The smew is a species of duck and is the only living member of the genus Mergellus. Mergellus is a diminutive of Mergus and albellus is from Latin albus "white". This genus is closely related to Mergus and is sometimes included in it, though it might be closer to the goldeneyes (Bucephala). The smew has hybridized with the common goldeneye.

Mergus is the genus of the typical mergansers fish-eating ducks in the subfamily Anatinae. The genus name is a Latin word used by Pliny the Elder and other Roman authors to refer to an unspecified waterbird.