Sanidine is the high temperature form of potassium feldspar with a general formula K(AlSi3O8). Sanidine is found most typically in felsic volcanic rocks such as obsidian, rhyolite and trachyte. Sanidine crystallizes in the monoclinic crystal system. Orthoclase is a monoclinic polymorph stable at lower temperatures. At yet lower temperatures, microcline, a triclinic polymorph of potassium feldspar, is stable.

Microcline (KAlSi3O8) is an important igneous rock-forming tectosilicate mineral. It is a potassium-rich alkali feldspar. Microcline typically contains minor amounts of sodium. It is common in granite and pegmatites. Microcline forms during slow cooling of orthoclase; it is more stable at lower temperatures than orthoclase. Sanidine is a polymorph of alkali feldspar stable at yet higher temperature. Microcline may be clear, white, pale-yellow, brick-red, or green; it is generally characterized by cross-hatch twinning that forms as a result of the transformation of monoclinic orthoclase into triclinic microcline.