In chemistry and crystallography, a symmetry element is a point, line, or plane about which symmetry operations can take place. In particular, a symmetry element can be a mirror plane, an axis of rotation, or a center of inversion. For an object such as a molecule or a crystal, a symmetry element corresponds to a set of symmetry operations, which are the rigid transformations employing the symmetry element that leave the object unchanged. The set containing these operations form one of the symmetry groups of the object. The elements of this symmetry group should not be confused with the "symmetry element" itself. Loosely, a symmetry element is the geometric set of fixed points of a symmetry operation. For example, for rotation about an axis, the points on the axis do not move and in a reflection the points that remain unchanged make up a plane of symmetry.
Mirror planes of XeF4
In mathematics, a symmetry operation is a geometric transformation of an object that leaves the object looking the same after it has been carried out. For example, a 1⁄3 turn rotation of a regular triangle about its center, a reflection of a square across its diagonal, a translation of the Euclidean plane, or a point reflection of a sphere through its center are all symmetry operations. Each symmetry operation is performed with respect to some symmetry element. Symmetry operations can be classified either as point symmetry operations or as travel symmetry operations.
Reflection operation
Inversion operation is shown here with a sulfur hexafluoride molecule. All of the fluorine atoms change their position to opposite side with respect to the sulfur center