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Coordination polymer
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A coordination polymer is an inorganic or organometallic polymer structure containing metal cation centers linked by ligands. More formally a coordination polymer is a coordination compound with repea
Figure 3. Three coordination polymers of different dimensionality. All three were made using the same ligand (4,5-dihydroxybenzene-1,3-disulfonate (L)
Figure 3. Three coordination polymers of different dimensionality. All three were made using the same ligand (4,5-dihydroxybenzene-1,3-disulfonate (L)), but different metal cations. All of the metals come from Group 2 on the periodic table (alkaline earth metals) and in this case, dimensionality increases with cation size and polarizability. A. [Ca(L)(H2O)4]•H2O B. [Sr(L)(H2O)4]•H2O C.[Ba(L)(H2O)]•H2O In each case, the metal is represented in green.
The addition and removal of guest molecules can have a large effect on the resulting structure of a coordination polymer. A few examples are (top) cha
The addition and removal of guest molecules can have a large effect on the resulting structure of a coordination polymer. A few examples are (top) change of a linear 1D chain to a zigzag pattern, (middle) staggered 2D sheets to stacked, and (bottom) 3D cubes become more widely spaced.
Organometallic chemistry
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Organometallic chemistry is the study of organometallic compounds, chemical compounds containing at least one chemical bond between a carbon atom of an organic molecule and a metal, including alkali,
Coordination polymer
…A coordination polymer is an inorganic or organometallic polymer structure containing metal cation centers linked by ligands. More formally a coordination polymer is a coordination compound with repeating…
A steel bottle containing MgCp2 (magnesium bis-cyclopentadienyl), which, like several other organometallic compounds, is pyrophoric in air.
A steel bottle containing MgCp2 (magnesium bis-cyclopentadienyl), which, like several other organometallic compounds, is pyrophoric in air.
a single crystal of a Mn(II) complex, [BnMIm]4[MnBr4]Br2. Its bright green color originates from spin-forbidden d-d transitions
a single crystal of a Mn(II) complex, [BnMIm]4[MnBr4]Br2. Its bright green color originates from spin-forbidden d-d transitions