1.
Glass
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Glass is a non-crystalline amorphous solid that is often transparent and has widespread practical, technological, and decorative usage in, for example, window panes, tableware, and optoelectronics. The most familiar, and historically the oldest, types of glass are silicate glasses based on the chemical compound silica, the primary constituent of sand. The term glass, in usage, is often used to refer only to this type of material. Many applications of silicate glasses derive from their optical transparency, giving rise to their use as window panes. Glass can be coloured by adding metallic salts, and can also be painted and printed with vitreous enamels and these qualities have led to the extensive use of glass in the manufacture of art objects and in particular, stained glass windows. Although brittle, silicate glass is extremely durable, and many examples of glass fragments exist from early glass-making cultures, because glass can be formed or moulded into any shape, it has been traditionally used for vessels, bowls, vases, bottles, jars and drinking glasses. In its most solid forms it has also used for paperweights, marbles. Some objects historically were so commonly made of glass that they are simply called by the name of the material, such as drinking glasses. Porcelains and many polymer thermoplastics familiar from everyday use are glasses and these sorts of glasses can be made of quite different kinds of materials than silica, metallic alloys, ionic melts, aqueous solutions, molecular liquids, and polymers. For many applications, like glass bottles or eyewear, polymer glasses are a lighter alternative than traditional glass, silica is a common fundamental constituent of glass. In nature, vitrification of quartz occurs when lightning strikes sand, forming hollow, fused quartz is a glass made from chemically-pure SiO2. It has excellent resistance to shock, being able to survive immersion in water while red hot. However, its high melting-temperature and viscosity make it difficult to work with, normally, other substances are added to simplify processing. One is sodium carbonate, which lowers the transition temperature. The soda makes the glass water-soluble, which is undesirable, so lime, some magnesium oxide. The resulting glass contains about 70 to 74% silica by weight and is called a soda-lime glass, soda-lime glasses account for about 90% of manufactured glass. Most common glass contains other ingredients to change its properties, lead glass or flint glass is more brilliant because the increased refractive index causes noticeably more specular reflection and increased optical dispersion. Adding barium also increases the refractive index, iron can be incorporated into glass to absorb infrared energy, for example in heat absorbing filters for movie projectors, while cerium oxide can be used for glass that absorbs UV wavelengths
2.
Cast iron
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Cast iron is a group of iron-carbon alloys with a carbon content greater than 2%. Its usefulness derives from its low melting temperature. Carbon ranging from 1. 8–4 wt%, and silicon 1–3 wt% are the main alloying elements of cast iron, Iron alloys with less carbon content are known as steel. While this technically makes the Fe–C–Si system ternary, the principle of cast iron solidification can be understood from the simpler binary iron–carbon phase diagram, cast iron tends to be brittle, except for malleable cast irons. It is resistant to destruction and weakening by oxidation, the earliest cast iron artefacts date to the 5th century BC, and were discovered by archaeologists in what is now Jiangsu in China. Cast iron was used in ancient China for warfare, agriculture, during the 15th century, cast iron became utilized for artillery in Burgundy, France, and in England during the Reformation. The first cast iron bridge was built during the 1770s by Abraham Darby III, cast iron is also used in the construction of buildings. Cast iron is made by re-melting pig iron, often along with quantities of iron, steel, limestone, carbon. Phosphorus and sulfur may be burnt out of the iron, but this also burns out the carbon. Depending on the application, carbon and silicon content are adjusted to the desired levels, other elements are then added to the melt before the final form is produced by casting. Cast iron is melted in a special type of blast furnace known as a cupola. After melting is complete, the molten cast iron is poured into a furnace or ladle. Cast irons properties are changed by adding various alloying elements, or alloyants, next to carbon, silicon is the most important alloyant because it forces carbon out of solution. A low percentage of silicon allows carbon to remain in solution forming iron carbide, a high percentage of silicon forces carbon out of solution forming graphite and the production of grey cast iron. Other alloying agents, manganese, chromium, molybdenum, titanium and vanadium counteracts silicon, promotes the retention of carbon, nickel and copper increase strength, and machinability, but do not change the amount of graphite formed. The carbon in the form of graphite results in an iron, reduces shrinkage, lowers strength. Sulfur, largely a contaminant when present, forms iron sulfide, the problem with sulfur is that it makes molten cast iron viscous, which causes defects. To counter the effects of sulfur, manganese is added because the two form into manganese sulfide instead of iron sulfide, the manganese sulfide is lighter than the melt so it tends to float out of the melt and into the slag
3.
Stress (physics)
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For example, when a solid vertical bar is supporting a weight, each particle in the bar pushes on the particles immediately below it. When a liquid is in a container under pressure, each particle gets pushed against by all the surrounding particles. The container walls and the pressure-inducing surface push against them in reaction and these macroscopic forces are actually the net result of a very large number of intermolecular forces and collisions between the particles in those molecules. Strain inside a material may arise by various mechanisms, such as stress as applied by external forces to the material or to its surface. Any strain of a material generates an internal elastic stress, analogous to the reaction force of a spring. In liquids and gases, only deformations that change the volume generate persistent elastic stress, however, if the deformation is gradually changing with time, even in fluids there will usually be some viscous stress, opposing that change. Elastic and viscous stresses are usually combined under the mechanical stress. Significant stress may exist even when deformation is negligible or non-existent, stress may exist in the absence of external forces, such built-in stress is important, for example, in prestressed concrete and tempered glass. Stress may also be imposed on a material without the application of net forces, for example by changes in temperature or chemical composition, stress that exceeds certain strength limits of the material will result in permanent deformation or even change its crystal structure and chemical composition. In some branches of engineering, the stress is occasionally used in a looser sense as a synonym of internal force. For example, in the analysis of trusses, it may refer to the total traction or compression force acting on a beam, since ancient times humans have been consciously aware of stress inside materials. Until the 17th century the understanding of stress was largely intuitive and empirical, with those tools, Augustin-Louis Cauchy was able to give the first rigorous and general mathematical model for stress in a homogeneous medium. Cauchy observed that the force across a surface was a linear function of its normal vector, and, moreover. The understanding of stress in liquids started with Newton, who provided a formula for friction forces in parallel laminar flow. Stress is defined as the force across a small boundary per unit area of that boundary, following the basic premises of continuum mechanics, stress is a macroscopic concept. In a fluid at rest the force is perpendicular to the surface, in a solid, or in a flow of viscous liquid, the force F may not be perpendicular to S, hence the stress across a surface must be regarded a vector quantity, not a scalar. Moreover, the direction and magnitude depend on the orientation of S. Thus the stress state of the material must be described by a tensor, called the stress tensor, with respect to any chosen coordinate system, the Cauchy stress tensor can be represented as a symmetric matrix of 3×3 real numbers
4.
Energy
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In physics, energy is the property that must be transferred to an object in order to perform work on – or to heat – the object, and can be converted in form, but not created or destroyed. The SI unit of energy is the joule, which is the transferred to an object by the mechanical work of moving it a distance of 1 metre against a force of 1 newton. Mass and energy are closely related, for example, with a sensitive enough scale, one could measure an increase in mass after heating an object. Living organisms require available energy to stay alive, such as the humans get from food. Civilisation gets the energy it needs from energy resources such as fuels, nuclear fuel. The processes of Earths climate and ecosystem are driven by the radiant energy Earth receives from the sun, the total energy of a system can be subdivided and classified in various ways. It may also be convenient to distinguish gravitational energy, thermal energy, several types of energy, electric energy. Many of these overlap, for instance, thermal energy usually consists partly of kinetic. Some types of energy are a mix of both potential and kinetic energy. An example is energy which is the sum of kinetic. Whenever physical scientists discover that a phenomenon appears to violate the law of energy conservation. Heat and work are special cases in that they are not properties of systems, in general we cannot measure how much heat or work are present in an object, but rather only how much energy is transferred among objects in certain ways during the occurrence of a given process. Heat and work are measured as positive or negative depending on which side of the transfer we view them from, the distinctions between different kinds of energy is not always clear-cut. In contrast to the definition, energeia was a qualitative philosophical concept, broad enough to include ideas such as happiness. The modern analog of this property, kinetic energy, differs from vis viva only by a factor of two, in 1807, Thomas Young was possibly the first to use the term energy instead of vis viva, in its modern sense. Gustave-Gaspard Coriolis described kinetic energy in 1829 in its modern sense, the law of conservation of energy was also first postulated in the early 19th century, and applies to any isolated system. It was argued for years whether heat was a physical substance, dubbed the caloric, or merely a physical quantity. In 1845 James Prescott Joule discovered the link between mechanical work and the generation of heat and these developments led to the theory of conservation of energy, formalized largely by William Thomson as the field of thermodynamics
5.
Strength of materials
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Strength of materials, also called mechanics of materials, is a subject which deals with the behavior of solid objects subject to stresses and strains. An important founding pioneer in mechanics of materials was Stephen Timoshenko, the study of strength of materials often refers to various methods of calculating the stresses and strains in structural members, such as beams, columns, and shafts. In materials science, the strength of a material is its ability to withstand a load without failure or plastic deformation. The field of strength of materials deals with forces and deformations that result from their acting on a material, a load applied to a mechanical member will induce internal forces within the member called stresses when those forces are expressed on a unit basis. The stresses acting on the material cause deformation of the material in various manners, deformation of the material is called strain when those deformations too are placed on a unit basis. The applied loads may be axial, or rotational, the stresses and strains that develop within a mechanical member must be calculated in order to assess the load capacity of that member. This requires a description of the geometry of the member, its constraints, the loads applied to the member. With a complete description of the loading and the geometry of the member, once the state of stress and strain within the member is known, the strength of that member, its deformations, and its stability can be calculated. The calculated stresses may then be compared to some measure of the strength of the such as its material yield or ultimate strength. The calculated deflection of the member may be compared to a deflection criteria that is based on the members use, the calculated buckling load of the member may be compared to the applied load. The calculated stiffness and mass distribution of the member may be used to calculate the dynamic response. The ultimate strength refers to the point on the engineering stress–strain curve corresponding to the stress that produces fracture, transverse loading - Forces applied perpendicular to the longitudinal axis of a member. Transverse loading causes the member to bend and deflect from its position, with internal tensile. Transverse loading also induces shear forces that cause shear deformation of the material, axial loading - The applied forces are collinear with the longitudinal axis of the member. The forces cause the member to either stretch or shorten, uniaxial stress is expressed by σ = F A where F is the force acting on an area A. The area can be the area or the deformed area. A simple case of compression is the uniaxial compression induced by the action of opposite, compressive strength for materials is generally higher than their tensile strength. However, structures loaded in compression are subject to additional failure modes, such as buckling, that are dependent on the members geometry
6.
Ceramic
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A ceramic is an inorganic, non-metallic, solid material comprising metal, non-metal or metalloid atoms primarily held in ionic and covalent bonds. This article gives an overview of ceramic materials from the point of view of materials science, the crystallinity of ceramic materials ranges from highly oriented to semi-crystalline, vitrified, and often completely amorphous. Most often, fired ceramics are either vitrified or semi-vitrified as is the case with earthenware, stoneware, varying crystallinity and electron consumption in the ionic and covalent bonds cause most ceramic materials to be good thermal and electrical insulators. With such a range of possible options for the composition/structure of a ceramic, the breadth of the subject is vast. Many composites, such as fiberglass and carbon fiber, while containing ceramic materials, are not considered to be part of the ceramic family. The earliest ceramics made by humans were pottery objects or figurines made from clay, either by itself or mixed with materials like silica, hardened, sintered. Later ceramics were glazed and fired to create smooth, colored surfaces, decreasing porosity through the use of glassy, ceramics now include domestic, industrial and building products, as well as a wide range of ceramic art. In the 20th century, new materials were developed for use in advanced ceramic engineering. The word ceramic comes from the Greek word κεραμικός, of pottery or for pottery, from κέραμος, potters clay, tile, the earliest known mention of the root ceram- is the Mycenaean Greek ke-ra-me-we, workers of ceramics, written in Linear B syllabic script. The word ceramic may be used as an adjective to describe a material, product or process, or it may be used as a noun, either singular, or, more commonly, as the plural noun ceramics. A ceramic material is an inorganic, non-metallic, often crystalline oxide, nitride or carbide material, some elements, such as carbon or silicon, may be considered ceramics. Ceramic materials are brittle, hard, strong in compression, weak in shearing and they withstand chemical erosion that occurs in other materials subjected to acidic or caustic environments. Ceramics generally can withstand high temperatures, such as temperatures that range from 1,000 °C to 1,600 °C. Glass is often not considered a ceramic because of its amorphous character. However, glassmaking involves several steps of the process and its mechanical properties are similar to ceramic materials. Traditional ceramic raw materials include minerals such as kaolinite, whereas more recent materials include aluminium oxide. The modern ceramic materials, which are classified as advanced ceramics, include silicon carbide, both are valued for their abrasion resistance, and hence find use in applications such as the wear plates of crushing equipment in mining operations. Advanced ceramics are used in the medicine, electrical, electronics industries. Crystalline ceramic materials are not amenable to a range of processing
7.
Polymer
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A polymer is a large molecule, or macromolecule, composed of many repeated subunits. Because of their range of properties, both synthetic and natural polymers play an essential and ubiquitous role in everyday life. Polymers range from familiar synthetic plastics such as polystyrene to natural biopolymers such as DNA and proteins that are fundamental to biological structure, Polymers, both natural and synthetic, are created via polymerization of many small molecules, known as monomers. The units composing polymers derive, actually or conceptually, from molecules of low molecular mass. The term was coined in 1833 by Jöns Jacob Berzelius, though with a distinct from the modern IUPAC definition. The modern concept of polymers as covalently bonded macromolecular structures was proposed in 1920 by Hermann Staudinger, Polymers are studied in the fields of biophysics and macromolecular science, and polymer science. Polyisoprene of latex rubber is an example of a polymer. In biological contexts, essentially all biological macromolecules—i. e, proteins, nucleic acids, and polysaccharides—are purely polymeric, or are composed in large part of polymeric components—e. g. Isoprenylated/lipid-modified glycoproteins, where small molecules and oligosaccharide modifications occur on the polyamide backbone of the protein. The simplest theoretical models for polymers are ideal chains, Polymers are of two types, Natural polymeric materials such as shellac, amber, wool, silk and natural rubber have been used for centuries. A variety of natural polymers exist, such as cellulose. Most commonly, the continuously linked backbone of a used for the preparation of plastics consists mainly of carbon atoms. A simple example is polyethylene, whose repeating unit is based on ethylene monomer, however, other structures do exist, for example, elements such as silicon form familiar materials such as silicones, examples being Silly Putty and waterproof plumbing sealant. Oxygen is also present in polymer backbones, such as those of polyethylene glycol, polysaccharides. Polymerization is the process of combining many small molecules known as monomers into a covalently bonded chain or network, during the polymerization process, some chemical groups may be lost from each monomer. This is the case, for example, in the polymerization of PET polyester, the distinct piece of each monomer that is incorporated into the polymer is known as a repeat unit or monomer residue. Laboratory synthetic methods are divided into two categories, step-growth polymerization and chain-growth polymerization. However, some methods such as plasma polymerization do not fit neatly into either category
8.
Poly(methyl methacrylate)
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The same material can be utilised as a casting resin, in inks and coatings, and has many other uses. Chemically, it is the polymer of methyl methacrylate. PMMA is an alternative to polycarbonate when extreme strength is not necessary. Additionally, PMMA does not contain the potentially harmful bisphenol-A subunits found in polycarbonate and it is often preferred because of its moderate properties, easy handling and processing, and low cost. The first acrylic acid was created in 1843, methacrylic acid, derived from acrylic acid, was formulated in 1865. The reaction between acid and methanol results in the ester methyl methacrylate. In 1877 the German chemist Wilhelm Rudolph Fittig discovered the process that turns methyl methacrylate into polymethyl methacrylate. In 1933, the brand name Plexiglas was patented and registered by another German chemist, in 1936 Imperial Chemical Industries began the first commercially viable production of acrylic safety glass. During World War II both Allied and Axis forces used acrylic glass for submarine periscopes and aircraft windshields, canopies, common orthographic stylings include polymethyl methacrylate and polymethylmethacrylate. The full chemical name is poly, although often called simply acrylic, acrylic can also refer to other polymers or copolymers containing polyacrylonitrile. The other notable names include, Acrylite, a trademark of Evonik Cyro since 1976 Lucite, a trademark of DuPont, first registered in 1937 R-Cast. Founded in 1987 after spinning off from Reynolds & Taylor and they specialize in large scale and thick monolithic acrylic. Plexiglas, a trademark of ELF Atochem, now a subsidiary of Arkema in the US, generally, radical initiation is used, but anionic polymerization of PMMA can also be performed. To produce 1 kg of PMMA, about 2 kg of petroleum is needed, PMMA produced by radical polymerization is atactic and completely amorphous. The glass transition temperature of atactic PMMA is 105 °C, PMMA is thus an organic glass at room temperature, i. e. it is below its Tg. The forming temperature starts at the transition temperature and goes up from there. All common molding processes may be used, including molding, compression molding. The highest quality PMMA sheets are produced by casting, but in this case
