The van der Waals equation, named for its originator, the Dutch physicist Johannes Diderik van der Waals, is an equation of state that extends the ideal gas law to include the non-zero size of gas molecules and the interactions between them. As a result the equation is able to model the phase change, liquid vapor. It also produces simple analytic expressions for the properties of real substances that shed light on their behavior. One way to write this equation is:
Van der Waals equation on a wall in Leiden
Figure 4: A plot of the correlation including data from various substances.
Johannes Diderik van der Waals
Johannes Diderik van der Waals was a Dutch theoretical physicist and thermodynamicist famous for his pioneering work on the equation of state for gases and liquids. Van der Waals started his career as a schoolteacher. He became the first physics professor of the University of Amsterdam when in 1877 the old Athenaeum was upgraded to Municipal University. Van der Waals won the 1910 Nobel Prize in physics for his work on the equation of state for gases and liquids.
Van der Waals in 1910