The Valentine Formation is a geologic unit formation or member within the Ogallala unit in northcentral Nebraska near the South Dakota border. It preserves fossils dating to the Miocene epoch of the Neogene period and is particularly noted for Canid fossils. This unit consists of loosely-consolidated sandstone that crumbles easily. These sands carry the water of the Ogallala Aquifer and is the source of much of the water in the Niobrara River. A particular feature of the Valentine is lenticular beds of green-gray opaline sandstone that can be identified in other states, including South Dakota, Nebraska, Kansas, and Colorado. Although three mammalian fauna stages can be mapped throughout the range of the Ogallala, no beddings of the Ogallala are mappable and all attempts of formally applying the Valentine name to any mappable lithology beyond the type location have been abandoned. Even so, opaline sandstone has been used to refer to this green-gray opalized conglomerate sandstone that is widely found in the lower Ogallala Formation.

The Ogallala Formation is a Miocene to early Pliocene geologic formation in the central High Plains of the western United States and the location of the Ogallala Aquifer. In Nebraska and South Dakota it is also classified as the Ogallala Group. Notably, it records the North American Land Mammal Ages (NALMAs) Hemphillian, Clarendonian, and Barstovian. It also includes an excellent record of grass seeds and other plant seeds, which can be used for biostratigraphic dating within the formation. The Ogallala Formation outcrops of Lake Meredith National Recreation Area preserve fish fossils. Similar specimens from the same unit are found at Alibates Flint Quarries National Monument in Texas.