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The steric effect of tri-(tert-butyl)amine makes electrophilic reactions, like forming the tetraalkylammonium cation, difficult. It is difficult for e
The steric effect of tri-(tert-butyl)amine makes electrophilic reactions, like forming the tetraalkylammonium cation, difficult. It is difficult for electrophiles to get close enough to allow attack by the lone pair of the nitrogen (nitrogen is shown in blue)
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Equilibrium distribution of two conformers at different temperatures given the free energy of their interconversion.
Equilibrium distribution of two conformers at different temperatures given the free energy of their interconversion.