in dendritic forms. Scientists are particularly interested in dendrite size, shape, and how the branches of the dendrites interact with each other and these characteristics largely determine the properties of the material. Monocrystalline whisker Whisker Brownian tree Patterns in nature STS-87 - Space Shuttle mission Mindat Manganese Dendrites What is a dendrite, the Isothermal Dendritic Growth Experiment Snow crystals Dendritic Solidification Dendritic growth in Local-Nonequilibrium Solidification Model
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Birnessite
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Birnessite 2O4 ·1.5 H2O is an oxide mineral of manganese along with calcium, potassium and sodium. It has a brown to black color with a submetallic luster. It is also soft, with a Mohs hardness of 1.5. Birnessite is formed by precipitation in lakes, oceans and groundwater and is a component of desert varnish. It was first described in 1956 and named for an occurrence in Birness, Aberdeenshire, Birnessite is found as an oxidation product of several other minerals, including rhodonite, rhodochrosite, and as a weathering product of franklinite-wilminite ore. It has also found as a coating along joint planes and fractures within a trachyte sill. However, it has been most commonly seen as a constituent of oceanic nodules of manganese, a recent study found that the mineral is able to break down prions via oxidation. How well this process works outside the laboratory is unclear, Birnessite is a phyllomanganate, which is a type of ferroalloy that contains a high proportion of manganese. While natural forms generally contain foreign ions they are considered non-essential, however, most of the synthetic versions of the mineral undergo significant water loss at temperatures below 100 °C. Its structure is thought to be similar to that of chalcophanite, the structure itself consists of sheets of water molecules found between sheets of edge-sharing molecules of MnO6 octahedra, and repeated on an average of every 7.2 Å, doing so along the c-axis. Of the six sites in the MnO6 octahedral layer, one is left unoccupied, Mn2+. These Mn ions are low-valence, and associate with O, in both the octahedral and in the water sheets, research results published in 2015 show that 2. 50eV band gap of Birnessite could be used to harvest sunlight to split water into hydrogen and oxygen. Other manganese oxides, Pyrolusite Psilomelane Mineral Data Publishing - PDF
46.
Psilomelane
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Psilomelane is a group name for hard black manganese oxides including hollandite and romanechite. Psilomelane consists of manganese oxide with variable amounts of barium and potassium. Psilomelane is erroneously, and uncommonly, known as hematite, despite not being related to true hematite. Generalized formula may be represented as Ba8O164 or as 2Mn5O10 and it is sometimes considered to be a hydrous manganese manganate, but of doubtful composition. The amount of manganese present corresponds to 70-80% of manganous oxide with 10-15% of available oxygen, Psilomelane is amorphous and occurs as botryoidal and stalactitic masses with a smooth shining surface and submetallic lustre. The mineral is readily distinguished from other hydrous manganese oxides by its greater hardness 5 to 6, the streak is brownish black and the fracture smooth. Owing to its amorphous nature, the mineral often contains admixed impurities and it is soluble in hydrochloric acid with evolution of chlorine gas. The name has reference to this appearance, from the Greek for and. It is a common and important ore of manganese, occurring under the same conditions, with pyrolusite it is extensively mined in Vermont, Virginia, Arkansas, and Nova Scotia. Other manganese oxides, Birnessite Pyrolusite This article incorporates text from a now in the public domain, Chisholm, Hugh. Mindat with locality data Webmineral Mineral galleries
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Public domain
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The term public domain has two senses of meaning. Anything published is out in the domain in the sense that it is available to the public. Once published, news and information in books is in the public domain, in the sense of intellectual property, works in the public domain are those whose exclusive intellectual property rights have expired, have been forfeited, or are inapplicable. Examples for works not covered by copyright which are therefore in the domain, are the formulae of Newtonian physics, cooking recipes. Examples for works actively dedicated into public domain by their authors are reference implementations of algorithms, NIHs ImageJ. The term is not normally applied to situations where the creator of a work retains residual rights, as rights are country-based and vary, a work may be subject to rights in one country and be in the public domain in another. Some rights depend on registrations on a basis, and the absence of registration in a particular country, if required. Although the term public domain did not come into use until the mid-18th century, the Romans had a large proprietary rights system where they defined many things that cannot be privately owned as res nullius, res communes, res publicae and res universitatis. The term res nullius was defined as not yet appropriated. The term res communes was defined as things that could be enjoyed by mankind, such as air, sunlight. The term res publicae referred to things that were shared by all citizens, when the first early copyright law was first established in Britain with the Statute of Anne in 1710, public domain did not appear. However, similar concepts were developed by British and French jurists in the eighteenth century, instead of public domain they used terms such as publici juris or propriété publique to describe works that were not covered by copyright law. The phrase fall in the domain can be traced to mid-nineteenth century France to describe the end of copyright term. In this historical context Paul Torremans describes copyright as a coral reef of private right jutting up from the ocean of the public domain. Because copyright law is different from country to country, Pamela Samuelson has described the public domain as being different sizes at different times in different countries. According to James Boyle this definition underlines common usage of the public domain and equates the public domain to public property. However, the usage of the public domain can be more granular. Such a definition regards work in copyright as private property subject to fair use rights, the materials that compose our cultural heritage must be free for all living to use no less than matter necessary for biological survival
This article incorporates text from a publication now in the public domain: Chisholm, Hugh, ed. (1911). "Pyrolusite". Encyclopædia Britannica. 22 (11th ed.). Cambridge University Press. p. 693.