1.
South America
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South America is a continent located in the western hemisphere, mostly in the southern hemisphere, with a relatively small portion in the northern hemisphere. It may also be considered a subcontinent of the Americas, which is the used in nations that speak Romance languages. The reference to South America instead of other regions has increased in the last decades due to changing geopolitical dynamics. It is bordered on the west by the Pacific Ocean and on the north and east by the Atlantic Ocean, North America and it includes twelve sovereign states, a part of France, and a non-sovereign area. In addition to this, the ABC islands of the Kingdom of the Netherlands, Trinidad and Tobago, South America has an area of 17,840,000 square kilometers. Its population as of 2005 has been estimated at more than 371,090,000, South America ranks fourth in area and fifth in population. Brazil is by far the most populous South American country, with more than half of the population, followed by Colombia, Argentina, Venezuela. In recent decades Brazil has also concentrated half of the regions GDP and has become a first regional power, most of the population lives near the continents western or eastern coasts while the interior and the far south are sparsely populated. Most of the continent lies in the tropics, the continents cultural and ethnic outlook has its origin with the interaction of indigenous peoples with European conquerors and immigrants and, more locally, with African slaves. Given a long history of colonialism, the majority of South Americans speak Portuguese or Spanish. South America occupies the portion of the Americas. The continent is delimited on the northwest by the Darién watershed along the Colombia–Panama border. Almost all of mainland South America sits on the South American Plate, South Americas major mineral resources are gold, silver, copper, iron ore, tin, and petroleum. These resources found in South America have brought high income to its countries especially in times of war or of rapid growth by industrialized countries elsewhere. However, the concentration in producing one major export commodity often has hindered the development of diversified economies and this is leading to efforts to diversify production to drive away from staying as economies dedicated to one major export. South America is one of the most biodiverse continents on earth, South America is home to many interesting and unique species of animals including the llama, anaconda, piranha, jaguar, vicuña, and tapir. The Amazon rainforests possess high biodiversity, containing a proportion of the Earths species. Brazil is the largest country in South America, encompassing around half of the land area
2.
Argentina
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Argentina, officially the Argentine Republic, is a federal republic in the southern half of South America. With a mainland area of 2,780,400 km2, Argentina is the eighth-largest country in the world, the second largest in Latin America, and the largest Spanish-speaking one. The country is subdivided into provinces and one autonomous city, Buenos Aires. The provinces and the capital have their own constitutions, but exist under a federal system, Argentina claims sovereignty over part of Antarctica, the Falkland Islands, and South Georgia and the South Sandwich Islands. The earliest recorded presence in the area of modern-day Argentina dates back to the Paleolithic period. The country has its roots in Spanish colonization of the region during the 16th century, Argentina rose as the successor state of the Viceroyalty of the Río de la Plata, a Spanish overseas viceroyalty founded in 1776. The country thereafter enjoyed relative peace and stability, with waves of European immigration radically reshaping its cultural. The almost-unparalleled increase in prosperity led to Argentina becoming the seventh wealthiest developed nation in the world by the early 20th century, Argentina retains its historic status as a middle power in international affairs, and is a prominent regional power in the Southern Cone and Latin America. Argentina has the second largest economy in South America, the third-largest in Latin America and is a member of the G-15 and it is the country with the second highest Human Development Index in Latin America with a rating of very high. Because of its stability, market size and growing high-tech sector, the description of the country by the word Argentina has to be found on a Venice map in 1536. In English the name Argentina probably comes from the Spanish language, however the naming itself is not Spanish, Argentina means in Italian of silver, silver coloured, probably borrowed from the Old French adjective argentine of silver > silver coloured already mentioned in the 12th century. The French word argentine is the form of argentin and derives of argent silver with the suffix -in. The Italian naming Argentina for the country implies Argentina Terra land of silver or Argentina costa coast of silver, in Italian, the adjective or the proper noun is often used in an autonomous way as a substantive and replaces it and it is said lArgentina. The name Argentina was probably first given by the Venitian and Genoese navigators, in Spanish and Portuguese, the words for silver are respectively plata and prata and of silver is said plateado and prateado. Argentina was first associated with the silver mountains legend, widespread among the first European explorers of the La Plata Basin. The first written use of the name in Spanish can be traced to La Argentina, a 1602 poem by Martín del Barco Centenera describing the region, the 1826 constitution included the first use of the name Argentine Republic in legal documents. The name Argentine Confederation was also used and was formalized in the Argentine Constitution of 1853. In 1860 a presidential decree settled the name as Argentine Republic
3.
NASA
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President Dwight D. Eisenhower established NASA in 1958 with a distinctly civilian orientation encouraging peaceful applications in space science. The National Aeronautics and Space Act was passed on July 29,1958, disestablishing NASAs predecessor, the new agency became operational on October 1,1958. Since that time, most US space exploration efforts have led by NASA, including the Apollo Moon landing missions, the Skylab space station. Currently, NASA is supporting the International Space Station and is overseeing the development of the Orion Multi-Purpose Crew Vehicle, the agency is also responsible for the Launch Services Program which provides oversight of launch operations and countdown management for unmanned NASA launches. NASA shares data with various national and international such as from the Greenhouse Gases Observing Satellite. Since 2011, NASA has been criticized for low cost efficiency, from 1946, the National Advisory Committee for Aeronautics had been experimenting with rocket planes such as the supersonic Bell X-1. In the early 1950s, there was challenge to launch a satellite for the International Geophysical Year. An effort for this was the American Project Vanguard, after the Soviet launch of the worlds first artificial satellite on October 4,1957, the attention of the United States turned toward its own fledgling space efforts. This led to an agreement that a new federal agency based on NACA was needed to conduct all non-military activity in space. The Advanced Research Projects Agency was created in February 1958 to develop technology for military application. On July 29,1958, Eisenhower signed the National Aeronautics and Space Act, a NASA seal was approved by President Eisenhower in 1959. Elements of the Army Ballistic Missile Agency and the United States Naval Research Laboratory were incorporated into NASA, earlier research efforts within the US Air Force and many of ARPAs early space programs were also transferred to NASA. In December 1958, NASA gained control of the Jet Propulsion Laboratory, NASA has conducted many manned and unmanned spaceflight programs throughout its history. Some missions include both manned and unmanned aspects, such as the Galileo probe, which was deployed by astronauts in Earth orbit before being sent unmanned to Jupiter, the experimental rocket-powered aircraft programs started by NACA were extended by NASA as support for manned spaceflight. This was followed by a space capsule program, and in turn by a two-man capsule program. This goal was met in 1969 by the Apollo program, however, reduction of the perceived threat and changing political priorities almost immediately caused the termination of most of these plans. NASA turned its attention to an Apollo-derived temporary space laboratory, to date, NASA has launched a total of 166 manned space missions on rockets, and thirteen X-15 rocket flights above the USAF definition of spaceflight altitude,260,000 feet. The X-15 was an NACA experimental rocket-powered hypersonic research aircraft, developed in conjunction with the US Air Force, the design featured a slender fuselage with fairings along the side containing fuel and early computerized control systems
4.
Weathering
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Weathering is the breaking down of rocks, soil, and minerals as well as wood and artificial materials through contact with the Earths atmosphere, waters, and biological organisms. Two important classifications of weathering processes exist – physical and chemical weathering, mechanical or physical weathering involves the breakdown of rocks and soils through direct contact with atmospheric conditions, such as heat, water, ice and pressure. While physical weathering is accentuated in very cold or very dry environments, chemical reactions are most intense where the climate is wet, however, both types of weathering occur together, and each tends to accelerate the other. For example, physical abrasion decreases the size of particles and therefore increases their surface area, the various agents act in concert to convert primary minerals to secondary minerals and release plant nutrient elements in soluble forms. The materials left over after the rock breaks down combined with organic material creates soil, in addition, many of Earths landforms and landscapes are the result of weathering processes combined with erosion and re-deposition. Physical weathering, also recognized as mechanical weathering, is the class of processes that causes the disintegration of rocks without chemical change, the primary process in physical weathering is abrasion. However, chemical and physical weathering often go hand in hand, physical weathering can occur due to temperature, pressure, frost etc. For example, cracks exploited by physical weathering will increase the area exposed to chemical action. Abrasion by water, ice, and wind loaded with sediment can have tremendous cutting power, as is amply demonstrated by the gorges, ravines. In glacial areas, huge moving ice masses embedded with soil and rock fragments grind down rocks in their path, plant roots sometimes enter cracks in rocks and pry them apart, resulting in some disintegration, Burrowing animals may help disintegrate rock through their physical action. However, such influences are usually of importance in producing parent material when compared to the drastic physical effects of water, ice, wind. Physical weathering is called mechanical weathering or disaggregation. Thermal stress weathering results from the expansion and contraction of rock, for example, heating of rocks by sunlight or fires can cause expansion of their constituent minerals. As some minerals expand more than others, temperature changes set up differential stresses that cause the rock to crack apart. Because the outer surface of a rock is often warmer or colder than the more protected inner portions and this process may be sharply accelerated if ice forms in the surface cracks. When water freezes, it expands with a force of about 1465 Mg/m^2, disintegrating huge rock masses, thermal stress weathering comprises two main types, thermal shock and thermal fatigue. Thermal stress weathering is an important mechanism in deserts, where there is a diurnal temperature range, hot in the day. The repeated heating and cooling exerts stress on the layers of rocks
5.
Andes
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The Andes or Andean Mountains are the longest continental mountain range in the world. They are a range of highlands along the western edge of South America. This range is about 7,000 km long, about 200 to 700 km wide, the Andes extend from north to south through seven South American countries, Venezuela, Colombia, Ecuador, Peru, Bolivia, Argentina and Chile. Along their length, the Andes are split into several ranges, the Andes are the location of several high plateaus – some of which host major cities, such as Quito, Bogotá, Arequipa, Medellín, Sucre, Mérida and La Paz. The Altiplano plateau is the worlds second-highest after the Tibetan plateau and these ranges are in turn grouped into three major divisions based on climate, the Tropical Andes, the Dry Andes, and the Wet Andes. The Andes are the worlds highest mountain range outside of Asia, the highest mountain outside Asia, Mount Aconcagua, rises to an elevation of about 6,961 m above sea level. The peak of Chimborazo in the Ecuadorean Andes is farther from the Earths center than any other location on the Earths surface, the worlds highest volcanoes are in the Andes, including Ojos del Salado on the Chile-Argentina border, which rises to 6,893 m. The etymology of the word Andes has been debated, the majority consensus is that it derives from the Quechua word anti, which means east as in Antisuyu, one of the four regions of the Inca Empire. In the northern part of the Andes, the isolated Sierra Nevada de Santa Marta range is considered to be part of the Andes. The term cordillera comes from the Spanish word cordel, meaning rope, the Andes range is about 200 km wide throughout its length, except in the Bolivian flexure where it is about 640 kilometres wide. The Andes are the result of plate tectonics processes, caused by the subduction of oceanic crust beneath the South American plate. The main cause of the rise of the Andes is the compression of the rim of the South American Plate due to the subduction of the Nazca Plate. In the south, the Andes share a boundary with the former Patagonia Terrane. To the west, the Andes end at the Pacific Ocean, from a geographical approach, the Andes are considered to have their western boundaries marked by the appearance of coastal lowlands and a less rugged topography. The Andes Mountains also contain large quantities of iron ore located in mountains within the range. The Andean orogen has a series of bends or oroclines, the Bolivian Orocline is a seaward concave bending in the coast of South America and the Andes Mountains at about 18° S. At this point the orientation of the Andes turns from Northwest in Peru to South in Chile, the Andean segment north and south of the orocline have been rotated 15° to 20° counter clockwise and clockwise respectively. The Bolivian Orocline area overlaps with the area of maximum width of the Altiplano Plateau, the specific point at 18° S where the coastline bends is known as the Arica Elbow
6.
Chile
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Chile, officially the Republic of Chile, is a South American country occupying a long, narrow strip of land between the Andes to the east and the Pacific Ocean to the west. It borders Peru to the north, Bolivia to the northeast, Argentina to the east, Chilean territory includes the Pacific islands of Juan Fernández, Salas y Gómez, Desventuradas, and Easter Island in Oceania. Chile also claims about 1,250,000 square kilometres of Antarctica, the arid Atacama Desert in northern Chile contains great mineral wealth, principally copper. Southern Chile is rich in forests and grazing lands, and features a string of volcanoes and lakes, the southern coast is a labyrinth of fjords, inlets, canals, twisting peninsulas, and islands. Spain conquered and colonized Chile in the century, replacing Inca rule in northern and central Chile. After declaring its independence from Spain in 1818, Chile emerged in the 1830s as a relatively stable authoritarian republic, in the 1960s and 1970s the country experienced severe left-right political polarization and turmoil. The regime, headed by Augusto Pinochet, ended in 1990 after it lost a referendum in 1988 and was succeeded by a coalition which ruled through four presidencies until 2010. Chile is today one of South Americas most stable and prosperous nations and it leads Latin American nations in rankings of human development, competitiveness, income per capita, globalization, state of peace, economic freedom, and low perception of corruption. It also ranks high regionally in sustainability of the state, Chile is a founding member of the United Nations, the Union of South American Nations and the Community of Latin American and Caribbean States. There are various theories about the origin of the word Chile, another theory points to the similarity of the valley of the Aconcagua with that of the Casma Valley in Peru, where there was a town and valley named Chili. Another origin attributed to chilli is the onomatopoeic cheele-cheele—the Mapuche imitation of the warble of a locally known as trile. The Spanish conquistadors heard about this name from the Incas, ultimately, Almagro is credited with the universalization of the name Chile, after naming the Mapocho valley as such. The older spelling Chili was in use in English until at least 1900 before switching over to Chile, stone tool evidence indicates humans sporadically frequented the Monte Verde valley area as long as 18,500 years ago. About 10,000 years ago, migrating Native Americans settled in fertile valleys, settlement sites from very early human habitation include Monte Verde, Cueva del Milodon and the Pali Aike Craters lava tube. They fought against the Sapa Inca Tupac Yupanqui and his army, the result of the bloody three-day confrontation known as the Battle of the Maule was that the Inca conquest of the territories of Chile ended at the Maule river. The next Europeans to reach Chile were Diego de Almagro and his band of Spanish conquistadors, the Spanish encountered various cultures that supported themselves principally through slash-and-burn agriculture and hunting. The conquest of Chile began in earnest in 1540 and was carried out by Pedro de Valdivia, one of Francisco Pizarros lieutenants, who founded the city of Santiago on 12 February 1541. Although the Spanish did not find the gold and silver they sought, they recognized the agricultural potential of Chiles central valley
7.
Salta Province
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Salta is a province of Argentina, located in the northwest of the country. Neighboring provinces are from the east clockwise Formosa, Chaco, Santiago del Estero, Tucumán, to the north it borders Bolivia and Paraguay and to the west lies Chile. The Atacamas lived in the Puna, and the Wichís, in the Chaco region, the first conquistador to venture into the area was Diego de Almagro in 1535, he was followed by Diego de Rojas. Hernando de Lerma founded San Felipe de Lerma in 1582, following orders of the viceroy Francisco de Toledo, Count of Oropesa, by 1650, the city had around five hundred inhabitants. An intendency of Salta del Tucumán was created within the Viceroyalty of the Río de la Plata, in 1774, San Ramón de La Nueva Orán was founded between Salta and Tarija. In 1783, in recognition of the importance of the city. The battle of Salta in 1813 freed the territory from Spain, gervasio de Posadas created the Province of Salta in 1814, containing the current provinces of Salta, Jujuy, and parts of southern Bolivia and northern Chile. Exploiting internal Argentine conflicts that arose after the Argentine Declaration of Independence, in 1834, Jujuy withdrew from Salta and became a separate province. The borders of Salta were further reduced in 1900, with the loss of Yacuiba to Bolivia. The National Government of Los Andes, constituted from the province in 1902 with a capital at San Antonio de los Cobres, was returned to Salta Province in 1943 as the Department of Los Andes. Antonio Alices painting, La muerte de Güemes, which received a Gold Medal at the Centenary Exposition, is on display at the offices of the Salta Provincial Government. The province is located in the zone and has a warm climate in general. The orientation of the Andes influences the distribution of precipitation within the province, the easternmost parts of the province have a semi-arid climate with a dry winter season. The mean annual temperature and precipitation are 20 °C and 500 millimetres, temperatures can reach up to 47 °C during summers, while they can fall down to −5 °C during winters. The first slopes of the Andes force the moist, easterly winds to rise, provoking very high condensation leading to the formation of clouds that generate copious amounts of rain. The eastern slopes of the mountains receive between 1,000 to 1,500 mm of precipitation a year, although some places receive up to 2,500 mm of precipitation annually owing to orographic precipitation. Most of the precipitation is concentrated in the summer, with winters being dry, the high rainfall on these first slopes creates a thick jungle that extends in a narrow strip along these ranges, creating an area of great species diversity. At higher altitudes on these slopes, the climate is cooler and more humid, with the vegetation consisting of deciduous, between the high altitudes to the east and the low plains to the west lie the valleys
8.
Puna de Atacama
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The Puna de Atacama or Atacama Plateau is an arid high plateau, in the Andes of northern Chile and Argentina. Geomorphologist Walther Penck based his Grossfalt landform association on Puna de Atacama, the plateaus elevation averages 4,500 metres above sea level, and it spans an area of 180,000 square kilometres. In Argentina, Punas territory is extended in the provinces of Salta, Jujuy, in Chile, it is included in the regions of Antofagasta and north-eastern Atacama. Before the War of the Pacific, the region belonged to Bolivia, in 1898 it was ceded to Argentina in exchange for recognition of Tarija as part of Bolivia. Chile, which had annexed the Litoral Province from Bolivia, declared the exchange illegal, the border was defined in 1899 after the Puna de Atacama dispute. Of the 75,000 km2 in dispute 64,000 were awarded to Argentina and 11,000 to Chile, Puna de Atacama dispute Atacama Desert Altiplano Altiplano–Puna volcanic complex Salar de Atacama Salar de Arizaro Puna grassland Tren a las Nubes Salta–Antofagasta railway
9.
Salt
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Salt is present in vast quantities in seawater, where it is the main mineral constituent. The open ocean has about 35 grams of solids per litre, Salt is essential for life in general, and saltiness is one of the basic human tastes. The tissues of animals contain larger quantities of salt than do plant tissues, Salt is one of the oldest and most ubiquitous food seasonings, and salting is an important method of food preservation. Salt was also prized by the ancient Hebrews, the Greeks, the Romans, the Byzantines, the Hittites, Egyptians, and the Indians. Salt became an important article of trade and was transported by boat across the Mediterranean Sea, along specially built salt roads, the scarcity and universal need for salt has led nations to go to war over it and use it to raise tax revenues. Salt is used in ceremonies and has other cultural significance. Salt is processed from salt mines, or by the evaporation of seawater or mineral-rich spring water in shallow pools. Its major industrial products are caustic soda and chlorine, and is used in industrial processes including the manufacture of polyvinyl chloride, plastics, paper pulp. Of the annual production of around two hundred million tonnes of salt, only about 6% is used for human consumption. Other uses include water conditioning processes, de-icing highways, and agricultural use, edible salt is sold in forms such as sea salt and table salt which usually contains an anti-caking agent and may be iodised to prevent iodine deficiency. As well as its use in cooking and at the table, sodium is an essential nutrient for human health via its role as an electrolyte and osmotic solute. Excessive salt consumption can increase the risk of diseases, such as hypertension, in children. Such health effects of salt have long been studied, accordingly, numerous world health associations and experts in developed countries recommend reducing consumption of popular salty foods. The World Health Organization recommends that adults should consume less than 2,000 mg of sodium, humans have always tended to build communities either around sources of salt, or where they can trade for it. All through history the availability of salt has been pivotal to civilization, the word salary comes from the Latin word for salt because the Roman Legions were sometimes paid in salt. The Natron Valley was a key region that supported the Egyptian Empire to its north, because it supplied it with a kind of salt that came to be called by its name, natron. Even before this, what is now thought to have been the first city in Europe is Solnitsata, in Bulgaria, even the name Solnisata means salt works. A very ancient salt-works operation has been discovered at the Poiana Slatinei archaeological site next to a spring in Lunca, Neamț County
10.
Marble
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Marble is a metamorphic rock composed of recrystallized carbonate minerals, most commonly calcite or dolomite. Geologists use the marble to refer to metamorphosed limestone, however. Marble is commonly used for sculpture and as a building material and this stem is also the basis for the English word marmoreal, meaning marble-like. In Hungarian it is called márvány, Marble is a rock resulting from metamorphism of sedimentary carbonate rocks, most commonly limestone or dolomite rock. Metamorphism causes variable recrystallization of the carbonate mineral grains. The resulting marble rock is composed of an interlocking mosaic of carbonate crystals. Primary sedimentary textures and structures of the carbonate rock have typically been modified or destroyed. Pure white marble is the result of metamorphism of a very pure limestone or dolomite protolith, green coloration is often due to serpentine resulting from originally magnesium-rich limestone or dolostone with silica impurities. These various impurities have been mobilized and recrystallized by the intense pressure, examples of historically notable marble varieties and locations, White marble has been prized for its use in sculptures since classical times. This preference has to do with its softness, which made it easier to carve, relative isotropy and homogeneity, construction marble is a stone which is composed of calcite, dolomite or serpentine which is capable of taking a polish. More generally in construction, specifically the dimension stone trade, the marble is used for any crystalline calcitic rock useful as building stone. For example, Tennessee marble is really a dense granular fossiliferous gray to pink to maroon Ordovician limestone that geologists call the Holston Formation. Ashgabat, the city of Turkmenistan, was recorded in the 2013 Guinness Book of Records as having the worlds highest concentration of white marble buildings. According to the United States Geological Survey, U. S. domestic marble production in 2006 was 46,400 tons valued at about $18.1 million, compared to 72,300 tons valued at $18.9 million in 2005. Crushed marble production in 2006 was 11.8 million tons valued at $116 million, of which 6.5 million tons was finely ground calcium carbonate and the rest was construction aggregate. For comparison,2005 crushed marble production was 7.76 million tons valued at $58.7 million, of which 4.8 million tons was finely ground calcium carbonate, U. S. dimension marble demand is about 1.3 million tons. The DSAN World Demand for Marble Index has shown a growth of 12% annually for the 2000–2006 period, the largest dimension marble application is tile. In 1998, marble production was dominated by 4 countries that accounted for almost half of production of marble
11.
Iron
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Iron is a chemical element with symbol Fe and atomic number 26. It is a metal in the first transition series and it is by mass the most common element on Earth, forming much of Earths outer and inner core. It is the fourth most common element in the Earths crust, like the other group 8 elements, ruthenium and osmium, iron exists in a wide range of oxidation states, −2 to +6, although +2 and +3 are the most common. Elemental iron occurs in meteoroids and other low oxygen environments, but is reactive to oxygen, fresh iron surfaces appear lustrous silvery-gray, but oxidize in normal air to give hydrated iron oxides, commonly known as rust. Unlike the metals that form passivating oxide layers, iron oxides occupy more volume than the metal and thus flake off, Iron metal has been used since ancient times, although copper alloys, which have lower melting temperatures, were used even earlier in human history. Pure iron is soft, but is unobtainable by smelting because it is significantly hardened and strengthened by impurities, in particular carbon. A certain proportion of carbon steel, which may be up to 1000 times harder than pure iron. Crude iron metal is produced in blast furnaces, where ore is reduced by coke to pig iron, further refinement with oxygen reduces the carbon content to the correct proportion to make steel. Steels and iron alloys formed with metals are by far the most common industrial metals because they have a great range of desirable properties. Iron chemical compounds have many uses, Iron oxide mixed with aluminium powder can be ignited to create a thermite reaction, used in welding and purifying ores. Iron forms binary compounds with the halogens and the chalcogens, among its organometallic compounds is ferrocene, the first sandwich compound discovered. Iron plays an important role in biology, forming complexes with oxygen in hemoglobin and myoglobin. Iron is also the metal at the site of many important redox enzymes dealing with cellular respiration and oxidation and reduction in plants. A human male of average height has about 4 grams of iron in his body and this iron is distributed throughout the body in hemoglobin, tissues, muscles, bone marrow, blood proteins, enzymes, ferritin, hemosiderin, and transport in plasma. The mechanical properties of iron and its alloys can be evaluated using a variety of tests, including the Brinell test, Rockwell test, the data on iron is so consistent that it is often used to calibrate measurements or to compare tests. An increase in the content will cause a significant increase in the hardness. Maximum hardness of 65 Rc is achieved with a 0. 6% carbon content, because of the softness of iron, it is much easier to work with than its heavier congeners ruthenium and osmium. Because of its significance for planetary cores, the properties of iron at high pressures and temperatures have also been studied extensively
12.
Copper
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Copper is a chemical element with symbol Cu and atomic number 29. It is a soft, malleable, and ductile metal with high thermal and electrical conductivity. A freshly exposed surface of copper has a reddish-orange color. Copper is one of the few metals that occur in nature in directly usable metallic form as opposed to needing extraction from an ore and this led to very early human use, from c.8000 BC. Copper used in buildings, usually for roofing, oxidizes to form a green verdigris, Copper is sometimes used in decorative art, both in its elemental metal form and in compounds as pigments. Copper compounds are used as agents, fungicides, and wood preservatives. Copper is essential to all living organisms as a trace dietary mineral because it is a key constituent of the enzyme complex cytochrome c oxidase. In molluscs and crustaceans, copper is a constituent of the blood pigment hemocyanin, replaced by the hemoglobin in fish. In humans, copper is found mainly in the liver, muscle, the adult body contains between 1.4 and 2.1 mg of copper per kilogram of body weight. The filled d-shells in these elements contribute little to interatomic interactions, unlike metals with incomplete d-shells, metallic bonds in copper are lacking a covalent character and are relatively weak. This observation explains the low hardness and high ductility of single crystals of copper, at the macroscopic scale, introduction of extended defects to the crystal lattice, such as grain boundaries, hinders flow of the material under applied stress, thereby increasing its hardness. For this reason, copper is supplied in a fine-grained polycrystalline form. The softness of copper partly explains its high conductivity and high thermal conductivity. The maximum permissible current density of copper in open air is approximately 3. 1×106 A/m2 of cross-sectional area, Copper is one of a few metallic elements with a natural color other than gray or silver. Pure copper is orange-red and acquires a reddish tarnish when exposed to air, as with other metals, if copper is put in contact with another metal, galvanic corrosion will occur. A green layer of verdigris can often be seen on old structures, such as the roofing of many older buildings. Copper tarnishes when exposed to sulfur compounds, with which it reacts to form various copper sulfides. There are 29 isotopes of copper, 63Cu and 65Cu are stable, with 63Cu comprising approximately 69% of naturally occurring copper, both have a spin of 3⁄2
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