Raney nickel, also called spongy nickel, is a fine-grained solid composed mostly of nickel derived from a nickel–aluminium alloy. Several grades are known, of which most are gray solids. Some are pyrophoric, but most are used as air-stable slurries. Raney nickel is used as a reagent and as a catalyst in organic chemistry. It was developed in 1926 by American engineer Murray Raney for the hydrogenation of vegetable oils.
Raney is a registered trademark of W. R. Grace and Company. Other major producers are Evonik and Johnson Matthey.
Dry activated Raney nickel
Raney nickel is pyrophoric and must be handled with care. This shipping container is filled with vermiculite to protect the sealed bottle inside.
Nickel is a chemical element; it has symbol Ni and atomic number 28. It is a silvery-white lustrous metal with a slight golden tinge. Nickel is a hard and ductile transition metal. Pure nickel is chemically reactive, but large pieces are slow to react with air under standard conditions because a passivation layer of nickel oxide forms on the surface that prevents further corrosion. Even so, pure native nickel is found in Earth's crust only in tiny amounts, usually in ultramafic rocks, and in the interiors of larger nickel–iron meteorites that were not exposed to oxygen when outside Earth's atmosphere.
Nickel
Electron micrograph of a Ni nanocrystal inside a single wall carbon nanotube; scale bar 5 nm
Widmanstätten pattern showing the two forms of nickel–iron, kamacite and taenite, in an octahedrite meteorite
Color of various Ni(II) complexes in aqueous solution. From left to right, [Ni(NH3)6]2+, [Ni(NH2CH2CH2NH2)]2+, [NiCl4]2−, [Ni(H2O)6]2+