1.
Orthoclase
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Orthoclase, or orthoclase feldspar, is an important tectosilicate mineral which forms igneous rock. The name is from the Ancient Greek for straight fracture, because its two planes are at right angles to each other. It is a type of potassium feldspar, also known as K-feldspar, the gem known as moonstone is largely composed of orthoclase. Orthoclase is a constituent of most granites and other felsic igneous rocks and often forms huge crystals. Typically, the pure potassium endmember of orthoclase forms a solution with albite. While slowly cooling within the earth, sodium-rich albite lamellae form by exsolution, the resulting intergrowth of the two feldspars is called perthite. The higher-temperature polymorph of KAlSi3O8 is sanidine, sanidine is common in rapidly cooled volcanic rocks such as obsidian and felsic pyroclastic rocks, and is notably found in trachytes of the Drachenfels, Germany. The lower-temperature polymorph of KAlSi3O8 is microcline, adularia is a low temperature form of either microcline or orthoclase originally reported from the low temperature hydrothermal deposits in the Adula Alps of Switzerland. It was first described by Ermenegildo Pini in 1781, the optical effect of adularescence in moonstone is typically due to adularia. The largest documented crystal of orthoclase was found in Ural mountains. It measured ~10×10×0.4 m and weighed ~100 tons, together with the other potassium feldspars, orthoclase is a common raw material for the manufacture of some glasses and some ceramics such as porcelain, and as a constituent of scouring powder. Some intergrowths of orthoclase and albite have an attractive pale luster and are called moonstone when used in jewellery, most moonstones are translucent and white, although grey and peach-colored varieties also occur. In gemology, their luster is called adularescence and is described as creamy or silvery white with a billowy quality. It is the gem of Florida. Orthoclase is one of the ten defining minerals of the Mohs scale of mineral hardness, nASAs Curiosity Rover discovery of high levels of orthoclase in Martian sandstones suggested that some Martian rocks may have experienced complex geological processing, such as repeated melting
2.
Crystallography
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Crystallography is the experimental science of determining the arrangement of atoms in the crystalline solids. The word crystallography derives from the Greek words crystallon cold drop, frozen drop, with its meaning extending to all solids with some degree of transparency, and graphein to write. In July 2012, the United Nations recognised the importance of the science of crystallography by proclaiming that 2014 would be the International Year of Crystallography, X-ray crystallography is used to determine the structure of large biomolecules such as proteins. Before the development of X-ray diffraction crystallography, the study of crystals was based on measurements of their geometry. This involved measuring the angles of crystal faces relative to other and to theoretical reference axes. This physical measurement is carried out using a goniometer, the position in 3D space of each crystal face is plotted on a stereographic net such as a Wulff net or Lambert net. The pole to face is plotted on the net. Each point is labelled with its Miller index, the final plot allows the symmetry of the crystal to be established. Crystallographic methods now depend on analysis of the patterns of a sample targeted by a beam of some type. X-rays are most commonly used, other beams used include electrons or neutrons and this is facilitated by the wave properties of the particles. Crystallographers often explicitly state the type of beam used, as in the terms X-ray crystallography and these three types of radiation interact with the specimen in different ways. X-rays interact with the distribution of electrons in the sample. Electrons are charged particles and therefore interact with the charge distribution of both the atomic nuclei and the electrons of the sample. Neutrons are scattered by the atomic nuclei through the nuclear forces, but in addition. They are therefore also scattered by magnetic fields, when neutrons are scattered from hydrogen-containing materials, they produce diffraction patterns with high noise levels. However, the material can sometimes be treated to substitute deuterium for hydrogen, because of these different forms of interaction, the three types of radiation are suitable for different crystallographic studies. An image of an object is made using a lens to focus the beam. However, the wavelength of light is three orders of magnitude longer than the length of typical atomic bonds and atoms themselves
3.
Crystal system
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In crystallography, the terms crystal system, crystal family and lattice system each refer to one of several classes of space groups, lattices, point groups or crystals. Informally, two crystals are in the crystal system if they have similar symmetries, though there are many exceptions to this. Space groups and crystals are divided into seven crystal systems according to their point groups, five of the crystal systems are essentially the same as five of the lattice systems, but the hexagonal and trigonal crystal systems differ from the hexagonal and rhombohedral lattice systems. The six crystal families are formed by combining the hexagonal and trigonal crystal systems into one hexagonal family, a lattice system is a class of lattices with the same set of lattice point groups, which are subgroups of the arithmetic crystal classes. The 14 Bravais lattices are grouped into seven lattice systems, triclinic, monoclinic, orthorhombic, tetragonal, rhombohedral, hexagonal, in a crystal system, a set of point groups and their corresponding space groups are assigned to a lattice system. Of the 32 point groups that exist in three dimensions, most are assigned to only one system, in which case both the crystal and lattice systems have the same name. However, five point groups are assigned to two systems, rhombohedral and hexagonal, because both exhibit threefold rotational symmetry. These point groups are assigned to the crystal system. In total there are seven crystal systems, triclinic, monoclinic, orthorhombic, tetragonal, trigonal, hexagonal, a crystal family is determined by lattices and point groups. It is formed by combining crystal systems which have space groups assigned to a lattice system. In three dimensions, the families and systems are identical, except the hexagonal and trigonal crystal systems. In total there are six families, triclinic, monoclinic, orthorhombic, tetragonal, hexagonal. Spaces with less than three dimensions have the number of crystal systems, crystal families and lattice systems. In one-dimensional space, there is one crystal system, in 2D space, there are four crystal systems, oblique, rectangular, square and hexagonal. The relation between three-dimensional crystal families, crystal systems and lattice systems is shown in the table, Note. To avoid confusion of terminology, the term trigonal lattice is not used, if the original structure and inverted structure are identical, then the structure is centrosymmetric. Still, even for non-centrosymmetric case, inverted structure in some cases can be rotated to align with the original structure and this is the case of non-centrosymmetric achiral structure. If the inverted structure cannot be rotated to align with the structure, then the structure is chiral
4.
Euclidean vector
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In mathematics, physics, and engineering, a Euclidean vector is a geometric object that has magnitude and direction. Vectors can be added to other vectors according to vector algebra, a Euclidean vector is frequently represented by a line segment with a definite direction, or graphically as an arrow, connecting an initial point A with a terminal point B, and denoted by A B →. A vector is what is needed to carry the point A to the point B and it was first used by 18th century astronomers investigating planet rotation around the Sun. The magnitude of the vector is the distance between the two points and the direction refers to the direction of displacement from A to B. These operations and associated laws qualify Euclidean vectors as an example of the more generalized concept of vectors defined simply as elements of a vector space. Vectors play an important role in physics, the velocity and acceleration of a moving object, many other physical quantities can be usefully thought of as vectors. Although most of them do not represent distances, their magnitude and direction can still be represented by the length, the mathematical representation of a physical vector depends on the coordinate system used to describe it. Other vector-like objects that describe physical quantities and transform in a similar way under changes of the system include pseudovectors and tensors. The concept of vector, as we know it today, evolved gradually over a period of more than 200 years, about a dozen people made significant contributions. Giusto Bellavitis abstracted the basic idea in 1835 when he established the concept of equipollence, working in a Euclidean plane, he made equipollent any pair of line segments of the same length and orientation. Essentially he realized an equivalence relation on the pairs of points in the plane, the term vector was introduced by William Rowan Hamilton as part of a quaternion, which is a sum q = s + v of a Real number s and a 3-dimensional vector. Like Bellavitis, Hamilton viewed vectors as representative of classes of equipollent directed segments, grassmanns work was largely neglected until the 1870s. Peter Guthrie Tait carried the standard after Hamilton. His 1867 Elementary Treatise of Quaternions included extensive treatment of the nabla or del operator ∇, in 1878 Elements of Dynamic was published by William Kingdon Clifford. Clifford simplified the quaternion study by isolating the dot product and cross product of two vectors from the complete quaternion product and this approach made vector calculations available to engineers and others working in three dimensions and skeptical of the fourth. Josiah Willard Gibbs, who was exposed to quaternions through James Clerk Maxwells Treatise on Electricity and Magnetism, the first half of Gibbss Elements of Vector Analysis, published in 1881, presents what is essentially the modern system of vector analysis. In 1901 Edwin Bidwell Wilson published Vector Analysis, adapted from Gibbs lectures, in physics and engineering, a vector is typically regarded as a geometric entity characterized by a magnitude and a direction. It is formally defined as a line segment, or arrow
5.
Crystal
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A crystal or crystalline solid is a solid material whose constituents are arranged in a highly ordered microscopic structure, forming a crystal lattice that extends in all directions. In addition, macroscopic single crystals are usually identifiable by their geometrical shape, the scientific study of crystals and crystal formation is known as crystallography. The process of crystal formation via mechanisms of crystal growth is called crystallization or solidification, the word crystal derives from the Ancient Greek word κρύσταλλος, meaning both ice and rock crystal, from κρύος, icy cold, frost. Examples of large crystals include snowflakes, diamonds, and table salt, most inorganic solids are not crystals but polycrystals, i. e. many microscopic crystals fused together into a single solid. Examples of polycrystals include most metals, rocks, ceramics, a third category of solids is amorphous solids, where the atoms have no periodic structure whatsoever. Examples of amorphous solids include glass, wax, and many plastics, Crystals are often used in pseudoscientific practices such as crystal therapy, and, along with gemstones, are sometimes associated with spellwork in Wiccan beliefs and related religious movements. The scientific definition of a crystal is based on the arrangement of atoms inside it. A crystal is a solid where the form a periodic arrangement. For example, when liquid water starts freezing, the change begins with small ice crystals that grow until they fuse. Most macroscopic inorganic solids are polycrystalline, including almost all metals, ceramics, ice, rocks, solids that are neither crystalline nor polycrystalline, such as glass, are called amorphous solids, also called glassy, vitreous, or noncrystalline. These have no periodic order, even microscopically, there are distinct differences between crystalline solids and amorphous solids, most notably, the process of forming a glass does not release the latent heat of fusion, but forming a crystal does. A crystal structure is characterized by its cell, a small imaginary box containing one or more atoms in a specific spatial arrangement. The unit cells are stacked in three-dimensional space to form the crystal, the symmetry of a crystal is constrained by the requirement that the unit cells stack perfectly with no gaps. There are 219 possible crystal symmetries, called space groups. These are grouped into 7 crystal systems, such as cubic crystal system or hexagonal crystal system, Crystals are commonly recognized by their shape, consisting of flat faces with sharp angles. Euhedral crystals are those with obvious, well-formed flat faces, anhedral crystals do not, usually because the crystal is one grain in a polycrystalline solid. The flat faces of a crystal are oriented in a specific way relative to the underlying atomic arrangement of the crystal. This occurs because some surface orientations are more stable than others, as a crystal grows, new atoms attach easily to the rougher and less stable parts of the surface, but less easily to the flat, stable surfaces
6.
Orthorhombic crystal system
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In crystallography, the orthorhombic crystal system is one of the 7 crystal systems. All three bases intersect at 90° angles, so the three lattice vectors remain mutually orthogonal, there are two orthorhombic Bravais lattices in two dimensions, Primitive rectangular and centered rectangular. The primitive rectangular lattice can also be described by a centered rhombic unit cell, there are four orthorhombic Bravais lattices, primitive orthorhombic, base-centered orthorhombic, body-centered orthorhombic, and face-centered orthorhombic. In this axis setting, the primitive and base-centered lattices interchange in centering type, crystal structure Overview of all space groups Hurlbut, Cornelius S. Klein, Cornelis. Hahn, Theo, ed. International Tables for Crystallography, Volume A, Space Group Symmetry
7.
Prism (geometry)
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In geometry, a prism is a polyhedron comprising an n-sided polygonal base, a second base which is a translated copy of the first, and n other faces joining corresponding sides of the two bases. All cross-sections parallel to the bases are translations of the bases, prisms are named for their bases, so a prism with a pentagonal base is called a pentagonal prism. The prisms are a subclass of the prismatoids, a right prism is a prism in which the joining edges and faces are perpendicular to the base faces. This applies if the faces are rectangular. If the joining edges and faces are not perpendicular to the base faces, for example a parallelepiped is an oblique prism of which the base is a parallelogram, or equivalently a polyhedron with six faces which are all parallelograms. A truncated prism is a prism with nonparallel top and bottom faces, some texts may apply the term rectangular prism or square prism to both a right rectangular-sided prism and a right square-sided prism. A right p-gonal prism with rectangular sides has a Schläfli symbol ×, a right rectangular prism is also called a cuboid, or informally a rectangular box. A right square prism is simply a box, and may also be called a square cuboid. A right rectangular prism has Schläfli symbol ××, an n-prism, having regular polygon ends and rectangular sides, approaches a cylindrical solid as n approaches infinity. The term uniform prism or semiregular prism can be used for a prism with square sides. A uniform p-gonal prism has a Schläfli symbol t, right prisms with regular bases and equal edge lengths form one of the two infinite series of semiregular polyhedra, the other series being the antiprisms. The dual of a prism is a bipyramid. The volume of a prism is the product of the area of the base, the volume is therefore, V = B ⋅ h where B is the base area and h is the height. The volume of a prism whose base is a regular n-sided polygon with side s is therefore. The surface area of a prism is 2 · B + P · h, where B is the area of the base, h the height. The surface area of a prism whose base is a regular n-sided polygon with side length s and height h is therefore. The rotation group is Dn of order 2n, except in the case of a cube, which has the symmetry group O of order 24. The symmetry group Dnh contains inversion iff n is even, a prismatic polytope is a higher-dimensional generalization of a prism
8.
Parallelogram
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In Euclidean geometry, a parallelogram is a simple quadrilateral with two pairs of parallel sides. The opposite or facing sides of a parallelogram are of equal length, by comparison, a quadrilateral with just one pair of parallel sides is a trapezoid in American English or a trapezium in British English. The three-dimensional counterpart of a parallelogram is a parallelepiped, rhomboid – A quadrilateral whose opposite sides are parallel and adjacent sides are unequal, and whose angles are not right angles Rectangle – A parallelogram with four angles of equal size. Rhombus – A parallelogram with four sides of equal length, square – A parallelogram with four sides of equal length and angles of equal size. A simple quadrilateral is a if and only if any one of the following statements is true. Two pairs of opposite angles are equal in measure, one pair of opposite sides are parallel and equal in length. Each diagonal divides the quadrilateral into two congruent triangles, the sum of the squares of the sides equals the sum of the squares of the diagonals. It has rotational symmetry of order 2, the sum of the distances from any interior point to the sides is independent of the location of the point. Thus all parallelograms have all the properties listed above, and conversely, if just one of statements is true in a simple quadrilateral. Opposite sides of a parallelogram are parallel and so will never intersect, the area of a parallelogram is twice the area of a triangle created by one of its diagonals. The area of a parallelogram is also equal to the magnitude of the cross product of two adjacent sides. Any line through the midpoint of a parallelogram bisects the area, any non-degenerate affine transformation takes a parallelogram to another parallelogram. A parallelogram has rotational symmetry of order 2, if it also has exactly two lines of reflectional symmetry then it must be a rhombus or an oblong. If it has four lines of symmetry, it is a square. The perimeter of a parallelogram is 2 where a and b are the lengths of adjacent sides, unlike any other convex polygon, a parallelogram cannot be inscribed in any triangle with less than twice its area. The centers of four squares all constructed either internally or externally on the sides of a parallelogram are the vertices of a square. If two lines parallel to sides of a parallelogram are constructed concurrent to a diagonal, then the parallelograms formed on opposite sides of that diagonal are equal in area, the diagonals of a parallelogram divide it into four triangles of equal area. All of the formulas for general convex quadrilaterals apply to parallelograms
9.
Bravais lattice
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This discrete set of vectors must be closed under vector addition and subtraction. For any choice of position vector R, the lattice looks exactly the same, when the discrete points are atoms, ions, or polymer strings of solid matter, the Bravais lattice concept is used to formally define a crystalline arrangement and its frontiers. A crystal is made up of an arrangement of one or more atoms repeated at each lattice point. Consequently, the crystal looks the same when viewed from any equivalent lattice point, two Bravais lattices are often considered equivalent if they have isomorphic symmetry groups. In this sense, there are 14 possible Bravais lattices in three-dimensional space, the 14 possible symmetry groups of Bravais lattices are 14 of the 230 space groups. In two-dimensional space, there are 5 Bravais lattices, grouped into four crystal families, the unit cells are specified according to the relative lengths of the cell edges and the angle between them. The area of the cell can be calculated by evaluating the norm || a × b ||. The properties of the families are given below, In three-dimensional space. These are obtained by combining one of the six families with one of the centering types. For example, the monoclinic I lattice can be described by a monoclinic C lattice by different choice of crystal axes, similarly, all A- or B-centred lattices can be described either by a C- or P-centering. This reduces the number of combinations to 14 conventional Bravais lattices, the unit cells are specified according to the relative lengths of the cell edges and the angles between them. The volume of the cell can be calculated by evaluating the triple product a ·, where a, b. The properties of the families are given below, In four dimensions. Of these,23 are primitive and 41 are centered, ten Bravais lattices split into enantiomorphic pairs. Bravais, A. Mémoire sur les systèmes formés par les points distribués régulièrement sur un plan ou dans lespace, hahn, Theo, ed. International Tables for Crystallography, Volume A, Space Group Symmetry. Catalogue of Lattices Smith, Walter Fox
10.
Crystal structure
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In crystallography, crystal structure is a description of the ordered arrangement of atoms, ions or molecules in a crystalline material. Ordered structures occur from the nature of the constituent particles to form symmetric patterns that repeat along the principal directions of three-dimensional space in matter. The smallest group of particles in the material that constitutes the pattern is the unit cell of the structure. The unit cell completely defines the symmetry and structure of the crystal lattice. The repeating patterns are said to be located at the points of the Bravais lattice, the lengths of the principal axes, or edges, of the unit cell and the angles between them are the lattice constants, also called lattice parameters. The symmetry properties of the crystal are described by the concept of space groups, all possible symmetric arrangements of particles in three-dimensional space may be described by the 230 space groups. The crystal structure and symmetry play a role in determining many physical properties, such as cleavage, electronic band structure. The crystal structure of a material can be described in terms of its unit cell, the unit cell is a box containing one or more atoms arranged in three dimensions. The unit cells stacked in three-dimensional space describe the arrangement of atoms of the crystal. Commonly, atomic positions are represented in terms of fractional coordinates, the atom positions within the unit cell can be calculated through application of symmetry operations to the asymmetric unit. The asymmetric unit refers to the smallest possible occupation of space within the unit cell and this does not, however imply that the entirety of the asymmetric unit must lie within the boundaries of the unit cell. Symmetric transformations of atom positions are calculated from the group of the crystal structure. Vectors and planes in a lattice are described by the three-value Miller index notation. It uses the indices ℓ, m, and n as directional parameters, which are separated by 90°, by definition, the syntax denotes a plane that intercepts the three points a1/ℓ, a2/m, and a3/n, or some multiple thereof. That is, the Miller indices are proportional to the inverses of the intercepts of the plane with the unit cell, if one or more of the indices is zero, it means that the planes do not intersect that axis. A plane containing a coordinate axis is translated so that it no longer contains that axis before its Miller indices are determined, the Miller indices for a plane are integers with no common factors. Negative indices are indicated with horizontal bars, as in, in an orthogonal coordinate system for a cubic cell, the Miller indices of a plane are the Cartesian components of a vector normal to the plane. Likewise, the planes are geometric planes linking nodes
11.
Rhombus
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In Euclidean geometry, a rhombus is a simple quadrilateral whose four sides all have the same length. Another name is equilateral quadrilateral, since equilateral means that all of its sides are equal in length, every rhombus is a parallelogram and a kite. A rhombus with right angles is a square, the word rhombus comes from Greek ῥόμβος, meaning something that spins, which derives from the verb ῥέμβω, meaning to turn round and round. The word was used both by Euclid and Archimedes, who used the term solid rhombus for two right circular cones sharing a common base, the surface we refer to as rhombus today is a cross section of this solid rhombus through the apex of each of the two cones. This is a case of the superellipse, with exponent 1. Every rhombus has two diagonals connecting pairs of vertices, and two pairs of parallel sides. Using congruent triangles, one can prove that the rhombus is symmetric across each of these diagonals and it follows that any rhombus has the following properties, Opposite angles of a rhombus have equal measure. The two diagonals of a rhombus are perpendicular, that is, a rhombus is an orthodiagonal quadrilateral, the first property implies that every rhombus is a parallelogram. Thus denoting the common side as a and the diagonals as p and q, not every parallelogram is a rhombus, though any parallelogram with perpendicular diagonals is a rhombus. In general, any quadrilateral with perpendicular diagonals, one of which is a line of symmetry, is a kite, every rhombus is a kite, and any quadrilateral that is both a kite and parallelogram is a rhombus. A rhombus is a tangential quadrilateral and that is, it has an inscribed circle that is tangent to all four sides. As for all parallelograms, the area K of a rhombus is the product of its base, the base is simply any side length a, K = a ⋅ h. The inradius, denoted by r, can be expressed in terms of the p and q as. The dual polygon of a rhombus is a rectangle, A rhombus has all sides equal, a rhombus has opposite angles equal, while a rectangle has opposite sides equal. A rhombus has a circle, while a rectangle has a circumcircle. A rhombus has an axis of symmetry through each pair of opposite vertex angles, the diagonals of a rhombus intersect at equal angles, while the diagonals of a rectangle are equal in length. The figure formed by joining the midpoints of the sides of a rhombus is a rectangle, a rhombohedron is a three-dimensional figure like a cube, except that its six faces are rhombi instead of squares. The rhombic dodecahedron is a polyhedron with 12 congruent rhombi as its faces
12.
Crystallographic point group
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For a periodic crystal, the group must also be consistent with maintenance of the three-dimensional translational symmetry that defines crystallinity. The macroscopic properties of a crystal would look exactly the same before, in the classification of crystals, each point group is also known as a crystal class. There are infinitely many three-dimensional point groups, however, the crystallographic restriction of the infinite families of general point groups results in there being only 32 crystallographic point groups. These 32 point groups are one-and-the same as the 32 types of morphological crystalline symmetries derived in 1830 by Johann Friedrich Christian Hessel from a consideration of observed crystal forms, the point groups are denoted by their component symmetries. There are a few standard notations used by crystallographers, mineralogists, for the correspondence of the two systems below, see crystal system. In Schoenflies notation, point groups are denoted by a symbol with a subscript. The symbols used in crystallography mean the following, Cn indicates that the group has a rotation axis. Cnh is Cn with the addition of a plane perpendicular to the axis of rotation. Cnv is Cn with the addition of n mirror planes parallel to the axis of rotation, s2n denotes a group that contains only a 2n-fold rotation-reflection axis. Dn indicates that the group has a rotation axis plus n twofold axes perpendicular to that axis. Dnh has, in addition, a plane perpendicular to the n-fold axis. Dnd has, in addition to the elements of Dn, mirror planes parallel to the n-fold axis, the letter T indicates that the group has the symmetry of a tetrahedron. Td includes improper rotation operations, T excludes improper rotation operations, the letter O indicates that the group has the symmetry of an octahedron, with or without improper operations. Due to the crystallographic restriction theorem, n =1,2,3,4, d4d and D6d are actually forbidden because they contain improper rotations with n=8 and 12 respectively. The 27 point groups in the table plus T, Td, Th, O, an abbreviated form of the Hermann–Mauguin notation commonly used for space groups also serves to describe crystallographic point groups. Group names are Molecular symmetry Point group Space group Point groups in three dimensions Crystal system Point-group symbols in International Tables for Crystallography,12.1, pp. 818-820 Names and symbols of the 32 crystal classes in International Tables for Crystallography. 10.1, p.794 Pictorial overview of the 32 groups Point Groups - Flow Chart Inorganic Chemistry Group Theory Practice Problems
13.
Orbifold
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In the mathematical disciplines of topology, geometry, and geometric group theory, an orbifold is a generalization of a manifold. It is a space with an orbifold structure. The underlying space locally looks like the quotient space of a Euclidean space under the action of a finite group. The definition of Thurston will be described here, it is the most widely used and is applicable in all cases, mathematically, orbifolds arose first as surfaces with singular points long before they were formally defined. In 3-manifold theory, the theory of Seifert fiber spaces, initiated by Seifert, in geometric group theory, post-Gromov, discrete groups have been studied in terms of the local curvature properties of orbihedra and their covering spaces. In string theory, the orbifold has a slightly different meaning. The main example of underlying space is a quotient space of a manifold under the properly discontinuous action of an infinite group of diffeomorphisms with finite isotropy subgroups. In particular this applies to any action of a group, thus a manifold with boundary carries a natural orbifold structure. Similarly the quotient space of a manifold by a proper action of S1 carries the structure of an orbifold. Orbifold structure gives a natural stratification by open manifolds on its underlying space and it should be noted that one topological space can carry many different orbifold structures. For example, consider the orbifold O associated with a space of the 2-sphere along a rotation by π, it is homeomorphic to the 2-sphere. It is possible to adopt most of the characteristics of manifolds to orbifolds, in the above example, the orbifold fundamental group of O is Z2 and its orbifold Euler characteristic is 1. The structure of an orbifold encodes not only that of the quotient space, which need not be a manifold. An n-dimensional orbifold is a Hausdorff topological space X, called the space, with a covering by a collection of open sets Ui. φj·ψij = φi the gluing maps are unique up to composition with group elements, note that the orbifold structure determines the isotropy subgroup of any point of the orbifold up to isomorphism, it can be computed as the stabilizer of the point in any orbifold chart. More generally, attached to a covering of an orbifold by orbifold charts. Exactly as in the case of manifolds, differentiability conditions can be imposed on the maps to give a definition of a differentiable orbifold. It will be a Riemannian orbifold if in addition there are invariant Riemannian metrics on the orbifold charts, for applications in geometric group theory, it is often convenient to have a slightly more general notion of orbifold, due to Haefliger
14.
Space groups
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In mathematics, physics and chemistry, a space group is the symmetry group of a configuration in space, usually in three dimensions. In three dimensions, there are 219 distinct types, or 230 if chiral copies are considered distinct, Space groups are also studied in dimensions other than 3 where they are sometimes called Bieberbach groups, and are discrete cocompact groups of isometries of an oriented Euclidean space. In crystallography, space groups are called the crystallographic or Fedorov groups. A definitive source regarding 3-dimensional space groups is the International Tables for Crystallography, in 1879 Leonhard Sohncke listed the 65 space groups whose elements preserve the orientation. More accurately, he listed 66 groups, but Fedorov and Schönflies both noticed that two of them were really the same, the space groups in 3 dimensions were first enumerated by Fedorov, and shortly afterwards were independently enumerated by Schönflies. The correct list of 230 space groups was found by 1892 during correspondence between Fedorov and Schönflies, burckhardt describes the history of the discovery of the space groups in detail. The space groups in three dimensions are made from combinations of the 32 crystallographic point groups with the 14 Bravais lattices, the combination of all these symmetry operations results in a total of 230 different space groups describing all possible crystal symmetries. The elements of the space group fixing a point of space are rotations, reflections, the identity element, the translations form a normal abelian subgroup of rank 3, called the Bravais lattice. There are 14 possible types of Bravais lattice, the quotient of the space group by the Bravais lattice is a finite group which is one of the 32 possible point groups. Translation is defined as the moves from one point to another point. A glide plane is a reflection in a plane, followed by a parallel with that plane. This is noted by a, b or c, depending on which axis the glide is along. There is also the n glide, which is a glide along the half of a diagonal of a face, and the d glide, the latter is called the diamond glide plane as it features in the diamond structure. In 17 space groups, due to the centering of the cell, the glides occur in two directions simultaneously, i. e. the same glide plane can be called b or c, a or b. For example, group Abm2 could be also called Acm2, group Ccca could be called Cccb, in 1992, it was suggested to use symbol e for such planes. The symbols for five groups have been modified, A screw axis is a rotation about an axis. These are noted by a number, n, to describe the degree of rotation, the degree of translation is then added as a subscript showing how far along the axis the translation is, as a portion of the parallel lattice vector. So,21 is a rotation followed by a translation of 1/2 of the lattice vector
15.
Coxeter notation
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The notation is named after H. S. M. Coxeter, and has been more comprehensively defined by Norman Johnson. For Coxeter groups defined by pure reflections, there is a correspondence between the bracket notation and Coxeter-Dynkin diagram. The numbers in the notation represent the mirror reflection orders in the branches of the Coxeter diagram. It uses the same simplification, suppressing 2s between orthogonal mirrors, the Coxeter notation is simplified with exponents to represent the number of branches in a row for linear diagram. So the An group is represented by, to imply n nodes connected by n-1 order-3 branches, example A2 = = or represents diagrams or. Coxeter initially represented bifurcating diagrams with vertical positioning of numbers, but later abbreviated with an exponent notation, like, Coxeter allowed for zeros as special cases to fit the An family, like A3 = = = =, like = =. Coxeter groups formed by cyclic diagrams are represented by parenthesese inside of brackets, if the branch orders are equal, they can be grouped as an exponent as the length the cycle in brackets, like =, representing Coxeter diagram or. More complicated looping diagrams can also be expressed with care, the paracompact complete graph diagram or, is represented as with the superscript as the symmetry of its regular tetrahedron coxeter diagram. The Coxeter diagram usually leaves order-2 branches undrawn, but the bracket notation includes an explicit 2 to connect the subgraphs, so the Coxeter diagram = A2×A2 = 2A2 can be represented by × =2 =. For the affine and hyperbolic groups, the subscript is one less than the number of nodes in each case, Coxeters notation represents rotational/translational symmetry by adding a + superscript operator outside the brackets which cuts the order of the group in half. This is called a direct subgroup because what remains are only direct isometries without reflective symmetry, + operators can also be applied inside of the brackets, and creates semidirect subgroups that include both reflective and nonreflective generators. Semidirect subgroups can only apply to Coxeter group subgroups that have even order branches next to it, the subgroup index is 2n for n + operators. So the snub cube, has symmetry +, and the tetrahedron, has symmetry. Johnson extends the + operator to work with a placeholder 1 nodes, in general this operation only applies to mirrors bounded by all even-order branches. The 1 represents a mirror so can be seen as, or, like diagram or, the effect of a mirror removal is to duplicate connecting nodes, which can be seen in the Coxeter diagrams, =, or in bracket notation, = =. Each of these mirrors can be removed so h = = = and this can be shown in a Coxeter diagram by adding a + symbol above the node, = =. If both mirrors are removed, a subgroup is generated, with the branch order becoming a gyration point of half the order, q = = +. For example, = = = ×, order 4. = +, the opposite to halving is doubling which adds a mirror, bisecting a fundamental domain, and doubling the group order
16.
Chirality (chemistry)
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Chirality /kaɪˈrælɪti/ is a geometric property of some molecules and ions. A chiral molecule/ion is non-superposable on its mirror image, the presence of an asymmetric carbon center is one of several structural features that induce chirality in organic and inorganic molecules. The term chirality is derived from the Greek word for hand, the mirror images of a chiral molecule/ion are called enantiomers or optical isomers. Individual enantiomers are often designated as either right- or left-handed, Chirality is an essential consideration when discussing the stereochemistry in organic and inorganic chemistry. The concept is of practical importance because most biomolecules and pharmaceuticals are chiral. Chirality is based on molecular symmetry elements, specifically, a chiral compound can contain no improper axis of rotation, which includes planes of symmetry and inversion center. Chiral molecules are always dissymmetric but not always asymmetric, in general, chiral molecules have point chirality at a single stereogenic atom, which has four different substituents. The two enantiomers of such compounds are said to have different absolute configurations at this center, the stereogenic atom is usually carbon, as in many biological molecules. However chirality can exist in any atom, including metals, phosphorus, Chiral nitrogen is equally possible, although the effects of nitrogen inversion can make many of these compounds impossible to isolate. While the presence of a stereogenic atom describes the great majority of cases, for instance it is not necessary for the chiral substance to have a stereogenic atom. Examples include 1-bromo-1-chloro-1-fluoroadamantane, methylethylphenyltetrahedrane, certain calixarenes and fullerenes, which have inherent chirality, the C2-symmetric species 1, 1-bi-2-naphthol,1, 3-dichloro-allene have axial chirality. -cyclooctene and many ferrocenes have planar chirality, when the optical rotation for an enantiomer is too low for practical measurement, the species is said to exhibit cryptochirality. Even isotopic differences must be considered when examining chirality, illustrative is the derivative of benzyl alcohol PhCHDOH is chiral. The S enantiomer has D = +0. 715°, many biologically active molecules are chiral, including the naturally occurring amino acids and sugars. In biological systems, most of these compounds are of the chirality, most amino acids are levorotatory. Typical naturally occurring proteins, made of L amino acids, are known as left-handed proteins, d-amino acids are very rare in nature and have only been found in small peptides attached to bacteria cell walls. The origin of this homochirality in biology is the subject of much debate, however, there is some suggestion that early amino acids could have formed in comet dust. Enzymes, which are chiral, often distinguish between the two enantiomers of a chiral substrate, one could imagine an enzyme as having a glove-like cavity that binds a substrate
17.
Chemical polarity
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In chemistry, polarity is a separation of electric charge leading to a molecule or its chemical groups having an electric dipole or multipole moment. Polar molecules must contain polar bonds due to a difference in electronegativity between the bonded atoms, a polar molecule with two or more polar bonds must have an asymmetric geometry so that the bond dipoles do not cancel each other. Polar molecules interact through dipole–dipole intermolecular forces and hydrogen bonds, Polarity underlies a number of physical properties including surface tension, solubility, and melting and boiling points. Not all atoms attract electrons with the same force, the amount of pull an atom exerts on its electrons is called its electronegativity. Atoms with high electronegativities – such as fluorine, oxygen and nitrogen – exert a pull on electrons than atoms with lower electronegativities. In a bond, this leads to sharing of electrons between the atoms, as electrons will be drawn closer to the atom with the higher electronegativity. Because electrons have a charge, the unequal sharing of electrons within a bond leads to the formation of an electric dipole. Because the amount of charge separated in such dipoles is usually smaller than a charge, they are called partial charges, denoted as δ+. These symbols were introduced by Christopher Kelk Ingold and Edith Hilda Ingold in 1926, the bond dipole moment is calculated by multiplying the amount of charge separated and the distance between the charges. These dipoles within molecules can interact with dipoles in other molecules, Bonds can fall between one of two extremes – being completely nonpolar or completely polar. A completely nonpolar bond occurs when the electronegativities are identical and therefore possess a difference of zero, a completely polar bond is more correctly called an ionic bond, and occurs when the difference between electronegativities is large enough that one atom actually takes an electron from the other. The terms polar and nonpolar are usually applied to covalent bonds, to determine the polarity of a covalent bond using numerical means, the difference between the electronegativity of the atoms is used. Bond polarity is typically divided into three groups that are based on the difference in electronegativity between the two bonded atoms. He estimated that a difference of 1.7 corresponds to 50% ionic character, see also dipole § Molecular dipoles. While the molecules can be described as covalent, nonpolar covalent, or ionic. However, the properties are typical of such molecules. A molecule is composed of one or more chemical bonds between molecular orbitals of different atoms, a polar molecule has a net dipole as a result of the opposing charges from polar bonds arranged asymmetrically. Water is an example of a polar molecule since it has a positive charge on one side
18.
Halotrichite
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Halotrichite, also known as feather alum, is a highly hydrated sulfate of aluminium and iron. It is formed by the weathering and decomposition of pyrite commonly near or in volcanic vents, the locations of natural occurrences include, the Atacama Desert, Chile, Dresden in Saxony, Germany, San Juan County, Utah, Iceland and Mont Saint-Hilaire, Canada. The name is from Latin, halotrichum for salt hair which accurately describes the precipitate/evaporite mineral
19.
Hilgardite
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Hilgardite is a borate mineral with the chemical formula Ca2B5O9Cl·H2O. It is transparent and has vitreous luster and it is colorless to light pink with a white streak. It is rated 5 on the Mohs Scale and it crystallizes in the triclinic crystal system. Crystals occur as distorted tabular triangles and are hemimorphic, polytypes exist and it was named for geologist Eugene W. Hilgard. It was first described in 1937 for an occurrence in the Choctaw Salt Dome of Iberville Parish, Louisiana and it occurs as an uncommon accessory mineral in evaporite deposits and salt domes worldwide. In Europe it is reported from the Konigshall-Hindenburg potash mine near Göttingen, Lower Saxony, Germany and in the Boulby potash mine, Whitby, Yorkshire, England. In Asia it is reported from the Chelkar salt dome, Uralsk district, Kazakhstan, the Ilga Basin, eastern Siberia, Russia, list of minerals S. Ghose and C. Wan, Hilgardite, Ca2Cl·H2O, a piezoelectric zeolite-type pentaborate, American Mineralogist, February 1979, v.64, 1-2, p. 187-195 Burns, P. C. and F. C. Hawthorne, Refinement of the structure of Hilgardite-1A, Acta crystallographica
20.
Centrosymmetry
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In crystallography, a point group which contains an inversion center as one of its symmetry elements is centrosymmetric. In such a point group, for point in the unit cell there is an indistinguishable point. Such point groups are said to have inversion symmetry. Point reflection is a term used in geometry. Crystals with an inversion center cannot display certain properties, such as the piezoelectric effect, point groups lacking an inversion center are further divided into polar and chiral types. A chiral point group is one without any rotoinversion symmetry elements, rotoinversion is rotation followed by inversion, for example, a mirror reflection corresponds to a twofold rotoinversion. Chiral point groups must therefore only contain rotational symmetry and these arise from the crystal point groups 1,2,3,4,6,222,422,622,32,23, and 432. Chiral molecules such as proteins crystallize in chiral point groups, the term polar is often used for those point groups which are neither centrosymmetric nor chiral. However, the term is more used for any point group containing a unique anisotropic axis. These occur in crystal point groups 1,2,3,4,6, m, mm2, 3m, 4mm, thus some chiral space groups are also polar
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Gypsum
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Gypsum is a soft sulfate mineral composed of calcium sulfate dihydrate, with the chemical formula CaSO4·2H2O. It is widely mined and is used as a fertilizer, and as the constituent in many forms of plaster, blackboard chalk. Mohs scale of hardness, based on scratch Hardness comparison. It forms as a mineral and as a hydration product of anhydrite. The word gypsum is derived from the Greek word γύψος, plaster, because the quarries of the Montmartre district of Paris have long furnished burnt gypsum used for various purposes, this dehydrated gypsum became known as plaster of Paris. Upon addition of water, after a few tens of minutes plaster of Paris becomes regular gypsum again, causing the material to harden or set in ways that are useful for casting, Gypsum was known in Old English as spærstān, spear stone, referring to its crystalline projections. Gypsum may act as a source of sulfur for plant growth, which was discovered by J. M. Mayer, american farmers were so anxious to acquire it that a lively smuggling trade with Nova Scotia evolved, resulting in the so-called Plaster War of 1820. In the 19th century, it was known as lime sulfate or sulfate of lime. Gypsum is moderately water-soluble and, in contrast to most other salts, it exhibits retrograde solubility, when gypsum is heated in air it loses water and converts first to calcium sulfate hemihydrate, and, if heated further, to anhydrous calcium sulfate. As for anhydrite, its solubility in saline solutions and in brines is also dependent on NaCl concentration. Gypsum crystals are found to contain water and hydrogen bonding. Gypsum occurs in nature as flattened and often twinned crystals, and transparent, selenite contains no significant selenium, rather, both substances were named for the ancient Greek word for the Moon. Selenite may also occur in a silky, fibrous form, in case it is commonly called satin spar. Finally, it may also be granular or quite compact, in hand-sized samples, it can be anywhere from transparent to opaque. A very fine-grained white or lightly tinted variety of gypsum, called alabaster, is prized for ornamental work of various sorts, in arid areas, gypsum can occur in a flower-like form, typically opaque, with embedded sand grains called desert rose. It also forms some of the largest crystals found in nature, up to 12 m long, Gypsum is a common mineral, with thick and extensive evaporite beds in association with sedimentary rocks. Deposits are known to occur in strata from as far back as the Archaean eon, Gypsum is deposited from lake and sea water, as well as in hot springs, from volcanic vapors, and sulfate solutions in veins. Hydrothermal anhydrite in veins is commonly hydrated to gypsum by groundwater in near-surface exposures and it is often associated with the minerals halite and sulfur
22.
Wallpaper group
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A wallpaper group is a mathematical classification of a two-dimensional repetitive pattern, based on the symmetries in the pattern. Such patterns occur frequently in architecture and decorative art, There are 17 possible distinct groups. Wallpaper groups are two-dimensional symmetry groups, intermediate in complexity between the simpler frieze groups and the space groups. Wallpaper groups categorize patterns by their symmetries, subtle differences may place similar patterns in different groups, while patterns that are very different in style, color, scale or orientation may belong to the same group. Consider the following examples, Examples A and B have the same group, it is called p4m in the IUC notation. Example C has a different wallpaper group, called p4g or 4*2, a complete list of all seventeen possible wallpaper groups can be found below. A symmetry of a pattern is, loosely speaking, a way of transforming the pattern so that it exactly the same after the transformation. For example, translational symmetry is present when the pattern can be translated some finite distance, think of shifting a set of vertical stripes horizontally by one stripe. Strictly speaking, a true symmetry only exists in patterns that repeat exactly, a set of only, say, five stripes does not have translational symmetry—when shifted, the stripe on one end disappears and a new stripe is added at the other end. In practice, however, classification is applied to finite patterns, sometimes two categorizations are meaningful, one based on shapes alone and one also including colors. When colors are ignored there may be more symmetry, the types of transformations that are relevant here are called Euclidean plane isometries. This type of symmetry is called a translation, Examples A and C are similar, except that the smallest possible shifts are in diagonal directions. If we turn example B clockwise by 90°, around the centre of one of the squares, Examples A and C also have 90° rotations, although it requires a little more ingenuity to find the correct centre of rotation for C. We can also flip example B across a horizontal axis that runs across the middle of the image, example B also has reflections across a vertical axis, and across two diagonal axes. The same can be said for A. However, example C is different and it only has reflections in horizontal and vertical directions, not across diagonal axes. If we flip across a line, we do not get the same pattern back. This is part of the reason that the group of A and B is different from the wallpaper group of C. A proof that there were only 17 possible patterns was first carried out by Evgraf Fedorov in 1891, the proof that the list of wallpaper groups was complete only came after the much harder case of space groups had been done
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International Standard Book Number
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The International Standard Book Number is a unique numeric commercial book identifier. An ISBN is assigned to each edition and variation of a book, for example, an e-book, a paperback and a hardcover edition of the same book would each have a different ISBN. The ISBN is 13 digits long if assigned on or after 1 January 2007, the method of assigning an ISBN is nation-based and varies from country to country, often depending on how large the publishing industry is within a country. The initial ISBN configuration of recognition was generated in 1967 based upon the 9-digit Standard Book Numbering created in 1966, the 10-digit ISBN format was developed by the International Organization for Standardization and was published in 1970 as international standard ISO2108. Occasionally, a book may appear without a printed ISBN if it is printed privately or the author does not follow the usual ISBN procedure, however, this can be rectified later. Another identifier, the International Standard Serial Number, identifies periodical publications such as magazines, the ISBN configuration of recognition was generated in 1967 in the United Kingdom by David Whitaker and in 1968 in the US by Emery Koltay. The 10-digit ISBN format was developed by the International Organization for Standardization and was published in 1970 as international standard ISO2108, the United Kingdom continued to use the 9-digit SBN code until 1974. The ISO on-line facility only refers back to 1978, an SBN may be converted to an ISBN by prefixing the digit 0. For example, the edition of Mr. J. G. Reeder Returns, published by Hodder in 1965, has SBN340013818 -340 indicating the publisher,01381 their serial number. This can be converted to ISBN 0-340-01381-8, the check digit does not need to be re-calculated, since 1 January 2007, ISBNs have contained 13 digits, a format that is compatible with Bookland European Article Number EAN-13s. An ISBN is assigned to each edition and variation of a book, for example, an ebook, a paperback, and a hardcover edition of the same book would each have a different ISBN. The ISBN is 13 digits long if assigned on or after 1 January 2007, a 13-digit ISBN can be separated into its parts, and when this is done it is customary to separate the parts with hyphens or spaces. Separating the parts of a 10-digit ISBN is also done with either hyphens or spaces, figuring out how to correctly separate a given ISBN number is complicated, because most of the parts do not use a fixed number of digits. ISBN issuance is country-specific, in that ISBNs are issued by the ISBN registration agency that is responsible for country or territory regardless of the publication language. Some ISBN registration agencies are based in national libraries or within ministries of culture, in other cases, the ISBN registration service is provided by organisations such as bibliographic data providers that are not government funded. In Canada, ISBNs are issued at no cost with the purpose of encouraging Canadian culture. In the United Kingdom, United States, and some countries, where the service is provided by non-government-funded organisations. Australia, ISBNs are issued by the library services agency Thorpe-Bowker
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Springer Science+Business Media
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Springer also hosts a number of scientific databases, including SpringerLink, Springer Protocols, and SpringerImages. Book publications include major works, textbooks, monographs and book series. Springer has major offices in Berlin, Heidelberg, Dordrecht, on 15 January 2015, Holtzbrinck Publishing Group / Nature Publishing Group and Springer Science+Business Media announced a merger. In 1964, Springer expanded its business internationally, opening an office in New York City, offices in Tokyo, Paris, Milan, Hong Kong, and Delhi soon followed. The academic publishing company BertelsmannSpringer was formed after Bertelsmann bought a majority stake in Springer-Verlag in 1999, the British investment groups Cinven and Candover bought BertelsmannSpringer from Bertelsmann in 2003. They merged the company in 2004 with the Dutch publisher Kluwer Academic Publishers which they bought from Wolters Kluwer in 2002, Springer acquired the open-access publisher BioMed Central in October 2008 for an undisclosed amount. In 2009, Cinven and Candover sold Springer to two private equity firms, EQT Partners and Government of Singapore Investment Corporation, the closing of the sale was confirmed in February 2010 after the competition authorities in the USA and in Europe approved the transfer. In 2011, Springer acquired Pharma Marketing and Publishing Services from Wolters Kluwer, in 2013, the London-based private equity firm BC Partners acquired a majority stake in Springer from EQT and GIC for $4.4 billion. In 2014, it was revealed that Springer had published 16 fake papers in its journals that had been computer-generated using SCIgen, Springer subsequently removed all the papers from these journals. IEEE had also done the thing by removing more than 100 fake papers from its conference proceedings. In 2015, Springer retracted 64 of the papers it had published after it was found that they had gone through a fraudulent peer review process, Springer provides its electronic book and journal content on its SpringerLink site, which launched in 1996. SpringerProtocols is home to a collection of protocols, recipes which provide step-by-step instructions for conducting experiments in research labs, SpringerImages was launched in 2008 and offers a collection of currently 1.8 million images spanning science, technology, and medicine. SpringerMaterials was launched in 2009 and is a platform for accessing the Landolt-Börnstein database of research and information on materials, authorMapper is a free online tool for visualizing scientific research that enables document discovery based on author locations and geographic maps. The tool helps users explore patterns in scientific research, identify trends, discover collaborative relationships. While open-access publishing typically requires the author to pay a fee for copyright retention, for example, a national institution in Poland allows authors to publish in open-access journals without incurring any personal cost - but using public funds. Springer is a member of the Open Access Scholarly Publishers Association, the Academic Publishing Industry, A Story of Merger and Acquisition – via Northern Illinois University
25.
Triclinic crystal system
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In crystallography, the triclinic crystal system is one of the 7 crystal systems. A crystal system is described by three basis vectors, in the triclinic system, the crystal is described by vectors of unequal length, as in the orthorhombic system. In addition, no vector is at right angles orthogonal to another, the triclinic lattice is the least symmetric of the 14 three-dimensional Bravais lattices. It is the lattice type that itself has no mirror planes. There are a total 2 space groups, with each only one space group is associated. Pinacoidal is also known as triclinic normal, pedial is also triclinic hemihedral Mineral examples include plagioclase, microcline, rhodonite, turquoise, wollastonite and amblygonite, all in triclinic normal. Crystal structure Hurlbut, Cornelius S. Klein, Cornelis,1985, Manual of Mineralogy, 20th ed. pp.64 –65, ISBN 0-471-80580-7
26.
Tetragonal crystal system
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In crystallography, the tetragonal crystal system is one of the 7 crystal systems. Tetragonal crystal lattices result from stretching a cubic lattice along one of its vectors, so that the cube becomes a rectangular prism with a square base. There is only one tetragonal Bravais lattice in two dimensions, the square lattice, there are two tetragonal Bravais lattices, the simple tetragonal and the centered tetragonal. One might suppose stretching face-centered cubic would result in face-centered tetragonal, BCT is considered more fundamental, so that is the standard terminology. Crystal structure point groups Bravais lattices
27.
Hexagonal crystal family
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In crystallography, the hexagonal crystal family is one of the 6 crystal families. In the hexagonal family, the crystal is described by a right rhombic prism unit cell with two equal axes, an included angle of 120° and a height perpendicular to the two base axes. There are 52 space groups associated with it, which are exactly those whose Bravais lattice is either hexagonal or rhombohedral, the hexagonal crystal family consists of two lattice systems, hexagonal and rhombohedral. Each lattice system consists of one Bravais lattice, hence, there are 3 lattice points per unit cell in total and the lattice is non-primitive. The Bravais lattices in the hexagonal crystal family can also be described by rhombohedral axes, the unit cell is a rhombohedron. This is a cell with parameters a = b = c, α = β = γ ≠ 90°. In practice, the description is more commonly used because it is easier to deal with a coordinate system with two 90° angles. However, the axes are often shown in textbooks because this cell reveals 3m symmetry of crystal lattice. However, such a description is rarely used, the hexagonal crystal family consists of two crystal systems, trigonal and hexagonal. A crystal system is a set of point groups in which the point groups themselves, the trigonal crystal system consists of the 5 point groups that have a single three-fold rotation axis. The crystal structures of alpha-quartz in the example are described by two of those 18 space groups associated with the hexagonal lattice system. The hexagonal crystal system consists of the seven point groups such that all their groups have the hexagonal lattice as underlying lattice. Graphite is an example of a crystal that crystallizes in the crystal system. Note that the atom in the center of the HCP unit cell in the hexagonal lattice system does not appear in the unit cell of the hexagonal lattice. It is part of the two atom motif associated with each point in the underlying lattice. The trigonal crystal system is the crystal system whose point groups have more than one lattice system associated with their space groups. The 5 point groups in this system are listed below, with their international number and notation, their space groups in name. The point groups in this system are listed below, followed by their representations in Hermann–Mauguin or international notation and Schoenflies notation
28.
Cubic crystal system
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In crystallography, the cubic crystal system is a crystal system where the unit cell is in the shape of a cube. This is one of the most common and simplest shapes found in crystals and minerals, there are three main varieties of these crystals, Primitive cubic Body-centered cubic, Face-centered cubic Each is subdivided into other variants listed below. Note that although the cell in these crystals is conventionally taken to be a cube. This is related to the fact that in most cubic crystal systems, a classic isometric crystal has square or pentagonal faces. The three Bravais lattices in the crystal system are, The primitive cubic system consists of one lattice point on each corner of the cube. Each atom at a point is then shared equally between eight adjacent cubes, and the unit cell therefore contains in total one atom. The body-centered cubic system has one point in the center of the unit cell in addition to the eight corner points. It has a net total of 2 lattice points per unit cell, Each sphere in a cF lattice has coordination number 12. The face-centered cubic system is related to the hexagonal close packed system. The plane of a cubic system is a hexagonal grid. Attempting to create a C-centered cubic crystal system would result in a simple tetragonal Bravais lattice, there are a total 36 cubic space groups. Other terms for hexoctahedral are, normal class, holohedral, ditesseral central class, a simple cubic unit cell has a single cubic void in the center. Additionally, there are 24 tetrahedral voids located in a square spacing around each octahedral void and these tetrahedral voids are not local maxima and are not technically voids, but they do occasionally appear in multi-atom unit cells. A face-centered cubic unit cell has eight tetrahedral voids located midway between each corner and the center of the cell, for a total of eight net tetrahedral voids. One important characteristic of a structure is its atomic packing factor. This is calculated by assuming all the atoms are identical spheres. The atomic packing factor is the proportion of space filled by these spheres, assuming one atom per lattice point, in a primitive cubic lattice with cube side length a, the sphere radius would be a⁄2 and the atomic packing factor turns out to be about 0.524. Similarly, in a bcc lattice, the atomic packing factor is 0.680, as a rule, since atoms in a solid attract each other, the more tightly packed arrangements of atoms tend to be more common
