1.
Inch
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The inch is a unit of length in the imperial and United States customary systems of measurement now formally equal to 1⁄36 yard but usually understood as 1⁄12 of a foot. Derived from the Roman uncia, inch is also used to translate related units in other measurement systems. The English word inch was a borrowing from Latin uncia not present in other Germanic languages. The vowel change from Latin /u/ to English /ɪ/ is known as umlaut, the consonant change from the Latin /k/ to English /tʃ/ or /ʃ/ is palatalisation. Both were features of Old English phonology, inch is cognate with ounce, whose separate pronunciation and spelling reflect its reborrowing in Middle English from Anglo-Norman unce and ounce. In many other European languages, the word for inch is the same as or derived from the word for thumb, the inch is a commonly used customary unit of length in the United States, Canada, and the United Kingdom. It is also used in Japan for electronic parts, especially display screens, for example, three feet two inches can be written as 3′ 2″. Paragraph LXVII sets out the fine for wounds of various depths, one inch, one shilling, an Anglo-Saxon unit of length was the barleycorn. After 1066,1 inch was equal to 3 barleycorns, which continued to be its legal definition for several centuries, similar definitions are recorded in both English and Welsh medieval law tracts. One, dating from the first half of the 10th century, is contained in the Laws of Hywel Dda which superseded those of Dyfnwal, both definitions, as recorded in Ancient Laws and Institutes of Wales, are that three lengths of a barleycorn is the inch. However, the oldest surviving manuscripts date from the early 14th century, john Bouvier similarly recorded in his 1843 law dictionary that the barleycorn was the fundamental measure. He noted that this process would not perfectly recover the standard, before the adoption of the international yard and pound, various definitions were in use. In the United Kingdom and most countries of the British Commonwealth, the United States adopted the conversion factor 1 metre =39.37 inches by an act in 1866. In 1930, the British Standards Institution adopted an inch of exactly 25.4 mm, the American Standards Association followed suit in 1933. By 1935, industry in 16 countries had adopted the industrial inch as it came to be known, in 1946, the Commonwealth Science Congress recommended a yard of exactly 0.9144 metres for adoption throughout the British Commonwealth. This was adopted by Canada in 1951, the United States on 1 July 1959, Australia in 1961, effective 1 January 1964, and the United Kingdom in 1963, effective on 1 January 1964. The new standards gave an inch of exactly 25.4 mm,1.7 millionths of a longer than the old imperial inch and 2 millionths of an inch shorter than the old US inch. The United States retains the 1/39. 37-metre definition for survey purposes and this is approximately 1/8-inch in a mile
2.
Iron
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Iron is a chemical element with symbol Fe and atomic number 26. It is a metal in the first transition series and it is by mass the most common element on Earth, forming much of Earths outer and inner core. It is the fourth most common element in the Earths crust, like the other group 8 elements, ruthenium and osmium, iron exists in a wide range of oxidation states, −2 to +6, although +2 and +3 are the most common. Elemental iron occurs in meteoroids and other low oxygen environments, but is reactive to oxygen, fresh iron surfaces appear lustrous silvery-gray, but oxidize in normal air to give hydrated iron oxides, commonly known as rust. Unlike the metals that form passivating oxide layers, iron oxides occupy more volume than the metal and thus flake off, Iron metal has been used since ancient times, although copper alloys, which have lower melting temperatures, were used even earlier in human history. Pure iron is soft, but is unobtainable by smelting because it is significantly hardened and strengthened by impurities, in particular carbon. A certain proportion of carbon steel, which may be up to 1000 times harder than pure iron. Crude iron metal is produced in blast furnaces, where ore is reduced by coke to pig iron, further refinement with oxygen reduces the carbon content to the correct proportion to make steel. Steels and iron alloys formed with metals are by far the most common industrial metals because they have a great range of desirable properties. Iron chemical compounds have many uses, Iron oxide mixed with aluminium powder can be ignited to create a thermite reaction, used in welding and purifying ores. Iron forms binary compounds with the halogens and the chalcogens, among its organometallic compounds is ferrocene, the first sandwich compound discovered. Iron plays an important role in biology, forming complexes with oxygen in hemoglobin and myoglobin. Iron is also the metal at the site of many important redox enzymes dealing with cellular respiration and oxidation and reduction in plants. A human male of average height has about 4 grams of iron in his body and this iron is distributed throughout the body in hemoglobin, tissues, muscles, bone marrow, blood proteins, enzymes, ferritin, hemosiderin, and transport in plasma. The mechanical properties of iron and its alloys can be evaluated using a variety of tests, including the Brinell test, Rockwell test, the data on iron is so consistent that it is often used to calibrate measurements or to compare tests. An increase in the content will cause a significant increase in the hardness. Maximum hardness of 65 Rc is achieved with a 0. 6% carbon content, because of the softness of iron, it is much easier to work with than its heavier congeners ruthenium and osmium. Because of its significance for planetary cores, the properties of iron at high pressures and temperatures have also been studied extensively
3.
Alloy
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An alloy is a mixture of metals or a mixture of a metal and another element. Alloys are defined by a metallic bonding character, an alloy may be a solid solution of metal elements or a mixture of metallic phases. Intermetallic compounds are alloys with a stoichiometry and crystal structure. Zintl phases are sometimes considered alloys depending on bond types. Alloys are used in a variety of applications. In some cases, a combination of metals may reduce the overall cost of the material while preserving important properties, in other cases, the combination of metals imparts synergistic properties to the constituent metal elements such as corrosion resistance or mechanical strength. Examples of alloys are steel, solder, brass, pewter, duralumin, bronze, the alloy constituents are usually measured by mass. Alloys are usually classified as substitutional or interstitial alloys, depending on the arrangement that forms the alloy. They can be classified as homogeneous, or heterogeneous or intermetallic. An alloy is a mixture of elements, which forms an impure substance that retains the characteristics of a metal. Alloys are made by mixing two or more elements, at least one of which is a metal and this is usually called the primary metal or the base metal, and the name of this metal may also be the name of the alloy. The other constituents may or may not be metals but, when mixed with the base, they will be soluble. The mechanical properties of alloys will often be different from those of its individual constituents. A metal that is very soft, such as aluminium, can be altered by alloying it with another soft metal. Although both metals are soft and ductile, the resulting aluminium alloy will have much greater strength. Adding a small amount of carbon to iron trades its great ductility for the greater strength of an alloy called steel. Due to its strength, but still substantial toughness, and its ability to be greatly altered by heat treatment, steel is one of the most useful. By adding chromium to steel, its resistance to corrosion can be enhanced, creating stainless steel, while adding silicon will alter its electrical characteristics, producing silicon steel
4.
Aluminium
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Aluminium or aluminum is a chemical element in the boron group with symbol Al and atomic number 13. It is a silvery-white, soft, nonmagnetic, ductile metal, Aluminium metal is so chemically reactive that native specimens are rare and limited to extreme reducing environments. Instead, it is combined in over 270 different minerals. The chief ore of aluminium is bauxite, Aluminium is remarkable for the metals low density and its ability to resist corrosion through the phenomenon of passivation. Aluminium and its alloys are vital to the industry and important in transportation and structures, such as building facades. The oxides and sulfates are the most useful compounds of aluminium, despite its prevalence in the environment, no known form of life uses aluminium salts metabolically, but aluminium is well tolerated by plants and animals. Because of these salts abundance, the potential for a role for them is of continuing interest. Aluminium is a soft, durable, lightweight, ductile. It is nonmagnetic and does not easily ignite, a fresh film of aluminium serves as a good reflector of visible light and an excellent reflector of medium and far infrared radiation. The yield strength of aluminium is 7–11 MPa, while aluminium alloys have yield strengths ranging from 200 MPa to 600 MPa. Aluminium has about one-third the density and stiffness of steel and it is easily machined, cast, drawn and extruded. Aluminium atoms are arranged in a cubic structure. Aluminium has an energy of approximately 200 mJ/m2. Aluminium is a thermal and electrical conductor, having 59% the conductivity of copper. Aluminium is capable of superconductivity, with a critical temperature of 1.2 kelvin. Aluminium is the most common material for the fabrication of superconducting qubits, the strongest aluminium alloys are less corrosion resistant due to galvanic reactions with alloyed copper. This corrosion resistance is reduced by aqueous salts, particularly in the presence of dissimilar metals. In highly acidic solutions, aluminium reacts with water to form hydrogen, primarily because it is corroded by dissolved chlorides, such as common sodium chloride, household plumbing is never made from aluminium
5.
Nickel
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Nickel is a chemical element with symbol Ni and atomic number 28. It is a silvery-white lustrous metal with a golden tinge. Nickel belongs to the metals and is hard and ductile. Meteoric nickel is found in combination with iron, a reflection of the origin of elements as major end products of supernova nucleosynthesis. An iron–nickel mixture is thought to compose Earths inner core, use of nickel has been traced as far back as 3500 BCE. Nickel was first isolated and classified as an element in 1751 by Axel Fredrik Cronstedt. The elements name comes from a mischievous sprite of German miner mythology, Nickel, an economically important source of nickel is the iron ore limonite, which often contains 1–2% nickel. Nickels other important ore minerals include garnierite, and pentlandite, major production sites include the Sudbury region in Canada, New Caledonia in the Pacific, and Norilsk in Russia. Nickel is slowly oxidized by air at room temperature and is considered corrosion-resistant, historically, it has been used for plating iron and brass, coating chemistry equipment, and manufacturing certain alloys that retain a high silvery polish, such as German silver. About 6% of world production is still used for corrosion-resistant pure-nickel plating. Nickel-plated objects sometimes provoke nickel allergy, Nickel has been widely used in coins, though its rising price has led to some replacement with cheaper metals in recent years. Nickel is one of four elements that are ferromagnetic around room temperature, alnico permanent magnets based partly on nickel are of intermediate strength between iron-based permanent magnets and rare-earth magnets. The metal is valuable in modern times chiefly in alloys, about 60% of world production is used in nickel-steels, other common alloys and some new superalloys comprise most of the remainder of world nickel use, with chemical uses for nickel compounds consuming less than 3% of production. As a compound, nickel has a number of chemical manufacturing uses. Nickel is a nutrient for some microorganisms and plants that have enzymes with nickel as an active site. Nickel is a metal with a slight golden tinge that takes a high polish. It is one of four elements that are magnetic at or near room temperature. Its Curie temperature is 355 °C, meaning that bulk nickel is non-magnetic above this temperature, the unit cell of nickel is a face-centered cube with the lattice parameter of 0.352 nm, giving an atomic radius of 0.124 nm
6.
Cobalt
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Cobalt is a chemical element with symbol Co and atomic number 27. Like nickel, cobalt is found in the Earths crust only in chemically combined form, the free element, produced by reductive smelting, is a hard, lustrous, silver-gray metal. In 1735, such ores were found to be reducible to a new metal, today, some cobalt is produced specifically from various metallic-lustered ores, for example cobaltite, but the main source of the element is as a by-product of copper and nickel mining. The copper belt in the Democratic Republic of the Congo, Central African Republic, cobalt is primarily used in the preparation of magnetic, wear-resistant and high-strength alloys. The compounds, cobalt silicate and cobalt aluminate give a deep blue color to glass, ceramics, inks, paints. Cobalt occurs naturally as only one isotope, cobalt-59. Cobalt-60 is an important radioisotope, used as a radioactive tracer. Cobalt is the center of coenzymes called cobalamins, the most common example of which is vitamin B12. As such, it is a trace dietary mineral for all animals. Cobalt in inorganic form is also a micronutrient for bacteria, algae, cobalt is a ferromagnetic metal with a specific gravity of 8.9. The Curie temperature is 1,115 °C and the moment is 1. 6–1.7 Bohr magnetons per atom. Cobalt has a relative permeability two-thirds that of iron, metallic cobalt occurs as two crystallographic structures, hcp and fcc. The ideal transition temperature between the hcp and fcc structures is 450 °C, but in practice, the difference is so small that random intergrowth of the two is common. Cobalt is a weakly reducing metal that is protected from oxidation by an oxide film. It is attacked by halogens and sulfur, heating in oxygen produces Co3O4 which loses oxygen at 900 °C to give the monoxide CoO. The metal reacts with fluorine at 520 K to give CoF3, with chlorine, bromine and iodine and it does not react with hydrogen gas or nitrogen gas even when heated, but it does react with boron, carbon, phosphorus, arsenic and sulfur. At ordinary temperatures, it reacts slowly with mineral acids, and very slowly with moist, common oxidation states of cobalt include +2 and +3, although compounds with oxidation states ranging from −3 to +5 are also known. A common oxidation state for simple compounds is +2 and these salts form the pink-colored metal aquo complex 2+ in water
7.
Copper
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Copper is a chemical element with symbol Cu and atomic number 29. It is a soft, malleable, and ductile metal with high thermal and electrical conductivity. A freshly exposed surface of copper has a reddish-orange color. Copper is one of the few metals that occur in nature in directly usable metallic form as opposed to needing extraction from an ore and this led to very early human use, from c.8000 BC. Copper used in buildings, usually for roofing, oxidizes to form a green verdigris, Copper is sometimes used in decorative art, both in its elemental metal form and in compounds as pigments. Copper compounds are used as agents, fungicides, and wood preservatives. Copper is essential to all living organisms as a trace dietary mineral because it is a key constituent of the enzyme complex cytochrome c oxidase. In molluscs and crustaceans, copper is a constituent of the blood pigment hemocyanin, replaced by the hemoglobin in fish. In humans, copper is found mainly in the liver, muscle, the adult body contains between 1.4 and 2.1 mg of copper per kilogram of body weight. The filled d-shells in these elements contribute little to interatomic interactions, unlike metals with incomplete d-shells, metallic bonds in copper are lacking a covalent character and are relatively weak. This observation explains the low hardness and high ductility of single crystals of copper, at the macroscopic scale, introduction of extended defects to the crystal lattice, such as grain boundaries, hinders flow of the material under applied stress, thereby increasing its hardness. For this reason, copper is supplied in a fine-grained polycrystalline form. The softness of copper partly explains its high conductivity and high thermal conductivity. The maximum permissible current density of copper in open air is approximately 3. 1×106 A/m2 of cross-sectional area, Copper is one of a few metallic elements with a natural color other than gray or silver. Pure copper is orange-red and acquires a reddish tarnish when exposed to air, as with other metals, if copper is put in contact with another metal, galvanic corrosion will occur. A green layer of verdigris can often be seen on old structures, such as the roofing of many older buildings. Copper tarnishes when exposed to sulfur compounds, with which it reacts to form various copper sulfides. There are 29 isotopes of copper, 63Cu and 65Cu are stable, with 63Cu comprising approximately 69% of naturally occurring copper, both have a spin of 3⁄2
8.
Titanium
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Titanium is a chemical element with symbol Ti and atomic number 22. It is a transition metal with a silver color, low density. Titanium is resistant to corrosion in sea water, aqua regia, titanium was discovered in Cornwall, Great Britain, by William Gregor in 1791, and it is named by Martin Heinrich Klaproth for the Titans of Greek mythology. The metal is extracted from its principal mineral ores by the Kroll, the most common compound, titanium dioxide, is a popular photocatalyst and is used in the manufacture of white pigments. Other compounds include titanium tetrachloride, a component of smoke screens and catalysts, and titanium trichloride, the two most useful properties of the metal are corrosion resistance and strength-to-density ratio, the highest of any metallic element. In its unalloyed condition, titanium is as strong as some steels, there are two allotropic forms and five naturally occurring isotopes of this element, 46Ti through 50Ti, with 48Ti being the most abundant. Although they have the number of valence electrons and are in the same group in the periodic table. As a metal, titanium is recognized for its high strength-to-weight ratio and it is a strong metal with low density that is quite ductile, lustrous, and metallic-white in color. The relatively high melting point makes it useful as a refractory metal and it is paramagnetic and has fairly low electrical and thermal conductivity. Commercial grades of titanium have ultimate tensile strength of about 434 MPa, equal to that of common, low-grade steel alloys, titanium is 60% denser than aluminium, but more than twice as strong as the most commonly used 6061-T6 aluminium alloy. Certain titanium alloys achieve tensile strengths of over 1400 MPa, however, titanium loses strength when heated above 430 °C. Titanium is not as hard as some grades of heat-treated steel, it is non-magnetic, machining requires precautions, because the material might gall unless sharp tools and proper cooling methods are used. Like steel structures, those made from titanium have a limit that guarantees longevity in some applications. The metal is an allotrope of an hexagonal α form that changes into a body-centered cubic β form at 882 °C. The specific heat of the α form increases dramatically as it is heated to this transition temperature but then falls, similar to zirconium and hafnium, an additional omega phase exists, which is thermodynamically stable at high pressures, but metastable at ambient pressures. This phase is usually hexagonal or trigonal and can be considered to be due to a soft longitudinal acoustic phonon of the β phase causing collapse of planes of atoms, like aluminium and magnesium, titanium metal and its alloys oxidize immediately upon exposure to air. Titanium readily reacts with oxygen at 1,200 °C in air and it is, however, slow to react with water and air at ambient temperatures because it forms a passive oxide coating that protects the bulk metal from further oxidation. When it first forms, this layer is only 1–2 nm thick but continues to grow slowly
9.
Ferromagnetism
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Not to be confused with Ferrimagnetism, for an overview see Magnetism. Ferromagnetism is the mechanism by which certain materials form permanent magnets. In physics, several different types of magnetism are distinguished, an everyday example of ferromagnetism is a refrigerator magnet used to hold notes on a refrigerator door. The attraction between a magnet and ferromagnetic material is the quality of magnetism first apparent to the ancient world, permanent magnets are either ferromagnetic or ferrimagnetic, as are the materials that are noticeably attracted to them. Only a few substances are ferromagnetic, the common ones are iron, nickel, cobalt and most of their alloys, some compounds of rare earth metals, and a few naturally occurring minerals, including some varieties of lodestone. Historically, the term ferromagnetism was used for any material that could exhibit spontaneous magnetization and this general definition is still in common use. In particular, a material is ferromagnetic in this sense only if all of its magnetic ions add a positive contribution to the net magnetization. If some of the magnetic ions subtract from the net magnetization, if the moments of the aligned and anti-aligned ions balance completely so as to have zero net magnetization, despite the magnetic ordering, then it is an antiferromagnet. These alignment effects only occur at temperatures below a critical temperature. Among the first investigations of ferromagnetism are the works of Aleksandr Stoletov on measurement of the magnetic permeability of ferromagnetics. The table on the right lists a selection of ferromagnetic and ferrimagnetic compounds, ferromagnetism is a property not just of the chemical make-up of a material, but of its crystalline structure and microstructure. There are ferromagnetic metal alloys whose constituents are not themselves ferromagnetic, called Heusler alloys, conversely there are non-magnetic alloys, such as types of stainless steel, composed almost exclusively of ferromagnetic metals. Amorphous ferromagnetic metallic alloys can be made by rapid quenching of a liquid alloy. These have the advantage that their properties are isotropic, this results in low coercivity, low hysteresis loss, high permeability. One such typical material is a transition metal-metalloid alloy, made from about 80% transition metal, a relatively new class of exceptionally strong ferromagnetic materials are the rare-earth magnets. They contain lanthanide elements that are known for their ability to carry large magnetic moments in well-localized f-orbitals, a number of actinide compounds are ferromagnets at room temperature or exhibit ferromagnetism upon cooling. PuP is a paramagnet with cubic symmetry at room temperature, in its ferromagnetic state, PuPs easy axis is in the <100> direction. In NpFe2 the easy axis is <111>, above TC ≈500 K NpFe2 is also paramagnetic and cubic
