1.
Colloid
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A colloid, in chemistry, is a mixture in which one substance of microscopically dispersed insoluble particles is suspended throughout another substance. Sometimes the dispersed substance alone is called the colloid, the colloidal suspension refers unambiguously to the overall mixture. Unlike a solution, whose solute and solvent constitute only one phase, a colloid has a dispersed phase, to qualify as a colloid, the mixture must be one that does not settle or would take a very long time to settle appreciably. The dispersed-phase particles have a diameter between approximately 1 and 1000 nanometers, such particles are normally easily visible in an optical microscope, although at the smaller size range, an ultramicroscope or an electron microscope may be required. Homogeneous mixtures with a phase in this size range may be called colloidal aerosols, colloidal emulsions, colloidal foams, colloidal dispersions. The dispersed-phase particles or droplets are affected largely by the surface chemistry present in the colloid, some colloids are translucent because of the Tyndall effect, which is the scattering of light by particles in the colloid. Other colloids may be opaque or have a slight color, Colloidal suspensions are the subject of interface and colloid science. This field of study was introduced in 1861 by Scottish scientist Thomas Graham, because of the size exclusion, the colloidal particles are unable to pass through the pores of an ultrafiltration membrane with a size smaller than their own dimension. The smaller the size of the pore of the ultrafiltration membrane, the measured value of the concentration of a truly dissolved species will thus depend on the experimental conditions applied to separate it from the colloidal particles also dispersed in the liquid. This is particularly important for solubility studies of readily hydrolyzed species such as Al, Eu, Am, Cm, the colloid particles are attracted toward water. They are also called reversible sols, hydrophobic colloids, These are opposite in nature to hydrophilic colloids. The colloid particles are repelled by water and they are also called irreversible sols. In some cases, a colloid suspension can be considered a homogeneous mixture and this is because the distinction between dissolved and particulate matter can be sometimes a matter of approach, which affects whether or not it is homogeneous or heterogeneous. The following forces play an important role in the interaction of particles, Excluded volume repulsion. Electrostatic interaction, Colloidal particles often carry a charge and therefore attract or repel each other. The charge of both the continuous and the phase, as well as the mobility of the phases are factors affecting this interaction. Van der Waals forces, This is due to interaction between two dipoles that are permanent or induced. Even if the particles do not have a permanent dipole, fluctuations of the electron density gives rise to a dipole in a particle
2.
Gel
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A gel is a solid jelly-like material that can have properties ranging from soft and weak to hard and tough. Gels are defined as a substantially dilute cross-linked system, which exhibits no flow when in the steady-state, by weight, gels are mostly liquid, yet they behave like solids due to a three-dimensional cross-linked network within the liquid. It is the crosslinking within the fluid that gives a gel its structure, in this way gels are a dispersion of molecules of a liquid within a solid in which the solid is the continuous phase and the liquid is the discontinuous phase. The word gel was coined by 19th-century Scottish chemist Thomas Graham by clipping from gelatine, gels consist of a solid three-dimensional network that spans the volume of a liquid medium and ensnares it through surface tension effects. This internal network structure may result from physical bonds or chemical bonds, virtually any fluid can be used as an extender including water, oil, and air. Both by weight and volume, gels are mostly fluid in composition, edible jelly is a common example of a hydrogel and has approximately the density of water. Polyionic polymers are polymers with a functional group. The ionic charges prevent the formation of tightly coiled polymer chains and this allows them to contribute more to viscosity in their stretched state, because the stretched-out polymer takes up more space. A hydrogel is a network of polymer chains that are hydrophilic, hydrogels are highly absorbent natural or synthetic polymeric networks. Hydrogels also possess a degree of flexibility very similar to tissue, due to their significant water content. The first appearance of the term hydrogel in the literature was in 1894, common uses for hydrogels include, Scaffolds in tissue engineering. When used as scaffolds, hydrogels may contain human cells to repair tissue and they mimic 3D microenvironment of cells. Hydrogel-coated wells have been used for cell culture Environmentally sensitive hydrogels and these hydrogels have the ability to sense changes of pH, temperature, or the concentration of metabolite and release their load as result of such a change. Wound gels are excellent for helping to create or maintain a moist environment, reservoirs in topical drug delivery, particularly ionic drugs, delivered by iontophoresis. Natural hydrogel materials are being investigated for tissue engineering, these materials include agarose, methylcellulose, hyaluronan, an organogel is a non-crystalline, non-glassy thermoreversible solid material composed of a liquid organic phase entrapped in a three-dimensionally cross-linked network. The liquid can be, for example, a solvent, mineral oil. The solubility and particle dimensions of the structurant are important characteristics for the elastic properties, often, these systems are based on self-assembly of the structurant molecules. Organogels have potential for use in a number of applications, such as in pharmaceuticals, cosmetics, art conservation, a xerogel /ˈzɪəroʊˌdʒɛl/ is a solid formed from a gel by drying with unhindered shrinkage
3.
Granular material
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A granular material is a conglomeration of discrete solid, macroscopic particles characterized by a loss of energy whenever the particles interact. The constituents that compose granular material must be large enough such that they are not subject to thermal motion fluctuations, thus, the lower size limit for grains in granular material is about 1 µm. Some examples of materials are snow, nuts, coal, sand, rice, coffee, corn flakes, fertilizer. Powders are a class of granular material due to their small particle size. Granular materials are important in applications as diverse as pharmaceutical industry, agriculture. Research into granular materials is thus directly applicable and goes back at least to Charles-Augustin de Coulomb, according to material scientist Patrick Richard, Granular materials are ubiquitous in nature and are the second-most manipulated material in industry. In some sense, granular materials do not constitute a phase of matter but have characteristics reminiscent of solids, liquids. However, in each of these states granular materials also exhibit properties which are unique, Granular materials also exhibit a wide range of pattern forming behaviors when excited. As such granular materials under excitation can be thought of as an example of a complex system, when the average energy of the individual grains is low and the grains are fairly stationary relative to each other, the granular material acts like a solid. In general, stress in a solid is not distributed uniformly but is conducted away along so-called force chains which are networks of grains resting on one another. Between these chains are regions of low stress whose grains are shielded for the effects of the grains above by vaulting and arching, if the granular material is driven harder such that contacts between the grains become highly infrequent, the material enters a gaseous state. Correspondingly, one can define a granular temperature equal to the mean square of grain velocity fluctuations that is analogous to thermodynamic temperature. Unlike conventional gases, granular materials will tend to cluster and clump due to the nature of the collisions between grains and this clustering has some interesting consequences. This effect, known as the granular Maxwells demon, does not violate any thermodynamics principles since energy is constantly being lost from the system in the process. Granular systems are known to exhibit jamming and undergo a transition which is thought of as a thermodynamic phase transition to a jammed state. The Lubachevsky-Stillinger algorithm of jamming allows one to produce simulated jammed granular configurations, excited granular matter is a rich pattern-forming system. Some of the pattern-forming behaviours seen in granular materials are, The un-mixing or segregation of unlike grains under vibration, Some larger materials get stuck while going down the circle and therefore stay on the top. The formation of surface patterns in vibrated granular layers and these patterns include but are not limited to stripes, squares and hexagons
4.
Sand
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Sand is a naturally occurring granular material composed of finely divided rock and mineral particles. It is defined by size, being finer than gravel and coarser than silt, Sand can also refer to a textural class of soil or soil type, i. e. a soil containing more than 85% sand-sized particles by mass. The second most common type of sand is calcium carbonate, for example aragonite, for example, it is the primary form of sand apparent in areas where reefs have dominated the ecosystem for millions of years like the Caribbean. Sand is a non renewable resource over human timescales, and sand suitable for making concrete is in high demand, in terms of particle size as used by geologists, sand particles range in diameter from 0.0625 mm to 2 mm. An individual particle in this size is termed a sand grain. Sand grains are between gravel and silt, a 1953 engineering standard published by the American Association of State Highway and Transportation Officials set the minimum sand size at 0.074 mm. A1938 specification of the United States Department of Agriculture was 0.05 mm. Sand feels gritty when rubbed between the fingers. ISO14688 grades sands as fine, medium and coarse with ranges 0.063 mm to 0.2 mm to 0.63 mm to 2.0 mm. In the United States, sand is commonly divided into five sub-categories based on size, very fine sand, fine sand, medium sand, coarse sand, and very coarse sand. These sizes are based on the Krumbein phi scale, where size in Φ = -log2D, on this scale, for sand the value of Φ varies from −1 to +4, with the divisions between sub-categories at whole numbers. The composition of sand is highly variable, depending on the local rock sources. The gypsum sand dunes of the White Sands National Monument in New Mexico are famous for their bright, arkose is a sand or sandstone with considerable feldspar content, derived from weathering and erosion of a granitic rock outcrop. Some sands contain magnetite, chlorite, glauconite or gypsum, Sands rich in magnetite are dark to black in color, as are sands derived from volcanic basalts and obsidian. Chlorite-glauconite bearing sands are typically green in color, as are sands derived from basaltic with a high olivine content, many sands, especially those found extensively in Southern Europe, have iron impurities within the quartz crystals of the sand, giving a deep yellow color. Sand deposits in some areas contain garnets and other resistant minerals, the study of individual grains can reveal much historical information as to the origin and kind of transport of the grain. Quartz sand that is weathered from granite or gneiss quartz crystals will be angular. It is called grus in geology or sharp sand in the trade where it is preferred for concrete. Sand that is transported long distances by water or wind will be rounded, people who collect sand as a hobby are known as arenophiles
5.
Silt
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Silt is granular material of a size between sand and clay, whose mineral origin is quartz and feldspar. Silt may occur as a soil or as sediment mixed in suspension with water in a body of such as a river. It may also exist as soil deposited at the bottom of a water body, Silt has a moderate specific area with a typically non-sticky, plastic feel. Silt usually has a floury feel when dry, and a slippery feel when wet, Silt can be visually observed with a hand lens. Silt is created by a variety of physical processes capable of splitting the generally sand-sized quartz crystals of primary rocks by exploiting deficiencies in their lattice and these involve chemical weathering of rock and regolith, and a number of physical weathering processes such as frost shattering and haloclasty. The main process is abrasion through transport, including fluvial comminution, aeolian attrition and it is in semi-arid environments that substantial quantities of silt are produced. Silt is sometimes known as rock flour or stone dust, especially produced by glacial action. Mineralogically, silt is composed mainly of quartz and feldspar, sedimentary rock composed mainly of silt is known as siltstone. Liquefaction created by an earthquake is silt suspended in water that is hydrodynamically forced up from below ground level. In the Udden–Wentworth scale, silt particles range between 0.0039 and 0.0625 mm, larger than clay but smaller than sand particles, ISO14688 grades silts between 0.002 mm and 0.063 mm. In actuality, silt is chemically distinct from clay, and unlike clay, grains of silt are approximately the size in all dimensions, furthermore. Clays are formed from thin plate-shaped particles held together by electrostatic forces, according to the U. S. Department of Agriculture Soil Texture Classification system, the sand-silt distinction is made at the 0.05 mm particle size. The USDA system has been adopted by the Food and Agriculture Organization, in the Unified Soil Classification System and the AASHTO Soil Classification system, the sand-silt distinction is made at the 0.075 mm particle size. Silts and clays are distinguished mechanically by their plasticity, Silt is easily transported in water or other liquid and is fine enough to be carried long distances by air in the form of dust. Thick deposits of silty material resulting from deposition by aeolian processes are called loess. Silt and clay contribute to turbidity in water, Silt is transported by streams or by water currents in the ocean. When silt appears as a pollutant in water the phenomenon is known as siltation, Silt, deposited by annual floods along the Nile River, created the rich, fertile soil that sustained the Ancient Egyptian civilization. In south east Bangladesh, in the Noakhali district, cross dams were built in the 1960s whereby silt gradually started forming new land called chars, the district of Noakhali has gained more than 28 square miles of land in the past 50 years
6.
Clay
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Clay is a fine-grained natural rock or soil material that combines one or more clay minerals with traces of metal oxides and organic matter. Geologic clay deposits are composed of phyllosilicate minerals containing variable amounts of water trapped in the mineral structure. Clays are plastic due to water content and become hard, brittle. Depending on the content in which it is found, clay can appear in various colours from white to dull grey or brown to deep orange-red. Although many naturally occurring deposits include both silts and clay, clays are distinguished from other fine-grained soils by differences in size, silts, which are fine-grained soils that do not include clay minerals, tend to have larger particle sizes than clays. There is, however, some overlap in size and other physical properties. The distinction between silt and clay varies by discipline, geologists and soil scientists usually consider the separation to occur at a particle size of 2 µm, sedimentologists often use 4–5 μm, and colloid chemists use 1 μm. Geotechnical engineers distinguish between silts and clays based on the plasticity properties of the soil, as measured by the soils Atterberg limits, ISO14688 grades clay particles as being smaller than 2 μm and silt particles as being larger. These solvents, usually acidic, migrate through the rock after leaching through upper weathered layers. In addition to the process, some clay minerals are formed through hydrothermal activity. There are two types of deposits, primary and secondary. Primary clays form as residual deposits in soil and remain at the site of formation, secondary clays are clays that have been transported from their original location by water erosion and deposited in a new sedimentary deposit. Clay deposits are associated with very low energy depositional environments such as large lakes. Depending on the source, there are three or four main groups of clays, kaolinite, montmorillonite-smectite, illite, and chlorite. Chlorites are not always considered to be a clay, sometimes being classified as a group within the phyllosilicates. There are approximately 30 different types of clays in these categories. Varve is clay with visible annual layers, which are formed by deposition of those layers and are marked by differences in erosion. This type of deposit is common in glacial lakes
7.
Water
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Water is a transparent and nearly colorless chemical substance that is the main constituent of Earths streams, lakes, and oceans, and the fluids of most living organisms. Its chemical formula is H2O, meaning that its molecule contains one oxygen, Water strictly refers to the liquid state of that substance, that prevails at standard ambient temperature and pressure, but it often refers also to its solid state or its gaseous state. It also occurs in nature as snow, glaciers, ice packs and icebergs, clouds, fog, dew, aquifers, Water covers 71% of the Earths surface. It is vital for all forms of life. Only 2. 5% of this water is freshwater, and 98. 8% of that water is in ice and groundwater. Less than 0. 3% of all freshwater is in rivers, lakes, and the atmosphere, a greater quantity of water is found in the earths interior. Water on Earth moves continually through the cycle of evaporation and transpiration, condensation, precipitation. Evaporation and transpiration contribute to the precipitation over land, large amounts of water are also chemically combined or adsorbed in hydrated minerals. Safe drinking water is essential to humans and other even though it provides no calories or organic nutrients. There is a correlation between access to safe water and gross domestic product per capita. However, some observers have estimated that by 2025 more than half of the population will be facing water-based vulnerability. A report, issued in November 2009, suggests that by 2030, in developing regions of the world. Water plays an important role in the world economy, approximately 70% of the freshwater used by humans goes to agriculture. Fishing in salt and fresh water bodies is a source of food for many parts of the world. Much of long-distance trade of commodities and manufactured products is transported by boats through seas, rivers, lakes, large quantities of water, ice, and steam are used for cooling and heating, in industry and homes. Water is an excellent solvent for a variety of chemical substances, as such it is widely used in industrial processes. Water is also central to many sports and other forms of entertainment, such as swimming, pleasure boating, boat racing, surfing, sport fishing, Water is a liquid at the temperatures and pressures that are most adequate for life. Specifically, at atmospheric pressure of 1 bar, water is a liquid between the temperatures of 273.15 K and 373.15 K
8.
Artesian aquifer
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See Great Artesian Basin for the water source in Australia. An artesian aquifer is a confined aquifer containing groundwater under positive pressure and this causes the water level in a well to rise to a point where hydrostatic equilibrium has been reached. A well drilled into such an aquifer is called an artesian well, if water reaches the ground surface under the natural pressure of the aquifer, the well is called a flowing artesian well. An aquifer is a layer of porous and permeable material such as sand and gravel, limestone, or sandstone. An artesian aquifer is confined between impermeable rocks or clay which causes this positive pressure, not all the aquifers are artesian, because the water table must reach the surface. The recharging of aquifers happens when the table at its recharge zone is at a higher elevation than the head of the well. Fossil water aquifers can also be if they are under sufficient pressure from the surrounding rocks. This is similar to how many newly tapped oil wells are pressurized, Artesian wells were named after the former province of Artois in France, where many artesian wells were drilled by Carthusian monks from 1126. Fluid mechanics Great Artesian Basin Hydrogeology Qanat Video of an artesian aquifer releasing water under its own pressure
9.
Effective stress
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Effective stress is a force that keeps a collection of particles rigid. Usually this applies to sand, soil, or gravel, if you pinch a stack of coins between your fingers, the stack stays together. If you then loosen the pressure between your fingers, the coin stack falls apart, similarly, a pile of sand keeps from spreading out like a liquid because the weight of the sand keeps the grains stuck together in their current arrangement, mostly out of static friction. This weight and pressure is the effective stress, effective stress is easy to disrupt by the application of additional forces, every footstep on a sand pile demonstrates this. It is an important factor in the study of stability and soil liquefaction. Karl von Terzaghi first proposed the relationship for effective stress in 1925, for him, the term effective meant the calculated stress that was effective in moving soil, or causing displacements. It represents the average stress carried by the soil skeleton, with these models, it is important to know the total weight of the soil above, and the pore water pressure within the slip plane, assuming it is acting as a confined layer. Consider a grouping of round quartz sand grains, piled loosely, as can be seen, there is a contact stress where the spheres actually touch. Pile on more spheres and the contact stresses increase, to the point of causing frictional instability, the independent parameter affecting the contacts is the force of the spheres above. This can be calculated by using the average density of the spheres. If we then have these spheres in a beaker and add some water, with natural soil materials, the effect can be significant, as anyone who has lifted a large rock out of a lake can attest. The contact stress on the spheres decreases as the beaker is filled to the top of the spheres, although the water pressure between the spheres is increasing, the effective stress remains the same, because the concept of total stress includes the weight of all the water above. This is where the equation can become confusing, and the stress can be calculated using the buoyant density of the spheres. The concept of effective stress truly becomes interesting when dealing with non-hydrostatic pore water pressure, under the conditions of a pore pressure gradient, the ground water flows, according to the permeability equation. Using our spheres as a model, this is the same as injecting water between the spheres, if water is being injected, the seepage force acts to separate the spheres and reduces the effective stress. Thus, the mass becomes weaker. If water is being withdrawn, the spheres are forced together, as well, effective stress plays an important role in slope stability, and other geotechnical engineering and engineering geology problems, such as groundwater-related subsidence
