Samuel Green was an early American printer, the first of several printers from the Green family who followed in his footsteps. One of Green's major accomplishments as a printer was the Eliot Indian Bible, translated by the missionary John Eliot, typeset by James Printer, which became the first Bible to be printed in British America in 1663. Members of his family who also became printers include his sons Bartholomew, Bartholomew Green Jr. and Joseph Dennie. Throughout his adult life Green also served in the Massachusetts Bay Colonial Militia, advancing to the rank of captain later in life.

The Eliot Indian Bible was the first translation of the Christian Bible into an indigenous American language, as well as the first Bible published in British North America. It was prepared by English Puritan missionary John Eliot by translating the Geneva Bible into the Massachusett language. Printed in Cambridge, Massachusetts, the work first appeared in 1661 with only the New Testament. An edition including all 66 books of both the Old and New Testaments was printed in 1663.