In physics and chemistry, a selection rule, or transition rule, formally constrains the possible transitions of a system from one quantum state to another. Selection rules have been derived for electromagnetic transitions in molecules, in atoms, in atomic nuclei, and so on. The selection rules may differ according to the technique used to observe the transition. The selection rule also plays a role in chemical reactions, where some are formally spin-forbidden reactions, that is, reactions where the spin state changes at least once from reactants to products.
The infrared spectrum of HCl gas
Spin is an intrinsic form of angular momentum carried by elementary particles, and thus by composite particles such as hadrons, atomic nuclei, and atoms. Spin is quantized, and accurate models for the interaction with spin require relativistic quantum mechanics or quantum field theory.
Schematic diagram depicting the spin of the neutron as the black arrow and magnetic field lines associated with the neutron magnetic moment. The neutron has a negative magnetic moment. While the spin of the neutron is upward in this diagram, the magnetic field lines at the center of the dipole are downward.
Wolfgang Pauli lecturing
