1.
Dye
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A dye is a colored substance that has an affinity to the substrate to which it is being applied. The dye is applied in an aqueous solution, and may require a mordant to improve the fastness of the dye on the fiber. Both dyes and pigments are colored because they absorb some wavelengths of light more than others, in contrast to dyes, pigments are insoluble and have no affinity for the substrate. Some dyes can be precipitated with a salt to produce a lake pigment. The majority of natural dyes are from plant sources, roots, berries, bark, leaves, and wood, fungi, textile dyeing dates back to the Neolithic period. Throughout history, people have dyed their textiles using common, locally available materials, scarce dyestuffs that produced brilliant and permanent colors such as the natural invertebrate dyes Tyrian purple and crimson kermes were highly prized luxury items in the ancient and medieval world. Plant-based dyes such as woad, indigo, saffron, and madder were raised commercially and were important trade goods in the economies of Asia, across Asia and Africa, patterned fabrics were produced using resist dyeing techniques to control the absorption of color in piece-dyed cloth. Dyes from the New World such as cochineal and logwood were brought to Europe by the Spanish treasure fleets, dyed flax fibers have been found in the Republic of Georgia in a prehistoric cave dated to 36,000 BP. Archaeological evidence shows that, particularly in India and Phoenicia, dyeing has been carried out for over 5,000 years. The dyes were obtained from animal, vegetable or mineral origin, by far the greatest source of dyes has been from the plant kingdom, notably roots, berries, bark, leaves and wood, but only a few have ever been used on a commercial scale. The discovery of synthetic dyes late in the 19th century ended the large-scale market for natural dyes. These dyes are made from synthetic resources such as petroleum by-products, the first human-made organic aniline dye, mauveine, was discovered serendipitously by William Henry Perkin in 1856, the result of a failed attempt at the total synthesis of quinine. Other aniline dyes followed, such as fuchsine, safranine, many thousands of synthetic dyes have since been prepared. These may be natural or synthetic, other than pigmentation, they have a range of applications including organic dye lasers, optical media and camera sensors. This is the basic classification Dyes are classified according to their solubility, acid dyes are water-soluble anionic dyes that are applied to fibers such as silk, wool, nylon and modified acrylic fibers using neutral to acid dye baths. Attachment to the fiber is attributed, at least partly, to salt formation between anionic groups in the dyes and cationic groups in the fiber, acid dyes are not substantive to cellulosic fibers. Most synthetic food colors fall in this category, basic dyes are water-soluble cationic dyes that are mainly applied to acrylic fibers, but find some use for wool and silk. Usually acetic acid is added to the dye bath to help the uptake of the dye onto the fiber, basic dyes are also used in the coloration of paper
2.
Death
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Death is the cessation of all biological functions that sustain a living organism. Bodies of living organisms begin to decompose shortly after death, other concerns include fear of death, necrophobia, anxiety, sorrow, grief, emotional pain, depression, sympathy, compassion, solitude, or saudade. The potential for an afterlife is of concern for some humans, the word death comes from Old English deað, which in turn comes from Proto-Germanic *dauthuz. This comes from the Proto-Indo-European stem *dheu- meaning the Process, act, when a person has died, it is also said they have passed away, passed on, expired, or are gone, among numerous other socially accepted, religiously specific, slang, and irreverent terms. Bereft of life, the person is then a corpse, cadaver, a body, a set of remains, and when all flesh has rotted away. The terms carrion and carcass can also be used, though more often connote the remains of non-human animals. As a polite reference to a person, it has become common practice to use the participle form of decease, as in the deceased. The ashes left after a cremation are sometimes referred to by the neologism cremains, senescence refers to a scenario when a living being is able to survive all calamities, but eventually dies due to causes relating to old age. Almost all animals who survive external hazards to their biological functioning eventually die from biological aging, some organisms experience negligible senescence, even exhibiting biological immortality. These include the jellyfish Turritopsis dohrnii, the hydra, and the planarian, unnatural causes of death include suicide and homicide. From all causes, roughly 150,000 people die around the world each day, physiological death is now seen as a process, more than an event, conditions once considered indicative of death are now reversible. Where in the process a dividing line is drawn between life and death depends on factors beyond the presence or absence of vital signs, in general, clinical death is neither necessary nor sufficient for a determination of legal death. A patient with working heart and lungs determined to be dead can be pronounced legally dead without clinical death occurring. As scientific knowledge and medicine advance, formulating a precise definition of death becomes more difficult. The concept of death is a key to understanding of the phenomenon. There are many approaches to the concept. For example, brain death, as practiced in medical science, One of the challenges in defining death is in distinguishing it from life. As a point in time, death would seem to refer to the moment at which life ends, determining when death has occurred requires drawing precise conceptual boundaries between life and death
3.
Goa
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Goa /ˈɡoʊ. ə/ is a state in India within the coastal region known as the Konkan in western India. It is bounded by Maharashtra to the north and Karnataka to the east and it is Indias smallest state by area and the fourth smallest by population. Goa is Indias richest state, with a GDP per capita two and a half times that of the country, Panaji is the states capital, while Vasco da Gama is its largest city. The historic city of Margao still exhibits the influence of the Portuguese. Goa is a former Portuguese province, the Portuguese overseas territory of Portuguese India existed for about 450 years until it was annexed by India in 1961. Goa is visited by large numbers of international and domestic tourists each year for its beaches, places of worship and it has rich flora and fauna, owing to its location on the Western Ghats range, a biodiversity hotspot. In ancient literature, Goa was known by names, such as Gomanchala, Gopakapattana, Gopakapattam, Gopakapuri, Govapuri, Govem. In the 3rd century BC, Goa was known as Aparantha and is mentioned by the Greek geographer Ptolemy, in the 13th century, the Greeks referred to Goa as Nelkinda. Other historical names for Goa are Sindapur, Sandabur, and Mahassapatam, Goas history goes back 20, 000–30,000 years. The rock art engravings exhibit the earliest traces of life in India. Upper Paleolithic or Mesolithic rock art engravings have been found on the bank of the river Kushavati at Usgalimal. Petroglyphs, cones, stone-axe, and choppers dating to 10,000 years ago have been found in places in Goa, such as Kazur, Mauxim. Evidence of Palaeolithic life is seen at Dabolim, Adkon, Shigao, Fatorpa, Arli, Maulinguinim, Diwar, Sanguem, Pilerne, difficulty in carbon dating the laterite rock compounds poses a problem for determining the exact time period. Early Goan society underwent radical change when Indo-Aryan and Dravidian migrants amalgamated with the aboriginal locals, in the 3rd century BC, Goa was part of the Maurya Empire, ruled by the Buddhist emperor, Ashoka of Magadha. Buddhist monks laid the foundation of Buddhism in Goa, between the 2nd century BC and the 6th century AD, Goa was ruled by the Bhojas of Goa. The rule later passed to the Chalukyas of Badami, who controlled it between 578 and 753, and later the Rashtrakutas of Malkhed from 753 to 963, from 765 to 1015, the Southern Silharas of Konkan ruled Goa as the feudatories of the Chalukyas and the Rashtrakutas. Over the next few centuries, Goa was successively ruled by the Kadambas as the feudatories of the Chalukyas of Kalyani, in 1312, Goa came under the governance of the Delhi Sultanate. The kingdoms grip on the region was weak, and by 1370 it was forced to surrender it to Harihara I of the Vijayanagara empire, the Vijayanagara monarchs held on to the territory until 1469, when it was appropriated by the Bahmani sultans of Gulbarga
4.
India
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India, officially the Republic of India, is a country in South Asia. It is the seventh-largest country by area, the second-most populous country, and it is bounded by the Indian Ocean on the south, the Arabian Sea on the southwest, and the Bay of Bengal on the southeast. It shares land borders with Pakistan to the west, China, Nepal, and Bhutan to the northeast, in the Indian Ocean, India is in the vicinity of Sri Lanka and the Maldives. Indias Andaman and Nicobar Islands share a border with Thailand. The Indian subcontinent was home to the urban Indus Valley Civilisation of the 3rd millennium BCE, in the following millennium, the oldest scriptures associated with Hinduism began to be composed. Social stratification, based on caste, emerged in the first millennium BCE, early political consolidations took place under the Maurya and Gupta empires, the later peninsular Middle Kingdoms influenced cultures as far as southeast Asia. In the medieval era, Judaism, Zoroastrianism, Christianity, and Islam arrived, much of the north fell to the Delhi sultanate, the south was united under the Vijayanagara Empire. The economy expanded in the 17th century in the Mughal empire, in the mid-18th century, the subcontinent came under British East India Company rule, and in the mid-19th under British crown rule. A nationalist movement emerged in the late 19th century, which later, under Mahatma Gandhi, was noted for nonviolent resistance, in 2015, the Indian economy was the worlds seventh largest by nominal GDP and third largest by purchasing power parity. Following market-based economic reforms in 1991, India became one of the major economies and is considered a newly industrialised country. However, it continues to face the challenges of poverty, corruption, malnutrition, a nuclear weapons state and regional power, it has the third largest standing army in the world and ranks sixth in military expenditure among nations. India is a constitutional republic governed under a parliamentary system. It is a pluralistic, multilingual and multi-ethnic society and is home to a diversity of wildlife in a variety of protected habitats. The name India is derived from Indus, which originates from the Old Persian word Hindu, the latter term stems from the Sanskrit word Sindhu, which was the historical local appellation for the Indus River. The ancient Greeks referred to the Indians as Indoi, which translates as The people of the Indus, the geographical term Bharat, which is recognised by the Constitution of India as an official name for the country, is used by many Indian languages in its variations. Scholars believe it to be named after the Vedic tribe of Bharatas in the second millennium B. C. E and it is also traditionally associated with the rule of the legendary emperor Bharata. Gaṇarājya is the Sanskrit/Hindi term for republic dating back to the ancient times, hindustan is a Persian name for India dating back to the 3rd century B. C. E. It was introduced into India by the Mughals and widely used since then and its meaning varied, referring to a region that encompassed northern India and Pakistan or India in its entirety
5.
Textile
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A textile or cloth is a flexible material consisting of a network of natural or artificial fibres. Yarn is produced by spinning raw fibres of wool, flax, cotton, hemp, Textiles are formed by weaving, knitting, crocheting, knotting, or felting. The words fabric and cloth are used in textile assembly trades as synonyms for textile, however, there are subtle differences in these terms in specialized usage. Textile refers to any material made of interlacing fibres, a fabric is a material made through weaving, knitting, spreading, crocheting, or bonding that may be used in production of further goods. Cloth may be used synonymously with fabric but is often a piece of fabric used for a specific purpose. The word textile is from Latin, from the adjective textilis, meaning woven, from textus, the word cloth derives from the Old English clað, meaning a cloth, woven or felted material to wrap around one, from Proto-Germanic kalithaz. The discovery of dyed flax fibres in a cave in the Republic of Georgia dated to 34,000 BCE suggests textile-like materials were made even in prehistoric times. The production of textiles is a craft whose speed and scale of production has been altered almost beyond recognition by industrialization, however, for the main types of textiles, plain weave, twill, or satin weave, there is little difference between the ancient and modern methods. Textiles have an assortment of uses, the most common of which are for clothing and for such as bags. In the household they are used in carpeting, upholstered furnishings, window shades, towels, coverings for tables, beds, and other flat surfaces, in the workplace they are used in industrial and scientific processes such as filtering. Textiles are used in traditional crafts such as sewing, quilting. Textiles for industrial purposes, and chosen for other than their appearance, are commonly referred to as technical textiles. Technical textiles include textile structures for applications, medical textiles, geotextiles, agrotextiles. In all these applications stringent performance requirements must be met, woven of threads coated with zinc oxide nanowires, laboratory fabric has been shown capable of self-powering nanosystems using vibrations created by everyday actions like wind or body movements. Fashion designers commonly rely on textile designs to set their fashion collections apart from others, armani, the late Gianni Versace, and Emilio Pucci can be easily recognized by their signature print driven designs. Textiles can be made from many materials and these materials come from four main sources, animal, plant, mineral, and synthetic. In the past, all textiles were made from natural fibres, including plant, animal, in the 20th century, these were supplemented by artificial fibres made from petroleum. Textiles are made in various strengths and degrees of durability, from the finest gossamer to the sturdiest canvas, microfibre refers to fibres made of strands thinner than one denier
6.
Fiber
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Fiber or fibre is a natural or synthetic substance that is significantly longer than it is wide. Fibers are often used in the manufacture of other materials, the strongest engineering materials often incorporate fibers, for example carbon fiber and ultra-high-molecular-weight polyethylene. Natural fibers develop or occur in the shape, and include those produced by plants, animals. Plant fibers are employed in the manufacture of paper and textile, wood fiber, distinguished from vegetable fiber, is from tree sources. Forms include groundwood, lacebark, thermomechanical pulp, and bleached or unbleached kraft or sulfite pulps, animal fibers consist largely of particular proteins. Instances are silkworm silk, spider silk, sinew, catgut, wool, sea silk and hair such as wool, mohair and angora, fur such as sheepskin, rabbit, mink, fox, beaver. Mineral fibers include the asbestos group, asbestos is the only naturally occurring long mineral fiber. Six minerals have been classified as asbestos including chrysotile of the serpentine class, short, fiber-like minerals include wollastonite and palygorskite. Instances are collagen family of proteins, tendon, muscle proteins like actin, cell proteins like microtubules and many others, spider silk, sinew, man-made or chemical fibers are fibers whose chemical composition, structure, and properties are significantly modified during the manufacturing process. Man-made fibers consist of regenerated fibers and synthetic fibers, the earliest semi-synthetic fiber is the cellulose regenerated fiber, rayon. Most semi-synthetic fibers are cellulose regenerated fibers, cellulose fibers are a subset of man-made fibers, regenerated from natural cellulose. The cellulose comes from sources, rayon from tree wood fiber, Modal from beech trees, bamboo fiber from bamboo, seacell from seaweed. In the production of fibers, the cellulose is reduced to a fairly pure form as a viscous mass. Therefore, the process leaves few characteristics distinctive of the natural source material in the finished products. Some examples are, rayon bamboo fiber Lyocell, a brand of rayon Modal, historically, cellulose diacetate and -triacetate were classified under the term rayon, but are now considered distinct materials. Synthetic come entirely from materials such as petrochemicals, unlike those man-made fibers derived from such natural substances as cellulose or protein. Metallic fibers can be drawn from ductile metals such as copper, gold or silver and extruded or deposited from more brittle ones, such as nickel, carbon fibers are often based on oxydized and via pyrolysis carbonized polymers like PAN, but the end product is almost pure carbon. Silicon carbide fibers, where the polymers are not hydrocarbons but polymers
7.
Yarn
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Yarn is a long continuous length of interlocked fibres, suitable for use in the production of textiles, sewing, crocheting, knitting, weaving, embroidery, and ropemaking. Thread is a type of yarn intended for sewing by hand or machine, modern manufactured sewing threads may be finished with wax or other lubricants to withstand the stresses involved in sewing. Embroidery threads are yarns specifically designed for hand or machine embroidery, the word yarn comes from Middle English, from the Old English gearn, akin to Old High Germans garn yarn, Greeks chordē string, and Sanskrits hira band. Yarn can be made from a number of natural or synthetic fibers, many types of yarn are made differently though. There are two types of yarn, spun and filament. The most common plant fiber is cotton, which is spun into fine yarn for mechanical weaving or knitting into cloth. Cotton and polyester are the most commonly spun fibers in the world, cotton is grown throughout the world, harvested, ginned, and prepared for yarn spinning. Polyester is extruded from polymers derived from gas and oil. Synthetic fibers are generally extruded in continuous strands of gel-state materials and these strands are drawn, annealed, and cured to obtain properties desirable for later processing. Synthetic fibers come in three forms, staple, tow, and filament. Staple is cut fibers, generally sold in lengths up to 120mm, tow is a continuous rope of fibers consisting of many filaments loosely joined side-to-side. Filament is a continuous strand consisting of anything from 1 filament to many, synthetic fiber is most often measured in a weight per linear measurement basis, along with cut length. Denier and Dtex are the most common weight to length measures, cut-length only applies to staple fiber. Filament extrusion is sometimes referred to as spinning but most people equate spinning with spun yarn production, the most commonly spun animal fiber is wool harvested from sheep. For hand knitting and hobby knitting, thick, wool and acrylic yarns are frequently used, other animal fibers used include alpaca, angora, mohair, llama, cashmere, and silk. More rarely, yarn may be spun from camel, yak, possum, musk ox, cat, dog, wolf, rabbit, or buffalo hair, and even turkey or ostrich feathers. Natural fibers such as these have the advantage of being slightly elastic and very breathable, while trapping a great deal of air, other natural fibers that can be used for yarn include linen and cotton. These tend to be much less elastic, and retain less warmth than the animal-hair yarns, the finished product will also look rather different from the woollen yarns
8.
Solution
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In chemistry, a solution is a homogeneous mixture composed of two or more substances. In such a mixture, a solute is a substance dissolved in another substance, the mixing process of a solution happens at a scale where the effects of chemical polarity are involved, resulting in interactions that are specific to solvation. The solution assumes the characteristics of the solvent when the solvent is the fraction of the mixture. The concentration of a solute in a solution is the mass of that solute expressed as a percentage of the mass of the whole solution, a solution is a homogeneous mixture of two or more substances. The particles of solute in a solution cannot be seen by the naked eye, a solution does not allow beams of light to scatter. The solute from a solution cannot be separated by filtration and it is composed of only one phase. Homogeneous means that the components of the form a single phase. Heterogeneous means that the components of the mixture are of different phase, the properties of the mixture can be uniformly distributed through the volume but only in absence of diffusion phenomena or after their completion. Usually, the present in the greatest amount is considered the solvent. Solvents can be gases, liquids or solids, one or more components present in the solution other than the solvent are called solutes. The solution has the physical state as the solvent. If the solvent is a gas, only gases are dissolved under a set of conditions. An example of a solution is air. Since interactions between molecules play almost no role, dilute gases form rather trivial solutions, in part of the literature, they are not even classified as solutions, but addressed as mixtures. If the solvent is a liquid, then almost all gases, liquids, here are some examples, Gas in liquid, Oxygen in water Carbon dioxide in water – a less simple example, because the solution is accompanied by a chemical reaction. Liquid in liquid, The mixing of two or more substances of the same chemistry but different concentrations to form a constant, alcoholic beverages are basically solutions of ethanol in water. Solid in liquid, Sucrose in water Sodium chloride or any other salt in water, solutions in water are especially common. Counterexamples are provided by liquid mixtures that are not homogeneous, colloids, body fluids are examples for complex liquid solutions, containing many solutes
9.
Molecule
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A molecule is an electrically neutral group of two or more atoms held together by chemical bonds. Molecules are distinguished from ions by their lack of electrical charge, however, in quantum physics, organic chemistry, and biochemistry, the term molecule is often used less strictly, also being applied to polyatomic ions. In the kinetic theory of gases, the molecule is often used for any gaseous particle regardless of its composition. According to this definition, noble gas atoms are considered molecules as they are in fact monoatomic molecules. A molecule may be homonuclear, that is, it consists of atoms of one element, as with oxygen, or it may be heteronuclear. Atoms and complexes connected by non-covalent interactions, such as hydrogen bonds or ionic bonds, are not considered single molecules. Molecules as components of matter are common in organic substances and they also make up most of the oceans and atmosphere. Also, no typical molecule can be defined for ionic crystals and covalent crystals, the theme of repeated unit-cellular-structure also holds for most condensed phases with metallic bonding, which means that solid metals are also not made of molecules. In glasses, atoms may also be together by chemical bonds with no presence of any definable molecule. The science of molecules is called molecular chemistry or molecular physics, in practice, however, this distinction is vague. In molecular sciences, a molecule consists of a system composed of two or more atoms. Polyatomic ions may sometimes be thought of as electrically charged molecules. The term unstable molecule is used for very reactive species, i. e, according to Merriam-Webster and the Online Etymology Dictionary, the word molecule derives from the Latin moles or small unit of mass. Molecule – extremely minute particle, from French molécule, from New Latin molecula, diminutive of Latin moles mass, a vague meaning at first, the vogue for the word can be traced to the philosophy of Descartes. The definition of the molecule has evolved as knowledge of the structure of molecules has increased, earlier definitions were less precise, defining molecules as the smallest particles of pure chemical substances that still retain their composition and chemical properties. Molecules are held together by covalent bonding or ionic bonding. Several types of non-metal elements exist only as molecules in the environment, for example, hydrogen only exists as hydrogen molecule. A molecule of a compound is made out of two or more elements, a covalent bond is a chemical bond that involves the sharing of electron pairs between atoms
10.
Chemical bond
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A chemical bond is a lasting attraction between atoms that enables the formation of chemical compounds. The bond may result from the force of attraction between atoms with opposite charges, or through the sharing of electrons as in the covalent bonds. Since opposite charges attract via an electromagnetic force, the negatively charged electrons that are orbiting the nucleus. An electron positioned between two nuclei will be attracted to both of them, and the nuclei will be attracted toward electrons in this position and this attraction constitutes the chemical bond. This phenomenon limits the distance between nuclei and atoms in a bond, in general, strong chemical bonding is associated with the sharing or transfer of electrons between the participating atoms. All bonds can be explained by quantum theory, but, in practice, simplification rules allow chemists to predict the strength, directionality, the octet rule and VSEPR theory are two examples. Electrostatics are used to describe bond polarities and the effects they have on chemical substances, a chemical bond is an attraction between atoms. This attraction may be seen as the result of different behaviors of the outermost or valence electrons of atoms and these behaviors merge into each other seamlessly in various circumstances, so that there is no clear line to be drawn between them. However it remains useful and customary to differentiate different types of bond, which result in different properties of condensed matter. In the simplest view of a covalent bond, one or more electrons are drawn into the space between the two atomic nuclei, energy is released by bond formation. This is not as a reduction in energy, because the attraction of the two electrons to the two protons is offset by the electron-electron and proton-proton repulsions. In a polar covalent bond, one or more electrons are shared between two nuclei. Such weak intermolecular bonds give organic molecular substances, such as waxes and oils, their soft bulk character, also, the melting points of such covalent polymers and networks increase greatly. In a simplified view of a bond, the bonding electron is not shared at all. In this type of bond, the atomic orbital of one atom has a vacancy which allows the addition of one or more electrons. These newly added electrons potentially occupy a lower energy-state than they experience in a different atom, thus, one nucleus offers a more tightly bound position to an electron than does another nucleus, with the result that one atom may transfer an electron to the other. This transfer causes one atom to assume a net charge. The bond then results from electrostatic attraction between atoms and the atoms become positive or negatively charged ions, ionic bonds may be seen as extreme examples of polarization in covalent bonds
11.
Temperature
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A temperature is an objective comparative measurement of hot or cold. It is measured by a thermometer, several scales and units exist for measuring temperature, the most common being Celsius, Fahrenheit, and, especially in science, Kelvin. Absolute zero is denoted as 0 K on the Kelvin scale, −273.15 °C on the Celsius scale, the kinetic theory offers a valuable but limited account of the behavior of the materials of macroscopic bodies, especially of fluids. Temperature is important in all fields of science including physics, geology, chemistry, atmospheric sciences, medicine. The Celsius scale is used for temperature measurements in most of the world. Because of the 100 degree interval, it is called a centigrade scale.15, the United States commonly uses the Fahrenheit scale, on which water freezes at 32°F and boils at 212°F at sea-level atmospheric pressure. Many scientific measurements use the Kelvin temperature scale, named in honor of the Scottish physicist who first defined it and it is a thermodynamic or absolute temperature scale. Its zero point, 0K, is defined to coincide with the coldest physically-possible temperature and its degrees are defined through thermodynamics. The temperature of zero occurs at 0K = −273. 15°C. For historical reasons, the triple point temperature of water is fixed at 273.16 units of the measurement increment, Temperature is one of the principal quantities in the study of thermodynamics. There is a variety of kinds of temperature scale and it may be convenient to classify them as empirically and theoretically based. Empirical temperature scales are historically older, while theoretically based scales arose in the middle of the nineteenth century, empirically based temperature scales rely directly on measurements of simple physical properties of materials. For example, the length of a column of mercury, confined in a capillary tube, is dependent largely on temperature. Such scales are only within convenient ranges of temperature. For example, above the point of mercury, a mercury-in-glass thermometer is impracticable. A material is of no use as a thermometer near one of its phase-change temperatures, in spite of these restrictions, most generally used practical thermometers are of the empirically based kind. Especially, it was used for calorimetry, which contributed greatly to the discovery of thermodynamics, nevertheless, empirical thermometry has serious drawbacks when judged as a basis for theoretical physics. Theoretically based temperature scales are based directly on theoretical arguments, especially those of thermodynamics, kinetic theory and they rely on theoretical properties of idealized devices and materials
12.
Natural dye
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Natural dyes are dyes or colorants derived from plants, invertebrates, or minerals. The majority of natural dyes are vegetable dyes from plant sources—roots, berries, bark, leaves, archaeologists have found evidence of textile dyeing dating back to the Neolithic period. In China, dyeing with plants, barks and insects has been traced more than 5,000 years. The essential process of dyeing changed little over time, typically, the dye material is put in a pot of water and then the textiles to be dyed are added to the pot, which is heated and stirred until the color is transferred. Textile fibre may be dyed before spinning, but most textiles are yarn-dyed or piece-dyed after weaving, many mordants, and some dyes themselves, produce strong odors, and large-scale dyeworks were often isolated in their own districts. Plant-based dyes such as woad, indigo, saffron, and madder were raised commercially and were important trade goods in the economies of Asia, across Asia and Africa, patterned fabrics were produced using resist dyeing techniques to control the absorption of color in piece-dyed cloth. Dyes such as cochineal and logwood were brought to Europe by the Spanish treasure fleets, the discovery of man-made synthetic dyes in the mid-19th century triggered a long decline in the large-scale market for natural dyes. Natural dyeing techniques are preserved by artisans in traditional cultures around the world. In the early 21st century, the market for natural dyes in the industry is experiencing a resurgence. Western consumers have become concerned about the health and environmental impact of synthetic dyes in manufacturing. The European Union, for example, has encouraged Indonesian batik cloth producers to switch to natural dyes to improve their market in Europe. Protein fibres require vat, acid, or indirect/mordant dyes, that require a bonding agent, each synthetic fibre requires its own dyeing method, for example, nylon requires acid, disperse and pigment dyes, rayon acetate requires disperse dyes, and so on. The earliest surviving evidence of textile dyeing was found at the large Neolithic settlement at Çatalhöyük in southern Anatolia, polychrome or multicolored fabrics seem to have been developed in the 3rd or 2nd millennium BCE. Textiles with a warp and an ochre-yellow weft were discovered in Egyptian pyramids of the Sixth Dynasty. His contributions to refining the process and his theories on colour brought much praise by the well known poet. Some dyestuffs, such as indigo and lichens, will give good color when used alone, the majority of plant dyes, however, also require the use of a mordant, a chemical used to fix the color in the textile fibres. These dyes are called adjective dyes, by using different mordants, dyers can often obtain a variety of colors and shades from the same dye. Fibres or cloth may be pretreated with mordants, or the mordant may be incorporated in the dyebath, salt helps to fix or increase fastness of colors, vinegar improves reds and purples, and the ammonia in stale urine assists in the fermentation of indigo dyes
13.
Nature
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Nature, in the broadest sense, is the natural, physical, or material world or universe. Nature can refer to the phenomena of the world. The study of nature is a part of science. Although humans are part of nature, human activity is understood as a separate category from other natural phenomena. The word nature is derived from the Latin word natura, or essential qualities, innate disposition, and in ancient times, literally meant birth. Natura is a Latin translation of the Greek word physis, which related to the intrinsic characteristics that plants, animals. This usage continued during the advent of scientific method in the last several centuries. Within the various uses of the word today, nature often refers to geology, for example, manufactured objects and human interaction generally are not considered part of nature, unless qualified as, for example, human nature or the whole of nature. Depending on the context, the term natural might also be distinguished from the unnatural or the supernatural. Earth is the planet known to support life, and its natural features are the subject of many fields of scientific research. Within the solar system, it is third closest to the sun, it is the largest terrestrial planet and its most prominent climatic features are its two large polar regions, two relatively narrow temperate zones, and a wide equatorial tropical to subtropical region. Precipitation varies widely with location, from several metres of water per year to less than a millimetre,71 percent of the Earths surface is covered by salt-water oceans. The remainder consists of continents and islands, with most of the land in the Northern Hemisphere. Earth has evolved through geological and biological processes that have left traces of the original conditions, the outer surface is divided into several gradually migrating tectonic plates. The interior remains active, with a layer of plastic mantle. This iron core is composed of a solid phase. Convective motion in the core generates electric currents through dynamo action, the atmospheric conditions have been significantly altered from the original conditions by the presence of life-forms, which create an ecological balance that stabilizes the surface conditions. Geology is the science and study of the solid and liquid matter that constitutes the Earth, the geology of an area evolves through time as rock units are deposited and inserted and deformational processes change their shapes and locations
14.
Animal
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Animals are multicellular, eukaryotic organisms of the kingdom Animalia. The animal kingdom emerged as a clade within Apoikozoa as the group to the choanoflagellates. Animals are motile, meaning they can move spontaneously and independently at some point in their lives and their body plan eventually becomes fixed as they develop, although some undergo a process of metamorphosis later in their lives. All animals are heterotrophs, they must ingest other organisms or their products for sustenance, most known animal phyla appeared in the fossil record as marine species during the Cambrian explosion, about 542 million years ago. Animals can be divided broadly into vertebrates and invertebrates, vertebrates have a backbone or spine, and amount to less than five percent of all described animal species. They include fish, amphibians, reptiles, birds and mammals, the remaining animals are the invertebrates, which lack a backbone. These include molluscs, arthropods, annelids, nematodes, flatworms, cnidarians, ctenophores, the study of animals is called zoology. The word animal comes from the Latin animalis, meaning having breath, the biological definition of the word refers to all members of the kingdom Animalia, encompassing creatures as diverse as sponges, jellyfish, insects, and humans. Aristotle divided the world between animals and plants, and this was followed by Carl Linnaeus, in the first hierarchical classification. In Linnaeuss original scheme, the animals were one of three kingdoms, divided into the classes of Vermes, Insecta, Pisces, Amphibia, Aves, and Mammalia. Since then the last four have all been subsumed into a single phylum, in 1874, Ernst Haeckel divided the animal kingdom into two subkingdoms, Metazoa and Protozoa. The protozoa were later moved to the kingdom Protista, leaving only the metazoa, thus Metazoa is now considered a synonym of Animalia. Animals have several characteristics that set apart from other living things. Animals are eukaryotic and multicellular, which separates them from bacteria and they are heterotrophic, generally digesting food in an internal chamber, which separates them from plants and algae. They are also distinguished from plants, algae, and fungi by lacking cell walls. All animals are motile, if only at life stages. In most animals, embryos pass through a stage, which is a characteristic exclusive to animals. With a few exceptions, most notably the sponges and Placozoa and these include muscles, which are able to contract and control locomotion, and nerve tissues, which send and process signals
15.
Plant
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Plants are mainly multicellular, predominantly photosynthetic eukaryotes of the kingdom Plantae. The term is generally limited to the green plants, which form an unranked clade Viridiplantae. This includes the plants, conifers and other gymnosperms, ferns, clubmosses, hornworts, liverworts, mosses and the green algae. Green plants have cell walls containing cellulose and obtain most of their energy from sunlight via photosynthesis by primary chloroplasts and their chloroplasts contain chlorophylls a and b, which gives them their green color. Some plants are parasitic and have lost the ability to produce amounts of chlorophyll or to photosynthesize. Plants are characterized by sexual reproduction and alternation of generations, although reproduction is also common. There are about 300–315 thousand species of plants, of which the great majority, green plants provide most of the worlds molecular oxygen and are the basis of most of Earths ecologies, especially on land. Plants that produce grains, fruits and vegetables form humankinds basic foodstuffs, Plants play many roles in culture. They are used as ornaments and, until recently and in variety, they have served as the source of most medicines. The scientific study of plants is known as botany, a branch of biology, Plants are one of the two groups into which all living things were traditionally divided, the other is animals. The division goes back at least as far as Aristotle, who distinguished between plants, which generally do not move, and animals, which often are mobile to catch their food. Much later, when Linnaeus created the basis of the system of scientific classification. Since then, it has become clear that the plant kingdom as originally defined included several unrelated groups, however, these organisms are still often considered plants, particularly in popular contexts. When the name Plantae or plant is applied to a group of organisms or taxon. The evolutionary history of plants is not yet settled. Those which have been called plants are in bold, the way in which the groups of green algae are combined and named varies considerably between authors. Algae comprise several different groups of organisms which produce energy through photosynthesis, most conspicuous among the algae are the seaweeds, multicellular algae that may roughly resemble land plants, but are classified among the brown, red and green algae. Each of these groups also includes various microscopic and single-celled organisms
16.
Acrylic fiber
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Acrylic fibers are synthetic fibers made from a polymer with an average molecular weight of ~100,000, about 1900 monomer units. For a fiber to be called acrylic in the US, the polymer must contain at least 85% acrylonitrile monomer, typical comonomers are vinyl acetate or methyl acrylate. DuPont created the first acrylic fibers in 1941 and trademarked them under the name Orlon and it was first developed in the mid-1940s but was not produced in large quantities until the 1950s. Strong and warm, acrylic fiber is used for sweaters and tracksuits and as linings for boots and gloves, as well as in furnishing fabrics. It is manufactured as a filament, then cut into short staple lengths similar to wool hairs, modacrylic is a modified acrylic fiber that contains at least 35% and at most 85% acrylonitrile monomer. The comonomers vinyl chloride, vinylidene chloride or vinyl bromide used in modacrylic give the fiber flame retardant properties, end-uses of modacrylic include faux fur, wigs, hair extensions and protective clothing. The polymer is formed by free-radical polymerization in aqueous suspension, washing, stretching, drying and crimping complete the processing. Acrylic fibers are produced in a range of deniers, typically from 0.9 to 15, end uses include sweaters, hats, hand-knitting yarns, socks, rugs, awnings, boat covers, and upholstery, the fiber is also used as PAN precursor for carbon fiber. Production of acrylic fibers is centered in the Far East, Turkey, India, Mexico, US producers have ended production, though acrylic tow and staple are still spun into yarns in the USA. Former U. S. brands of acrylic included Acrilan, other brand names that are still in use include Dralon and Drytex. Acrylic is lightweight, soft, and warm, with a wool-like feel and it can also be made to mimic other fibers, such as cotton, when spun on short staple equipment. Some acrylic is extruded in colored or pigmented form, other is extruded in ecru, otherwise known as natural, raw white and its fibers are very resilient compared to both other synthetics and natural fibers. Some acrylic is used in clothing as an expensive alternative to cashmere. Some acrylic fabrics may fuzz or pill easily, though there are low-pilling variants, acrylic takes color well, is washable, and is generally hypoallergenic. End-uses include socks, hats, gloves, scarves, sweaters, home furnishing fabrics, acrylic can also be used to make fake fur and to make many different knitted clothes. As acrylic is a fiber, the larvae of clothes moths are unable to digest it. However, acrylic fibers that are blended with wool or soiled may be eaten as a consequence of having blended fibers, the fiber requires heat to relax or set the shape of the finished garment, and it isnt as warm when wet as alternatives like wool. Some hand-knitters also complain that the fiber squeaks when knitted, or that it is painful to knit with because of a lack of give or stretch in the yarn, on the other hand, it is machine-washable and extremely color-fast
17.
Nylon
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Nylon is a generic designation for a family of synthetic polymers, more specifically aliphatic or semi-aromatic polyamides. They can be melt-processed into fibers, films or shapes, the first example of nylon was produced on February 28,1935, by Wallace Carothers at DuPonts research facility at the DuPont Experimental Station. Nylon polymers have significant commercial applications in fibers, in shapes. Nylon is made of repeating units linked by bonds and is a type of polyamide and is frequently referred to as such. Nylon was the first commercially successful synthetic thermoplastic polymer, commercially, nylon polymer is made by reacting monomers which are either lactams, acid/amines or stoichiometric mixtures of diamines and diacids. Mixtures of these can be polymerized together to make copolymers, Nylon polymers can be mixed with a wide variety of additives to achieve many different property variations. Nylon was invented accidentally by Julian W. Hill, a chemist for DuPont under Wallace Carotherss supervision and it was only given this name at the 1939 New York Worlds Fair. The patents were owned by DuPont, Nylon was intended to be a synthetic replacement for silk and substituted for it in many different products after silk became scarce during World War II. It replaced silk in military applications such as parachutes and flak vests, after initial commercialization of nylon as a fiber, applications in the form of shapes and films were also developed. The main market for nylon shapes now is in auto components, in 1940, John W. Eckelberry of DuPont stated that the letters nyl were arbitrary and the on was copied from the suffixes of other fibers such as cotton and rayon. A later publication by DuPont explained that the name was intended to be No-Run. Since the products were not really run-proof, the vowels were swapped to produce nuron, for clarity in pronunciation, the i was changed to y. Most nylons are made from the reaction of an acid with a diamine or a lactam or amino acid with itself. In the first case, the structure is so-called ABAB similar to polyesters and polyurethanes, in the second case, the repeating unit corresponds to the single monomer. It is difficult to get the proportions exactly correct, and deviations can lead to termination at molecular weights less than a desirable 10,000 daltons. To overcome this problem, a crystalline, solid nylon salt can be formed at room temperature, using an exact 1,1 ratio of the acid, the salt is crystallized to purify it and obtain the desired precise stoichiometry. Heated to 285 °C, the salt reacts to form nylon polymer with the production of water, Wallace Carothers at DuPont patented nylon 66, but overlooked the possibility to use lactams. That synthetic route was developed by Paul Schlack at IG Farben, leading to nylon 6, the peptide bond within the caprolactam is broken with the exposed active groups on each side being incorporated into two new bonds as the monomer becomes part of the polymer backbone
18.
Wool
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Wool is the textile fiber obtained from sheep and other animals, including cashmere and mohair from goats, qiviut from muskoxen, angora from rabbits, and other types of wool from camelids. Wool has several qualities that distinguish it from hair or fur, it is crimped, Wool is produced by follicles which are small cells located in the skin. These follicles are located in the layer of the skin called the epidermis. Follicles can be classed as primary or secondary follicles. Primary follicles produce three types of fiber, Kemp, medullated fibers and true wool fibers, secondary follicles only produce true wool fibers. Medullated fibers share nearly identical characteristics to hair and are long but lack crimp, Kemp fibers are very coarse and shed out. Wools scaling and crimp make it easier to spin the fleece by helping the individual fibers attach to each other, because of the crimp, wool fabrics have greater bulk than other textiles, and they hold air, which causes the fabric to retain heat. Wool has a specific heat coefficient, so it impedes heat transfer in general. This effect has benefited desert peoples, as Bedouins and Tuaregs use wool clothes for insulation, felting of wool occurs upon hammering or other mechanical agitation as the microscopic barbs on the surface of wool fibers hook together. The amount of crimp corresponds to the fineness of the wool fibers, a fine wool like Merino may have up to 100 crimps per inch, while coarser wool like karakul may have as few as one or two. In contrast, hair has little if any scale and no crimp, on sheep, the hair part of the fleece is called kemp. Wool fibers readily absorb moisture, but are not hollow, Wool can absorb almost one-third of its own weight in water. Wool absorbs sound like many other fabrics and it is generally a creamy white color, although some breeds of sheep produce natural colors, such as black, brown, silver, and random mixes. Wool ignites at a higher temperature than cotton and some synthetic fibers, Wool carpets are specified for high safety environments, such as trains and aircraft. Wool is usually specified for garments for firefighters, soldiers, Wool is considered by the medical profession to be allergenic. Sheep shearing is the process by which the fleece of a sheep is cut off. After shearing, the wool is separated into four categories, fleece, broken, bellies. In Australia before being auctioned, all Merino fleece wool is objectively measured for micron, yield, staple length, staple strength, the sheep is given a dip in antiseptic solution after shearing, so as to cure the wounds caused during shearing
19.
Silk
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Silk is a natural protein fiber, some forms of which can be woven into textiles. The protein fiber of silk is composed mainly of fibroin and is produced by insect larvae to form cocoons. The best-known silk is obtained from the cocoons of the larvae of the mulberry silkworm Bombyx mori reared in captivity, Silk is produced by several insects, but generally only the silk of moth caterpillars has been used for textile manufacturing. There has been research into other types of silk, which differ at the molecular level. Silk is mainly produced by the larvae of insects undergoing complete metamorphosis, Silk production also occurs in Hymenoptera, silverfish, mayflies, thrips, leafhoppers, beetles, lacewings, fleas, flies, and midges. Other types of arthropod produce silk, most notably various arachnids such as spiders, the word silk comes from Old English sioloc, from Greek σηρικός serikos, silken, ultimately from an Asian source. Several kinds of silk, which are produced by caterpillars other than the mulberry silkworm, have been known and used in China, South Asia. However, the scale of production was far smaller than for cultivated silks. Thus, the way to obtain silk suitable for spinning into textiles in areas where commercial silks are not cultivated was by tedious. Commercial silks originate from reared silkworm pupae, which are bred to produce a silk thread with no mineral on the surface. The pupae are killed by either dipping them in boiling water before the adult moths emerge or by piercing them with a needle. These factors all contribute to the ability of the cocoon to be unravelled as one continuous thread. Wild silks also tend to be difficult to dye than silk from the cultivated silkworm. Genetic modification of domesticated silkworms is used to facilitate the production of more types of silk. Silk fabric was first developed in ancient China, the earliest example of silk fabric is from 3630 BC, and it was used as wrapping for the body of a child from a Yangshao culture site in Qingtaicun at Xingyang, Henan. Legend gives credit for developing silk to a Chinese empress, Leizu, because of its texture and lustre, silk rapidly became a popular luxury fabric in the many areas accessible to Chinese merchants. Silk was in demand, and became a staple of pre-industrial international trade. In July 2007, archaeologists discovered intricately woven and dyed silk textiles in a tomb in Jiangxi province, Silk is described in a chapter on mulberry planting by Si Shengzhi of the Western Han
20.
Acid dye
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An acid dye is a dye which is a salt of a sulfuric, carboxylic or phenolic organic acid. The salts are often sodium or ammonium salts, Acid dyes are typically soluble in water and possess affinity for amphoteric fibers while lacking direct dyes affinity for cellulose fibers. When dyeing, ionic bonding with fiber cationic sites accounts for fixation of colored anions in the dyed material, acids are added to dyeing baths to increase the number of protonated amino-groups in fibers. Some acid dyes are used as food colorants, in the laboratory, home, or art studio, the acid used in the dye-bath is often vinegar or citric acid. The uptake rate of the dye is controlled with the use of sodium chloride, in textiles, acid dyes are effective on protein fibers, i. e. animal hair fibers like wool, alpaca and mohair. They are also effective on silk and they are effective in dyeing the synthetic fiber nylon, but of minimum interest in dyeing any other synthetic fibers. In staining during microscopic examination for diagnosis or research, acid dyes are used to color basic tissue proteins, in contrast, basic dyes are used to stain cell nuclei and some other acidic components of tissues. Acid dyes are generally divided into three classes depend on fastness requirements, level dyeing properties and economy. The classes overlap and generally depend on type of fiber to be colored as well as the process used, Acid dyes affix to fibers by hydrogen bonding, Van der Waals forces and ionic bonding. They are normally sold as the Sodium salt, therefore they are in solution anionic, animal protein fibers and synthetic nylon fibers contain many cationic sites. Therefore, there is an attraction of anionic dye molecule to a site on the fiber. The strength of bond is related to the tendency of the dye to remain dissolved in water over fixation to the fiber. The chemistry of acid dyes is quite complex, dyes are normally very large aromatic molecules consisting of many linked rings. Acid dyes usually have a sulfo or carboxy group on the molecule making them soluble in water, water is the medium in which dyeing takes place. Many blue dyes have this structure as their basic shape, the structure predominates in the leveling class of acid dye. Triphenylmethane related, Acid dyes having structures related to triphenylmethane predominate in the class of dye. There are many yellow and green dyes commercially applied to fibers that are related to triphenylmethane, equalizing/leveling acid dyes, Highest level dyeing properties. Relatively small molecule therefore high migration before fixation, low wet fastness therefore normally not suited for apparel fabric
21.
Polyester
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Polyester is a category of polymers that contain the ester functional group in their main chain. As a specific material, it most commonly refers to a type called polyethylene terephthalate, polyesters include naturally occurring chemicals, such as in the cutin of plant cuticles, as well as synthetics through step-growth polymerization such as polybutyrate. Natural polyesters and a few synthetic ones are biodegradable, but most synthetic polyesters are not and this material is used very widely in clothing. Depending on the structure, polyester can be a thermoplastic or thermoset. There are also polyester resins cured by hardeners, however, the most common polyesters are thermoplastics, industrial polyester fibers, yarns and ropes are used in car tire reinforcements, fabrics for conveyor belts, safety belts, coated fabrics and plastic reinforcements with high-energy absorption. Polyester fiber is used as cushioning and insulating material in pillows, comforters, Polyester fabrics are highly stain-resistant— in fact, the only class of dyes which can be used to alter the color of polyester fabric are what are known as disperse dyes. Polyester fibers are spun together with natural fibers to produce a cloth with blended properties. Cotton-polyester blends can be strong, wrinkle and tear-resistant, and reduce shrinking, synthetic fibers in polyester also create materials with water, wind and environmental resistance compared to plant-derived fibers. Disadvantages of cotton and polyester blends include being less breathable than cotton and they are also less fire resistant and can melt when ignited. Polyester blends have been renamed so as to suggest their similarity or even superiority to natural fibers. Polyesters are also used to make bottles, films, tarpaulin, canoes, liquid crystal displays, holograms, filters, dielectric film for capacitors, film insulation for wire, polyesters are widely used as a finish on high-quality wood products such as guitars, pianos and vehicle/yacht interiors. Thixotropic properties of spray-applicable polyesters make them ideal for use on open-grain timbers, as they can quickly fill wood grain, cured polyesters can be sanded and polished to a high-gloss, durable finish. Liquid crystalline polyesters are among the first industrially used liquid crystal polymers and they are used for their mechanical properties and heat-resistance. These traits are important in their application as an abradable seal in jet engines. Polyesters as thermoplastics may change shape after the application of heat, while combustible at high temperatures, polyesters tend to shrink away from flames and self-extinguish upon ignition. Polyester fibers have high tenacity and E-modulus as well as low water absorption and they are used in the liquid state as casting materials, in sheet molding compounds, as fiberglass laminating resins and in non-metallic auto-body fillers. They are also used as the polymer matrix in pre-pregs. Fiberglass-reinforced unsaturated polyesters find wide application in bodies of yachts and as parts of cars
22.
Cotton
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Cotton is a soft, fluffy staple fiber that grows in a boll, or protective case, around the seeds of the cotton plants of the genus Gossypium in the family of Malvaceae. The fiber is almost pure cellulose, under natural conditions, the cotton bolls will tend to increase the dispersal of the seeds. The plant is a native to tropical and subtropical regions around the world, including the Americas, Africa. The greatest diversity of wild species is found in Mexico, followed by Australia. Cotton was independently domesticated in the Old and New Worlds, the fiber is most often spun into yarn or thread and used to make a soft, breathable textile. Current estimates for world production are about 25 million tonnes or 110 million bales annually, China is the worlds largest producer of cotton, but most of this is used domestically. The United States has been the largest exporter for many years, in the United States, cotton is usually measured in bales, which measure approximately 0.48 cubic meters and weigh 226.8 kilograms. Cotton cultivation in the region is dated to the Indus Valley Civilization, the Indus cotton industry was well-developed and some methods used in cotton spinning and fabrication continued to be used until the industrialization of India. Between 2000 and 1000 BC cotton became widespread across much of India, for example, it has been found at the site of Hallus in Karnataka dating from around 1000 BC. Cotton fabrics discovered in a cave near Tehuacán, Mexico have been dated to around 5800 BC, the domestication of Gossypium hirsutum in Mexico is dated between 3400 and 2300 BC. Cotton was grown upriver, made into nets, and traded with fishing villages along the coast for supplies of fish. The Spanish who came to Mexico and Peru in the early 16th century found the people growing cotton and this may be a reference to tree cotton, Gossypium arboreum, which is a native of the Indian subcontinent. According to the Columbia Encyclopedia, Cotton has been spun, woven and it clothed the people of ancient India, Egypt, and China. Hundreds of years before the Christian era, cotton textiles were woven in India with matchless skill, in Iran, the history of cotton dates back to the Achaemenid era, however, there are few sources about the planting of cotton in pre-Islamic Iran. The planting of cotton was common in Merv, Ray and Pars of Iran, in Persian poets poems, especially Ferdowsis Shahname, there are references to cotton. Marco Polo refers to the products of Persia, including cotton. John Chardin, a French traveler of the 17th century who visited the Safavid Persia, during the Han dynasty, cotton was grown by Chinese peoples in the southern Chinese province of Yunnan. Mohamed Ali Pasha accepted the proposition and granted himself the monopoly on the sale and export of cotton in Egypt, and later dictated cotton should be grown in preference to other crops
23.
Vat dye
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Vat dyes are a class of dyes that are classified as such because of the method by which they are applied. Vat dyeing is a process refers to dyeing that takes place in a bucket or vat. Almost any dye, including dyes, direct dyes, and acid dyes. Cotton, wool, and other fibers can be all dyed with vat dyes, the original vat dye is indigo, once obtained from plants but now produced synthetically. Although almost all dyeing can be done in a vat, the term vat dye is used to describe a class of dyes that are applied to cellulosic fibre using a redox reaction as described below. Because of the use of soda, and the very high pH of the dye bath in the dyeing process. Wool is soluble in caustic soda solutions and it is possible to dye wool at room temperatures with indigo and other low substantive vat dyes using soda ash as the alkali source with very little strength loss. Vat red 10, vat violet 13 and vat orange 1 can be applied in this manner as well, vat dyes characteristically require a reducing agent to solubilize them. The most common reducing agent is sodium dithionite, which converts the dye to its form that is soluble. Once attached to the fabric, the dye is then oxidized to the insoluble state which is intensely colored. The dye is only in its reduced form. The fiber is immersed repeatedly in this oxygen-free dyebath, then exposed to the air, for these reasons, vat dyes are less suitable than fiber-reactive dyes for amateur use. Indigo is an example of this dye class, it changes from yellow, in the dyebath, not all vat dyeing is done with vat dyes. The vat dyes have high color fastness, which is uncommon in other dye classes, on the other hand, vat dyes tend to have poor rubbing fastness, but this can be mitigated with special treatments to the fabric. Indigo is subject to major crocking unless it is applied carefully and this means use a weaker dyebath, and dipping many times, rather than a single strong dipping. Inkodye is a type of vat dye that uses light rather than oxygen to fix the dye and these dyes, which are chemically similar to vat dyes, are developed by light instead of being applied in an oxygen-free bath and being developed in the fabric by exposure to oxygen. Inkodyes are true dyes, not fabric paints, a dye itself attaches to the fabric, fabric paint includes a glue-like binder, which imparts a stiffer feeling to the fabric. Many vat dyes are derivatives of indigo dye, for example, vat blue 2 and 3 are halogenated or methylated derivatives and so are several violets
24.
Middle English
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This stage of the development of the English language roughly followed the High to the Late Middle Ages. Middle English developed out of Late Old English, seeing many dramatic changes in its grammar, pronunciation and this largely forms the basis for Modern English spelling, although pronunciation has changed considerably since that time. Middle English was succeeded in England by the era of Early Modern English, by that time, a variant of the Northumbrian dialect was developing into the Scots language. During the Middle English period many Old English grammatical features were simplified or disappeared, noun, adjective and verb inflections were simplified, a process that included the reduction of most grammatical case distinctions. Middle English also saw an adoption of Norman French vocabulary, especially in areas such as politics, law. Everyday English vocabulary remained mostly Germanic, with Old Norse influence becoming apparent, significant changes in pronunciation took place, especially for long vowels and diphthongs, which in the later Middle English period began to undergo the Great Vowel Shift. Little survives of early Middle English literature, most likely due to the Norman domination, poets wrote both in the vernacular and courtly English. It is popularly believed that William Shakespeare wrote in Middle English, the latter part of the 11th century was a period of transition from Late Old English to Early Middle English. The influence of Old Norse certainly helped move English from a synthetic language towards a more analytic or isolating word order and it was, after all, a salutary influence. The gain was greater than the loss, there was a gain in directness, in clarity, and in strength. The change to Old English from Old Norse was substantive, pervasive and it is most important to recognise that in many words the English and Scandinavian language differed chiefly in their inflectional elements. The body of the word was so nearly the same in the two languages only the endings would put obstacles in the way of mutual understanding. In the mixed population which existed in the Danelaw these endings must have led to confusion, tending gradually to become obscured. This blending of peoples and languages resulted in simplifying English grammar. There are also many Norman-derived terms relating to the cultures that arose in the 12th century. Sometimes, and particularly later, words were taken from Latin, giving such sets as kingly, later French borrowings came from standard rather than Norman French, this leads to such cognate pairs as warden, guardian. The end of Anglo-Saxon rule did not, of course, change the language immediately, the general population would have spoken the same dialects as before the Conquest, these changed slowly until written records of them became available for study, which varies in different regions. Once the writing of Old English came to an end, Middle English had no standard language, Early Middle English has a largely Anglo-Saxon vocabulary, but a greatly simplified inflectional system
25.
Old English
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Old English or Anglo-Saxon is the earliest historical form of the English language, spoken in England and southern and eastern Scotland in the early Middle Ages. It was brought to Great Britain by Anglo-Saxon settlers probably in the mid 5th century, Old English developed from a set of Anglo-Frisian or North Sea Germanic dialects originally spoken by Germanic tribes traditionally known as the Angles, Saxons, and Jutes. As the Anglo-Saxons became dominant in England, their language replaced the languages of Roman Britain, Common Brittonic, a Celtic language, Old English had four main dialects, associated with particular Anglo-Saxon kingdoms, Mercian, Northumbrian, Kentish and West Saxon. It was West Saxon that formed the basis for the standard of the later Old English period, although the dominant forms of Middle. The speech of eastern and northern parts of England was subject to strong Old Norse influence due to Scandinavian rule, Old English is one of the West Germanic languages, and its closest relatives are Old Frisian and Old Saxon. Like other old Germanic languages, it is different from Modern English. Old English grammar is similar to that of modern German, nouns, adjectives, pronouns, and verbs have many inflectional endings and forms. The oldest Old English inscriptions were using a runic system. Old English was not static, and its usage covered a period of 700 years, from the Anglo-Saxon settlement of Britain in the 5th century to the late 11th century, some time after the Norman invasion. While indicating that the establishment of dates is a process, Albert Baugh dates Old English from 450 to 1150, a period of full inflections. Perhaps around 85 per cent of Old English words are no longer in use, Old English is a West Germanic language, developing out of Ingvaeonic dialects from the 5th century. It came to be spoken over most of the territory of the Anglo-Saxon kingdoms which became the Kingdom of England and this included most of present-day England, as well as part of what is now southeastern Scotland, which for several centuries belonged to the Anglo-Saxon kingdom of Northumbria. Other parts of the island – Wales and most of Scotland – continued to use Celtic languages, Norse was also widely spoken in the parts of England which fell under Danish law. Anglo-Saxon literacy developed after Christianisation in the late 7th century, the oldest surviving text of Old English literature is Cædmons Hymn, composed between 658 and 680. There is a corpus of runic inscriptions from the 5th to 7th centuries. The Old English Latin alphabet was introduced around the 9th century, with the unification of the Anglo-Saxon kingdoms by Alfred the Great in the later 9th century, the language of government and literature became standardised around the West Saxon dialect. In Old English, typical of the development of literature, poetry arose before prose, a later literary standard, dating from the later 10th century, arose under the influence of Bishop Æthelwold of Winchester, and was followed by such writers as the prolific Ælfric of Eynsham. This form of the language is known as the Winchester standard and it is considered to represent the classical form of Old English
26.
Fez, Morocco
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Fez is the second largest city of Morocco, with a population of 1.1 million. Fez was the city of modern Morocco until 1925 and is now the capital of the Fès-Meknès administrative region. The city has two old medina quarters, the larger of which is Fes el Bali and it is listed as a World Heritage Site and is believed to be one of the worlds largest urban pedestrian zones. University of Al Quaraouiyine, founded in 859, is the oldest continuously functioning university in the world, the city has been called the Mecca of the West and the Athens of Africa. The Arabic word فأس Faʾs means pickaxe, which legends say Idris I of Morocco used when he created the lines of the city, one noticeable thing was that the pickaxe was made from silver and gold. During the rule of the Idrisid dynasty, Fez consisted of two cities, Fas Elbali, founded by Idris I, and al-ʿĀliyá, founded by his son and it is not known whether the name al-ʿĀliyá ever referred to both urban areas. It wasnt until 1070 that the two agglomerations were united and the name Fas was used for the combined site, the city was founded on a bank of the Jawhar river by Idris I in 789, founder of the Zaydi Shii Idrisid dynasty. His son, Idris II, built a settlement on the river bank. These settlements would soon develop into two walled and largely autonomous sites, often in conflict with one another, Madinat Fas, in 808 Al-Aliya replaced Walili as the capital of the Idrisids. The Andalusians settled in what is called the Old Fez, while the Tunisians found their home in the New Fez and these two waves of immigrants would subsequently give their name to the sites Adwat Al-Andalus and Adwat al-Qarawiyyin. Upon the death of Idris II in 828, the territory was divided among his sons. The newly fragmented Idrisid power would never again be reunified, during Yahya ibn Muhammads rule in Fez the Kairouyine mosque, one of the oldest and largest in Africa, was built and its associated University of Al Quaraouiyine was founded. Comparatively little is known about Idrisid Fez, owing to the lack of historical narratives. The sources that mention Idrisid Fez, describe a rather rural one, not having the cultural sophistication of the important cities of Al-Andalus and Ifriqiya. In the 10th century the city was contested by the Caliphate of Córdoba and the Fatimid Caliphate of Tunisia, the Fatimids took the city in 927 and expelled the Idrissids, after which their Miknasa were installed there. The Miknasa were driven out of Fez in 980 by the Maghrawa, their fellow Zenata and it was in this period that the great Andalusian ruler Almanzor commissioned the Maghrawa to rebuild and refurnish the Al-Kairouan mosque, giving it much of its current appearance. Thus, the two grew into each other, being now only separated by their walls and the river. His sons fortified the city to a great extent and this could not keep the Almoravid emir Ibn Tashfin from conquering it in 1070, after more than a decade of battling the Zenata warriors in the area and constant besieging of the city
27.
Flax
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Flax, Linum usitatissimum, is a member of the genus Linum in the family Linaceae. It is a food and fiber crop cultivated in regions of the world. The textiles made from flax are known in the Western countries as linen, and traditionally used for bed sheets, underclothes, the oil is known as linseed oil. In addition to referring to the plant itself, the word flax may refer to the fibers of the flax plant. The plant species is only as a cultivated plant, and appears to have been domesticated just once from the wild species Linum bienne. Several other species in the genus Linum are similar in appearance to L. usitatissimum, cultivated flax, including some that have similar blue flowers, some of these are perennial plants, unlike L. usitatissimum, which is an annual plant. Cultivated flax plants grow to 1.2 m tall, with slender stems, the leaves are glaucous green, slender lanceolate, 20–40 mm long, and 3 mm broad. The flowers are pale blue, 15–25 mm in diameter. The fruit is a round, dry capsule 5–9 mm in diameter, containing several brown seeds shaped like an apple pip. Flax was first domesticated in the Fertile Crescent region, evidence exists of a domesticated oilseed flax with increased seed size by 9,000 years ago from Tell Ramad in Syria. Use of the crop steadily spread, reaching as far as Switzerland, in China and India, domesticated flax was cultivated also by at least 5,000 years ago. Flax was extensively cultivated in ancient Egypt, where the walls had paintings of flowering flax. Egyptian priests only wore linen, as flax was considered a symbol of purity, phoenicians traded Egyptian linen throughout the Mediterranean, and the Romans used it for their sails. Eventually, Flanders became the center of the linen industry in the European Middle Ages. Since then, flax has lost its importance as a commercial crop, Flax is grown for its oil, used as a nutritional supplement, and as an ingredient in many wood-finishing products. Flax is also grown as a plant in gardens. Flax fibers are used to make linen, the Latin species name usitatissimum means most useful. Flax fibers are taken from the stem of the plant, and are two to three times as strong as those of cotton, additionally, flax fibers are naturally smooth and straight
28.
Georgia (country)
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Georgia is a country in the Caucasus region of Eurasia. The capital and largest city is Tbilisi, Georgia covers a territory of 69,700 square kilometres, and its 2016 population is about 3.72 million. Georgia is a unitary, semi-presidential republic, with the government elected through a representative democracy, during the classical era, several independent kingdoms became established in what is now Georgia. The kingdoms of Colchis and Iberia adopted Christianity in the early 4th century, a unified Kingdom of Georgia reached the peak of its political and economic strength during the reign of King David IV and Queen Tamar in the 12th and early 13th centuries. Thereafter the kingdom declined and eventually disintegrated under hegemony of various powers, including the Mongols, the Ottoman Empire. Russian rule over Georgia was eventually acknowledged in various treaties with Iran. Since the establishment of the modern Georgian republic in April 1991, post-communist Georgia suffered from civil, the countrys Western orientation soon led to the worsening of relations with Russia, culminating in the brief Russo-Georgian War in August 2008. Georgia is a member of the United Nations, the Council of Europe, and it contains two de facto independent regions, Abkhazia and South Ossetia, which gained limited international recognition after the 2008 Russo-Georgian War. Georgia and a part of the international community consider the regions to be part of Georgias sovereign territory under Russian military occupation. Georgia probably stems from the Persian designation of the Georgians – gurğān, in the 11th and 12th centuries adapted via Syriac gurz-ān/gurz-iyān, starting with the Persian word gurğ/gurğān, the word was later adopted in numerous other languages, including Slavic and West European languages. This term itself might have established through the ancient Iranian appellation of the near-Caspian region. The self-designation used by ethnic Georgians is Kartvelebi, the medieval Georgian Chronicles present an eponymous ancestor of the Kartvelians, Kartlos, a great-grandson of Japheth. However, scholars agree that the word is derived from the Karts, the name Sakartvelo consists of two parts. Its root, kartvel-i, specifies an inhabitant of the core central-eastern Georgian region of Kartli, ancient Greeks and Romans referred to early western Georgians as Colchians and eastern Georgians as Iberians. Today the full, official name of the country is Georgia, before the 1995 constitution came into force the countrys name was the Republic of Georgia. The territory of modern-day Georgia was inhabited by Homo erectus since the Paleolithic Era, the proto-Georgian tribes first appear in written history in the 12th century BC. The earliest evidence of wine to date has found in Georgia. In fact, early metallurgy started in Georgia during the 6th millennium BC, the classical period saw the rise of a number of early Georgian states, the principal of which was Colchis in the west and Iberia in the east
29.
Neolithic
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It ended when metal tools became widespread. The Neolithic is a progression of behavioral and cultural characteristics and changes, including the use of wild and domestic crops, the beginning of the Neolithic culture is considered to be in the Levant about 10, 200–8800 BC. It developed directly from the Epipaleolithic Natufian culture in the region, whose people pioneered the use of wild cereals, which then evolved into true farming. The Natufian period was between 12,000 and 10,200 BC, and the so-called proto-Neolithic is now included in the Pre-Pottery Neolithic between 10,200 and 8800 BC. By 10, 200–8800 BC, farming communities arose in the Levant and spread to Asia Minor, North Africa, Mesopotamia is the site of the earliest developments of the Neolithic Revolution from around 10,000 BC. Early Neolithic farming was limited to a range of plants, both wild and domesticated, which included einkorn wheat, millet and spelt, and the keeping of dogs, sheep. By about 6900–6400 BC, it included domesticated cattle and pigs, the establishment of permanently or seasonally inhabited settlements, not all of these cultural elements characteristic of the Neolithic appeared everywhere in the same order, the earliest farming societies in the Near East did not use pottery. Early Japanese societies and other East Asian cultures used pottery before developing agriculture, unlike the Paleolithic, when more than one human species existed, only one human species reached the Neolithic. The term Neolithic derives from the Greek νέος néos, new and λίθος líthos, stone, the term was invented by Sir John Lubbock in 1865 as a refinement of the three-age system. In the Middle East, cultures identified as Neolithic began appearing in the 10th millennium BC, early development occurred in the Levant and from there spread eastwards and westwards. Neolithic cultures are attested in southeastern Anatolia and northern Mesopotamia by around 8000 BC. The total excavated area is more than 1,200 square yards, the Neolithic 1 period began roughly 10,000 years ago in the Levant. A temple area in southeastern Turkey at Göbekli Tepe dated around 9500 BC may be regarded as the beginning of the period. This site was developed by nomadic tribes, evidenced by the lack of permanent housing in the vicinity. At least seven stone circles, covering 25 acres, contain limestone pillars carved with animals, insects, Stone tools were used by perhaps as many as hundreds of people to create the pillars, which might have supported roofs. Other early PPNA sites dating to around 9500–9000 BC have been found in Jericho, Israel, Gilgal in the Jordan Valley, the start of Neolithic 1 overlaps the Tahunian and Heavy Neolithic periods to some degree. The major advance of Neolithic 1 was true farming, in the proto-Neolithic Natufian cultures, wild cereals were harvested, and perhaps early seed selection and re-seeding occurred. The grain was ground into flour, emmer wheat was domesticated, and animals were herded and domesticated
30.
Anatolia
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Anatolia, in geography known as Asia Minor, Asian Turkey, Anatolian peninsula, or Anatolian plateau, is the westernmost protrusion of Asia, which makes up the majority of modern-day Turkey. The region is bounded by the Black Sea to the north, the Mediterranean Sea to the south, the Sea of Marmara forms a connection between the Black and Aegean Seas through the Bosphorus and Dardanelles straits and separates Anatolia from Thrace on the European mainland. Traditionally, Anatolia is considered to extend in the east to a line between the Gulf of Alexandretta and the Black Sea to the Armenian Highlands, thus, traditionally Anatolia is the territory that comprises approximately the western two-thirds of the Asian part of Turkey. The Turkification of Anatolia began under the Seljuk Empire in the late 11th century, however, various non-Turkic languages continue to be spoken by minorities in Anatolia today, including Kurdish, Assyrian, Armenian, Arabic, Laz, Georgian, and Greek. Traditionally, Anatolia is considered to extend in the east to a line running from the Gulf of Alexandretta to the Black Sea. This traditional geographical definition is used, for example, in the latest edition of Merriam-Websters Geographical Dictionary, under this definition, Anatolia is bounded to the east by the Armenian Highlands, and the Euphrates before that river bends to the southeast to enter Mesopotamia. To the southeast, it is bounded by the ranges that separate it from the Orontes valley in Syria, the first name the Greeks used for the Anatolian peninsula was Ἀσία, presumably after the name of the Assuwa league in western Anatolia. As the name of Asia came to be extended to areas east of the Mediterranean. The name Anatolia derives from the Greek ἀνατολή meaning “the East” or more literally “sunrise”, the precise reference of this term has varied over time, perhaps originally referring to the Aeolian, Ionian and Dorian colonies on the west coast of Asia Minor. In the Byzantine Empire, the Anatolic Theme was a theme covering the western, the modern Turkish form of Anatolia is Anadolu, which again derives from the Greek name Aνατολή. The Russian male name Anatoly and the French Anatole share the same linguistic origin, in English the name of Turkey for ancient Anatolia first appeared c. It is derived from the Medieval Latin Turchia, which was used by the Europeans to define the Seljuk controlled parts of Anatolia after the Battle of Manzikert. Human habitation in Anatolia dates back to the Paleolithic, neolithic Anatolia has been proposed as the homeland of the Indo-European language family, although linguists tend to favour a later origin in the steppes north of the Black Sea. However, it is clear that the Anatolian languages, the oldest branch of Indo-European, have spoken in Anatolia since at least the 19th century BC. The earliest historical records of Anatolia stem from the southeast of the region and are from the Mesopotamian-based Akkadian Empire during the reign of Sargon of Akkad in the 24th century BC, scholars generally believe the earliest indigenous populations of Anatolia were the Hattians and Hurrians. The region was famous for exporting raw materials, and areas of Hattian-, one of the numerous cuneiform records dated circa 20th century BC, found in Anatolia at the Assyrian colony of Kanesh, uses an advanced system of trading computations and credit lines. They were speakers of an Indo-European language, the Hittite language, originating from Nesa, they conquered Hattusa in the 18th century BC, imposing themselves over Hattian- and Hurrian-speaking populations. According to the most widely accepted Kurgan theory on the Proto-Indo-European homeland, however, the Hittites adopted the cuneiform script, invented in Mesopotamia
31.
Ochre
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Ochre (/ˈoʊkər/ OH-kər, from Greek, ὠχρός, ōkhrós, or ocher, is a natural earth pigment containing hydrated iron oxide, which ranges in color from yellow to deep orange or brown. It is also the name of the produced by this pigment. A variant of ochre containing an amount of hematite, or dehydrated iron oxide, has a reddish tint known as red ochre. Ochre is a family of pigments, which includes yellow ochre, red ochre, purple ochre, sienna. The major ingredient of all the ochres is iron oxide-hydroxide, known as limonite, which gives them a yellow color. Yellow ochre, FeO·nH 2O, is a hydrated iron hydroxide also called gold ochre Red ochre, Fe 2O3, takes its color from the mineral hematite. Purple ochre, is identical to red ochre chemically but of a different hue caused by different light diffraction properties associated with an average particle size. Brown ochre, also FeO, is a hydrated iron oxide. Sienna contains both limonite and an amount of manganese oxide, which makes it darker than ochre. Umber pigments contain a proportion of manganese which make them a dark brown. When natural sienna and umber pigments are heated, they are dehydrated and some of the limonite is transformed into hematite, giving them more reddish colors, called burnt sienna and burnt umber. Ochres are non-toxic, and can be used to make an oil paint that dries quickly, modern ochre pigments often are made using synthetic iron oxide. Pigments which use natural ochre pigments indicate it with the name PY-43 on the label, pieces of ochre engraved with abstract designs have been found at the site of the Blombos Cave in South Africa, dated to around 75,000 years ago. In Wales, the paleolithic burial called the Red Lady of Paviland from its coating of red ochre has been dated to around 33,000 years before present. Paintings of animals made with red and yellow ochre pigments have been found in sites at Pech Merle in France. The cave of Lascaux has an image of a horse colored with yellow estimated to be 17,300 years old. In Ancient Egypt, yellow was associated with gold, which was considered to be eternal, the skin and bones of the gods were believed to be made of gold. The Egyptians used yellow extensively in tomb painting, though occasionally they used orpiment
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Iron oxide
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Iron oxides are chemical compounds composed of iron and oxygen. All together, there are sixteen known iron oxides and oxyhydroxides, common rust is a form of iron oxide. Iron oxides are used as inexpensive, durable pigments in paints, coatings. Colors commonly available are in the end of the yellow/orange/red/brown/black range. When used as a coloring, it has E number E172. Limonite Iron oxide nanoparticles List of inorganic pigments Information from Nano-Oxides, http, //chemed. chem. purdue. edu/demos/demosheets/12.3. html http, //minerals. usgs. gov/minerals/pubs/commodity/iron_oxide/ CDC - NIOSH Pocket Guide to Chemical Hazards de
33.
Pigment
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A pigment is a material that changes the color of reflected or transmitted light as the result of wavelength-selective absorption. This physical process differs from fluorescence, phosphorescence, and other forms of luminescence, many materials selectively absorb certain wavelengths of light. Materials that humans have chosen and developed for use as pigments usually have properties that make them ideal for coloring other materials. A pigment must have a high tinting strength relative to the materials it colors and it must be stable in solid form at ambient temperatures. For industrial applications, as well as in the arts, permanence, pigments that are not permanent are called fugitive. Fugitive pigments fade over time, or with exposure to light, pigments are used for coloring paint, ink, plastic, fabric, cosmetics, food, and other materials. Most pigments used in manufacturing and the arts are dry colorants. This powder is added to a binder, a neutral or colorless material that suspends the pigment. A distinction is made between a pigment, which is insoluble in its vehicle, and a dye, which either is itself a liquid or is soluble in its vehicle. A colorant can act as either a pigment or a dye depending on the vehicle involved, in some cases, a pigment can be manufactured from a dye by precipitating a soluble dye with a metallic salt. The resulting pigment is called a lake pigment, the term biological pigment is used for all colored substances independent of their solubility. In 2006, around 7.4 million tons of inorganic, organic, asia has the highest rate on a quantity basis followed by Europe and North America. By 2020, revenues will have risen to approx, the global demand on pigments was roughly US$20.5 billion in 2009, around 1. 5-2% up from the previous year. It is predicted to increase in a growth rate in the coming years. The worldwide sales are said to increase up to US$24.5 billion in 2015, pigments appear the colors they are because they selectively reflect and absorb certain wavelengths of visible light. White light is an equal mixture of the entire spectrum of visible light with a wavelength in a range from about 375 or 400 nanometers to about 760 or 780 nm. When this light encounters a pigment, parts of the spectrum are absorbed by the molecules or ions of the pigment, in organic pigments such as diazo or phthalocyanine compounds the light is absorbed by the conjugated systems of double bonds in the molecule. Some of the inorganic pigments such as vermilion or cadmium yellow absorb light by transferring an electron from the ion to the positive ion
34.
Clay
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Clay is a fine-grained natural rock or soil material that combines one or more clay minerals with traces of metal oxides and organic matter. Geologic clay deposits are composed of phyllosilicate minerals containing variable amounts of water trapped in the mineral structure. Clays are plastic due to water content and become hard, brittle. Depending on the content in which it is found, clay can appear in various colours from white to dull grey or brown to deep orange-red. Although many naturally occurring deposits include both silts and clay, clays are distinguished from other fine-grained soils by differences in size, silts, which are fine-grained soils that do not include clay minerals, tend to have larger particle sizes than clays. There is, however, some overlap in size and other physical properties. The distinction between silt and clay varies by discipline, geologists and soil scientists usually consider the separation to occur at a particle size of 2 µm, sedimentologists often use 4–5 μm, and colloid chemists use 1 μm. Geotechnical engineers distinguish between silts and clays based on the plasticity properties of the soil, as measured by the soils Atterberg limits, ISO14688 grades clay particles as being smaller than 2 μm and silt particles as being larger. These solvents, usually acidic, migrate through the rock after leaching through upper weathered layers. In addition to the process, some clay minerals are formed through hydrothermal activity. There are two types of deposits, primary and secondary. Primary clays form as residual deposits in soil and remain at the site of formation, secondary clays are clays that have been transported from their original location by water erosion and deposited in a new sedimentary deposit. Clay deposits are associated with very low energy depositional environments such as large lakes. Depending on the source, there are three or four main groups of clays, kaolinite, montmorillonite-smectite, illite, and chlorite. Chlorites are not always considered to be a clay, sometimes being classified as a group within the phyllosilicates. There are approximately 30 different types of clays in these categories. Varve is clay with visible annual layers, which are formed by deposition of those layers and are marked by differences in erosion. This type of deposit is common in glacial lakes
35.
China
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China, officially the Peoples Republic of China, is a unitary sovereign state in East Asia and the worlds most populous country, with a population of over 1.381 billion. The state is governed by the Communist Party of China and its capital is Beijing, the countrys major urban areas include Shanghai, Guangzhou, Beijing, Chongqing, Shenzhen, Tianjin and Hong Kong. China is a power and a major regional power within Asia. Chinas landscape is vast and diverse, ranging from forest steppes, the Himalaya, Karakoram, Pamir and Tian Shan mountain ranges separate China from much of South and Central Asia. The Yangtze and Yellow Rivers, the third and sixth longest in the world, respectively, Chinas coastline along the Pacific Ocean is 14,500 kilometers long and is bounded by the Bohai, Yellow, East China and South China seas. China emerged as one of the worlds earliest civilizations in the basin of the Yellow River in the North China Plain. For millennia, Chinas political system was based on hereditary monarchies known as dynasties, in 1912, the Republic of China replaced the last dynasty and ruled the Chinese mainland until 1949, when it was defeated by the communist Peoples Liberation Army in the Chinese Civil War. The Communist Party established the Peoples Republic of China in Beijing on 1 October 1949, both the ROC and PRC continue to claim to be the legitimate government of all China, though the latter has more recognition in the world and controls more territory. China had the largest economy in the world for much of the last two years, during which it has seen cycles of prosperity and decline. Since the introduction of reforms in 1978, China has become one of the worlds fastest-growing major economies. As of 2016, it is the worlds second-largest economy by nominal GDP, China is also the worlds largest exporter and second-largest importer of goods. China is a nuclear weapons state and has the worlds largest standing army. The PRC is a member of the United Nations, as it replaced the ROC as a permanent member of the U. N. Security Council in 1971. China is also a member of numerous formal and informal multilateral organizations, including the WTO, APEC, BRICS, the Shanghai Cooperation Organization, the BCIM, the English name China is first attested in Richard Edens 1555 translation of the 1516 journal of the Portuguese explorer Duarte Barbosa. The demonym, that is, the name for the people, Portuguese China is thought to derive from Persian Chīn, and perhaps ultimately from Sanskrit Cīna. Cīna was first used in early Hindu scripture, including the Mahābhārata, there are, however, other suggestions for the derivation of China. The official name of the state is the Peoples Republic of China. The shorter form is China Zhōngguó, from zhōng and guó and it was then applied to the area around Luoyi during the Eastern Zhou and then to Chinas Central Plain before being used as an occasional synonym for the state under the Qing
36.
Bark (botany)
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Bark is the outermost layers of stems and roots of woody plants. Plants with bark include trees, woody vines, and shrubs, Bark refers to all the tissues outside of the vascular cambium and is a nontechnical term. It overlays the wood and consists of the bark and the outer bark. The inner bark, which in older stems is living tissue, the outer bark in older stems includes the dead tissue on the surface of the stems, along with parts of the innermost periderm and all the tissues on the outer side of the periderm. The outer bark on trees which lies external to the last formed periderm is also called the rhytidome, Bark has been used to make cloth, canoes, and ropes and used as a surface for paintings and map making. A number of plants are grown for their attractive or interesting bark colorations. What is commonly called bark includes a number of different tissues, Cork is an external, secondary tissue that is impermeable to water and gases, and is also called the phellem. The cork is produced by the cork cambium which is a layer of active cells which serve as a lateral meristem for the periderm. The cork cambium, which is called the phellogen, is normally only one cell layer thick. The phelloderm, which is not always present in all barks, is a layer of cells formed by, together, the phellem, phellogen and phelloderm constitute the periderm. Cork cell walls contain suberin, a substance which protects the stem against water loss, the invasion of insects into the stem. The cambium tissues, i. e. Phloem is a nutrient-conducting tissue composed of sieve tubes or sieve cells mixed with parenchyma, the cortex is the primary tissue of stems and roots. In stems the cortex is between the layer and the phloem, in roots the inner layer is not phloem. From the outside to the inside of a woody stem. The bark includes through, and is composed of periderm and phloem, as the stem ages and grows, changes occur that transform the surface of the stem into the bark. The epidermis is a layer of cells that cover the plant body, including the stems, leaves, flowers and fruits, in old stems the epidermal layer, cortex, and primary phloem become separated from the inner tissues by thicker formations of cork. Due to the cork layer these cells die because they do not receive water. This dead layer is the rough corky bark that forms around tree trunks, often a secondary covering called the periderm forms on small woody stems and many non woody plants, which is composed of cork, the cork cambium, and the phelloderm
37.
Cochineal
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The cochineal is a scale insect in the suborder Sternorrhyncha, from which the natural dye carmine is derived. A primarily sessile parasite native to tropical and subtropical South America as well as Mexico and Arizona and these insects are found on the pads of prickly pear cacti, then are brushed off and dried. The insect produces carminic acid that deters predation by other insects, carminic acid, typically 17-24% of dried insects weight, can be extracted from the body and eggs, then mixed with aluminium or calcium salts to make carmine dye, also known as cochineal. Today, carmine is primarily used as a colorant in food, the carmine dye was used in Central America in the 15th century for coloring fabrics and became an important export good during the colonial period. After synthetic pigments and dyes such as alizarin were invented in the late 19th century, some towns in the Mexican state of Oaxaca are still working in handmade textiles using this cochineal. The primary biological distinctions between species are minor differences in host plant preferences, in addition to different geographic distributions. Cochineal is probably from French cochenille, Spanish cochinilla, Latin coccinus, meaning scarlet-colored, and Latin coccum, meaning berry yielding scarlet dye. See also the word kermes which is the source of a similar but weaker Mediterranean dye also called crimson. Some sources identify the Spanish source word for cochineal as cochinilla wood louse, Cochineal dye was used by the Aztec and Maya peoples of Central and North America. Eleven cities conquered by Montezuma in the 15th century paid a tribute of 2000 decorated cotton blankets and 40 bags of cochineal dye each. Production of cochineal is depicted in Codex Osuna, during the colonial period, the production of cochineal grew rapidly. Produced almost exclusively in Oaxaca by indigenous producers, cochineal became Mexicos second-most valued export after silver, soon after the Spanish conquest of the Aztec Empire, it began to be exported to Spain, and by the 17th century was a commodity traded as far away as India. The dyestuff was consumed throughout Europe and was so prized, its price was regularly quoted on the London. In 1777, French botanist Nicolas-Joseph Thiéry de Menonville, presenting himself as a physician, smuggled the insects. This particular collection failed to thrive and ultimately died out, leaving the Mexican monopoly intact, after the Mexican War of Independence in 1810–1821, the Mexican monopoly on cochineal came to an end. Large-scale production of cochineal emerged, especially in Guatemala and the Canary Islands, it was cultivated in Spain. The delicate manual labour required for the breeding of the insect could not compete with the methods of the new industry. The tuna blood dye stopped being used and trade in cochineal almost totally disappeared in the course of the 20th century, the breeding of the cochineal insect has been done mainly for the purposes of maintaining the tradition rather than to satisfy any sort of demand
38.
Sindh
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Sindh /sɪnd/ is one of the four provinces of Pakistan, in the southeast of the country. Historically home to the Sindhi people, it is locally known as the Mehran. It was formerly known as Sind until 1956, Sindh is the third largest province of Pakistan by area, and second largest province by population after Punjab. Sindh is bordered by Balochistan province to the west, and Punjab province to the north, Sindh also borders the Indian states of Gujarat and Rajasthan to the east, and Arabian Sea to the south. Sindhs climate is noted for hot summers and mild winters, the provincial capital of Sindh is Pakistans largest city and financial hub, Karachi. Sindh has Pakistans second largest economy with Karachi being its capital hosts the headquarters of several multinational banks. Sindh is home to a portion of Pakistans industrial sector. The remainder of Sindh has an agriculture based economy, and produces fruit, food consumer items, Sindh is also the centre of Pakistans pharmaceutical industry. Sindh is known for its culture which is strongly influenced by Sufism. Several important Sufi shrines are located throughout the province which attract millions of annual devotees, Sindh also has Pakistans highest percentage of Hindu residents. Karachi and other centres of Sindh have seen ethnic tensions between the native Sindhis and the Muhajirs boil over into violence on several occasions. Sindh is home to two UNESCO World Heritage Sites - the Historical Monuments at Makli, and the Archaeological Ruins at Moenjodaro, the word Sindh is derived from the Sanskrit language and is adapted from the Sanskrit term Sindhu which literally means river hence a reference to Indus River. Spelling of its name as Sind was discontinued in 1988 by an amendment passed in Sindh Assembly. The Greeks who conquered Sindh in 325 BC under the command of Alexander the Great rendered it as Indós, the ancient Iranians referred to everything east of the river Indus as hind from the word Sindh. When the British arrived in the 17th century in India, then ruled by the Maratha Empire, they applied the Greek version of the name Sindh to all of South Asia, calling it India. The name of Pakistan is actually an acronym in which the letter s is derived from the first letter in Sindh, Sindhs first known village settlements date as far back as 7000 BCE. Permanent settlements at Mehrgarh, currently in Balochistan, to the west expanded into Sindh and this culture blossomed over several millennia and gave rise to the Indus Valley Civilization around 3000 BCE. The primitive village communities in Balochistan were still struggling against a difficult highland environment and this was one of the most developed urban civilizations of the ancient world
39.
Pakistan
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Pakistan, officially the Islamic Republic of Pakistan, is a federal parliamentary republic in South Asia on the crossroads of Central Asia and Western Asia. It is the sixth-most populous country with a population exceeding 200 million people, in terms of area, it is the 33rd-largest country in the world with an area covering 881,913 square kilometres. It is separated from Tajikistan by Afghanistans narrow Wakhan Corridor in the north, Pakistan is unique among Muslim countries in that it is the only country to have been created in the name of Islam. As a result of the Pakistan Movement led by Muhammad Ali Jinnah and it is an ethnically and linguistically diverse country, with a similarly diverse geography and wildlife. Initially a dominion, Pakistan adopted a constitution in 1956, becoming an Islamic republic, an ethnic civil war in 1971 resulted in the secession of East Pakistan as the new country of Bangladesh. The new constitution stipulated that all laws were to conform to the injunctions of Islam as laid down in the Quran. Pakistan has an economy with a well-integrated agriculture sector. The Pakistani economy is the 24th-largest in the world in terms of purchasing power and it is ranked among the emerging and growth-leading economies of the world, and is backed by one of the worlds largest and fastest-growing middle classes. The post-independence history of Pakistan has been characterised by periods of military rule, the country continues to face challenging problems such as illiteracy, healthcare, and corruption, but has substantially reduced poverty and terrorism and expanded per capita income. It is also a member of CERN. Pakistan is a signatory to the Kyoto Protocol, the Paris Agreement, the name Pakistan literally means land of the pure in Urdu and Persian. It is a play on the word pāk meaning pure in Persian and Pashto, the letter i was incorporated to ease pronunciation and form the linguistically correct and meaningful name. Some of the earliest ancient human civilisations in South Asia originated from areas encompassing present-day Pakistan, the earliest known inhabitants in the region were Soanian during the Lower Paleolithic, of whom stone tools have been found in the Soan Valley of Punjab. The Vedic Civilization, characterised by Indo-Aryan culture, laid the foundations of Hinduism, Multan was an important Hindu pilgrimage centre. The Vedic civilisation flourished in the ancient Gandhāran city of Takṣaśilā, the Indo-Greek Kingdom founded by Demetrius of Bactria included Gandhara and Punjab and reached its greatest extent under Menander, prospering the Greco-Buddhist culture in the region. Taxila had one of the earliest universities and centres of education in the world. At its zenith, the Rai Dynasty of Sindh ruled this region, the Pala Dynasty was the last Buddhist empire, which, under Dharampala and Devapala, stretched across South Asia from what is now Bangladesh through Northern India to Pakistan. The Arab conqueror Muhammad bin Qasim conquered the Indus valley from Sindh to Multan in southern Punjab in 711 AD, the Pakistan governments official chronology identifies this as the time when the foundation of Pakistan was laid
40.
Mohenjo-daro
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Mohenjo-daro is an archeological site in the province of Sindh, Pakistan. Mohenjo-daro was abandoned in the 19th century BCE as the Indus Valley Civilization declined, significant excavation has since been conducted at the site of the city, which was designated an UNESCO World Heritage Site in 1980. The site is threatened by erosion and improper restoration. Mohenjo-daro, the name for the site, has been variously interpreted as Mound of the Dead Men in Sindhi. The citys original name is unknown, based on his analysis of a Mohenjo-daro seal, Iravatham Mahadevan speculates that the citys ancient name could have been Kukkutarma. Cock-fighting may have had ritual and religious significance for the city, with domesticated chickens bred there for sacred purposes, Mohenjo-daro may also have been a point of diffusion for the eventual worldwide domestication of chickens. Mohenjo-daro is located west of the Indus River in Larkana District, Sindh, Pakistan and it is sited on a Pleistocene ridge in the middle of the flood plain of the Indus River Valley, around 28 kilometres from the town of Larkana. The Indus still flows east of the site, but the Ghaggar-Hakra riverbed on the side is now dry. Mohenjo-daro was built in the 26th century BCE and it was one of the largest cities of the ancient Indus Valley Civilization, also known as the Harappan Civilization, which developed around 3,000 BCE from the prehistoric Indus culture. Mohenjo-daro was the most advanced city of its time, with remarkably sophisticated civil engineering, when the Indus civilization went into sudden decline around 1900 BCE, Mohenjo-daro was abandoned. The ruins of the city remained undocumented for around 3,700 years until R. D and this led to large-scale excavations of Mohenjo-daro led by Kashinath Narayan Dikshit in 1924–25, and John Marshall in 1925–26. In the 1930s, major excavations were conducted at the site under the leadership of Marshall, D. K. Dikshitar, further excavations were carried out in 1945 by Ahmad Hasan Dani and Mortimer Wheeler. The last major series of excavations were conducted in 1964 and 1965 by Dr. George F. Dales, a dry core drilling conducted in 2015 by Pakistans National Fund for Mohenjo-daro revealed that the site is larger than the unearthed area. Mohenjo-daro has a layout based on a street grid of rectilinear buildings. Most were built of fired and mortared brick, some incorporated sun-dried mud-brick, the covered area of Mohenjo-daro is estimated at 300 hectares. The Oxford Handbook of Cities in World History offers an estimate of a peak population of around 40,000. The sheer size of the city, and its provision of buildings and facilities. The city is divided into two parts, the so-called Citadel and the Lower City
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Rubia
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Rubia is a genus of flowering plants in the Rubiaceae family. It contains around 80 species of perennial scrambling or climbing herbs and subshrubs native to the Old World, the genus and its best-known species are commonly known as madder, e. g. Rubia tinctorum, Rubia peregrina, and Rubia cordifolia. Rubia was an important source of a red pigment in many regions of Asia, Europe. The genus name Rubia derives from the Latin ruber meaning red, the plants roots contain an anthracene compound called alizarin that gives its red colour to a textile dye known as Rose madder. It was also used as a colourant, especially for paint, the synthesis of alizarin greatly reduced demand for the natural compound. Cloth dyed with it has found on Egyptian mummies. It was the used for dyeing the cloaks of the Libyan women in the days of Herodotus. It is the erythrodanon of Pedanius Dioscorides, who wrote of its cultivation in Caria, and of Hippocrates, and the Rubia of Pliny. R. tinctorum was extensively cultivated in south Europe, France, where it is called garance, and the Netherlands, large quantities were imported into England from Smyrna, Trieste, Livorno, etc. The cultivation, however, decreased after alizarin was made artificially, Madder was employed medicinally in ancient civilizations and in the middle ages. Its most remarkable physiological effect was found to be that of colouring red the bones of animals fed upon it, as also the claws and this appears to be due to the chemical affinity of calcium phosphate for the colouring matter. This property was used to enable physiologists to ascertain the manner in which bones develop, Rubia in the World Checklist of Rubiaceae
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Indigo dye
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Indigo dye is an organic compound with a distinctive blue color. Historically, indigo was a dye extracted from the leaves of certain plants. A large percentage of indigo dye produced today – several thousand each year – is synthetic. It is the blue often associated with blue jeans, the primary use for indigo is as a dye for cotton yarn, which is mainly for the production of denim cloth for blue jeans. On average, a pair of blue jean trousers requires 3–12 g of indigo, small amounts are used for dyeing wool and silk. Indigo carmine, or indigo, is a derivative which is also used as a colorant. About 20 thousand tons are produced annually, again mainly for blue jeans and it is also used as a food colorant, and is listed in the United States as FD&C Blue No.2. A variety of plants have provided indigo throughout history, but most natural indigo was obtained from those in the genus Indigofera, the primary commercial indigo species in Asia was true indigo. A common alternative used in the relatively colder subtropical locations such as Japans Ryukyu Islands, dyers knotweed was the most important blue dye in East Asia until the arrival of the Indigofera species from the south, which yield more dye. In Central and South America, the species grown is I. suffruticosa, in Europe woad containing the same dye was used for blue-dying. Several plants contain indigo, but low concentrations make them difficult to work with, natural sources also include mollusks, the Murex sea snails produce a mixture of indigo and dibromoindigo which together produce a range of purple hues known as Tyrian purple. Light exposure during part of the process can convert the dibromoindigo into indigo resulting in blue hues known as royal blue or hyacinth purple. The precursor to indigo is indican, a colorless, water-soluble derivative of the amino acid tryptophan, indican readily hydrolyzes to release β-D-glucose and indoxyl. Oxidation by exposure to air converts indoxyl to indigo, indican was obtained from the processing of the plants leaves, which contain as much as 0. 2–0. 8% of this compound. The leaves were soaked in water and fermented to convert the glycoside indican present in the plant to the blue dye indigotin, the precipitate from the fermented leaf solution was mixed with a strong base such as lye, pressed into cakes, dried, and powdered. The powder was mixed with various other substances to produce different shades of blue. Indigo was used in India, which was also the earliest major center for its production, the I. tinctoria species was domesticated in India. Indigo, used as a dye, made its way to the Greeks and the Romans, Indigo is among the oldest dyes to be used for textile dyeing and printing
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Kermes (dye)
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Kermes is a red dye derived from the dried bodies of the females of a scale insect in the genus Kermes, primarily Kermes vermilio. The Kermes insects are native in the Mediterranean region and live on the sap of the Kermes oak and they were used as a red dye by the ancient Greeks and Romans. The kermes dye is a rich red and it has good colour fastness in silk and wool. It was much esteemed in the era for dyeing silk. Post-medievally it was replaced by other red dyes and it is no longer in use today. Kermes dye is of ancient origin, jars of kermes have been found in a Neolithic cave-burial at Adaouste, in the Middle Ages, rich crimson and scarlet silks dyed with kermes in the new silk-weaving centers of Italy and Sicily exceeded the legendary Tyrian purple in status and desirability. The dyestuff was called grain in all Western European languages because the desiccated eggs resembled fine grains of wheat or sand, and textiles dyed with kermes were described as dyed in the grain. Following the Spanish conquest of the Aztec Empire, Mexican cochineal, alchermes Coccus The torah process of curing tzoraath, using tolaath shani תולעת שני, the Kermes dye Barber, E. J. W. Prehistoric Textiles. The Cambridge History of Western Textiles, netherton, Robin, and Gale R. Owen-Crocker, eds. CS1 maint, Uses editors parameter Schoeser, Mary
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Isatis tinctoria
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Isatis tinctoria, also called woad, dyers woad, or glastum, is a flowering plant in the family Brassicaceae. It is occasionally known as Asp of Jerusalem, Woad is also the name of a blue dye produced from the leaves of the plant. Woad is native to the steppe and desert zones of the Caucasus, Central Asia to eastern Siberia and Western Asia but is now found in southeastern and Central Europe. Long important as a source from which is obtained a blue dye, indigo, it has been cultivated throughout Europe, especially in Western and southern Europe, in medieval times there were important woad-growing regions in England, Germany and France. Towns such as Toulouse became prosperous from the woad trade, Woad was eventually replaced by the stronger Indigofera tinctoria and, in the early 20th century, both woad and Indigofera tinctoria were replaced by synthetic indigos. Used in traditional Chinese medicine for centuries, woad is now being studied for use in the treatment of cancer, there has also been some revival of the use of woad for craft purposes. The first archaeological finds of woad seeds date to the Neolithic, the seeds have been found in the French cave of lAudoste, Bouches-du-Rhône, France. Impressions of the seeds of Färberwaid or German indigo, of the plant family Brassicaceae, have found on pottery in the Iron Age settlement of the Heuneburg. Seed and pod fragments have also found in Iron Age pit at Dragonby, South Humberside. The Hallstatt burials of the Hochdorf Chieftains Grave and Hohmichele contained textiles dyed with woad dye, melo and Rondão write that woad was known as far back as the time of the ancient Egyptians, who used it to dye the cloth wrappings applied for the mummies. Skelton informs us that one of the early dyes discovered by the ancient Egyptians was blue woad, lucas writes, What has been assumed to have been Indian Indigo on ancient Egyptian fabrics may have been woad. Hall states that the ancient Egyptians created their blue dye by using indigotin, julius Caesar reported that the Britanni used to colour their bodies blue with vitrum, a word that roughly translates to glass, but has also been translated as woad. Carr suggests the translation of, dye themselves with glazes or infect themselves with glass, the latter could refer to using glass in the tattooing process or to scarification. It has also claimed that Caesar was referring to some form of copper- or iron-based pigment. Analysis done on the Lindow Man did return evidence of copper, the same study also noted that the earliest definite reference to the woad plant in the British Isles dates to a seed impression on an Anglo-Saxon pot. The authors theorized that vitrum could have referred to Copper sulfates naturally occurring variant Chalcanthite or to the mineral Azurite. A later study concluded the amount was not of sufficient magnitude to provide convincing evidence that the copper was applied as paint. In terms of usage, vitrum is more used to refer to glass rather than woad
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William Henry Perkin
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Sir William Henry Perkin, FRS was an English chemist best known for his accidental discovery of the first aniline dye, the purple mauveine. Though failing in trying to synthesise quinine for the treatment of malaria, William Perkin was born in the East End of London, the youngest of the seven children of George Perkin, a successful carpenter. His mother, Sarah, was of Scottish descent but moved to east London as a child and he was baptised in the parish church of St Pauls, Shadwell, which had been connected to such luminaries as James Cook, Jane Randolph Jefferson and John Wesley. At the age of 14, Perkin attended the City of London School, where he was taught by Thomas Hall, who fostered his scientific talent and encouraged him to pursue a career in chemistry. In 1853, at the age of 15, Perkin entered the Royal College of Chemistry in London. Hofmann had published a hypothesis on how it might be possible to synthesise quinine, perkin—who had by then become one of Hofmanns assistants—embarked on a series of experiments to try to achieve this end. Perkin, who had an interest in painting and photography, immediately became enthusiastic about this result and carried out trials with his friend Arthur Church. Since these experiments were not part of the work on quinine which had been assigned to Perkin and they satisfied themselves that they might be able to scale up production of the purple substance and commercialise it as a dye, which they called mauveine. Their initial experiments indicated that it dyed silk in a way which was stable when washed or exposed to light and they sent some samples to a dye works in Perth, Scotland, and received a very promising reply from the general manager of the company, Robert Pullar. Perkin filed for a patent in August 1856, when he was still only 18, at the time, all dyes used for colouring cloth were natural substances, many of which were expensive and labour-intensive to extract. Furthermore, many lacked stability, or fastness and its extraction was variable and complicated, and so Perkin and his brother realised that they had discovered a possible substitute whose production could be commercially successful. Everything seemed to fall into place by dint of hard work, with a little luck, after the discovery of mauveine, many new aniline dyes appeared, and factories producing them were constructed across Europe. This discovery was the subject of a question on the 2012 season of Eggheads, local lore has it that the colour of the nearby Grand Union Canal changed from week to week depending on the activity at Perkins Greenford dyeworks. During the next decade, the new German Empire was rapidly eclipsing Britain as the centre of Europes chemical industry, by the 1890s, Germany had a near-monopoly on the business and Perkin was compelled to sell off his holdings and retire. Perkin died in 1907 of pneumonia and other complications resulting from a burst appendix and he is buried in the grounds of Christchurch, Harrow, UK. Perkin married Jemima Harriet, the daughter of John Lissett, in 1859, Perkins second marriage was in 1866, to Alexandrine Caroline, daughter of Helman Mollwo, which resulted in one son and four daughters. Perkin received many honours in his lifetime, in June 1866, he was elected a Fellow of the Royal Society. In 1879, received their Royal Medal and, in 1889 and he was knighted in 1906, and in the same year was awarded the first Perkin Medal, established to commemorate the fiftieth anniversary of his discovery of mauveine
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Mauveine
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Mauveine, also known as aniline purple and Perkins mauve, was the first synthetic organic chemical dye, discovered serendipitously in 1856. It is also among the first chemical dyes to have been mass-produced, mauveine is a mixture of four related aromatic compounds differing in number and placement of methyl groups. Its organic synthesis involves dissolving aniline, p-toluidine, and o-toluidine in sulfuric acid and water in a roughly 1,1,2 ratio, mauveine A incorporates 2 molecules of aniline, one of p-toluidine, and one of o-toluidine. Mauveine B incorporates one molecule each of aniline, p-toluidine, in 1879, Perkin showed mauveine B related to safranines by oxidative/reductive loss of the p-tolyl group. In fact, safranine is a 2, 8-dimethyl phenazinium salt, whereas the produced by Perkin is presumed to be the 1. The molecular structure of mauveine proved difficult to determine, finally being identified in 1994. In 2007, two more were isolated and identified, mauveine B2, an isomer of mauveine B with methyl on different aryl group, and mauveine C, in 2008, additional mauveines and pseudomauveines were discovered, bringing the total number of these compounds up to 12. In 1856, William Henry Perkin, then age 18, was given a challenge by his professor, August Wilhelm von Hofmann, in one attempt, Perkin oxidized aniline using potassium dichromate, whose toluidine impurities reacted with the aniline and yielded a black solid—suggesting a failed organic synthesis. Cleaning the flask with alcohol, Perkin noticed purple portions of the solution, suitable as a dye of silk and other textiles, it was patented by Perkin, who the next year opened a dyeworks mass-producing it at Greenford on the banks of the Grand Union Canal in London. It was originally called aniline purple or Tyrian purple, the name of an ancient natural dye derived from mollusks, in 1859, it attained the name mauve in England via the French name for the mallow flower, and chemists later called it mauveine. By 1870, its great demand succumbed to newer synthetic colors in the dye industry launched by mauveine. In the early 20th century, the U. S. Perkin anniversary website Rotatable 3D models of mauveine are available using Jmol
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Coal tar
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Coal tar, also known as liquor carbonis detergens, is a very thick, dark liquid with a number of medical and industrial uses. As a medication it is used to treat psoriasis and seborrheic dermatitis, for psoriasis it may be used together with ultraviolet light therapy. It is used by application to the affected area, industrial uses include preservation of railway ties and improving the surface of roads. Side effects include skin irritation, sun sensitivity, allergic reactions and it is unclear if use during pregnancy is safe for the baby and use during breastfeeding is not typically recommended. Coal tar is one of the by-products when coal is made into coke and it is a complex mixture of phenols, polycyclic aromatic hydrocarbons, and heterocyclic compounds. Coal tar was discovered around 1665 and used for purposes as early as the 1800s. It is on the World Health Organizations List of Essential Medicines, Coal tar is available as a generic medication and over the counter. In the United Kingdom 125 ml of 5% shampoo costs the NHS about 1.89 pounds, in the United States a month of treatment costs less than 25 USD. Coal-tar was one of the key starting materials for the pharmaceutical industry. It can be used in medicated shampoo, soap and ointment, as a treatment for dandruff and psoriasis, as well as being used to kill and repel head lice. When used as a medication in the U. S. coal tar preparations are considered over-the-counter drug pharmaceuticals and are subject to regulation by the FDA, named brands include Denorex, Balnetar, Psoriasin, Tegrin, T/Gel, and Neutar. Pine tar has also been used for this purpose. Various phenolic coal tar derivatives have analgesic properties and these included acetanilide, phenacetin, and paracetamol. Paracetamol is the only coal-tar derived analgesic still in use today, Coal tar is incorporated into some parking-lot sealcoat products, which are used to protect and beautify the underlying pavement. Sealcoat products that are coal-tar based typically contain 20 to 35 percent coal-tar pitch, Coal tar was a component of the first sealed roads. In its original development by Edgar Purnell Hooley, tarmac was tar covered with granite chips, later the filler used was industrial slag. Today, petroleum derived binders and sealers are more commonly used and these sealers are used to extend the life and reduce maintenance cost associated with asphalt pavements, primarily in asphalt road paving, car parks and walkways. Being flammable, coal tar is used for heating or to fire boilers
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Alizarin
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Alizarin or 1, 2-dihydroxyanthraquinone is an organic compound with formula C 14H 8O4 that has been used throughout history as a prominent red dye, principally for dyeing textile fabrics. Historically it was derived from the roots of plants of the madder genus, in 1869, it became the first natural pigment to be duplicated synthetically. Alizarin is the ingredient for the manufacture of the madder lake pigments known to painters as Rose madder. A notable use of alizarin in modern times is as an agent in biological research because it stains free calcium. Alizarin continues to be used commercially as a red textile dye, Madder has been cultivated as a dyestuff since antiquity in central Asia and Egypt, where it was grown as early as 1500 BC. Cloth dyed with madder root pigment was found in the tomb of the Pharaoh Tutankhamun and in the ruins of Pompeii, in the Middle Ages, Charlemagne encouraged madder cultivation. Madder was widely used as a dye in Western Europe in the Late Medieval centuries, in 17th century England, alizarin was used as a red dye for the clothing of the parliamentary New Model Army. The distinctive red color would continue to be worn for centuries, giving English, the madder dyestuff is combined with a dye mordant. According to which mordant used, the color may be anywhere from pink through purple to dark brown. In the 18th century the most valued color was a bright red known as Turkey Red, the combination of mordants and overall technique used to obtain the Turkey Red originated in the Middle East or Turkey. It was a complex and multi-step technique in its Middle Eastern formulation, the process was simplified in late 18th-century Europe. This resulting madder lake has a color, and can be used more efficaciously. This general method of preparing lakes has been known for centuries but was simplified in the late 18th, in 1826, the French chemist Pierre-Jean Robiquet found that madder root contained two colorants, the red alizarin and the more rapidly fading purpurin. About the same time, the English dye chemist William Henry Perkin independently discovered the same synthesis, the subsequent discovery that anthracene could be abstracted from coal tar further advanced the importance and affordability of alizarins artificial synthesis. The synthetic alizarin could be produced for a fraction of the cost of the product. The principal synthesis entailed oxidation of anthraquinone-2-sulfonic acid with sodium nitrate in concentrated sodium hydroxide, Alizarin itself has been in turn largely replaced today by the more light-resistant quinacridone pigments developed at DuPont in 1958. Alizarin is one of ten dihydroxyanthraquinone isomers and its molecular structure can be viewed as being derived from anthraquinone by replacement of two neighboring hydrogen atoms by hydroxyl groups. It is soluble in hexane and chloroform, and can be obtained from the latter as red-purple crystals, Alizarin changes color depending on the pH of the solution it is in, thereby making it a pH indicator
