1.
Ceramic
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A ceramic is an inorganic, non-metallic, solid material comprising metal, non-metal or metalloid atoms primarily held in ionic and covalent bonds. This article gives an overview of ceramic materials from the point of view of materials science, the crystallinity of ceramic materials ranges from highly oriented to semi-crystalline, vitrified, and often completely amorphous. Most often, fired ceramics are either vitrified or semi-vitrified as is the case with earthenware, stoneware, varying crystallinity and electron consumption in the ionic and covalent bonds cause most ceramic materials to be good thermal and electrical insulators. With such a range of possible options for the composition/structure of a ceramic, the breadth of the subject is vast. Many composites, such as fiberglass and carbon fiber, while containing ceramic materials, are not considered to be part of the ceramic family. The earliest ceramics made by humans were pottery objects or figurines made from clay, either by itself or mixed with materials like silica, hardened, sintered. Later ceramics were glazed and fired to create smooth, colored surfaces, decreasing porosity through the use of glassy, ceramics now include domestic, industrial and building products, as well as a wide range of ceramic art. In the 20th century, new materials were developed for use in advanced ceramic engineering. The word ceramic comes from the Greek word κεραμικός, of pottery or for pottery, from κέραμος, potters clay, tile, the earliest known mention of the root ceram- is the Mycenaean Greek ke-ra-me-we, workers of ceramics, written in Linear B syllabic script. The word ceramic may be used as an adjective to describe a material, product or process, or it may be used as a noun, either singular, or, more commonly, as the plural noun ceramics. A ceramic material is an inorganic, non-metallic, often crystalline oxide, nitride or carbide material, some elements, such as carbon or silicon, may be considered ceramics. Ceramic materials are brittle, hard, strong in compression, weak in shearing and they withstand chemical erosion that occurs in other materials subjected to acidic or caustic environments. Ceramics generally can withstand high temperatures, such as temperatures that range from 1,000 °C to 1,600 °C. Glass is often not considered a ceramic because of its amorphous character. However, glassmaking involves several steps of the process and its mechanical properties are similar to ceramic materials. Traditional ceramic raw materials include minerals such as kaolinite, whereas more recent materials include aluminium oxide. The modern ceramic materials, which are classified as advanced ceramics, include silicon carbide, both are valued for their abrasion resistance, and hence find use in applications such as the wear plates of crushing equipment in mining operations. Advanced ceramics are used in the medicine, electrical, electronics industries. Crystalline ceramic materials are not amenable to a range of processing
2.
Glass art
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Glass art refers to individual works of art that are substantially or wholly made of glass. It ranges in size from monumental works and installation pieces, to wall hangings and windows, to works of art made in studios and factories, including glass jewelry, as a decorative and functional medium, glass was extensively developed in Egypt and Assyria. Invented by the Phoenicians, was brought to the fore by the Romans, Glass from Murano, in the Venetian Lagoon, is the result of hundreds of years of refinement and invention. Murano is still held as the birthplace of modern glass art, the turn of the 19th Century was the height of the old art glass movement while the factory glass blowers were being replaced by mechanical bottle blowing and continuous window glass. Great ateliers like Tiffany, Lalique, Daum, Gallé, the Corning schools in upper New York state, the first uses of glass were in beads and other small pieces of jewelry and decoration. Beads and jewelry are still among the most common uses of glass in art and it later became fashionable to wear functional jewelry with glass elements, such as pocketwatches and monocles. Starting in the late 20th century, glass couture refers to the creation of exclusive custom-fitted clothing made from sculpted glass and these are made to order for the body of the wearer. They are partly or entirely made of glass with extreme attention to fit, the result is usually delicate, and not intended for regular use. Some of the earliest and most practical works of art were glass vessels. Goblets and pitchers were popular as glassblowing developed as an art form, many early methods of etching, painting, and forming glass were honed on these vessels. For instance the technique dates back at least to Rome. More recently, lead glass or crystal glass were used to make vessels that rang like a bell when struck, in the 20th century, mass produced glass work including artistic glass vessels were sometimes known as factory glass. Starting in the Middle Ages, glass became more widely produced, Stained glass became common for windows in cathedrals and grand civic buildings. The invention of glass and the Bessemer process allowed for glass to be used in larger segments, to support more structural loads. A striking example of this was the Crystal Palace in 1851, in the 20th century, glass became used for tables and shelves, for internal walls, and even for floors. Some of the best known sculptures are statuesque or monumental structures such as the statues by Livio Seguso, or by Stanislav Libenský. Another example is René Roubíceks Object 1960, a blown and hot-worked piece of 52.2 cm shown at the Design in an Age of Adversity exhibition at the Corning Museum of Glass in 2005, in the early 20th century, most glass production happened in factories. Even individual glassblowers making their own personalized designs would do their work in large shared buildings
3.
Rust
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Rust is an iron oxide, usually red oxide formed by the redox reaction of iron and oxygen in the presence of water or air moisture. Several forms of rust are distinguishable both visually and by spectroscopy, and form under different circumstances, Rust consists of hydrated iron oxides Fe2O3·nH2O and iron oxide-hydroxide. Given sufficient time, oxygen, and water, any iron mass will eventually convert entirely to rust, surface rust is flaky and friable, and it provides no protection to the underlying iron, unlike the formation of patina on copper surfaces. Rusting is the term for corrosion of iron and its alloys. Many other metals undergo similar corrosion, but the resulting oxides are not commonly called rust, other forms of rust exist, like the result of reactions between iron and chloride in an environment deprived of oxygen. Rebar used in concrete pillars, which generates green rust, is an example. Rust is another name for iron oxide, which occurs when iron or an alloy that contains iron, like steel, is exposed to oxygen and moisture for a long period of time. Over time, the oxygen combines with the metal at a level, forming a new compound called an oxide. Although some people refer to rust generally as oxidation, that term is more general, although rust forms when iron undergoes oxidation. Only iron or alloys that contain iron can rust, but other metals can corrode in similar ways, the main catalyst for the rusting process is water. Iron or steel structures might appear to be solid, but water molecules can penetrate the microscopic pits, the hydrogen atoms present in water molecules can combine with other elements to form acids, which will eventually cause more metal to be exposed. If chloride ions are present, as is the case with saltwater, meanwhile, the oxygen atoms combine with metallic atoms to form the destructive oxide compound. As the atoms combine, they weaken the metal, making the structure brittle, when impure iron is in contact with water, oxygen, other strong oxidants, or acids, it rusts. If salt is present, for example in seawater or salt spray, iron metal is relatively unaffected by pure water or by dry oxygen. As with other metals, like aluminium, a tightly adhering oxide coating, the conversion of the passivating ferrous oxide layer to rust results from the combined action of two agents, usually oxygen and water. Other degrading solutions are sulfur dioxide in water and carbon dioxide in water, under these corrosive conditions, iron hydroxide species are formed. Unlike ferrous oxides, the hydroxides do not adhere to the bulk metal, when iron rusts, the oxides take up more volume than the original metal, this expansion can generate enormous forces, damaging structures made with iron. See Economic effect for more details, the rusting of iron is an electrochemical process that begins with the transfer of electrons from iron to oxygen
4.
Metal
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A metal is a material that is typically hard, opaque, shiny, and has good electrical and thermal conductivity. Metals are generally malleable—that is, they can be hammered or pressed permanently out of shape without breaking or cracking—as well as fusible and ductile, about 91 of the 118 elements in the periodic table are metals, the others are nonmetals or metalloids. Some elements appear in both metallic and non-metallic forms, astrophysicists use the term metal to collectively describe all elements other than hydrogen and helium, the simplest two, in a star. The star fuses smaller atoms, mostly hydrogen and helium, to larger ones over its lifetime. In that sense, the metallicity of an object is the proportion of its matter made up of all chemical elements. Many elements and compounds that are not normally classified as metals become metallic under high pressures, the atoms of metallic substances are typically arranged in one of three common crystal structures, namely body-centered cubic, face-centered cubic, and hexagonal close-packed. In bcc, each atom is positioned at the center of a cube of eight others, in fcc and hcp, each atom is surrounded by twelve others, but the stacking of the layers differs. Some metals adopt different structures depending on the temperature, atoms of metals readily lose their outer shell electrons, resulting in a free flowing cloud of electrons within their otherwise solid arrangement. This provides the ability of metallic substances to easily transmit heat, while this flow of electrons occurs, the solid characteristic of the metal is produced by electrostatic interactions between each atom and the electron cloud. This type of bond is called a metallic bond, Metals are usually inclined to form cations through electron loss, reacting with oxygen in the air to form oxides over various timescales. Examples,4 Na + O2 →2 Na2O2 Ca + O2 →2 CaO4 Al +3 O2 →2 Al2O3, the transition metals are slower to oxidize because they form a passivating layer of oxide that protects the interior. Others, like palladium, platinum and gold, do not react with the atmosphere at all, some metals form a barrier layer of oxide on their surface which cannot be penetrated by further oxygen molecules and thus retain their shiny appearance and good conductivity for many decades. The oxides of metals are generally basic, as opposed to those of nonmetals, exceptions are largely oxides with very high oxidation states such as CrO3, Mn2O7, and OsO4, which have strictly acidic reactions. Painting, anodizing or plating metals are good ways to prevent their corrosion, however, a more reactive metal in the electrochemical series must be chosen for coating, especially when chipping of the coating is expected. Water and the two form an electrochemical cell, and if the coating is less reactive than the coatee. Metals in general have high conductivity, high thermal conductivity. Typically they are malleable and ductile, deforming under stress without cleaving, in terms of optical properties, metals are shiny and lustrous. Sheets of metal beyond a few micrometres in thickness appear opaque, although most metals have higher densities than most nonmetals, there is wide variation in their densities, lithium being the least dense solid element and osmium the densest
5.
Aluminium
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Aluminium or aluminum is a chemical element in the boron group with symbol Al and atomic number 13. It is a silvery-white, soft, nonmagnetic, ductile metal, Aluminium metal is so chemically reactive that native specimens are rare and limited to extreme reducing environments. Instead, it is combined in over 270 different minerals. The chief ore of aluminium is bauxite, Aluminium is remarkable for the metals low density and its ability to resist corrosion through the phenomenon of passivation. Aluminium and its alloys are vital to the industry and important in transportation and structures, such as building facades. The oxides and sulfates are the most useful compounds of aluminium, despite its prevalence in the environment, no known form of life uses aluminium salts metabolically, but aluminium is well tolerated by plants and animals. Because of these salts abundance, the potential for a role for them is of continuing interest. Aluminium is a soft, durable, lightweight, ductile. It is nonmagnetic and does not easily ignite, a fresh film of aluminium serves as a good reflector of visible light and an excellent reflector of medium and far infrared radiation. The yield strength of aluminium is 7–11 MPa, while aluminium alloys have yield strengths ranging from 200 MPa to 600 MPa. Aluminium has about one-third the density and stiffness of steel and it is easily machined, cast, drawn and extruded. Aluminium atoms are arranged in a cubic structure. Aluminium has an energy of approximately 200 mJ/m2. Aluminium is a thermal and electrical conductor, having 59% the conductivity of copper. Aluminium is capable of superconductivity, with a critical temperature of 1.2 kelvin. Aluminium is the most common material for the fabrication of superconducting qubits, the strongest aluminium alloys are less corrosion resistant due to galvanic reactions with alloyed copper. This corrosion resistance is reduced by aqueous salts, particularly in the presence of dissimilar metals. In highly acidic solutions, aluminium reacts with water to form hydrogen, primarily because it is corroded by dissolved chlorides, such as common sodium chloride, household plumbing is never made from aluminium
6.
Brass
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Brass is a metal alloy made of copper and zinc, the proportions of zinc and copper can be varied to create a range of brasses with varying properties. It is an alloy, atoms of the two constituents may replace each other within the same crystal structure. By comparison, bronze is principally an alloy of copper and tin, however, bronze and brass may also include small proportions of a range of other elements including arsenic, phosphorus, aluminium, manganese, and silicon. The term is applied to a variety of brasses. Modern practice in museums and archaeology increasingly avoids both terms for objects in favour of the all-embracing copper alloy. It is also used in zippers, Brass is often used in situations in which it is important that sparks not be struck, such as in fittings and tools used near flammable or explosive materials. Brass has higher malleability than bronze or zinc, the relatively low melting point of brass and its flow characteristics make it a relatively easy material to cast. By varying the proportions of copper and zinc, the properties of the brass can be changed, allowing hard, the density of brass is 8.4 to 8.73 grams per cubic centimetre. Today, almost 90% of all alloys are recycled. Because brass is not ferromagnetic, it can be separated from ferrous scrap by passing the scrap near a powerful magnet, Brass scrap is collected and transported to the foundry where it is melted and recast into billets. Billets are heated and extruded into the form and size. The general softness of brass means that it can often be machined without the use of cutting fluid, aluminium makes brass stronger and more corrosion-resistant. Aluminium also causes a highly beneficial hard layer of oxide to be formed on the surface that is thin, transparent. Tin has an effect and finds its use especially in seawater applications. Combinations of iron, aluminium, silicon and manganese make brass wear and tear resistant, to enhance the machinability of brass, lead is often added in concentrations of around 2%. Since lead has a melting point than the other constituents of the brass. The pattern the globules form on the surface of the brass increases the available surface area which in turn affects the degree of leaching. In addition, cutting operations can smear the lead globules over the surface and these effects can lead to significant lead leaching from brasses of comparatively low lead content
7.
Bronze
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These additions produce a range of alloys that may be harder than copper alone, or have other useful properties, such as stiffness, ductility, or machinability. The archeological period where bronze was the hardest metal in use is known as the Bronze Age. In the ancient Near East this began with the rise of Sumer in the 4th millennium BC, with India and China starting to use bronze around the same time, everywhere it gradually spread across regions. The Bronze Age was followed by the Iron Age starting from about 1300 BC and reaching most of Eurasia by about 500 BC, the discovery of bronze enabled people to create metal objects which were harder and more durable than previously possible. Bronze tools, weapons, armor, and building such as decorative tiles were harder and more durable than their stone. It was only later that tin was used, becoming the major ingredient of bronze in the late 3rd millennium BC. Tin bronze was superior to arsenic bronze in that the process could be more easily controlled. Also, unlike arsenic, metallic tin and fumes from tin refining are not toxic, the earliest tin-alloy bronze dates to 4500 BCE in a Vinča culture site in Pločnik. Other early examples date to the late 4th millennium BC in Africa, Susa and some ancient sites in China, Luristan, ores of copper and the far rarer tin are not often found together, so serious bronze work has always involved trade. Tin sources and trade in ancient times had a influence on the development of cultures. In Europe, a source of tin was the British deposits of ore in Cornwall. In many parts of the world, large hoards of bronze artefacts are found, suggesting that bronze also represented a store of value, in Europe, large hoards of bronze tools, typically socketed axes, are found, which mostly show no signs of wear. With Chinese ritual bronzes, which are documented in the inscriptions they carry and from other sources and these were made in enormous quantities for elite burials, and also used by the living for ritual offerings. Pure iron is soft, and the process of beating and folding sponge iron to wrought iron removes from the metal carbon. Careful control of the alloying and tempering eventually allowed for wrought iron with properties comparable to modern steel, Bronze was still used during the Iron Age, and has continued in use for many purposes to the modern day. Among other advantages, it does not rust, the weaker wrought iron was found to be sufficiently strong for many uses. Archaeologists suspect that a disruption of the tin trade precipitated the transition. The population migrations around 1200–1100 BC reduced the shipping of tin around the Mediterranean, limiting supplies, there are many different bronze alloys, but typically modern bronze is 88% copper and 12% tin
8.
Stainless steel
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In metallurgy, stainless steel, also known as inox steel or inox from French inoxydable, is a steel alloy with a minimum of 10. 5% chromium content by mass. Stainless steel is notable for its resistance, and it is widely used for food handling. Stainless steel does not readily corrode, rust or stain with water as ordinary steel does, however, it is not fully stain-proof in low-oxygen, high-salinity, or poor air-circulation environments. There are various grades and surface finishes of stainless steel to suit the environment the alloy must endure, Stainless steel is used where both the properties of steel and corrosion resistance are required. Stainless steel differs from carbon steel by the amount of chromium present, unprotected carbon steel rusts readily when exposed to air and moisture. This iron oxide film is active and accelerates corrosion by making it easier for more iron oxide to form, since iron oxide has lower density than steel, the film expands and tends to flake and fall away. In comparison, stainless steels contain sufficient chromium to undergo passivation and this layer prevents further corrosion by blocking oxygen diffusion to the steel surface and stops corrosion from spreading into the bulk of the metal. Passivation occurs only if the proportion of chromium is high enough, Stainless steel’s resistance to corrosion and staining, low maintenance, and familiar lustre make it an ideal material for many applications. Storage tanks and tankers used to transport orange juice and other food are made of stainless steel. This also influences its use in kitchens and food processing plants, as it can be steam-cleaned and sterilized. High oxidation resistance in air at ambient temperature is achieved with addition of a minimum of 13% chromium. The chromium forms a layer of chromium oxide when exposed to oxygen. The layer is too thin to be visible, and the metal remains lustrous, the layer is impervious to water and air, protecting the metal beneath, and this layer quickly reforms when the surface is scratched. This phenomenon is called passivation and is seen in other metals, corrosion resistance can be adversely affected if the component is used in a non-oxygenated environment, a typical example being underwater keel bolts buried in timber. When stainless steel parts such as nuts and bolts are forced together, when forcibly disassembled, the welded material may be torn and pitted, a destructive effect known as galling. Galling can be avoided by the use of materials for the parts forced together, for example bronze and stainless steel. However, two different alloys electrically connected in a humid, even mildly acidic environment may act as a voltaic pile, nitronic alloys, made by selective alloying with manganese and nitrogen, may have a reduced tendency to gall. Additionally, threaded joints may be lubricated to provide a film between the two parts and prevent galling, low-temperature carburizing is another option that virtually eliminates galling and allows the use of similar materials without the risk of corrosion and the need for lubrication
9.
Wood
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Wood is a porous and fibrous structural tissue found in the stems and roots of trees, and other woody plants. It is a material, a natural composite of cellulose fibers which are strong in tension embedded in a matrix of lignin which resists compression. Wood is sometimes defined as only the secondary xylem in the stems of trees, in a living tree it performs a support function, enabling woody plants to grow large or to stand up by themselves. It also conveys water and nutrients between the leaves, other growing tissues, and the roots, Wood may also refer to other plant materials with comparable properties, and to material engineered from wood, or wood chips or fiber. In 2005, the stock of forests worldwide was about 434 billion cubic meters. As an abundant, carbon-neutral renewable resource, woody materials have been of intense interest as a source of renewable energy, in 1991 approximately 3.5 billion cubic meters of wood were harvested. Dominant uses were for furniture and building construction, a 2011 discovery in the Canadian province of New Brunswick discovered the earliest known plants to have grown wood, approximately 395 to 400 million years ago. Wood can be dated by carbon dating and in species by dendrochronology to make inferences about when a wooden object was created. People have used wood for millennia for many purposes, primarily as a fuel or as a material for making houses, tools, weapons, furniture, packaging, artworks. Constructions using wood date back ten thousand years, buildings like the European Neolithic long house were made primarily of wood. Recent use of wood has changed by the addition of steel. The year-to-year variation in tree-ring widths and isotopic abundances gives clues to the climate at that time. This process is known as growth, it is the result of cell division in the vascular cambium, a lateral meristem. These cells then go on to form thickened secondary cell walls, composed mainly of cellulose, hemicellulose, if the distinctiveness between seasons is annual, these growth rings are referred to as annual rings. Where there is little seasonal difference growth rings are likely to be indistinct or absent, if the bark of the tree has been removed in a particular area, the rings will likely be deformed as the plant overgrows the scar. It is usually lighter in color than that near the portion of the ring. The outer portion formed later in the season is known as the latewood or summerwood. However, there are differences, depending on the kind of wood
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