Hydroxyapatite is a naturally occurring mineral form of calcium apatite with the formula Ca5(PO4)3(OH), often written Ca10(PO4)6(OH)2 to denote that the crystal unit cell comprises two entities. It is the hydroxyl endmember of the complex apatite group. The OH− ion can be replaced by fluoride or chloride, producing fluorapatite or chlorapatite. It crystallizes in the hexagonal crystal system. Pure hydroxyapatite powder is white. Naturally occurring apatites can, however, also have brown, yellow, or green colorations, comparable to the discolorations of dental fluorosis.
Hydroxyapatite crystals on matrix
Hydroxyapatite
Needle-like hydroxyapatite crystals on stainless steel. Scanning electron microscope picture from University of Tartu.
In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid substance with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.
Crystals of serandite, natrolite, analcime, and aegirine from Mont Saint-Hilaire, Quebec, Canada
Schist is a metamorphic rock characterized by an abundance of platy minerals. In this example, the rock has prominent sillimanite porphyroblasts as large as 3 cm (1.2 in).
Hübnerite, the manganese-rich end-member of the wolframite series, with minor quartz in the background
When minerals react, the products will sometimes assume the shape of the reagent; the product mineral is termed a pseudomorph of (or after) the reagent. Illustrated here is a pseudomorph of kaolinite after orthoclase. Here, the pseudomorph preserved the Carlsbad twinning common in orthoclase.